KR101539784B1 - 게르마늄-제올라이트 촉매를 이용한 알칸의 방향족화 - Google Patents

게르마늄-제올라이트 촉매를 이용한 알칸의 방향족화 Download PDF

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KR101539784B1
KR101539784B1 KR1020097023645A KR20097023645A KR101539784B1 KR 101539784 B1 KR101539784 B1 KR 101539784B1 KR 1020097023645 A KR1020097023645 A KR 1020097023645A KR 20097023645 A KR20097023645 A KR 20097023645A KR 101539784 B1 KR101539784 B1 KR 101539784B1
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zeolite
catalyst
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germanium
hydrogen
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KR20100016490A (ko
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스콧 에이. 스티븐슨
더스틴 비. 파머
스콧 에프. 미첼
고팔라크리쉬난 지. 주투
알라 케이. 콴-마메도바
폴 이. 엘리스
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사우디 베이식 인더스트리즈 코포레이션
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/50—Diels-Alder conversion
    • C07C2/52—Catalytic processes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
    • C07C5/373—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen with simultaneous isomerisation
    • C07C5/393—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen with simultaneous isomerisation with cyclisation to an aromatic six-membered ring, e.g. dehydrogenation of n-hexane to benzene
    • C07C5/41—Catalytic processes
    • C07C5/415—Catalytic processes with metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/047—Germanosilicates; Aluminogermanosilicates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B01J29/42—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively containing iron group metals, noble metals or copper
    • B01J29/44—Noble metals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
    • C07C5/373—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen with simultaneous isomerisation
    • C07C5/393—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen with simultaneous isomerisation with cyclisation to an aromatic six-membered ring, e.g. dehydrogenation of n-hexane to benzene
    • C07C5/41—Catalytic processes
    • C07C5/415—Catalytic processes with metals
    • C07C5/417—Catalytic processes with metals of the platinum group
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C6/00—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions
    • C07C6/08—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond
    • C07C6/12—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond of exclusively hydrocarbons containing a six-membered aromatic ring
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/58—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins
    • C10G45/68—Aromatisation of hydrocarbon oil fractions
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/58—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins
    • C10G45/68—Aromatisation of hydrocarbon oil fractions
    • C10G45/70—Aromatisation of hydrocarbon oil fractions with catalysts containing platinum group metals or compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/18—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/18—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself
    • B01J2229/186—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself not in framework positions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/42—Platinum
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
    • C07C2529/42—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11 containing iron group metals, noble metals or copper
    • C07C2529/44—Noble metals
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Materials Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
KR1020097023645A 2007-04-12 2008-03-20 게르마늄-제올라이트 촉매를 이용한 알칸의 방향족화 Expired - Fee Related KR101539784B1 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US11/786,590 US7902413B2 (en) 2007-04-12 2007-04-12 Aromatization of alkanes using a germanium-zeolite catalyst
US11/786,590 2007-04-12

Publications (2)

Publication Number Publication Date
KR20100016490A KR20100016490A (ko) 2010-02-12
KR101539784B1 true KR101539784B1 (ko) 2015-07-27

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Country Status (6)

Country Link
US (1) US7902413B2 (https=)
EP (1) EP2155633B1 (https=)
JP (1) JP5576266B2 (https=)
KR (1) KR101539784B1 (https=)
CN (1) CN101679141A (https=)
WO (1) WO2008127538A1 (https=)

Cited By (2)

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KR20220064236A (ko) 2020-11-11 2022-05-18 전남대학교산학협력단 포화탄화수소제거용 귀금속 담지 제올라이트 촉매 제조방법 및 그 방법으로 제조된 포화탄화수소제거용 귀금속 담지 제올라이트 촉매
KR102918664B1 (ko) 2023-11-02 2026-01-28 한국화학연구원 Aei형 제올라이트 및 이의 제조방법

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WO2008153759A2 (en) 2007-05-24 2008-12-18 Saudi Basic Industries Corporation Catalyst for conversion of hydrocarbons, process of making and process of using thereof-bimetallic deposition
US9221723B2 (en) * 2007-05-24 2015-12-29 Saudi Basic Industries Corporation Catalyst for conversion of hydrocarbons, process of making and process of using thereof—incorporation-1
US8993468B2 (en) * 2007-05-24 2015-03-31 Saudi Basic Industries Corporation Catalyst for conversion of hydrocarbons, process of making and process of using thereof—Ge zeolites
US8969232B2 (en) * 2007-05-24 2015-03-03 Saudi Basic Industries Corporation Catalyst for conversion of hydrocarbons, process of making and process of using thereof—incorporation 2
US20110132804A1 (en) * 2009-12-04 2011-06-09 Saudi Basic Industries Corporation Increasing octane number of light naphtha using a germanium-zeolite catalyst
JP5468957B2 (ja) 2010-03-29 2014-04-09 Ｊｘ日鉱日石エネルギー株式会社 水素化異性化触媒、その製造方法、炭化水素油の脱蝋方法、炭化水素の製造方法及び潤滑油基油の製造方法
US8722950B2 (en) 2010-04-26 2014-05-13 Saudi Basic Industries Corporation Process for producing propylene and aromatics from butenes by metathesis and aromatization
US9242233B2 (en) 2012-05-02 2016-01-26 Saudi Basic Industries Corporation Catalyst for light naphtha aromatization
US8772192B2 (en) * 2012-06-29 2014-07-08 Saudi Basic Industries Corporation Germanium silicalite catalyst and method of preparation and use
US9180441B2 (en) 2012-09-20 2015-11-10 Saudi Basic Industries Corporation Method of forming zeolite shaped body with silica binder
US9782758B2 (en) * 2013-04-23 2017-10-10 Saudi Basic Industries Corporation Method of preparing hydrocarbon aromatization catalyst, the catalyst, and the use of the catalyst
US10207255B2 (en) 2013-11-22 2019-02-19 Saudi Basic Industries Corporation Catalyst with improved activity/selectivity for light naphtha aromatization
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WO2021048693A1 (en) 2019-09-10 2021-03-18 Sabic Global Technologies B.V. Aromatization catalyst with improved isomerization, reactor configurations and use thereof
US11439991B2 (en) * 2019-12-19 2022-09-13 King Fahd University Of Petroleum & Minerals Catalyst compositions for aromatizing hydrocarbons and processes for producing aromatic compounds using the catalyst compositions
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JP2022127708A (ja) * 2021-02-22 2022-09-01 東ソー株式会社 ベンゼンの製造方法
JP7712653B2 (ja) * 2021-04-19 2025-07-24 公立大学法人北九州市立大学 芳香族炭化水素の製造方法
CN117185892A (zh) * 2022-05-31 2023-12-08 中国石油化工股份有限公司 多产乙苯的烷烃转化方法
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CN118045625A (zh) * 2024-02-02 2024-05-17 山东省科学院能源研究所 一种c3-c9链烷烃催化重整用锗改性催化剂及其制备方法与应用
CN121307067B (zh) * 2025-12-12 2026-03-17 江苏源氢新能源科技股份有限公司 一种Cs沉淀沸石结构膜电极的制备方法

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20220064236A (ko) 2020-11-11 2022-05-18 전남대학교산학협력단 포화탄화수소제거용 귀금속 담지 제올라이트 촉매 제조방법 및 그 방법으로 제조된 포화탄화수소제거용 귀금속 담지 제올라이트 촉매
KR102918664B1 (ko) 2023-11-02 2026-01-28 한국화학연구원 Aei형 제올라이트 및 이의 제조방법

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EP2155633A1 (en) 2010-02-24
EP2155633B1 (en) 2018-04-25
EP2155633A4 (en) 2013-07-10
WO2008127538A1 (en) 2008-10-23
JP5576266B2 (ja) 2014-08-20
US20080255398A1 (en) 2008-10-16
KR20100016490A (ko) 2010-02-12
CN101679141A (zh) 2010-03-24
JP2010523657A (ja) 2010-07-15
US7902413B2 (en) 2011-03-08

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