KR101445431B1 - 촉매 조성물 및 에틸렌의 올리고머화를 위한 공정 - Google Patents

촉매 조성물 및 에틸렌의 올리고머화를 위한 공정 Download PDF

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Publication number
KR101445431B1
KR101445431B1 KR1020107009317A KR20107009317A KR101445431B1 KR 101445431 B1 KR101445431 B1 KR 101445431B1 KR 1020107009317 A KR1020107009317 A KR 1020107009317A KR 20107009317 A KR20107009317 A KR 20107009317A KR 101445431 B1 KR101445431 B1 KR 101445431B1
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oligomerization
ethylene
unit
rti
chromium
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KR20100088665A (ko
Inventor
부가르 아리예브
모하메드 하산 알-하즈미
푸아드 모사
피터 엠. 프리츠
하인즈 뵐트
아니나 볼
볼프강 뮐러
플로리안 윙클러
안톤 웰렌호퍼
우베 로젠탈
베른트 에이치 뮐러
마르코 하프케
노르멘 페울레케
Original Assignee
린데 악티엔게젤샤프트
사우디 베이식 인더스트리즈 코포레이션
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/189—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms containing both nitrogen and phosphorus as complexing atoms, including e.g. phosphino moieties, in one at least bidentate or bridging ligand
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
    • B01J31/143—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron of aluminium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
    • B01J31/1875—Phosphinites (R2P(OR), their isomeric phosphine oxides (R3P=O) and RO-substitution derivatives thereof)
    • B01J31/188—Amide derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08—Catalytic processes
    • C07C2/26—Catalytic processes with hydrides or organic compounds
    • C07C2/36—Catalytic processes with hydrides or organic compounds as phosphines, arsines, stilbines or bismuthines
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/20—Olefin oligomerisation or telomerisation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
    • B01J2531/0238—Complexes comprising multidentate ligands, i.e. more than 2 ionic or coordinative bonds from the central metal to the ligand, the latter having at least two donor atoms, e.g. N, O, S, P
    • B01J2531/0258—Flexible ligands, e.g. mainly sp3-carbon framework as exemplified by the "tedicyp" ligand, i.e. cis-cis-cis-1,2,3,4-tetrakis(diphenylphosphinomethyl)cyclopentane
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/60—Complexes comprising metals of Group VI (VIA or VIB) as the central metal
    • B01J2531/62—Chromium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • C07C2531/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • C07C2531/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • C07C2531/24—Phosphines

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
KR1020107009317A 2007-11-28 2008-11-05 촉매 조성물 및 에틸렌의 올리고머화를 위한 공정 Expired - Fee Related KR101445431B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP07023013 2007-11-28
EP07023013.1 2007-11-28
PCT/EP2008/009305 WO2009068157A1 (en) 2007-11-28 2008-11-05 Catalyst composition and process for oligomerization of ethylene

Publications (2)

Publication Number Publication Date
KR20100088665A KR20100088665A (ko) 2010-08-10
KR101445431B1 true KR101445431B1 (ko) 2014-09-26

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Country Link
US (1) US8778827B2 (enExample)
EP (1) EP2219784B1 (enExample)
JP (1) JP5462179B2 (enExample)
KR (1) KR101445431B1 (enExample)
CN (1) CN101855015B (enExample)
BR (1) BRPI0819904B1 (enExample)
CA (1) CA2703021C (enExample)
ES (1) ES2397303T3 (enExample)
MX (1) MX2010005266A (enExample)
MY (1) MY150515A (enExample)
RU (1) RU2467797C2 (enExample)
TW (1) TWI440503B (enExample)
WO (1) WO2009068157A1 (enExample)

Cited By (2)

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US10392451B2 (en) 2015-06-12 2019-08-27 Lg Chem, Ltd. Ligand compound, organic chromium compound, catalyst system for olefin oligomerization, and method for oligomerizing olefins using the same thereof
US10688473B2 (en) 2014-12-11 2020-06-23 Lg Chem, Ltd. Ligand compound, organic chromium compound, catalyst system for oligomerization of olefins, and method for oligomerizing olefins using the same

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CA2703021C (en) 2007-11-28 2015-01-20 Vugar Aliyev Catalyst composition and process for oligomerization of ethylene
ES2371218T3 (es) * 2009-04-09 2011-12-28 Saudi Basic Industries Corporation Composición de catalizador y procedimiento para la oligomerización de etileno.
EP2354113A1 (en) 2010-02-04 2011-08-10 Linde AG Method for deactivation of a catalyst
EP2489431B1 (en) 2011-02-16 2013-05-01 Linde AG Method for preparing a catalyst composition for oligomerization of ethylene and respective catalyst composition pre-formation unit
MX352923B (es) 2012-05-09 2017-12-14 Sasol Tech Pty Ltd Oligomerizacion de compuestos olefinicos con menor formacion de polimeros.
KR101513145B1 (ko) 2012-05-10 2015-04-17 주식회사 엘지화학 리간드 화합물, 크롬 화합물 및 이를 포함하는 촉매계
EP2684857A1 (en) 2012-07-10 2014-01-15 Saudi Basic Industries Corporation Method for oligomerization of ethylene
WO2015114611A1 (en) * 2014-02-03 2015-08-06 Saudi Basic Industries Corporation Catalyst composition pre-formation unit for preparing a catalyst composition for oligomerization of ethylene
CA2954836C (en) * 2014-07-24 2018-10-09 Sabic Global Technologies B.V. Catalyst composition and process for oligomerization of ethylene to produce 1-hexene and/or 1-octene
KR101757370B1 (ko) * 2015-06-01 2017-07-12 주식회사 엘지화학 1-옥텐 조성물
US10604457B2 (en) * 2016-12-29 2020-03-31 Chevron Phillips Chemical Company Lp Ethylene oligomerization processes
EP3562585B1 (en) 2016-12-30 2023-08-23 SABIC Global Technologies B.V. Method for preparation of homogenous catalyst for selective 1-hexene production
CN110494218A (zh) 2016-12-30 2019-11-22 沙特基础工业全球技术有限公司 用于选择性1-己烯生产的催化剂溶液的制备方法
CN107899614B (zh) * 2017-11-20 2020-05-26 常州大学 一种双核占吨桥连胺基-吡啶镍催化剂及其制备方法和应用
ES2943660T3 (es) * 2018-11-12 2023-06-15 Sabic Global Technologies Bv Ligandos para la producción de 1-octeno en el proceso de oligomerización de etileno asistido por cromo
US12440830B2 (en) 2019-03-19 2025-10-14 Sabic Global Technologies B.V. Ligands for production of 1-octene in chromium assisted ethylene oligomerization process
CN114409495B (zh) * 2020-10-28 2024-09-27 中国石油天然气股份有限公司 一种乙烯四聚的方法
EP4581003A1 (en) 2022-09-02 2025-07-09 SABIC Global Technologies B.V. Methods for producing 1-hexene
CN116553993B (zh) * 2023-05-17 2025-01-03 中化学科学技术研究有限公司 一种α-烯烃的生产方法

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WO2003053891A1 (en) * 2001-12-20 2003-07-03 Sasol Technology (Pty) Ltd. Trimerisation and oligomerisation of olefins using a chromium based catalyst

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10688473B2 (en) 2014-12-11 2020-06-23 Lg Chem, Ltd. Ligand compound, organic chromium compound, catalyst system for oligomerization of olefins, and method for oligomerizing olefins using the same
US10392451B2 (en) 2015-06-12 2019-08-27 Lg Chem, Ltd. Ligand compound, organic chromium compound, catalyst system for olefin oligomerization, and method for oligomerizing olefins using the same thereof

Also Published As

Publication number Publication date
JP5462179B2 (ja) 2014-04-02
EP2219784B1 (en) 2012-10-24
CA2703021C (en) 2015-01-20
US20100298618A1 (en) 2010-11-25
MY150515A (en) 2014-01-30
RU2010126183A (ru) 2012-01-10
KR20100088665A (ko) 2010-08-10
CA2703021A1 (en) 2009-06-04
WO2009068157A1 (en) 2009-06-04
TW200942327A (en) 2009-10-16
CN101855015B (zh) 2013-07-17
JP2011504799A (ja) 2011-02-17
EP2219784A1 (en) 2010-08-25
CN101855015A (zh) 2010-10-06
BRPI0819904B1 (pt) 2018-02-06
ES2397303T3 (es) 2013-03-06
US8778827B2 (en) 2014-07-15
BRPI0819904A2 (pt) 2015-09-15
RU2467797C2 (ru) 2012-11-27
TWI440503B (zh) 2014-06-11
MX2010005266A (es) 2010-06-02

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