WO2009068157A1 - Catalyst composition and process for oligomerization of ethylene - Google Patents

Catalyst composition and process for oligomerization of ethylene Download PDF

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Publication number
WO2009068157A1
WO2009068157A1 PCT/EP2008/009305 EP2008009305W WO2009068157A1 WO 2009068157 A1 WO2009068157 A1 WO 2009068157A1 EP 2008009305 W EP2008009305 W EP 2008009305W WO 2009068157 A1 WO2009068157 A1 WO 2009068157A1
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WO
WIPO (PCT)
Prior art keywords
catalyst composition
ethylene
composition according
catalyst
oligomerization
Prior art date
Application number
PCT/EP2008/009305
Other languages
English (en)
French (fr)
Inventor
Vugar Aliyev
Mohammed Hassan Al-Hazmi
Fuad Mosa
Peter M. Fritz
Heinz BÖLT
Anina Wöhl
Wolfgang Müller
Florian Winkler
Anton Wellenhofer
Uwe Rosenthal
Bernd H. MÜLLER
Marko Hapke
Normen Peulecke
Original Assignee
Linde Ag
Saudi Basic Industries Corporation
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Linde Ag, Saudi Basic Industries Corporation filed Critical Linde Ag
Priority to US12/734,770 priority Critical patent/US8778827B2/en
Priority to RU2010126183/04A priority patent/RU2467797C2/ru
Priority to MX2010005266A priority patent/MX2010005266A/es
Priority to ES08855368T priority patent/ES2397303T3/es
Priority to CN2008801154457A priority patent/CN101855015B/zh
Priority to EP08855368A priority patent/EP2219784B1/en
Priority to BRPI0819904-3A priority patent/BRPI0819904B1/pt
Priority to KR1020107009317A priority patent/KR101445431B1/ko
Priority to CA2703021A priority patent/CA2703021C/en
Priority to JP2010535257A priority patent/JP5462179B2/ja
Publication of WO2009068157A1 publication Critical patent/WO2009068157A1/en

Links

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/189—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms containing both nitrogen and phosphorus as complexing atoms, including e.g. phosphino moieties, in one at least bidentate or bridging ligand
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
    • B01J31/143—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron of aluminium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
    • B01J31/1875—Phosphinites (R2P(OR), their isomeric phosphine oxides (R3P=O) and RO-substitution derivatives thereof)
    • B01J31/188—Amide derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08—Catalytic processes
    • C07C2/26—Catalytic processes with hydrides or organic compounds
    • C07C2/36—Catalytic processes with hydrides or organic compounds as phosphines, arsines, stilbines or bismuthines
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/20—Olefin oligomerisation or telomerisation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
    • B01J2531/0238—Complexes comprising multidentate ligands, i.e. more than 2 ionic or coordinative bonds from the central metal to the ligand, the latter having at least two donor atoms, e.g. N, O, S, P
    • B01J2531/0258—Flexible ligands, e.g. mainly sp3-carbon framework as exemplified by the "tedicyp" ligand, i.e. cis-cis-cis-1,2,3,4-tetrakis(diphenylphosphinomethyl)cyclopentane
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/60—Complexes comprising metals of Group VI (VIA or VIB) as the central metal
    • B01J2531/62—Chromium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • C07C2531/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • C07C2531/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • C07C2531/24—Phosphines
PCT/EP2008/009305 2007-11-28 2008-11-05 Catalyst composition and process for oligomerization of ethylene WO2009068157A1 (en)

Priority Applications (10)

Application Number Priority Date Filing Date Title
US12/734,770 US8778827B2 (en) 2007-11-28 2008-11-05 Catalyst composition and process for oligomerization of ethylene
RU2010126183/04A RU2467797C2 (ru) 2007-11-28 2008-11-05 Каталитическая композиция и способ олигомеризации этилена
MX2010005266A MX2010005266A (es) 2007-11-28 2008-11-05 Composicion catalizadora y proceso para oligomerizacion de etileno.
ES08855368T ES2397303T3 (es) 2007-11-28 2008-11-05 Composición de catalizador y procedimiento para la oligomerización de etileno
CN2008801154457A CN101855015B (zh) 2007-11-28 2008-11-05 催化剂组合物以及乙烯低聚的方法
EP08855368A EP2219784B1 (en) 2007-11-28 2008-11-05 Catalyst composition and process for oligomerization of ethylene
BRPI0819904-3A BRPI0819904B1 (pt) 2007-11-28 2008-11-05 Composição catalisadora e processo para oligomerização de etileno
KR1020107009317A KR101445431B1 (ko) 2007-11-28 2008-11-05 촉매 조성물 및 에틸렌의 올리고머화를 위한 공정
CA2703021A CA2703021C (en) 2007-11-28 2008-11-05 Catalyst composition and process for oligomerization of ethylene
JP2010535257A JP5462179B2 (ja) 2007-11-28 2008-11-05 エチレンのオリゴマー化のための触媒組成物およびプロセス

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP07023013 2007-11-28
EP07023013.1 2007-11-28

Publications (1)

Publication Number Publication Date
WO2009068157A1 true WO2009068157A1 (en) 2009-06-04

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2008/009305 WO2009068157A1 (en) 2007-11-28 2008-11-05 Catalyst composition and process for oligomerization of ethylene

Country Status (13)

Country Link
US (1) US8778827B2 (en_2)
EP (1) EP2219784B1 (en_2)
JP (1) JP5462179B2 (en_2)
KR (1) KR101445431B1 (en_2)
CN (1) CN101855015B (en_2)
BR (1) BRPI0819904B1 (en_2)
CA (1) CA2703021C (en_2)
ES (1) ES2397303T3 (en_2)
MX (1) MX2010005266A (en_2)
MY (1) MY150515A (en_2)
RU (1) RU2467797C2 (en_2)
TW (1) TWI440503B (en_2)
WO (1) WO2009068157A1 (en_2)

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2239056A1 (en) * 2009-04-09 2010-10-13 Saudi Basic Industries Corporation Catalyst composition and process for oligomerization of ethylene
EP2354113A1 (en) 2010-02-04 2011-08-10 Linde AG Method for deactivation of a catalyst
EP2489431A1 (en) 2011-02-16 2012-08-22 Linde AG Method for preparing a catalyst composition for oligomerization of ethylene and respective catalyst composition pre-formation unit
WO2013168103A1 (en) 2012-05-09 2013-11-14 Sasol Technology (Proprietary) Limited Oligomerisation of olefinic compounds with reduced polymer formation
EP2684857A1 (en) * 2012-07-10 2014-01-15 Saudi Basic Industries Corporation Method for oligomerization of ethylene
WO2016012948A1 (en) * 2014-07-24 2016-01-28 Sabic Global Technologies B.V. Catalyst composition and process for oligomerization of ethylene to produce 1-hexene and/or 1-octene
WO2020188476A1 (en) * 2019-03-19 2020-09-24 Sabic Global Technologies B.V. Ligands for production of 1-octene in chromium assisted ethylene oligomerization process
US11285469B2 (en) 2016-12-30 2022-03-29 Sabic Global Technologies B.V. Method for preparation of a catalyst solution for selective 1-hexene production
US11331655B2 (en) 2016-12-30 2022-05-17 Sabic Global Technologies B.V. Method for preparation of homogenous catalyst for selective 1-hexene production
US11511265B2 (en) 2018-11-12 2022-11-29 Sabic Global Technologies B.V. Ligands for production of 1-octene in chromium assisted ethylene oligomerization process

Families Citing this family (10)

* Cited by examiner, † Cited by third party
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CA2703021C (en) 2007-11-28 2015-01-20 Vugar Aliyev Catalyst composition and process for oligomerization of ethylene
KR101579880B1 (ko) 2012-05-10 2016-01-04 주식회사 엘지화학 에틸렌 올리고머화 방법
CN105960417A (zh) * 2014-02-03 2016-09-21 沙特基础工业公司 用于制备用于乙烯低聚的催化剂组合物的催化剂组合物预形成单元
KR101757369B1 (ko) 2014-12-11 2017-07-12 주식회사 엘지화학 리간드 화합물, 유기크롬 화합물, 올레핀 올리고머화용 촉매 시스템, 및 이를 이용한 올레핀의 올리고머화 방법
KR101757370B1 (ko) 2015-06-01 2017-07-12 주식회사 엘지화학 1-옥텐 조성물
KR101757835B1 (ko) 2015-06-12 2017-07-13 주식회사 엘지화학 리간드 화합물, 유기 크롬 화합물, 올레핀 올리고머화용 촉매 시스템, 및 이를 이용한 올레핀의 올리고머화 방법
US10604457B2 (en) * 2016-12-29 2020-03-31 Chevron Phillips Chemical Company Lp Ethylene oligomerization processes
CN107899614B (zh) * 2017-11-20 2020-05-26 常州大学 一种双核占吨桥连胺基-吡啶镍催化剂及其制备方法和应用
CN114409495A (zh) * 2020-10-28 2022-04-29 中国石油天然气股份有限公司 一种乙烯四聚的方法
WO2024047612A1 (en) 2022-09-02 2024-03-07 Sabic Global Technologies B.V. Methods for producing 1-hexene

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Cited By (20)

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Publication number Priority date Publication date Assignee Title
US9018431B2 (en) 2009-04-09 2015-04-28 Saudi Basic Industries Corporation Catalyst composition and process for oligomerization of ethylene
WO2010115520A1 (en) * 2009-04-09 2010-10-14 Linde Ag Catalyst composition and process for oligomerization of ethylene
CN102387860A (zh) * 2009-04-09 2012-03-21 林德股份公司 用于乙烯低聚的催化剂组合物和方法
CN102387860B (zh) * 2009-04-09 2013-11-20 林德股份公司 用于乙烯低聚的催化剂组合物和方法
EP2239056A1 (en) * 2009-04-09 2010-10-13 Saudi Basic Industries Corporation Catalyst composition and process for oligomerization of ethylene
EP2354113A1 (en) 2010-02-04 2011-08-10 Linde AG Method for deactivation of a catalyst
WO2011095272A1 (en) 2010-02-04 2011-08-11 Linde Aktiengesellschaft Method for deactivation of a catalyst
EP2489431A1 (en) 2011-02-16 2012-08-22 Linde AG Method for preparing a catalyst composition for oligomerization of ethylene and respective catalyst composition pre-formation unit
WO2012110174A1 (en) 2011-02-16 2012-08-23 Linde Ag Method for preparing a catalyst composition for oligomerization of ethylene and respective catalyst composition pre-formation unit
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ES2397303T3 (es) 2013-03-06
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BRPI0819904A2 (pt) 2015-09-15
RU2010126183A (ru) 2012-01-10
TWI440503B (zh) 2014-06-11
US20100298618A1 (en) 2010-11-25
RU2467797C2 (ru) 2012-11-27
EP2219784B1 (en) 2012-10-24
CA2703021C (en) 2015-01-20
TW200942327A (en) 2009-10-16
CA2703021A1 (en) 2009-06-04
KR101445431B1 (ko) 2014-09-26
EP2219784A1 (en) 2010-08-25
MX2010005266A (es) 2010-06-02
CN101855015A (zh) 2010-10-06
MY150515A (en) 2014-01-30
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BRPI0819904B1 (pt) 2018-02-06
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