KR100804732B1 - 작은 결정체 제올라이트 ｓｓｚ-32 및 이의 제조방법과 이를 이용한 탈납방법 - Google Patents

작은 결정체 제올라이트 ｓｓｚ-32 및 이의 제조방법과 이를 이용한 탈납방법 Download PDF

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KR100804732B1
KR100804732B1 KR1020067008372A KR20067008372A KR100804732B1 KR 100804732 B1 KR100804732 B1 KR 100804732B1 KR 1020067008372 A KR1020067008372 A KR 1020067008372A KR 20067008372 A KR20067008372 A KR 20067008372A KR 100804732 B1 KR100804732 B1 KR 100804732B1
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zeolite
ssz
range
group
mixture
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KR20060076323A (ko
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스테이시 아이 존스
구앙 장
카말라 크리쉬나
조셉 에이 비스카르디
폴 마르칸토니오
유티미오스 비토라토스
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셰브런 유.에스.에이.인크.
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    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/04—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof using at least one organic template directing agent, e.g. an ionic quaternary ammonium compound or an aminated compound
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/7049—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing rare earth elements, titanium, zirconium, hafnium, zinc, cadmium, mercury, gallium, indium, thallium, tin or lead
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/72—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing iron group metals, noble metals or copper
    • B01J29/74—Noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/46—Other types characterised by their X-ray diffraction pattern and their defined composition
    • C01B39/48—Other types characterised by their X-ray diffraction pattern and their defined composition using at least one organic template directing agent
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/58—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins
    • C10G45/60—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins characterised by the catalyst used
    • C10G45/64—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins characterised by the catalyst used containing crystalline alumino-silicates, e.g. molecular sieves
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G73/00—Recovery or refining of mineral waxes, e.g. montan wax
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G73/00—Recovery or refining of mineral waxes, e.g. montan wax
    • C10G73/38—Chemical modification of petroleum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/42—Addition of matrix or binder particles

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • General Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
KR1020067008372A 2003-10-31 2004-10-29 작은 결정체 제올라이트 ｓｓｚ-32 및 이의 제조방법과 이를 이용한 탈납방법 Expired - Lifetime KR100804732B1 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US10/698,250 2003-10-31
US10/698,250 US7390763B2 (en) 2003-10-31 2003-10-31 Preparing small crystal SSZ-32 and its use in a hydrocarbon conversion process

Publications (2)

Publication Number Publication Date
KR20060076323A KR20060076323A (ko) 2006-07-04
KR100804732B1 true KR100804732B1 (ko) 2008-02-19

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Country Status (11)

Country Link
US (3) US7390763B2 (enExample)
EP (1) EP1684897A4 (enExample)
JP (1) JP4671967B2 (enExample)
KR (1) KR100804732B1 (enExample)
CN (1) CN100587035C (enExample)
BR (1) BRPI0415948A (enExample)
CA (1) CA2543283C (enExample)
EA (1) EA010635B1 (enExample)
SG (3) SG148147A1 (enExample)
WO (1) WO2005042144A2 (enExample)
ZA (1) ZA200603295B (enExample)

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KR20080038203A (ko) * 2005-08-04 2008-05-02 셰브런 유.에스.에이.인크. 제올라이트 ｍｔｔ 및 ｍｔｗ를 이용한 탈납 방법
US20080083657A1 (en) * 2006-10-04 2008-04-10 Zones Stacey I Isomerization process using metal-modified small crystallite mtt molecular sieve
US7824658B2 (en) * 2006-12-28 2010-11-02 Chevron U.S.A., Inc. Method of making ultrasmall crystal MTT molecular sieves
US20090137728A1 (en) * 2007-08-30 2009-05-28 Ashland Licensing And Intellectual Property Llc Low blush gelcoats having high color fastness
JP2010116328A (ja) * 2008-11-11 2010-05-27 Nippon Oil Corp 不飽和炭化水素および含酸素化合物の製造方法、触媒およびその製造方法
US8500991B2 (en) * 2008-12-16 2013-08-06 Exxonmobil Research And Engineering Company High activity MTT framework type molecular sieves
TWI473652B (zh) 2008-12-26 2015-02-21 Nippon Oil Corp Hydrogenated isomerization catalyst, method for producing the same, dewaxing method for hydrocarbon oil and method for producing lubricating base oil
AU2010233109B2 (en) 2009-04-09 2014-10-30 California Institute Of Technology Molecular sieves and related methods and structure directing agents
US8431014B2 (en) * 2009-10-06 2013-04-30 Chevron U.S.A. Inc. Process and catalyst system for improving dewaxing catalyst stability and lubricant oil yield
US8679451B2 (en) * 2009-11-20 2014-03-25 Chevron U.S.A. Inc. Method for making aluminosilicate ZSM-12
US8101811B2 (en) * 2009-11-20 2012-01-24 Chevron U.S.A. Inc. Process for isomerizing a hydrocarbonaceous feedstock using aluminosilicate ZSM-12
US8475648B2 (en) * 2010-06-29 2013-07-02 Chevron U.S.A. Inc. Catalytic processes and systems for base oil production from heavy feedstock
US8617387B2 (en) * 2010-06-29 2013-12-31 Chevron U.S.A. Inc. Catalytic processes and systems for base oil production from light feedstock
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US8545805B2 (en) * 2010-11-05 2013-10-01 Chevron U.S.A. Inc. Method for preparing small crystal SSZ-32
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US9573124B2 (en) * 2014-05-21 2017-02-21 Chevron U.S.A. Inc. Method for making molecular sieve SSZ-95
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EP3317227B1 (en) 2015-06-30 2021-03-24 Uop Llc Uzm-53, an mtt zeolite
WO2017044365A1 (en) * 2015-09-11 2017-03-16 Chevron U.S.A. Inc. Method for preparing zeolite ssz-98
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CN106745029A (zh) * 2017-01-22 2017-05-31 天津大学 一种无模板剂快速合成ssz‑32分子筛的方法
DE102018107630A1 (de) * 2018-03-29 2019-10-02 Wpx Faserkeramik Gmbh Oxidkeramischer Faserverbundwerkstoff
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CN108408735B (zh) * 2018-05-21 2021-03-23 太原理工大学 一种利用硅灰制备suz-4分子筛的方法
CN108726534B (zh) * 2018-06-07 2021-08-10 西安工程大学 一种微介孔zsm-5分子筛的制备方法
CN112352033B (zh) 2018-09-20 2022-09-02 诺维有限责任公司 制备表现出独特分支结构的烃混合物的方法
US11753355B2 (en) 2019-05-01 2023-09-12 Chevron U.S.A. Inc. Base oil synthesis via ionic catalyst oligomerization and waterless separation of the oligomerization catalyst
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CN112830499B (zh) * 2021-01-15 2022-12-13 天津大学 一种单分散ssz-32分子筛、其制备方法和应用
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US5558851A (en) * 1992-12-16 1996-09-24 Chevron U.S.A. Inc. Preparation of aluminosilicate zeolites

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Publication number Publication date
EA010635B1 (ru) 2008-10-30
EP1684897A4 (en) 2011-03-30
JP2007511457A (ja) 2007-05-10
JP4671967B2 (ja) 2011-04-20
CA2543283C (en) 2011-09-13
SG148145A1 (en) 2008-12-31
US20050092651A1 (en) 2005-05-05
EA200600883A1 (ru) 2007-02-27
SG148146A1 (en) 2008-12-31
US7390763B2 (en) 2008-06-24
WO2005042144A2 (en) 2005-05-12
CA2543283A1 (en) 2005-05-12
ZA200603295B (en) 2007-10-31
US20070041898A1 (en) 2007-02-22
CN1942560A (zh) 2007-04-04
US7569507B2 (en) 2009-08-04
BRPI0415948A (pt) 2007-01-02
WO2005042144A3 (en) 2006-10-19
US7468126B2 (en) 2008-12-23
US20070048214A1 (en) 2007-03-01
KR20060076323A (ko) 2006-07-04
EP1684897A2 (en) 2006-08-02
CN100587035C (zh) 2010-02-03
SG148147A1 (en) 2008-12-31

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