JPS6356895B2 - - Google Patents
Info
- Publication number
- JPS6356895B2 JPS6356895B2 JP56071375A JP7137581A JPS6356895B2 JP S6356895 B2 JPS6356895 B2 JP S6356895B2 JP 56071375 A JP56071375 A JP 56071375A JP 7137581 A JP7137581 A JP 7137581A JP S6356895 B2 JPS6356895 B2 JP S6356895B2
- Authority
- JP
- Japan
- Prior art keywords
- rubber
- resin composition
- present
- weight
- polymer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000011342 resin composition Substances 0.000 claims description 43
- 239000002245 particle Substances 0.000 claims description 41
- 229920001890 Novodur Polymers 0.000 claims description 40
- -1 polysiloxane Polymers 0.000 claims description 36
- 238000000034 method Methods 0.000 claims description 35
- 229920001296 polysiloxane Polymers 0.000 claims description 34
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 22
- 229920000642 polymer Polymers 0.000 claims description 21
- 239000000203 mixture Substances 0.000 claims description 19
- 238000006116 polymerization reaction Methods 0.000 claims description 14
- 229910052710 silicon Inorganic materials 0.000 claims description 13
- 238000012662 bulk polymerization Methods 0.000 claims description 11
- 238000009826 distribution Methods 0.000 claims description 11
- 239000006185 dispersion Substances 0.000 claims description 8
- 239000010703 silicon Substances 0.000 claims description 5
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 claims description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical group C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 31
- 229920001971 elastomer Polymers 0.000 description 29
- 229920005989 resin Polymers 0.000 description 23
- 239000011347 resin Substances 0.000 description 23
- 238000002156 mixing Methods 0.000 description 17
- 239000000178 monomer Substances 0.000 description 16
- 238000003756 stirring Methods 0.000 description 13
- 230000000052 comparative effect Effects 0.000 description 8
- 238000006243 chemical reaction Methods 0.000 description 7
- 230000000694 effects Effects 0.000 description 7
- 238000010558 suspension polymerization method Methods 0.000 description 7
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
- 238000004458 analytical method Methods 0.000 description 6
- 239000000243 solution Substances 0.000 description 6
- 239000000654 additive Substances 0.000 description 5
- 238000011156 evaluation Methods 0.000 description 5
- 238000005469 granulation Methods 0.000 description 5
- 230000003179 granulation Effects 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 5
- 150000003440 styrenes Chemical class 0.000 description 5
- YNQLUTRBYVCPMQ-UHFFFAOYSA-N Ethylbenzene Chemical compound CCC1=CC=CC=C1 YNQLUTRBYVCPMQ-UHFFFAOYSA-N 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 238000000465 moulding Methods 0.000 description 4
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 239000004205 dimethyl polysiloxane Substances 0.000 description 3
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 125000000962 organic group Chemical group 0.000 description 3
- 239000008188 pellet Substances 0.000 description 3
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 3
- 229920002857 polybutadiene Polymers 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 2
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- 238000010894 electron beam technology Methods 0.000 description 2
- 238000000635 electron micrograph Methods 0.000 description 2
- 229920000578 graft copolymer Polymers 0.000 description 2
- 229940057995 liquid paraffin Drugs 0.000 description 2
- 229920001921 poly-methyl-phenyl-siloxane Polymers 0.000 description 2
- 239000003505 polymerization initiator Substances 0.000 description 2
- 230000000379 polymerizing effect Effects 0.000 description 2
- 239000005060 rubber Substances 0.000 description 2
- 229920003048 styrene butadiene rubber Polymers 0.000 description 2
- 230000008961 swelling Effects 0.000 description 2
- 229920005992 thermoplastic resin Polymers 0.000 description 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- YAJYJWXEWKRTPO-UHFFFAOYSA-N 2,3,3,4,4,5-hexamethylhexane-2-thiol Chemical compound CC(C)C(C)(C)C(C)(C)C(C)(C)S YAJYJWXEWKRTPO-UHFFFAOYSA-N 0.000 description 1
- SBYMUDUGTIKLCR-UHFFFAOYSA-N 2-chloroethenylbenzene Chemical class ClC=CC1=CC=CC=C1 SBYMUDUGTIKLCR-UHFFFAOYSA-N 0.000 description 1
- FCYVWWWTHPPJII-UHFFFAOYSA-N 2-methylidenepropanedinitrile Chemical compound N#CC(=C)C#N FCYVWWWTHPPJII-UHFFFAOYSA-N 0.000 description 1
- CEBRPXLXYCFYGU-UHFFFAOYSA-N 3-methylbut-1-enylbenzene Chemical class CC(C)C=CC1=CC=CC=C1 CEBRPXLXYCFYGU-UHFFFAOYSA-N 0.000 description 1
- JLBJTVDPSNHSKJ-UHFFFAOYSA-N 4-Methylstyrene Chemical compound CC1=CC=C(C=C)C=C1 JLBJTVDPSNHSKJ-UHFFFAOYSA-N 0.000 description 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 1
- 239000004610 Internal Lubricant Substances 0.000 description 1
- GYCMBHHDWRMZGG-UHFFFAOYSA-N Methylacrylonitrile Chemical compound CC(=C)C#N GYCMBHHDWRMZGG-UHFFFAOYSA-N 0.000 description 1
- 239000005062 Polybutadiene Substances 0.000 description 1
- 150000001253 acrylic acids Chemical class 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 125000003545 alkoxy group Chemical group 0.000 description 1
- 125000005907 alkyl ester group Chemical group 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 1
- 125000003277 amino group Chemical group 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- 239000008346 aqueous phase Substances 0.000 description 1
- 125000003710 aryl alkyl group Chemical group 0.000 description 1
- 238000001479 atomic absorption spectroscopy Methods 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 229920001400 block copolymer Polymers 0.000 description 1
- MPMBRWOOISTHJV-UHFFFAOYSA-N but-1-enylbenzene Chemical class CCC=CC1=CC=CC=C1 MPMBRWOOISTHJV-UHFFFAOYSA-N 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 238000005119 centrifugation Methods 0.000 description 1
- 238000004581 coalescence Methods 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 230000018044 dehydration Effects 0.000 description 1
- 238000006297 dehydration reaction Methods 0.000 description 1
- LSXWFXONGKSEMY-UHFFFAOYSA-N di-tert-butyl peroxide Chemical compound CC(C)(C)OOC(C)(C)C LSXWFXONGKSEMY-UHFFFAOYSA-N 0.000 description 1
- 150000001993 dienes Chemical class 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 125000003700 epoxy group Chemical group 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 238000010528 free radical solution polymerization reaction Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- KETWBQOXTBGBBN-UHFFFAOYSA-N hex-1-enylbenzene Chemical class CCCCC=CC1=CC=CC=C1 KETWBQOXTBGBBN-UHFFFAOYSA-N 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 239000003999 initiator Substances 0.000 description 1
- 230000001678 irradiating effect Effects 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 125000005395 methacrylic acid group Chemical class 0.000 description 1
- 239000011259 mixed solution Substances 0.000 description 1
- 239000006082 mold release agent Substances 0.000 description 1
- 150000001451 organic peroxides Chemical class 0.000 description 1
- 150000003961 organosilicon compounds Chemical class 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920005604 random copolymer Polymers 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 229920002379 silicone rubber Polymers 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 238000001256 steam distillation Methods 0.000 description 1
- 238000010557 suspension polymerization reaction Methods 0.000 description 1
- 229920001897 terpolymer Polymers 0.000 description 1
- GJBRNHKUVLOCEB-UHFFFAOYSA-N tert-butyl benzenecarboperoxoate Chemical compound CC(C)(C)OOC(=O)C1=CC=CC=C1 GJBRNHKUVLOCEB-UHFFFAOYSA-N 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 150000003673 urethanes Chemical class 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
- Silicon Polymers (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP7137581A JPS57187346A (en) | 1981-05-14 | 1981-05-14 | Improved rubber-modified styrene resin composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP7137581A JPS57187346A (en) | 1981-05-14 | 1981-05-14 | Improved rubber-modified styrene resin composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS57187346A JPS57187346A (en) | 1982-11-18 |
| JPS6356895B2 true JPS6356895B2 (de) | 1988-11-09 |
Family
ID=13458686
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP7137581A Granted JPS57187346A (en) | 1981-05-14 | 1981-05-14 | Improved rubber-modified styrene resin composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS57187346A (de) |
Families Citing this family (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS60166338A (ja) * | 1984-02-08 | 1985-08-29 | Asahi Chem Ind Co Ltd | 外観，衝撃強度，耐熱性に優れたゴム変性スチレン系樹脂組成物 |
| JPS60217254A (ja) * | 1984-04-13 | 1985-10-30 | Dainippon Ink & Chem Inc | 耐摩耗性のすぐれたゴム変性スチレン系樹脂組成物 |
| JPS6185461A (ja) * | 1984-10-02 | 1986-05-01 | Asahi Chem Ind Co Ltd | 高光沢ポリスチレン樹脂組成物 |
| JPS61163950A (ja) * | 1985-01-16 | 1986-07-24 | Dainippon Ink & Chem Inc | 熱可塑性の樹脂組成物 |
| JPS61183339A (ja) * | 1985-02-12 | 1986-08-16 | Asahi Chem Ind Co Ltd | 改良されたゴム変性ポリスチレン組成物 |
| JPS61183340A (ja) * | 1985-02-12 | 1986-08-16 | Asahi Chem Ind Co Ltd | ゴム変性ポリスチレン組成物 |
| JPS61183341A (ja) * | 1985-02-12 | 1986-08-16 | Asahi Chem Ind Co Ltd | ゴム補強ポリスチレン組成物 |
| NL193458C (nl) * | 1985-10-22 | 1999-11-02 | Asahi Chemical Ind | Werkwijze voor de continue bereiding van een rubberversterkte polystyreensamenstelling met een hoge slagvastheid. |
| CA1335524C (en) * | 1988-04-11 | 1995-05-09 | Hideo Kasahara | Rubber-modified polystyrene resin composition |
| JPH0689204B2 (ja) * | 1989-11-29 | 1994-11-09 | 出光石油化学株式会社 | スチレン系樹脂組成物 |
| KR100411696B1 (ko) * | 2000-10-30 | 2003-12-18 | 제일모직주식회사 | 초고광택 및 초고충격성을 갖는 열가소성 수지 조성물 및그 제조방법 |
| WO2019020688A1 (en) | 2017-07-26 | 2019-01-31 | Ineos Styrolution Group Gmbh | STYRENE COPOLYMER COMPOSITION HAVING ENHANCED RESIDUAL GLOSS |
| ES2930761T3 (es) | 2017-07-26 | 2022-12-21 | Ineos Styrolution Group Gmbh | Composición de copolímero de estireno modificado al impacto que comprende un aditivo de polisiloxano que tiene características de abrasión mejoradas |
| ES2895445T3 (es) | 2017-07-26 | 2022-02-21 | Ineos Styrolution Group Gmbh | Composición de copolímero de estireno resistente a los arañazos, que contiene compuestos de organopolisiloxano modificado |
| CN111247205A (zh) | 2017-07-26 | 2020-06-05 | 英力士苯领集团股份公司 | 含有耐磨性能改善的聚硅氧烷添加剂的抗冲改性的苯乙烯共聚物组合物 |
Citations (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS497343A (de) * | 1972-05-10 | 1974-01-23 | ||
| JPS49109438A (de) * | 1973-02-21 | 1974-10-17 | ||
| JPS49132126A (de) * | 1973-04-02 | 1974-12-18 | ||
| JPS5058189A (de) * | 1973-09-19 | 1975-05-20 | ||
| JPS5078643A (de) * | 1973-10-18 | 1975-06-26 | ||
| JPS50122589A (de) * | 1974-03-07 | 1975-09-26 | ||
| JPS5142619A (ja) * | 1974-10-04 | 1976-04-10 | Ikegai Iron Works Ltd | Mitsuchakudonotakainetsukasoseihatsuhojushiseihitsukigu |
| JPS5174047A (de) * | 1974-12-25 | 1976-06-26 | Mitsubishi Monsanto Chem | |
| JPS51100145A (ja) * | 1975-03-01 | 1976-09-03 | Japan Synthetic Rubber Co Ltd | Netsukasoseijushisoseibutsu |
| JPS5212255A (en) * | 1975-07-18 | 1977-01-29 | Nittan Co Ltd | Process for producing lustrous molded articles based on synthetic resi ns |
| JPS5286444A (en) * | 1976-01-14 | 1977-07-18 | Mitsui Toatsu Chem Inc | Rubber-modified styrene resin compositions |
| JPS53124561A (en) * | 1977-04-06 | 1978-10-31 | Japan Synthetic Rubber Co Ltd | Preparation of rubber-modified thermoplastic resin composition |
| JPS57170950A (en) * | 1981-04-16 | 1982-10-21 | Mitsui Toatsu Chem Inc | Improved rubber-moldified styrene resin composition |
| JPS57170949A (en) * | 1981-04-16 | 1982-10-21 | Mitsui Toatsu Chem Inc | Rubber-modified styrene resin composition |
| JPS57172948A (en) * | 1981-04-17 | 1982-10-25 | Mitsui Toatsu Chem Inc | Rubber-modified styrene resin composition |
| JPS6326774A (ja) * | 1986-07-21 | 1988-02-04 | Mitsubishi Electric Corp | 信号処理装置 |
| JPS6351460A (ja) * | 1986-08-22 | 1988-03-04 | Mitsubishi Chem Ind Ltd | モノアゾ染料 |
-
1981
- 1981-05-14 JP JP7137581A patent/JPS57187346A/ja active Granted
Patent Citations (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS497343A (de) * | 1972-05-10 | 1974-01-23 | ||
| JPS49109438A (de) * | 1973-02-21 | 1974-10-17 | ||
| JPS49132126A (de) * | 1973-04-02 | 1974-12-18 | ||
| JPS5058189A (de) * | 1973-09-19 | 1975-05-20 | ||
| JPS5078643A (de) * | 1973-10-18 | 1975-06-26 | ||
| JPS50122589A (de) * | 1974-03-07 | 1975-09-26 | ||
| JPS5142619A (ja) * | 1974-10-04 | 1976-04-10 | Ikegai Iron Works Ltd | Mitsuchakudonotakainetsukasoseihatsuhojushiseihitsukigu |
| JPS5174047A (de) * | 1974-12-25 | 1976-06-26 | Mitsubishi Monsanto Chem | |
| JPS51100145A (ja) * | 1975-03-01 | 1976-09-03 | Japan Synthetic Rubber Co Ltd | Netsukasoseijushisoseibutsu |
| JPS5212255A (en) * | 1975-07-18 | 1977-01-29 | Nittan Co Ltd | Process for producing lustrous molded articles based on synthetic resi ns |
| JPS5286444A (en) * | 1976-01-14 | 1977-07-18 | Mitsui Toatsu Chem Inc | Rubber-modified styrene resin compositions |
| JPS53124561A (en) * | 1977-04-06 | 1978-10-31 | Japan Synthetic Rubber Co Ltd | Preparation of rubber-modified thermoplastic resin composition |
| JPS57170950A (en) * | 1981-04-16 | 1982-10-21 | Mitsui Toatsu Chem Inc | Improved rubber-moldified styrene resin composition |
| JPS57170949A (en) * | 1981-04-16 | 1982-10-21 | Mitsui Toatsu Chem Inc | Rubber-modified styrene resin composition |
| JPS57172948A (en) * | 1981-04-17 | 1982-10-25 | Mitsui Toatsu Chem Inc | Rubber-modified styrene resin composition |
| JPS6326774A (ja) * | 1986-07-21 | 1988-02-04 | Mitsubishi Electric Corp | 信号処理装置 |
| JPS6351460A (ja) * | 1986-08-22 | 1988-03-04 | Mitsubishi Chem Ind Ltd | モノアゾ染料 |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS57187346A (en) | 1982-11-18 |
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