KR101717073B1 - 필름 형성 특성이 개선된 플루오로중합체 수성 하이브리드 조성물 - Google Patents
필름 형성 특성이 개선된 플루오로중합체 수성 하이브리드 조성물 Download PDFInfo
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- KR101717073B1 KR101717073B1 KR1020117000296A KR20117000296A KR101717073B1 KR 101717073 B1 KR101717073 B1 KR 101717073B1 KR 1020117000296 A KR1020117000296 A KR 1020117000296A KR 20117000296 A KR20117000296 A KR 20117000296A KR 101717073 B1 KR101717073 B1 KR 101717073B1
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- fluoropolymer
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- polymer
- monomer
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- 239000000203 mixture Substances 0.000 title claims abstract description 182
- 229920002313 fluoropolymer Polymers 0.000 title claims abstract description 108
- 239000004811 fluoropolymer Substances 0.000 title claims abstract description 108
- 230000015572 biosynthetic process Effects 0.000 title description 3
- 239000000178 monomer Substances 0.000 claims abstract description 170
- 239000006185 dispersion Substances 0.000 claims abstract description 39
- 229920002554 vinyl polymer Polymers 0.000 claims description 60
- 229920000642 polymer Polymers 0.000 claims description 31
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 31
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims description 22
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- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 claims description 15
- 238000000034 method Methods 0.000 claims description 14
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- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 claims description 8
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- IBDVWXAVKPRHCU-UHFFFAOYSA-N 2-(2-methylprop-2-enoyloxy)ethyl 3-oxobutanoate Chemical compound CC(=O)CC(=O)OCCOC(=O)C(C)=C IBDVWXAVKPRHCU-UHFFFAOYSA-N 0.000 claims description 3
- 239000004606 Fillers/Extenders Substances 0.000 claims description 3
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- SUPCQIBBMFXVTL-UHFFFAOYSA-N ethyl 2-methylprop-2-enoate Chemical compound CCOC(=O)C(C)=C SUPCQIBBMFXVTL-UHFFFAOYSA-N 0.000 claims description 3
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 3
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- HCDGVLDPFQMKDK-UHFFFAOYSA-N hexafluoropropylene Chemical group FC(F)=C(F)C(F)(F)F HCDGVLDPFQMKDK-UHFFFAOYSA-N 0.000 claims description 2
- 238000000518 rheometry Methods 0.000 claims description 2
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- 239000000463 material Substances 0.000 description 14
- BTBJBAZGXNKLQC-UHFFFAOYSA-N ammonium lauryl sulfate Chemical compound [NH4+].CCCCCCCCCCCCOS([O-])(=O)=O BTBJBAZGXNKLQC-UHFFFAOYSA-N 0.000 description 12
- 229940063953 ammonium lauryl sulfate Drugs 0.000 description 12
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 11
- 239000000243 solution Substances 0.000 description 11
- 239000002904 solvent Substances 0.000 description 11
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- 238000009472 formulation Methods 0.000 description 9
- 239000003795 chemical substances by application Substances 0.000 description 8
- OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 7
- 239000002033 PVDF binder Substances 0.000 description 7
- 150000001875 compounds Chemical class 0.000 description 7
- 229920001577 copolymer Polymers 0.000 description 7
- 238000006116 polymerization reaction Methods 0.000 description 7
- 229920002981 polyvinylidene fluoride Polymers 0.000 description 7
- 238000002360 preparation method Methods 0.000 description 7
- WAEVWDZKMBQDEJ-UHFFFAOYSA-N 2-[2-(2-methoxypropoxy)propoxy]propan-1-ol Chemical compound COC(C)COC(C)COC(C)CO WAEVWDZKMBQDEJ-UHFFFAOYSA-N 0.000 description 6
- 125000001153 fluoro group Chemical group F* 0.000 description 6
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- AVTLBBWTUPQRAY-UHFFFAOYSA-N 2-(2-cyanobutan-2-yldiazenyl)-2-methylbutanenitrile Chemical compound CCC(C)(C#N)N=NC(C)(CC)C#N AVTLBBWTUPQRAY-UHFFFAOYSA-N 0.000 description 5
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 5
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 5
- 229910052786 argon Inorganic materials 0.000 description 5
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- 235000013351 cheese Nutrition 0.000 description 5
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- 229920001519 homopolymer Polymers 0.000 description 5
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 description 5
- 239000011342 resin composition Substances 0.000 description 5
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- 238000012360 testing method Methods 0.000 description 5
- ORDRGXFSRBRQQG-UHFFFAOYSA-N 6-methylheptyl 2-sulfanylpropanoate Chemical compound CC(C)CCCCCOC(=O)C(C)S ORDRGXFSRBRQQG-UHFFFAOYSA-N 0.000 description 4
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 4
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 4
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 4
- 239000007864 aqueous solution Substances 0.000 description 4
- 238000001035 drying Methods 0.000 description 4
- 230000007613 environmental effect Effects 0.000 description 4
- 239000000843 powder Substances 0.000 description 4
- 230000008569 process Effects 0.000 description 4
- QTKPMCIBUROOGY-UHFFFAOYSA-N 2,2,2-trifluoroethyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCC(F)(F)F QTKPMCIBUROOGY-UHFFFAOYSA-N 0.000 description 3
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 239000006229 carbon black Substances 0.000 description 3
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- 230000000052 comparative effect Effects 0.000 description 3
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- XOFYZVNMUHMLCC-ZPOLXVRWSA-N prednisone Chemical compound O=C1C=C[C@]2(C)[C@H]3C(=O)C[C@](C)([C@@](CC4)(O)C(=O)CO)[C@@H]4[C@@H]3CCC2=C1 XOFYZVNMUHMLCC-ZPOLXVRWSA-N 0.000 description 3
- 150000003254 radicals Chemical class 0.000 description 3
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- MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 description 2
- FRIBMENBGGCKPD-UHFFFAOYSA-N 3-(2,3-dimethoxyphenyl)prop-2-enal Chemical compound COC1=CC=CC(C=CC=O)=C1OC FRIBMENBGGCKPD-UHFFFAOYSA-N 0.000 description 2
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
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- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 2
- SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 description 2
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- JRKICGRDRMAZLK-UHFFFAOYSA-L persulfate group Chemical group S(=O)(=O)([O-])OOS(=O)(=O)[O-] JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 description 2
- 239000003505 polymerization initiator Substances 0.000 description 2
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- XWGJFPHUCFXLBL-UHFFFAOYSA-M rongalite Chemical compound [Na+].OCS([O-])=O XWGJFPHUCFXLBL-UHFFFAOYSA-M 0.000 description 2
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- CFVWNXQPGQOHRJ-UHFFFAOYSA-N 2-methylpropyl prop-2-enoate Chemical compound CC(C)COC(=O)C=C CFVWNXQPGQOHRJ-UHFFFAOYSA-N 0.000 description 1
- GNSFRPWPOGYVLO-UHFFFAOYSA-N 3-hydroxypropyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCCO GNSFRPWPOGYVLO-UHFFFAOYSA-N 0.000 description 1
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- PNXMTCDJUBJHQJ-UHFFFAOYSA-N propyl prop-2-enoate Chemical compound CCCOC(=O)C=C PNXMTCDJUBJHQJ-UHFFFAOYSA-N 0.000 description 1
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- CHQMHPLRPQMAMX-UHFFFAOYSA-L sodium persulfate Substances [Na+].[Na+].[O-]S(=O)(=O)OOS([O-])(=O)=O CHQMHPLRPQMAMX-UHFFFAOYSA-L 0.000 description 1
- AKHNMLFCWUSKQB-UHFFFAOYSA-L sodium thiosulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=S AKHNMLFCWUSKQB-UHFFFAOYSA-L 0.000 description 1
- 235000019345 sodium thiosulphate Nutrition 0.000 description 1
- PPASLZSBLFJQEF-RXSVEWSESA-M sodium-L-ascorbate Chemical compound [Na+].OC[C@H](O)[C@H]1OC(=O)C(O)=C1[O-] PPASLZSBLFJQEF-RXSVEWSESA-M 0.000 description 1
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- 239000011755 sodium-L-ascorbate Substances 0.000 description 1
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- PANBYUAFMMOFOV-UHFFFAOYSA-N sodium;sulfuric acid Chemical compound [Na].OS(O)(=O)=O PANBYUAFMMOFOV-UHFFFAOYSA-N 0.000 description 1
- 238000001694 spray drying Methods 0.000 description 1
- 238000010561 standard procedure Methods 0.000 description 1
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- 239000008399 tap water Substances 0.000 description 1
- 235000020679 tap water Nutrition 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
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- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
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- JREYOWJEWZVAOR-UHFFFAOYSA-N triazanium;[3-methylbut-3-enoxy(oxido)phosphoryl] phosphate Chemical compound [NH4+].[NH4+].[NH4+].CC(=C)CCOP([O-])(=O)OP([O-])([O-])=O JREYOWJEWZVAOR-UHFFFAOYSA-N 0.000 description 1
- 239000000326 ultraviolet stabilizing agent Substances 0.000 description 1
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- NLVXSWCKKBEXTG-UHFFFAOYSA-N vinylsulfonic acid Chemical class OS(=O)(=O)C=C NLVXSWCKKBEXTG-UHFFFAOYSA-N 0.000 description 1
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Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F259/00—Macromolecular compounds obtained by polymerising monomers on to polymers of halogen containing monomers as defined in group C08F14/00
- C08F259/08—Macromolecular compounds obtained by polymerising monomers on to polymers of halogen containing monomers as defined in group C08F14/00 on to polymers containing fluorine
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F14/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
- C08F14/18—Monomers containing fluorine
- C08F14/22—Vinylidene fluoride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/12—Polymerisation in non-solvents
- C08F2/16—Aqueous medium
- C08F2/22—Emulsion polymerisation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F285/00—Macromolecular compounds obtained by polymerising monomers on to preformed graft polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/003—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D151/00—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers
- C09D151/003—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers grafted on to macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/04—Homopolymers or copolymers of esters
- C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
- C08L33/062—Copolymers with monomers not covered by C08L33/06
- C08L33/066—Copolymers with monomers not covered by C08L33/06 containing -OH groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/04—Homopolymers or copolymers of esters
- C08L33/14—Homopolymers or copolymers of esters of esters containing halogen, nitrogen, sulfur, or oxygen atoms in addition to the carboxy oxygen
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Graft Or Block Polymers (AREA)
- Paints Or Removers (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Polymerisation Methods In General (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US7861908P | 2008-07-07 | 2008-07-07 | |
| US61/078,619 | 2008-07-07 | ||
| PCT/US2009/047769 WO2010005756A1 (en) | 2008-07-07 | 2009-06-18 | Fluoropolymer aqueous hybrid compositions with improved film formation |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| KR20110041460A KR20110041460A (ko) | 2011-04-21 |
| KR101717073B1 true KR101717073B1 (ko) | 2017-03-16 |
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| KR1020117000296A Active KR101717073B1 (ko) | 2008-07-07 | 2009-06-18 | 필름 형성 특성이 개선된 플루오로중합체 수성 하이브리드 조성물 |
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| US (1) | US20110118403A1 (enExample) |
| EP (1) | EP2297215B1 (enExample) |
| JP (1) | JP5698127B2 (enExample) |
| KR (1) | KR101717073B1 (enExample) |
| CN (1) | CN102083876B (enExample) |
| WO (1) | WO2010005756A1 (enExample) |
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| EP2611840B1 (en) | 2010-09-01 | 2019-03-27 | Arkema, Inc. | Method of producing fluoropolymers using acid-functionalized monomers |
| JP5472507B2 (ja) * | 2012-03-27 | 2014-04-16 | ダイキン工業株式会社 | フルオロポリマー水性分散液 |
| EP2838964B1 (en) * | 2012-04-17 | 2019-05-22 | Arkema, Inc. | Process for coating a glass substrate with an aqueous fluroropolymer coating |
| US10399892B2 (en) | 2012-04-17 | 2019-09-03 | Arkema Inc. | Aqueous fluoropolymer glass coating |
| JP2014152186A (ja) * | 2013-02-05 | 2014-08-25 | Jsr Corp | 水性フッ素樹脂組成物 |
| AR099038A1 (es) | 2014-01-08 | 2016-06-22 | General Cable Tech Corp | Conductor aéreo recubierto |
| US10533109B2 (en) | 2014-07-01 | 2020-01-14 | Arkema Inc. | Stable aqueous fluoropolymer coating composition |
| CN106488961B (zh) * | 2014-07-14 | 2020-04-10 | 3M创新有限公司 | 包含氟化共聚物的共形涂料组合物 |
| WO2016022687A1 (en) | 2014-08-05 | 2016-02-11 | General Cable Technologies Corporation | Fluoro copolymer coatings for overhead conductors |
| JP7301010B2 (ja) * | 2015-09-09 | 2023-06-30 | ダイキン工業株式会社 | 複合重合体粒子及びその製造方法 |
| JP6701648B2 (ja) * | 2015-09-09 | 2020-05-27 | ダイキン工業株式会社 | 複合重合体粒子及びその製造方法 |
| EP3374453B1 (en) * | 2015-11-13 | 2020-01-08 | General Cable Technologies Corporation | Cables coated with fluorocopolymer coatings |
| CN107735418B (zh) * | 2015-11-25 | 2020-12-08 | 阿科玛股份有限公司 | 具有改善的机械阻尼的氟聚合物组合物 |
| WO2017122700A1 (ja) * | 2016-01-14 | 2017-07-20 | 旭硝子株式会社 | 水性分散液、その製造方法、水性塗料および塗装物品 |
| WO2017197220A1 (en) | 2016-05-13 | 2017-11-16 | Arkema Inc. | Compositions based on fluoropolymers, fluoropolymer-miscible polymers and free radically-curable components |
| WO2018145263A1 (en) * | 2017-02-08 | 2018-08-16 | Akzo Nobel Coatings International B.V. | A coating composition, the preparation method therefore and use thereof |
| FR3067715B1 (fr) * | 2017-06-15 | 2019-07-05 | Arkema France | Encre a base de polymere fluore presentant une adhesion amelioree |
| US20210197130A1 (en) * | 2018-06-08 | 2021-07-01 | Arkema Inc. | Fluoropolymer latex coatings for membranes |
| CN109851705A (zh) * | 2019-03-20 | 2019-06-07 | 济南大学 | 一种一锅法制备分子量可控的四氟乙烯共聚物的方法 |
| KR20220024179A (ko) * | 2019-06-25 | 2022-03-03 | 알케마 인코포레이티드 | 리튬 이온 전지를 위한 플루오로중합체로 코팅된 분리막 |
| KR20220162685A (ko) | 2020-03-31 | 2022-12-08 | 도레이 카부시키가이샤 | 중합체 입자 |
| WO2022140149A1 (en) * | 2020-12-23 | 2022-06-30 | Arkema Inc. | Novel pvdf powder for reduced dispersion viscosity coatings |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5756573A (en) | 1995-10-05 | 1998-05-26 | Sc Johnson Commerical Markets, Inc. | Seed polymerized latex polymer having a gradient polymeric morphology and process for preparing the same |
| US7183356B2 (en) | 2001-10-23 | 2007-02-27 | Asahi Glass Company, Limited | Fluororesin powder coating composition |
Family Cites Families (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4537916A (en) * | 1984-06-25 | 1985-08-27 | The Dow Chemical Company | Structured latex particles which are film forming and a process for their preparation |
| EP0360575B1 (en) * | 1988-09-20 | 1993-12-29 | Japan Synthetic Rubber Co., Ltd. | Aqueous fluorine-containing polymer dispersion and aqueous dispersion containing fluorine-containing polymer and water-soluble resin and/or water dispersible resin |
| US5349003A (en) * | 1988-09-20 | 1994-09-20 | Japan Synthetic Rubber Co., Ltd. | Aqueous fluorine-containing polymer dispersion and aqueous dispersion containing fluorine-containing polymer and water-soluble resin and/or water dispersible resin |
| JP3227705B2 (ja) * | 1993-09-22 | 2001-11-12 | ダイキン工業株式会社 | 含フッ素共重合体水性分散液 |
| JPH07258499A (ja) * | 1994-03-23 | 1995-10-09 | Japan Synthetic Rubber Co Ltd | 含フッ素重合体水性分散液 |
| DE69500430T2 (de) * | 1994-04-01 | 1998-02-26 | Toagosei Co | Wässrige, fluorhaltige Anstrichzusammensetzung und Herstellungsverfahren |
| CA2156975A1 (en) * | 1994-08-26 | 1996-02-27 | Yoshihiro Maeyama | Aqueous resin dispersion |
| JP3298321B2 (ja) * | 1994-08-31 | 2002-07-02 | ダイキン工業株式会社 | ビニリデンフルオライド系共重合体水性分散液、ビニリデンフルオライド系シード重合体水性分散液およびそれらの製法 |
| US6680357B1 (en) * | 1999-07-14 | 2004-01-20 | Atofina Chemicals, Inc. | Crosslinkable aqueous fluoropolymer based dispersions |
| DE10049791A1 (de) * | 2000-10-09 | 2002-04-18 | Basf Ag | Pigmenthaltige Beschichtungsmittel auf Wasserbasis |
| US7081216B2 (en) * | 2001-02-15 | 2006-07-25 | Arkema Inc. | Foams and coatings |
| JP4103399B2 (ja) * | 2002-01-22 | 2008-06-18 | 旭硝子株式会社 | 含フッ素樹脂粉体塗料組成物および塗膜を有する物品 |
| JP2003231722A (ja) * | 2002-02-13 | 2003-08-19 | Daikin Ind Ltd | フッ素樹脂水性分散組成物 |
| US7893157B2 (en) * | 2002-08-26 | 2011-02-22 | Rohm And Haas Company | Polymeric compositions having low glass transition temperatures |
| US7803867B2 (en) * | 2005-05-19 | 2010-09-28 | Arkema Inc. | Highly weatherable roof coatings containing aqueous fluoropolymer dispersions |
| WO2007026949A1 (en) * | 2005-09-02 | 2007-03-08 | Nippon Shokubai Co., Ltd. | Emulsion type resin composition |
| JP2007145977A (ja) * | 2005-11-28 | 2007-06-14 | Dainippon Ink & Chem Inc | 水性コーティング液及び機能性皮膜 |
-
2009
- 2009-06-18 US US13/001,878 patent/US20110118403A1/en not_active Abandoned
- 2009-06-18 JP JP2011517454A patent/JP5698127B2/ja active Active
- 2009-06-18 CN CN200980126789.2A patent/CN102083876B/zh active Active
- 2009-06-18 WO PCT/US2009/047769 patent/WO2010005756A1/en not_active Ceased
- 2009-06-18 KR KR1020117000296A patent/KR101717073B1/ko active Active
- 2009-06-18 EP EP09794948.1A patent/EP2297215B1/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5756573A (en) | 1995-10-05 | 1998-05-26 | Sc Johnson Commerical Markets, Inc. | Seed polymerized latex polymer having a gradient polymeric morphology and process for preparing the same |
| US7183356B2 (en) | 2001-10-23 | 2007-02-27 | Asahi Glass Company, Limited | Fluororesin powder coating composition |
Also Published As
| Publication number | Publication date |
|---|---|
| US20110118403A1 (en) | 2011-05-19 |
| JP2011527374A (ja) | 2011-10-27 |
| JP5698127B2 (ja) | 2015-04-08 |
| CN102083876A (zh) | 2011-06-01 |
| EP2297215A1 (en) | 2011-03-23 |
| KR20110041460A (ko) | 2011-04-21 |
| EP2297215A4 (en) | 2012-09-05 |
| WO2010005756A1 (en) | 2010-01-14 |
| EP2297215B1 (en) | 2016-07-27 |
| CN102083876B (zh) | 2014-01-01 |
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