KR100675053B1 - 실질적으로 무정형인 프로필렌 기재 중합체의 제조 방법 - Google Patents

실질적으로 무정형인 프로필렌 기재 중합체의 제조 방법 Download PDF

Info

Publication number
KR100675053B1
KR100675053B1 KR1020017011897A KR20017011897A KR100675053B1 KR 100675053 B1 KR100675053 B1 KR 100675053B1 KR 1020017011897 A KR1020017011897 A KR 1020017011897A KR 20017011897 A KR20017011897 A KR 20017011897A KR 100675053 B1 KR100675053 B1 KR 100675053B1
Authority
KR
South Korea
Prior art keywords
formula
delete delete
groups
group
mmol
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
KR1020017011897A
Other languages
English (en)
Korean (ko)
Other versions
KR20010112350A (ko
Inventor
레스꼬니루이지
구이도띠시모나
바루지지오반니
그란디니크리스띠아노
니판테브일리야이
카슈린이고르에이
이브첸코파벨브이
Original Assignee
바셀 테크놀로지 캄파니 비이브이
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 바셀 테크놀로지 캄파니 비이브이 filed Critical 바셀 테크놀로지 캄파니 비이브이
Publication of KR20010112350A publication Critical patent/KR20010112350A/ko
Application granted granted Critical
Publication of KR100675053B1 publication Critical patent/KR100675053B1/ko
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
    • C07F7/02—Silicon compounds
    • C07F7/08—Compounds having one or more C—Si linkages
    • C07F7/0803—Compounds with Si-C or Si-Si linkages
    • C07F7/081—Compounds with Si-C or Si-Si linkages comprising at least one atom selected from the elements N, O, halogen, S, Se or Te
    • C07F7/0812—Compounds with Si-C or Si-Si linkages comprising at least one atom selected from the elements N, O, halogen, S, Se or Te comprising a heterocyclic ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04—Monomers containing three or four carbon atoms
    • C08F10/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
KR1020017011897A 2000-01-18 2001-01-12 실질적으로 무정형인 프로필렌 기재 중합체의 제조 방법 Expired - Fee Related KR100675053B1 (ko)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
EP00200193 2000-01-18
EP00200193.1 2000-01-18
EP00202791 2000-08-07
EP00202791.0 2000-08-07

Publications (2)

Publication Number Publication Date
KR20010112350A KR20010112350A (ko) 2001-12-20
KR100675053B1 true KR100675053B1 (ko) 2007-01-26

Family

ID=26071752

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1020017011897A Expired - Fee Related KR100675053B1 (ko) 2000-01-18 2001-01-12 실질적으로 무정형인 프로필렌 기재 중합체의 제조 방법

Country Status (11)

Country Link
US (1) US6730754B2 (enExample)
EP (2) EP1159310B1 (enExample)
JP (1) JP2003520869A (enExample)
KR (1) KR100675053B1 (enExample)
CN (1) CN100457787C (enExample)
AT (2) ATE292148T1 (enExample)
AU (1) AU3729501A (enExample)
BR (1) BR0105177A (enExample)
DE (2) DE60109680T2 (enExample)
ES (2) ES2239665T3 (enExample)
WO (1) WO2001053360A1 (enExample)

Families Citing this family (69)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AU2760599A (en) * 1998-02-04 1999-08-23 Friedman, Robert F. Method and apparatus for combining transponders on multiple satellites into virtual channels
WO2000050470A2 (en) 1999-02-22 2000-08-31 Eastman Chemical Company Catalysts containing n-pyrrolyl substituted nitrogen donors
DE60226427D1 (de) 2001-04-10 2008-06-19 Basell Polyolefine Gmbh Verfahren zur herstellung von mono oder bis halogensubstituierten metallozenverbindungen
US6759361B2 (en) 2001-06-04 2004-07-06 Equistar Chemicals, Lp Aluminoboronate activators for single-site olefin polymerization catalysts
JP2004535505A (ja) 2001-07-17 2004-11-25 バセル ポリオレフィン ジーエムビーエイチ オレフィン（共）重合のための多工程方法
DE10145453A1 (de) * 2001-09-14 2003-06-05 Basell Polyolefine Gmbh Monocyclopentadienylkomplexe mit einem kondensierten Heterocyclus
BR0212317A (pt) * 2001-09-14 2004-09-21 Basell Polyolefine Gmbh Processo para a polimerização de olefinas na presença de um sistema de catalisador, uso do mesmo, e, polìmero
JP4062929B2 (ja) 2002-02-08 2008-03-19 住友化学株式会社 遷移金属錯体、配位子、オレフィン重合用触媒およびオレフィン重合体の製造方法
US20050010039A1 (en) * 2002-03-14 2005-01-13 Graf David D Polycyclic fused heteroring compounds metal complexes and polymerization process
CA2494611C (en) * 2002-08-02 2012-01-24 Equistar Chemicals, Lp Catalyst comprising bridged indeno[1,2-b]indolyl metal complex
US6559251B1 (en) * 2002-08-02 2003-05-06 Equistar Chemicals, Lp Process for making low-density polyolefins
US7662885B2 (en) 2002-08-12 2010-02-16 Exxonmobil Chemical Patents Inc. Method to make an article comprising polymer concentrate
US8003725B2 (en) 2002-08-12 2011-08-23 Exxonmobil Chemical Patents Inc. Plasticized hetero-phase polyolefin blends
US7271209B2 (en) 2002-08-12 2007-09-18 Exxonmobil Chemical Patents Inc. Fibers and nonwovens from plasticized polyolefin compositions
US7531594B2 (en) 2002-08-12 2009-05-12 Exxonmobil Chemical Patents Inc. Articles from plasticized polyolefin compositions
EP1530611B1 (en) 2002-08-12 2013-12-04 ExxonMobil Chemical Patents Inc. Plasticized polyolefin compositions
US7998579B2 (en) 2002-08-12 2011-08-16 Exxonmobil Chemical Patents Inc. Polypropylene based fibers and nonwovens
US6841500B2 (en) 2002-12-03 2005-01-11 Equistar Chemicals, Lp Bimetallic indenoindolyl catalysts
US6683150B1 (en) 2002-12-19 2004-01-27 Equistar Chemicals, Lp High molecular weight polypropylene process
DE10303225A1 (de) * 2003-01-28 2004-08-05 Inventis Technologies Gmbh Katalysatorkombination, isotaktische Polymere sowie ein Verfahren zur Herstellung von linearen isotaktischen Polymeren und dessen Verwendung
US6693155B1 (en) * 2003-03-05 2004-02-17 Equistar Chemicals, Lp Propylene polymerization process
US6794468B1 (en) 2003-05-12 2004-09-21 Equistar Chemicals, Lp Olefin polymerization process
US6927264B2 (en) 2003-05-28 2005-08-09 Dow Global Technologies Inc. Metal complexes and polymerization process using same
US6998451B2 (en) 2003-07-01 2006-02-14 Equistar Chemicals, Lp Olefin polymerization process
US6933353B2 (en) 2003-07-07 2005-08-23 Equistar Chemicals, Lp Olefin polymerization process
US6818713B1 (en) * 2003-08-11 2004-11-16 Equistar Chemicals, Lp Process for making polyethylene
US8192813B2 (en) 2003-08-12 2012-06-05 Exxonmobil Chemical Patents, Inc. Crosslinked polyethylene articles and processes to produce same
US6939930B2 (en) 2003-09-09 2005-09-06 Equistar Chemicals, Lp Hydrosilane additives for increased polyolefin molecular weight
US6958377B2 (en) 2003-10-15 2005-10-25 Equistar Chemicals, Lp Olefin polymerization process
US7589145B2 (en) 2004-04-15 2009-09-15 Exxonmobil Chemical Patents Inc. Syndiotactic rich polyolefins
US6995220B2 (en) 2004-04-29 2006-02-07 Equistar Chemicals, Lp Ethylene polymerization process
US6967231B1 (en) 2004-09-23 2005-11-22 Equistar Chemicals, Lp Olefin polymerization process
GB2420348B (en) * 2004-10-28 2009-11-18 Exxonmobil Chem Patents Inc Syndiotactic rich polyolefins
DE602005015359D1 (de) * 2004-12-17 2009-08-20 Exxonmobil Chem Patents Inc Folien aus polymerblends
US8389615B2 (en) 2004-12-17 2013-03-05 Exxonmobil Chemical Patents Inc. Elastomeric compositions comprising vinylaromatic block copolymer, polypropylene, plastomer, and low molecular weight polyolefin
US7230056B2 (en) 2005-07-01 2007-06-12 Equistar Chemicals, Lp Catalyst preparation method
US7196147B2 (en) 2005-07-01 2007-03-27 Equistar Chemicals, Lp Olefin polymerization process with improved operability and polymer properties
CN101218296B (zh) 2005-07-15 2010-12-08 埃克森美孚化学专利公司 弹性体组合物
WO2007011462A1 (en) 2005-07-19 2007-01-25 Exxonmobil Chemical Patents Inc. Lubricants from mixed alpha-olefin feeds
US8696888B2 (en) 2005-10-20 2014-04-15 Exxonmobil Chemical Patents Inc. Hydrocarbon resid processing
US7423098B2 (en) 2006-01-17 2008-09-09 Equistar Chemicals, Lp Polyethylene process
US7638584B2 (en) 2006-06-20 2009-12-29 Equistar Chemicals, Lp Olefin polymerization process
US7638586B2 (en) 2006-09-26 2009-12-29 Equistar Chemicals, Lp Olefin polymerization process
US7829641B2 (en) 2008-07-16 2010-11-09 Equistar Chemicals, Lp Process for the preparation of multimodal polyethylene resins
US7816478B2 (en) 2008-09-03 2010-10-19 Equistar Chemicals, Lp Polyethylene thick film and process for preparing polyethylene
CN102666806B (zh) * 2009-12-24 2015-09-16 埃克森美孚化学专利公司 用于生产新型合成基础油料的方法
SG10201802959WA (en) 2013-07-17 2018-05-30 Exxonmobil Chemical Patents Inc Cyclopropyl substituted metallocene catalysts
US10647795B2 (en) 2014-02-07 2020-05-12 Eastman Chemical Company Adhesive composition comprising amorphous propylene-ethylene copolymer and polyolefins
US10696765B2 (en) 2014-02-07 2020-06-30 Eastman Chemical Company Adhesive composition comprising amorphous propylene-ethylene copolymer and propylene polymer
US10723824B2 (en) 2014-02-07 2020-07-28 Eastman Chemical Company Adhesives comprising amorphous propylene-ethylene copolymers
US10308740B2 (en) 2014-02-07 2019-06-04 Eastman Chemical Company Amorphous propylene-ethylene copolymers
US11267916B2 (en) 2014-02-07 2022-03-08 Eastman Chemical Company Adhesive composition comprising amorphous propylene-ethylene copolymer and polyolefins
US9428598B2 (en) 2014-02-07 2016-08-30 Eastman Chemical Company Amorphous propylene-ethylene copolymers
KR101637982B1 (ko) 2014-11-07 2016-07-11 주식회사 엘지화학 리간드 화합물, 전이금속 화합물 및 이를 포함하는 촉매 조성물
KR101719064B1 (ko) 2014-11-13 2017-03-22 주식회사 엘지화학 리간드 화합물, 전이금속 화합물 및 이를 포함하는 촉매 조성물
KR101910701B1 (ko) * 2015-07-02 2018-10-22 주식회사 엘지화학 전이금속 화합물 및 이를 포함하는 촉매 조성물
KR102584264B1 (ko) * 2017-06-28 2023-10-05 주식회사 엘지화학 신규한 리간드 화합물 및 이를 포함하는 전이금속 화합물
KR102531558B1 (ko) * 2017-06-28 2023-05-15 주식회사 엘지화학 리간드 화합물 및 전이금속 화합물의 제조방법
WO2019022569A1 (ko) * 2017-07-27 2019-01-31 주식회사 엘지화학 신규한 전이금속 화합물 및 이를 제조하는 방법
KR102328690B1 (ko) * 2017-07-27 2021-11-18 주식회사 엘지화학 신규한 전이금속 화합물 및 이를 제조하는 방법
WO2019059665A1 (ko) 2017-09-25 2019-03-28 주식회사 엘지화학 리간드 화합물, 전이금속 화합물 및 이를 포함하는 촉매 조성물
EP3705503A4 (en) * 2017-12-26 2020-12-30 Lg Chem, Ltd. OLEFINE BASED POLYMER
KR20190127591A (ko) * 2018-05-04 2019-11-13 주식회사 엘지화학 에틸렌/알파-올레핀 공중합체를 포함하는 접착제 조성물
CN111902438B (zh) 2018-05-04 2023-01-10 Lg化学株式会社 乙烯/α-烯烃共聚物及其制备方法
JP7034287B2 (ja) 2018-05-04 2022-03-11 エルジー・ケム・リミテッド エチレン／アルファ－オレフィン共重合体を含む接着剤組成物
KR102601720B1 (ko) * 2018-09-07 2023-11-14 주식회사 엘지화학 리간드 화합물, 전이금속 화합물 및 이를 포함하는 촉매 조성물
JP7423332B2 (ja) * 2019-03-29 2024-01-29 三井化学株式会社 遷移金属化合物、オレフィン重合用触媒、およびオレフィン重合体の製造方法
JP7308644B2 (ja) * 2019-03-29 2023-07-14 三井化学株式会社 オレフィン・環状オレフィン共重合体の製造方法
CN116212948B (zh) * 2023-02-14 2024-07-09 四川九天五洋新材料有限责任公司 一种丙烯气相环氧化成型催化剂及其制备方法

Family Cites Families (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ZA844157B (en) 1983-06-06 1986-01-29 Exxon Research Engineering Co Process and catalyst for polyolefin density and molecular weight control
US5055438A (en) 1989-09-13 1991-10-08 Exxon Chemical Patents, Inc. Olefin polymerization catalysts
NZ235032A (en) 1989-08-31 1993-04-28 Dow Chemical Co Constrained geometry complexes of titanium, zirconium or hafnium comprising a substituted cyclopentadiene ligand; use as olefin polymerisation catalyst component
US5026798A (en) * 1989-09-13 1991-06-25 Exxon Chemical Patents Inc. Process for producing crystalline poly-α-olefins with a monocyclopentadienyl transition metal catalyst system
AU660808B2 (en) 1992-06-18 1995-07-06 Montell Technology Company B.V. Catalysts for the polymerization of olefins
IT1273661B (it) 1994-07-20 1997-07-09 Spherilene Srl Catalizzatori per la polimerizzazione delle olefine
IT1275857B1 (it) 1995-03-03 1997-10-24 Spherilene Srl Copolimeri atattici del propilene con l'etilene
CZ42399A3 (cs) * 1996-08-08 1999-07-14 The Dow Chemical Company Kovové komplexy obsahující 3-heteroatom-substituovaný cyklopentadienyl, katalytický systém obsahující tento kovový komplex, způsob polymerace, cyklopentadienylový ligand a použití tohoto ligandu
PL331526A1 (en) 1996-08-08 1999-07-19 Dow Chemical Co Metal complexes containing cyclopentadienyl substututed with a heteroatom at position 2 and method of polymerising olefins
IL129600A0 (en) * 1996-11-15 2000-02-29 Montell Technology Company Bv Heterocyclic metallocenes and polymerization catalysts
US6451938B1 (en) 1997-02-25 2002-09-17 Exxon Mobil Chemical Patents Inc. Polymerization catalyst system comprising heterocyclic fused cyclopentadienide ligands
US6559252B1 (en) 1997-10-29 2003-05-06 Basell Technology Company Bv Catalysts and processes for the polymerization of olefins
PL334470A1 (en) 1997-11-12 2000-02-28 Montell Technology Company Bv Metalocenes and olefins polymerisation catalysts
CN1243763C (zh) * 1998-01-14 2006-03-01 蒙特尔技术有限公司 茂金属化合物的制备方法
DE60001902T2 (de) 1999-06-04 2003-11-13 Basell Polyolefine Gmbh Verfahren zur herstellung titankomplexen
EP1214364B1 (en) 1999-09-22 2003-07-16 Basell Polyolefine GmbH Catalyst system and process for the polymerization of olefins
US6232260B1 (en) * 1999-10-14 2001-05-15 Equistar Chemicals, L.P. Single-site catalysts for olefin polymerization
AU3016401A (en) 1999-12-28 2001-07-09 Basell Technology Company B.V. Process for the preparation of ethylene polymers
EP1157046B1 (en) 1999-12-28 2005-12-07 Basell Polyolefine GmbH Process for the preparation of ethylene polymers
CN1280300C (zh) 1999-12-28 2006-10-18 巴塞尔技术有限公司 杂环茂金属化合物及其在生产烯烃聚合物的催化剂体系中的用途
US6559251B1 (en) 2002-08-02 2003-05-06 Equistar Chemicals, Lp Process for making low-density polyolefins

Also Published As

Publication number Publication date
US20020147286A1 (en) 2002-10-10
CN100457787C (zh) 2009-02-04
CN1372571A (zh) 2002-10-02
US6730754B2 (en) 2004-05-04
EP1159310A1 (en) 2001-12-05
ATE430753T1 (de) 2009-05-15
EP1533324A3 (en) 2006-06-07
ES2326537T3 (es) 2009-10-14
DE60138657D1 (de) 2009-06-18
EP1533324A2 (en) 2005-05-25
BR0105177A (pt) 2002-01-15
AU3729501A (en) 2001-07-31
EP1533324B1 (en) 2009-05-06
ATE292148T1 (de) 2005-04-15
EP1159310B1 (en) 2005-03-30
DE60109680T2 (de) 2006-02-02
DE60109680D1 (de) 2005-05-04
WO2001053360A1 (en) 2001-07-26
ES2239665T3 (es) 2005-10-01
KR20010112350A (ko) 2001-12-20
JP2003520869A (ja) 2003-07-08

Similar Documents

Publication Publication Date Title
EP1159310B1 (en) Process for producing substantially amorphous propylene-based polymers
EP0952978B1 (en) Metallocenes and catalysts for olefin-polymerisation
KR101293405B1 (ko) 메탈로센 화합물
JP4119843B2 (ja) メタロセン類、及びそれらから誘導される触媒組成物
DE69710838T2 (de) Katalysator zur polyolefinherstellung und polyolefinherstellungsverfahren
KR20130125311A (ko) 안사-메탈로센 화합물 및 이를 이용한 담지 촉매의 제조방법
JP2007513906A (ja) 有機金属遷移金属化合物、ビスシクロペンタジエニル配位子、触媒組成物、及びポリオレフィンの製造方法
EP1680453B1 (en) Organometallic transition metal compound, biscyclopentadienyl ligand system, catalyst system and process for preparing polyolefins
CA2317485A1 (en) Bridged metallocenes, preparation, use in catalytic systems
EP3882282A1 (en) Supported catalyst for propylene polymerization and method for producing polypropylene resin using same
KR20010034211A (ko) 올레핀-중합-촉매로서 비스(테트라히드로-인데닐)메탈로센
JP2005510591A (ja) プロピレンの多孔性ポリマー
JPH08183814A (ja) α‐オレフィンの重合
US12098158B2 (en) Transition metal compound, catalyst composition and method for preparing polypropylene using the same
KR20170074678A (ko) 신규한 전이금속 화합물
EP3524612B1 (en) Ligand compound, transition metal compound, and catalyst composition comprising the transition metal compound
KR102839804B1 (ko) 전이금속 화합물을 포함하는 촉매 조성물을 이용한 폴리올레핀의 제조방법
KR20190131454A (ko) 테트라하이드로인덴 유도체로부터 메탈로센 화합물을 제조하는 방법

Legal Events

Date Code Title Description
PA0105 International application

St.27 status event code: A-0-1-A10-A15-nap-PA0105

PG1501 Laying open of application

St.27 status event code: A-1-1-Q10-Q12-nap-PG1501

A201 Request for examination
E13-X000 Pre-grant limitation requested

St.27 status event code: A-2-3-E10-E13-lim-X000

P11-X000 Amendment of application requested

St.27 status event code: A-2-2-P10-P11-nap-X000

P13-X000 Application amended

St.27 status event code: A-2-2-P10-P13-nap-X000

PA0201 Request for examination

St.27 status event code: A-1-2-D10-D11-exm-PA0201

E701 Decision to grant or registration of patent right
PE0701 Decision of registration

St.27 status event code: A-1-2-D10-D22-exm-PE0701

GRNT Written decision to grant
PR0701 Registration of establishment

St.27 status event code: A-2-4-F10-F11-exm-PR0701

PR1002 Payment of registration fee

St.27 status event code: A-2-2-U10-U12-oth-PR1002

Fee payment year number: 1

PG1601 Publication of registration

St.27 status event code: A-4-4-Q10-Q13-nap-PG1601

LAPS Lapse due to unpaid annual fee
PC1903 Unpaid annual fee

St.27 status event code: A-4-4-U10-U13-oth-PC1903

Not in force date: 20100123

Payment event data comment text: Termination Category : DEFAULT_OF_REGISTRATION_FEE

PC1903 Unpaid annual fee

St.27 status event code: N-4-6-H10-H13-oth-PC1903

Ip right cessation event data comment text: Termination Category : DEFAULT_OF_REGISTRATION_FEE

Not in force date: 20100123

P22-X000 Classification modified

St.27 status event code: A-4-4-P10-P22-nap-X000

P22-X000 Classification modified

St.27 status event code: A-4-4-P10-P22-nap-X000