KR101287772B1 - Duplex stainless steel wire material, steel wire, bolt, and method for production of the bolt - Google Patents

Abstract

The austenite-ferritic two-phase steel wire for high strength and high corrosion resistance bolts excellent in cold forging is in mass%, C; 0.005 to 0.05%, Si; 0.1 to 1.0%, Mn; 0.1 to 10.0%, Ni; 1.0 to 6.0%, Cr; 19.0 to 30.0%, Cu; 0.05 to 3.0%, N; 0.005 to 0.20%, and the remainder is composed of Fe and substantially inevitable impurities, and C + N; 0.20% or less, M value of (a) formula is 60 or less, F value of (b) formula is 45-85, and tensile strength is 550-750 N / mm <2>.

Description

2-phase stainless steel wire, steel wire and bolt and manufacturing method thereof {DUPLEX STAINLESS STEEL WIRE MATERIAL, STEEL WIRE, BOLT, AND METHOD FOR PRODUCTION OF THE BOLT}

The present invention relates to a two-phase stainless steel wire material having excellent cold forging, and provides, for example, a high-strength bolt having corrosion resistance on the order of SUS304 at low cost.

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a soft two-phase stainless steel wire rod having magnetic properties with excellent cold workability. For example, cold-worked parts such as screws, pins, wire mesh, wires, ropes, and springs having corrosion resistance of about SUS304 and SUS316. The present invention relates to a soft two-phase stainless steel wire rod having excellent cold workability that can be provided at a low cost and which has been magnetized.

This application claims priority based on Japanese Patent Application No. 2007-264992 for which it applied to Japan on October 10, 2007, and Japanese Patent Application No. 2007-264993 for which it applied to Japan on October 10, 2007, and , Use the content here.

Up to now, SUS304 wire rods have been used universally for high strength and high corrosion resistant bolts having a strength of 700 N / mm 2. However, in recent years, higher strength (lighter weight) of bolts has been demanded in the fields of automobiles and home appliances. In addition, since SUS304 bolts contain many expensive Ni raw materials and have a high price, low cost has also been strongly demanded.

Up to now, the high strength of the bolt has been supported by, for example, SUS630 bolt of martensitic stainless steel (for example, Patent Document 1).

However, SUS630 bolts are excellent in strength, but not only have insufficient corrosion resistance, but also have a significantly low cold forging, so the manufacturing cost is significantly high, and their use has been very limited.

In addition, high-strength bolts made of inexpensive martensitic stainless steel of about 13% Cr having excellent manufacturability have been proposed (Patent Document 2). However, its corrosion resistance is insufficient and its use is limited.

In addition, high-strength bolts made of high (C + N) austenitic stainless steel have been proposed (Patent Document 3). However, since cold forging is inferior, manufacturing cost is significantly high and it is not accepted by the market.

On the other hand, in recent years, the low-Ni low-cost two-phase stainless steel (patent documents 4-6) which suppressed use of expensive Ni is proposed.

However, in the conventional two-phase stainless steel, cold forging property is bad and manufacturing cost is high, and the bolt of two-phase stainless steel did not exist in the market.

As described above, there have been no products having high corrosion resistance, high strength, high cold forging, and low cost in the stainless steel bolt and the stainless steel wire for bolt.

Products such as screws, pins, wire mesh, and wires that require corrosion resistance have been manufactured by using austenitic stainless steel wires such as SUS304 and SUSXM7 by cold working such as drawing, cold forging, and bending. . In the cold working of wire rods, unlike the press formability of steel sheets which require high drawing properties of materials, soft and high tensile breaking drawing properties are required (high drawing properties are not required). Soft is the tensile strength of the wire rod, 700 N / mm 2 or less, preferably 650 N / mm 2 or less is required.

However, since a large amount of expensive Ni is added to the product of the austenitic stainless steel, there is a drawback that the product price is high despite being an inexpensive manufacturing process.

In addition, the austenitic stainless steel is not magnetic, and thus it does not adhere to the tool during fastening of the fastener, so the workability is poor. There was no magnetic force, such as the mixing could not be checked, causing further inconvenience.

For products requiring magnetic and corrosion resistance, ferritic stainless steel wires made of ferritic stainless steel wires and containing Nb at low C and N have been proposed (Patent Documents 7 to 9).

However, not only the corrosion resistance of the cold worked product was insufficient, but the manufacturing cost was high in the high Cr system due to surface damage during wire rod rolling.

On the other hand, a lot of inexpensive two-phase stainless steel which reduced Ni recently is proposed (patent document 10-12).

Patent document 10 describes a high strength two-phase stainless steel having excellent Young's modulus containing 0.04% or more of nitrogen which increases strength in a low Ni system. However, in order to increase the strength, more than 1% of Si and 0.04% or more of nitrogen are added, and high-strength steels exceeding 80 kg / mm 2 are described in the examples, and a thinking method of soft and high tensile fracture drawing characteristics is described. There is no substantially cold workability of the wire rod.

Patent Document 11 describes a two-phase stainless steel having corrosion resistance and good weldability containing 0.05% or more of nitrogen in a low Ni system. However, the cold workability is not described, and the preferred range of nitrogen for increasing the strength is 0.06 to 0.12%, and the examples include steel (low Si steel) containing 0.13% or more of nitrogen, and soft and high tensile fracture. There is no way of thinking called drawing characteristics, and the cold workability of the wire rod is practically difficult.

Patent document 12 describes a high strength two-phase stainless steel having excellent relaxation in a low Ni system containing 0.05% or more of nitrogen. However, in Examples, steels containing 0.13% or more of nitrogen to increase the strength are described, and there is no thought of soft and high tensile fracture drawing characteristics, and the cold workability of the wire rod is practically difficult.

Patent document 13 describes a two-phase stainless steel having excellent ductility and deep drawing properties containing nitrogen of 0.05% or more in a low Ni system. However, the examples describe steel containing 0.08% or more of nitrogen, which increases the strength in order to improve the drawing and improve the deep drawing property of the steel sheet, and there is no way of thinking that it is soft and has high tensile fracture drawing characteristics. Cold workability of wire rod is difficult.

Thus far, stainless steel has not been soft and has high breaking drawing characteristics necessary for cold workability of wire rods, and is inexpensive and exhibits high corrosion resistance and magnetization.

(Patent Document 1) Patent Document 1: Japanese Patent Application Laid-open No. Hei 9-314276

(Patent Document 2) Patent Document 2: Japanese Patent Application Laid-Open No. 2005-179718

(Patent Document 3) Patent Document 3: Japanese Patent Application Laid-Open No. 2006-274295

(Patent Document 4) Patent Document 4: International Publication WO2005 / 073422

(Patent Document 5) Patent Document 5: Japanese Patent No. 3327262

(Patent Document 6) Patent Document 6: EP0337846

Patent Document 7: Patent Document 7: Japanese Patent No. 2906445

(Patent Document 8) Patent Document 8: Japanese Patent No. 2817266

Patent Document 9: Patent Document 9: Japanese Patent Application Laid-open No. 2006-16665

(Patent Document 10) Patent Document 10: Japanese Patent Application Laid-open No. 62-47461

(Patent Document 11) Patent Document 11: Japanese Patent Application Laid-Open No. 61-56267

(Patent Document 12) Patent Document 12: Japanese Patent Application Laid-open No. Hei 2-305940

(Patent Document 13) Patent Document 13: Japanese Patent Application Laid-open No. 2006-169622

SUMMARY OF THE INVENTION An object of the present invention is to provide an inexpensive high-strength, high corrosion resistant bolt of austenitic and ferritic two-phase steel wire, steel wire and bolt, and a method of manufacturing the same. This provides cold forging and high strength of bolt products.

SUMMARY OF THE INVENTION An object of the present invention is to provide an inexpensive two-phase stainless steel wire having excellent cold workability and corrosion resistance, and having magnetic properties, thereby significantly reducing the manufacturing cost of a cold-worked product of a conventional austenitic stainless steel wire and providing magnetism. To give.

MEANS TO SOLVE THE PROBLEM As a result of various examinations in order to solve the said subject, as a result of reducing the expensive Ni content in highly corrosion-resistant two-phase stainless steel, the structure was stabilized by component adjustment (low M value), and the volume fraction of a ferrite phase was improved. It was found that by controlling the height and optimizing the tensile strengths of wire rods and steel wires by heat treatment and drawing, it is possible to achieve both low cold forging and high strength of bolt products.

In addition, the inventors of the present invention, based on the ferritic + austenite phase of high corrosion resistance two-phase stainless steel, reduce the cost of Ni and control the structure by controlling the components (M value control), and further reduce the (C + N) By suppressing work hardening, it has been found that it is possible to impart a remarkably excellent cold workability in an inexpensive high corrosion resistant two-phase stainless steel wire.

This invention is made | formed based on the said knowledge, The summary is as follows.

That is, the first aspect of the present invention,

In terms of% by mass,

C; 0.005 to 0.05%,

Si; 0.1 to 1.0%,

Mn; 0.1 to 10.0%,

Ni; 3.0% or more but 6.0% or less,

Cr; 19.0 to 30.0%,

Cu; 0.05 to 3.0%,

N; 0.005 to 0.20%, and the remainder is composed of Fe and substantially inevitable impurities, and C + N; It is an austenite-ferritic two-phase steel wire of 0.20% or less, M value of formula (a) is 60 or less, F value of formula (b) is 45 to 85, and tensile strength is 550 to 750 N / mm 2.

The second aspect of the present invention, in addition to the first aspect,

In terms of% by mass,

Mo; 1.0% or less,

B; You may contain one or both in 0.01% or less.

The third aspect of the present invention is in addition to the first aspect,

In terms of% by mass,

Al; 0.1% or less,

Mg; 0.01% or less,

Ca; You may contain 1 or more types in 0.01% or less.

The fourth aspect of the present invention is in addition to the first aspect,

In terms of% by mass,

Mo; 1.0% or less,

B; It contains one or both in 0.01% or less,

Al; 0.1% or less,

Mg; 0.01% or less,

Ca; In 0.01% or less, you may contain 1 or more types.

The fifth aspect of the present invention is in addition to the first aspect,

In terms of% by mass,

Nb; 1.0% or less,

Ti; 0.5% or less,

V; 1.0% or less,

Zr; You may contain 1 or more types in 1.0% or less.

The sixth aspect of the present invention is in addition to the first aspect,

In terms of% by mass,

Mo; 1.0% or less,

B; It contains one or both in 0.01% or less,

Nb; 1.0% or less,

Ti; 0.5% or less,

V; 1.0% or less,

Zr; You may further contain 1 or more types in 1.0% or less.

7th aspect of this invention is in addition to a 1st aspect,

In terms of% by mass,

Al; 0.1% or less,

Mg; 0.01% or less,

Ca; It contains 1 or more types in 0.01% or less,

Nb; 1.0% or less,

Ti; 0.5% or less,

V; 1.0% or less,

Zr; You may further contain 1 or more types in 1.0% or less.

The eighth aspect of the present invention is in addition to the first aspect,

In terms of% by mass,

Mo; 1.0% or less,

B; It contains one or both in 0.01% or less,

Al; 0.1% or less,

Mg; 0.01% or less,

Ca; In 0.01% or less, 1 or more types are further contained,

Nb; 1.0% or less,

Ti; 0.5% or less,

V; 1.0% or less,

Zr; You may further contain 1 or more types in 1.0% or less.

The ninth aspect of the present invention has the chemical composition according to any one of the first to eighth aspects, and has a high-strength, high corrosion-resistant austenitic-ferritic bolt for cold forging with a tensile strength of 700 to 1000 N / mm 2. It is a 2-phase steel wire.

A tenth aspect of the present invention is a high strength, high corrosion resistant bolt having a chemical composition according to any one of the first to eighth aspects and having a tensile strength of 700 to 1200 N / mm 2.

The eleventh aspect of the present invention has the chemical composition according to any one of the first to eighth aspects, and the austenitic ferritic two-phase steel wire having a tensile strength of 700 to 1000 N / mm 2 is 300 to 300 after cold bolt forming. It is a manufacturing method of high strength and high corrosion resistance bolt which performs the aging heat treatment for 1 to 100 minutes at 600 degreeC.

According to a twelfth aspect of the present invention,

In terms of% by mass,

C; 0.005 to 0.05%,

Si; 0.1 to 1.0%,

Mn; 0.1 to 10.0%,

Ni; 3.5 to 6.0%,

Cr; 19.0 to 30.0%,

Cu: 0.05 to 3.0%,

N; 0.005% or more and less than 0.06%, the remainder being composed of Fe and substantially unavoidable impurities, and C + N; It is a soft two-phase stainless steel wire material which has magnetization excellent in cold workability which is 0.09% or less, M value of (a) formula is 60 or less, tensile strength is 700 N / mm <2> or less, and tensile fracture drawing is 70% or more.

The thirteenth aspect of the present invention is in addition to the twelfth aspect,

In terms of% by mass,

Mo; 3.0% or less,

B; You may contain one or both in 0.01% or less.

A fourteenth aspect of the present invention is in addition to the twelfth aspect,

In terms of% by mass,

Al; 0.1% or less,

Mg; 0.01% or less,

Ca; You may contain 1 or more types in 0.01% or less.

A fifteenth aspect of the present invention is in addition to the twelfth aspect,

In terms of% by mass,

Mo; 3.0% or less,

B; It contains one or both in 0.01% or less,

Al; 0.1% or less,

Mg; 0.01% or less,

Ca; In 0.01% or less, you may contain 1 or more types.

A sixteenth aspect of the present invention is in addition to the twelfth aspect,

In terms of% by mass,

Nb; 1.0% or less,

Ti; 0.5% or less,

V; 1.0% or less,

Zr; You may contain 1 or more types in 1.0% or less.

A seventeenth aspect of the present invention is in addition to the twelfth aspect,

In terms of% by mass,

Mo; 3.0% or less,

B; It contains one or both in 0.01% or less,

Nb; 1.0% or less,

Ti; 0.5% or less,

V; 1.0% or less,

Zr; You may further contain 1 or more types in 1.0% or less.

An eighteenth aspect of the present invention is in addition to the twelfth aspect,

In terms of% by mass,

Al; 0.1% or less,

Mg; 0.01% or less,

Ca; It contains 1 or more types in 0.01% or less,

Nb; 1.0% or less,

Ti; 0.5% or less,

V; 1.0% or less,

Zr; You may further contain 1 or more types in 1.0% or less.

A nineteenth aspect of the present invention is in addition to the twelfth aspect,

In terms of% by mass,

Mo; 3.0% or less,

B; It contains one or both in 0.01% or less,

Al; 0.1% or less,

Mg; 0.01% or less,

Ca; In 0.01% or less, 1 or more types are further contained,

Nb; 1.0% or less,

Ti; 0.5% or less,

V; 1.0% or less,

Zr; You may further contain 1 or more types in 1.0% or less.

Although the two-phase stainless steel wire for high strength and high corrosion resistance bolts having excellent cold forging property according to the present invention does not contain expensive Ni much, it is possible to secure excellent cold forging properties and to provide high corrosion resistance and high strength of about SUS304 or more. It is possible to provide high strength and high corrosion resistance bolts at low cost.

Although the soft two-phase stainless steel wire rod having excellent cold workability according to the present invention does not contain much expensive Ni, it has a remarkably excellent cold workability, magnetization and corrosion resistance as much as austenitic stainless steel such as SUS304 and SUS316. It is possible to impart, and exhibits a remarkable effect that it is possible to provide a highly corrosion-resistant product having magnetism at a low cost.

BRIEF DESCRIPTION OF THE DRAWINGS It is a figure which shows the relationship between the F value and the volume fraction of the ferrite phase of a wire rod product.
It is a figure which shows the relationship between the processing rate (%) of a steel wire (15% drawn material), and compressive strain stress (N / mm <2>) according to F value.

The reason for limitation of the 1st-8th aspect of this invention is demonstrated.

C is contained 0.005% or more in order to secure the strength of the bolt product. However, if it contains more than 0.05%, Cr carbonitride is produced and corrosion resistance is not only deteriorated, but cold forging property is deteriorated, and it is limited to 0.05% or less. Preferably it is 0.03% or less.

N is contained in an amount of 0.005% or more in order to secure the strength of the bolt product by solid solution strengthening and aging hardening. However, when it contains exceeding 0.20%, cold forging property will remarkably deteriorate. Therefore, an upper limit is made into 0.20%. The preferred range is less than 0.05%.

C + N is limited to 0.20% or less from the above-mentioned reasons of cold forging. Preferably it is 0.10% or less.

Si contains 0.1% or more for deoxidation. However, when it contains exceeding 1.0%, cold forging property will deteriorate. Therefore, an upper limit is made into 1.0%. The preferred range is 0.2 to 0.6%.

Mn contains at least 0.1% as an adjustment for deoxidation and to obtain a stable austenite structure. However, when it contains exceeding 10.0%, rust prevention and a ferrite volume fraction will decrease, tensile strength will rise, and cold forging property will deteriorate. Therefore, the upper limit is limited to 10.0%. The preferred range is 0.5 to 5.0%.

Ni is contained 3.0% or more in order to stabilize austenite structure and to secure cold forging property. However, even if it contains more than 6.0%, the effect will be saturated, conversely, the volume fraction of a ferrite phase will be 45% or less, cold forging property (tool life) will not only deteriorate, but Ni will be expensive and it will be inferior in economic efficiency. Therefore, an upper limit is limited to 6.0%. Preferable range is more than 3.0 and 5.0% or less.

Cr is contained 19.0% or more in order to secure corrosion resistance, increase the volume fraction of the ferrite phase, stabilize the austenite structure and secure cold forging. However, even if it contains exceeding 30.0%, the effect is saturated, and since the volume fraction of a ferrite phase exceeds 85%, the strength of a bolt product falls. Therefore, an upper limit is made into 30.0%. The preferred range is 22.0 to 26.0%.

Cu is effective in stabilizing the austenite structure, suppressing work hardening to improve cold forging property, and promoting the hardening of ferrite phase by aging at the time of aging treatment after cold forging, thereby increasing the strength of bolt products. Therefore, it contains 0.05% or more. However, when it contains exceeding 3.0%, since the hot manufacturability of a raw material will remarkably deteriorate over the solid solution limit of Cu, an upper limit shall be 3.0%. Preferable ranges are 0.2% or more and less than 1.0%.

The M value of the following formula (a) contributes to the stability of the austenite phase and is an index described in Iron and Steel, 63 (1977), page 772. When the M value is high, a hard processed organic martensite phase is produced. In the case of cold forging of two-phase stainless steel, when the M value exceeds 60, a hard processed organic martensite phase is generated during cold forging, and the cold forging property is significantly degraded. [Tool life inferiority, cold forging crack generation] ]. Therefore, M value is limited to 60 or less. The preferable range is 40 or less.

The F value of the following formula (b) contributes to the volume fraction of the ferrite phase, and is an index described in Japanese Patent Application Laid-open No. Hei 7-74416. As the F value increases, the ferrite phase increases. FIG. 1 shows the F value and the volume fraction of the ferrite phase of the two-phase stainless steel product. When the F value is 45 or more, the volume fraction of the ferrite phase becomes 45 vol.% Or more, showing high yield strength and low-pore curing properties (Fig. 2), and the strength (tensile strength of the bolt shaft portion) of the product is 700 to 1200 N / mm 2. It is possible to increase the strength and ensure cold forging of the head portion. Therefore, F value is limited to 45 or more. As shown in the relationship between the machining rate (%) and the compressive strain stress (N / mm 2) according to the F value in FIG. 2, when the F value is less than 45, the work hardening is large and the cold forging property (pressure cracking, tool damage) This is greatly degraded. On the other hand, when the F value exceeds 85, the soft ferrite phase exceeds 85%, and the high austenite phase stems, so that the strength of the bolt product is reversed. Therefore, the upper limit is made into 85. The preferred range is 50 to 80.

The tensile strength of the wire rod greatly contributes to cold forging. When the tensile strength of the wire rod is less than 550 N / mm 2, the strength of cold forged parts such as bolts is low, and the value as a high strength product is lowered. Therefore, the minimum is limited to 550 N / mm 2. On the other hand, when the tensile strength of the wire rod exceeds 750 N / mm 2, the cold forging property is remarkably deteriorated (deterioration of tool life and cold forging cracking). Therefore, an upper limit is made into 750 N / mm <2>. The preferred range is 600 to 700 N / mm 2.

Mo is an effective element for improving corrosion resistance, and the effect is stably obtained by addition of 0.1% or more. However, when it contains exceeding 1.0%, not only will cost of a material rise, but a material will become hard and cold forging property will deteriorate. Therefore, an upper limit is limited to 1.0%. Preferable ranges are 0.2% or more and less than 0.5%.

B is an element effective for improving hot workability, and the effect is stably obtained by addition of 0.001% or more. However, even if it contains exceeding 0.01%, boride will generate | occur | produce, and corrosion resistance and cold forging property will deteriorate. Therefore, an upper limit is limited to 0.01%. The preferred range is 0.002% to 0.006%.

Al, Mg, Ca are effective for deoxidation, and therefore Al; 0.005% or more and Mg; 0.001% or more and Ca; The effect is stably obtained by adding one or more kinds of 0.001% or more. However, Al; 0.1%, Mg; 0.01%, Ca; Even if it contains exceeding 0.01%, the effect will be saturated, a coarse oxide (inclusion) will generate | occur | produce, and cold forging crack will generate | occur | produce. Therefore, an upper limit is Al; 0.1%, Mg; 0.01%, Ca; Let it be 0.01%. Preferred ranges are Al; 0.01 to 0.06%, Mg; 0.002 to 0.005%, Ca; It is made to contain one or more types of 0.002 to 0.005%.

Nb, Ti, V, and Zr are effective for inhibiting the formation of Cr carbonitride and securing corrosion resistance, and Nb; 0.05% or more and Ti; 0.02% or more, V; 0.05% or more, Zr; The effect is stably obtained by addition of one or more kinds of 0.05% or more. However, Nb; 1.0%, Ti; 0.5%, V; 1.0%, Zr; Even if it contains exceeding 1.0%, the effect will be saturated, a coarse precipitate will generate | occur | produce, and cold forging crack will generate | occur | produce. Therefore, the upper limit of each element is prescribed | regulated. Preferred ranges are Nb; 0.1 to 0.6%, Ti; 0.05 to 0.5%, V; 0.1 to 0.6%, Zr; In 0.1 to 0.6%, 1 or more types are contained.

Usually, as an unavoidable impurity, steel contains oxygen in a manufacturing process, but in this invention, it is preferable to set it as 0.01% or less of oxygen as an unavoidable impurity.

Although the wire rod is drawn and drawn into a drawn steel wire, the tensile strength of the steel wire greatly contributes to cold forging and bolt product strength. When the tensile strength of the steel wire is less than 700 N / mm 2, the strength of the bolt product is lowered, and the value as a high strength product Lowers. Therefore, the lower limit is limited to 700 N / mm 2. On the other hand, when the tensile strength of the steel wire exceeds 1000 N / mm 2, the cold forging property is remarkably deteriorated (deterioration of tool life and cold forging cracking). Therefore, an upper limit shall be 1000 N / mm <2>. The preferred range is 750 to 900 N / mm 2.

The tensile strength of the high strength bolt of the present invention is increased in aging heat treatment after drawing and cold forging. At this time, when the tensile strength of the bolt product is less than 700 N / mm 2, the value as a high strength bolt product is low. On the other hand, when the tensile strength of a bolt product is 1200 N / mm <2> or more, cold forging costs, such as a cold forging crack and a tool damage, remarkably deteriorate. Therefore, the upper limit of the tensile strength of a bolt product shall be 1200 N / mm <2>. The range with preferable economic effect is 800-1000 N / mm <2>.

After forming the steel wire of the present invention to the bolt by cold forging, in order to effectively improve the tensile strength of the bolt product, it is effective to perform an aging heat treatment of 300 ° C. or more for 1 minute or more. On the other hand, when it exceeds 600 degreeC, since it becomes overaging, the tensile strength of a bolt product falls. Therefore, an upper limit is made into 600 degreeC. The preferred temperature range is 400 to 550 ° C. In addition, when the holding time exceeds 100 minutes, not only the effect of aging hardening is saturated, but also the tensile strength of a bolt product falls by overaging in some cases. Therefore, the upper limit of the holding time is 100 minutes. Preferred retention times range from 5 to 60 minutes.

The reason for limitation of the 9th thru | or 13th aspect of this invention is demonstrated.

C is added 0.005% or more in order to secure the strength of the steel. However, when it exceeds 0.05%, not only cold workability deteriorates but Cr carbide produces | generates and corrosion resistance also deteriorates. Therefore, an upper limit is made into 0.05% or less. The preferred range is 0.01 to 0.03%.

N is added in 0.005% or more in order to secure the strength of the cold worked part by solid solution strengthening. However, when 0.06% or more is added, tensile strength rises and cold workability deteriorates. Therefore, an upper limit is made into less than 0.06%. In ordinary two-phase stainless steels, N is added at least 0.06% in order to reduce the use of expensive alloying elements. However, in the case of this steel, the N content is kept low while controlling the structure and the balance of components, thereby making it soft and cold workability of wire rods is remarkable. It is characterized by the improvement. Preferable ranges are 0.02 or more and less than 0.05%.

C + N is limited to 0.09% or less for the reasons of the cold workability described above. Preferably it is 0.07% or less.

Si is added at least 0.1% for deoxidation. However, when it adds exceeding 1.0%, it will harden and deteriorate cold workability. Therefore, an upper limit is made into 1.0%. The preferred range is 0.2 to 0.6%.

Mn is added in an amount of 0.1% or more for deoxidation and to obtain a two-phase structure of ferrite + austenite and to stabilize the austenite structure. However, when it adds exceeding 10.0%, cold workability will deteriorate by corrosion resistance and strength increase. Therefore, the upper limit is limited to 10.0%. The preferred range is 0.5 to 5.0%.

Ni lowers the M value to obtain a two-phase structure of ferrite + austenite, stabilizes the austenite structure, and adds 3.5% to secure cold workability. However, even if it adds exceeding 6.0%, the effect is saturated, and since Ni is expensive, it is inferior to economic efficiency. Therefore, an upper limit is limited to 6.0%. Preferred range is 3.5 to 5.0%.

Cr is added 19.0% or more in order to secure corrosion resistance, to obtain a two-phase structure of ferrite + austenite, to stabilize the austenite structure and to secure cold workability. However, even if it adds exceeding 30.0%, the effect is saturated and cold workability deteriorates on the contrary. Therefore, an upper limit is made into 30.0%. The preferred range is 20.0 to 26.0%.

Cu is contained at 0.05% or more in order to lower M value to obtain a two-phase structure of ferrite + austenite, stabilize the austenite structure, suppress work hardening and improve cold workability. However, when it contains exceeding 3.0%, since the hot manufacturability of a raw material will remarkably deteriorate over the solid solution limit of Cu, an upper limit shall be 3.0%. The preferred range is less than 1.0%.

The M value of the following formula (a) contributes to the stability of the austenite phase and is an index described in Iron and Steel, 63 (1977), page 772. When the M value is high, a hard processed organic martensite phase is produced. In the case of cold forging of two-phase stainless steel, when the M value exceeds 60, a hard processed organic martensite phase is produced at the time of cold working, and cold workability deteriorates remarkably. Therefore, M value is limited to 60 or less. The preferable range is 40 or less.

The tensile strength of the wire rod greatly contributes to the cold workability of the wire rod, and when the tensile strength of the wire rod exceeds 700 N / mm 2, the cold workability is significantly degraded. Therefore, an upper limit is made into 700 N / mm <2>. On the other hand, when the tensile strength of the wire rod is less than 500 N / mm 2, the strength of the cold worked product is too low, resulting in low value as a product. Therefore, Preferably, a minimum is limited to 500 N / mm <2>. The preferable range is 500-650 N / mm <2>.

The tensile breaking drawing of the wire rod greatly contributes to the cold workability of the wire rod, and when the tensile breaking drawing of the wire rod is less than 70%, cold workability such as cold drawing and cold forging deteriorates. Therefore, it limits to 70% or more. The preferable range is 75% or more.

Magnetism is a function not found in austenitic stainless steel, and it improves workability by magnetization to a magnetic tool when fastening fasteners, and materials are dropped into wires and meshes (especially food conveyors, etc.) and incorporated into food. In the case of the magnetic sensor in this case, the magnetization is industrially large, such as mixing prevention. Therefore, magnetism is limited in the present invention. Preferably it is 3.0 or more in specific induction rate.

Mo is an effective element for improving the corrosion resistance, and the effect is stably obtained by addition of 0.1% or more. However, when the content exceeds 3%, not only the material is hardened, but also sigma phase is precipitated, and the cold workability is significantly degraded. Therefore, an upper limit is limited to 3%. The preferred range is 0.3 to 1.0%.

B is an effective element for improving hot workability, and the effect is stably obtained by addition of 0.001% or more. However, even if it adds exceeding 0.01%, boride will generate | occur | produce, and corrosion resistance and cold workability will deteriorate. Therefore, an upper limit is limited to 0.01%. The preferred range is 0.002% to 0.006%.

Al, Mg, Ca are effective for deoxidation, and therefore Al; 0.005% or more and Mg; 0.001% or more and Ca; The effect is stably obtained by adding one or more kinds of 0.001% or more. However, Al; 0.1%, Mg; 0.01%, Ca; Even if it contains exceeding 0.01%, the effect is saturated, a coarse oxide (inclusion) arises on the contrary, and cold workability deteriorates. Therefore, an upper limit is Al; 0.1%, Mg; 0.01%, Ca; Let it be 0.01%. Preferred ranges are Al; 0.008 to 0.06%, Mg; 0.001 to 0.005%, Ca; It is made to contain one or more types of 0.001 to 0.005%.

Nb, Ti, V, and Zr are effective for inhibiting the formation of Cr carbonitride and securing corrosion resistance, and Nb; 0.01% or more and Ti; 0.01% or more, V; 0.01% or more and Zr; The effect is stably obtained by addition of one or more types of 0.01% or more. However, Nb; 1.0%, Ti; 0.5%, V; 1.0%, Zr; Even if it contains exceeding 1.0%, the effect will be saturated, a coarse precipitate will arise on the contrary, and cold workability will deteriorate. Therefore, the upper limit of each element is prescribed | regulated. Preferred ranges are Nb; 0.05 to 0.6%, Ti; 0.05 to 0.5%, V; 0.1 to 0.6%, Zr; At least 1 type is contained in 0.05 to 0.6%.

Usually, as an unavoidable impurity, steel contains oxygen in a manufacturing process, but in this invention, it is preferable to set it as 0.01% or less of oxygen as an unavoidable impurity.

(First embodiment)

The first embodiment of the present invention will be described below.

Tables 1 to 4 show the chemical composition of the steel of the first example.

Steels of these chemical compositions were melted in a 300 kg vacuum melting furnace, cast into φ180 mm cast pieces, hot rolled the cast pieces to φ5.5 to 6.5 mm, and finished hot rolling at 1050 ° C. Subsequently, an inline heat treatment was performed at 1050 ° C. for 5 minutes, followed by a solution treatment of water cooling, followed by pickling to obtain a wire rod product. Thereafter, an oxalic acid film treatment was performed, the drawing wire processing was performed by cold to φ5.2 mm, and finished with cold forging steel wire.

Then, about 5000 pieces were processed by the hexagon bolt by cold forging and rolling. And some ageed 300-650 degreeC and the aging process for 3 to 200 minutes hold | maintenance were performed. Thereafter, all bolts were finished with a hexagon bolt product by barrel polishing and washing.

The evaluation evaluated the tensile strength of the steel wire, the volume fraction of the ferrite phase of the steel wire, the cold forging property (with or without cracks and the absence of tools), the tensile strength of the bolt product, and the corrosion resistance. The evaluation results are shown in Tables 5 to 8.

Mechanical properties were evaluated by tensile strength and fracture drawing in the tensile test of JIS Z 2241. In the steel wire of the example of this invention, all were in the range of 650-1000 N / mm <2>, In the bolt product of this invention, all were in the range of 700-1200 N / mm <2>, and were excellent in high strength.

The volume fraction of the ferrite phase of the steel wire was mirror-polished on the longitudinal cross section of the steel wire, the ferrite phase was colored with Murakami reagent, and the area ratio was calculated by image analysis to obtain the volume fraction. The ferrite fraction of the steel wire of the example of this invention was in the range of 45-85 vol.%.

Cold forging was carried out by 5000 pressure milling to a hexagonal head by a three-stage header, and evaluated for the presence or absence of a pressure crack and tool damage. The tool life (circle) and the case where tool damage generate | occur | produced the case where tool damage did not generate | occur | produced and evaluated it as tool life x. The wire rod of the example of this invention was excellent in cold forging property with the absence of a cold crack and tool life (circle).

Corrosion resistance of the bolt product was evaluated according to the salt spray test of JIS Z 2371 by performing a spray test for 10 hours on each bolt product for 100 hours to determine whether rust occurred. In the case of no rust generation and a slight spot rust level, the corrosion resistance was evaluated as ○, in the case of flowing rust and total surface rust generation, the corrosion resistance was evaluated as x. The antirust property of the bolt product of the example of this invention was all (circle).

On the other hand, Comparative Examples Nos. 38 to 61 are outside the scope of the present invention, and the cold forging property, the strength of the bolt product, the corrosion resistance, and the like are deteriorated, and the superiority of the present invention is obvious.

(Second Embodiment)

A second embodiment of the present invention will be described below.

In Table 9 and Table 10, the chemical composition (mass%) of the steel (test material) used by the 2nd Example is shown.

Steels of these chemical compositions were melted in a 150 kg vacuum melting furnace, cast into φ180 mm cast pieces, hot rolled the cast pieces to φ5.5 mm, and finished hot rolling at 1050 ° C. , 1050 ° C. for 5 minutes, water-cooled continuous heat treatment was performed, and pickling was performed to obtain a wire rod. Thereafter, cold steel wire working was performed to a diameter of 2.0 mm by a normal process, and the steel wire was cold worked by bending with a mesh mesh for conveyors.

The evaluation evaluated the tensile strength of the wire rod, the tensile fracture drawing, the cold workability, the corrosion resistance, and the magnetization. The evaluation results are shown in Tables 11 and 12.

Tensile strength and tensile breaking drawing of the wire rod were evaluated by tensile strength and breaking drawing in the tensile test of JIS Z2241. In the wire rod of the example of the present invention, all have tensile strength; 500-700 N / mm <2> and breaking drawing more than 70% of range.

Cold workability was evaluated by cold drawing and subsequent wire mesh workability. The cold formability in the case where it could be formed into a wire mesh without disconnection or breakage was evaluated as (circle), and the case where it could not be formed into the wire mesh by disconnection or breakage was evaluated as x. In the wire rod of the example of the present invention, there was no disconnection or breakage and excellent cold workability.

After the surface layer of the pickled wire rod was polished to # 500, corrosion resistance was tested by a salt spray test of JIS Z 2371 for 100 hours to evaluate whether or not rust occurred. In the case of no rust generation and the point rust level, corrosion resistance was evaluated as ○, and in the case of flowing rust and whole surface rust generation, corrosion resistance was evaluated as x. The evaluation of the corrosion resistance of the steel of this invention was all (circle).

Magnetism was measured in specific wire by ferrite meter (simple rheometer) in wire mesh. When the specific inertia rate was 3.0 or more in which magnetism was clearly confirmed, the case with magnetism and less than 3.0 was evaluated as no magnetization.

On the other hand, Comparative Examples Nos. 86 to 107 are outside the scope of the present invention and deteriorate in cold workability, corrosion resistance, cost, magnetism, and the like, and the superiority of the present invention is obvious.

As is clear from each of the above examples, the highly corrosion-resistant two-phase stainless steel wire which does not contain much expensive Ni of the present invention has excellent cold forging ability and high strength of bolt products, and high strength and high corrosion resistance bolts are inexpensive. It is also possible to provide a nut, and also can be applied to nuts, which is extremely useful industrially.

As is clear from each of the above examples, the present invention makes it possible to produce inexpensive two-phase stainless steel wire which is soft and has magnetism, and has excellent cold workability, which is equivalent to that of austenitic stainless steels such as SUS304 and SUS316. Corrosion resistance can be imparted, and highly corrosion-resistant cold work products having magnetism such as screws, pins, wire mesh, wires, ropes, and springs can be provided at low cost, and are extremely useful industrially.

Claims (19)

In mass%
C; 0.005 to 0.05%,
Si; 0.1 to 1.0%,
Mn; 0.1 to 10.0%,
Ni; 3.0% or more but 6.0% or less,
Cr; 19.0 to 30.0%,
Cu: 0.05-3.0%,
N; 0.005 to 0.20%
&Lt; / RTI &gt;
The remainder is composed of Fe and substantially inevitable impurities, and C + N; Austenite-ferritic two-phase excellent in cold forging property of 0.20% or less, M value of formula (a) is 60 or less, F value of formula (b) is 45 to 85, and tensile strength is 550 to 750 N / mm 2 Steel wire.

3. The composition according to claim 1, wherein, in mass%
Mo; 1.0% or less,
B; An austenite-ferritic two-phase steel wire which is excellent in cold forging property containing one or both in 0.01% or less. 3. The composition according to claim 1, wherein, in mass%
Al; 0.1% or less,
Mg; 0.01% or less,
Ca; An austenite-ferritic two-phase steel wire which is excellent in cold forging property containing 1 or more types in 0.01% or less. 3. The composition according to claim 1, wherein, in mass%
Mo; 1.0% or less,
B; It contains one or both in 0.01% or less,
Al; 0.1% or less,
Mg; 0.01% or less,
Ca; An austenite-ferritic two-phase steel wire which is excellent in cold forging property which further contains 1 or more types in 0.01% or less. 3. The composition according to claim 1, wherein, in mass%
Nb; 1.0% or less,
Ti; 0.5% or less,
V; 1.0% or less,
Zr; An austenite-ferritic two-phase steel wire which is excellent in cold forging property containing 1 or more types in 1.0% or less. 3. The composition according to claim 1, wherein, in mass%
Mo; 1.0% or less,
B; It contains one or both in 0.01% or less,
Nb; 1.0% or less,
Ti; 0.5% or less,
V; 1.0% or less,
Zr; An austenite-ferritic two-phase steel wire which is excellent in cold forging property which further contains 1 or more types in 1.0% or less. 3. The composition according to claim 1, wherein, in mass%
Al; 0.1% or less,
Mg; 0.01% or less,
Ca; It contains 1 or more types in 0.01% or less,
Nb; 1.0% or less,
Ti; 0.5% or less,
V; 1.0% or less,
Zr; An austenite-ferritic two-phase steel wire which is excellent in cold forging property which further contains 1 or more types in 1.0% or less. 3. The composition according to claim 1, wherein, in mass%
Mo; 1.0% or less,
B; It contains one or both in 0.01% or less,
Al; 0.1% or less,
Mg; 0.01% or less,
Ca; In 0.01% or less, 1 or more types are further contained,
Nb; 1.0% or less,
Ti; 0.5% or less,
V; 1.0% or less,
Zr; An austenite-ferritic two-phase steel wire which is excellent in cold forging property which further contains 1 or more types in 1.0% or less. An austenite-ferritic two-phase steel wire having the chemical composition according to any one of claims 1 to 8 and having excellent cold forging property, having a tensile strength of 700 to 1000 N / mm 2. The high strength, high corrosion resistance bolt which has a chemical composition as described in any one of Claims 1-8, and whose tensile strength is 700-1200 N / mm <2>. An austenitic ferritic two-phase steel wire having the chemical composition according to any one of claims 1 to 8 and having a tensile strength of 700 to 1000 N / mm 2 at 300 to 600 ° C. after cold bolt forming for 1 to 100 minutes. A method for producing a high strength, high corrosion resistant bolt that undergoes aging heat treatment. In mass%,
C; 0.005 to 0.05%,
Si; 0.1 to 1.0%,
Mn; 0.1 to 10.0%,
Ni; 3.5 to 6.0%,
Cr; 19.0 to 30.0%,
Cu: 0.05 to 3.0%,
N; 0.005% or more and less than 0.06%, the remainder being composed of Fe and substantially unavoidable impurities, and C + N; The soft two-phase stainless steel wire material which has the magnetism excellent in cold workability which is 0.09% or less, M value of (a) formula is 60 or less, tensile strength is 700 N / mm <2> or less, and tensile fracture drawing is 70% or more.

M = 551-462 (C + N) -9.2Si-8.1Mn-29 (Ni + Cu) -13.7Cr-18.5Mo... (a) The method according to claim 12, in mass%,
Mo; 3.0% or less,
B; The soft 2-phase stainless steel wire material which has the magnetism excellent in cold workability containing one or both in 0.01% or less. The method according to claim 12, in mass%,
Al; 0.1% or less,
Mg; 0.01% or less,
Ca; The soft 2-phase stainless steel wire material which has the magnetism excellent in cold workability containing one or more types in 0.01% or less. The method according to claim 12, in mass%,
Mo; 3.0% or less,
B; It contains one or both in 0.01% or less,
Al; 0.1% or less,
Mg; 0.01% or less,
Ca; The soft 2-phase stainless steel wire material which has the magnetism excellent in cold workability further containing 1 or more types in 0.01% or less. The method according to claim 12, in mass%,
Nb; 1.0% or less,
Ti; 0.5% or less,
V; 1.0% or less,
Zr; The soft 2-phase stainless steel wire material which has the magnetism excellent in cold workability containing 1 or more types in 1.0% or less. The method according to claim 12, in mass%,
Mo; 3.0% or less,
B; It contains one or both in 0.01% or less,
Nb; 1.0% or less,
Ti; 0.5% or less,
V; 1.0% or less,
Zr; The soft 2-phase stainless steel wire material which has the magnetism excellent in cold workability further containing 1 or more types in 1.0% or less. The method according to claim 12, in mass%,
Al; 0.1% or less,
Mg; 0.01% or less,
Ca; It contains 1 or more types in 0.01% or less,
Nb; 1.0% or less,
Ti; 0.5% or less,
V; 1.0% or less,
Zr; The soft 2-phase stainless steel wire material which has the magnetism excellent in cold workability further containing 1 or more types in 1.0% or less. The method according to claim 12, in mass%,
Mo; 3.0% or less,
B; It contains one or both in 0.01% or less,
Al; 0.1% or less,
Mg; 0.01% or less,
Ca; In 0.01% or less, 1 or more types are further contained,
Nb; 1.0% or less,
Ti; 0.5% or less,
V; 1.0% or less,
Zr; The soft 2-phase stainless steel wire material which has the magnetism excellent in cold workability further containing 1 or more types in 1.0% or less.

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