KR100904297B1 - 연속적인 2단계 촉매 반응을 이용한 합성가스로부터 경질올레핀의 제조방법 - Google Patents

연속적인 2단계 촉매 반응을 이용한 합성가스로부터 경질올레핀의 제조방법 Download PDF

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KR100904297B1
KR100904297B1 KR1020070108494A KR20070108494A KR100904297B1 KR 100904297 B1 KR100904297 B1 KR 100904297B1 KR 1020070108494 A KR1020070108494 A KR 1020070108494A KR 20070108494 A KR20070108494 A KR 20070108494A KR 100904297 B1 KR100904297 B1 KR 100904297B1
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catalyst
reaction
range
selectivity
olefin
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KR20090042630A (ko
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전기원
이윤조
박조용
배종욱
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한국화학연구원
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Priority to KR1020070108494A priority Critical patent/KR100904297B1/ko
Priority to PCT/KR2008/005606 priority patent/WO2009054616A2/en
Priority to CN200880113431.1A priority patent/CN101868434B/zh
Priority to JP2010530920A priority patent/JP5518727B2/ja
Priority to EP08842028.6A priority patent/EP2215038B1/en
Priority to US12/739,217 priority patent/US8395004B2/en
Publication of KR20090042630A publication Critical patent/KR20090042630A/ko
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/02—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
    • C07C1/04—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen
    • C07C1/0425—Catalysts; their physical properties
    • C07C1/043—Catalysts; their physical properties characterised by the composition
    • C07C1/0435—Catalysts; their physical properties characterised by the composition containing a metal of group 8 or a compound thereof
    • C07C1/044—Catalysts; their physical properties characterised by the composition containing a metal of group 8 or a compound thereof containing iron
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C9/00—Aliphatic saturated hydrocarbons
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    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002—Mixed oxides other than spinels, e.g. perovskite
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    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/745—Iron
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    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/78—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with alkali- or alkaline earth metals
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    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/80—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with zinc, cadmium or mercury
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    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
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    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/889—Manganese, technetium or rhenium
    • B01J23/8892—Manganese
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    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
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    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B01J29/405—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively containing rare earth elements, titanium, zirconium, hafnium, zinc, cadmium, mercury, gallium, indium, thallium, tin or lead
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    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/03—Precipitation; Co-precipitation
    • B01J37/031—Precipitation
    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
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    • C—CHEMISTRY; METALLURGY
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    • C07C4/00—Preparation of hydrocarbons from hydrocarbons containing a larger number of carbon atoms
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C7/00—Purification; Separation; Use of additives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
    • C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
    • C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
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    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
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    • C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
    • C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
    • C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
    • C10G2/33—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used
    • C10G2/331—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals
    • C10G2/332—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals of the iron-group
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    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/18—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself
    • B01J2229/186—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself not in framework positions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/20—C2-C4 olefins
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Water Supply & Treatment (AREA)
  • Analytical Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
KR1020070108494A 2007-10-26 2007-10-26 연속적인 2단계 촉매 반응을 이용한 합성가스로부터 경질올레핀의 제조방법 Expired - Fee Related KR100904297B1 (ko)

Priority Applications (6)

Application Number Priority Date Filing Date Title
KR1020070108494A KR100904297B1 (ko) 2007-10-26 2007-10-26 연속적인 2단계 촉매 반응을 이용한 합성가스로부터 경질올레핀의 제조방법
PCT/KR2008/005606 WO2009054616A2 (en) 2007-10-26 2008-09-22 Process for producing light olefins from synthesis gas using dual sequential bed reactor
CN200880113431.1A CN101868434B (zh) 2007-10-26 2008-09-22 使用双顺序床反应器由合成气生产轻烯烃的方法
JP2010530920A JP5518727B2 (ja) 2007-10-26 2008-09-22 連続的な２段階反応を利用した合成ガスからの軽質オレフィンの製造方法
EP08842028.6A EP2215038B1 (en) 2007-10-26 2008-09-22 Process for producing light olefins from synthesis gas using dual sequential bed reactor
US12/739,217 US8395004B2 (en) 2007-10-26 2008-09-22 Process for producing light olefins from synthesis gas using dual sequential bed reactor

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
KR1020070108494A KR100904297B1 (ko) 2007-10-26 2007-10-26 연속적인 2단계 촉매 반응을 이용한 합성가스로부터 경질올레핀의 제조방법

Publications (2)

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KR20090042630A KR20090042630A (ko) 2009-04-30
KR100904297B1 true KR100904297B1 (ko) 2009-06-25

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US (1) US8395004B2 (https=)
EP (1) EP2215038B1 (https=)
JP (1) JP5518727B2 (https=)
KR (1) KR100904297B1 (https=)
CN (1) CN101868434B (https=)
WO (1) WO2009054616A2 (https=)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20230020118A (ko) * 2021-08-03 2023-02-10 포항공과대학교 산학협력단 Pst-32 및 pst-2 제올라이트 촉매를 이용한 탄화수소 전환방법

Families Citing this family (10)

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Publication number Priority date Publication date Assignee Title
KR20110026709A (ko) * 2009-09-08 2011-03-16 한국화학연구원 올레핀 크레킹 반응용 제올라이트계 성형촉매 및 합성가스로부터 경질 올레핀의 제조방법
CA2795553C (en) * 2010-05-10 2019-09-24 Casale Sa Process for the production of light olefins from synthesis gas
CN103270005B (zh) * 2010-12-21 2016-01-06 陶氏环球技术有限责任公司 增强的合成气向丙烯的转化
CN102442872A (zh) * 2011-11-10 2012-05-09 北京化工大学 一种合成气直接合成低碳烯烃的方法
CN105143157B (zh) * 2013-04-24 2018-11-13 沙特基础工业公司 从天然资源产生产物
WO2014174107A1 (en) * 2013-04-26 2014-10-30 Bp P.L.C. Production of hydrocarbons from synthesis gas
US10329209B2 (en) * 2015-10-30 2019-06-25 Dow Global Technologies, Llc Process to convert synthesis gas to olefins over a bifunctional chromium oxide/zinc oxide-SAPO-34 catalyst
JP7492232B2 (ja) * 2020-08-07 2024-05-29 三菱ケミカル株式会社 低級オレフィン製造用の触媒、及び低級オレフィンの製造方法
KR102828271B1 (ko) * 2022-09-16 2025-07-04 한국화학연구원 메탄의 비산화 직접전환 반응기 및 이를 이용한 c2 탄화수소 화합물 및 방향족 화합물의 제조방법
KR20250055823A (ko) * 2023-10-18 2025-04-25 한국화학연구원 폐플라스틱으로부터 경질올레핀을 제조하는 방법

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5371308A (en) 1992-08-25 1994-12-06 Shell Oil Company Process for the preparation of lower olefins
WO2006070006A2 (en) 2004-12-30 2006-07-06 Shell Internationale Research Maatschappij B.V. Process for the preparation of lower olefins from heavy wax
KR100632571B1 (ko) 2005-10-07 2006-10-09 에스케이 주식회사 탄화수소 원료 혼합물로부터 접촉분해공정을 통해서 경질올레핀계 탄화수소 화합물을 증산하는 방법

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WO2009054616A2 (en) 2009-04-30
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