KR100853366B1 - 올레핀 중합체의 제조방법 및 이를 위해 선택된 촉매 - Google Patents
올레핀 중합체의 제조방법 및 이를 위해 선택된 촉매 Download PDFInfo
- Publication number
- KR100853366B1 KR100853366B1 KR1020037014525A KR20037014525A KR100853366B1 KR 100853366 B1 KR100853366 B1 KR 100853366B1 KR 1020037014525 A KR1020037014525 A KR 1020037014525A KR 20037014525 A KR20037014525 A KR 20037014525A KR 100853366 B1 KR100853366 B1 KR 100853366B1
- Authority
- KR
- South Korea
- Prior art keywords
- hydrocarbon
- iii
- mixed catalyst
- mixture
- catalyst
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000003054 catalyst Substances 0.000 title claims abstract description 68
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 10
- 229920000098 polyolefin Polymers 0.000 title description 10
- 239000010936 titanium Substances 0.000 claims abstract description 54
- 229930195733 hydrocarbon Natural products 0.000 claims abstract description 49
- 150000002430 hydrocarbons Chemical class 0.000 claims abstract description 49
- -1 magnesium alkoxide Chemical class 0.000 claims abstract description 32
- 239000004215 Carbon black (E152) Substances 0.000 claims abstract description 30
- 239000000203 mixture Substances 0.000 claims abstract description 28
- 238000000034 method Methods 0.000 claims abstract description 27
- 238000006116 polymerization reaction Methods 0.000 claims abstract description 25
- 150000001336 alkenes Chemical class 0.000 claims abstract description 15
- 230000008569 process Effects 0.000 claims abstract description 14
- 239000011777 magnesium Substances 0.000 claims abstract description 12
- 229910052749 magnesium Inorganic materials 0.000 claims abstract description 11
- 229910052719 titanium Inorganic materials 0.000 claims abstract description 11
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims abstract description 10
- 238000006243 chemical reaction Methods 0.000 claims abstract description 10
- 239000000126 substance Substances 0.000 claims abstract description 10
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229920001577 copolymer Polymers 0.000 claims abstract description 6
- 230000003647 oxidation Effects 0.000 claims abstract description 6
- 238000007254 oxidation reaction Methods 0.000 claims abstract description 6
- 229920001519 homopolymer Polymers 0.000 claims abstract description 5
- 150000001875 compounds Chemical class 0.000 claims description 38
- 239000000463 material Substances 0.000 claims description 11
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 10
- 239000005977 Ethylene Substances 0.000 claims description 10
- VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 claims description 9
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 claims description 7
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 7
- 239000001301 oxygen Substances 0.000 claims description 7
- 229910052760 oxygen Inorganic materials 0.000 claims description 7
- MCULRUJILOGHCJ-UHFFFAOYSA-N triisobutylaluminium Chemical compound CC(C)C[Al](CC(C)C)CC(C)C MCULRUJILOGHCJ-UHFFFAOYSA-N 0.000 claims description 7
- 229920000831 ionic polymer Polymers 0.000 claims description 4
- 239000000178 monomer Substances 0.000 claims description 4
- 229920002492 poly(sulfone) Polymers 0.000 claims description 4
- 229920000768 polyamine Polymers 0.000 claims description 4
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims description 4
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 4
- VSYZXASVWVQEMR-UHFFFAOYSA-N 2-methylbuta-1,3-dienylalumane Chemical compound CC(=C[AlH2])C=C VSYZXASVWVQEMR-UHFFFAOYSA-N 0.000 claims description 3
- YNLAOSYQHBDIKW-UHFFFAOYSA-M diethylaluminium chloride Chemical compound CC[Al](Cl)CC YNLAOSYQHBDIKW-UHFFFAOYSA-M 0.000 claims description 3
- 150000002681 magnesium compounds Chemical class 0.000 claims description 3
- 239000003607 modifier Substances 0.000 claims description 3
- ORYGRKHDLWYTKX-UHFFFAOYSA-N trihexylalumane Chemical compound CCCCCC[Al](CCCCCC)CCCCCC ORYGRKHDLWYTKX-UHFFFAOYSA-N 0.000 claims description 3
- JLTRXTDYQLMHGR-UHFFFAOYSA-N trimethylaluminium Chemical compound C[Al](C)C JLTRXTDYQLMHGR-UHFFFAOYSA-N 0.000 claims description 3
- CMAOLVNGLTWICC-UHFFFAOYSA-N 2-fluoro-5-methylbenzonitrile Chemical compound CC1=CC=C(F)C(C#N)=C1 CMAOLVNGLTWICC-UHFFFAOYSA-N 0.000 claims description 2
- HQMRIBYCTLBDAK-UHFFFAOYSA-M bis(2-methylpropyl)alumanylium;chloride Chemical compound CC(C)C[Al](Cl)CC(C)C HQMRIBYCTLBDAK-UHFFFAOYSA-M 0.000 claims description 2
- SIPUZPBQZHNSDW-UHFFFAOYSA-N bis(2-methylpropyl)aluminum Chemical compound CC(C)C[Al]CC(C)C SIPUZPBQZHNSDW-UHFFFAOYSA-N 0.000 claims description 2
- PPQUYYAZSOKTQD-UHFFFAOYSA-M diethylalumanylium;iodide Chemical compound CC[Al](I)CC PPQUYYAZSOKTQD-UHFFFAOYSA-M 0.000 claims description 2
- GCPCLEKQVMKXJM-UHFFFAOYSA-N ethoxy(diethyl)alumane Chemical compound CCO[Al](CC)CC GCPCLEKQVMKXJM-UHFFFAOYSA-N 0.000 claims description 2
- UAIZDWNSWGTKFZ-UHFFFAOYSA-L ethylaluminum(2+);dichloride Chemical compound CC[Al](Cl)Cl UAIZDWNSWGTKFZ-UHFFFAOYSA-L 0.000 claims description 2
- 239000012442 inert solvent Substances 0.000 claims description 2
- SQBBHCOIQXKPHL-UHFFFAOYSA-N tributylalumane Chemical compound CCCC[Al](CCCC)CCCC SQBBHCOIQXKPHL-UHFFFAOYSA-N 0.000 claims description 2
- LFXVBWRMVZPLFK-UHFFFAOYSA-N trioctylalumane Chemical compound CCCCCCCC[Al](CCCCCCCC)CCCCCCCC LFXVBWRMVZPLFK-UHFFFAOYSA-N 0.000 claims description 2
- CNWZYDSEVLFSMS-UHFFFAOYSA-N tripropylalumane Chemical compound CCC[Al](CCC)CCC CNWZYDSEVLFSMS-UHFFFAOYSA-N 0.000 claims 2
- 230000004913 activation Effects 0.000 claims 1
- 125000003158 alcohol group Chemical group 0.000 claims 1
- HRLHOWWCFUKTIY-UHFFFAOYSA-L dichloroalumanylium Chemical compound Cl[Al+]Cl HRLHOWWCFUKTIY-UHFFFAOYSA-L 0.000 claims 1
- JGHYBJVUQGTEEB-UHFFFAOYSA-M dimethylalumanylium;chloride Chemical compound C[Al](C)Cl JGHYBJVUQGTEEB-UHFFFAOYSA-M 0.000 claims 1
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 claims 1
- SOQBVABWOPYFQZ-UHFFFAOYSA-N oxygen(2-);titanium(4+) Chemical class [O-2].[O-2].[Ti+4] SOQBVABWOPYFQZ-UHFFFAOYSA-N 0.000 claims 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims 1
- 239000004698 Polyethylene Substances 0.000 abstract description 15
- 230000015572 biosynthetic process Effects 0.000 abstract description 12
- 229920000573 polyethylene Polymers 0.000 abstract description 6
- 229910052782 aluminium Inorganic materials 0.000 abstract description 3
- 229920000642 polymer Polymers 0.000 description 25
- 239000002612 dispersion medium Substances 0.000 description 19
- 238000002474 experimental method Methods 0.000 description 17
- 230000000694 effects Effects 0.000 description 13
- 239000002245 particle Substances 0.000 description 9
- 239000000654 additive Substances 0.000 description 8
- 230000003197 catalytic effect Effects 0.000 description 7
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 6
- 239000007787 solid Substances 0.000 description 6
- 230000002411 adverse Effects 0.000 description 5
- 238000002360 preparation method Methods 0.000 description 5
- 239000000725 suspension Substances 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- YWAKXRMUMFPDSH-UHFFFAOYSA-N pentene Chemical compound CCCC=C YWAKXRMUMFPDSH-UHFFFAOYSA-N 0.000 description 4
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 230000000996 additive effect Effects 0.000 description 3
- 238000009835 boiling Methods 0.000 description 3
- 125000004432 carbon atom Chemical group C* 0.000 description 3
- 238000004821 distillation Methods 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- 238000001179 sorption measurement Methods 0.000 description 3
- 239000006228 supernatant Substances 0.000 description 3
- 238000012546 transfer Methods 0.000 description 3
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 2
- RVDLHGSZWAELAU-UHFFFAOYSA-N 5-tert-butylthiophene-2-carbonyl chloride Chemical compound CC(C)(C)C1=CC=C(C(Cl)=O)S1 RVDLHGSZWAELAU-UHFFFAOYSA-N 0.000 description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 230000009471 action Effects 0.000 description 2
- 239000004480 active ingredient Substances 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- 125000001931 aliphatic group Chemical group 0.000 description 2
- 239000003146 anticoagulant agent Substances 0.000 description 2
- 229940127219 anticoagulant drug Drugs 0.000 description 2
- 239000006227 byproduct Substances 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 150000001735 carboxylic acids Chemical class 0.000 description 2
- 239000000460 chlorine Substances 0.000 description 2
- 229910052801 chlorine Inorganic materials 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 230000009881 electrostatic interaction Effects 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 238000002347 injection Methods 0.000 description 2
- 239000007924 injection Substances 0.000 description 2
- 239000002609 medium Substances 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 150000002902 organometallic compounds Chemical class 0.000 description 2
- 230000000737 periodic effect Effects 0.000 description 2
- 239000002244 precipitate Substances 0.000 description 2
- 238000000746 purification Methods 0.000 description 2
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 description 2
- 239000004711 α-olefin Substances 0.000 description 2
- ZMZGFLUUZLELNE-UHFFFAOYSA-N 2,3,5-triiodobenzoic acid Chemical compound OC(=O)C1=CC(I)=CC(I)=C1I ZMZGFLUUZLELNE-UHFFFAOYSA-N 0.000 description 1
- NMVXHZSPDTXJSJ-UHFFFAOYSA-L 2-methylpropylaluminum(2+);dichloride Chemical compound CC(C)C[Al](Cl)Cl NMVXHZSPDTXJSJ-UHFFFAOYSA-L 0.000 description 1
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 1
- 239000004705 High-molecular-weight polyethylene Substances 0.000 description 1
- NHTMVDHEPJAVLT-UHFFFAOYSA-N Isooctane Chemical compound CC(C)CC(C)(C)C NHTMVDHEPJAVLT-UHFFFAOYSA-N 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 239000011954 Ziegler–Natta catalyst Substances 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 238000005054 agglomeration Methods 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 125000002723 alicyclic group Chemical group 0.000 description 1
- 125000005234 alkyl aluminium group Chemical group 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 238000010923 batch production Methods 0.000 description 1
- 239000011324 bead Substances 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
- 229910052794 bromium Inorganic materials 0.000 description 1
- 239000001273 butane Substances 0.000 description 1
- 239000013065 commercial product Substances 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- JVSWJIKNEAIKJW-UHFFFAOYSA-N dimethyl-hexane Natural products CCCCCC(C)C JVSWJIKNEAIKJW-UHFFFAOYSA-N 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 125000005843 halogen group Chemical group 0.000 description 1
- 150000002367 halogens Chemical group 0.000 description 1
- 229920006158 high molecular weight polymer Polymers 0.000 description 1
- 238000000703 high-speed centrifugation Methods 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 230000004941 influx Effects 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000011089 mechanical engineering Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 238000005065 mining Methods 0.000 description 1
- 239000002808 molecular sieve Substances 0.000 description 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
- 239000000615 nonconductor Substances 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000002574 poison Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 229920005638 polyethylene monopolymer Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 238000010517 secondary reaction Methods 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 1
- 239000011949 solid catalyst Substances 0.000 description 1
- 239000011877 solvent mixture Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 150000003460 sulfonic acids Chemical class 0.000 description 1
- 150000003464 sulfur compounds Chemical class 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 150000003623 transition metal compounds Chemical class 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/04—Monomers containing three or four carbon atoms
- C08F110/06—Propene
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE10122111A DE10122111B4 (de) | 2001-05-08 | 2001-05-08 | Verfahren zur Herstellung von Olefinpolymeren, sowie ausgewählte Katalysatoren |
| DE10122111.8 | 2001-05-08 | ||
| PCT/EP2002/005026 WO2002094891A2 (de) | 2001-05-08 | 2002-05-07 | Verfahren zur herstellung von olefinpolymeren sowie ausgewählte katalysatoren |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| KR20030096364A KR20030096364A (ko) | 2003-12-24 |
| KR100853366B1 true KR100853366B1 (ko) | 2008-08-22 |
Family
ID=7683884
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| KR1020037014525A Expired - Lifetime KR100853366B1 (ko) | 2001-05-08 | 2002-05-07 | 올레핀 중합체의 제조방법 및 이를 위해 선택된 촉매 |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US7157532B2 (enExample) |
| EP (1) | EP1401888B1 (enExample) |
| JP (1) | JP2004527633A (enExample) |
| KR (1) | KR100853366B1 (enExample) |
| CN (1) | CN1249101C (enExample) |
| AT (1) | ATE438665T1 (enExample) |
| BR (1) | BR0209542B1 (enExample) |
| CA (1) | CA2446612A1 (enExample) |
| DE (2) | DE10122111B4 (enExample) |
| WO (1) | WO2002094891A2 (enExample) |
Families Citing this family (36)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102006022256A1 (de) * | 2006-05-11 | 2007-11-15 | Basell Polyolefine Gmbh | Verfahren zur Dosierung von Prozessadditiven, insbesondere Antistatika, in Polymerisationsreaktoren |
| EP2062924A1 (en) * | 2007-11-22 | 2009-05-27 | Ineos Europe Limited | Process for polymerising ethylene |
| US10351640B2 (en) * | 2010-04-22 | 2019-07-16 | Fina Technology, Inc. | Formation of Ziegler-Natta catalyst using non-blended components |
| US8993704B2 (en) | 2010-07-06 | 2015-03-31 | Ticona Gmbh | High molecular weight polyethylene fibers and membranes, their production and use |
| WO2012004675A2 (en) * | 2010-07-06 | 2012-01-12 | Ticona Gmbh | Process for producing high molecular weight polyethylene |
| CN102958957B (zh) | 2010-07-06 | 2015-09-02 | 提克纳有限公司 | 产生高分子量聚乙烯的方法 |
| BR112012032539A2 (pt) | 2010-07-06 | 2016-11-22 | Ticona Gmbh | processo para produção de polietileno de alto peso molecular |
| BR112012032832A2 (pt) * | 2010-07-06 | 2016-11-08 | Ticona Gmbh | polietileno de ultra-alto peso molecular, sua produção e uso. |
| US9034999B2 (en) | 2010-07-06 | 2015-05-19 | Ticona Gmbh | Process for producing high molecular weight polyethylene |
| CN106458883A (zh) * | 2014-06-11 | 2017-02-22 | 弗纳技术股份有限公司 | 耐氯聚乙烯化合物和由其制造的制品 |
| JP7014609B2 (ja) | 2015-06-19 | 2022-02-01 | サウジ アラビアン オイル カンパニー | 防汚オリゴマー化触媒系 |
| US11104621B2 (en) | 2016-01-07 | 2021-08-31 | Saudi Arabian Oil Company | Antifouling oligomerization catalyst systems |
| US10295685B2 (en) | 2017-04-06 | 2019-05-21 | Saudi Arabian Oil Company | Generating common image gather using wave-field separation |
| US11016212B2 (en) | 2017-04-11 | 2021-05-25 | Saudi Arabian Oil Company | Compressing seismic wavefields in three-dimensional reverse time migration |
| CN109810398A (zh) * | 2017-11-21 | 2019-05-28 | 中国石油天然气股份有限公司 | 一种超高分子量等规聚丙烯树脂组合物及其制备方法 |
| US11275190B2 (en) | 2018-05-16 | 2022-03-15 | Saudi Arabian Oil Company | Generating diffraction images based on wave equations |
| US11681043B2 (en) * | 2019-09-03 | 2023-06-20 | Saudi Arabian Oil Company | Diffraction imaging using pseudo dip-angle gather |
| CN112812207A (zh) * | 2019-11-18 | 2021-05-18 | 上海立得催化剂有限公司 | 一种复合型双峰聚乙烯催化剂及其制备方法 |
| US11313988B2 (en) | 2019-12-13 | 2022-04-26 | Saudi Arabian Oil Company | Identifying geologic features in a subterranean formation using seismic diffraction imaging |
| US11098140B2 (en) * | 2020-01-03 | 2021-08-24 | Saudi Arabian Oil Company | Production of 1-butene and ultra-high-molecular-weight polyethylene |
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| US4447587A (en) | 1981-06-20 | 1984-05-08 | Hoechst Aktiengesellschaft | Process for the preparation of a polyolefin, and a catalyst for this process |
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| DE7340562U (de) * | 1973-11-13 | 1974-05-22 | Draegerwerk Ag | Atemalkohol-pruefgeraet |
| US4059720A (en) * | 1973-12-11 | 1977-11-22 | Ruhrchemie Aktiengesellschaft | Process for the production of polyethylene having molecular weights above 500,000 |
| DE2361508C3 (de) | 1973-12-11 | 1979-03-29 | Ruhrchemie Ag, 4200 Oberhausen | Verfahren zur Herstellung von Polyäthylen mit einem Molekulargewicht fiber 500 000 |
| US3917466A (en) | 1974-10-29 | 1975-11-04 | Du Pont | Compositions of olefin-sulfur dioxide copolymers and polyamines as antistatic additives for hydrocarbon fuels |
| US4182810A (en) * | 1978-04-21 | 1980-01-08 | Phillips Petroleum Company | Prevention of fouling in polymerization reactors |
| JPS5964604A (ja) * | 1982-10-06 | 1984-04-12 | Sumitomo Chem Co Ltd | ポリオレフインの製造方法 |
| DE3538099A1 (de) | 1985-10-26 | 1987-04-30 | Ruhrchemie Ag | Verfahren zur homo- und mischpolymerisation von olefinen |
| IT1251465B (it) * | 1991-07-12 | 1995-05-15 | Enichem Polimeri | Catalizzatore supportato per la (co)polimerizzazione dell'etilene. |
| DE4332786A1 (de) * | 1993-09-27 | 1995-03-30 | Hoechst Ag | Verfahren zur Herstellung von ultrahochmolekularem Polyethylen mit hoher Schüttdichte |
| US6114271A (en) * | 1998-01-22 | 2000-09-05 | Ticona Gmbh | Process for the preparation of a polymerization and copolymerization of ethylene to give ultrahigh molecular-weight ethylene polymers |
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2001
- 2001-05-08 DE DE10122111A patent/DE10122111B4/de not_active Expired - Fee Related
-
2002
- 2002-05-07 EP EP02771637A patent/EP1401888B1/de not_active Expired - Lifetime
- 2002-05-07 AT AT02771637T patent/ATE438665T1/de not_active IP Right Cessation
- 2002-05-07 CN CNB028107799A patent/CN1249101C/zh not_active Expired - Lifetime
- 2002-05-07 US US10/476,959 patent/US7157532B2/en not_active Expired - Lifetime
- 2002-05-07 JP JP2002592365A patent/JP2004527633A/ja active Pending
- 2002-05-07 WO PCT/EP2002/005026 patent/WO2002094891A2/de not_active Ceased
- 2002-05-07 DE DE50213743T patent/DE50213743D1/de not_active Expired - Lifetime
- 2002-05-07 KR KR1020037014525A patent/KR100853366B1/ko not_active Expired - Lifetime
- 2002-05-07 BR BRPI0209542-4A patent/BR0209542B1/pt not_active IP Right Cessation
- 2002-05-07 CA CA002446612A patent/CA2446612A1/en not_active Abandoned
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4447587A (en) | 1981-06-20 | 1984-05-08 | Hoechst Aktiengesellschaft | Process for the preparation of a polyolefin, and a catalyst for this process |
Also Published As
| Publication number | Publication date |
|---|---|
| ATE438665T1 (de) | 2009-08-15 |
| EP1401888B1 (de) | 2009-08-05 |
| KR20030096364A (ko) | 2003-12-24 |
| DE50213743D1 (de) | 2009-09-17 |
| US7157532B2 (en) | 2007-01-02 |
| EP1401888A2 (de) | 2004-03-31 |
| US20040152850A1 (en) | 2004-08-05 |
| WO2002094891A3 (de) | 2003-02-27 |
| CA2446612A1 (en) | 2002-11-28 |
| CN1249101C (zh) | 2006-04-05 |
| BR0209542B1 (pt) | 2011-12-13 |
| BR0209542A (pt) | 2004-04-20 |
| JP2004527633A (ja) | 2004-09-09 |
| CN1520430A (zh) | 2004-08-11 |
| DE10122111B4 (de) | 2007-03-01 |
| WO2002094891A2 (de) | 2002-11-28 |
| DE10122111A1 (de) | 2002-11-28 |
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