KR100632196B1 - 패턴 형성방법 - Google Patents
패턴 형성방법 Download PDFInfo
- Publication number
- KR100632196B1 KR100632196B1 KR1019997011568A KR19997011568A KR100632196B1 KR 100632196 B1 KR100632196 B1 KR 100632196B1 KR 1019997011568 A KR1019997011568 A KR 1019997011568A KR 19997011568 A KR19997011568 A KR 19997011568A KR 100632196 B1 KR100632196 B1 KR 100632196B1
- Authority
- KR
- South Korea
- Prior art keywords
- film
- photosensitive material
- pattern
- etched
- etching
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000000034 method Methods 0.000 title claims abstract description 59
- 230000007261 regionalization Effects 0.000 title claims abstract description 13
- 239000000463 material Substances 0.000 claims abstract description 115
- -1 salt compound Chemical class 0.000 claims abstract description 90
- 238000005530 etching Methods 0.000 claims abstract description 87
- 238000001312 dry etching Methods 0.000 claims abstract description 37
- 239000004065 semiconductor Substances 0.000 claims abstract description 37
- 239000002253 acid Substances 0.000 claims abstract description 31
- 239000000758 substrate Substances 0.000 claims abstract description 30
- 150000001875 compounds Chemical class 0.000 claims description 15
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 14
- 239000011368 organic material Substances 0.000 claims description 14
- 229910052717 sulfur Inorganic materials 0.000 claims description 14
- 239000011593 sulfur Substances 0.000 claims description 14
- 230000003667 anti-reflective effect Effects 0.000 claims description 13
- 230000002265 prevention Effects 0.000 claims description 3
- 239000007795 chemical reaction product Substances 0.000 abstract description 30
- 229910021420 polycrystalline silicon Inorganic materials 0.000 abstract description 14
- 229920005591 polysilicon Polymers 0.000 abstract description 14
- 230000015572 biosynthetic process Effects 0.000 abstract description 6
- 239000007789 gas Substances 0.000 description 46
- WQGWDDDVZFFDIG-UHFFFAOYSA-N pyrogallol Chemical compound OC1=CC=CC(O)=C1O WQGWDDDVZFFDIG-UHFFFAOYSA-N 0.000 description 20
- 239000010410 layer Substances 0.000 description 18
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 17
- 239000000460 chlorine Substances 0.000 description 14
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 12
- 229910052801 chlorine Inorganic materials 0.000 description 12
- 235000012431 wafers Nutrition 0.000 description 12
- 230000000052 comparative effect Effects 0.000 description 11
- 229940079877 pyrogallol Drugs 0.000 description 10
- 125000001424 substituent group Chemical group 0.000 description 10
- 229910021332 silicide Inorganic materials 0.000 description 9
- FVBUAEGBCNSCDD-UHFFFAOYSA-N silicide(4-) Chemical compound [Si-4] FVBUAEGBCNSCDD-UHFFFAOYSA-N 0.000 description 9
- 150000007514 bases Chemical class 0.000 description 8
- 229910052757 nitrogen Inorganic materials 0.000 description 8
- YXHKONLOYHBTNS-UHFFFAOYSA-N Diazomethane Chemical compound C=[N+]=[N-] YXHKONLOYHBTNS-UHFFFAOYSA-N 0.000 description 7
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 7
- 238000011161 development Methods 0.000 description 7
- 230000018109 developmental process Effects 0.000 description 7
- 229910001882 dioxygen Inorganic materials 0.000 description 7
- 230000000694 effects Effects 0.000 description 7
- 239000000126 substance Substances 0.000 description 7
- 239000011347 resin Substances 0.000 description 6
- 229920005989 resin Polymers 0.000 description 6
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 6
- 125000003118 aryl group Chemical group 0.000 description 5
- DNIAPMSPPWPWGF-UHFFFAOYSA-N monopropylene glycol Natural products CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 5
- 229920000642 polymer Polymers 0.000 description 5
- 239000000243 solution Substances 0.000 description 5
- CPELXLSAUQHCOX-UHFFFAOYSA-N Hydrogen bromide Chemical compound Br CPELXLSAUQHCOX-UHFFFAOYSA-N 0.000 description 4
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 4
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 4
- 125000000217 alkyl group Chemical group 0.000 description 4
- 230000007547 defect Effects 0.000 description 4
- 238000013461 design Methods 0.000 description 4
- 238000004090 dissolution Methods 0.000 description 4
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- LLHKCFNBLRBOGN-UHFFFAOYSA-N propylene glycol methyl ether acetate Chemical compound COCC(C)OC(C)=O LLHKCFNBLRBOGN-UHFFFAOYSA-N 0.000 description 4
- 229910052710 silicon Inorganic materials 0.000 description 4
- 239000010703 silicon Substances 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- WGTYBPLFGIVFAS-UHFFFAOYSA-M tetramethylammonium hydroxide Chemical compound [OH-].C[N+](C)(C)C WGTYBPLFGIVFAS-UHFFFAOYSA-M 0.000 description 4
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 3
- WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 description 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 239000000654 additive Substances 0.000 description 3
- 230000006866 deterioration Effects 0.000 description 3
- 238000010894 electron beam technology Methods 0.000 description 3
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 3
- 239000003112 inhibitor Substances 0.000 description 3
- 230000005855 radiation Effects 0.000 description 3
- 229960000834 vinyl ether Drugs 0.000 description 3
- DLDWUFCUUXXYTB-UHFFFAOYSA-N (2-oxo-1,2-diphenylethyl) 4-methylbenzenesulfonate Chemical compound C1=CC(C)=CC=C1S(=O)(=O)OC(C=1C=CC=CC=1)C(=O)C1=CC=CC=C1 DLDWUFCUUXXYTB-UHFFFAOYSA-N 0.000 description 2
- YPENZRNEWQQNDR-UHFFFAOYSA-N 1-[diazo-(3-methylphenyl)sulfonylmethyl]sulfonyl-3-methylbenzene Chemical compound CC1=CC=CC(S(=O)(=O)C(=[N+]=[N-])S(=O)(=O)C=2C=C(C)C=CC=2)=C1 YPENZRNEWQQNDR-UHFFFAOYSA-N 0.000 description 2
- ULGCVKBNCOLUAV-UHFFFAOYSA-N 1-chloro-4-[(4-chlorophenyl)sulfonyl-diazomethyl]sulfonylbenzene Chemical compound C1=CC(Cl)=CC=C1S(=O)(=O)C(=[N+]=[N-])S(=O)(=O)C1=CC=C(Cl)C=C1 ULGCVKBNCOLUAV-UHFFFAOYSA-N 0.000 description 2
- IVCKPVXMLYBDOM-UHFFFAOYSA-N 1-methyl-3-[(3-methylphenyl)sulfonylmethylsulfonyl]benzene Chemical compound CC1=CC=CC(S(=O)(=O)CS(=O)(=O)C=2C=C(C)C=CC=2)=C1 IVCKPVXMLYBDOM-UHFFFAOYSA-N 0.000 description 2
- XLOXYWLRAKCDQL-UHFFFAOYSA-N 1-methyl-4-[(4-methylphenyl)sulfonylmethylsulfonyl]benzene Chemical compound C1=CC(C)=CC=C1S(=O)(=O)CS(=O)(=O)C1=CC=C(C)C=C1 XLOXYWLRAKCDQL-UHFFFAOYSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical compound CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 description 2
- 229910008484 TiSi Inorganic materials 0.000 description 2
- QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical class C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 description 2
- 230000002159 abnormal effect Effects 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- 230000003321 amplification Effects 0.000 description 2
- QCHNSJNRFSOCLJ-UHFFFAOYSA-N benzenesulfonylmethylsulfonylbenzene Chemical compound C=1C=CC=CC=1S(=O)(=O)CS(=O)(=O)C1=CC=CC=C1 QCHNSJNRFSOCLJ-UHFFFAOYSA-N 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- YCIMNLLNPGFGHC-UHFFFAOYSA-N catechol Chemical compound OC1=CC=CC=C1O YCIMNLLNPGFGHC-UHFFFAOYSA-N 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 230000002301 combined effect Effects 0.000 description 2
- 125000006165 cyclic alkyl group Chemical group 0.000 description 2
- 125000004122 cyclic group Chemical group 0.000 description 2
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 2
- BGTOWKSIORTVQH-UHFFFAOYSA-N cyclopentanone Chemical compound O=C1CCCC1 BGTOWKSIORTVQH-UHFFFAOYSA-N 0.000 description 2
- 238000000151 deposition Methods 0.000 description 2
- 230000008021 deposition Effects 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- LZCLXQDLBQLTDK-UHFFFAOYSA-N ethyl 2-hydroxypropanoate Chemical compound CCOC(=O)C(C)O LZCLXQDLBQLTDK-UHFFFAOYSA-N 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 125000005842 heteroatom Chemical group 0.000 description 2
- 229910000042 hydrogen bromide Inorganic materials 0.000 description 2
- 239000011810 insulating material Substances 0.000 description 2
- 230000001678 irradiating effect Effects 0.000 description 2
- 238000001459 lithography Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000003199 nucleic acid amplification method Methods 0.000 description 2
- 150000004010 onium ions Chemical class 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 150000003254 radicals Chemical class 0.000 description 2
- GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 description 2
- 229910052814 silicon oxide Inorganic materials 0.000 description 2
- 238000004544 sputter deposition Methods 0.000 description 2
- 150000003871 sulfonates Chemical class 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- FAYMLNNRGCYLSR-UHFFFAOYSA-M triphenylsulfonium triflate Chemical compound [O-]S(=O)(=O)C(F)(F)F.C1=CC=CC=C1[S+](C=1C=CC=CC=1)C1=CC=CC=C1 FAYMLNNRGCYLSR-UHFFFAOYSA-M 0.000 description 2
- GCIYMCNGLUNWNR-UHFFFAOYSA-N (2,4-dinitrophenyl)methyl 4-methylbenzenesulfonate Chemical compound C1=CC(C)=CC=C1S(=O)(=O)OCC1=CC=C([N+]([O-])=O)C=C1[N+]([O-])=O GCIYMCNGLUNWNR-UHFFFAOYSA-N 0.000 description 1
- MCJPJAJHPRCILL-UHFFFAOYSA-N (2,6-dinitrophenyl)methyl 4-methylbenzenesulfonate Chemical compound C1=CC(C)=CC=C1S(=O)(=O)OCC1=C([N+]([O-])=O)C=CC=C1[N+]([O-])=O MCJPJAJHPRCILL-UHFFFAOYSA-N 0.000 description 1
- MCVVDMSWCQUKEV-UHFFFAOYSA-N (2-nitrophenyl)methyl 4-methylbenzenesulfonate Chemical compound C1=CC(C)=CC=C1S(=O)(=O)OCC1=CC=CC=C1[N+]([O-])=O MCVVDMSWCQUKEV-UHFFFAOYSA-N 0.000 description 1
- ZFAUJVNVQXJRTR-UHFFFAOYSA-N 1,1,1,2-tetrafluoro-2-methyl-3-phenylpentane-3-sulfonic acid Chemical compound CCC(C1=CC=CC=C1)(C(C)(C(F)(F)F)F)S(=O)(=O)O ZFAUJVNVQXJRTR-UHFFFAOYSA-N 0.000 description 1
- CYIGRWUIQAVBFG-UHFFFAOYSA-N 1,2-bis(2-ethenoxyethoxy)ethane Chemical compound C=COCCOCCOCCOC=C CYIGRWUIQAVBFG-UHFFFAOYSA-N 0.000 description 1
- RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 description 1
- YXUCKLDGMUBDBK-UHFFFAOYSA-N 1-(benzenesulfonyl)-1-diazonio-3,3-dimethylbut-1-en-2-olate Chemical compound CC(C)(C)C(=O)C(=[N+]=[N-])S(=O)(=O)C1=CC=CC=C1 YXUCKLDGMUBDBK-UHFFFAOYSA-N 0.000 description 1
- FWWTYWYFKDSTHP-UHFFFAOYSA-N 1-[(2,4-dimethylphenyl)sulfonylmethylsulfonyl]-2,4-dimethylbenzene Chemical compound CC1=CC(C)=CC=C1S(=O)(=O)CS(=O)(=O)C1=CC=C(C)C=C1C FWWTYWYFKDSTHP-UHFFFAOYSA-N 0.000 description 1
- DPOPGHCRRJYPMP-UHFFFAOYSA-N 1-[diazo(methylsulfonyl)methyl]sulfonyl-4-methylbenzene Chemical compound CC1=CC=C(S(=O)(=O)C(=[N+]=[N-])S(C)(=O)=O)C=C1 DPOPGHCRRJYPMP-UHFFFAOYSA-N 0.000 description 1
- OESYNCIYSBWEQV-UHFFFAOYSA-N 1-[diazo-(2,4-dimethylphenyl)sulfonylmethyl]sulfonyl-2,4-dimethylbenzene Chemical compound CC1=CC(C)=CC=C1S(=O)(=O)C(=[N+]=[N-])S(=O)(=O)C1=CC=C(C)C=C1C OESYNCIYSBWEQV-UHFFFAOYSA-N 0.000 description 1
- STDUMFWSACODTF-UHFFFAOYSA-N 1-[diazo-(4-ethylphenyl)sulfonylmethyl]sulfonyl-4-ethylbenzene Chemical compound C1=CC(CC)=CC=C1S(=O)(=O)C(=[N+]=[N-])S(=O)(=O)C1=CC=C(CC)C=C1 STDUMFWSACODTF-UHFFFAOYSA-N 0.000 description 1
- NRIGUVWTNMVMCA-UHFFFAOYSA-N 1-[diazo-(4-methoxyphenyl)sulfonylmethyl]sulfonyl-4-methoxybenzene Chemical compound C1=CC(OC)=CC=C1S(=O)(=O)C(=[N+]=[N-])S(=O)(=O)C1=CC=C(OC)C=C1 NRIGUVWTNMVMCA-UHFFFAOYSA-N 0.000 description 1
- GYQQFWWMZYBCIB-UHFFFAOYSA-N 1-[diazo-(4-methylphenyl)sulfonylmethyl]sulfonyl-4-methylbenzene Chemical compound C1=CC(C)=CC=C1S(=O)(=O)C(=[N+]=[N-])S(=O)(=O)C1=CC=C(C)C=C1 GYQQFWWMZYBCIB-UHFFFAOYSA-N 0.000 description 1
- JWCUOEQTPMTRIL-UHFFFAOYSA-N 1-bromo-4-[(4-bromophenyl)sulfonyl-diazomethyl]sulfonylbenzene Chemical compound C1=CC(Br)=CC=C1S(=O)(=O)C(=[N+]=[N-])S(=O)(=O)C1=CC=C(Br)C=C1 JWCUOEQTPMTRIL-UHFFFAOYSA-N 0.000 description 1
- GNLWRDUYIDEDLG-UHFFFAOYSA-N 1-bromo-4-[(4-bromophenyl)sulfonylmethylsulfonyl]benzene Chemical compound C1=CC(Br)=CC=C1S(=O)(=O)CS(=O)(=O)C1=CC=C(Br)C=C1 GNLWRDUYIDEDLG-UHFFFAOYSA-N 0.000 description 1
- UQLKRAFFXYZVBU-UHFFFAOYSA-N 1-chloro-4-[(4-chlorophenyl)sulfonylmethylsulfonyl]benzene Chemical compound C1=CC(Cl)=CC=C1S(=O)(=O)CS(=O)(=O)C1=CC=C(Cl)C=C1 UQLKRAFFXYZVBU-UHFFFAOYSA-N 0.000 description 1
- UGDXXMCTNJHYKN-UHFFFAOYSA-N 1-cyclohexyl-2-cyclohexylsulfonyl-2-diazonioethenolate Chemical compound C1CCCCC1S(=O)(=O)C(=[N+]=[N-])C(=O)C1CCCCC1 UGDXXMCTNJHYKN-UHFFFAOYSA-N 0.000 description 1
- DDPLKUDCQKROTF-UHFFFAOYSA-N 1-cyclohexyl-2-methyl-2-(4-methylphenyl)sulfonylpropan-1-one Chemical compound C1=CC(C)=CC=C1S(=O)(=O)C(C)(C)C(=O)C1CCCCC1 DDPLKUDCQKROTF-UHFFFAOYSA-N 0.000 description 1
- KJPDERSXMYGMBR-UHFFFAOYSA-N 1-cyclohexylsulfonyl-1-diazonio-3,3-dimethylbut-1-en-2-olate Chemical compound CC(C)(C)C(=O)C(=[N+]=[N-])S(=O)(=O)C1CCCCC1 KJPDERSXMYGMBR-UHFFFAOYSA-N 0.000 description 1
- DLVVNYRNTPABEQ-UHFFFAOYSA-N 1-diazonio-1-propan-2-ylsulfonylprop-1-en-2-olate Chemical compound CC(C)S(=O)(=O)C(=[N+]=[N-])C(C)=O DLVVNYRNTPABEQ-UHFFFAOYSA-N 0.000 description 1
- AFMKLJCLBQEQTM-UHFFFAOYSA-N 1-diazonio-3,3-dimethyl-1-(4-methylphenyl)sulfonylbut-1-en-2-olate Chemical compound CC1=CC=C(S(=O)(=O)C(=[N+]=[N-])C(=O)C(C)(C)C)C=C1 AFMKLJCLBQEQTM-UHFFFAOYSA-N 0.000 description 1
- BPDJYHYNEQRLLW-UHFFFAOYSA-N 1-diazonio-3-methyl-1-(4-methylphenyl)sulfonylbut-1-en-2-olate Chemical compound CC(C)C(=O)C(=[N+]=[N-])S(=O)(=O)C1=CC=C(C)C=C1 BPDJYHYNEQRLLW-UHFFFAOYSA-N 0.000 description 1
- UPVWJVSYMSZWQF-UHFFFAOYSA-N 1-ethenyl-4-(1-ethoxyethoxy)benzene;4-ethenylphenol Chemical compound OC1=CC=C(C=C)C=C1.CCOC(C)OC1=CC=C(C=C)C=C1 UPVWJVSYMSZWQF-UHFFFAOYSA-N 0.000 description 1
- SDYJGSMJUIHMKT-UHFFFAOYSA-N 1-ethyl-4-[(4-ethylphenyl)sulfonylmethylsulfonyl]benzene Chemical compound C1=CC(CC)=CC=C1S(=O)(=O)CS(=O)(=O)C1=CC=C(CC)C=C1 SDYJGSMJUIHMKT-UHFFFAOYSA-N 0.000 description 1
- QBTQTYZIRALXPA-UHFFFAOYSA-N 1-methoxy-4-[(4-methoxyphenyl)sulfonylmethylsulfonyl]benzene Chemical compound C1=CC(OC)=CC=C1S(=O)(=O)CS(=O)(=O)C1=CC=C(OC)C=C1 QBTQTYZIRALXPA-UHFFFAOYSA-N 0.000 description 1
- NHAPGXMXFCIWQP-UHFFFAOYSA-N 1-methyl-4-(methylsulfonylmethylsulfonyl)benzene Chemical compound CC1=CC=C(S(=O)(=O)CS(C)(=O)=O)C=C1 NHAPGXMXFCIWQP-UHFFFAOYSA-N 0.000 description 1
- ZBZAGZCFEOTODC-UHFFFAOYSA-N 1-tert-butyl-4-[(4-tert-butylphenyl)sulfonyl-diazomethyl]sulfonylbenzene Chemical compound C1=CC(C(C)(C)C)=CC=C1S(=O)(=O)C(=[N+]=[N-])S(=O)(=O)C1=CC=C(C(C)(C)C)C=C1 ZBZAGZCFEOTODC-UHFFFAOYSA-N 0.000 description 1
- SWOGZDBSWSFUIE-UHFFFAOYSA-N 1-tert-butyl-4-[(4-tert-butylphenyl)sulfonylmethylsulfonyl]benzene Chemical compound C1=CC(C(C)(C)C)=CC=C1S(=O)(=O)CS(=O)(=O)C1=CC=C(C(C)(C)C)C=C1 SWOGZDBSWSFUIE-UHFFFAOYSA-N 0.000 description 1
- JPSDCHFODMCZCM-UHFFFAOYSA-N 1-tert-butylsulfonyl-1-diazonio-3,3-dimethylbut-1-en-2-olate Chemical compound CC(C)(C)C(=O)C(=[N+]=[N-])S(=O)(=O)C(C)(C)C JPSDCHFODMCZCM-UHFFFAOYSA-N 0.000 description 1
- MOLRNXJUYCXJTN-UHFFFAOYSA-N 2,4-dimethyl-2-(4-methylphenyl)sulfonylpentan-3-one Chemical compound CC(C)C(=O)C(C)(C)S(=O)(=O)C1=CC=C(C)C=C1 MOLRNXJUYCXJTN-UHFFFAOYSA-N 0.000 description 1
- FEWSKCAVEJNPBX-UHFFFAOYSA-N 2-(2-hydroxy-2-phenylacetyl)benzenesulfonic acid Chemical class C=1C=CC=CC=1C(O)C(=O)C1=CC=CC=C1S(O)(=O)=O FEWSKCAVEJNPBX-UHFFFAOYSA-N 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- XKZQKPRCPNGNFR-UHFFFAOYSA-N 2-(3-hydroxyphenyl)phenol Chemical compound OC1=CC=CC(C=2C(=CC=CC=2)O)=C1 XKZQKPRCPNGNFR-UHFFFAOYSA-N 0.000 description 1
- YIHOJFNAXBGDSE-UHFFFAOYSA-N 2-(benzenesulfonyl)-2-diazonio-1-phenylethenolate Chemical compound C=1C=CC=CC=1S(=O)(=O)C(=[N+]=[N-])C(=O)C1=CC=CC=C1 YIHOJFNAXBGDSE-UHFFFAOYSA-N 0.000 description 1
- WEDBXRDHNUCFRC-UHFFFAOYSA-N 2-(diazomethylsulfonyl)ethylsulfonylcyclohexane Chemical compound [N-]=[N+]=CS(=O)(=O)CCS(=O)(=O)C1CCCCC1 WEDBXRDHNUCFRC-UHFFFAOYSA-N 0.000 description 1
- XNWFRZJHXBZDAG-UHFFFAOYSA-N 2-METHOXYETHANOL Chemical compound COCCO XNWFRZJHXBZDAG-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- QVWIVAMXJITXGI-UHFFFAOYSA-N 2-[1,1,1,3,3,3-hexafluoro-2-(4-methylphenyl)propan-2-yl]-4-(2-phenoxyethoxy)benzenesulfonic acid Chemical compound CC1=CC=C(C=C1)C(C2=C(C=CC(=C2)OCCOC3=CC=CC=C3)S(=O)(=O)O)(C(F)(F)F)C(F)(F)F QVWIVAMXJITXGI-UHFFFAOYSA-N 0.000 description 1
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Classifications
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- G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
- G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
- G03F7/004—Photosensitive materials
- G03F7/0045—Photosensitive materials with organic non-macromolecular light-sensitive compounds not otherwise provided for, e.g. dissolution inhibitors
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- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
- G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
- G03F7/004—Photosensitive materials
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- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
- G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
- G03F7/004—Photosensitive materials
- G03F7/09—Photosensitive materials characterised by structural details, e.g. supports, auxiliary layers
- G03F7/091—Photosensitive materials characterised by structural details, e.g. supports, auxiliary layers characterised by antireflection means or light filtering or absorbing means, e.g. anti-halation, contrast enhancement
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
- H01L21/18—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
- H01L21/30—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26
- H01L21/31—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26 to form insulating layers thereon, e.g. for masking or by using photolithographic techniques; After treatment of these layers; Selection of materials for these layers
- H01L21/3105—After-treatment
- H01L21/311—Etching the insulating layers by chemical or physical means
- H01L21/31127—Etching organic layers
- H01L21/31133—Etching organic layers by chemical means
- H01L21/31138—Etching organic layers by chemical means by dry-etching
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
- H01L21/18—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
- H01L21/30—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26
- H01L21/31—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26 to form insulating layers thereon, e.g. for masking or by using photolithographic techniques; After treatment of these layers; Selection of materials for these layers
- H01L21/3205—Deposition of non-insulating-, e.g. conductive- or resistive-, layers on insulating layers; After-treatment of these layers
- H01L21/321—After treatment
- H01L21/3213—Physical or chemical etching of the layers, e.g. to produce a patterned layer from a pre-deposited extensive layer
- H01L21/32133—Physical or chemical etching of the layers, e.g. to produce a patterned layer from a pre-deposited extensive layer by chemical means only
- H01L21/32135—Physical or chemical etching of the layers, e.g. to produce a patterned layer from a pre-deposited extensive layer by chemical means only by vapour etching only
- H01L21/32136—Physical or chemical etching of the layers, e.g. to produce a patterned layer from a pre-deposited extensive layer by chemical means only by vapour etching only using plasmas
- H01L21/32137—Physical or chemical etching of the layers, e.g. to produce a patterned layer from a pre-deposited extensive layer by chemical means only by vapour etching only using plasmas of silicon-containing layers
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
- H01L21/18—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
- H01L21/30—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26
- H01L21/31—Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26 to form insulating layers thereon, e.g. for masking or by using photolithographic techniques; After treatment of these layers; Selection of materials for these layers
- H01L21/3205—Deposition of non-insulating-, e.g. conductive- or resistive-, layers on insulating layers; After-treatment of these layers
- H01L21/321—After treatment
- H01L21/3213—Physical or chemical etching of the layers, e.g. to produce a patterned layer from a pre-deposited extensive layer
- H01L21/32139—Physical or chemical etching of the layers, e.g. to produce a patterned layer from a pre-deposited extensive layer using masks
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/027—Making masks on semiconductor bodies for further photolithographic processing not provided for in group H01L21/18 or H01L21/34
- H01L21/0271—Making masks on semiconductor bodies for further photolithographic processing not provided for in group H01L21/18 or H01L21/34 comprising organic layers
- H01L21/0273—Making masks on semiconductor bodies for further photolithographic processing not provided for in group H01L21/18 or H01L21/34 comprising organic layers characterised by the treatment of photoresist layers
- H01L21/0274—Photolithographic processes
- H01L21/0276—Photolithographic processes using an anti-reflective coating
Landscapes
- Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Power Engineering (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- Manufacturing & Machinery (AREA)
- Computer Hardware Design (AREA)
- Microelectronics & Electronic Packaging (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Chemical & Material Sciences (AREA)
- Architecture (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Structural Engineering (AREA)
- Plasma & Fusion (AREA)
- Materials For Photolithography (AREA)
- Exposure Of Semiconductors, Excluding Electron Or Ion Beam Exposure (AREA)
- Photosensitive Polymer And Photoresist Processing (AREA)
- Exposure And Positioning Against Photoresist Photosensitive Materials (AREA)
- Drying Of Semiconductors (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP09568198A JP3955385B2 (ja) | 1998-04-08 | 1998-04-08 | パターン形成方法 |
| JP98-95681 | 1998-04-08 | ||
| PCT/JP1999/001792 WO1999053378A1 (fr) | 1998-04-08 | 1999-04-05 | Procede de formation de motif |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| KR20010013561A KR20010013561A (ko) | 2001-02-26 |
| KR100632196B1 true KR100632196B1 (ko) | 2006-10-11 |
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| Application Number | Title | Priority Date | Filing Date |
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| KR1019997011568A Expired - Lifetime KR100632196B1 (ko) | 1998-04-08 | 1999-04-05 | 패턴 형성방법 |
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| Country | Link |
|---|---|
| US (1) | US6527966B1 (enExample) |
| EP (1) | EP0989460B1 (enExample) |
| JP (1) | JP3955385B2 (enExample) |
| KR (1) | KR100632196B1 (enExample) |
| CN (2) | CN1273865C (enExample) |
| DE (1) | DE69942409D1 (enExample) |
| TW (1) | TWI227812B (enExample) |
| WO (1) | WO1999053378A1 (enExample) |
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| JP3955384B2 (ja) * | 1998-04-08 | 2007-08-08 | Azエレクトロニックマテリアルズ株式会社 | 化学増幅型レジスト組成物 |
| JP4272805B2 (ja) * | 1999-12-27 | 2009-06-03 | 富士フイルム株式会社 | ポジ型感放射線性組成物 |
| JP4562240B2 (ja) * | 2000-05-10 | 2010-10-13 | 富士フイルム株式会社 | ポジ型感放射線性組成物及びそれを用いたパターン形成方法 |
| EP1179750B1 (en) | 2000-08-08 | 2012-07-25 | FUJIFILM Corporation | Positive photosensitive composition and method for producing a precision integrated circuit element using the same |
| US6605394B2 (en) | 2001-05-03 | 2003-08-12 | Applied Materials, Inc. | Organic bottom antireflective coating for high performance mask making using optical imaging |
| US6703169B2 (en) | 2001-07-23 | 2004-03-09 | Applied Materials, Inc. | Method of preparing optically imaged high performance photomasks |
| US6760153B2 (en) * | 2001-11-26 | 2004-07-06 | Nortel Networks Limited | Optical component with signal amplification |
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- 1999-04-05 CN CNB998004960A patent/CN1273865C/zh not_active Expired - Lifetime
- 1999-04-05 DE DE69942409T patent/DE69942409D1/de not_active Expired - Lifetime
- 1999-04-05 WO PCT/JP1999/001792 patent/WO1999053378A1/ja not_active Ceased
- 1999-04-05 CN CNB2005101346188A patent/CN100476594C/zh not_active Expired - Lifetime
- 1999-04-05 KR KR1019997011568A patent/KR100632196B1/ko not_active Expired - Lifetime
- 1999-04-05 US US09/445,346 patent/US6527966B1/en not_active Expired - Lifetime
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Also Published As
| Publication number | Publication date |
|---|---|
| CN1811600A (zh) | 2006-08-02 |
| US6527966B1 (en) | 2003-03-04 |
| WO1999053378A1 (fr) | 1999-10-21 |
| CN100476594C (zh) | 2009-04-08 |
| TWI227812B (en) | 2005-02-11 |
| EP0989460A1 (en) | 2000-03-29 |
| DE69942409D1 (enExample) | 2010-07-08 |
| EP0989460B1 (en) | 2010-05-26 |
| CN1273865C (zh) | 2006-09-06 |
| EP0989460A4 (en) | 2001-10-24 |
| JPH11295888A (ja) | 1999-10-29 |
| CN1263611A (zh) | 2000-08-16 |
| KR20010013561A (ko) | 2001-02-26 |
| JP3955385B2 (ja) | 2007-08-08 |
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