KR101677672B1 - 건축폐기물을 이용한 고순도 합성 제올라이트 대량생산 제조방법 - Google Patents
건축폐기물을 이용한 고순도 합성 제올라이트 대량생산 제조방법 Download PDFInfo
- Publication number
- KR101677672B1 KR101677672B1 KR1020160050957A KR20160050957A KR101677672B1 KR 101677672 B1 KR101677672 B1 KR 101677672B1 KR 1020160050957 A KR1020160050957 A KR 1020160050957A KR 20160050957 A KR20160050957 A KR 20160050957A KR 101677672 B1 KR101677672 B1 KR 101677672B1
- Authority
- KR
- South Korea
- Prior art keywords
- zeolite
- weight
- parts
- pulverized
- clay brick
- Prior art date
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- 239000010457 zeolite Substances 0.000 title claims abstract description 100
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 39
- 239000002699 waste material Substances 0.000 title claims abstract description 37
- 238000010276 construction Methods 0.000 title abstract description 12
- 230000015572 biosynthetic process Effects 0.000 title description 9
- 238000003786 synthesis reaction Methods 0.000 title description 8
- 229910021536 Zeolite Inorganic materials 0.000 claims abstract description 99
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims abstract description 97
- 239000011449 brick Substances 0.000 claims abstract description 92
- 239000004927 clay Substances 0.000 claims abstract description 69
- 238000000034 method Methods 0.000 claims abstract description 67
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 30
- 239000004035 construction material Substances 0.000 claims abstract description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical group [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 36
- 239000000463 material Substances 0.000 claims description 32
- 238000002425 crystallisation Methods 0.000 claims description 27
- 230000008025 crystallization Effects 0.000 claims description 27
- 239000003513 alkali Substances 0.000 claims description 26
- 229910044991 metal oxide Inorganic materials 0.000 claims description 26
- 150000004706 metal oxides Chemical class 0.000 claims description 26
- 239000004566 building material Substances 0.000 claims description 19
- 239000000203 mixture Substances 0.000 claims description 19
- 229910018072 Al 2 O 3 Inorganic materials 0.000 claims description 17
- 229910004298 SiO 2 Inorganic materials 0.000 claims description 17
- 229910052782 aluminium Inorganic materials 0.000 claims description 17
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 17
- 238000002156 mixing Methods 0.000 claims description 17
- 239000000843 powder Substances 0.000 claims description 17
- 239000000126 substance Substances 0.000 claims description 17
- 238000010438 heat treatment Methods 0.000 claims description 15
- 239000011812 mixed powder Substances 0.000 claims description 14
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 12
- 229910010413 TiO 2 Inorganic materials 0.000 claims description 11
- 230000032683 aging Effects 0.000 claims description 10
- 230000004927 fusion Effects 0.000 claims description 10
- 239000013078 crystal Substances 0.000 claims description 8
- 238000001035 drying Methods 0.000 claims description 8
- 238000003756 stirring Methods 0.000 claims description 7
- 239000011734 sodium Substances 0.000 claims description 6
- 229910000029 sodium carbonate Inorganic materials 0.000 claims description 6
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 claims description 4
- 238000005406 washing Methods 0.000 claims description 3
- 230000008569 process Effects 0.000 abstract description 47
- 239000002689 soil Substances 0.000 abstract description 10
- 238000010828 elution Methods 0.000 abstract description 5
- 239000003795 chemical substances by application Substances 0.000 abstract description 4
- 230000000694 effects Effects 0.000 abstract description 4
- 230000007547 defect Effects 0.000 abstract description 2
- 239000000047 product Substances 0.000 description 13
- 239000002994 raw material Substances 0.000 description 9
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 6
- -1 loess Substances 0.000 description 6
- 238000010298 pulverizing process Methods 0.000 description 6
- 239000002245 particle Substances 0.000 description 5
- 235000017550 sodium carbonate Nutrition 0.000 description 5
- 238000013019 agitation Methods 0.000 description 4
- 238000007499 fusion processing Methods 0.000 description 4
- 238000001027 hydrothermal synthesis Methods 0.000 description 4
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 3
- 239000010882 bottom ash Substances 0.000 description 3
- 239000012459 cleaning agent Substances 0.000 description 3
- 238000010924 continuous production Methods 0.000 description 3
- 239000012153 distilled water Substances 0.000 description 3
- 238000009408 flooring Methods 0.000 description 3
- 239000010881 fly ash Substances 0.000 description 3
- 239000008187 granular material Substances 0.000 description 3
- 238000004064 recycling Methods 0.000 description 3
- 239000005995 Aluminium silicate Substances 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 238000002441 X-ray diffraction Methods 0.000 description 2
- 239000003463 adsorbent Substances 0.000 description 2
- 235000012211 aluminium silicate Nutrition 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 2
- 239000011230 binding agent Substances 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 239000004568 cement Substances 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 230000002950 deficient Effects 0.000 description 2
- 230000018044 dehydration Effects 0.000 description 2
- 238000006297 dehydration reaction Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000003344 environmental pollutant Substances 0.000 description 2
- 239000003337 fertilizer Substances 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- 238000005469 granulation Methods 0.000 description 2
- 230000003179 granulation Effects 0.000 description 2
- 229910001385 heavy metal Inorganic materials 0.000 description 2
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 231100000719 pollutant Toxicity 0.000 description 2
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 2
- 238000000746 purification Methods 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 235000012239 silicon dioxide Nutrition 0.000 description 2
- 239000004575 stone Substances 0.000 description 2
- 230000002194 synthesizing effect Effects 0.000 description 2
- 239000002351 wastewater Substances 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- 244000205754 Colocasia esculenta Species 0.000 description 1
- 235000006481 Colocasia esculenta Nutrition 0.000 description 1
- 241000195493 Cryptophyta Species 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- YKTSYUJCYHOUJP-UHFFFAOYSA-N [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] Chemical compound [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] YKTSYUJCYHOUJP-UHFFFAOYSA-N 0.000 description 1
- 238000004887 air purification Methods 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 235000019730 animal feed additive Nutrition 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 229910052788 barium Inorganic materials 0.000 description 1
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 1
- RQPZNWPYLFFXCP-UHFFFAOYSA-L barium dihydroxide Chemical compound [OH-].[OH-].[Ba+2] RQPZNWPYLFFXCP-UHFFFAOYSA-L 0.000 description 1
- 229910001863 barium hydroxide Inorganic materials 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 1
- 239000000920 calcium hydroxide Substances 0.000 description 1
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 1
- 239000000701 coagulant Substances 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 229910052681 coesite Inorganic materials 0.000 description 1
- 239000013065 commercial product Substances 0.000 description 1
- 239000011456 concrete brick Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 229910052593 corundum Inorganic materials 0.000 description 1
- 229910052906 cristobalite Inorganic materials 0.000 description 1
- 238000004332 deodorization Methods 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 244000144972 livestock Species 0.000 description 1
- 239000010871 livestock manure Substances 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- 239000012452 mother liquor Substances 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 229910000027 potassium carbonate Inorganic materials 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 229910052682 stishovite Inorganic materials 0.000 description 1
- 239000000271 synthetic detergent Substances 0.000 description 1
- 229910052905 tridymite Inorganic materials 0.000 description 1
- 238000009423 ventilation Methods 0.000 description 1
- 239000012855 volatile organic compound Substances 0.000 description 1
- 230000036642 wellbeing Effects 0.000 description 1
- 229910001845 yogo sapphire Inorganic materials 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B09—DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
- B09B—DISPOSAL OF SOLID WASTE NOT OTHERWISE PROVIDED FOR
- B09B3/00—Destroying solid waste or transforming solid waste into something useful or harmless
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
- C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
-
- B09B3/0016—
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B09—DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
- B09B—DISPOSAL OF SOLID WASTE NOT OTHERWISE PROVIDED FOR
- B09B3/00—Destroying solid waste or transforming solid waste into something useful or harmless
- B09B3/80—Destroying solid waste or transforming solid waste into something useful or harmless involving an extraction step
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
- C01F7/00—Compounds of aluminium
- C01F7/02—Aluminium oxide; Aluminium hydroxide; Aluminates
- C01F7/04—Preparation of alkali metal aluminates; Aluminium oxide or hydroxide therefrom
- C01F7/12—Alkali metal aluminates from alkaline-earth metal aluminates
-
- C—CHEMISTRY; METALLURGY
- C30—CRYSTAL GROWTH
- C30B—SINGLE-CRYSTAL GROWTH; UNIDIRECTIONAL SOLIDIFICATION OF EUTECTIC MATERIAL OR UNIDIRECTIONAL DEMIXING OF EUTECTOID MATERIAL; REFINING BY ZONE-MELTING OF MATERIAL; PRODUCTION OF A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; SINGLE CRYSTALS OR HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; AFTER-TREATMENT OF SINGLE CRYSTALS OR A HOMOGENEOUS POLYCRYSTALLINE MATERIAL WITH DEFINED STRUCTURE; APPARATUS THEREFOR
- C30B29/00—Single crystals or homogeneous polycrystalline material with defined structure characterised by the material or by their shape
- C30B29/10—Inorganic compounds or compositions
- C30B29/34—Silicates
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/58—Construction or demolition [C&D] waste
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Geology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Metallurgy (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Environmental & Geological Engineering (AREA)
- Processing Of Solid Wastes (AREA)
- Silicates, Zeolites, And Molecular Sieves (AREA)
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR1020160050957A KR101677672B1 (ko) | 2016-04-26 | 2016-04-26 | 건축폐기물을 이용한 고순도 합성 제올라이트 대량생산 제조방법 |
| PCT/KR2017/004444 WO2017188727A1 (fr) | 2016-04-26 | 2017-04-26 | Procédé de production en masse de zéolite synthétique de haute pureté à l'aide de déchets de construction |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR1020160050957A KR101677672B1 (ko) | 2016-04-26 | 2016-04-26 | 건축폐기물을 이용한 고순도 합성 제올라이트 대량생산 제조방법 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| KR101677672B1 true KR101677672B1 (ko) | 2016-11-18 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1020160050957A KR101677672B1 (ko) | 2016-04-26 | 2016-04-26 | 건축폐기물을 이용한 고순도 합성 제올라이트 대량생산 제조방법 |
Country Status (2)
| Country | Link |
|---|---|
| KR (1) | KR101677672B1 (fr) |
| WO (1) | WO2017188727A1 (fr) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2017188727A1 (fr) * | 2016-04-26 | 2017-11-02 | 주식회사 지엔티엔에스 | Procédé de production en masse de zéolite synthétique de haute pureté à l'aide de déchets de construction |
| CN112850739A (zh) * | 2021-03-12 | 2021-05-28 | 许昌学院 | 一种大晶粒ltj沸石及其制备方法 |
| KR102393723B1 (ko) | 2021-10-18 | 2022-05-04 | 주식회사 성광이엔텍 | 석유화학공정에서 발생되는 폐촉매를 이용한 합성제올라이트 제조방법 및 그에 의하여 제조된 흡착제 |
| KR102459709B1 (ko) * | 2022-03-30 | 2022-10-28 | 주식회사 성광이엔텍 | 다공성 합성제올라이트볼용 조성물 및 합성제올라이트볼 제조방법 |
| CN115318242A (zh) * | 2022-07-19 | 2022-11-11 | 昆明理工大学 | 一种建筑粘土砖合成不同二氧化碳吸附剂的方法 |
| KR102623570B1 (ko) | 2023-04-20 | 2024-01-11 | 주식회사 성광이엔텍 | 하수 슬러지 가스화 공정에서 발생되는 슬러지잔재물을 이용한 합성 제올라이트 제조방법 및 그에 의하여 제조된 합성제올라이트 |
| KR20240025371A (ko) | 2022-08-18 | 2024-02-27 | 주식회사 성광이엔텍 | 수처리 슬러지를 이용한 합성제올라이트 제조방법 및 이를 통해 제조된 흡착제 |
Families Citing this family (2)
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| KR102472749B1 (ko) * | 2022-01-18 | 2022-12-02 | 주식회사 위엔씨 | 유해가스제거 및 항균탈취기능을 함유한 흡착소재 제조방법 |
| CN114933312A (zh) * | 2022-05-09 | 2022-08-23 | 同济大学 | 一种废弃黏土砖粉合成Na-P型沸石分子筛的方法及其应用 |
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| KR970026966A (ko) * | 1995-11-23 | 1997-06-24 | 김주환 | 산업폐기물을 이용한 경량세라믹 모래 제조방법 |
| KR101138854B1 (ko) | 2009-08-27 | 2012-05-21 | 부산가톨릭대학교 산학협력단 | 실리카 및 알루미나가 포함된 폐기물로부터 합성된 합성 제올라이트 |
| KR101216660B1 (ko) * | 2011-02-10 | 2012-12-31 | 부산가톨릭대학교 산학협력단 | 폐기물로부터 합성 제올라이트를 제조하는 장치 |
| KR20140089631A (ko) * | 2013-01-03 | 2014-07-16 | 주식회사 넥스트윅 | 정수 슬러지를 재활용한 다공성 조습보드용 조성물 및 이를 이용한 다공성 조습보드의 제조방법 |
| KR101602926B1 (ko) | 2015-10-23 | 2016-03-11 | 주식회사 지엔티엔에스 | 경석을 이용한 합성 제올라이트 제조방법 |
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|---|---|---|---|---|
| KR101216659B1 (ko) * | 2011-02-10 | 2012-12-28 | 부산가톨릭대학교 산학협력단 | 폐기물로부터 합성된 합성 제올라이트 |
| KR101602933B1 (ko) * | 2015-11-05 | 2016-03-11 | 주식회사 지엔티엔에스 | 화력발전소의 바닥재를 이용한 합성 제올라이트 제조방법 |
| KR101677672B1 (ko) * | 2016-04-26 | 2016-11-18 | 주식회사 지엔티엔에스 | 건축폐기물을 이용한 고순도 합성 제올라이트 대량생산 제조방법 |
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2016
- 2016-04-26 KR KR1020160050957A patent/KR101677672B1/ko active IP Right Grant
-
2017
- 2017-04-26 WO PCT/KR2017/004444 patent/WO2017188727A1/fr active Application Filing
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR970026966A (ko) * | 1995-11-23 | 1997-06-24 | 김주환 | 산업폐기물을 이용한 경량세라믹 모래 제조방법 |
| KR101138854B1 (ko) | 2009-08-27 | 2012-05-21 | 부산가톨릭대학교 산학협력단 | 실리카 및 알루미나가 포함된 폐기물로부터 합성된 합성 제올라이트 |
| KR101216660B1 (ko) * | 2011-02-10 | 2012-12-31 | 부산가톨릭대학교 산학협력단 | 폐기물로부터 합성 제올라이트를 제조하는 장치 |
| KR20140089631A (ko) * | 2013-01-03 | 2014-07-16 | 주식회사 넥스트윅 | 정수 슬러지를 재활용한 다공성 조습보드용 조성물 및 이를 이용한 다공성 조습보드의 제조방법 |
| KR101602926B1 (ko) | 2015-10-23 | 2016-03-11 | 주식회사 지엔티엔에스 | 경석을 이용한 합성 제올라이트 제조방법 |
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| WO2017188727A1 (fr) * | 2016-04-26 | 2017-11-02 | 주식회사 지엔티엔에스 | Procédé de production en masse de zéolite synthétique de haute pureté à l'aide de déchets de construction |
| CN112850739A (zh) * | 2021-03-12 | 2021-05-28 | 许昌学院 | 一种大晶粒ltj沸石及其制备方法 |
| CN112850739B (zh) * | 2021-03-12 | 2023-07-25 | 许昌学院 | 一种大晶粒ltj沸石及其制备方法 |
| KR102393723B1 (ko) | 2021-10-18 | 2022-05-04 | 주식회사 성광이엔텍 | 석유화학공정에서 발생되는 폐촉매를 이용한 합성제올라이트 제조방법 및 그에 의하여 제조된 흡착제 |
| KR102459709B1 (ko) * | 2022-03-30 | 2022-10-28 | 주식회사 성광이엔텍 | 다공성 합성제올라이트볼용 조성물 및 합성제올라이트볼 제조방법 |
| CN115318242A (zh) * | 2022-07-19 | 2022-11-11 | 昆明理工大学 | 一种建筑粘土砖合成不同二氧化碳吸附剂的方法 |
| KR20240025371A (ko) | 2022-08-18 | 2024-02-27 | 주식회사 성광이엔텍 | 수처리 슬러지를 이용한 합성제올라이트 제조방법 및 이를 통해 제조된 흡착제 |
| KR102623570B1 (ko) | 2023-04-20 | 2024-01-11 | 주식회사 성광이엔텍 | 하수 슬러지 가스화 공정에서 발생되는 슬러지잔재물을 이용한 합성 제올라이트 제조방법 및 그에 의하여 제조된 합성제올라이트 |
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