KR101059401B1 - 1-부텐 중합체 제조 방법 - Google Patents

1-부텐 중합체 제조 방법 Download PDF

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Publication number
KR101059401B1
KR101059401B1 KR1020057010233A KR20057010233A KR101059401B1 KR 101059401 B1 KR101059401 B1 KR 101059401B1 KR 1020057010233 A KR1020057010233 A KR 1020057010233A KR 20057010233 A KR20057010233 A KR 20057010233A KR 101059401 B1 KR101059401 B1 KR 101059401B1
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formula
optionally
alkyl
radical
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Korean (ko)
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KR20050089028A (ko
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루이지 레스코니
인구르지 안토니오 카스치
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바젤 폴리올레핀 게엠베하
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04Monomers containing three or four carbon atoms
    • C08F10/08Butenes
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00Metallocenes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04Monomers containing three or four carbon atoms
    • C08F110/08Butenes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943Polymerization with metallocene catalysts

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Polymerization Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
KR1020057010233A 2002-12-04 2003-11-03 1-부텐 중합체 제조 방법 Expired - Lifetime KR101059401B1 (ko)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
EP02080120 2002-12-04
EP02080120.5 2002-12-04
US43180302P 2002-12-09 2002-12-09
US60/431,803 2002-12-09
PCT/EP2003/012236 WO2004050724A1 (en) 2002-12-04 2003-11-03 Process for preparing 1-butene polymers

Publications (2)

Publication Number Publication Date
KR20050089028A KR20050089028A (ko) 2005-09-07
KR101059401B1 true KR101059401B1 (ko) 2011-08-29

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KR1020057010233A Expired - Lifetime KR101059401B1 (ko) 2002-12-04 2003-11-03 1-부텐 중합체 제조 방법

Country Status (7)

Country Link
EP (1) EP1567565B1 (https=)
JP (1) JP4758650B2 (https=)
KR (1) KR101059401B1 (https=)
AT (1) ATE383379T1 (https=)
AU (1) AU2003276242A1 (https=)
DE (1) DE60318616T2 (https=)
WO (1) WO2004050724A1 (https=)

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US7459511B2 (en) 2001-06-12 2008-12-02 Basell Polyolefine Gmbh Process for the polymerization of 1-butene
JP2006502260A (ja) 2002-10-10 2006-01-19 バセル ポリオレフィン ジーエムビーエイチ エチレンの共重合方法
US7589160B2 (en) 2002-12-04 2009-09-15 Basell Polyolefine Gmbh Process for preparing 1-butene polymers
DE60329523D1 (de) 2002-12-04 2009-11-12 Basell Polyolefine Gmbh 1-Buten-Copolymere und Herstellungsverfahren dafür
DE10358082A1 (de) * 2003-12-10 2005-07-14 Basell Polyolefine Gmbh Organübergangsmetallverbindung, Bscyclopentadienyligandsystem, Katalysatorsystem und Hertellung von Polyolefinen
ATE445650T1 (de) 2004-05-04 2009-10-15 Basell Polyolefine Gmbh Verfahren zur herstellung von ataktischen 1- butenpolymeren
KR20070039930A (ko) 2004-07-08 2007-04-13 엑손모빌 케미칼 패턴츠 인코포레이티드 초임계 조건에서 중합체의 제조방법
RU2410388C2 (ru) * 2005-03-18 2011-01-27 Базелль Полиолефине Гмбх Металлоценовые соединения
US7803887B2 (en) 2005-03-18 2010-09-28 Basell Polyolefine Gmbh Metallocene compounds
US7799880B2 (en) 2005-03-23 2010-09-21 Basell Polyolefine Gmbh Process for the polymerization of olefins
CN101146836B (zh) 2005-03-23 2011-06-08 巴塞尔聚烯烃股份有限公司 烯烃聚合方法
WO2006117285A1 (en) 2005-05-03 2006-11-09 Basell Polyolefine Gmbh Process for the polymerization of alpha olefins
ATE515533T1 (de) 2005-05-11 2011-07-15 Basell Poliolefine Srl Polymerisationsverfahren zur herstellung von polyolefinblends
WO2007107448A1 (en) 2006-03-17 2007-09-27 Basell Polyolefine Gmbh Metallocene compounds
US7834205B2 (en) 2006-04-12 2010-11-16 Basell Polyolifine GmbH Metallocene compounds
US8785575B2 (en) * 2006-04-21 2014-07-22 Basell Polyolefine Gmbh Process for the preparation of ethylene propylene copolymers
EP2010580B1 (en) * 2006-04-21 2016-07-13 Basell Polyolefine GmbH Process for the preparation of ethylene copolymers
WO2011061151A1 (en) 2009-11-17 2011-05-26 Basell Polyolefine Gmbh Ethylene copolymers
EP2402353B1 (en) * 2010-07-01 2018-04-25 Borealis AG Group 4 metallocenes useful as catalysts for the polymerization of olefins
ES2565438T3 (es) 2010-07-01 2016-04-04 Borealis Ag Proceso para la polimerización de olefinas usando metalocenos del grupo 4 como catalizadores
JP5966321B2 (ja) * 2010-11-19 2016-08-10 日本ポリプロ株式会社 メタロセン錯体およびオレフィンの重合方法
WO2012134721A2 (en) * 2011-03-25 2012-10-04 Exxonmobil Chemical Patents Inc. Vinyl terminated higher olefin polymers and methods to produce thereof
JP5880000B2 (ja) * 2011-12-14 2016-03-08 日本ポリプロ株式会社 メタロセン錯体およびオレフィンの重合方法
JP5980339B2 (ja) 2012-09-25 2016-08-31 三井化学株式会社 オレフィン重合体の製造方法およびオレフィン重合体
EP2722344B1 (en) 2012-10-18 2017-03-22 Borealis AG Polymerisation process
ES2711081T3 (es) 2012-10-18 2019-04-30 Borealis Ag Catalizador para la polimerización de olefinas
EP2722346A1 (en) 2012-10-18 2014-04-23 Borealis AG Polymerisation process and catalyst
JP6264808B2 (ja) * 2013-09-26 2018-01-24 日本ポリプロ株式会社 メタロセン化合物及びそれを使用する重合触媒によるオレフィン重合体の製造方法
EP3192817B1 (en) 2014-09-11 2020-12-23 Mitsui Chemicals, Inc. Method for producing olefin (co)polymer containing constituent unit derived from 1-butene
JP6921563B2 (ja) * 2017-03-07 2021-08-18 出光興産株式会社 遷移金属化合物及びオレフィン系重合体の製造方法
WO2022210844A1 (ja) 2021-03-31 2022-10-06 三井化学株式会社 エチレン-α-オレフィン共重合体、熱可塑性樹脂組成物、およびフィルム
JP7660662B2 (ja) 2021-03-31 2025-04-11 三井化学株式会社 エチレン系樹脂組成物および成形体
WO2022210843A1 (ja) 2021-03-31 2022-10-06 三井化学株式会社 エチレン-α-オレフィン共重合体、熱可塑性樹脂組成物、フィルムおよび積層体

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DE59206948D1 (de) * 1991-11-30 1996-09-26 Hoechst Ag Metallocene mit benzokondensierten Indenylderivaten als Liganden, Verfahren zu ihrer Herstellung und ihre Verwendung als Katalysatoren
JP3394578B2 (ja) * 1993-12-28 2003-04-07 三井化学株式会社 予備重合触媒、オレフィン重合用触媒およびオレフィンの重合方法
JP3337905B2 (ja) * 1995-04-24 2002-10-28 三井化学株式会社 キラルな新規メタロセン化合物とその合成方法及びそれを用いたオレフィンの重合方法
JPH10298219A (ja) * 1997-04-30 1998-11-10 Mitsui Chem Inc 新規な遷移金属化合物および該遷移金属化合物からなるオレフィン重合用触媒成分
ES2182494T3 (es) * 1998-03-11 2003-03-01 Dow Chemical Co Procedimiento integrado para la preparacion de complejos de dienos.
JPH11286519A (ja) * 1998-04-02 1999-10-19 Mitsui Chem Inc オレフィンの重合方法
US6479424B1 (en) * 1998-12-14 2002-11-12 Bp Corporation North America Inc. Fluxional catalysts and related ligands containing bulky substituents
JP2001081124A (ja) * 1999-09-17 2001-03-27 Sumitomo Chem Co Ltd 付加重合用触媒、およびオレフィン重合体の製造方法
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US7459511B2 (en) * 2001-06-12 2008-12-02 Basell Polyolefine Gmbh Process for the polymerization of 1-butene

Also Published As

Publication number Publication date
AU2003276242A1 (en) 2004-06-23
ATE383379T1 (de) 2008-01-15
JP2006509059A (ja) 2006-03-16
KR20050089028A (ko) 2005-09-07
WO2004050724A1 (en) 2004-06-17
DE60318616T2 (de) 2009-01-08
EP1567565B1 (en) 2008-01-09
EP1567565A1 (en) 2005-08-31
JP4758650B2 (ja) 2011-08-31
DE60318616D1 (de) 2008-02-21

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