JPS6356895B2 - - Google Patents
Info
- Publication number
- JPS6356895B2 JPS6356895B2 JP56071375A JP7137581A JPS6356895B2 JP S6356895 B2 JPS6356895 B2 JP S6356895B2 JP 56071375 A JP56071375 A JP 56071375A JP 7137581 A JP7137581 A JP 7137581A JP S6356895 B2 JPS6356895 B2 JP S6356895B2
- Authority
- JP
- Japan
- Prior art keywords
- rubber
- resin composition
- present
- weight
- polymer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000011342 resin composition Substances 0.000 claims description 43
- 239000002245 particle Substances 0.000 claims description 41
- 229920001890 Novodur Polymers 0.000 claims description 40
- -1 polysiloxane Polymers 0.000 claims description 36
- 238000000034 method Methods 0.000 claims description 35
- 229920001296 polysiloxane Polymers 0.000 claims description 34
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 22
- 229920000642 polymer Polymers 0.000 claims description 21
- 239000000203 mixture Substances 0.000 claims description 19
- 238000006116 polymerization reaction Methods 0.000 claims description 14
- 229910052710 silicon Inorganic materials 0.000 claims description 13
- 238000012662 bulk polymerization Methods 0.000 claims description 11
- 238000009826 distribution Methods 0.000 claims description 11
- 239000006185 dispersion Substances 0.000 claims description 8
- 239000010703 silicon Substances 0.000 claims description 5
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 claims description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical group C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 31
- 229920001971 elastomer Polymers 0.000 description 29
- 229920005989 resin Polymers 0.000 description 23
- 239000011347 resin Substances 0.000 description 23
- 238000002156 mixing Methods 0.000 description 17
- 239000000178 monomer Substances 0.000 description 16
- 238000003756 stirring Methods 0.000 description 13
- 230000000052 comparative effect Effects 0.000 description 8
- 238000006243 chemical reaction Methods 0.000 description 7
- 230000000694 effects Effects 0.000 description 7
- 238000010558 suspension polymerization method Methods 0.000 description 7
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
- 238000004458 analytical method Methods 0.000 description 6
- 239000000243 solution Substances 0.000 description 6
- 239000000654 additive Substances 0.000 description 5
- 238000011156 evaluation Methods 0.000 description 5
- 238000005469 granulation Methods 0.000 description 5
- 230000003179 granulation Effects 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 5
- 150000003440 styrenes Chemical class 0.000 description 5
- YNQLUTRBYVCPMQ-UHFFFAOYSA-N Ethylbenzene Chemical compound CCC1=CC=CC=C1 YNQLUTRBYVCPMQ-UHFFFAOYSA-N 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 238000000465 moulding Methods 0.000 description 4
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 239000004205 dimethyl polysiloxane Substances 0.000 description 3
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 125000000962 organic group Chemical group 0.000 description 3
- 239000008188 pellet Substances 0.000 description 3
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 3
- 229920002857 polybutadiene Polymers 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 2
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- 238000010894 electron beam technology Methods 0.000 description 2
- 238000000635 electron micrograph Methods 0.000 description 2
- 229920000578 graft copolymer Polymers 0.000 description 2
- 229940057995 liquid paraffin Drugs 0.000 description 2
- 229920001921 poly-methyl-phenyl-siloxane Polymers 0.000 description 2
- 239000003505 polymerization initiator Substances 0.000 description 2
- 230000000379 polymerizing effect Effects 0.000 description 2
- 239000005060 rubber Substances 0.000 description 2
- 229920003048 styrene butadiene rubber Polymers 0.000 description 2
- 230000008961 swelling Effects 0.000 description 2
- 229920005992 thermoplastic resin Polymers 0.000 description 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- YAJYJWXEWKRTPO-UHFFFAOYSA-N 2,3,3,4,4,5-hexamethylhexane-2-thiol Chemical compound CC(C)C(C)(C)C(C)(C)C(C)(C)S YAJYJWXEWKRTPO-UHFFFAOYSA-N 0.000 description 1
- SBYMUDUGTIKLCR-UHFFFAOYSA-N 2-chloroethenylbenzene Chemical class ClC=CC1=CC=CC=C1 SBYMUDUGTIKLCR-UHFFFAOYSA-N 0.000 description 1
- FCYVWWWTHPPJII-UHFFFAOYSA-N 2-methylidenepropanedinitrile Chemical compound N#CC(=C)C#N FCYVWWWTHPPJII-UHFFFAOYSA-N 0.000 description 1
- CEBRPXLXYCFYGU-UHFFFAOYSA-N 3-methylbut-1-enylbenzene Chemical class CC(C)C=CC1=CC=CC=C1 CEBRPXLXYCFYGU-UHFFFAOYSA-N 0.000 description 1
- JLBJTVDPSNHSKJ-UHFFFAOYSA-N 4-Methylstyrene Chemical compound CC1=CC=C(C=C)C=C1 JLBJTVDPSNHSKJ-UHFFFAOYSA-N 0.000 description 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 1
- 239000004610 Internal Lubricant Substances 0.000 description 1
- GYCMBHHDWRMZGG-UHFFFAOYSA-N Methylacrylonitrile Chemical compound CC(=C)C#N GYCMBHHDWRMZGG-UHFFFAOYSA-N 0.000 description 1
- 239000005062 Polybutadiene Substances 0.000 description 1
- 150000001253 acrylic acids Chemical class 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 125000003545 alkoxy group Chemical group 0.000 description 1
- 125000005907 alkyl ester group Chemical group 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 1
- 125000003277 amino group Chemical group 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- 239000008346 aqueous phase Substances 0.000 description 1
- 125000003710 aryl alkyl group Chemical group 0.000 description 1
- 238000001479 atomic absorption spectroscopy Methods 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 229920001400 block copolymer Polymers 0.000 description 1
- MPMBRWOOISTHJV-UHFFFAOYSA-N but-1-enylbenzene Chemical class CCC=CC1=CC=CC=C1 MPMBRWOOISTHJV-UHFFFAOYSA-N 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 238000005119 centrifugation Methods 0.000 description 1
- 238000004581 coalescence Methods 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 230000018044 dehydration Effects 0.000 description 1
- 238000006297 dehydration reaction Methods 0.000 description 1
- LSXWFXONGKSEMY-UHFFFAOYSA-N di-tert-butyl peroxide Chemical compound CC(C)(C)OOC(C)(C)C LSXWFXONGKSEMY-UHFFFAOYSA-N 0.000 description 1
- 150000001993 dienes Chemical class 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 125000003700 epoxy group Chemical group 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 238000010528 free radical solution polymerization reaction Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- KETWBQOXTBGBBN-UHFFFAOYSA-N hex-1-enylbenzene Chemical class CCCCC=CC1=CC=CC=C1 KETWBQOXTBGBBN-UHFFFAOYSA-N 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 239000003999 initiator Substances 0.000 description 1
- 230000001678 irradiating effect Effects 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 125000005395 methacrylic acid group Chemical class 0.000 description 1
- 239000011259 mixed solution Substances 0.000 description 1
- 239000006082 mold release agent Substances 0.000 description 1
- 150000001451 organic peroxides Chemical class 0.000 description 1
- 150000003961 organosilicon compounds Chemical class 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920005604 random copolymer Polymers 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 229920002379 silicone rubber Polymers 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 238000001256 steam distillation Methods 0.000 description 1
- 238000010557 suspension polymerization reaction Methods 0.000 description 1
- 229920001897 terpolymer Polymers 0.000 description 1
- GJBRNHKUVLOCEB-UHFFFAOYSA-N tert-butyl benzenecarboperoxoate Chemical compound CC(C)(C)OOC(=O)C1=CC=CC=C1 GJBRNHKUVLOCEB-UHFFFAOYSA-N 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 150000003673 urethanes Chemical class 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
- Silicon Polymers (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP7137581A JPS57187346A (en) | 1981-05-14 | 1981-05-14 | Improved rubber-modified styrene resin composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP7137581A JPS57187346A (en) | 1981-05-14 | 1981-05-14 | Improved rubber-modified styrene resin composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS57187346A JPS57187346A (en) | 1982-11-18 |
| JPS6356895B2 true JPS6356895B2 (de) | 1988-11-09 |
Family
ID=13458686
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP7137581A Granted JPS57187346A (en) | 1981-05-14 | 1981-05-14 | Improved rubber-modified styrene resin composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS57187346A (de) |
Families Citing this family (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS60166338A (ja) * | 1984-02-08 | 1985-08-29 | Asahi Chem Ind Co Ltd | 外観，衝撃強度，耐熱性に優れたゴム変性スチレン系樹脂組成物 |
| JPS60217254A (ja) * | 1984-04-13 | 1985-10-30 | Dainippon Ink & Chem Inc | 耐摩耗性のすぐれたゴム変性スチレン系樹脂組成物 |
| JPS6185461A (ja) * | 1984-10-02 | 1986-05-01 | Asahi Chem Ind Co Ltd | 高光沢ポリスチレン樹脂組成物 |
| JPS61163950A (ja) * | 1985-01-16 | 1986-07-24 | Dainippon Ink & Chem Inc | 熱可塑性の樹脂組成物 |
| JPS61183340A (ja) * | 1985-02-12 | 1986-08-16 | Asahi Chem Ind Co Ltd | ゴム変性ポリスチレン組成物 |
| JPS61183341A (ja) * | 1985-02-12 | 1986-08-16 | Asahi Chem Ind Co Ltd | ゴム補強ポリスチレン組成物 |
| JPS61183339A (ja) * | 1985-02-12 | 1986-08-16 | Asahi Chem Ind Co Ltd | 改良されたゴム変性ポリスチレン組成物 |
| NL193458C (nl) * | 1985-10-22 | 1999-11-02 | Asahi Chemical Ind | Werkwijze voor de continue bereiding van een rubberversterkte polystyreensamenstelling met een hoge slagvastheid. |
| CA1335524C (en) * | 1988-04-11 | 1995-05-09 | Hideo Kasahara | Rubber-modified polystyrene resin composition |
| JPH0689204B2 (ja) * | 1989-11-29 | 1994-11-09 | 出光石油化学株式会社 | スチレン系樹脂組成物 |
| KR100411696B1 (ko) * | 2000-10-30 | 2003-12-18 | 제일모직주식회사 | 초고광택 및 초고충격성을 갖는 열가소성 수지 조성물 및그 제조방법 |
| WO2019020688A1 (en) | 2017-07-26 | 2019-01-31 | Ineos Styrolution Group Gmbh | STYRENE COPOLYMER COMPOSITION HAVING ENHANCED RESIDUAL GLOSS |
| ES2930761T3 (es) | 2017-07-26 | 2022-12-21 | Ineos Styrolution Group Gmbh | Composición de copolímero de estireno modificado al impacto que comprende un aditivo de polisiloxano que tiene características de abrasión mejoradas |
| WO2019020677A1 (en) | 2017-07-26 | 2019-01-31 | Ineos Styrolution Group Gmbh | STYRENE COPOLYMER COMPOSITION WITH IMPROVED SHOCK RESISTANCE COMPRISING POLYSILOXANE ADDITIVE HAVING IMPROVED ABRASION FEATURES |
| ES2895445T3 (es) | 2017-07-26 | 2022-02-21 | Ineos Styrolution Group Gmbh | Composición de copolímero de estireno resistente a los arañazos, que contiene compuestos de organopolisiloxano modificado |
Citations (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS497343A (de) * | 1972-05-10 | 1974-01-23 | ||
| JPS49109438A (de) * | 1973-02-21 | 1974-10-17 | ||
| JPS49132126A (de) * | 1973-04-02 | 1974-12-18 | ||
| JPS5058189A (de) * | 1973-09-19 | 1975-05-20 | ||
| JPS5078643A (de) * | 1973-10-18 | 1975-06-26 | ||
| JPS50122589A (de) * | 1974-03-07 | 1975-09-26 | ||
| JPS5142619A (ja) * | 1974-10-04 | 1976-04-10 | Ikegai Iron Works Ltd | Mitsuchakudonotakainetsukasoseihatsuhojushiseihitsukigu |
| JPS5174047A (de) * | 1974-12-25 | 1976-06-26 | Mitsubishi Monsanto Chem | |
| JPS51100145A (ja) * | 1975-03-01 | 1976-09-03 | Japan Synthetic Rubber Co Ltd | Netsukasoseijushisoseibutsu |
| JPS5212255A (en) * | 1975-07-18 | 1977-01-29 | Nittan Co Ltd | Process for producing lustrous molded articles based on synthetic resi ns |
| JPS5286444A (en) * | 1976-01-14 | 1977-07-18 | Mitsui Toatsu Chem Inc | Rubber-modified styrene resin compositions |
| JPS53124561A (en) * | 1977-04-06 | 1978-10-31 | Japan Synthetic Rubber Co Ltd | Preparation of rubber-modified thermoplastic resin composition |
| JPS57170950A (en) * | 1981-04-16 | 1982-10-21 | Mitsui Toatsu Chem Inc | Improved rubber-moldified styrene resin composition |
| JPS57170949A (en) * | 1981-04-16 | 1982-10-21 | Mitsui Toatsu Chem Inc | Rubber-modified styrene resin composition |
| JPS57172948A (en) * | 1981-04-17 | 1982-10-25 | Mitsui Toatsu Chem Inc | Rubber-modified styrene resin composition |
| JPS6326774A (ja) * | 1986-07-21 | 1988-02-04 | Mitsubishi Electric Corp | 信号処理装置 |
| JPS6351460A (ja) * | 1986-08-22 | 1988-03-04 | Mitsubishi Chem Ind Ltd | モノアゾ染料 |
-
1981
- 1981-05-14 JP JP7137581A patent/JPS57187346A/ja active Granted
Patent Citations (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS497343A (de) * | 1972-05-10 | 1974-01-23 | ||
| JPS49109438A (de) * | 1973-02-21 | 1974-10-17 | ||
| JPS49132126A (de) * | 1973-04-02 | 1974-12-18 | ||
| JPS5058189A (de) * | 1973-09-19 | 1975-05-20 | ||
| JPS5078643A (de) * | 1973-10-18 | 1975-06-26 | ||
| JPS50122589A (de) * | 1974-03-07 | 1975-09-26 | ||
| JPS5142619A (ja) * | 1974-10-04 | 1976-04-10 | Ikegai Iron Works Ltd | Mitsuchakudonotakainetsukasoseihatsuhojushiseihitsukigu |
| JPS5174047A (de) * | 1974-12-25 | 1976-06-26 | Mitsubishi Monsanto Chem | |
| JPS51100145A (ja) * | 1975-03-01 | 1976-09-03 | Japan Synthetic Rubber Co Ltd | Netsukasoseijushisoseibutsu |
| JPS5212255A (en) * | 1975-07-18 | 1977-01-29 | Nittan Co Ltd | Process for producing lustrous molded articles based on synthetic resi ns |
| JPS5286444A (en) * | 1976-01-14 | 1977-07-18 | Mitsui Toatsu Chem Inc | Rubber-modified styrene resin compositions |
| JPS53124561A (en) * | 1977-04-06 | 1978-10-31 | Japan Synthetic Rubber Co Ltd | Preparation of rubber-modified thermoplastic resin composition |
| JPS57170950A (en) * | 1981-04-16 | 1982-10-21 | Mitsui Toatsu Chem Inc | Improved rubber-moldified styrene resin composition |
| JPS57170949A (en) * | 1981-04-16 | 1982-10-21 | Mitsui Toatsu Chem Inc | Rubber-modified styrene resin composition |
| JPS57172948A (en) * | 1981-04-17 | 1982-10-25 | Mitsui Toatsu Chem Inc | Rubber-modified styrene resin composition |
| JPS6326774A (ja) * | 1986-07-21 | 1988-02-04 | Mitsubishi Electric Corp | 信号処理装置 |
| JPS6351460A (ja) * | 1986-08-22 | 1988-03-04 | Mitsubishi Chem Ind Ltd | モノアゾ染料 |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS57187346A (en) | 1982-11-18 |
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