KR100788544B1 - 난연성 및 대전방지성을 갖는 열가소성 수지 조성물 - Google Patents
난연성 및 대전방지성을 갖는 열가소성 수지 조성물 Download PDFInfo
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- KR100788544B1 KR100788544B1 KR1020020085298A KR20020085298A KR100788544B1 KR 100788544 B1 KR100788544 B1 KR 100788544B1 KR 1020020085298 A KR1020020085298 A KR 1020020085298A KR 20020085298 A KR20020085298 A KR 20020085298A KR 100788544 B1 KR100788544 B1 KR 100788544B1
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L69/00—Compositions of polycarbonates; Compositions of derivatives of polycarbonates
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/04—Carbon
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/51—Phosphorus bound to oxygen
- C08K5/52—Phosphorus bound to oxygen only
- C08K5/521—Esters of phosphoric acids, e.g. of H3PO4
- C08K5/523—Esters of phosphoric acids, e.g. of H3PO4 with hydroxyaryl compounds
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/12—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L55/00—Compositions of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08L23/00 - C08L53/00
- C08L55/02—ABS [Acrylonitrile-Butadiene-Styrene] polymers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2300/00—Characterised by the use of unspecified polymers
- C08J2300/22—Thermoplastic resins
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/001—Conductive additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/002—Physical properties
- C08K2201/005—Additives being defined by their particle size in general
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/04—Antistatic
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
실시예1 | 실시예2 | 실시예3 | 실시예4 | 비교예1 | 비교예2 | 비교예3 | 비교예4 | |
PC수지(1) (중량부) | 40 | 40 | 60 | 80 | 30 | 40 | 40 | 90 |
ABS수지(2) (중량부) | 60 | 60 | 40 | 20 | 70 | 60 | 60 | 10 |
전도성 카본블랙(3) (중량부) | 15 | 17 | 18 | 19 | 15 | 30 | 17 | 18 |
난연제(4) (중량부) | 24 | 25 | 24 | 25 | 24 | 24 | 35 | 10 |
불소화 폴리올레핀(5) (중량부) | 0.5 | 1.0 | 1.0 | 0.5 | 1.0 | 0.5 | 1.0 | 0.5 |
인장강도 (kgf/cm2) | 460 | 480 | 510 | 530 | 420 | 620 | 420 | 570 |
충격강도 (kgf·cm/cm) | 30 | 22 | 15 | 12 | 40 | 5.0 | 7.0 | 6.0 |
난연성 (UL 94,1/16”) | V-0 | V-0 | V-0 | V-0 | V-2 | Fail | V-0 | Fail |
표면저항(Ω) | 108 | 106 | 106 | 106 | 1012 | 107 | 109 | 1011 |
Claims (5)
- 폴리카보네이트(PC) 수지 40 내지 80 중량% 및 아크릴로니트릴/부타디엔/스티렌(ABS) 수지 60 내지 20 중량%로 구성된 기초 수지 100 중량부;인계 난연제 15 내지 30 중량부;불소화 폴리올레핀계 수지 0.2 내지 2.0중량부; 및,전도성 카본블랙 15 내지 25 중량부:로 이루어지는 열가소성 수지 조성물로서, 상기 전도성 카본블랙은 평균 입자크기가 30 내지 40 ㎚, DBP 흡수율 값이 250~300 ㎖/100g인 것이고, 상기 인계 난연제는 하기 화학식(II)의 구조를 가지는 것인 난연성 및 대전 방지성이 우수한 열가소성 수지 조성물.
- 삭제
- 삭제
- 제1항에 있어서, 상기 불소화 폴리올레핀계 수지는 폴리테트라플루오로에틸렌, 폴리비닐리덴플루오라이드, 테트라플루오로에틸렌과 비닐리덴플루오로라이드의 공중합체 및 테트라플루오로에틸렌과 헥사플루오로프로필렌의 공중합체로 이루어지는 군에서 선택되는 것을 하나 또는 2종류 이상 혼합하여 사용하는 것을 특징으로 하는 난연성 및 대전 방지성이 우수한 열가소성 수지 조성물.
- 제1항에 있어서, 상기 수지 조성물은 충격보강제, 무기물 첨가제, 열안정제, 산화방지제, 이형제, 활제, 광안정제, 안료, 염료 및 가소제로 이루어지는 군으로부터 선택되는 하나 이상의 첨가제를 더 포함하는 것을 특징으로 하는 난연성 및 대전 방지성이 우수한 열가소성 수지 조성물.
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KR1020020085298A KR100788544B1 (ko) | 2002-12-27 | 2002-12-27 | 난연성 및 대전방지성을 갖는 열가소성 수지 조성물 |
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KR1020020085298A KR100788544B1 (ko) | 2002-12-27 | 2002-12-27 | 난연성 및 대전방지성을 갖는 열가소성 수지 조성물 |
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KR20040059618A KR20040059618A (ko) | 2004-07-06 |
KR100788544B1 true KR100788544B1 (ko) | 2007-12-26 |
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Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
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KR100865612B1 (ko) * | 2005-11-18 | 2008-10-27 | 주식회사 삼양사 | 대전방지성을 가지는 비할로겐 난연성폴리카보네이트/아크릴로니트릴-부타디엔-스티렌얼로이수지 조성물 |
KR101596542B1 (ko) | 2012-12-27 | 2016-02-22 | 제일모직주식회사 | 적하방지 효과가 우수한 열가소성 수지 조성물 |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4914114A (en) | 1984-05-28 | 1990-04-03 | Merck Patent Gesellschaft Mit Breschrankter Haftung | 3-[4-(4-phenyl-1,2,3,6-tetrahydro-1-pyridyl)butyl]-5-hydroxy-indole methanesulfonate having sedating and anti-parkinsonism properties |
JPH06166809A (ja) * | 1992-11-30 | 1994-06-14 | Lion Corp | 導電性フィルム又はシート |
US5552465A (en) | 1990-10-24 | 1996-09-03 | Bayer Atkiengesellschaft | Polycarbonate molding compounds stable to light ageing |
US20020111405A1 (en) | 2000-12-20 | 2002-08-15 | General Electric Company | Flame retardant polycarbonate resin/ABS graft copolymer blends |
US6448316B1 (en) | 1997-09-18 | 2002-09-10 | Mitsubishi Engineering-Plastics Corporation | Flame retardant polycarbonate-styrene (or acrylate) polymers, and/or copolymers and/or graft polymer/copolymer mixtures |
KR20040056713A (ko) * | 2002-12-24 | 2004-07-01 | 주식회사 삼양사 | 대전방지성을 갖는 열가소성 수지 조성물 |
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- 2002-12-27 KR KR1020020085298A patent/KR100788544B1/ko active IP Right Grant
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4914114A (en) | 1984-05-28 | 1990-04-03 | Merck Patent Gesellschaft Mit Breschrankter Haftung | 3-[4-(4-phenyl-1,2,3,6-tetrahydro-1-pyridyl)butyl]-5-hydroxy-indole methanesulfonate having sedating and anti-parkinsonism properties |
US5552465A (en) | 1990-10-24 | 1996-09-03 | Bayer Atkiengesellschaft | Polycarbonate molding compounds stable to light ageing |
JPH06166809A (ja) * | 1992-11-30 | 1994-06-14 | Lion Corp | 導電性フィルム又はシート |
US6448316B1 (en) | 1997-09-18 | 2002-09-10 | Mitsubishi Engineering-Plastics Corporation | Flame retardant polycarbonate-styrene (or acrylate) polymers, and/or copolymers and/or graft polymer/copolymer mixtures |
US20020111405A1 (en) | 2000-12-20 | 2002-08-15 | General Electric Company | Flame retardant polycarbonate resin/ABS graft copolymer blends |
KR20040056713A (ko) * | 2002-12-24 | 2004-07-01 | 주식회사 삼양사 | 대전방지성을 갖는 열가소성 수지 조성물 |
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