JP2000001380A - Coating composition for fire protection and sound absorption - Google Patents

Coating composition for fire protection and sound absorption

Info

Publication number
JP2000001380A
JP2000001380A JP12760399A JP12760399A JP2000001380A JP 2000001380 A JP2000001380 A JP 2000001380A JP 12760399 A JP12760399 A JP 12760399A JP 12760399 A JP12760399 A JP 12760399A JP 2000001380 A JP2000001380 A JP 2000001380A
Authority
JP
Japan
Prior art keywords
coating composition
sound
fire
weight
absorbing
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP12760399A
Other languages
Japanese (ja)
Inventor
Sang Oak Jung
サンオク ジュン
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
SAMSON CO Ltd
Samson Perlite Co Ltd
Original Assignee
SAMSON CO Ltd
Samson Perlite Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by SAMSON CO Ltd, Samson Perlite Co Ltd filed Critical SAMSON CO Ltd
Publication of JP2000001380A publication Critical patent/JP2000001380A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B14/00Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B14/02Granular materials, e.g. microballoons
    • C04B14/04Silica-rich materials; Silicates
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B22/00Use of inorganic materials as active ingredients for mortars, concrete or artificial stone, e.g. accelerators, shrinkage compensating agents
    • C04B22/008Cement and like inorganic materials added as expanding or shrinkage compensating ingredients in mortar or concrete compositions, the expansion being the result of a recrystallisation
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • C04B28/10Lime cements or magnesium oxide cements
    • C04B28/105Magnesium oxide or magnesium carbonate cements
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/50Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2103/00Function or property of ingredients for mortars, concrete or artificial stone
    • C04B2103/0068Ingredients with a function or property not provided for elsewhere in C04B2103/00
    • C04B2103/0091Organic co-binders for mineral binder compositions
    • C04B2103/0092Organic co-binders for mineral binder compositions for improving green strength
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2103/00Function or property of ingredients for mortars, concrete or artificial stone
    • C04B2103/20Retarders
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2103/00Function or property of ingredients for mortars, concrete or artificial stone
    • C04B2103/40Surface-active agents, dispersants
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2103/00Function or property of ingredients for mortars, concrete or artificial stone
    • C04B2103/44Thickening, gelling or viscosity increasing agents
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2103/00Function or property of ingredients for mortars, concrete or artificial stone
    • C04B2103/60Agents for protection against chemical, physical or biological attack
    • C04B2103/67Biocides
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00474Uses not provided for elsewhere in C04B2111/00
    • C04B2111/00482Coating or impregnation materials
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/20Resistance against chemical, physical or biological attack
    • C04B2111/28Fire resistance, i.e. materials resistant to accidental fires or high temperatures
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/91Use of waste materials as fillers for mortars or concrete

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Civil Engineering (AREA)
  • Building Environments (AREA)
  • Paints Or Removers (AREA)
  • Porous Artificial Stone Or Porous Ceramic Products (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)

Abstract

PROBLEM TO BE SOLVED: To obtain a coating compsn. which exhibits excellent fire resistance and sound absorbing performance in the min. coating thickness by incorporating specified proportions of a lightweight aggregate, a binder, a heat absorbing material, an expanding material and carbonaceous sound absorbing fibers. SOLUTION: The coating compsn. contains 25-60 wt.% lightweight aggregate having 0.01-0.8 g/cc specific gravity such as vermiculite, 20-60 wt.% binder such as Portland cement, <=50 wt.% heat absorbing material such as gypsum plaster, 5-30 wt.% expanding material such as silica and 2-20 wt.% carbonaceous sound absorbing fibers having <=30 mm length such as carbon fibers or further contains <=1.5 wt.% surfactant such as lignin, <=5 wt.% thickener such as CMC, <2 wt.% strength enhancer such as PVA, <2 wt.% retarder such as animal protein and <=1 wt.% antibacterial agent such as pentachlorolaurate. When the compsn. is sprayed, >=60 mm coating thickness is obtd. at a time.

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【発明の属する技術分野】本発明は、耐火及び吸音用被
覆組成物に係るもので、詳しくは建築物の鉄骨構造物の
表面に吹き付けコーティングをすることにより、火事の
際に際して、高熱による鉄骨の強度及び耐力の低下を防
止し、又、建築物の壁面及び天井などに吹き付けコーテ
ィングをすることにより、音響性をも付与できる耐火及
び吸音用被覆組成物に関する。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a fire-resistant and sound-absorbing coating composition and, more particularly, to spray coating on the surface of a steel structure of a building so that the steel frame can be heated by high heat during a fire. The present invention relates to a fire-resistant and sound-absorbing coating composition that can prevent deterioration in strength and proof strength, and can also impart acoustic properties by spray coating on walls and ceilings of buildings.

【0002】[0002]

【従来の技術】現代社会が都市化されて人口密集地域が
増えてくるに従い、狭い地域において大勢の人々が生き
るための方策として、建築物の高層化及び大型化がなさ
れており、その手段としては一般的に鉄骨構造が適用さ
れている。
2. Description of the Related Art As modern society is urbanized and densely populated areas are increasing, as a measure for a large number of people to live in a small area, buildings are being increased in height and size. Generally, a steel structure is applied.

【0003】しかし、鉄骨構造をそのまま大型化の高層
建物に適用すれば、建物の火事発生に際して火炎及び内
装材が燃えながら発生される有毒ガスなどで人命被害が
生じる危険があり、又、高熱により鉄骨構造物の強度及
び耐力が劣化して建物がその自体の荷重を耐えずに崩壊
する危険がある。従って、鉄骨構造物の表面には耐火材
を被覆することが必要になる。
However, if the steel frame structure is applied to a large-sized high-rise building as it is, there is a danger that human life is injured by fire and toxic gas generated while the interior materials are burning when a building fire occurs, There is a danger that the strength and proof stress of the steel structure will deteriorate and the building will collapse without bearing its own load. Therefore, it is necessary to coat the surface of the steel structure with a refractory material.

【0004】以下、従来の耐火被覆材に対し具体的に説
明する。
[0004] Hereinafter, a conventional refractory coating material will be specifically described.

【0005】耐火被覆材は、成分に従いパーライト系、
バーミキュライト、岩綿系、及びこれらの混合系に区分
され、その被覆方法は、耐火性成型物を設置する方法と
水性スラリを吹き付けコーティングする方法とに分類さ
れる。
[0005] The refractory coating material is made of pearlite,
It is classified into vermiculite, rock wool, and a mixture thereof, and its coating method is classified into a method of installing a refractory molded product and a method of spray coating with an aqueous slurry.

【0006】今まで耐火被覆材は耐火性能面において大
きな発展があった。特に、耐熱性を向上させるための技
術的発展、即ち、高温で吸熱機能を有する材料を使用す
ることにより耐火性能が大きく向上された。ここで、高
温で吸熱機能を有する材料は、火事のときに周りの熱を
奪いながらその自体の結合が分解(結合水の脱水又は耐
火炭酸ガスの発生)されるものであって、火熱が鉄骨に
伝導されることを防止する役割をして耐火被覆材の耐火
性能を向上させるようになる。しかし、吸熱機能を有す
る材料は、高温で周りの熱を奪うが、結合水の脱水又は
炭酸ガスへの転換などと共に体積の急激な減少を伴う。
このため、被覆材は体積の変化により大形亀裂及び被着
面から離れる現象が発生し、更には、火事に際して被覆
材が脱落することにより、特に鉄骨が火災に露出されて
強度と耐力の低下をもたらす。
Hitherto, fire-resistant coating materials have made great progress in terms of fire resistance performance. In particular, the technical development for improving the heat resistance, that is, the use of a material having an endothermic function at a high temperature greatly improved the fire resistance performance. Here, a material having an endothermic function at a high temperature is one in which its own bond is decomposed (dehydration of combined water or generation of refractory carbon dioxide gas) while taking away the surrounding heat in the event of a fire, and the fire heat is It plays a role in preventing conduction to the outside, thereby improving the fire resistance performance of the fire-resistant coating material. However, a material having an endothermic function removes surrounding heat at a high temperature, but is accompanied by a sharp decrease in volume along with dehydration of bound water or conversion to carbon dioxide gas.
As a result, the coating material undergoes a large crack due to the change in volume and a phenomenon that the coating material separates from the surface to be adhered.Furthermore, the coating material falls off in the event of a fire, and especially the steel frame is exposed to the fire and the strength and proof strength decrease. Bring.

【0007】このような問題のため、一部では無機繊維
を用いてこれを解決しようとする試みがあるが、無機繊
維のうちに岩綿又はガラス繊維は人体の皮膚などを刺激
して深刻な場合は発疹の原因となり、セピオライト(sep
iolite)などは高温で完全に分解されないことにより、
火事の際に被覆材に作用して体積変化を起こす応力の除
去問題を新たに発生し、この問題は未だに解決されてい
ない。
[0007] Due to such problems, some attempts have been made to solve the problem by using inorganic fibers. Among the inorganic fibers, rock wool or glass fiber irritates the skin of the human body and causes serious problems. May cause a rash and may cause sepiolite (sep
iolite) is not completely decomposed at high temperature,
In the event of a fire, a new problem of removing stress that acts on the coating material and causes a change in volume has newly arisen, and this problem has not yet been solved.

【0008】これと関連して、既に公開された出願を用
いて説明する。
[0008] In this connection, a description will be given using an already published application.

【0009】大韓民国特許公告第94-9412号明細書、大
韓民国特許公告第89-4281号明細書、日本国特開平6-326
66号公報、日本国特開平6-32667号公報、日本国特開平6
-80909号公報及び日本国特公平6-99177号公などに開示
された被覆材は、無機繊維(岩綿、ガラス繊維など)を
用いており、これらは皮膚刺激などを起こして人体に有
害である。
Korean Patent Publication No. 94-9412, Korean Patent Publication No. 89-4281, Japanese Patent Application Laid-Open No. 6-326
No. 66, Japanese Unexamined Patent Publication No. 6-32667, Japanese Unexamined Patent Publication No. 6
The coating materials disclosed in JP-80909 and Japanese Patent Publication No. 6-99177 use inorganic fibers (rock wool, glass fiber, etc.), which cause skin irritation and the like and are harmful to the human body. is there.

【0010】大韓民国特許公告第92-3227号明細書、日
本国特開平6-32666号公報及び同6-32667号公報に開示さ
れた被覆材は、再乳化形樹脂粉末を多量に含むため、建
物の火事に際して被覆材から有毒ガスが多量発生され、
人体に非常に有害であり、再乳化形樹脂粉末を少量使用
する場合は、ミクロ亀裂を誘導することの代わりに中大
形亀裂が発生されるという問題がある。又、日本国特開
平6-32666号公報の未焼性バーミキュライトを用いる場
合は、火事の際に膨張されるバーミキュライトの応力を
制御することが難しいため、これも中大形亀裂の原因と
して作用する。
[0010] The coating materials disclosed in Korean Patent Publication No. 92-3227, JP-A-6-32666 and JP-A-6-32667 contain a large amount of re-emulsifying resin powder, and In the event of a fire, a large amount of toxic gas was generated from the coating material,
It is very harmful to the human body, and when a small amount of re-emulsified resin powder is used, there is a problem that a medium-sized crack is generated instead of inducing a micro-crack. Further, in the case of using unburned vermiculite disclosed in Japanese Patent Application Laid-Open No. 6-32666, it is difficult to control the stress of the vermiculite that is expanded during a fire, which also acts as a cause of a medium-large crack. .

【0011】日本国特開平3-100243号公報に開示された
被覆材は、吸熱材の量が少なくて耐火性能が劣ることに
起因して、耐火時間の1時間に要求される厚さが30mmと
して非常に厚く、日本国特公平5-20375号公報において
は、吸熱材の量を多くして耐熱性能は向上されたが、密
度が0.7と高く、且つ、高温で吸熱材による収縮が大き
くい。また膨張材としてコーティングされた粒状のケイ
酸ソーダを用いているが、膨張材の多すぎる使用のため
に、高温で膨張及び収縮膨張による被覆材の離脱が発生
し、コーティングされた粒状のケイ酸ソーダの製造が容
易でなく、経済性にも問題があった。
The coating material disclosed in Japanese Patent Application Laid-Open No. 3-100243 has a thickness of 30 mm required for one hour of the fire resistance time due to the small amount of the heat absorbing material and the poor fire resistance performance. As very thick, in Japanese Patent Publication No. 5-20375, the heat-resistant performance was improved by increasing the amount of heat-absorbing material, but the density was as high as 0.7, and the shrinkage due to the heat-absorbing material was large at high temperatures. . Also, coated granular sodium silicate is used as the expanding material, but due to excessive use of the expanding material, detachment of the coating material due to expansion and contraction expansion at high temperatures occurs, and the coated granular silicate is used. The production of soda was not easy, and there was a problem in economy.

【0012】又、日本国特公平7-13380号公報において
は、日本国特公平5-20375号公報の問題点を改善するた
めに、被覆材としてガラス繊維を用いており、ヨーロッ
パ特許第661241号明細書に提案されている、結合水を含
めた骨材を製造して用いる形態の被覆材組成物において
も、セメントを40%以上使用することにより、乾燥収縮
及び熱間から結合水が脱落されて収縮を誘発させて発生
される被覆材の脱落及び/又は剥離現象を解決するため
人体に有害なガラス繊維を用いているが、これは現場作
業者が使用を避けるという問題点があった。
In Japanese Patent Publication No. 7-13380, glass fiber is used as a covering material in order to improve the problem of Japanese Patent Publication No. 5-20375. Also proposed in the specification, even in the coating composition in the form of manufacturing and using aggregates including bound water, by using 40% or more of cement, bound water is dropped from drying shrinkage and hot. Glass fibers harmful to the human body are used to solve the phenomenon of falling off and / or exfoliation of the coating material caused by inducing shrinkage, but this has a problem that field workers avoid using the glass fibers.

【0013】[0013]

【発明が解決しようとする課題】このように従来の耐火
被覆材は、乾燥収縮及び熱間収縮に対する解決策として
岩綿或いはガラス繊維などの無機繊維を用いて問題を解
決しようとしたが、前記無機繊維は人体に有害し、別の
方法により繊維類を使用していない場合は膨張材を用い
て収縮による亀裂を防止しようとしたが、その均衡をな
すことが容易でないという問題点を有していた。
As described above, conventional refractory coating materials have attempted to solve the problem by using inorganic fibers such as rock wool or glass fiber as a solution to drying shrinkage and hot shrinkage. Inorganic fibers are harmful to the human body, and when fibers are not used by another method, the expansion material is used to prevent cracks due to shrinkage, but there is a problem that it is not easy to balance them. I was

【0014】一方、吸音被覆材(吸音材)は、施工形態
に従い建築物の天井、壁面及び底部に埋設するマット形
と吹き付け被覆する吹き付け形とに分類される。又、材
料の組成に従い高周波帯における吸音率に優れた多孔性
吸音材、低周波帯における吸音率に優れた板振動形、及
び共鳴形吸音材に分類される。
On the other hand, the sound-absorbing covering material (sound-absorbing material) is classified into a mat type buried in the ceiling, wall and bottom of the building and a spray type which is spray-coated according to the construction form. Further, according to the composition of the material, it is classified into a porous sound absorbing material having an excellent sound absorption coefficient in a high frequency band, a plate vibration type having an excellent sound absorbing coefficient in a low frequency band, and a resonance type sound absorbing material.

【0015】この中に吹き付け形吸音材は、無機繊維、
結合剤、増粘剤、鉱油、及びその他の有機添加剤などを
混合して製造するか、又はバーミキュライト或いは食物
性ファイバなどを主材として用いて製造する。しかし、
これらは一定した吸音と断熱の効果は得られるが、前者
は無機繊維が作業上粉塵発生の危険があるので、取り扱
うに注意すべきであることは勿論で、吹き付け後の充分
な強度を得るために圧密(compaction)作業をしなければ
ならいないという煩雑さがある。
The spray type sound absorbing material includes inorganic fibers,
It is manufactured by mixing a binder, a thickener, mineral oil, and other organic additives, or is manufactured using vermiculite or dietary fiber as a main material. But,
These have a constant sound absorbing and heat insulating effect, but the former is not only to be handled with care because the inorganic fiber has the danger of generating dust in the work, but in order to obtain sufficient strength after spraying Has to perform the compaction work.

【0016】最近、各種騒音から脱した快適な室内環境
を組成するための吸音材の開発が持続的に行われてお
り、このような吸音材の開発は耐火及び断熱の効果をも
一緒に得る方向になされている。
[0016] Recently, sound absorbing materials for composing a comfortable indoor environment free from various noises have been continuously developed, and the development of such sound absorbing materials also obtains the effects of fire resistance and heat insulation. The direction has been made.

【0017】本発明の目的は、火事に際して、被覆材の
大形亀裂及び被着面からの離脱を防止して鉄骨の火事に
対する安全性を向上し、且つ最小の被覆厚さで優れた耐
火及び吸音性能を発揮し得る耐火及び吸音用被覆組成物
を提供することにある。
An object of the present invention is to prevent a large crack in a cladding material and detachment from an adhered surface in a fire, to improve the safety of a steel frame against a fire, and to provide an excellent fire resistance and a fire resistance with a minimum coating thickness. An object of the present invention is to provide a fire-resistant and sound-absorbing coating composition capable of exhibiting sound absorbing performance.

【0018】[0018]

【課題を解決するための手段】このような本発明の目的
を達成するための耐火及び吸音用被覆組成物は、軽量骨
材25-60重量%の範囲、結合材20-60重量%の範囲、吸熱
材50重量%以下、膨張材5-30重量%の範囲、及び炭化性
吸音繊維2-20重量%の範囲を含むことを特徴とする。
The refractory and sound absorbing coating composition for achieving the object of the present invention has a lightweight aggregate in the range of 25-60% by weight and a binder in the range of 20-60% by weight. , 50% or less by weight of the heat absorbing material, 5-30% by weight of the expanding material, and 2-20% by weight of the carbonizable sound absorbing fiber.

【0019】又、本発明は、選択的に吹き付けコーティ
ング作業のときにスラリの分散性、空気連行効果及び潤
滑性などの物理的性質を向上させるため、界面活性剤を
全体の1.5重量%以内に、施工収率の向上と乾燥時の被
覆層表面の細かい亀裂を防止するための増粘剤を全体の
5重量%以内に、特別な強度の発現が求めれる場所に使
用するための強度補強材を全体の2重量%以内に、充分
な作業時間を付与させるための遅延剤を全体の2重量%
以内に、そして、黴び又は菌類からの防菌及び抗菌を目
的として抗菌剤を全体の1重量%以内に使用できる。
The present invention is also directed to selectively improving the physical properties such as the dispersibility of the slurry, the air entrainment effect and the lubricity during the spray coating operation, by adding a surfactant within 1.5% by weight of the whole. Thickener to improve the construction yield and prevent fine cracks on the coating layer surface during drying.
Within 5% by weight, within 2% by weight of a strength reinforcing material for use in places where the development of special strength is required, and 2% by weight of a retarder to give sufficient working time
The antibacterial agent can be used within 1% by weight, and for the purpose of preventing bacteria and fungi from fungi or fungi.

【0020】このように組成される本発明の耐火及び吸
音用被覆組成物は、吹き付けの施工後の乾燥による収
縮、亀裂及び離脱がなく、火事の際に膨張材による収縮
をも防止すると共に炭化性吸音繊維によりミクロ亀裂を
誘導して熱容量の大きい結合材及び吸熱材の収縮による
応力を分散処理することにより、大形亀裂を防止し、被
覆材の離脱を防止して火事鎮圧ときまでも被覆材の形態
がそのまま維持されて充分な耐火性能を発揮できる。
The fire-resistant and sound-absorbing coating composition of the present invention thus formed is free from shrinkage, cracking and detachment due to drying after spraying, prevents shrinkage due to the expansive material in the event of fire, and provides carbonization. Micro-cracks are induced by the conductive sound absorbing fiber to disperse the stress caused by the shrinkage of the binder and heat absorbing material with a large heat capacity to prevent large cracks, prevent detachment of the covering material, and cover even during fire suppression. The shape of the material is maintained as it is, and sufficient fire resistance can be exhibited.

【0021】[0021]

【発明の実施の形態】本発明に係る耐火及び吸音用被覆
組成物の原料及びこれらの作用に対し説明する。
BEST MODE FOR CARRYING OUT THE INVENTION Raw materials of the fire-resistant and sound-absorbing coating composition according to the present invention and their actions will be described.

【0022】軽量骨材は大きさ4-200マッシュのもの
で、膨張或いは未膨張されたパーライト、軽石、バーミ
キュライト、火山災、浮石などのような天然の鉱物質
と、人工的にガラス系及び鉱物質に気孔が含められるよ
うに製造した中空球体と、粒状発泡ポリスチレン及び破
砕発泡ポリスチレンからなった有機質骨材を単独又は2
種以上混合して使用する。
Lightweight aggregates are 4-200 mash in size and are made of natural minerals such as expanded or unexpanded perlite, pumice, vermiculite, volcanic disasters, floating stones, etc., and artificially made of glass and minerals. A hollow sphere manufactured so as to include pores in the material, and an organic aggregate made of granular expanded polystyrene and crushed expanded polystyrene alone or
Mix and use more than one species.

【0023】上述した軽量骨材は、比重が0.01-0.8g/cc
として軽いので、建築物に対する荷重負担が軽減され
る。又、軽量骨材は無数の小さい気孔が形成されていて
熱伝導率(0.03-0.04kcal/mh℃)が低く、既に知られて
いるように、吸音性、断熱性、及び強度の面で相当に優
れて被覆材の耐火、断熱及び吸音性能を向上させること
ができる。特に、パーライトは食物添加物として用いら
れるほどに人体に対する有毒性がないので一層親和的で
ある。
The above-mentioned lightweight aggregate has a specific gravity of 0.01-0.8 g / cc.
As a result, the load on the building is reduced. In addition, lightweight aggregates have numerous small pores and low thermal conductivity (0.03-0.04 kcal / mh ° C). As is already known, they are equivalent in sound absorption, heat insulation, and strength. Excellent in fire resistance, heat insulation and sound absorption performance of the covering material. In particular, perlite is more compatible because it is less toxic to the human body than is used as a food additive.

【0024】このような軽量骨材は、本発明の被覆組成
物に60重量%を越える量加えると、吹き付け施工された
被覆材の密度と熱伝導率が低くなる利点はあるが、付着
力と強度が劣り、20重量%未満では、付着力と強度は優
れているが、吹き付け施工された被覆材の密度及び熱伝
導率が高くなるため、全体に対し25-60重量%の範囲使
用することが好ましい。
When such a lightweight aggregate is added to the coating composition of the present invention in an amount exceeding 60% by weight, there is an advantage that the density and thermal conductivity of the sprayed coating material are lowered, but the adhesive force and the adhesive strength are reduced. If the strength is inferior and less than 20% by weight, the adhesive strength and strength are excellent, but the density and thermal conductivity of the sprayed coating material will be high, so use in the range of 25-60% by weight based on the whole Is preferred.

【0025】結合材は、軽量骨材の相互間及び軽量骨材
と鉄骨構造物の表面(又は建築物の天井及び壁面などの
被着面)とを円滑に結合させる材料として、ポートラン
ドセメント、高炉セメント、シリカセメント、アルミナ
セメント又はマグネシアセメントからなるセメント類、
又は二水石膏、半水石膏、石膏プラスターからなる石膏
類、又はマグネシア、硫酸マグネシウムを1種以上混合
して使用する。
[0025] The binder is made of Portland cement, as a material for smoothly bonding between the lightweight aggregates and between the lightweight aggregate and the surface of the steel structure (or the adhered surface such as the ceiling and the wall surface of the building). Blast furnace cement, silica cement, alumina cement or magnesia cement,
Alternatively, gypsum consisting of gypsum dihydrate, hemihydrate gypsum, gypsum plaster, or magnesia or magnesium sulfate is used as a mixture.

【0026】このような結合材は、本発明の組成物に対
し60重量%を越える量加えると、被覆材の付着力と強度
は優れているが、密度と熱伝導率が高くなって耐火性能
が劣り、又、火事の際に組成物の応力発生が大きく、局
部的に応力が集中されて大形亀裂の要因として作用し、
20重量%未満では被覆材の密度及び熱伝導率は低くなる
が付着力と強度が劣るので、全体に対し20-60重量%使
用する。
When such a binder is added in an amount exceeding 60% by weight based on the composition of the present invention, the adhesive strength and strength of the coating material are excellent, but the density and thermal conductivity are increased and the fire resistance is increased. Is inferior, and in the event of a fire, the stress of the composition is large, and the stress is locally concentrated and acts as a factor for large cracks,
If the content is less than 20% by weight, the density and thermal conductivity of the coating material will be low, but the adhesion and strength will be poor.

【0027】吸熱材は、炭酸カルシウム、消石灰、生石
灰などの石灰類、二水石膏、石膏プラスターなどの石膏
類、水酸化アルミニウム、硫酸アルミニウム、ほう砂、
炭酸マグネシウム、水酸化マグネシウム、モンモリロナ
イト、ベントナイト、炭酸水素ナトリウム、ケイ酸ナト
リウム、或いはガス化合物、或いは前記吸熱材を用いて
1次加工した粉末状又は骨材状態の人工吸熱材を1種以
上混合して使用する。前記人工吸熱材は、一層吸熱性を
高めるためのものであって、高温で結合水或いは炭酸ガ
スが発生して外部の熱を吸水する作用を有する。
Examples of the heat absorbing material include limes such as calcium carbonate, slaked lime and quick lime, gypsums such as gypsum and gypsum plaster, aluminum hydroxide, aluminum sulfate, borax,
Magnesium carbonate, magnesium hydroxide, montmorillonite, bentonite, sodium bicarbonate, sodium silicate, or a gas compound, or a mixture of at least one kind of powdered or aggregated artificial heat absorbing material using the heat absorbing material. To use. The artificial heat absorbing material is for further enhancing the heat absorbing property, and has a function of generating combined water or carbon dioxide gas at a high temperature to absorb external heat.

【0028】前記吸熱材は、耐火及び吸音用被覆組成物
が鉄骨及び建築物の被着面に被覆され、火事の際に熱を
吸水して結晶水或いは炭酸ガスを放出させながら鉄骨構
造物或いは建築物の被着面の急激な温度上昇を低下させ
るに有効に作用する。即ち、前記吸熱材は、別の原材料
と一緒に鉄骨構造物に対する熱遮断効果をもたらすため
被覆組成物の耐火性能を一層向上させる。
The heat-absorbing material is a fire-resistant and sound-absorbing coating composition coated on a steel frame and an adhered surface of a building, and absorbs heat in the event of a fire to release crystallization water or carbon dioxide gas. It works effectively to reduce the rapid rise in temperature of the building attachment surface. That is, the heat-absorbing material, together with another raw material, provides a heat-blocking effect on the steel structure, so that the fire resistance of the coating composition is further improved.

【0029】このような吸熱材は被覆組成物の全体の50
重量%を越える量加えると、耐火性能が向上する反面、
吸熱材以外の被覆組成物のそれぞれの比率が少なくなっ
て収縮の原因となり、更には直接的な大形亀裂の原因と
なり、又、被覆材の剥離と脱落の原因となる。従って、
吸熱材は被覆材組成物の全体の50重量%以下使用するこ
とが好ましい。
[0029] Such a heat absorbing material is used for the entire coating composition.
Addition of more than 10% by weight improves fire resistance,
The proportion of each of the coating compositions other than the heat absorbing material decreases, causing shrinkage, directly causing large cracks, and causing peeling and falling off of the coating material. Therefore,
The heat absorbing material is preferably used in an amount of 50% by weight or less based on the total weight of the coating composition.

【0030】膨張材は、シリカ、マグネシア、膨張性未
膨張バーミキュライト、膨張性未膨張軽石、膨張性未膨
張パーライト、炭酸マグネシウム、ケイセン石(sillima
nite)、カイヤナイト(kyanite)、アンダルサイト(andal
usite)、ボーキサイト(bauxite)、パイロフィライト(py
rophyllite)、ドロマイト(dolomite)、酸化第二鉄、フ
ェロ-酸化第二鉄(ferro-ferric oxide)、酸化第一鉄、
イライト(illite)、滑石(talc)、正長石(orthoclase)、
ロウ石(agalmatolite)、ジルコン、炭化ケイ素、膨脹性
未膨脹けつ岩または膨脹性未膨脹粘土等を1種以上混合
して使用する。
The expanding material may be silica, magnesia, expandable unexpanded vermiculite, expandable unexpanded pumice, expandable unexpanded perlite, magnesium carbonate, sillima.
nite), kyanite (kyanite), andalusite (andal
usite), bauxite, pyrophyllite (py
rophyllite), dolomite, ferric oxide, ferro-ferric oxide, ferrous oxide,
Illite (illite), talc (talc), feldspar (orthoclase),
A mixture of at least one of agalmatolite, zircon, silicon carbide, intumescent unexpanded shale or intumescent unexpanded clay is used.

【0031】膨張材は、耐火及び吸音用被覆組成物が火
事の時に収縮する場合、これに対する体積減少を補償し
て鉄骨及び建築物の被着面に被覆された耐火及び吸音組
成物の収縮に従う体積変化を抑制する。特に、シリカの
場合、高温における体積膨張率が20%ほどである。
When the fire-resistant and sound-absorbing coating composition shrinks in the event of a fire, the expanding material compensates for the decrease in volume, and follows the shrinkage of the fire-resistant and sound-absorbing composition coated on the adhered surface of the steel frame and the building. Suppress volume change. In particular, in the case of silica, the volume expansion coefficient at a high temperature is about 20%.

【0032】従って、被覆材は、外形的変化を起こさな
くて火事中に堅く鉄骨などの被着面を保護するので、被
覆材の耐火性能を向上させる。
Therefore, the coating material protects the adhered surface such as a steel frame firmly during a fire without causing a change in external shape, and thus improves the fire resistance performance of the coating material.

【0033】このような膨張材は、本発明の組成物に対
し5重量%未満の量では、火事の際に充分な役割を期待
できないし、30重量%を越える量を使用すると、火事の
際に被覆材に応力を発生させて被着面から被覆材が離れ
るか又は剥離される原因として作用する。従って、膨張
材は被覆組成物の全体に対し5-30重量%使用することが
好ましい。
When the amount of the expanding material is less than 5% by weight based on the composition of the present invention, it cannot be expected to play a sufficient role in a fire. This causes a stress on the coating material and acts as a cause for the coating material to separate or peel off from the adherend surface. Therefore, it is preferable to use 5-30% by weight of the expanding material based on the whole coating composition.

【0034】炭化性吸音繊維はパルプ、炭素繊維、天然
繊維(例えば綿糸等)、合成繊維(例えばポリエチレン
繊維、ポリスチレン繊維、ポリプロピレン繊維、ポリビ
ニルアルコール繊維等)、化学繊維(例えばレーヨン
等)、化学パルプなどを1種以上混合して使用する。
The carbonizable sound absorbing fiber may be pulp, carbon fiber, natural fiber (eg, cotton yarn), synthetic fiber (eg, polyethylene fiber, polystyrene fiber, polypropylene fiber, polyvinyl alcohol fiber, etc.), chemical fiber (eg, rayon, etc.), chemical pulp. And the like.

【0035】炭化性吸音繊維は耐火及び吸音用被覆組成
物が火事の際に収縮を起こして大形亀裂及び脱落の原因
を除去するものであって、炭化性吸音繊維は火事の際に
その自体が炭化することにより、炭化された空間に沿っ
て被覆材に微細なミクロ亀裂が蜘蛛の糸のように発生し
て、火事時に被覆材に発生される応力を分散させる役割
をして、被覆材が被着面にそのまま付着されて、大形亀
裂及び脱落によりできた隙間に熱が浸透して鉄骨などの
被着面の温度が上昇することを防止する。
The carbonizable sound-absorbing fiber is intended to eliminate the cause of large cracks and falling off due to shrinkage of the fire-resistant and sound-absorbing coating composition during a fire. The carbonization causes fine micro-cracks in the coating along the carbonized space, like spider threads, and plays a role in dispersing the stress generated in the coating during a fire. Is attached to the adherend surface as it is, preventing heat from penetrating into gaps formed by the large cracks and falling off and increasing the temperature of the adherend surface such as a steel frame.

【0036】このような炭化性吸音繊維は本発明の組成
物に対し2重量%未満の量の使用では、充分なミクロ亀
裂を誘導することが難しく、吸音性能を確保することが
難しく、且つ、20重量%を越える量では、製品の強度が
顕著に劣る原因となるため、被覆組成物の全体に対し2-
20重量%の範囲使用する。
When such a carbonizable sound absorbing fiber is used in an amount of less than 2% by weight based on the composition of the present invention, it is difficult to induce sufficient microcracks, it is difficult to secure sound absorbing performance, and If the amount exceeds 20% by weight, the strength of the product is remarkably deteriorated.
Use in the range of 20% by weight.

【0037】吸音性繊維は長さが30mmを越える長さであ
ると、施工の時に被覆材が好ましく形成されないので30
mm以下の長さにするのが好ましい。
If the length of the sound-absorbing fiber is more than 30 mm, the covering material is not preferably formed at the time of construction.
The length is preferably equal to or less than mm.

【0038】以下、その他の添加剤に対し説明する。Hereinafter, other additives will be described.

【0039】界面活性剤は、耐火及び吸音用被覆組成物
の吹き付けコーティングの作業時にスラリの分散性、空
気連行(随伴流)効果及び潤滑性などの物理的性質を向
上させるためのものであって、ナトリウム系、ベンゼン
系、リグニン系、メラミン系の界面活性剤のうち1種以
上選択して被覆組成物全体の1.5重量%以下使用する。
The surfactant is used to improve the physical properties such as the dispersibility of the slurry, the effect of entrained air (entrained flow) and the lubricity during the spray coating operation of the fire-resistant and sound-absorbing coating composition. One or more of sodium, benzene, lignin and melamine surfactants are selected and used in an amount of not more than 1.5% by weight of the whole coating composition.

【0040】増粘剤は、施工収率の向上と乾燥のときに
被覆層の表面の細かい亀裂を防止するためのもので、カ
ルボキシメチルセルロース(CMC)、メチルセルロース、
ポリエチレンオキシド、糖類、膨潤性のある粘土類(ベ
ントナイト、けい藻土など)から1種以上選択して全体
の5重量%以下使用する。
The thickener is used to improve the work yield and prevent fine cracks on the surface of the coating layer during drying. Carboxymethyl cellulose (CMC), methyl cellulose,
One or more selected from polyethylene oxide, sugars, and swellable clays (bentonite, diatomaceous earth, etc.) are used in an amount of 5% by weight or less.

【0041】強度補強材は、特別な強度の発現が求めら
れる場所に使用するものであって、ポリビニルアルコー
ル(PVA)、ポリビニルアセテート(PVAc)、エチレンビニ
ルアセテート(EVA)、レドックス樹脂、硝酸ビニル樹
脂、硝酸塩化ビニル樹脂、アクリル樹脂、ポリウレタ
ン、エポキシ、フェノール樹脂などのうち1種以上選択
して全体の2重量%以内に使用する。
The strength reinforcing material is used in a place where the development of special strength is required, and includes polyvinyl alcohol (PVA), polyvinyl acetate (PVAc), ethylene vinyl acetate (EVA), redox resin, and vinyl nitrate resin. , A vinyl nitrate chloride resin, an acrylic resin, a polyurethane, an epoxy, a phenol resin, etc., to be used within 2% by weight of the total.

【0042】遅延剤は十分な作業時間を付与させるため
のものであって、動物性蛋白質類、糖類などのうち1種
以上選択して全体の2重量%以内に使用する。
The retarder is used to provide a sufficient working time, and one or more of animal proteins, sugars and the like are selected and used within 2% by weight of the whole.

【0043】抗菌剤は黴又は菌類からの防菌及び抗菌を
目的として使用するもので、フェノール系、有機スズ
系、有機水銀系、トリアジン系、第4級アンモニウム塩
系、ハロゲン化スルホニルピリジン系、キャプタン系、
有機銅系、有機窒素系、ヨード系、銀系、クロロナフタ
レン類、デヒドロアビエチルアミンペンタクロロフェノ
ル(dehydroabiethylamine pentachlorophenol)、ペンタ
クロロラウレート(pentachlorolaurate)から1種以上選
択して全体の1重量%以下使用する。
The antibacterial agent is used for the purpose of preventing bacteria and fungi from fungi and fungi, and includes phenol-based, organotin-based, organic mercury-based, triazine-based, quaternary ammonium salt-based, sulfonylpyridine halide-based, Captan type,
Select at least one from organocopper, organic nitrogen, iodine, silver, chloronaphthalenes, dehydroabiethylamine pentachlorophenol, and pentachlorolaurate to 1% by weight or less of the total use.

【0044】このように組成される本発明の耐火及び吸
音被覆組成物は、吹き付け施工のときに1回に60mm以上
の被覆厚さが得られる。
The refractory and sound-absorbing coating composition of the present invention thus formed can provide a coating thickness of 60 mm or more at a time during spraying.

【0045】[0045]

【実施例】以下、本発明の実施例を通じて詳しく説明す
る。これらの実施例は本発明の好ましい組成を提示する
ためのもので、本発明の範疇を限定していない。実施例
1−6と比較例1−3は、本発明に係る被覆組成物を耐
火被覆材用途に使用する場合で、実施例7は吸音材の用
途に使用した場合である。
DESCRIPTION OF THE PREFERRED EMBODIMENTS Hereinafter, the present invention will be described in detail through embodiments. These examples are intended to illustrate preferred compositions of the invention and do not limit the scope of the invention. Example 1-6 and Comparative Example 1-3 are cases where the coating composition according to the present invention is used for a fireproof coating material, and Example 7 is a case where the coating composition is used for a sound absorbing material.

【0046】[0046]

【実施例1−6】表1のような組成にパーライト、セメ
ント、石膏プラスター、シリカ、パルプ及びその他の添
加剤を混合し、ここに適正量の水を混ぜてスラリに作っ
た後、これを試片のH形鋼(300×300×10×20mmt、L2000
mm)の表面にコーティングした。被覆材は被着面に対し
30cmの距離を置き、噴射器を垂直にして吐出量2m3/hr
で吹き出しスプレーコーティングした。被着面にコーテ
ィングされた被覆材を塗装して、1回吹き付け塗装の厚
さを測定した。そして、被着面にコーティングされた被
覆層を、試片の中央部位に垂直に、試片の被着面まで厚
さ測定器を押し入れて、各試片に対し2回ずつ厚さを測
定した。具体的に、厚さ測定ピンが被着面に当たったと
き、被覆材の表面が表面となるように充分な力を加えて
スライディングディスクを作動させた後、測定器を被覆
層から離脱させて厚さ指示器を読んで、1mm単位に厚さ
を測定した。製作された試片を4週間の間放置して充分
に養成させた後、コーティングされた被覆材(被覆層)
の厚さと密度を測定し、肉眼で被覆材の垂れ、剥離及び
亀裂状態を観察した。又、耐火性能を知るため、試片を
それぞれ加熱炉に入れて内部温度を1000℃(KS F 2257及
びASTM E 119による加熱温度)で維持しながら試片の被
覆材コーティング面の温度を測定した。温度測定は試片
に対し被覆材コーティングの前に温度センサを付着して
このセンサにより時間経過に従う温度変化を測定した。
そして、耐火性能試験が終結された後、加熱炉で出して
亀裂の長さ、幅、数及び状態などを測定し、その結果を
表2に示した。
Example 1-6 Perlite, cement, gypsum plaster, silica, pulp and other additives were mixed with the composition shown in Table 1, and an appropriate amount of water was mixed therewith to form a slurry. Specimen H-beam (300 × 300 × 10 × 20mmt, L2000
mm). The coating material should be
To distance of 30 cm, discharge the injectors in the vertical amount 2m 3 / hr
Spray coating. The coating material coated on the surface to be adhered was painted, and the thickness of one-time spray painting was measured. Then, the thickness of the coating layer coated on the adhered surface was pushed into the specimen perpendicular to the center of the specimen to the adhered surface of the specimen, and the thickness was measured twice for each specimen. . Specifically, when the thickness measuring pin hits the surface to be adhered, after applying a sufficient force so that the surface of the coating material becomes the surface and operating the sliding disk, the measuring instrument is detached from the coating layer. Reading the thickness indicator, the thickness was measured in 1 mm units. After leaving the manufactured specimens for 4 weeks and cultivating them sufficiently, the coated coating material (coating layer)
Of the coating material was visually observed for dripping, peeling and cracking of the coating material. In addition, in order to know the fire resistance performance, the test pieces were each placed in a heating furnace, and the temperature of the coating surface of the coating material of the test pieces was measured while maintaining the internal temperature at 1000 ° C. (heating temperature according to KS F 2257 and ASTM E 119). . In the temperature measurement, a temperature sensor was attached to the specimen before coating the coating material, and the temperature change over time was measured by the sensor.
After the fire resistance test was completed, the test pieces were taken out in a heating furnace to measure the length, width, number and state of the cracks, and the results are shown in Table 2.

【0047】[0047]

【比較例1−3】表1の組成に従いパーライト、セメン
ト、石膏プラスター、シリカ、パルプ及びその他の添加
剤を混合し、ここで適正量の水を混ぜてスラリに作った
後、これを試片のH形鋼(300×300×10×15mmt)の表面
をそれぞれコーティングし、養生及び物性測定は実施例
1−6と同様な方法により施した。その結果を表2に示
した。
Comparative Example 1-3 Perlite, cement, gypsum plaster, silica, pulp and other additives were mixed in accordance with the composition shown in Table 1, and an appropriate amount of water was mixed into the slurry to prepare a slurry. The surface of each H-section steel (300 × 300 × 10 × 15 mmt) was coated, and curing and measurement of physical properties were performed in the same manner as in Example 1-6. The results are shown in Table 2.

【0048】[0048]

【表1】 [Table 1]

【0049】[0049]

【表2】 [Table 2]

【0050】前記表2で確認されたように、本発明の耐
火及び吸音用被覆組成物は、鉄骨構造物に対する耐火被
覆材として使用される場合、大韓民国建築法上で要求さ
れる耐火性能(1000℃で1時間:350℃以下)を充分に満
足させると共に、施工後の被覆材の亀裂、剥離及び垂れ
が発生していないことが確認できた。
As can be seen from Table 2, when the fire-resistant and sound-absorbing coating composition of the present invention is used as a fire-resistant coating material for steel structures, the fire resistance performance required by the Korean Building Law (1000) is required. (1 hour at 350 ° C .: 350 ° C. or less), and it was confirmed that cracking, peeling and sagging of the coating material after the application did not occur.

【0051】又、被覆層を20mm程度の厚さで施工するに
際して、実施例1−6で製作された試片、即ち、本発明
に係る被覆組成物を使用した場合は、1000℃の加熱炉で
1時間放置した試片の裏面の温度が大略200℃以下(185
〜211℃)である反面、既存に公知された被覆組成物を
使用した場合は、同一な条件における裏面温度は測定が
不可能であるか100℃以上であることがわかる。これは
従来の組成物自体は耐火性能を満足させているが、火事
に際して被覆材の中大形亀裂の発生と脱落が発生して被
覆体に熱が直接的に浸透するからと認められる。
When the coating layer is applied at a thickness of about 20 mm, the sample manufactured in Example 1-6, that is, when the coating composition according to the present invention is used, a heating furnace of 1000 ° C. The temperature of the back side of the specimen left for 1 hour at approximately 200 ° C or less (185
On the other hand, when a coating composition known in the art is used, the backside temperature under the same conditions cannot be measured or is 100 ° C or higher. This is considered because the conventional composition itself satisfies the fire resistance performance, however, in the event of a fire, medium-sized cracks and falling off of the coating material occur, and heat penetrates directly into the coating.

【0052】さらに、既存の被覆組成物を使用した場合
は、被覆層厚さが20mm以内であるので、1時間、2時間及
び3時間に該当する充分な耐火性能を有する厚さであっ
て、鉄骨構造物を被覆するため、2-5回に亘った吹き付
けコーティングの作業及びコーティングされた被覆材の
硬化過程を経るべきであることがわかる。反面、本発明
により1回吹き付けコーティングの作業で十分な厚さの
被覆層を形成し得ることがわかる。又、時間当たり被覆
材の吹き付け量を従来より2倍以上程度まで増えること
ができて被覆材の施工の経済性を向上することができ
る。
Further, when the existing coating composition is used, the thickness of the coating layer is within 20 mm, so that it has a sufficient fire resistance performance corresponding to 1 hour, 2 hours and 3 hours, It can be seen that in order to coat the steel structure, 2-5 spray coating operations and a curing process of the coated coating should be performed. On the other hand, it is understood that a coating layer having a sufficient thickness can be formed by a single spray coating operation according to the present invention. Further, the spraying amount of the coating material per hour can be increased to about twice or more as compared with the related art, and the economical efficiency of the coating material application can be improved.

【0053】実施例7 実施例1のような組成でパーライト、セメント、石膏プ
ラスター、シリカ、パルプ及び添加剤混合物を適正量の
水と混合してスラリに作り、単位試片としては10mm厚
さ、1.2m×1.2m大きさの石綿セメント板と、50mm厚さ、
1.2m×1.2m大きさの発泡スチレンを基材として用いてそ
の上に被覆組成物をコーティングした。
Example 7 Perlite, cement, gypsum plaster, silica, pulp and an additive mixture having the same composition as in Example 1 were mixed with an appropriate amount of water to form a slurry. 1.2m x 1.2m asbestos cement board and 50mm thickness,
The coating composition was coated thereon using 1.2 mx 1.2 m expanded styrene as a substrate.

【0054】石綿セメントにそれぞれ10mm(試片1)、
20mm(試片2)、30mm(試片3)及び50mm(試片4)厚
さで被覆組成物を吹き付けコーティングし、又、発泡ス
チレンを基材にそれぞれ10mm(試片5)と20mm(試片
6)の厚さで被覆組成物を吹き付けコーティングした。
製作された試片の密度は320-370kg/m3の範囲であった。
10 mm each of asbestos cement (sample 1),
The coating composition was spray-coated at a thickness of 20 mm (sample 2), 30 mm (sample 3) and 50 mm (sample 4), and 10 mm (sample 5) and 20 mm (sample The coating composition was spray-coated at the thickness of piece 6).
Density of the fabricated specimens ranged from 320-370kg / m 3.

【0055】前記試片1-6を吸音室に運搬して吸音性能
測定のために単位試片を組合せ、吸音率測定法中に残響
室法のKS F 2805に規定された試片大きさに適合するよ
うに、2.93m×3.63m、全体面積10.64m2を吸音室の中央
に設置した後、鉄材フレームで四辺を巻き、その隙間は
テープと建築用シーラントで密封した後、吸音率を測定
した。このとき、単位試片の間は同じ材質で充填し、残
響室法により測定したNRC(Noise Reduction Cofficien
t:平均吸音率)を次の表3に示した。
The test piece 1-6 was transported to the sound absorbing chamber, and the unit test pieces were combined for sound absorption performance measurement. During the sound absorption coefficient measurement method, the sample size specified in KS F 2805 of the reverberation chamber method was used. to fit, 2.93m × 3.63m, after placing the whole area 10.64M 2 in the center of the acoustic chamber, winding the four sides with iron frame, then the gap is sealed with a sealant for buildings and tape, measuring the sound absorption rate did. At this time, the unit specimens were filled with the same material, and NRC (Noise Reduction Cofficien
t: average sound absorption coefficient) is shown in Table 3 below.

【0056】[0056]

【表3】 [Table 3]

【0057】前記表3の実験結果は試片を一体に作って
測定した値ではない。従って、試片を結合せず一体に製
作した場合は、継ぎ目がなくなって平均吸音率は一層よ
くなる。
The experimental results in Table 3 are not values measured by integrally preparing test pieces. Therefore, when the test pieces are integrally manufactured without being joined, the seams are eliminated and the average sound absorption coefficient is further improved.

【0058】表3から分かるように、基材として発泡ス
チレンを使用した場合、吸音率が若干優れており、基材
として発泡スチレンを使用しなくても本発明の組成物は
50mmに塗布する場合、平均吸音率が0.72以上に通常の吸
音材よりも優れている。しかし、低周波帯における吸音
率は、全ての多孔質吸音材のように、基材として板振動
形吸音材、例えば、合板、石綿セメント板、石膏ボード
などを使用することが好ましく、特に発泡スチレンのよ
うな発泡スチロール樹脂を使用すれば一層好ましい。
As can be seen from Table 3, when foamed styrene was used as the base material, the sound absorption coefficient was slightly superior, and even when foamed styrene was not used as the base material, the composition of the present invention could be used.
When applied to 50 mm, the average sound absorption coefficient is 0.72 or more, which is superior to ordinary sound absorbing materials. However, the sound absorption coefficient in the low frequency band is, like all porous sound absorbing materials, it is preferable to use a plate vibration type sound absorbing material as a base material, for example, plywood, asbestos cement board, gypsum board, etc. It is more preferable to use a foamed styrene resin as described above.

【0059】[0059]

【発明の効果】以上説明したように、本発明に係る耐火
及び吸音用被覆組成物は、耐火性能において大韓民国建
築法上の耐火性能(350℃以下)を満足するためには、厚
さ(1時間)が20mmであれば充分であり、従来の耐火被
覆材を使用したよりも耐火性能が優れている。即ち、軽
量骨材の無数な気孔による熱遮断効果など多様な耐火メ
カニズムにより大韓民国建築法上の耐火基準で基準温度
限界を維持し得る厚さを最小化できる。それとともに、
被覆体から被覆材が脱落しないようにして、実質的な耐
火性能が保障され、吸音効果が優れており、作業性の向
上を含めて周辺環境に対する悪影響を最大限に減らすこ
とができる。特に、本発明は、火事の際して被覆材にミ
クロ亀裂を誘導して充分な耐火性能が火事鎮圧時まで被
覆材が被着面に付着維持されるようにして、鉄骨の火事
に対する安全性を実質的に大きく向上させている。
As described above, the fire-resistant and sound-absorbing coating composition according to the present invention has a thickness (1) in order to satisfy the fire resistance (350 ° C. or less) according to the Korean Building Law in fire resistance. A time of 20 mm is sufficient, and the fire resistance is superior to that of a conventional fire-resistant coating material. That is, the thickness that can maintain the reference temperature limit in accordance with the fire resistance standard in the Republic of Korea can be minimized by various fire resistance mechanisms such as the heat blocking effect by the countless pores of the lightweight aggregate. With it,
By preventing the coating material from falling off the coating, substantial fire resistance performance is ensured, the sound absorbing effect is excellent, and the adverse effect on the surrounding environment including workability can be minimized. In particular, the present invention provides a method for inducing micro-cracks in a cladding material during a fire so that sufficient fire resistance is maintained so that the cladding material adheres to an adherend surface until the time of fire suppression. Is substantially improved.

フロントページの続き (51)Int.Cl.7 識別記号 FI テーマコート゛(参考) E04B 1/76 E04B 1/76 E 1/94 1/94 E (72)発明者 ジュン サンオク 大韓民国、780−130 キュンジュ−シテ ィ、ホワンンサン−ドン、101−1206、セ イミック アパートメントContinued on the front page (51) Int.Cl. 7 Identification symbol FI Theme coat II (Reference) E04B 1/76 E04B 1/76 E 1/94 1/94 E (72) Inventor Jun Sang-ok Korea, 780-130 Citi, Hwangsan-dong, 101-1206, Themic Apartment

Claims (12)

【特許請求の範囲】[Claims] 【請求項1】 軽量骨材25-60重量%の範囲、結合材20-
60重量%の範囲、吸熱材50重量%以下、膨張材5-30重量
%の範囲、及び炭化性吸音繊維2-20重量%の範囲を含む
耐火及び吸音用被覆組成物。
1. Light weight aggregate in the range of 25-60% by weight, binder 20-
A fire and sound absorbing coating composition comprising 60% by weight, 50% by weight or less of heat absorbing material, 5-30% by weight of intumescent material, and 2-20% by weight of carbonizable sound absorbing fiber.
【請求項2】 軽量骨材は、膨張或いは未膨張のパーラ
イト、軽石、バーミキュライト、火山災及び浮石から選
ばれる少なくとも一つの天然無機質鉱物質、人工的にガ
ラス系又は鉱物質に無数の微細気孔を形成した中空球
体、及び粒状発泡スチロール樹脂または破砕発泡スチロ
ール樹脂からなる有機質骨材のうちから選択された一種
以上であることを特徴とする請求項1に記載の耐火及び
吸音用被覆組成物。
2. The lightweight aggregate has at least one natural mineral mineral selected from expanded or unexpanded pearlite, pumice, vermiculite, volcanic disaster and spar, artificially glass or mineral, and has numerous micropores. 2. The fire-resistant and sound-absorbing coating composition according to claim 1, wherein the coating composition is at least one selected from a formed hollow sphere and an organic aggregate made of a granular polystyrene resin or a crushed polystyrene resin.
【請求項3】 結合材は、ポートランドセメント、高炉
セメント、シリカセメント、アルミナセメント、マグネ
シアセメント、石膏、石膏プラスター、マグネシア及び
硫酸マグネシウムのうちから選択された一種以上である
ことを特徴とする請求項1に記載の耐火及び吸音用被覆
組成物。
3. The binder according to claim 1, wherein the binder is at least one selected from Portland cement, blast furnace cement, silica cement, alumina cement, magnesia cement, gypsum, gypsum plaster, magnesia and magnesium sulfate. Item 4. The coating composition for refractory and sound absorption according to Item 1.
【請求項4】 吸熱材は、石灰、消石灰、生石灰、二水
石膏、半水石膏、石膏プラスター、水酸化アルミニウ
ム、水酸化マグネシウム、炭酸マグネシウム、炭酸カル
シウム、硫酸アルミニウム、ほう砂、モンモリロナイ
ト、ベントナイト、炭酸水素ナトリウム及びケイ酸ナト
リウムのうちから選択された一種以上であることを特徴
とする請求項1に記載の耐火及び吸音用被覆組成物。
4. The heat absorbing material includes lime, slaked lime, quicklime, gypsum dihydrate, hemihydrate gypsum, gypsum plaster, aluminum hydroxide, magnesium hydroxide, magnesium carbonate, calcium carbonate, aluminum sulfate, borax, montmorillonite, bentonite, The fire-resistant and sound-absorbing coating composition according to claim 1, wherein the coating composition is at least one selected from sodium hydrogen carbonate and sodium silicate.
【請求項5】 膨張材は、シリカ、マグネシア、膨張性
未膨張バーミキュライト、膨張性未膨張軽石,膨張性未
膨張パーライト、炭酸マグネシウム、ケイセン石(silli
manite)、カイヤナイト(kyanite)、アンダルサイト(and
alusite)、ボーキサイト(bauxite)、パイロフィライト
(pyrophyllite)、ドロマイト(dolomite)、酸化第二鉄、
フェロ-酸化第二鉄(ferro-ferric oxide)、酸化第一
鉄、イライト(illite)、滑石(talc)、正長石(orthoclas
e)、ロウ石(agalmatolite)、ジルコン、炭化ケイ素、膨
脹性未膨脹けつ岩、及び膨脹性未膨脹粘土のうちから選
択された一種以上であることを特徴とする請求項1に記
載の耐火及び吸音用被覆組成物。
5. The expanding material is silica, magnesia, expandable unexpanded vermiculite, expandable unexpanded pumice, expandable unexpanded perlite, magnesium carbonate, sillimanite.
manite), kyanite, andalusite (and
alusite), bauxite, pyrophyllite
(pyrophyllite), dolomite, ferric oxide,
Ferro-ferric oxide, ferrous oxide, illite, talc, talc, orthoclas
e), algite, zircon, silicon carbide, intumescent unexpanded shale, and intumescent unexpanded clay, at least one selected from the group consisting of fireproof and refractory clays according to claim 1, wherein A coating composition for sound absorption.
【請求項6】 炭化性吸音繊維は、パルプ、炭素繊維、
天然繊維、合成繊維、化学繊維及び化学パルプのうちか
ら選択された一種以上であることを特徴とする請求項1
に記載の耐火及び吸音用被覆組成物。
6. The carbonizable sound absorbing fiber is pulp, carbon fiber,
2. The method according to claim 1, wherein the fiber is at least one selected from natural fibers, synthetic fibers, chemical fibers and chemical pulp.
4. The coating composition for refractory and sound absorption according to claim 1.
【請求項7】 添加剤として選択的に界面活性剤、増粘
剤、強度補強剤、遅延剤及び抗菌剤のうち一種以上含め
て構成することを特徴とする請求項1に記載の耐火及び
吸音用被覆組成物。
7. The fire-resistant and sound-absorbing composition according to claim 1, wherein the additive comprises at least one of a surfactant, a thickener, a strength reinforcing agent, a retarder and an antibacterial agent. Coating composition.
【請求項8】 界面活性剤は、ナトリウム系、ベンゼン
系、リグニン系及びメラミン系のうち選択された一種以
上が1.5重量%以下添加されたものであることを特徴と
する請求項7に記載の耐火及び吸音用被覆組成物。
8. The method according to claim 7, wherein the surfactant contains at least 1.5% by weight of at least one selected from sodium, benzene, lignin and melamine. Fire resistant and sound absorbing coating compositions.
【請求項9】 増粘剤は、カルボキシメチルセルロー
ス、メチルセルロース、ポリエチレンオキシド、糖類及
び膨潤性のある粘土類から選択された一種以上が5重量
%以下添加されたものであることを特徴とする請求項7
に記載の耐火及び吸音用被覆組成物。
9. The thickener according to claim 1, wherein at least one selected from carboxymethylcellulose, methylcellulose, polyethylene oxide, saccharides and swellable clays is added in an amount of 5% by weight or less. 7
4. The coating composition for refractory and sound absorption according to claim 1.
【請求項10】 強度補強材は、ポリビニルアルコー
ル、ポリビニルアセテート、エチレンビニルアセテー
ト、レドックス樹脂、硝酸ビニル樹脂、硝酸塩化ビニル
樹脂、アクリル樹脂、ポリウレタン、エポキシ及びフェ
ノール樹脂のうちから選択された一種以上が2重量%以
下添加されたものであることを特徴とする請求項7に記
載の耐火及び吸音用被覆組成物。
10. The strength reinforcing material may be at least one selected from polyvinyl alcohol, polyvinyl acetate, ethylene vinyl acetate, redox resin, vinyl nitrate resin, vinyl nitrate resin, acrylic resin, polyurethane, epoxy and phenol resin. The fire-resistant and sound-absorbing coating composition according to claim 7, which is added in an amount of 2% by weight or less.
【請求項11】 遅延剤は、動物性蛋白質類又は糖類で
選択された一種以上が2重量%以下添加されたものであ
ることを特徴とする請求項7に記載の耐火及び吸音用被
覆組成物。
11. The fire-resistant and sound-absorbing coating composition according to claim 7, wherein at least one selected from animal proteins or sugars is added to the retarder in an amount of 2% by weight or less. .
【請求項12】 抗菌剤は、フェノール系、有機すず
系、有機水銀系、トリアジン系、第4級アンモニウム塩
系、ハロゲン化スルホニルピリジン系、キャプタン系、
有機銅系、有機窒素系、ヨード系、銀系、クロロナフタ
レン類、デヒドロアビエチルアミンペンタクロロフェノ
ール類及びペンタクロロラウレート類のうちから選択さ
れた一種以上が1重量%以下添加されたものであること
を特徴とする請求項7に記載の耐火及び吸音用被覆組成
物。
12. Antibacterial agents include phenol-based, organotin-based, organic mercury-based, triazine-based, quaternary ammonium salt-based, halogenated sulfonylpyridine-based, captan-based,
One or more selected from organocopper, organic nitrogen, iodine, silver, chloronaphthalenes, dehydroabiethylamine pentachlorophenols and pentachlorolaurate in an amount of 1% by weight or less. The coating composition for fireproof and sound absorbing according to claim 7, characterized in that:
JP12760399A 1998-05-15 1999-05-07 Coating composition for fire protection and sound absorption Pending JP2000001380A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
KR1019980017649A KR100272624B1 (en) 1998-05-15 1998-05-15 Fireproofing and sound-absorbing composition
KR98-17649 1998-05-15

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Publication Number Publication Date
JP2000001380A true JP2000001380A (en) 2000-01-07

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ID=19537400

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KR (1) KR100272624B1 (en)
CN (1) CN1175062C (en)
DE (1) DE19922247A1 (en)

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KR100272624B1 (en) 2000-12-01
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CN1175062C (en) 2004-11-10
CN1269385A (en) 2000-10-11

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