KR100272624B1 - Fireproofing and sound-absorbing composition - Google Patents

Fireproofing and sound-absorbing composition Download PDF

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KR100272624B1
KR100272624B1 KR1019980017649A KR19980017649A KR100272624B1 KR 100272624 B1 KR100272624 B1 KR 100272624B1 KR 1019980017649 A KR1019980017649 A KR 1019980017649A KR 19980017649 A KR19980017649 A KR 19980017649A KR 100272624 B1 KR100272624 B1 KR 100272624B1
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sound
absorbing
fire
weight
coating composition
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KR19990085310A (en
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정상옥
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손연호
주식회사삼손퍼라이트
주식회사삼손
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Priority to KR1019980017649A priority Critical patent/KR100272624B1/en
Priority to JP12760399A priority patent/JP2000001380A/en
Priority to CNB99106707XA priority patent/CN1175062C/en
Priority to DE1999122247 priority patent/DE19922247A1/en
Publication of KR19990085310A publication Critical patent/KR19990085310A/en
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    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
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    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
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    • C04B14/00Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B14/02Granular materials, e.g. microballoons
    • C04B14/04Silica-rich materials; Silicates
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    • C04B22/00Use of inorganic materials as active ingredients for mortars, concrete or artificial stone, e.g. accelerators, shrinkage compensating agents
    • C04B22/008Cement and like inorganic materials added as expanding or shrinkage compensating ingredients in mortar or concrete compositions, the expansion being the result of a recrystallisation
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    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
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    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/50Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
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    • C04B2103/00Function or property of ingredients for mortars, concrete or artificial stone
    • C04B2103/0068Ingredients with a function or property not provided for elsewhere in C04B2103/00
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    • C04B2103/0092Organic co-binders for mineral binder compositions for improving green strength
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    • C04B2103/20Retarders
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    • C04B2103/40Surface-active agents, dispersants
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    • C04B2103/00Function or property of ingredients for mortars, concrete or artificial stone
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    • C04B2111/00482Coating or impregnation materials
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    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/20Resistance against chemical, physical or biological attack
    • C04B2111/28Fire resistance, i.e. materials resistant to accidental fires or high temperatures
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/91Use of waste materials as fillers for mortars or concrete

Abstract

PURPOSE: A fire-retardant and sound-absorbent coating composition is provided to prevent releasing of the coating material from the subject substrate with causing no shrinkage, crack and peeling off of the coating material even at extinguishing fire by comprising particular composition of respective constructional materials. CONSTITUTION: The composition comprises 25-60 wt.% of light aggregates, 20-60 wt.% of binder, less than 50 wt.% of heat-absorbent material, 5-30 wt.% of bulky agent and 2-20 wt.% of carbonating sound-absorbing fiber. The composition further is added with at least one of additives, for instance, less than 1.5 wt.% of surfactant, 5 wt.% or less of thickener, less than 2 wt.% of reinforcing agent, 2 wt.% or less of delaying agent and/or less than 1 wt.% of anti-bacterial agent. The coating composition is applied to surface of structural frame of buildings and/or constructional subjects to improve hardness and internal intensity, and/or sound-insulation effects of them.

Description

내화 흡음용 피복 조성물Fireproof Sound Absorbing Coating Composition

본 발명은 내화 흡음용 피복 조성물에 관한 것으로서, 보다 상세하게는 건축물의 철골구조물 표면에 분무 코팅하여 화재시 고열에 의한 철골의 강도 및 내력저하를 방지할 수 있고 또한 건축물의 벽면이나 천장 등에 분무 코팅하여 음향절연성을 부여할 수 있는 내화 흡음용 피복 조성물에 관한 것이다. 현대사회가 빠르게 도시화되어 인구 밀집 지역이 늘어감에 따라 좁은 지역에서 많은 사람들이 살아가기 위한 방편으로 건축물의 고층화 및 대형화가 이루어지고 있으며, 그 수단으로는 대부분 철골구조가 적용되고 있다.The present invention relates to a coating composition for fire-absorbing sound absorption, and more particularly, spray coating on the surface of the steel structure of the building to prevent the reduction of strength and strength of the steel frame due to high heat in the event of fire and also spray coating on the wall or ceiling of the building The present invention relates to a coating composition for fire-absorbing sound absorption which can provide acoustic insulation. As the modern society is rapidly urbanized and the population density is increasing, high-rise and large-scale buildings are being used as a means for many people to live in small areas, and most of them are steel structures.

하지만 철골구조를 그대로 대형화된 고층건물에 적용하면, 건물 화재시 화염 및 내장재가 타면서 뿜어내는 유독가스 등에 의해 인명 피해가 발생할 위험이 있을 뿐만 아니라 고열에 의해 철골구조물의 강도와 내력이 떨어져 건물이 자체 하중을 견디지 못하고 붕괴될 위험이 있다. 따라서 철골구조물의 표면에는 내화재를 피복하게 된다.However, if the steel structure is applied to a large-scale high-rise building as it is, there is a risk of human injury due to the toxic gas emitted by the flame and the interior material when the building fires, and the strength and strength of the steel structure are degraded due to the high temperature. There is a risk of failure to withstand its own load. Therefore, the fire resistant material is coated on the surface of the steel structure.

기존의 내화 피복재에 대해 구체적으로 설명하면 다음과 같다.Referring to the existing refractory coating materials in detail as follows.

내화 피복재는 주성분에 따라 퍼라이트계, 질석계, 암면계 및 이들의 혼합계로 구분될 수 있으며, 그 피복방법은 내화성 성형물은 설치하는 방법과 수성페이스트(슬러리)를 분무 코팅하는 방법으로 분류될 수 있다.Refractory coating materials may be classified into perlite, vermiculite, rock wool and mixed systems according to the main components, and the coating method may be classified into a method of installing a refractory molding and spray coating of an aqueous paste (slurry). .

그 동안 내화 피복재는 내화 성능 면에서 큰 발전이 있었다. 특히 내열성 향상 위주의 기술적 발전, 즉 고온에서 흡열 기능을 가지는 재료들을 사용함으로서 내화성능이 크게 향상되었다. 여기서 고온에서 흡열 기능을 가지는 재료들은 화재시 주위의 열을 빼앗으면서 자체의 결합이 분해(결합수의 탈수 혹은 탄산가스의 발생)되는 것으로 화염이 철골로 전도되는 것을 방지하는 역할을 하여 내화 피복재의 내화 성능을 향상시키게 된다. 그러나 흡열 기능을 가지는 재료들은 고온에서 주위의 열을 빼앗는 반면에 결합수의 탈수 혹은 탄산가스로의 전환 등과 아울러 체적의 급격한 감소를 동반하게 된다. 이로서 피복재는 체적 변화에 의해 대형 균열 및 피착면으로부터 들뜨는 현상이 발생하고, 심한 경우에는 화재시 피복재가 탈락됨으로써 피착면 특히 철골이 화재에 노출되어 강도와 내력 저하를 가져오게된다.In the meantime, fireproof coating materials have made great progress in terms of fire resistance performance. In particular, the technical development mainly to improve the heat resistance, that is, by using materials having an endothermic function at a high temperature, the fire resistance is greatly improved. Here, materials that have an endothermic function at high temperatures decompose their bonds (dehydration of bound water or generation of carbon dioxide gas) while taking away the heat of a fire, which serves to prevent the flame from conducting to steel frame. It will improve the fire resistance performance. However, materials having an endothermic function take away the heat of the surroundings at high temperatures, while accompanied by a drastic decrease in volume along with dehydration of the bound water or conversion to carbon dioxide gas. As a result, the coating material is lifted from the large crack and the adhered surface due to the volume change, and in severe cases, the coating material is dropped during the fire, thereby exposing the adhered surface, especially steel, to the fire, resulting in a decrease in strength and strength.

이러한 문제점 때문에 일부에서는 무기섬유를 사용하여 이를 해결코자 하였지만, 무기섬유중에 암면이나 유리섬유는 인체의 피부 등을 자극하여 심한 경우 발진의 원인이 되고, 세피오라이트 등은 고온에서 완전히 분해하지 않아 화재시 피복재에 작용하여 체적 변화를 일으키는 응력을 완전하게 제거하지 못하는 문제점을 갖고 있다.In order to solve this problem, some use inorganic fiber to solve this problem, but rock wool or glass fiber in the inorganic fiber irritates the skin of the human body and causes rash in severe cases. There is a problem in that it is not possible to completely remove the stress acting on the volume change.

이를 기존에 공개된 문헌을 통해 살펴보면 다음과 같다.Looking at this through the previously published literature is as follows.

한국 특허공고 94-9412호, 한국 특허공고 89-4281호, 일본 특허공개 평6-32666호, 일본 특허공개 평6-32667호, 일본 특허공개 평6-80909호 및 일본 특허 공고 평6-99177호에 등에 개시된 피복재는 무기섬유(암면, 유리섬유 등)를 사용하므로 피부자극 등을 일으켜 인체에 유해하다.Korean Patent Publication No. 94-9412, Korean Patent Publication No. 89-4281, Japanese Patent Publication No. Hei 6-32666, Japanese Patent Publication No. Hei 6-32667, Japanese Patent Publication No. Hei 6-80909 and Japanese Patent Publication Hei 6-99177 Since the coating | covering material disclosed in this issue uses inorganic fiber (rock wool, glass fiber, etc.), it causes skin irritation, etc., and is harmful to a human body.

한국 특허공고 92-3227호, 일본 특허공개 평6-32666호 및 동6-32667호에 개시된 피복재는 재유화형 분말수지가 다량으로 함유되어 있어 건물의 화재시 피복재로부터 유독가스가 다량 발생되어 인체에 매우 유해하며, 재유화형 분말수지를 소량으로 사용하는 경우에는 마이크로 균열을 유도하기 어렵고, 중, 대형 균열이 발생키 쉽다는 단점이 있다. 또한 일본 특허공개 평6-32666호의 미소성 질석을 사용하는 경우에는 화재시 팽창되는 질석의 응력을 제어하기가 어렵기 때문에 이 또한 중,대형 균열의 원인으로 작용할 수 있다.The coating materials disclosed in Korean Patent Publication Nos. 92-3227, 6-32666, and 6-32667 contain a large amount of re-emulsified powder resin, which generates a large amount of toxic gas from the coating in case of fire in a building. It is very harmful, when using a small amount of re-emulsified powder resin it is difficult to induce micro cracks, there is a disadvantage that it is easy to generate medium and large cracks. In addition, when using the unbaked vermiculite of Japanese Patent Application Laid-Open No. 6-32666, since it is difficult to control the stress of vermiculite which is expanded during a fire, this may also act as a cause of medium and large cracks.

일본 특허공개 평3-100243호에 개시된 피복재는 흡열재의 양이 적어 내화 성능이 떨어지므로 내화시간 1시간에 요구되는 두께가 30㎜로 매우 두껍고, 일본 특허공고 평5-20375호는 흡열재의 양이 많아 내열 성능은 향상되었으나 밀도가 0.7로 높고 고온에서 흡열재에 의한 수축이 커서 팽창재로 코팅된 입상의 규산소다를 사용하였지만 팽창재의 과다 사용으로 고온에서 팽창 및 수축의 균형을 이루지 못해 수축 팽창에 의한 피복재의 탈락이 발생함은 물론 코팅된 입상의 규산소다의 제조가 용이치 않아 경제성에도 문제가 있다.Since the coating material disclosed in Japanese Patent Application Laid-Open No. 3-100243 has a small amount of heat absorbing material, which is inferior in fire resistance performance, the thickness required for one hour of fire resistance is 30 mm, which is very thick, and Japanese Patent Publication No. Hei 5-20375 has a large amount of heat absorbing material. The heat-resistance performance was improved, but the density was high as 0.7 and the shrinkage by the heat absorbing material was high, so that granular sodium silicate coated with the expanding material was used, but the expansion and contraction at high temperature could not be balanced due to the expansion of shrinkage due to the excessive use of the expanding material. Falling of the coating material occurs as well as the production of coated granular sodium silicate is not easy, there is a problem in economic efficiency.

아울러 일본 특허공고 평7-13380호에는 일본 특허공고 평5-20375호에서의 문제점을 개선키 위하여 피복재에 유리섬유를 사용하고 있고, 유럽 특허공고 661241호에 개시된 결합수를 포함한 골재를 제조하여 사용하는 형태의 피복재 조성물에서도 시멘트를 40% 이상 사용함으로서 건조수축 및 열간에서 결합수가 탈락되어 수축을 유발하면서 발생하는 피복재의 탈락 및/또는 박리 현상을 해결하기 위하여 인체에 유해한 유리섬유를 사용하고 있어 현장 사업자가 기피하는 문제점을 가지고 있다.In addition, Japanese Patent Publication No. 7-13380 uses glass fiber as a coating material to improve the problems in Japanese Patent Publication No. 5-20375, and manufactures and uses aggregates including binding water disclosed in European Patent Publication No. 661241. In the coating composition, which is used in the form of cement, more than 40% of cement is used to solve the dropping and / or peeling phenomenon of the coating material which is caused by the dry water shrinkage and the bond water dropping out during the shrinkage and the hot air. There are problems that operators avoid.

이와 같이 종래의 내화 피복재는 건조 수축 및 열간 수출에 대한 해결책으로서 암면 혹은 유리섬유 등 무기섬유를 사용하여 이를 해결코자 하였지만, 이러한 무기섬유들은 인체에 유해하고, 다른 방법으로 섬유류를 사용하지 않은 경우에는 팽창재를 사용하여 수축에 의한 균열을 방지코자 하였지만 그 균형을 이루기가 용이치 않은 문제점을 가지고 있다.As described above, the conventional fireproof coating material is intended to solve the problem by using inorganic fibers such as rock wool or glass fiber as a solution for dry shrinkage and hot export. However, when these inorganic fibers are harmful to the human body and the fiber is not used in any other way, Although an expansion material is used to prevent cracking by shrinkage, there is a problem that the balance is not easy to achieve.

한편, 흡음 피복재(흡음재)는 시공 형태에 따라 건축물의 천장, 벽면 및 바닥 등에 매설하는 매트형과 분무 피복하는 분무형 피복재로 분류될 수 있다. 또한 재료의 조성에 따라 고주파대에서 흡음율이 우수한 다공성 흡음재와 저주파대에서 흡음율이 우수한 판진동형 및 공명형 흡음재로 분류될 수 있다.On the other hand, the sound absorbing coating material (absorption material) may be classified into a mat-type and a spray-type coating material for spray coating embedded in the ceiling, wall and floor of the building according to the construction form. In addition, according to the composition of the material can be classified into a porous sound absorbing material having a good sound absorption at high frequency band and a plate vibration type and resonant sound absorbing material having a good sound absorption at low frequency band.

이중에 분무형 흡음재는 무기섬유, 결합제, 증점제, 광유 및 기타 유기 첨가제 등을 혼합하여 제조하거나, 질석 또는 식물성 화이버 등을 주재로 이용하여 제조한다. 그러나 이들은 모두 일정한 흡음과 단열의 효과는 얻을 수 있지만, 전자는 무기섬유가 작업상 분진 발생의 위험이 있기 때문에 취급에 주의해야 함은 물론 분무 후 충분한 강도를 얻기 위해 다짐작업을 해야 하는 등 번거로움이 따른다.The spray-type sound absorbing material is prepared by mixing inorganic fibers, binders, thickeners, mineral oils and other organic additives, or using vermiculite or vegetable fibers as a main component. However, they all have the effect of constant sound absorption and heat insulation, but the former has to be handled with care because of the risk of dust generation in the inorganic fiber, and it is cumbersome to compact to obtain sufficient strength after spraying. This follows.

최근에는 각종 소음으로부터 쾌적한 실내 환경을 조성하기 위한 흡음재의 개발이 지속적으로 이루어지고 있으며 이러한 흡음재의 개발은 내화 및 단열의 효과를 함께 얻을 수 있는 방향으로 이루어지고 있다.Recently, development of sound absorbing materials for creating a pleasant indoor environment from various noises has been made continuously, and the development of such sound absorbing materials has been made in a direction to obtain the effects of fire resistance and heat insulation.

따라서 본 발명도 선행 기술에서 나타나는 내화 피복재와 흡음 피복재의 문제점을 해결하고자 한 것으로, 그 목적은 화재시 피복재의 대형 균열이나 피착면으로부터의 탈락을 방지하여 철골의 화재에 대한 안전성을 극대화하여 최소의 피복두께로서 우수한 내화 및 흡음 성능을 발휘할 수 있도록 한 내화 흡음용 피복 조성물을 제공하는 데에 있다.Therefore, the present invention is also intended to solve the problems of the fire-resistant cladding and sound-absorbing cladding appearing in the prior art, the object of which is to prevent the large crack of the cladding or falling off from the adhered surface in the case of fire to maximize the safety of the steel fire to minimize An object of the present invention is to provide a coating composition for fire resistance and sound absorption which can exhibit excellent fire resistance and sound absorption performance as a coating thickness.

이러한 본 발명의 목적을 달성하기 위한 내화 흡음용 피복 조성물은 경량골재 25∼60중량%, 결합재 20∼60중량%, 흡열재 50중량%이하, 팽창재 5∼30중량%, 및 탄화성 흡음섬유 2∼20중량%를 포함하는 데에 특징이 있다.The coating composition for fire-absorbing sound absorption for achieving the object of the present invention is 25 to 60% by weight of the lightweight aggregate, 20 to 60% by weight of the binder, 50% by weight or less of the heat absorbing material, 5 to 30% by weight of the expandable material, and carbonizable sound absorbing fiber 2 It is characteristic to contain -20 weight%.

아울러 본 발명의 내화 및 흡음용 피복 조성물은 선택적으로 분무 코팅 작업시 슬러리의 분산성, 공기 연행 효과 및 윤활성 등의 물리적 성질을 향상시키기 위한 계면활성제를 전체의 1.5중량% 이내로, 그리고 시공 수율의 향상과 건조시 피복층 표면의 미미한 균열을 방지하기 위한 증점제를 전체의 5중량% 이내로, 그리고 특별한 강도의 발현이 요구되어지는 장소에 사용키 위한 강도보강재를 전체의 2중량% 이내로, 그리고 충분한 작업시간을 부여키 위한 지연제를 전체의 2중량% 이내로, 그리고 곰팡이나 균류로부터의 방균 및 항균을 목적으로 항균제를 전체의 1중량% 이내로 더 사용할 수 있다.In addition, the coating composition for fire resistance and sound absorption of the present invention optionally has a surfactant for improving physical properties such as dispersibility, air entraining effect, and lubricity of the slurry during spray coating, within 1.5% by weight of the whole, and improving construction yield. Within 5% by weight of the thickener to prevent minor cracks on the surface of the coating layer during drying, and within 2% by weight of the strength reinforcing material for use in places where special strength is required, and sufficient working time Retardants for imparting may be used within 2% by weight of the total, and antimicrobial agents within 1% by weight of the total for the purpose of antibacterial and antibacterial from fungi or fungi.

이와 같이 조성되는 본 발명의 내화 및 흡음용 피복 조성물은 분무시공 후 건조에 의한 수축, 균열 및 탈락이 없으며, 화재시 팽창재에 의해 수축을 방지함은 물론 탄화성 흡음섬유에 의해서 마이크로 균열을 유도하여 열용량이 큰 결합재나 흡열재의 수축에 의한 응력을 분산처리함으로서 대형 균열을 방지하고 피복재의 탈락을 방지하여 화재진압시까지도 피복재의 형태가 그대로 유지되어 충분한 내화성능을 발휘할 수 있다.The coating composition for fire resistance and sound absorption of the present invention thus formed is free from shrinkage, cracking and dropping by drying after spraying, and prevents shrinkage by expanding material in the fire and of course induces micro cracking by the carbonizable sound absorbing fiber. By dispersing stress caused by shrinkage of binder or heat absorber with large heat capacity, it prevents large cracks and prevents the coating from falling off, and maintains the shape of coating even when fire is extinguished.

본 발명의 내화 및 흡음용 피복 조성물의 원료 및 이들의 작용에 대해 상세히 설명하다.The raw material of the coating composition for fireproof and sound absorption of this invention, and its action are demonstrated in detail.

경량골재로는 크기 4∼200 메쉬의 것으로, 팽창 혹은 미팽창된 퍼라이트, 경석, 질석, 화산재, 부석 등과 같이 천연의 광물질과; 인공적으로 유리계나 광물질에 기공을 함유케하여 제조한 중공구체; 및, 입상발포폴리스티렌과 파쇄발포폴리스티렌으로 구성된 유기질 골재를 단독 또는 2종 이상 혼합하여 사용한다.Lightweight aggregates of 4 to 200 mesh in size include natural minerals such as expanded or unexpanded perlite, pumice, vermiculite, volcanic ash, pumice and the like; Hollow spheres made by artificially containing pores in glass or mineral materials; And an organic aggregate composed of granular foamed polystyrene and crushed foamed polystyrene, alone or in combination of two or more thereof.

위에 열거한 경량골재는 비중이 0.01∼0.8g/cc로서 가볍기 때문에 건축물에 대한 하중 부담이 경감된다. 또한 경량골재는 무수히 많은 작은 기공들이 형성되어 있어 열전도율(0.03-0.04㎉/mh℃)이 낮고 이미 널리 알려진 바와 같이 흡음성, 단열성 및 강도 면에서 매우 뛰어나 피복재의 내화, 단열 및 흡음 성능을 향상시킨다. 특히 퍼라이트는 식물 첨가물로 쓰일 정도로 인체에 대한 유독성이 없으므로 보다 친화적이다.The light weight aggregates listed above are light, with a specific gravity of 0.01 to 0.8 g / cc, reducing the load on buildings. In addition, the lightweight aggregate has a number of small pores are formed to have a low thermal conductivity (0.03-0.04㎉ / mh ℃) and as already well known in terms of sound absorption, heat insulation and strength is very good, improving the fire resistance, insulation and sound absorption performance of the coating material. Perlite, in particular, is more friendly because it is not toxic to the human body as a plant additive.

이러한 경량골재는 본 발명의 피복 조성물에 60중량% 이상 포함되면 분무 시공된 피복재의 밀도와 열전도율이 낮아지는 이점은 있으나 부착력과 강도가 떨어지고, 25중량% 이하로 포함되면 부착력과 강도는 우수해지나 분무 시공된 피복재의 밀도 및 열전도율이 높아지게 되므로 전체에 대하여 25∼60중량%의 범위로 사용하는 것이 바람직하다.Such lightweight aggregates have the advantage of lowering the density and thermal conductivity of the sprayed coating material when it is included in the coating composition of the present invention more than 60% by weight, but the adhesion and strength is lowered, when included in less than 25% by weight, the adhesion and strength is excellent Since the density and the thermal conductivity of the coating material sprayed become high, it is preferable to use it in the range of 25 to 60 weight% with respect to the whole.

결합재는 경량골재 상호간 및 경량골재와 철골 구조물의 표면(또는 건축물의 천정이나 벽면 등 피착면)이 원활히 결합되도록 하는 재료로서, 포틀랜드 시멘트, 고로 시멘트, 실리카 시멘트, 알루미나 시멘트, 마그네시아 시멘트로 구성된 시멘트류 또는 이수석고, 반수석고, 석고플라스터로 구성된 석고류 또는 마그네시아, 황산마그네슘을 1종 이상 혼합하여 사용한다.The binder is a material that allows the lightweight aggregates to be smoothly bonded to each other and to the surface of the steel structure (or the surface of the building or the surface of the building), and cements composed of portland cement, blast furnace cement, silica cement, alumina cement, and magnesia cement. Alternatively, gypsum or magnesia or magnesium sulfate composed of dihydrate gypsum, hemihydrate gypsum and gypsum plaster is used.

이러한 결합재는 본 발명의 조성물에 대하여 60중량% 이상 사용하면 피복재의 부착력과 강도는 우수해지는 반면 밀도와 열전도율이 높아져 내화성능이 떨어지며 또한 화재시 조성물의 응력 발생이 크고 국부적으로 응력이 집중되어 대형 균열의 요인으로 작용하게 되며, 20중량% 이하로 사용하면 피복재의 밀도 및 열전도율이 낮아지는 반면 부착력과 강도가 떨어지므로, 전체에 대하여 20∼60중량%로 사용한다.When the binder is used in an amount of 60% by weight or more with respect to the composition of the present invention, the adhesion and strength of the coating material are excellent, while the density and thermal conductivity are increased, so that the fire resistance is decreased. When used at 20% by weight or less, the density and thermal conductivity of the coating material decreases while the adhesion and strength decreases, so 20 to 60% by weight of the total is used.

흡열재는 탄산칼슘, 소석회, 생석회 등의 석회류; 이수석고, 반수석고, 석고 플라스터 등의 석고류; 수산화알루미늄; 황산알루미늄; 붕사; 탄산마그네슘; 수산화마그네슘; 몬모릴로나이트; 벤토나이트; 탄산수소나트륨; 규산나트륨; 혹은 가스 화합물이나 혹은 상기 흡열재을 사용하여 1차 가공한 분말상 또는 골재상태인 인공 흡열재를 1종 이상 혼합하여 사용한다. 상기에서 인공흡열재는 보다 흡열성을 높이기 위한 것으로 고온에서 결합수 혹은 탄산가스가 발생하여 외부의 열을 흡수토록 한 것으로서, 구체적으로 각 흡열재의 흡열량은 다음과 같다;The heat absorbing material includes limes such as calcium carbonate, slaked lime and quicklime; Gypsum such as dihydrate gypsum, hemihydrate gypsum and gypsum plaster; Aluminum hydroxide; Aluminum sulfate; borax; Magnesium carbonate; Magnesium hydroxide; Montmorillonite; Bentonite; Sodium bicarbonate; Sodium silicate; Alternatively, one or more kinds of artificial heat absorbing materials in the form of a powder or aggregate, which are primarily processed using a gas compound or the heat absorbing material, may be used. In the above, the endothermic material is to increase the endothermic ability to absorb the external heat by the generation of the combined water or carbon dioxide gas at a high temperature, specifically, the endothermic amount of each endothermic material is as follows;

수산화알루미늄: CaO + H2O ⇔ Ca(OH)2+ 15,600㎉/㏖Aluminum hydroxide: CaO + H 2 O ⇔ Ca (OH) 2 + 15,600 dl / mol

석고: CaSO4 + H2O ⇔ CaSO4·2H2O +(4,000∼7,000)㎉/㏖Gypsum: CaSO 4 + H 2 O ⇔ CaSO 4 · 2H 2 O + (4,000 ~ 7,000) ㎉ / mol

수산화마그네슘: MgO + H2O ⇔ Mg(OH)2+ 8840㎉/㏖Magnesium hydroxide: MgO + H 2 O ⇔ Mg (OH) 2 + 8840 dl / mol

붕사: Na2B4O7+ 10H2O ⇔ Na2B4O7·10H2O +(400∼3,800)㎉/㏖Borax: Na 2 B 4 O 7 + 10 H 2 O ⇔ Na 2 B 4 O 7 10 H 2 O + (400-3,800) ㎉ / mol

탄산수소나트륨: Na2CO3+ H2O + CO2⇔ 2NaHCO + 63,000㎉/㏖Sodium bicarbonate: Na 2 CO 3 + H 2 O + CO 2 ⇔ 2NaHCO + 63,000 dl / mol

수산화알루미늄: Al2O3+ 3H2O ⇔ 2Al(OH)3+ 200㎉/㏖Aluminum hydroxide: Al 2 O 3 + 3H 2 O ⇔ 2Al (OH) 3 + 200 ㎉ / mol

규산나트륨: Na2O·nSiO2+ mH2O ⇔ Na2O·nSiO2·mH2O + 1,800㎉/㏖Sodium silicate: Na2O · nSiO 2 + mH 2 O ⇔ Na 2 O · nSiO 2 · mH 2 O + 1,800㎉ / ㏖

몬모릴로나이트: 팽창성 3층판으로 이루어져 팽윤특성을 지니며, 가소성이 매우 높은 점토광물로 칼슘계와 소듐계로 나뉘고, 100℃ 부근에서 H2O를 방출한다.Montmorillonite: It is composed of an expandable three-layered plate and has swelling characteristics. It is a highly plastic clay mineral divided into calcium-based and sodium-based, and emits H 2 O at around 100 ° C.

벤토나이트: 통상 90% 이상의 몬모릴로나이트를 포함하는 것으로 몬모릴로나이트와 같음.Bentonite: Contains 90% or more of montmorillonite, the same as montmorillonite.

상기와 같은 물질들이 결합수의 탈수 혹은 탄산가스의 방출로 인해 흡열반응을 동반하게 됨으로써 기능적으로 내화 흡음용 피복 조성물에서 외부의 열환경으로부터 열을 흡수하게 됨으로써 내화 흡음용 피복 조성물의 열용량을 증대시켜주는 역할을 하게 되어 조성물의 내화성능을 향상시키게 된다. 보다 구체적으로 설명하면 200℃ 이하에서 분해하여 수증기 가스층의 형성에 따른 흡열작용은 갖게 되는 것으로는 석고류인 반수석고, 석고플라스터 등이며, 내화 흡음 피복조성물 형성시에 물의 존재하에 이수석고와 반수석고로서 존재하며, 미약한 결합수를 함유하는 것으로서는 몬모릴나이트, 벤토나이트, 규산나트륨 등이 이에 해당된다.Such materials are accompanied by an endothermic reaction due to dehydration of bound water or release of carbon dioxide gas, thereby functionally absorbing heat from the external thermal environment in the fireproof sound absorbing coating composition, thereby increasing the heat capacity of the fireproof sound absorbing coating composition. It serves to improve the fire resistance of the composition. More specifically, the endothermic effect of the decomposition of the gas at 200 ° C. or lower, and the formation of the vapor gas layer, is the gypsum, such as hemihydrate gypsum and gypsum plaster. Existing and containing the weak bonding water is montmorillonite, bentonite, sodium silicate and the like.

그리고, 500℃ 이하에서 분해하여 수증기 가스층의 형성에 따른 흡열작용을 갖게 되는 것으로는 석회류인 소석회, 생석회 등으로, 내화 흡음 피복조성물 형성시에 물의 존재하에 규산 등의 화합물과 결합하여 존재한다.In addition, it is decomposed at 500 ° C. or lower, and has an endothermic effect due to the formation of a water vapor gas layer, which is a lime lime, quicklime, or the like, which is present in combination with a compound such as silicic acid in the presence of water during formation of a refractory sound-absorbing coating composition.

700℃ 이하에서 분해하여 수증기가스층 및 탄산가스층의 형성에 따른 흡열작용을 갖게 되는 것으로는 탄산수소나트륨을 들 수 있으며, 800℃ 이하에서 결합수의 분해에 의한 수증기가스층의 형성에 따른 흡열작용을 갖게 되는 것으로는 수산화 화합물인 수산화알루미늄, 수산화마그네슘을 들 수 있다. 그리고, 1000℃ 이하에서 분해하여 탄산가스층의 형성에 따른 흡열작용을 갖게 되는 것으로서는 탄산염화물인 탄산칼슘, 탄산마그네슘을 들 수 있다.Examples of the endothermic effect of the decomposition of the water vapor gas layer and the carbon dioxide gas layer by decomposition at 700 ° C. include sodium hydrogen carbonate, and the endothermic action of the formation of the water vapor gas layer by decomposition of the bound water at 800 ° C. or less. As what is mentioned, aluminum hydroxide and magnesium hydroxide which are hydroxide compounds are mentioned. In addition, examples of decomposing at 1000 ° C. or lower to have an endothermic effect due to the formation of a carbon dioxide gas layer include calcium carbonate and magnesium carbonate, which are carbonates.

상기와 같이 온도의 상승과 더불어 탈수 혹은 결합수의 방출로 인한 흡열작용과 탄산가스의 발생으로 인한 흡열작용 등이 흡열재가 가지는 성질이다.As described above, the endothermic action of the endothermic material due to the endothermic action due to the dehydration or release of the combined water and the generation of carbon dioxide gas is the property of the endothermic material.

이러한 흡열재는 내화 및 흡음용 피복 조성물이 철골이나 건축물의 피착면에 피복된 후 화재시 열을 흡수하여 결정수 혹은 탄산가스를 방출시키면서 철골구조물 혹은 건축물 피착면의 급격한 온도 상승을 저하시키는 데에 유효하게 작용한다. 즉, 흡열재는 다른 원재료와 함께 철골 구조물에 대한 열차단 효과를 가져오기 때문에 피복 조성물의 내화 성능을 한층 더 향상시키게 된다.This heat absorbing material is effective to reduce the rapid rise in temperature of the steel structure or building surface while absorbing heat in the event of fire and absorbing heat in a fire after the fireproof and sound absorption coating composition is coated on the steel or building surface. It works. In other words, the heat absorbing material, together with other raw materials bring a thermal barrier effect on the steel structure, further improving the fire resistance performance of the coating composition.

이러한 흡열재는 피복 조성물 전체의 50중량% 이상으로 사용하면 내화 성능이 향상되는 반면 흡열재 이외의 피복조성물 각각의 비율이 적어지게 되어 수축의 원인이 되며 나아가 직선적인 대형 균열의 원인이 되고 또한 피복재의 박리와 탈락의 원인이 된다. 따라서 흡열재는 피복재 조성물 전체의 50중량% 이내로 사용하는 것이 바람직하다.When the heat absorbing material is used in more than 50% by weight of the entire coating composition, the fire resistance is improved, while the proportion of each coating composition other than the heat absorbing material decreases, causing shrinkage, and further, causing a large linear crack. This can cause peeling and dropping. Therefore, it is preferable to use a heat absorbing material within 50 weight% of the whole coating material composition.

팽창재는 고온에서 피복조성물이 수축을 일으킬 경우, 체적 감소를 보상해줌으로써 피복재의 외형적 변화를 방지하여 화재가 지속되는 동안 견고하게 철골 등의 피착면을 보호하게 되므로 피복재의 내화성능을 향상시킬 수 있는 물질이며, 구체적으로는 실리카, 마그네시아, 팽창성 미팽창 질석, 팽창성 미창팽 경석, 팽창성 미팽창 퍼라이트, 실리카, 마그네시아, 팽창성 미팽창 질석, 팽창성 미창팽 경석, 팽창성 미팽창 퍼라이트 마그네슘 카보네이트, 실리마나이트(silimanite), 남정석(kyanite), 홍주석(andalusite), 복사이트(bauxite), 파이로필라이트(pyrophylite), 돌로마이트(dolomite), 페릭옥사이드(ferric oxide), 페로페릭옥사이드(ferro-ferric oxide), 페로스 옥사이드(ferrous oxide), 일라이트(illite), 활석(talc), 정장석(orthoclase), 납석(agalmatolite), 지르콘, 탄화규소, 팽창성 미팽창 혈암(shale) 및 팽창성 미팽창 점토 등을 1종 이상 혼합하여 사용한다.The expansion material compensates for the volume reduction when the coating composition contracts at high temperature, thereby preventing the appearance change of the coating material, thus protecting the adhered surface such as steel frame firmly during the fire, thereby improving the fire resistance performance of the coating material. Specifically, silica, magnesia, expandable unexpanded vermiculite, expandable unexpanded pumice, expandable unexpanded perlite, silica, magnesia, expandable unexpanded vermiculite, expandable unexpanded pumice, expandable unexpanded perlite magnesium carbonate, silimite (silimanite), kyanite, andandalusite, bauxite, pyrophylite, dolomite, ferric oxide, ferro-ferric oxide, Ferrous oxide, illite, talc, orthoclase, agalmatolite, zircon, silicon carbide, expandable Swelling shale (shale) and non-expandable expanded clay or the like by mixing at least one member.

일반적으로, 실리카, 마그네시아, 마그네슘 카보네이트, 실리마나이트, 남정석, 홍주석, 복사이트, 파이로필라이트 돌로마이트 또는 활석 등을 10∼30in/in, ℃×106의 열팽창 특성을 가지며, 페릭옥사이드, 페로페릭옥사이드, 페로스 옥사이드, 일라이트, 정장석, 납석, 지르콘, 탄화규소 등은 5∼10 in:/in.℃×106의 열팽창 특성을 가지며, 상기의 팽창재들 모두 내화 흡음용 피복조성물 구성시 고온에서 조성물이 수축을 일으키는 경우 이에 대한 체적 감소를 보상해줌으로써 피복재의 외형적 변화를 방지하여 화재가 지속되는 동안 견고하게 철골 등의 피착면을 보호하게 되므로 피복재의 내화성능을 향상시킬 수 있다.Generally, silica, magnesia, magnesium carbonate, silimite, citrine, red tin, boxite, pyrophyllite dolomite, or talc have thermal expansion properties of 10 to 30 in / in, ℃ 10 6 , ferric oxide, ferro Ferric oxide, ferros oxide, illite, feldspar, lead stone, zircon, silicon carbide, etc., have thermal expansion characteristics of 5 to 10 in: /in.°C×106, and all of the above expandable materials have a high temperature when constructing a fireproof sound absorbing coating composition. When the composition causes the shrinkage to compensate for the reduction in volume by preventing the appearance change of the coating material to protect the adhered surface such as steel firmly during the fire, it is possible to improve the fire resistance performance of the coating material.

팽창재는 내화 흡음용 피복 조성물이 화재시 수축을 일으키는 경우, 이에 대한 체적 감소를 보상해줌으로써 특히, 고온에서 실리카의 체적팽창율이 10% 내외로 철골이나 건축물의 피착면에 피복된 내하 흡음 조성물의 수축에 따른 체적 변화를 조상해주는 역할을 한다. 따라서 피복재는 외형적 변화를 일으키지 않아 화재가 지속되는 동안 견고하게 철골 등의 피착면을 보호하게 되므로 피복재의 내화성능을 향상시키게 되는 것이다.The expansion material compensates for the volume reduction when the fire-resistant sound-absorbing coating composition causes shrinkage in a fire, and in particular, shrinkage of the sound-absorbing sound-absorbing composition coated on the surface of steel or building with a volume expansion rate of about 10% of silica at high temperatures. It plays a role in ancestoring volume change. Therefore, the coating material does not cause an appearance change, so that the surface of the steel is firmly protected during the fire, thereby improving the fire resistance performance of the coating material.

이러한 팽창재는 본 발명의 조성물에 대하여 5중량% 이하로 사용하게되면 화재시 충분한 역할을 기대할 수 없으며, 30중량% 이상 사용하게 되면 화재시에 피복재에 응력을 발생시켜 피착면으로부터 피복재가 들뜨거나 박리되는 원인으로 작용하게 된다. 따라서 팽창재는 피복 조성물 전체에 대하여 5∼30중량%로 사용하는 것이 바람직하다.Such an expansion material may not be expected to play a sufficient role in the case of fire when used in less than 5% by weight with respect to the composition of the present invention, when used by more than 30% by weight causes stress on the coating material in the event of a fire, the coating material is lifted or peeled off the adhered surface It becomes a cause of becoming. Therefore, it is preferable to use the expansion material at 5-30 weight% with respect to the whole coating composition.

탄화성 흡음섬유는 펄프, 탄소섬유, 면사, 폴리에칠렌섬유, 폴리스틸렌섬유, 폴리프로필렌섬유, 화학펄프 등을 1종 이상 혼합하여 사용한다.The carbonizable sound-absorbing fibers are used by mixing one or more kinds of pulp, carbon fiber, cotton yarn, polyethylene fiber, polystyrene fiber, polypropylene fiber, chemical pulp and the like.

탄화성 흡음섬유는 내화 및 흡음용 피복 조성물이 화재시 수축을 일으켜 대형 균열 및 탈락의 원인을 제거하는 것으로 탄화성 흡음섬유는 화재시 자체가 탄화함으로써 탄화된 공간을 따라 피복재에 아주 미세한 마이크로 균열이 거미줄 같이 발생하여 화재시 피복재에 생기는 응력을 분산시키는 역할을 함으로써 피복재가 피착면에 그대로 부착되어 있어 대형 균열이나 탈락에 의해 생긴 부분으로 열이 침투되어 철골 등 피착면의 온도가 상승하는 것을 방지하게 된다.Carbonized sound-absorbing fibers eliminate the cause of large cracks and droppings due to the shrinkage of fire- and sound-absorbing coating compositions in the case of fire. It acts as a spider web and distributes the stress generated in the coating material in case of fire, so that the coating material is attached to the surface as it is, so that the heat penetrates into the portion caused by large cracks or dropouts and prevents the temperature of the surface such as steel frame from rising. do.

이러한 탄화성 흡음섬유는 본 발명의 조성물에 대하여 2중량% 이하로 사용하게 되면 충분한 마이크로 균열을 유도하기 어려울 뿐만 아니라 흡음 성능 확보키 어렵고, 20중량% 이상 사용하게 되면 제품의 강도가 현저히 떨어지는 원인이 되기 때문에 피복 조성물 전체에 대하여 2∼20중량%로 사용한다.When the carbonizable sound-absorbing fiber is used in an amount of 2 wt% or less with respect to the composition of the present invention, it is difficult to induce sufficient micro cracks, and it is difficult to secure sound absorption performance. Therefore, it is used at 2 to 20% by weight based on the entire coating composition.

흡음성 섬유는 길이가 30㎜ 이상이면 시공시 피복재가 제대로 형성되지 않으므로 30㎜ 이내의 것이 좋다.If the sound-absorbing fibers are 30 mm or more in length, the coating material is not properly formed during construction, so that the sound absorbing fibers are preferably within 30 mm.

이하 기타 첨가제에 대해 설명한다.Other additives will be described below.

계면활성제는 내화 흡음용 피복 조성물의 분무 코팅 작업시 슬러리의 분산성, 공기 연행 효과 및 윤활성 등의 물리적 성질을 향상시키기 위한 것으로, 나트륨계, 벤젠계, 리그닌계, 멜라민계 계면활성제 등으로부터 1종 이상 선택하여 피복 조성물 전체의 1.5중량% 이내로 사용한다.Surfactant is for improving physical properties such as dispersibility, air entraining effect and lubricity of slurry during spray coating operation of coating composition for fire-absorbing and sound absorption, and one kind from surfactants of sodium, benzene, lignin, melamine, etc. It selects above and uses within 1.5 weight% of the whole coating composition.

증점제는 시공 수율의 향상과 건조시 피복층 표면의 미미한 균열을 방지하기 위한 것으로, 카르복시메틸셀룰로오스(CMC), 메칠셀룰로오스, 폴리에칠렌옥사이드, 당류, 팽윤성이 있는 점토류(벤토나이트, 규조토 등) 등으로부터 1종 이상 선택하여 전체의 5중량% 이내로 사용한다.Thickeners are used to improve construction yields and to prevent minor cracks on the surface of the coating layer during drying.These thickeners are selected from carboxymethyl cellulose (CMC), methylcellulose, polyethylene oxide, sugars, and swellable clays (bentonite, diatomaceous earth, etc.). Select the above and use within 5% by weight of the whole.

강도보강재는 특별한 강도의 발현이 요구되어지는 장소에 사용키 위한 것으로 폴리비닐알콜(PVA), 폴리비닐아세테이트(PVAc), 에틸렌비닐아세테이트(EVA), 라텍스수지, 초산비닐수지, 초산염화비닐수지, 아크릴수지, 폴리우레탄, 에폭시, 페놀수지 등으로부터 1종 이상 선택하여 전체의 2중량% 이내로 사용한다.Strength reinforcing materials are intended for use in places where special strength is required. Polyvinyl alcohol (PVA), polyvinylacetate (PVAc), ethylene vinyl acetate (EVA), latex resins, vinyl acetate resins, vinyl acetate resins, Select one or more from acrylic resin, polyurethane, epoxy, phenol resin, etc., and use it within 2% by weight of the whole.

지연제는 충분한 작업시간을 부여키 위한 것으로 동물성 단백질류, 당류 등으로 1종 이상 선택하여 전체의 2중량% 이내로 사용한다.Retardant is to give sufficient working time, and at least one of animal proteins, sugars, etc. is used within 2% by weight of the total.

항균제는 곰팡이나 균류로부터의 방균 및 항균을 목적으로 사용하는 것으로 페놀계, 유기주석계, 유기수은계 트리아딘계, 제4급 암모니아염계, 할로겐화술포닐피리딘계, 켑탄계, 유기동계, 유기질소계, 요오드계, 은계, 클로로나프탈렌류, 데하이드로아비에틸아민 펜타클로로페놀(dehydroabiethylamine pentachlorophenol), 펜타클로로라우레이트(pentachloro laurate) 등으로부터 1종 이상 선택하여 전체의 1중량% 이내로 사용한다.Antibacterial agents are used for the purpose of preventing fungi and fungi, and are antibacterial.Phenol, organotin, organomercury triadin, quaternary ammonia salts, sulfonylpyridine, pentane, organic copper, organic nitrogen, and iodine Select one or more from silver, chloronaphthalenes, dehydroabiethylamine pentachlorophenol, pentachloro laurate, etc. and use within 1% by weight of the total.

이렇게 조성되는 본 발명의 내화 및 흡음 피복 조성물은 분무 시공시 1회에 60㎜ 이상의 피복 두께를 얻을 수 있다.Thus, the fireproof and sound absorption coating composition of this invention can obtain the coating thickness of 60 mm or more at the time of spraying.

이하, 본 발명의 실시예를 통하여 자세히 설명하고자 한다. 이들 실시예는 본 발명의 바람직한 조성을 제시하기 위한 것으로서 본 발명의 범주를 한정하는 것은 아니다. 실시예 1∼6과 비교예 1∼3은 본 발명의 피복 조성물을 내화 피복재 용도로 사용하는 경우이고, 실시예 7은 흡음재 용도로 사용한 경우에 대한 것이다.Hereinafter, it will be described in detail through an embodiment of the present invention. These examples are intended to suggest preferred compositions of the present invention and not to limit the scope of the present invention. Examples 1-6 and Comparative Examples 1-3 are cases where the coating composition of this invention is used for a fireproof coating material use, and Example 7 is a case where it is used for a sound absorption material use.

[실시예 1∼6]EXAMPLES 1-6

표 1과 같은 조성으로, 퍼라이트, 시멘트, 석고플라스터, 실리카, 펄프 및 기타 첨가제를 혼합하고, 여기에 적정량의 물을 섞어 슬러리로 만든 다음, 이를 시편인 H형강(300×300×10×20㎜t, L2000㎜)의 표면을 코팅하였다. 피복재는 피착면에 대해서 30㎝의 거리를 두고 분사기를 수직으로 하여 토출량 2㎥/hr로서 분무하였다. 피착면에 코팅된 피복재가 떨어지기 직전까지 시공하여 1회 분무 시공 두께를 측정하였다. 그리고 피착면에 코팅된 피복층을 시편의 중앙 부위에 수직으로 시편의 피착면까지 두께 측정기를 밀어 넣어 각 시편에 대하여 2회씩 두께를 측정하였다. 구체적으로, 두께 측정핀이 피착면에 닿았을 때 피복재 표면이 평면이 유지되도록 충분한 힘을 가하여 슬라이딩 디스크를 움직인 다음, 측정기를 피복층으로부터 이탈시켜 두께 지시기를 읽어 1㎜ 단위로 두께를 측정하였다. 제작된 시편을 4주 동안 방치하여 충분히 양생시킨 다음, 코팅된 피복재(피복층)의 두께와 밀도를 측정하고, 육안으로 피복재의 처짐, 박리 및 균열상태를 관찰하였다. 또한 내화 성능을 알아보기 위해 시편을 각각 가열로에 넣어 내부온도를 1000℃(KS F 2257 및 ASTM E 119에 의한 가열온도)로 유지하면서 시편의 피복재 코팅면의 온도를 측정하였다. 온도 측정은 시편에 대해 피복재 코팅 전에 온도센서를 부착하여 이 센서에 의해 시간 경과에 따른 온도변화를 측정하였다. 그리고 내화성능시험이 종결된 후 가열로에서 꺼내어 균열의 길이, 균열의 폭, 균열의 수 및 균열 상태 등을 측정하였으며, 그 결과는 표 2에 나타냈다.In the composition shown in Table 1, perlite, cement, gypsum plaster, silica, pulp and other additives are mixed, and an appropriate amount of water is mixed into a slurry, which is then a specimen of H-shaped steel (300 × 300 × 10 × 20 mm). t, L2000 mm) was coated. The coating material was sprayed with a discharge amount of 2 m 3 / hr with the injector perpendicular to the adhered surface at a distance of 30 cm. The coating material coated on the adherend surface was applied until just before falling, and the thickness of one spray coating was measured. Then, the coating layer coated on the surface of the coating was pushed to the surface of the specimen perpendicularly to the center portion of the specimen, and the thickness was measured twice for each specimen. Specifically, the sliding disk was moved by applying sufficient force so that the surface of the coating material was kept flat when the thickness measuring pin touched the adhered surface, and then the thickness meter was read out from the coating layer to measure the thickness in units of 1 mm. The specimen was left to cure for 4 weeks, and then sufficiently cured. The thickness and density of the coated coating material (coating layer) were measured, and the deflection, peeling, and cracking state of the coating material were visually observed. In addition, in order to determine the fire resistance performance, the specimens were placed in a heating furnace, and the temperature of the coating material coated surface of the specimen was measured while maintaining the internal temperature at 1000 ° C. (heating temperature according to KS F 2257 and ASTM E 119). The temperature measurement was performed by attaching a temperature sensor to the specimen before coating the coating material and measuring the temperature change over time by the sensor. After the fire resistance test was terminated, the length of the crack, the width of the crack, the number of cracks and the crack state were measured. The results are shown in Table 2.

[비교예 1∼3]Comparative Examples 1-3

표 1의 조성에 따라 퍼라이트, 시멘트, 석고플라스터, 실리카, 펄프 및 기타 첨가제를 혼합하고 여기에 적정량의 물을 섞어 슬러리로 만든 다음, 이를 시편인 H 형강(300×300×10×15㎜t)의 표면을 각각 코팅하였으며, 양생 및 물성 측정은 실시예 1∼3과 동일한 방법으로 실시하였다. 그 결과는 표 2에 나타냈다.According to the composition of Table 1, perlite, cement, gypsum plaster, silica, pulp, and other additives are mixed, and an appropriate amount of water is mixed into a slurry, and the specimen is H-shaped steel (300 × 300 × 10 × 15 mmt). The surface of each was coated, and curing and physical properties were measured in the same manner as in Examples 1 to 3. The results are shown in Table 2.

상기 표 2에서 확인되듯이, 본 발명의 내화 및 흡음용 피복 조성물은 구조물에 대한 내화 피복재로 사용되는 경우 대한민국 건축법상 요구되는 내화성능 (1000℃에서 1시간; 350℃ 이하)을 충분히 만족시키며, 아울러 시공후 피복재의 균열, 박리 및 처짐이 발생하지 않았음을 알 수 있었다.As confirmed in Table 2, the fireproof and sound absorbing coating composition of the present invention satisfies the fire resistance performance required by the Korean Building Law (1 hour at 1000 ℃; 350 ℃ or less) when used as a fireproof coating material for the structure, In addition, it was found that cracking, peeling and sagging of the coating material did not occur after construction.

또한 피복층을 20㎜ 정도의 두께로 시공하는 경우에 있어서, 실시예1∼6에서 제작된 시편, 즉 본 발명에 따른 피복 조성물을 사용한 경우에는 1000℃의 가열로 내에서 1시간 방치한 시편의 이면온도가 대체적으로 200℃ 이하인데 반하여, 기존에 공지된 피복 조성물을 사용한 경우에는 같은 조건에서 이면온도는 측정이 불가능하거나 500℃ 이상임을 알 수 있다. 이것은 종래의 경우 조성물 자체는 내화성능을 만족시키지만 화재시 피복재의 중대형 균열의 발생과 탈락이 발생하여 피복체에 열이 직접적으로 침투하기 때문인 것으로 보인다.In the case of coating the coating layer with a thickness of about 20 mm, when the specimen prepared in Examples 1 to 6, that is, the coating composition according to the present invention is used, the back surface of the specimen left in a heating furnace at 1000 ° C. for 1 hour. While the temperature is generally 200 ° C. or less, in the case of using a known coating composition, it can be seen that the back temperature is impossible to measure or 500 ° C. or more under the same conditions. This is because the composition itself satisfies the fire resistance in the conventional case, but it seems to be due to the occurrence of large and large cracks and dropping of the coating material in the event of fire and heat directly penetrating the coating material.

아울러 기존의 피복 조성물을 사용한 경우에는 피복층 두께가 20㎜ 이내이기 때문에 1시간, 2시간 및 3시간에 해당하는 충분한 내화 성능을 갖는 두께로 철골 구조물을 피복하기 위해서는 2∼5회에 걸친 분무 코팅 작업 및 코팅된 피복재의 경화의 과정을 거쳐야 함을 알 수 있다. 반면에 본 발명에 의해 1회 분무 코팅 작업으로 충분한 두께의 피복층을 형성할 수 있음을 알 수 있다. 또한, 시간당 피복재의 분무량을 종래보다 2배 이상 정도까지 늘릴 수 있게 되어 피복재 시공의 경제성을 향상시킬 수 있다.In addition, in the case of using the existing coating composition, since the coating layer thickness is within 20 mm, spray coating is performed two to five times to coat the steel structure at a thickness having sufficient fire resistance for 1 hour, 2 hours and 3 hours. And it can be seen that the process of curing the coated coating material. On the other hand it can be seen that the coating layer of sufficient thickness can be formed by one spray coating operation by the present invention. In addition, it is possible to increase the spray amount of the coating material per hour up to about 2 times or more than conventional, it is possible to improve the economics of the coating material construction.

[실시예 7]Example 7

실시예 1과 같은 조성으로, 퍼라이트, 시멘트, 석고플라스터, 실리카, 펄프 및 첨가제 혼합물을 적정량의 물과 혼합하여 슬러리로 만든 후, 단위 시편으로는 10㎜ 두께, 1.2m×1.2m 크기의 밤라이트(바탕재)와 50㎜ 두께, 1.2m×1.2m 크기의 발포스틸렌폼을 바탕재로 사용하여 그 위에 피복 조성물을 코팅하였다.In the same composition as in Example 1, a mixture of perlite, cement, gypsum plaster, silica, pulp, and additives was mixed with an appropriate amount of water to form a slurry, and the unit specimens were 10 mm thick and 1.2 m × 1.2 m in size. The coating composition was coated thereon using a (stamp) material and a foamed styrene foam having a thickness of 50 mm and a size of 1.2 m x 1.2 m as a base material.

밤라이트(바탕재)에 각각 10㎜(시편 1), 20㎜(시편 2), 30㎜(시편 3) 및 50㎜(시편 4) 두께로 피복 조성물을 분무 코팅하였고, 또한 발포스틸렌폼을 바탕재에 각각 10㎜(시편 5)와 20㎜(시편 6)의 두께로 피복 조성물을 분무 코팅하였다. 제작된 시편의 밀도는 320∼370㎏/㎥ 범위이었다.The coating composition was spray-coated with a thickness of 10 mm (Sample 1), 20 mm (Sample 2), 30 mm (Sample 3), and 50 mm (Sample 4), respectively, on the night light (base material). The ash was spray coated with the coating composition to a thickness of 10 mm (Sample 5) and 20 mm (Sample 6), respectively. The prepared specimens had a density ranging from 320 to 370 kg / m 3.

상기 시편 1∼6을 흡음실로 운반하여 흡음 성능 측정을 위해 단위 시편을 조합하고, 흡음율 측정법 중에 잔향실법인 KS F 2805에 규정된 시편 크기에 적합하도록 2.93m×3.63m, 전체면적 10.64㎡으로 흡음실 중앙에 설치한 후 철제 프레임으로 사변을 둘러싸고 그 틈은 테이프와 건축용 실런트로 밀봉한 후 흡음율을 측정하였다. 이 때 단위시편의 사이는 같은 재질로 충전하였으며, 잔향실법으로 측정한 NRC(Noise Reduction Cofficient : 평균흡음율)는 다음 표 3에 나타냈다.The specimens 1 to 6 were transported to the sound absorbing chamber, and the unit specimens were combined to measure the sound absorbing performance. After installing in the center of the room, the four sides were surrounded by an iron frame and the gap was sealed with tape and building sealant, and then the sound absorption rate was measured. At this time, the unit specimen was filled with the same material, and the NRC (Noise Reduction Cofficient) measured by the reverberation chamber method is shown in Table 3 below.

상기 표 3의 실험 결과는 시편을 일체로 만들어 측정한 값이 아니다. 따라서 시편을 결합하지 않고 일체로 제작하였을 경우에는 이음매 부분이 없어지게 되어 평균흡음율은 더 좋아질 것이다.The experimental result of Table 3 is not a value measured by making the specimen integrally. Therefore, if the specimen is manufactured in one piece without bonding, the seam is eliminated and the average sound absorption will be better.

표 3에서 알 수 있는 바와 같이, 바탕재로 발포스틸렌폼을 사용한 경우에 흡음율이 약간 우수한 것으로 나타났으며, 바탕재로 발포스틸렌폼을 사용하지 않더라도 본 발명의 조성물은 50㎜로 도포하는 경우 평균 흡음율이 0.72 이상으로 통상의 흡음재보다 우수하였다. 그러나 저주파대에서 흡음율은 다공질 흡음재 모두가 그렇듯이 낮으므로 바탕재로 판진동형 흡음재, 예를 들면 합판, 밤라이트, 석고보드 등을 사용하는 것이 바람직하고, 특히 발포스틸렌폼과 같은 스티로폴을 사용하면 더욱 좋을 것으로 보인다.As can be seen from Table 3, when the foamed styrene foam was used as a base material, the sound absorption rate was shown to be slightly superior, and the composition of the present invention was averaged when 50 mm was applied even if the foamed styrene foam was not used as the base material. The sound absorption rate was 0.72 or more, which was superior to the normal sound absorption material. However, at low frequencies, sound absorption is low, as is the case for all porous sound absorbing materials, so it is preferable to use plate vibration-type sound absorbing materials such as plywood, chestnut, gypsum board, etc., in particular, styropol such as foamed styrene foam. Seems to be.

이상에서 상세히 설명하였듯이, 본 발명의 내화 흡음용 피복 조성물은 내화 성능에 있어서 대한민국 건축법상의 내화성능(350℃ 이하)을 발휘하기 위한 두께(1시간)가 20㎜이면 충분하고, 종래의 내화 피복재를 사용한 것보다 내화 성능이 우수하다. 즉 경량골재의 무수한 기공에 의한 열 차단 효과 등, 다양한 내화 메카니즘에 의해 대한민국 건축법상의 내화기준으로 기준온도 한계를 유지할 수 있는 두께를 최소화할 수 있었다. 아울러 피복체로부터 피복재가 탈락되지 않게 함으로써 실질적인 내화성능이 보장되며, 흡음 효과가 뛰어나고, 작업성의 향상은 물론 주변환경에 대한 악영향을 최대한 줄일 수 있다. 특히 본 발명은 화재시 피복재에 마이크로 균열을 유도하여 충분한 내화 성능이 화재 진압시까지 피복재가 피착면에 부착 유지될 수 있도록 함으로써 철골이 화재에 대한 안전성을 실질적으로 극대화 하였다.As described in detail above, the fireproof sound-absorbing coating composition of the present invention has a thickness (1 hour) for exhibiting the fire resistance performance (350 ° C. or less) under the Korean Building Law in fire resistance performance, and is sufficient to provide a conventional fireproof coating material. Better fire resistance than used. In other words, various fire resistance mechanisms such as heat shielding effect due to numerous pores of lightweight aggregates could minimize the thickness to maintain the limit of the reference temperature as the fire resistance standard of the Korean Building Law. In addition, by preventing the coating material from falling off from the coating, substantial fire resistance is ensured, the sound absorption effect is excellent, and the workability is improved as well as the adverse effect on the surrounding environment can be minimized. In particular, the present invention induces micro-cracks in the coating material in case of fire so that sufficient fire resistance can be maintained on the surface of the coating material until the fire is extinguished, thereby substantially maximizing safety for fire.

Claims (7)

팽창 혹은 미팽창된 퍼라이트, 경석, 질석, 화산재, 부석으로 구성된 천연 무기질 광물질; 인공적으로 유리계나 광물질에 무수한 미세 기공을 형성한 중공구체; 및 입상발포스치로폴과 파쇄발포스치로폴로 구성된 유기질 골재로부터 선택된 1종 이상의 경량골재 25∼60중량%; 포틀랜드 시멘트, 고로 시멘트, 실리카 시멘트, 알루미나 시멘트, 마그네시아 시멘트, 석고, 석고플라스터, 마그네시아, 황산마그네슘으로부터 선택된 1종 이상의 결합재 20∼60중량%; 석회, 소석회, 생석회, 이수석고, 반수석고, 석고플라스터, 수산화알루미늄, 수산화마그네슘, 탄산마그네슘, 탄산칼슘, 황산알루미늄, 붕사, 몬로릴로나이트, 벤토나이트로, 탄산수소나트륨, 규산나트륨으로 선택된 1종 이상의 흡열재 50중량% 이하; 팽창성 미팽창질석, 팽창성 미창팽 경석, 팽창성 미팽창 퍼라이트, 팽창성 미팽창 혈압(shale), 팽창성 미팽창 점토, 실리카, 마그네시아, 마그네슘 카보네이트, 실리마나이트(silimanite), 남정석(kyanite), 홍주석(andalusite), 복사이트(bauxite), 파이로필라이트(pyrophylite), 돌로마이트(dolomite) 및 활석으로부터 선택된 1종 이상의 팽창재 5∼30중량%; 및 펄프, 면사 및 화학펄프로부터 선택된 1종 이상의 탄화성 흡음섬유 2∼20중량%를 포함하는 내화 흡음용 피복 조성물.Natural mineral minerals consisting of expanded or unexpanded perlite, pumice, vermiculite, volcanic ash and pumice; Hollow spheres artificially formed innumerable micropores in glass or minerals; And 25 to 60% by weight of at least one lightweight aggregate selected from organic aggregates consisting of granular phospholipids and crushed polyphospholipids; 20 to 60% by weight of at least one binder selected from Portland cement, blast furnace cement, silica cement, alumina cement, magnesia cement, gypsum, gypsum plaster, magnesia and magnesium sulfate; Lime, hydrated lime, quicklime, dihydrate gypsum, hemihydrate gypsum, gypsum plaster, aluminum hydroxide, magnesium hydroxide, magnesium carbonate, calcium carbonate, aluminum sulfate, borax, monlorilonite, bentonite, sodium bicarbonate, sodium silicate Up to 50% by weight of heat absorbing material; Expandable Unexpanded Vermiculite, Expandable Unexpanded Pumice, Expandable Unexpanded Perlite, Expandable Unexpanded Blood (shale), Expandable Unexpanded Clay, Silica, Magnesia, Magnesium Carbonate, Silimanite, Kyanite, Scarlet (andalusite) 5-30% by weight of at least one expandable material selected from the group consisting of boxite, pyrophylite, dolomite and talc; And 2 to 20% by weight of at least one carbonizable sound absorbing fiber selected from pulp, cotton yarn, and chemical pulp. 제1항에 있어서, 첨가제로서 나트륨계, 벤젠계, 리그닌계 및 멜라민계에서 선택된 1종 이상의 계면활성제; 카르복시메틸셀룰로오스, 메칠셀룰로오스, 폴리에칠렌옥사이드, 당류 및 팽윤성이 있는 점토류(벤토나이트, 규조토 등)로 부터 선택된 1종 이상의 증점제; 폴리비닐알콜, 폴리비닐아세테이트, 에틸렌비닐아세테이드, 라텍스수지, 초산비닐수지, 초산염화비닐수지, 아크릴수지, 폴리우레탄, 에폭시 및 페놀수지로부터 선택된 1종 이상의 강도보강재; 동물성 단백질류 또는 당류에서 선택된 1종 이상의 지연제; 및 페놀계, 유기주석계, 유기수은계, 트리아딘계, 제4급 암모니아염계, 할로겐화술포닐피리딘계, 켑탄계, 유기동계, 유기질소계, 요오드계, 은계, 클로로나프탈렌류, 데하이드로아비에틸아민 펜타클로로페놀(dehydroabiethylamine pentachlorophenol) 및 펜타클로로라우레이트(pentachloro laurate)에서 선택된 1종 이상의 항균제로 이루어진 군으로부터 선택된 1종 이상의 화합물이 더 포함되어 구성된 것을 특징으로 하는 내화 흡음용 피복 조성물.The method of claim 1, wherein the additive comprises at least one surfactant selected from sodium, benzene, lignin and melamine based; One or more thickeners selected from carboxymethylcellulose, methylcellulose, polyethylene oxide, sugars and swellable clays (bentonite, diatomaceous earth, etc.); At least one strength reinforcing material selected from polyvinyl alcohol, polyvinylacetate, ethylene vinyl acetate, latex resin, vinyl acetate resin, vinyl acetate resin, acrylic resin, polyurethane, epoxy and phenol resin; One or more retardants selected from animal proteins or sugars; And phenolic, organotin, organomercury, triadine, quaternary ammonia salts, halogenated sulfonylpyridine, pentane, organic copper, organonitrogen, iodine, silver, chloronaphthalenes, dehydroabiethylamine pentachloro A coating composition for fire-absorbing sound absorption, characterized in that the composition further comprises at least one compound selected from the group consisting of at least one antimicrobial agent selected from phenol (dehydroabiethylamine pentachlorophenol) and pentachloro laurate. 제2항에 있어서, 계면활성제는 1.5중량% 이하로 첨가된 것임을 특징으로 하는 내화 흡음용 피복 조성물.The coating composition for fire-absorbing sound absorption according to claim 2, wherein the surfactant is added in an amount of 1.5 wt% or less. 제2항에 있어서, 증점제는 5중량% 이하로 첨가된 것임을 특징으로 하는 내화 흡음용 피복 조성물.The coating composition for fire-absorbing sound absorption according to claim 2, wherein the thickener is added at 5% by weight or less. 제2항에 있어서, 강도보강재는 2중량% 이하로 첨가된 것임을 특징으로 하는 내화 흡음용 피복 조성물.The fire-retardant sound-absorbing coating composition according to claim 2, wherein the strength reinforcing material is added at 2% by weight or less. 제2항에 있어서, 지연제는 2중량% 이하로 첨가된 것임을 특징으로 하는 내화 흡음용 피복 조성물.3. The fireproof sound-absorbing coating composition according to claim 2, wherein the retardant is added in an amount of 2 wt% or less. 제2항에 있어서, 항균제는 1중량% 이하로 첨가된 것임을 특징으로 하는 내화 흡음용 피복 조성물.The fireproof sound-absorbing coating composition according to claim 2, wherein the antimicrobial agent is added in an amount of 1 wt% or less.
KR1019980017649A 1998-05-15 1998-05-15 Fireproofing and sound-absorbing composition KR100272624B1 (en)

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CNB99106707XA CN1175062C (en) 1998-05-15 1999-05-14 Coating composition for fire-preventing and acoustics use
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KR100457426B1 (en) * 2001-01-09 2004-11-16 박종원 An ultra lightweight smoke-resistant composite and an apparatus and a method of manufacturing the same
KR100525564B1 (en) * 2002-05-03 2005-10-31 주식회사 경동세라텍 Covering composite for fire resistance and sound absorption
KR100966322B1 (en) 2008-06-17 2010-06-28 ㈜익성텍 Panel manufacturing composition and its process and its panel product with fireproof resistance
KR20150109916A (en) * 2014-03-21 2015-10-02 구본신 The composition for insulation
KR101658610B1 (en) * 2014-03-21 2016-09-22 김찬홍 The composition for insulation

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CN1175062C (en) 2004-11-10
CN1269385A (en) 2000-10-11
DE19922247A1 (en) 1999-12-02
JP2000001380A (en) 2000-01-07

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