KR101589780B1 - 실릴 에스테르 내부 공여체를 포함하는 전촉매 조성물 및 방법 - Google Patents

실릴 에스테르 내부 공여체를 포함하는 전촉매 조성물 및 방법 Download PDF

Info

Publication number
KR101589780B1
KR101589780B1 KR1020117014608A KR20117014608A KR101589780B1 KR 101589780 B1 KR101589780 B1 KR 101589780B1 KR 1020117014608 A KR1020117014608 A KR 1020117014608A KR 20117014608 A KR20117014608 A KR 20117014608A KR 101589780 B1 KR101589780 B1 KR 101589780B1
Authority
KR
South Korea
Prior art keywords
electron donor
composition
group
pro
carbon atoms
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
KR1020117014608A
Other languages
English (en)
Korean (ko)
Other versions
KR20110094087A (ko
Inventor
린펭 첸
탁 더블유 레웅
타오 타오
Original Assignee
더블유.알. 그레이스 앤드 캄파니-콘.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 더블유.알. 그레이스 앤드 캄파니-콘. filed Critical 더블유.알. 그레이스 앤드 캄파니-콘.
Publication of KR20110094087A publication Critical patent/KR20110094087A/ko
Application granted granted Critical
Publication of KR101589780B1 publication Critical patent/KR101589780B1/ko
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04—Monomers containing three or four carbon atoms
    • C08F10/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
    • C08F4/652—Pretreating with metals or metal-containing compounds
    • C08F4/656—Pretreating with metals or metal-containing compounds with silicon or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/02—Silicon compounds
    • C07F7/08—Compounds having one or more C—Si linkages
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/02—Silicon compounds
    • C07F7/08—Compounds having one or more C—Si linkages
    • C07F7/0803—Compounds with Si-C or Si-Si linkages
    • C07F7/081—Compounds with Si-C or Si-Si linkages comprising at least one atom selected from the elements N, O, halogen, S, Se or Te
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
    • C08F4/651—Pretreating with non-metals or metal-free compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
KR1020117014608A 2008-11-25 2009-11-23 실릴 에스테르 내부 공여체를 포함하는 전촉매 조성물 및 방법 Expired - Fee Related KR101589780B1 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US11782008P 2008-11-25 2008-11-25
US61/117,820 2008-11-25

Publications (2)

Publication Number Publication Date
KR20110094087A KR20110094087A (ko) 2011-08-19
KR101589780B1 true KR101589780B1 (ko) 2016-01-28

Family

ID=41718309

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1020117014608A Expired - Fee Related KR101589780B1 (ko) 2008-11-25 2009-11-23 실릴 에스테르 내부 공여체를 포함하는 전촉매 조성물 및 방법

Country Status (10)

Country Link
US (1) US8088872B2 (https=)
EP (1) EP2350144B1 (https=)
JP (2) JP6081700B2 (https=)
KR (1) KR101589780B1 (https=)
CN (2) CN104059095A (https=)
BR (1) BRPI0916095B1 (https=)
MX (1) MX2011005542A (https=)
RU (1) RU2505548C2 (https=)
SG (1) SG171799A1 (https=)
WO (1) WO2010065361A1 (https=)

Families Citing this family (41)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2350143B1 (en) * 2008-11-25 2016-02-17 W.R. Grace & CO. - CONN. Procatalyst composition multiple internal donor having silyl ester and method
US8088872B2 (en) * 2008-11-25 2012-01-03 Dow Global Technologies Llc Procatalyst composition including silyl ester internal donor and method
EP2681248A1 (en) * 2011-03-01 2014-01-08 Dow Global Technologies LLC Process for improving bulk density with multi-contact procatalyst and product
CN102746426A (zh) * 2011-04-22 2012-10-24 中国石油天然气股份有限公司 一种烯烃聚合催化剂及其制备和应用
EP2707400A1 (en) * 2011-05-13 2014-03-19 Reliance Industries Limited Catalyst system for polymerization of propylene
US9790291B2 (en) 2013-03-14 2017-10-17 Formosa Plastics Corporation, Usa Non-phthalate compounds as electron donors for polyolefin catalysts
EP3033348B1 (en) 2013-08-12 2017-11-29 Saudi Basic Industries Corporation Catalyst system for polymerisation of an olefin
MX2016008039A (es) 2013-12-20 2017-05-12 Saudi Basic Ind Corp Sistema catalizador para polimerizacion de una olefina.
EP3083722B1 (en) 2013-12-20 2021-11-10 Saudi Basic Industries Corporation Catalyst system for polymerisation of an olefin
KR102365377B1 (ko) 2013-12-20 2022-02-21 사우디 베이식 인더스트리즈 코포레이션 올레핀 중합용 촉매 시스템
KR20160102018A (ko) 2013-12-20 2016-08-26 사우디 베이식 인더스트리즈 코포레이션 올레핀 중합용 전구 촉매
BR112016013951B1 (pt) 2013-12-20 2022-02-22 Sabic Global Technologies B.V. Processo para a preparação de um pró-catalisador para polimerização de uma olefina, uso de uma benzamida, composição de catalisador, pró-catalisador e processo para a preparação de poliolefinas compreendendo o mesmo
EP3083723B1 (en) 2013-12-20 2022-01-19 Saudi Basic Industries Corporation Catalyst system for polymerisation of an olefin
EP3083724B1 (en) 2013-12-20 2018-07-25 Saudi Basic Industries Corporation Catalyst system for polymerization of an olefin
US9593184B2 (en) 2014-10-28 2017-03-14 Formosa Plastics Corporation, Usa Oxalic acid diamides as modifiers for polyolefin catalysts
EP3050906B1 (en) * 2015-01-27 2020-07-22 Indian Oil Corporation Limited Catalyst process modification and polymerization thereof
CN107406539B (zh) 2015-03-25 2020-04-07 巴塞尔聚烯烃股份有限公司 连续气相聚合方法
WO2016168108A1 (en) * 2015-04-13 2016-10-20 Basf Corporation Olefin polymerization catalyst component with auxiliary internal electron donor
BR112017026534B1 (pt) 2015-06-12 2021-12-07 Sabic Global Technologies B.V. Copolímero de propileno heterofásico, seu processo para a fabricação e uso, artigo que o compreende
EP3181625A1 (en) 2015-12-18 2017-06-21 SABIC Global Technologies B.V. Composition comprising heterophasic propylene copolymer
US9777084B2 (en) 2016-02-19 2017-10-03 Formosa Plastics Corporation, Usa Catalyst system for olefin polymerization and method for producing olefin polymer
US11427660B2 (en) 2016-08-17 2022-08-30 Formosa Plastics Corporation, Usa Organosilicon compounds as electron donors for olefin polymerization catalysts and methods of making and using same
US9815920B1 (en) 2016-10-14 2017-11-14 Formosa Plastics Corporation, Usa Olefin polymerization catalyst components and process for the production of olefin polymers therewith
US11168158B2 (en) * 2017-03-06 2021-11-09 Braskem America, Inc. Electron donors for ziegler-natta precatalyst preparation and catalyst system for olefin polymerization
EP3596136A1 (en) 2017-03-17 2020-01-22 SABIC Global Technologies B.V. Process for the polymerization of a polyolefin
WO2018167155A1 (en) 2017-03-17 2018-09-20 Sabic Global Technologies B.V. Process of making polyolefins
US10124324B1 (en) 2017-05-09 2018-11-13 Formosa Plastics Corporation, Usa Olefin polymerization catalyst components and process for the production of olefin polymers therewith
US10822438B2 (en) 2017-05-09 2020-11-03 Formosa Plastics Corporation Catalyst system for enhanced stereo-specificity of olefin polymerization and method for producing olefin polymer
CN108440692B (zh) * 2018-04-20 2019-08-27 天津科技大学 催化乙烯聚合Ziegler-Natta催化剂内给电子体、催化剂组分及制备方法
US20210403691A1 (en) 2018-11-19 2021-12-30 Sabic Global Technologies B.V. Food packaging comprising a polymer composition and use of said polymer composition for manufacturing of food packaging
KR20210146976A (ko) * 2019-03-31 2021-12-06 다우 글로벌 테크놀로지스 엘엘씨 촉매 전구체 물질의 제조 방법
WO2021043784A1 (en) 2019-09-06 2021-03-11 Sabic Global Technologies B.V. Healthcare article comprising a random propylene-ethylene copolymer.
CN114426603B (zh) * 2020-10-16 2023-11-14 中国石油化工股份有限公司 乙烯聚合的方法及聚乙烯
CN115433296B (zh) * 2021-06-03 2024-04-05 中国科学院化学研究所 一种催化剂组合物及其在烯烃聚合中的应用
US20250066513A1 (en) 2023-08-23 2025-02-27 Formosa Plastics Corporation, U.S.A. Catalyst System For Enhanced Stereo-Specificity Of Olefin Polymerization
US20250066514A1 (en) 2023-08-24 2025-02-27 Formosa Plastics Corporation, U.S.A. Catalysts component and process for the production of polypropylene having high melt flow rate with high isotacticity
US20250109218A1 (en) 2023-09-29 2025-04-03 Formosa Plastics Corporation, U.S.A. Method for preparing catalyst component for polymerization of polyolefin without the use of internal electron donors
US20250115687A1 (en) 2023-10-06 2025-04-10 Formosa Plastics Corporation, U.S.A. Production method for solid catalyst component for polymerizing olefins, and catalyst for polymerizaing olefins
US20250115686A1 (en) 2023-10-09 2025-04-10 Formosa Plastics Corporation, U.S.A. Olefin polymerization catalyst components containing silane and process for the production of polypropylene having high isotacticity at high melt flow rate
US20250297039A1 (en) 2024-03-19 2025-09-25 Formosa Plastics Corporation, U.S.A. Olefin polymerization catalyst components containing diglycidylester components and its use for the production of polypropylene having high isotacticity at high melt flow rate
WO2026063967A1 (en) 2024-09-19 2026-03-26 Formosa Plastics Corporation, Usa Olefin polymerization ziegler-natta catalyst components and process for the production of olefin polymers therewith

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP3226538B2 (ja) 1991-05-09 2001-11-05 ボレアリス ホールディング エイ／エス 二種の電子供与体に基づく重合触媒
US20050239636A1 (en) 2002-02-07 2005-10-27 Mingzhi Gao Solid catalyst component for polymerization of olefins, catalyst comprising the same and use thereof
JP2007535593A (ja) 2004-04-30 2007-12-06 中国石油化工股▲分▼有限公司 オレフィン重合用触媒成分及びそれを含む触媒

Family Cites Families (50)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB630951A (en) 1947-08-26 1949-10-24 Dow Corning Improvements in or relating to the manufacture of organo silicon esters
US5106806A (en) 1990-10-18 1992-04-21 Shell Oil Company Olefin polymerization catalyst
US5082907A (en) 1990-10-18 1992-01-21 Shell Oil Company Olefin polymerization catalyst
US5066737A (en) 1990-10-22 1991-11-19 Shell Oil Company Olefin polymerization catalyst
US5151399A (en) 1990-10-18 1992-09-29 Shell Oil Company Olefin polymerization catalyst
US5077357A (en) 1990-10-22 1991-12-31 Shell Oil Company Olefin polymerization catalyst
NL160286C (https=) 1971-06-25
IT1209255B (it) 1980-08-13 1989-07-16 Montedison Spa Catalizzatori per la polimerizzazione di olefine.
JPS5883006A (ja) * 1981-11-13 1983-05-18 Mitsui Petrochem Ind Ltd オレフインの重合方法
IT1190681B (it) * 1982-02-12 1988-02-24 Montedison Spa Componenti e catalizzatori per la polimerizzazione di olefine
US4442276A (en) 1982-02-12 1984-04-10 Mitsui Petrochemical Industries, Ltd. Process for polymerizing or copolymerizing olefins
IT1190683B (it) * 1982-02-12 1988-02-24 Montedison Spa Componenti e catalizzatori per la polimerizzazione di olefine
JPS5991107A (ja) 1982-11-17 1984-05-25 Toho Titanium Co Ltd オレフイン類重合用触媒成分の製造方法
US4458027A (en) * 1983-03-18 1984-07-03 E. I. Du Pont De Nemours And Company Olefin polymerization catalysts
JPS6023404A (ja) 1983-07-20 1985-02-06 Toho Titanium Co Ltd オレフィン類重合用触媒成分
US4540679A (en) 1984-03-23 1985-09-10 Amoco Corporation Magnesium hydrocarbyl carbonate supports
JPH06104693B2 (ja) 1986-01-06 1994-12-21 東邦チタニウム株式会社 オレフイン類重合用触媒
EP0268685B2 (en) 1986-05-06 1996-08-07 Toho Titanium Co. Ltd. Catalyst for polymerizing olefins
CA1310955C (en) 1987-03-13 1992-12-01 Mamoru Kioka Process for polymerization of olefins and polymerization catalyst
US4927797A (en) 1987-04-09 1990-05-22 Fina Technology, Inc. Catalyst system for the polymerization of olefins
US5066738A (en) 1987-04-09 1991-11-19 Fina Technology, Inc. Polymerization of olefins with an improved catalyst system using a new electron donor
JP2536531B2 (ja) * 1987-06-19 1996-09-18 東ソー株式会社 立体規則性ポリオレフィンの製造方法
EP0350170B2 (en) 1988-06-17 2001-09-12 Mitsui Chemicals, Inc. Process for polymerising olefins and polymerisation catalyst therefor
US5247031A (en) 1988-09-13 1993-09-21 Mitsui Petrochemical Industries, Ltd. Olefin polymerization catalyst component, process for production thereof, olefin polymerization catalyst, and process for polymerizing olefins
IT1227258B (it) 1988-09-30 1991-03-28 Himont Inc Componenti e catalizzatori per la polimerizzazione di olefine
JP2940684B2 (ja) 1989-12-29 1999-08-25 三井化学株式会社 オレフィン重合用固体状触媒成分およびこの触媒成分を用いたオレフィンの重合方法
US5247032A (en) 1989-12-29 1993-09-21 Mitsui Petrochemical Industries, Ltd. Solid catalyst components for olefin polymerization and processes for the polymerization of olefin using same
IT1241062B (it) 1990-01-10 1993-12-29 Himont Inc Componenti e catalizzatori per la polimerizzazione di olefine
US5034361A (en) 1990-05-24 1991-07-23 Shell Oil Company Catalyst precursor production
US5146028A (en) 1990-10-18 1992-09-08 Shell Oil Company Olefin polymerization catalyst and process of polymerization
US5229342A (en) 1990-10-18 1993-07-20 Shell Oil Company Olefin polymerization catalyst
US5432244A (en) 1990-12-12 1995-07-11 Union Carbide Chemicals & Plastics Technology Corporation Process for the production of polypropylene
GB9300318D0 (en) 1993-01-08 1993-03-03 Oxford Analytical Instr Ltd Improvements relating to sample monitoring
CN1246341C (zh) * 1997-09-05 2006-03-22 英国石油化学品有限公司 聚合催化剂
KR20010033872A (ko) 1998-11-04 2001-04-25 간디 지오프레이 에이치. 올레핀의 중합을 위한 성분 및 촉매
CN1240729C (zh) 1999-04-15 2006-02-08 巴塞尔聚烯烃意大利有限公司 用于烯烃聚合的组分和催化剂
CN1177868C (zh) * 1999-06-30 2004-12-01 联合碳化物化学和塑料技术公司 镁/钛烷氧基配合物以及由此制得的聚合催化剂
US6391985B1 (en) 1999-10-21 2002-05-21 Union Carbide Chemicals & Plastics Technology Corporation High condensing mode polyolefin production under turbulent conditions in a fluidized bed
CN1367184A (zh) 2001-01-12 2002-09-04 弗纳技术股份有限公司 生产超高熔体流动聚丙烯树脂的方法
EP1401884A1 (en) * 2001-05-29 2004-03-31 Union Carbide Chemicals & Plastics Technology Corporation Olefin polymerization catalyst compositions and method of preperation
US6825146B2 (en) * 2001-05-29 2004-11-30 Union Carbide Chemicals & Plastics Technology Corporation Olefin polymerization catalyst compositions and method of preparation
US6960635B2 (en) 2001-11-06 2005-11-01 Dow Global Technologies Inc. Isotactic propylene copolymers, their preparation and use
CN100441561C (zh) 2002-02-07 2008-12-10 中国石油化工股份有限公司 用于制备烯烃聚合催化剂的多酯化合物
CN1297534C (zh) 2003-08-06 2007-01-31 中国石油化工股份有限公司 用于制备烯烃聚合催化剂的二醇酯化合物
EP1668044B1 (en) * 2003-09-23 2014-05-07 W.R. Grace & CO. - CONN. Self limiting catalyst composition with dicarboxylic acid ester internal donor and propylene polymerization process
US20070191558A1 (en) * 2004-04-07 2007-08-16 Gonzalez Kelly A Olefin polymerization procatalyst compositions and method of preparation
CN1282670C (zh) * 2004-04-30 2006-11-01 中国石油化工股份有限公司 用于烯烃聚合反应的催化剂组分及其催化剂
JP2011506718A (ja) * 2007-12-20 2011-03-03 バーゼル・ポリオレフィン・イタリア・ソチエタ・ア・レスポンサビリタ・リミタータ 改良された特性を有する高立体規則性ポリプロピレン
US8088872B2 (en) * 2008-11-25 2012-01-03 Dow Global Technologies Llc Procatalyst composition including silyl ester internal donor and method
EP2350143B1 (en) * 2008-11-25 2016-02-17 W.R. Grace & CO. - CONN. Procatalyst composition multiple internal donor having silyl ester and method

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP3226538B2 (ja) 1991-05-09 2001-11-05 ボレアリス ホールディング エイ／エス 二種の電子供与体に基づく重合触媒
US20050239636A1 (en) 2002-02-07 2005-10-27 Mingzhi Gao Solid catalyst component for polymerization of olefins, catalyst comprising the same and use thereof
JP2007535593A (ja) 2004-04-30 2007-12-06 中国石油化工股▲分▼有限公司 オレフィン重合用触媒成分及びそれを含む触媒

Also Published As

Publication number Publication date
BRPI0916095A8 (pt) 2017-09-19
US20100130709A1 (en) 2010-05-27
BRPI0916095B1 (pt) 2019-05-07
JP6081700B2 (ja) 2017-02-15
WO2010065361A1 (en) 2010-06-10
EP2350144A1 (en) 2011-08-03
JP2012509890A (ja) 2012-04-26
CN104059095A (zh) 2014-09-24
JP2015155558A (ja) 2015-08-27
RU2505548C2 (ru) 2014-01-27
RU2011126139A (ru) 2013-01-10
MX2011005542A (es) 2011-06-21
US8088872B2 (en) 2012-01-03
CN102282181A (zh) 2011-12-14
SG171799A1 (en) 2011-07-28
BRPI0916095A2 (pt) 2015-11-17
EP2350144B1 (en) 2015-07-15
CN102282181B (zh) 2014-06-25
KR20110094087A (ko) 2011-08-19

Similar Documents

Publication Publication Date Title
KR101589780B1 (ko) 실릴 에스테르 내부 공여체를 포함하는 전촉매 조성물 및 방법
KR101589779B1 (ko) 실릴 에스테르를 갖는 다중 내부 공여체를 구비한 전촉매 조성물 및 방법
US11993672B2 (en) Production of high melt flow propylene-based polymer and product from same
KR101600365B1 (ko) 치환된 1,2-페닐렌 방향족 디에스테르 내부 공여체를 갖는 전촉매 조성물 및 방법
KR101745738B1 (ko) 아다만탄 함유 전촉매 조성물 및 방법
US8247341B2 (en) Procatalyst composition with silyl glutarate and method

Legal Events

Date Code Title Description
PA0105 International application

St.27 status event code: A-0-1-A10-A15-nap-PA0105

PG1501 Laying open of application

St.27 status event code: A-1-1-Q10-Q12-nap-PG1501

N231 Notification of change of applicant
PN2301 Change of applicant

St.27 status event code: A-3-3-R10-R13-asn-PN2301

St.27 status event code: A-3-3-R10-R11-asn-PN2301

P11-X000 Amendment of application requested

St.27 status event code: A-2-2-P10-P11-nap-X000

P13-X000 Application amended

St.27 status event code: A-2-2-P10-P13-nap-X000

A201 Request for examination
A302 Request for accelerated examination
P11-X000 Amendment of application requested

St.27 status event code: A-2-2-P10-P11-nap-X000

P13-X000 Application amended

St.27 status event code: A-2-2-P10-P13-nap-X000

PA0201 Request for examination

St.27 status event code: A-1-2-D10-D11-exm-PA0201

PA0302 Request for accelerated examination

St.27 status event code: A-1-2-D10-D17-exm-PA0302

St.27 status event code: A-1-2-D10-D16-exm-PA0302

E902 Notification of reason for refusal
PE0902 Notice of grounds for rejection

St.27 status event code: A-1-2-D10-D21-exm-PE0902

T11-X000 Administrative time limit extension requested

St.27 status event code: U-3-3-T10-T11-oth-X000

T11-X000 Administrative time limit extension requested

St.27 status event code: U-3-3-T10-T11-oth-X000

T11-X000 Administrative time limit extension requested

St.27 status event code: U-3-3-T10-T11-oth-X000

T11-X000 Administrative time limit extension requested

St.27 status event code: U-3-3-T10-T11-oth-X000

P11-X000 Amendment of application requested

St.27 status event code: A-2-2-P10-P11-nap-X000

P13-X000 Application amended

St.27 status event code: A-2-2-P10-P13-nap-X000

E701 Decision to grant or registration of patent right
PE0701 Decision of registration

St.27 status event code: A-1-2-D10-D22-exm-PE0701

GRNT Written decision to grant
PR0701 Registration of establishment

St.27 status event code: A-2-4-F10-F11-exm-PR0701

PR1002 Payment of registration fee

St.27 status event code: A-2-2-U10-U12-oth-PR1002

Fee payment year number: 1

PG1601 Publication of registration

St.27 status event code: A-4-4-Q10-Q13-nap-PG1601

FPAY Annual fee payment

Payment date: 20190109

Year of fee payment: 4

PR1001 Payment of annual fee

St.27 status event code: A-4-4-U10-U11-oth-PR1001

Fee payment year number: 4

FPAY Annual fee payment

Payment date: 20200110

Year of fee payment: 5

PR1001 Payment of annual fee

St.27 status event code: A-4-4-U10-U11-oth-PR1001

Fee payment year number: 5

PR1001 Payment of annual fee

St.27 status event code: A-4-4-U10-U11-oth-PR1001

Fee payment year number: 6

PR1001 Payment of annual fee

St.27 status event code: A-4-4-U10-U11-oth-PR1001

Fee payment year number: 7

PR1001 Payment of annual fee

St.27 status event code: A-4-4-U10-U11-oth-PR1001

Fee payment year number: 8

PR1001 Payment of annual fee

St.27 status event code: A-4-4-U10-U11-oth-PR1001

Fee payment year number: 9

PC1903 Unpaid annual fee

St.27 status event code: A-4-4-U10-U13-oth-PC1903

Not in force date: 20250123

Payment event data comment text: Termination Category : DEFAULT_OF_REGISTRATION_FEE

H13 Ip right lapsed

Free format text: ST27 STATUS EVENT CODE: N-4-6-H10-H13-OTH-PC1903 (AS PROVIDED BY THE NATIONAL OFFICE); TERMINATION CATEGORY : DEFAULT_OF_REGISTRATION_FEE

Effective date: 20250123

PC1903 Unpaid annual fee

St.27 status event code: N-4-6-H10-H13-oth-PC1903

Ip right cessation event data comment text: Termination Category : DEFAULT_OF_REGISTRATION_FEE

Not in force date: 20250123