KR101445431B1 - 촉매 조성물 및 에틸렌의 올리고머화를 위한 공정 - Google Patents

촉매 조성물 및 에틸렌의 올리고머화를 위한 공정 Download PDF

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Publication number
KR101445431B1
KR101445431B1 KR1020107009317A KR20107009317A KR101445431B1 KR 101445431 B1 KR101445431 B1 KR 101445431B1 KR 1020107009317 A KR1020107009317 A KR 1020107009317A KR 20107009317 A KR20107009317 A KR 20107009317A KR 101445431 B1 KR101445431 B1 KR 101445431B1
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South Korea
Prior art keywords
oligomerization
ethylene
unit
rti
chromium
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KR1020107009317A
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English (en)
Korean (ko)
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KR20100088665A (ko
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부가르 아리예브
모하메드 하산 알-하즈미
푸아드 모사
피터 엠. 프리츠
하인즈 뵐트
아니나 볼
볼프강 뮐러
플로리안 윙클러
안톤 웰렌호퍼
우베 로젠탈
베른트 에이치 뮐러
마르코 하프케
노르멘 페울레케
Original Assignee
린데 악티엔게젤샤프트
사우디 베이식 인더스트리즈 코포레이션
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Publication of KR20100088665A publication Critical patent/KR20100088665A/ko
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/189—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms containing both nitrogen and phosphorus as complexing atoms, including e.g. phosphino moieties, in one at least bidentate or bridging ligand
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
    • B01J31/143—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron of aluminium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
    • B01J31/1875—Phosphinites (R2P(OR), their isomeric phosphine oxides (R3P=O) and RO-substitution derivatives thereof)
    • B01J31/188—Amide derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08—Catalytic processes
    • C07C2/26—Catalytic processes with hydrides or organic compounds
    • C07C2/36—Catalytic processes with hydrides or organic compounds as phosphines, arsines, stilbines or bismuthines
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/20—Olefin oligomerisation or telomerisation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
    • B01J2531/0238—Complexes comprising multidentate ligands, i.e. more than 2 ionic or coordinative bonds from the central metal to the ligand, the latter having at least two donor atoms, e.g. N, O, S, P
    • B01J2531/0258—Flexible ligands, e.g. mainly sp3-carbon framework as exemplified by the "tedicyp" ligand, i.e. cis-cis-cis-1,2,3,4-tetrakis(diphenylphosphinomethyl)cyclopentane
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/60—Complexes comprising metals of Group VI (VIA or VIB) as the central metal
    • B01J2531/62—Chromium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • C07C2531/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • C07C2531/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • C07C2531/24—Phosphines
KR1020107009317A 2007-11-28 2008-11-05 촉매 조성물 및 에틸렌의 올리고머화를 위한 공정 KR101445431B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP07023013 2007-11-28
EP07023013.1 2007-11-28
PCT/EP2008/009305 WO2009068157A1 (en) 2007-11-28 2008-11-05 Catalyst composition and process for oligomerization of ethylene

Publications (2)

Publication Number Publication Date
KR20100088665A KR20100088665A (ko) 2010-08-10
KR101445431B1 true KR101445431B1 (ko) 2014-09-26

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Country Status (13)

Country Link
US (1) US8778827B2 (en_2)
EP (1) EP2219784B1 (en_2)
JP (1) JP5462179B2 (en_2)
KR (1) KR101445431B1 (en_2)
CN (1) CN101855015B (en_2)
BR (1) BRPI0819904B1 (en_2)
CA (1) CA2703021C (en_2)
ES (1) ES2397303T3 (en_2)
MX (1) MX2010005266A (en_2)
MY (1) MY150515A (en_2)
RU (1) RU2467797C2 (en_2)
TW (1) TWI440503B (en_2)
WO (1) WO2009068157A1 (en_2)

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US10392451B2 (en) 2015-06-12 2019-08-27 Lg Chem, Ltd. Ligand compound, organic chromium compound, catalyst system for olefin oligomerization, and method for oligomerizing olefins using the same thereof
US10688473B2 (en) 2014-12-11 2020-06-23 Lg Chem, Ltd. Ligand compound, organic chromium compound, catalyst system for oligomerization of olefins, and method for oligomerizing olefins using the same

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CA2703021C (en) 2007-11-28 2015-01-20 Vugar Aliyev Catalyst composition and process for oligomerization of ethylene
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KR101579880B1 (ko) 2012-05-10 2016-01-04 주식회사 엘지화학 에틸렌 올리고머화 방법
EP2684857A1 (en) * 2012-07-10 2014-01-15 Saudi Basic Industries Corporation Method for oligomerization of ethylene
CN105960417A (zh) * 2014-02-03 2016-09-21 沙特基础工业公司 用于制备用于乙烯低聚的催化剂组合物的催化剂组合物预形成单元
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KR101757370B1 (ko) 2015-06-01 2017-07-12 주식회사 엘지화학 1-옥텐 조성물
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WO2018122773A1 (en) 2016-12-30 2018-07-05 Sabic Global Technologies B.V. Method for preparation of a catalyst solution for selective 1-hexene production
ES2962319T3 (es) 2016-12-30 2024-03-18 Sabic Global Technologies Bv Método de preparación de un catalizador homogéneo para la producción selectiva de 1-hexeno
CN107899614B (zh) * 2017-11-20 2020-05-26 常州大学 一种双核占吨桥连胺基-吡啶镍催化剂及其制备方法和应用
CN113242764B (zh) * 2018-11-12 2023-10-20 沙特基础全球技术有限公司 用于铬辅助乙烯低聚工艺中生产1-辛烯的配体
KR20210138694A (ko) * 2019-03-19 2021-11-19 사빅 글로벌 테크놀러지스 비.브이. 크롬 보조 에틸렌 올리고머화 방법에서 1-옥텐 생성용 리간드
CN114409495A (zh) * 2020-10-28 2022-04-29 中国石油天然气股份有限公司 一种乙烯四聚的方法
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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10688473B2 (en) 2014-12-11 2020-06-23 Lg Chem, Ltd. Ligand compound, organic chromium compound, catalyst system for oligomerization of olefins, and method for oligomerizing olefins using the same
US10392451B2 (en) 2015-06-12 2019-08-27 Lg Chem, Ltd. Ligand compound, organic chromium compound, catalyst system for olefin oligomerization, and method for oligomerizing olefins using the same thereof

Also Published As

Publication number Publication date
US8778827B2 (en) 2014-07-15
ES2397303T3 (es) 2013-03-06
CN101855015B (zh) 2013-07-17
JP2011504799A (ja) 2011-02-17
BRPI0819904A2 (pt) 2015-09-15
RU2010126183A (ru) 2012-01-10
TWI440503B (zh) 2014-06-11
WO2009068157A1 (en) 2009-06-04
US20100298618A1 (en) 2010-11-25
RU2467797C2 (ru) 2012-11-27
EP2219784B1 (en) 2012-10-24
CA2703021C (en) 2015-01-20
TW200942327A (en) 2009-10-16
CA2703021A1 (en) 2009-06-04
EP2219784A1 (en) 2010-08-25
MX2010005266A (es) 2010-06-02
CN101855015A (zh) 2010-10-06
MY150515A (en) 2014-01-30
KR20100088665A (ko) 2010-08-10
BRPI0819904B1 (pt) 2018-02-06
JP5462179B2 (ja) 2014-04-02

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