KR100885310B1 - 피셔-트롭쉬 합성용 코발트／인―알루미나 촉매와 이의제조방법 - Google Patents

피셔-트롭쉬 합성용 코발트／인―알루미나 촉매와 이의제조방법 Download PDF

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KR100885310B1
KR100885310B1 KR1020070075065A KR20070075065A KR100885310B1 KR 100885310 B1 KR100885310 B1 KR 100885310B1 KR 1020070075065 A KR1020070075065 A KR 1020070075065A KR 20070075065 A KR20070075065 A KR 20070075065A KR 100885310 B1 KR100885310 B1 KR 100885310B1
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phosphorus
alumina
cobalt
catalyst
reaction
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Korean (ko)
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KR20090011457A (ko
Inventor
전기원
배종욱
이윤조
김승문
Original Assignee
한국화학연구원
대림산업 주식회사
두산메카텍 주식회사
한국석유공사
현대엔지니어링 주식회사
에스케이에너지 주식회사
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Priority to KR1020070075065A priority Critical patent/KR100885310B1/ko
Priority to CN2008800122143A priority patent/CN101842156B/zh
Priority to PCT/KR2008/000549 priority patent/WO2009014292A2/en
Priority to US12/594,617 priority patent/US8084387B2/en
Priority to EP08705005.0A priority patent/EP2173481B1/en
Priority to JP2010506028A priority patent/JP5174890B2/ja
Publication of KR20090011457A publication Critical patent/KR20090011457A/ko
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/75—Cobalt
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
    • B01J21/04—Alumina
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/185—Phosphorus; Compounds thereof with iron group metals or platinum group metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/615—100-500 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/617—500-1000 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/66—Pore distribution
    • B01J35/69—Pore distribution bimodal
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0207—Pretreatment of the support
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/03—Precipitation; Co-precipitation
    • B01J37/031—Precipitation
    • B01J37/033—Using Hydrolysis
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/16—Phosphorus; Compounds thereof containing oxygen, i.e. acids, anhydrides and their derivates with N, S, B or halogens without carriers or on carriers based on C, Si, Al or Zr; also salts of Si, Al and Zr
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/185—Phosphorus; Compounds thereof with iron group metals or platinum group metals
    • B01J27/1853—Phosphorus; Compounds thereof with iron group metals or platinum group metals with iron, cobalt or nickel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/16—Reducing
    • B01J37/18—Reducing with gases containing free hydrogen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/28—Phosphorising

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
KR1020070075065A 2007-07-26 2007-07-26 피셔-트롭쉬 합성용 코발트／인―알루미나 촉매와 이의제조방법 Active KR100885310B1 (ko)

Priority Applications (6)

Application Number Priority Date Filing Date Title
KR1020070075065A KR100885310B1 (ko) 2007-07-26 2007-07-26 피셔-트롭쉬 합성용 코발트／인―알루미나 촉매와 이의제조방법
CN2008800122143A CN101842156B (zh) 2007-07-26 2008-01-30 用于在钴/磷-氧化铝上费-托合成的催化剂及其制备方法
PCT/KR2008/000549 WO2009014292A2 (en) 2007-07-26 2008-01-30 Catalysts for fischer-tropsch synthesis on cobalt/phosphorus-aluminum oxide and preparation methods thereof
US12/594,617 US8084387B2 (en) 2007-07-26 2008-01-30 Catalysts for fischer-tropsch synthesis on cobalt/phosphorus-aluminum oxide and preparation methods thereof
EP08705005.0A EP2173481B1 (en) 2007-07-26 2008-01-30 Cobalt/phosphorus-aluminum oxide catalysts, preparation methods thereof and use in fischer-tropsch synthesis
JP2010506028A JP5174890B2 (ja) 2007-07-26 2008-01-30 フィッシャー・トロプシュ合成用コバルト／リン−アルミナ触媒及びその製造方法

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
KR1020070075065A KR100885310B1 (ko) 2007-07-26 2007-07-26 피셔-트롭쉬 합성용 코발트／인―알루미나 촉매와 이의제조방법

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KR20090011457A KR20090011457A (ko) 2009-02-02
KR100885310B1 true KR100885310B1 (ko) 2009-02-24

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Country Status (6)

Country Link
US (1) US8084387B2 (enExample)
EP (1) EP2173481B1 (enExample)
JP (1) JP5174890B2 (enExample)
KR (1) KR100885310B1 (enExample)
CN (1) CN101842156B (enExample)
WO (1) WO2009014292A2 (enExample)

Cited By (1)

* Cited by examiner, † Cited by third party
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KR101284161B1 (ko) 2011-05-26 2013-07-10 한국화학연구원 피셔-트롭쉬 반응용 촉매의 제조방법

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KR100885311B1 (ko) 2007-09-04 2009-02-24 한국화학연구원 피셔-트롭쉬 합성용 코발트/인-알루미나 촉매와 이의 제조방법
CN103418388B (zh) * 2012-05-24 2015-09-23 中国石油化工股份有限公司 一种费托合成催化剂及其制备和应用
KR101412518B1 (ko) * 2012-08-29 2014-06-26 한국과학기술연구원 합성가스를 이용한 액체 탄화수소 제조용 촉매, 및 이의 제조 방법
KR101298783B1 (ko) 2012-12-14 2013-08-26 한국가스공사 피셔-트롭쉬 촉매의 제조방법
CN103073036B (zh) * 2012-12-25 2014-09-10 太原理工大学 超微孔高比表面积氧化铝材料及其制备方法
US9358526B2 (en) 2013-11-19 2016-06-07 Emerging Fuels Technology, Inc. Optimized fischer-tropsch catalyst
US9180436B1 (en) 2013-11-19 2015-11-10 Emerging Fuels Technology, Inc. Optimized fischer-tropsch catalyst
FR3018810B1 (fr) * 2014-03-20 2017-06-09 Ifp Energies Now Procede fischer-tropsch utilisant un catalyseur a base d'un metal du groupe viiib et d'un support d'oxydes comprenant de l'alumine, de la silice et du phosphore
FR3018702B1 (fr) 2014-03-20 2017-10-20 Ifp Energies Now Catalyseur fischer-tropsch a base d'un metal du groupe viiib et d'un support d'oxydes comprenant de l'alumine, de la silice, une spinelle et du phosphore
FR3028770B1 (fr) * 2014-11-26 2016-12-02 Ifp Energies Now Procede de preparation d'un catalyseur fischer-tropsch avec traitement a la vapeur
JP6824168B2 (ja) * 2014-12-19 2021-02-03 シエル・インターナシヨネイル・リサーチ・マーチヤツピイ・ベー・ウイＳｈｅｌｌ Ｉｎｔｅｒｎａｔｉｏｎａｌｅ Ｒｅｓｅａｒｃｈ Ｍａａｔｓｃｈａｐｐｉｊ Ｂｅｓｌｏｔｅｎ Ｖｅｎｎｏｏｔｓｈａｐ 触媒の調製方法
KR101829917B1 (ko) * 2015-07-14 2018-02-20 성균관대학교산학협력단 피셔-트롭쉬 합성 반응용 메조 기공 구조의 주골격을 갖는 코발트계 촉매 및 이의 제조방법
FR3041270A1 (fr) * 2015-09-17 2017-03-24 Ifp Energies Now Catalyseur fischer-tropsch a base d'un metal du groupe viiib, de bore et d'un support contenant du phosphore introduit sous forme d'un sel
WO2017175638A1 (ja) * 2016-04-04 2017-10-12 花王株式会社 アルコールの製造方法
WO2018162363A1 (en) * 2017-03-06 2018-09-13 Studiengesellschaft Kohle Mbh Serial process for converting syngas to liquid hydrocarbons, device used therefor including ft- and ht-catalysts, ft-catalyst
KR101982773B1 (ko) * 2017-05-18 2019-05-27 한국화학연구원 내열성이 개선된 메탄 개질 반응용 모노리스 촉매 및 이의 제조방법
KR101933014B1 (ko) * 2017-05-18 2018-12-27 한국화학연구원 이산화탄소를 이용한 메탄 개질 반응용 촉매 및 이의 제조방법
CN108187708B (zh) * 2018-02-01 2021-05-04 中科合成油内蒙古有限公司 一种含磷高稳定性重质烃费托合成催化剂及其制备方法和应用
CN110252358B (zh) * 2018-03-12 2022-03-22 国家能源投资集团有限责任公司 费托合成钴催化剂及其制备方法以及费托合成的方法
FR3093653B1 (fr) 2019-03-15 2021-12-24 Ifp Energies Now Procede de preparation d’un support de catalyseur
FR3102069B1 (fr) 2019-10-22 2021-12-31 Ifp Energies Now Procede de preparation d’un support de catalyseur
EP4157484A1 (en) 2020-05-29 2023-04-05 Climeworks AG Method for capture of carbon dioxide from ambient air and corresponding adsorber structures with a plurality of parallel surfaces
CN114950573B (zh) * 2021-02-24 2024-09-06 中国石油天然气股份有限公司 大孔氧化铝载体及其制备方法
AU2023325524A1 (en) 2022-08-15 2025-03-13 W. L. Gore & Associates, Inc. Structures and methods for enhancing capture of carbon dioxide from ambient air
CN119793494B (zh) * 2025-01-06 2025-10-14 山西大学 一种用于硝酸生产尾气中n2o催化分解的钴基-多孔铝催化剂及其制备方法和应用

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Publication number Priority date Publication date Assignee Title
KR101284161B1 (ko) 2011-05-26 2013-07-10 한국화학연구원 피셔-트롭쉬 반응용 촉매의 제조방법

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EP2173481A4 (en) 2011-06-29
EP2173481A2 (en) 2010-04-14
CN101842156A (zh) 2010-09-22
JP2010524681A (ja) 2010-07-22
EP2173481B1 (en) 2016-03-23
KR20090011457A (ko) 2009-02-02
US20100093523A1 (en) 2010-04-15
WO2009014292A2 (en) 2009-01-29
US8084387B2 (en) 2011-12-27
JP5174890B2 (ja) 2013-04-03
CN101842156B (zh) 2013-01-30
WO2009014292A3 (en) 2009-03-26

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