JPWO2021232784A5 - Method for producing highly wear-resistant far-infrared ceramic polished glaze tiles - Google Patents
Method for producing highly wear-resistant far-infrared ceramic polished glaze tiles Download PDFInfo
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- 238000004519 manufacturing process Methods 0.000 title claims 5
- 239000000919 ceramic Substances 0.000 title claims 3
- 239000010433 feldspar Substances 0.000 claims description 10
- 239000000843 powder Substances 0.000 claims description 10
- 239000000203 mixture Substances 0.000 claims description 9
- 239000005995 Aluminium silicate Substances 0.000 claims description 6
- 235000012211 aluminium silicate Nutrition 0.000 claims description 6
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 6
- 229910018072 Al 2 O 3 Inorganic materials 0.000 claims description 4
- 229910004298 SiO 2 Inorganic materials 0.000 claims description 4
- 229910052500 inorganic mineral Inorganic materials 0.000 claims description 4
- 239000011707 mineral Substances 0.000 claims description 4
- 239000000126 substance Substances 0.000 claims description 4
- 150000001875 compounds Chemical class 0.000 claims description 3
- 239000006004 Quartz sand Substances 0.000 claims description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 2
- 229910052656 albite Inorganic materials 0.000 claims description 2
- HZVVJJIYJKGMFL-UHFFFAOYSA-N almasilate Chemical compound O.[Mg+2].[Al+3].[Al+3].O[Si](O)=O.O[Si](O)=O HZVVJJIYJKGMFL-UHFFFAOYSA-N 0.000 claims description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 2
- 239000012535 impurity Substances 0.000 claims description 2
- 150000002500 ions Chemical class 0.000 claims description 2
- GFQYVLUOOAAOGM-UHFFFAOYSA-N zirconium(iv) silicate Chemical compound [Zr+4].[O-][Si]([O-])([O-])[O-] GFQYVLUOOAAOGM-UHFFFAOYSA-N 0.000 claims description 2
- 238000005498 polishing Methods 0.000 claims 11
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims 8
- 238000000034 method Methods 0.000 claims 4
- 239000011787 zinc oxide Substances 0.000 claims 4
- 229910010413 TiO 2 Inorganic materials 0.000 claims 3
- AYJRCSIUFZENHW-DEQYMQKBSA-L barium(2+);oxomethanediolate Chemical compound [Ba+2].[O-][14C]([O-])=O AYJRCSIUFZENHW-DEQYMQKBSA-L 0.000 claims 2
- 239000011521 glass Substances 0.000 claims 2
- 230000005484 gravity Effects 0.000 claims 2
- 239000000454 talc Substances 0.000 claims 2
- 229910052623 talc Inorganic materials 0.000 claims 2
- 230000004580 weight loss Effects 0.000 claims 2
- 229910052593 corundum Inorganic materials 0.000 claims 1
- 239000010431 corundum Substances 0.000 claims 1
- 238000010304 firing Methods 0.000 claims 1
- 238000007641 inkjet printing Methods 0.000 claims 1
- 239000000463 material Substances 0.000 claims 1
- MCMNRKCIXSYSNV-UHFFFAOYSA-N ZrO2 Inorganic materials O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 2
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 2
- 229910052613 tourmaline Inorganic materials 0.000 description 2
- 239000011032 tourmaline Substances 0.000 description 2
- 229940070527 tourmaline Drugs 0.000 description 2
- 238000009472 formulation Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
Description
本発明の実施形態の遠赤外線表面釉薬処方の鉱物組成は、質量で、遠赤外線長石粉末３０％～４０％、曹長石：１０～２０％、カオリン５％～１０％、石英砂１５％～２５％、ケイ酸ジルコニウム５％～１５％、か焼カオリン５％～１０％、アルミナ５％～１０％を含む。遠赤外線長石粉末とは、遠赤外線放射率の高い長石粉末の一種で、不純物イオンをドープした、格子が高度に非対称なマグネシウムアルミノケイ酸塩を含む化合物であり、該化合物は高い遠赤外線放射率を持っている。一つの実施例では、その化学組成は、質量で、ＳｉＯ２：７０～８０％、Ａｌ２Ｏ３：１０～１３％、Ｆｅ２Ｏ３：０．３～０．５％、Ｐ２Ｏ５：０．２５～０．３５％、ＣａＯ：０．５～１．０％、ＭｇＯ：０．８～１．２％、Ｒｂ２Ｏ：４００ｐｐｍ～４５０ｐｐｍ、Ｙ２Ｏ３：２８０ｐｐｍ～３２０ｐｐｍ、Ｋ２Ｏ：８．０～９．０％、Ｎａ２Ｏ：２．０～３．０％、強熱減量：０．５～１．０％である。その遠赤外線放射率は０．９１以上に達することができる。この分野では、トルマリン、二酸化ジルコニウムなどが一般的に遠赤外線機能を提供するために使用されるが、トルマリンはヒドロキシシリケート化合物であり、９５０度を超える温度で分解し、構造が破壊され、遠赤外線放射率が大幅に削減され、二酸化ジルコニウムの分離は難しく、コストは比較的高く、放射性は比較的高い。遠赤外線長石粉末は、優れた高温安定性と低い放射性を持っている。この実施形態では、遠赤外線長石粉末を使用して遠赤外線機能を提供し、放射性なしで低コストで高い遠赤外線放射率を提供でき、人体および環境に害を及ぼさない。 The mineral composition of the far-infrared surface glaze formulation of the embodiment of the present invention is, by mass, far-infrared feldspar powder 30% to 40%, albite: 10 to 20%, kaolin 5% to 10%, quartz sand 15% to 25%. %, zirconium silicate 5%-15%, calcined kaolin 5%-10%, alumina 5%-10%. Far-infrared feldspar powder is a type of feldspar powder with high far-infrared emissivity, and is a compound containing magnesium aluminosilicate with a highly asymmetric lattice doped with impurity ions. have. In one embodiment, the chemical composition is, by weight, SiO 2 : 70-80%, Al 2 O 3 : 10-13%, Fe 2 O 3 : 0.3-0.5%, P 2 O 5 : 0.25 to 0.35%, CaO: 0.5 to 1.0%, MgO: 0.8 to 1.2%, Rb 2 O: 400 ppm to 450 ppm, Y 2 O 3 : 280 ppm to 320 ppm, K 2 O: 8.0 to 9.0%, Na 2 O: 2.0 to 3.0%, and loss on ignition: 0.5 to 1.0%. Its far-infrared emissivity can reach more than 0.91. In this field, tourmaline, zirconium dioxide, etc. are commonly used to provide far-infrared functionality, but tourmaline is a hydroxysilicate compound that decomposes at temperatures above 950 degrees, destroying its structure and producing far-infrared The emissivity is greatly reduced, the separation of zirconium dioxide is difficult, the cost is relatively high, and the radioactivity is relatively high. Far-infrared feldspar powder has excellent high temperature stability and low radioactivity. In this embodiment, far-infrared feldspar powder is used to provide far-infrared function, which can provide high far-infrared emissivity at low cost without radioactivity, and does not harm the human body and environment.
Claims (6)
ここで、前記遠赤外線表面釉薬の化学組成は、質量で、ＳｉＯ２：６３％～７３％、Ａｌ２Ｏ３：１６％～２４％、Ｆｅ２Ｏ３：０．５～０．７％、ＴｉＯ２：０．２５～０．３５％、ＣａＯ：０．３～０．６％、ＭｇＯ：０．４～１．０％、Ｋ２Ｏ：３．０～４．０％、Ｎａ２Ｏ：１．５～２．５％、ＺｒＯ２：３．２～９．６％、Ｒｂ２Ｏ：１２０～１８０ｐｐｍ、Ｙ２Ｏ３：９０～１３０ｐｐｍ、強熱減量：１．１～１．５％を含み、
前記透明な遠赤外線研磨釉薬の化学組成は、質量で、ＳｉＯ２：５０％～６０％、Ａｌ２Ｏ３：６％～８％、Ｆｅ２Ｏ３：０．２～０．３％、ＴｉＯ２：０．２５～０．３５％、ＣａＯ：５．５～８．５％、ＭｇＯ：３．１～４．２％、ＢａＯ：３．５～６．５％、ＺｎＯ：８．０～１３．０％、Ｋ２Ｏ：３．０～４．０％、Ｎａ２Ｏ：１．０～２．０％、Ｒｂ２Ｏ：１００～１５５ｐｐｍ、Ｙ２Ｏ３：７０～１１０ｐｐｍ、強熱減量：２．０～３．５％を含み、
前記耐摩耗性の遠赤外線研磨釉薬の化学組成は、質量で、ＳｉＯ２：４０～５０％、Ａｌ２Ｏ３：９～１１．５％、Ｆｅ２Ｏ３：０．２～０．３％、ＴｉＯ２：０．２５～０．３５％、ＣａＯ：６～８．５％、ＭｇＯ：２．５～４．５％、ＢａＯ：９．５～１３．０％、ＺｎＯ：１０．０～１６．０％、Ｋ２Ｏ：２．０～４．０％、Ｎａ２Ｏ：０．６～１．０％、Ｒｂ２Ｏ：６０～１１０ｐｐｍ、Ｙ２Ｏ３：４０～８０ｐｐｍ、強熱減量：３．５～５．０％を含み、
さらに、前記遠赤外線表面釉薬、前記透明な遠赤外線研磨釉薬、前記耐摩耗性の遠赤外線研磨釉薬は、遠赤外線長石粉末を使用して遠赤外線機能を提供し、かつ前記遠赤外線長石粉末は不純物イオンがドープされ、格子が高度に非対称なマグネシウムアルミノケイ酸塩を含む化合物であることを特徴とする高耐摩耗性の遠赤外線セラミック研磨釉薬タイルの製造方法。 A method for producing highly wear-resistant far-infrared ceramic polished glaze tiles, comprising sequentially applying far-infrared surface glaze, inkjet printing, transparent far-infrared polishing glaze, and wear-resistant far-infrared polishing glaze on the base material, and then Including firing and polishing,
Here, the chemical composition of the far-infrared surface glaze is, by mass, SiO 2 : 63% to 73%, Al 2 O 3 : 16% to 24%, Fe 2 O 3 : 0.5 to 0.7%, TiO 2 : 0.25-0.35%, CaO: 0.3-0.6%, MgO: 0.4-1.0%, K 2 O: 3.0-4.0%, Na 2 O : 1.5 to 2.5%, ZrO 2 : 3.2 to 9.6%, Rb 2 O: 120 to 180 ppm, Y 2 O 3 : 90 to 130 ppm, loss on ignition: 1.1 to 1.5 including %,
The chemical composition of the transparent far-infrared polishing glaze is, by mass, SiO 2 : 50% to 60%, Al 2 O 3 : 6% to 8%, Fe 2 O 3 : 0.2 to 0.3%, TiO 2 : 0.25-0.35%, CaO: 5.5-8.5%, MgO: 3.1-4.2%, BaO: 3.5-6.5%, ZnO: 8.0- 13.0%, K 2 O: 3.0-4.0%, Na 2 O: 1.0-2.0%, Rb 2 O: 100-155 ppm, Y 2 O 3 : 70-110 ppm, ignition Weight loss: Contains 2.0-3.5%,
The chemical composition of the wear-resistant far-infrared polishing glaze is, by mass, SiO 2 : 40-50%, Al 2 O 3 : 9-11.5%, Fe 2 O 3 : 0.2-0.3%. , TiO 2 : 0.25-0.35%, CaO: 6-8.5%, MgO: 2.5-4.5%, BaO: 9.5-13.0%, ZnO: 10.0- 16.0%, K 2 O: 2.0-4.0%, Na 2 O: 0.6-1.0%, Rb 2 O: 60-110 ppm, Y 2 O 3 : 40-80 ppm, ignition Weight loss: Contains 3.5-5.0%,
Furthermore, the far-infrared surface glaze, the transparent far-infrared polishing glaze, and the wear-resistant far-infrared polishing glaze use far-infrared feldspar powder to provide far-infrared function, and the far-infrared feldspar powder is free of impurities. A method for producing a far-infrared ceramic polished glaze tile with high wear resistance, characterized in that it is a compound containing magnesium aluminosilicate doped with ions and whose lattice is highly asymmetric .
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| CN202010422883.0 | 2020-05-19 | ||
| CN202010422883.0A CN111333433B (en) | 2020-05-19 | 2020-05-19 | High-wear-resistance far-infrared ceramic glazed brick and preparation method thereof |
| PCT/CN2020/138630 WO2021232784A1 (en) | 2020-05-19 | 2020-12-23 | High-wear-resistance far-infrared ceramic polished glazed tile and preparation method therefor |
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| EP (1) | EP4155283A4 (en) |
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