JPS6324415B2 - - Google Patents
Info
- Publication number
- JPS6324415B2 JPS6324415B2 JP59122979A JP12297984A JPS6324415B2 JP S6324415 B2 JPS6324415 B2 JP S6324415B2 JP 59122979 A JP59122979 A JP 59122979A JP 12297984 A JP12297984 A JP 12297984A JP S6324415 B2 JPS6324415 B2 JP S6324415B2
- Authority
- JP
- Japan
- Prior art keywords
- collection
- mno
- collection material
- kcfc
- rate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000463 material Substances 0.000 claims description 76
- 229920002972 Acrylic fiber Polymers 0.000 claims description 27
- 229910001385 heavy metal Inorganic materials 0.000 claims description 10
- 229910052759 nickel Inorganic materials 0.000 claims description 9
- -1 ferrocyanate compound Chemical class 0.000 claims description 8
- 229910052725 zinc Inorganic materials 0.000 claims description 8
- 229910052751 metal Inorganic materials 0.000 claims description 6
- 239000002184 metal Substances 0.000 claims description 6
- 229910052726 zirconium Inorganic materials 0.000 claims description 6
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 29
- 239000011701 zinc Substances 0.000 description 23
- 239000011572 manganese Substances 0.000 description 20
- 238000000034 method Methods 0.000 description 16
- 239000007788 liquid Substances 0.000 description 15
- 239000000835 fiber Substances 0.000 description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 13
- 239000007864 aqueous solution Substances 0.000 description 12
- 239000013535 sea water Substances 0.000 description 12
- 238000003756 stirring Methods 0.000 description 12
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 10
- 239000012286 potassium permanganate Substances 0.000 description 10
- 239000002901 radioactive waste Substances 0.000 description 10
- 239000000276 potassium ferrocyanide Substances 0.000 description 8
- XOGGUFAVLNCTRS-UHFFFAOYSA-N tetrapotassium;iron(2+);hexacyanide Chemical compound [K+].[K+].[K+].[K+].[Fe+2].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-] XOGGUFAVLNCTRS-UHFFFAOYSA-N 0.000 description 8
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- 229910017052 cobalt Inorganic materials 0.000 description 6
- 239000010941 cobalt Substances 0.000 description 6
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 6
- 239000011734 sodium Substances 0.000 description 6
- 239000002699 waste material Substances 0.000 description 6
- 239000000243 solution Substances 0.000 description 5
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 4
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 4
- 239000003153 chemical reaction reagent Substances 0.000 description 4
- 238000011038 discontinuous diafiltration by volume reduction Methods 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 229910052742 iron Inorganic materials 0.000 description 4
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 3
- 150000001450 anions Chemical class 0.000 description 3
- UFMZWBIQTDUYBN-UHFFFAOYSA-N cobalt dinitrate Chemical compound [Co+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O UFMZWBIQTDUYBN-UHFFFAOYSA-N 0.000 description 3
- 229910001981 cobalt nitrate Inorganic materials 0.000 description 3
- 239000012530 fluid Substances 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 239000010842 industrial wastewater Substances 0.000 description 3
- 238000005342 ion exchange Methods 0.000 description 3
- 229910052700 potassium Inorganic materials 0.000 description 3
- 239000011591 potassium Substances 0.000 description 3
- 239000002516 radical scavenger Substances 0.000 description 3
- 230000002285 radioactive effect Effects 0.000 description 3
- 238000004062 sedimentation Methods 0.000 description 3
- 238000005406 washing Methods 0.000 description 3
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 2
- 239000004698 Polyethylene Substances 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 2
- AIYUHDOJVYHVIT-UHFFFAOYSA-M caesium chloride Chemical compound [Cl-].[Cs+] AIYUHDOJVYHVIT-UHFFFAOYSA-M 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 229910052748 manganese Inorganic materials 0.000 description 2
- NUJOXMJBOLGQSY-UHFFFAOYSA-N manganese dioxide Chemical compound O=[Mn]=O NUJOXMJBOLGQSY-UHFFFAOYSA-N 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 229920000573 polyethylene Polymers 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 239000010802 sludge Substances 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 239000002351 wastewater Substances 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- 101100496858 Mus musculus Colec12 gene Proteins 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- LFYJSSARVMHQJB-QIXNEVBVSA-N bakuchiol Chemical compound CC(C)=CCC[C@@](C)(C=C)\C=C\C1=CC=C(O)C=C1 LFYJSSARVMHQJB-QIXNEVBVSA-N 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 238000005119 centrifugation Methods 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 239000000498 cooling water Substances 0.000 description 1
- 238000005202 decontamination Methods 0.000 description 1
- 230000003588 decontaminative effect Effects 0.000 description 1
- 230000018044 dehydration Effects 0.000 description 1
- 238000006297 dehydration reaction Methods 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000008394 flocculating agent Substances 0.000 description 1
- 239000003456 ion exchange resin Substances 0.000 description 1
- 229920003303 ion-exchange polymer Polymers 0.000 description 1
- CYPPCCJJKNISFK-UHFFFAOYSA-J kaolinite Chemical compound [OH-].[OH-].[OH-].[OH-].[Al+3].[Al+3].[O-][Si](=O)O[Si]([O-])=O CYPPCCJJKNISFK-UHFFFAOYSA-J 0.000 description 1
- 229910052622 kaolinite Inorganic materials 0.000 description 1
- 150000002605 large molecules Chemical class 0.000 description 1
- 239000003077 lignite Substances 0.000 description 1
- 239000010808 liquid waste Substances 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 239000003415 peat Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- XXQBEVHPUKOQEO-UHFFFAOYSA-N potassium peroxide Inorganic materials [K+].[K+].[O-][O-] XXQBEVHPUKOQEO-UHFFFAOYSA-N 0.000 description 1
- CLSKHAYBTFRDOV-UHFFFAOYSA-N potassium;molecular oxygen Chemical compound [K+].O=O CLSKHAYBTFRDOV-UHFFFAOYSA-N 0.000 description 1
- 238000011085 pressure filtration Methods 0.000 description 1
- 239000008213 purified water Substances 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 239000000941 radioactive substance Substances 0.000 description 1
- 239000000700 radioactive tracer Substances 0.000 description 1
- 238000005070 sampling Methods 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 238000003828 vacuum filtration Methods 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
Landscapes
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP12297984A JPS614530A (ja) | 1984-06-15 | 1984-06-15 | 放射性核種および重金属捕集材 |
| US06/719,433 US4720422A (en) | 1984-06-06 | 1985-04-03 | Material for collecting radionuclides and heavy metals |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP12297984A JPS614530A (ja) | 1984-06-15 | 1984-06-15 | 放射性核種および重金属捕集材 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS614530A JPS614530A (ja) | 1986-01-10 |
| JPS6324415B2 true JPS6324415B2 (cs) | 1988-05-20 |
Family
ID=14849304
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP12297984A Granted JPS614530A (ja) | 1984-06-06 | 1984-06-15 | 放射性核種および重金属捕集材 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS614530A (cs) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2013027652A1 (ja) * | 2011-08-19 | 2013-02-28 | 一般財団法人生産技術研究奨励会 | 放射性セシウム吸着材およびその製造方法、ならびに該吸着材による環境中の放射性セシウムの除去方法 |
| JP2013061220A (ja) * | 2011-09-13 | 2013-04-04 | Futaba Shoji Kk | 放射性セシウム吸着性布帛 |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6439600A (en) * | 1987-08-06 | 1989-02-09 | Ebara Corp | Treatment of radioactive waste liquid containing salts at high concentration |
| GB9402334D0 (en) * | 1994-02-07 | 1994-03-30 | Bradtecltd | Magnetic particles a method for the preparation thereof and their use in the purification of solutions |
| JP5999675B2 (ja) * | 2010-08-30 | 2016-09-28 | 国立研究開発法人産業技術総合研究所 | 無欠陥型プルシアンブルー類似体によるリチウムイオン２次電池用電極材料 |
| JP5858473B2 (ja) * | 2011-05-06 | 2016-02-10 | 国立研究開発法人産業技術総合研究所 | 金属錯体を含む複合体及びそれを用いた放射性セシウム吸着材 |
| WO2013065829A1 (ja) * | 2011-11-02 | 2013-05-10 | ダイワボウホールディングス株式会社 | 放射性物質吸着材、その製造方法及びそれを含む繊維製品 |
| JP6343760B2 (ja) * | 2012-01-10 | 2018-06-20 | 国立研究開発法人日本原子力研究開発機構 | 液中からの放射性元素の分離・除去方法 |
| JP2014102240A (ja) * | 2012-11-20 | 2014-06-05 | Kankyo Joka Kenkyusho:Kk | 滞留した放射性液体の除染方法及びその装置 |
| JP5713375B1 (ja) * | 2013-12-02 | 2015-05-07 | 国立大学法人東京工業大学 | セシウム吸着剤及びその製造方法並びにセシウム吸着剤を使用したセシウムの除去方法 |
| JP2017121616A (ja) * | 2016-01-08 | 2017-07-13 | 日本化学工業株式会社 | 吸着剤 |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS4932466A (cs) * | 1972-07-24 | 1974-03-25 | ||
| JPS5035753A (cs) * | 1973-06-14 | 1975-04-04 |
-
1984
- 1984-06-15 JP JP12297984A patent/JPS614530A/ja active Granted
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS4932466A (cs) * | 1972-07-24 | 1974-03-25 | ||
| JPS5035753A (cs) * | 1973-06-14 | 1975-04-04 |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2013027652A1 (ja) * | 2011-08-19 | 2013-02-28 | 一般財団法人生産技術研究奨励会 | 放射性セシウム吸着材およびその製造方法、ならびに該吸着材による環境中の放射性セシウムの除去方法 |
| US9455054B2 (en) | 2011-08-19 | 2016-09-27 | The Foundation For The Promotion Of Industrial Science | Radioactive cesium adsorbent, method for producing the same, and method for removing radioactive cesium in environment with said adsorbent |
| JP2013061220A (ja) * | 2011-09-13 | 2013-04-04 | Futaba Shoji Kk | 放射性セシウム吸着性布帛 |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS614530A (ja) | 1986-01-10 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| LAPS | Cancellation because of no payment of annual fees |