KR101753922B1 - 수소의 전기화학적 분리 및 수소의 물로의 전기화학적 반응을 포함하는, 탄화수소의 아미노탄화수소로의 직접 아미노화 방법 - Google Patents

수소의 전기화학적 분리 및 수소의 물로의 전기화학적 반응을 포함하는, 탄화수소의 아미노탄화수소로의 직접 아미노화 방법 Download PDF

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KR101753922B1
KR101753922B1 KR1020127003641A KR20127003641A KR101753922B1 KR 101753922 B1 KR101753922 B1 KR 101753922B1 KR 1020127003641 A KR1020127003641 A KR 1020127003641A KR 20127003641 A KR20127003641 A KR 20127003641A KR 101753922 B1 KR101753922 B1 KR 101753922B1
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hydrogen
hydrocarbons
membrane
amino
hydrocarbon
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KR20120046742A (ko
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페트르 쿠바넥
알렉산더 판첸코
안드레아스 피셔
토마스 하이데만
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바스프 에스이
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C209/00—Preparation of compounds containing amino groups bound to a carbon skeleton
    • C07C209/02—Preparation of compounds containing amino groups bound to a carbon skeleton by substitution of hydrogen atoms by amino groups
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B3/00—Electrolytic production of organic compounds
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B3/00—Electrolytic production of organic compounds
    • C25B3/01—Products
    • C25B3/09—Nitrogen containing compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2256/00—Main component in the product gas stream after treatment
    • B01D2256/16—Hydrogen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/10—Single element gases other than halogens
    • B01D2257/108—Hydrogen
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/582—Recycling of unreacted starting or intermediate materials

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
  • Electrodes For Compound Or Non-Metal Manufacture (AREA)
KR1020127003641A 2009-07-10 2010-07-07 수소의 전기화학적 분리 및 수소의 물로의 전기화학적 반응을 포함하는, 탄화수소의 아미노탄화수소로의 직접 아미노화 방법 Active KR101753922B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP09165224 2009-07-10
EP09165224.8 2009-07-10
PCT/EP2010/059710 WO2011003933A2 (de) 2009-07-10 2010-07-07 Verfahren zur direktaminierung von kohlenwasserstoffen zu aminokohlenwasserstoffen mit elektrochemischer abtrennung von wasserstoff und elektrochemischer umsetzung des wasserstoffs zu wasser

Publications (2)

Publication Number Publication Date
KR20120046742A KR20120046742A (ko) 2012-05-10
KR101753922B1 true KR101753922B1 (ko) 2017-07-04

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KR1020127003641A Active KR101753922B1 (ko) 2009-07-10 2010-07-07 수소의 전기화학적 분리 및 수소의 물로의 전기화학적 반응을 포함하는, 탄화수소의 아미노탄화수소로의 직접 아미노화 방법

Country Status (10)

Country Link
US (1) US8642810B2 (enExample)
EP (1) EP2451770B1 (enExample)
JP (1) JP5800808B2 (enExample)
KR (1) KR101753922B1 (enExample)
CN (1) CN102548953B (enExample)
BR (1) BR112012000625A2 (enExample)
ES (1) ES2533702T3 (enExample)
HU (1) HUE024550T2 (enExample)
PT (1) PT2451770E (enExample)
WO (1) WO2011003933A2 (enExample)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
PT104812A (pt) * 2009-11-06 2011-05-06 Cuf Qu Micos Ind S A Reactor catal?tico de membrana com bombagem electroqu?mica de hidrog?nio ou de oxig?nio e suas aplica??es
WO2013131864A1 (de) 2012-03-06 2013-09-12 Basf Se Verfahren zur herstellung von aminokohlenwasserstoffen durch direktaminierung von kohlenwasserstoffen
WO2013131723A1 (de) 2012-03-06 2013-09-12 Basf Se Verfahren zur herstellung von aminokohlenwasserstoffen durch direktaminierung von kohlenwasserstoffen
PT106860A (pt) * 2013-03-28 2014-09-29 Cuf Químicos Ind S A Conjunto elétrodos/eletrólito, reator e método para a aminação direta de hidrocarbonetos
US9770688B2 (en) 2015-10-22 2017-09-26 King Fahd University Of Petroleum And Minerals Si—Y nanocomposite membrane and methods of making and use thereof
JP6691247B1 (ja) * 2019-01-22 2020-04-28 東京瓦斯株式会社 反応装置及び燃料電池発電システム
CN115710185B (zh) * 2021-08-23 2024-05-03 中国石油化工股份有限公司 利用金属碳化物催化剂生产甲胺的方法

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2006286397A (ja) 2005-03-31 2006-10-19 Espec Corp 固体電解質膜構造体とその製造方法、イオン伝導度測定装置
JP2008513336A (ja) 2004-09-14 2008-05-01 本田技研工業株式会社 水素分離方法及び装置
JP2009506090A (ja) 2005-08-30 2009-02-12 ビーエーエスエフ ソシエタス・ヨーロピア 炭化水素の直接アミノ化

Family Cites Families (31)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB738515A (en) * 1952-04-01 1955-10-12 Rohm & Haas Improvements in or relating to a process of producing amines
US3919155A (en) 1970-12-18 1975-11-11 Du Pont Synthesis of aromatic amines by reaction of aromatic compounds with ammonia
US3929889A (en) 1971-02-16 1975-12-30 Du Pont Synthesis of aromatic amines by reaction of aromatic compounds with ammonia
US4031106A (en) 1973-12-19 1977-06-21 E. I. Du Pont De Nemours And Company Synthesis of aromatic amines by reaction of aromatic compounds with ammonia
US4001260A (en) 1973-12-19 1977-01-04 E. I. Du Pont De Nemours And Company Synthesis of aromatic amines by reaction of aromatic compounds with ammonia
AU8742598A (en) 1997-08-21 1999-03-16 Huntsman International Llc Process for the production of aromatic amines
US5879828A (en) * 1997-10-10 1999-03-09 Minnesota Mining And Manufacturing Company Membrane electrode assembly
JP3978757B2 (ja) * 1998-08-05 2007-09-19 株式会社ジーエス・ユアサコーポレーション 燃料電池用ガス拡散電極−電解質膜接合体およびその製造方法
WO2000069804A1 (en) 1999-05-13 2000-11-23 Symyx Technologies Inc. Amination of aromatic hydrocarbons and heterocyclic analogs thereof
JP3740677B2 (ja) * 2002-10-31 2006-02-01 長一 古屋 ガス拡散電極及びその製造方法
CN101351268B (zh) * 2005-12-28 2012-06-13 株式会社日立制作所 具有脱氢作用或加氢作用的催化剂及用该催化剂的燃料电池和氢贮藏、供给装置
US7741522B2 (en) 2006-02-24 2010-06-22 Basf Aktiengesellschaft Direct amination of hydrocarbons
US7838702B2 (en) 2006-02-24 2010-11-23 Basf Se Direct amination of hydrocarbons
JP2007287357A (ja) * 2006-04-12 2007-11-01 Denso Corp 熱再生型の燃料電池システムならびに燃料電池の燃料循環方法
CN101489978A (zh) 2006-07-21 2009-07-22 巴斯夫欧洲公司 烃的直接胺化方法
US20080199774A1 (en) * 2007-02-20 2008-08-21 Commonwealth Scientific And Industrial Research Organisation Membrane electrode assembly with electrode support
CN101903092B (zh) 2007-12-21 2013-03-20 巴斯夫欧洲公司 生产胺的方法
EP2225030B1 (de) 2007-12-21 2012-04-18 Basf Se Verfahren zur herstellung eines amins
WO2009080515A1 (de) 2007-12-21 2009-07-02 Basf Se Verfahren zur herstellung eines amins
EP2225031A1 (de) 2007-12-21 2010-09-08 Basf Se Verfahren zur herstellung eines amins
EP2225029B1 (de) 2007-12-21 2016-08-03 Basf Se Verfahren und katalysator zur herstellung eines amins
WO2009080509A1 (de) 2007-12-21 2009-07-02 Basf Se Verfahren zur herstellung eines amins
WO2009080510A1 (de) 2007-12-21 2009-07-02 Basf Se Verfahren zur herstellung eines amins
US8742189B2 (en) 2008-04-08 2014-06-03 Basf Se Catalyst for the dehydroaromatisation of methane and mixtures containing methane
WO2010000600A1 (de) 2008-06-30 2010-01-07 Basf Se Verfahren zur elektrochemischen direktaminierung von kohlenwasserstoffen
EA020793B9 (ru) 2009-04-06 2015-05-29 Басф Се Способ электрохимического отделения водорода из реакционной смеси
EA020178B1 (ru) 2009-04-06 2014-09-30 Басф Се Способ превращения природного газа в ароматические углеводороды с электрохимическим отделением водорода и электрохимическим превращением водорода в воду
EP2417084B1 (de) 2009-04-06 2014-11-26 Basf Se Verfahren zur umsetzung von erdgas zu aromaten mit elektrochemischer abtrennung von wasserstoff unter erzeugung von elektrischem strom und wasserstoff
CN102459067B (zh) 2009-04-06 2015-08-19 巴斯夫欧洲公司 使天然气反应成芳族烃同时电化学分离氢气的方法
WO2011003934A2 (de) 2009-07-10 2011-01-13 Basf Se Verfahren zur direktaminierung von kohlenwasserstoffen zu aminokohlenwasserstoffen mit elektrochemischer abtrennung von wasserstoff
WO2011003932A2 (de) 2009-07-10 2011-01-13 Basf Se Verfahren zur direktaminierung von kohlenwasserstoffen zu aminokohlenwasserstoffen mit elektrochemischer abtrennung von wasserstoff

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2008513336A (ja) 2004-09-14 2008-05-01 本田技研工業株式会社 水素分離方法及び装置
JP2006286397A (ja) 2005-03-31 2006-10-19 Espec Corp 固体電解質膜構造体とその製造方法、イオン伝導度測定装置
JP2009506090A (ja) 2005-08-30 2009-02-12 ビーエーエスエフ ソシエタス・ヨーロピア 炭化水素の直接アミノ化

Also Published As

Publication number Publication date
US20120107707A1 (en) 2012-05-03
WO2011003933A3 (de) 2011-05-19
ES2533702T3 (es) 2015-04-14
BR112012000625A2 (pt) 2016-02-10
EP2451770B1 (de) 2015-01-07
US8642810B2 (en) 2014-02-04
CN102548953A (zh) 2012-07-04
PT2451770E (pt) 2015-03-04
JP2012532984A (ja) 2012-12-20
CN102548953B (zh) 2014-10-08
WO2011003933A2 (de) 2011-01-13
HUE024550T2 (en) 2016-02-29
EP2451770A2 (de) 2012-05-16
KR20120046742A (ko) 2012-05-10
JP5800808B2 (ja) 2015-10-28

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