JPS6323742A - 還元触媒の製造方法 - Google Patents
還元触媒の製造方法Info
- Publication number
- JPS6323742A JPS6323742A JP62147320A JP14732087A JPS6323742A JP S6323742 A JPS6323742 A JP S6323742A JP 62147320 A JP62147320 A JP 62147320A JP 14732087 A JP14732087 A JP 14732087A JP S6323742 A JPS6323742 A JP S6323742A
- Authority
- JP
- Japan
- Prior art keywords
- catalyst
- carrier
- cobalt
- gas
- iron
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000003054 catalyst Substances 0.000 title claims abstract description 66
- 238000004519 manufacturing process Methods 0.000 title description 8
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract description 37
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 24
- AMWRITDGCCNYAT-UHFFFAOYSA-L hydroxy(oxo)manganese;manganese Chemical compound [Mn].O[Mn]=O.O[Mn]=O AMWRITDGCCNYAT-UHFFFAOYSA-L 0.000 claims abstract description 24
- 239000010941 cobalt Substances 0.000 claims abstract description 21
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims abstract description 21
- 229910052742 iron Inorganic materials 0.000 claims abstract description 18
- 229910052751 metal Inorganic materials 0.000 claims abstract description 17
- 239000002184 metal Substances 0.000 claims abstract description 17
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical group [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims abstract description 17
- 229910017052 cobalt Inorganic materials 0.000 claims abstract description 16
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 12
- 239000000758 substrate Substances 0.000 claims description 7
- 239000000203 mixture Substances 0.000 abstract description 22
- 229910052739 hydrogen Inorganic materials 0.000 abstract description 13
- 239000001257 hydrogen Substances 0.000 abstract description 13
- 229910000428 cobalt oxide Inorganic materials 0.000 abstract description 5
- 230000002829 reductive effect Effects 0.000 abstract description 5
- -1 for example Substances 0.000 abstract description 4
- 125000004435 hydrogen atom Chemical class [H]* 0.000 abstract 1
- 238000002156 mixing Methods 0.000 abstract 1
- 239000007789 gas Substances 0.000 description 46
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 16
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 11
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 11
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 11
- 238000000034 method Methods 0.000 description 11
- 229930195733 hydrocarbon Natural products 0.000 description 10
- 150000002430 hydrocarbons Chemical class 0.000 description 10
- 238000010438 heat treatment Methods 0.000 description 9
- 239000000571 coke Substances 0.000 description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 8
- 229910002651 NO3 Inorganic materials 0.000 description 7
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 description 7
- 239000007864 aqueous solution Substances 0.000 description 7
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 6
- 125000004432 carbon atom Chemical group C* 0.000 description 6
- 238000006243 chemical reaction Methods 0.000 description 6
- 229910021529 ammonia Inorganic materials 0.000 description 5
- 229910052707 ruthenium Inorganic materials 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- 229910052799 carbon Inorganic materials 0.000 description 4
- 229910002092 carbon dioxide Inorganic materials 0.000 description 4
- 230000007423 decrease Effects 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 239000011572 manganese Substances 0.000 description 4
- 239000003345 natural gas Substances 0.000 description 4
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 3
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 3
- 239000001569 carbon dioxide Substances 0.000 description 3
- 229910002091 carbon monoxide Inorganic materials 0.000 description 3
- 229910002090 carbon oxide Inorganic materials 0.000 description 3
- 239000003245 coal Substances 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 2
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 2
- 238000007605 air drying Methods 0.000 description 2
- 239000006227 byproduct Substances 0.000 description 2
- 238000005470 impregnation Methods 0.000 description 2
- 229910052748 manganese Inorganic materials 0.000 description 2
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 2
- 229910001510 metal chloride Inorganic materials 0.000 description 2
- 229910001960 metal nitrate Inorganic materials 0.000 description 2
- 229910044991 metal oxide Inorganic materials 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 238000001179 sorption measurement Methods 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 238000005979 thermal decomposition reaction Methods 0.000 description 2
- 235000002918 Fraxinus excelsior Nutrition 0.000 description 1
- 229910019891 RuCl3 Inorganic materials 0.000 description 1
- 239000002956 ash Substances 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000010981 drying operation Methods 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 239000000295 fuel oil Substances 0.000 description 1
- 238000002309 gasification Methods 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 229910052741 iridium Inorganic materials 0.000 description 1
- GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000011259 mixed solution Substances 0.000 description 1
- 150000002823 nitrates Chemical class 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000002250 progressing effect Effects 0.000 description 1
- 239000012495 reaction gas Substances 0.000 description 1
- 238000002407 reforming Methods 0.000 description 1
- 229910052703 rhodium Inorganic materials 0.000 description 1
- 239000010948 rhodium Substances 0.000 description 1
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 description 1
- 150000003303 ruthenium Chemical class 0.000 description 1
- YBCAZPLXEGKKFM-UHFFFAOYSA-K ruthenium(iii) chloride Chemical compound [Cl-].[Cl-].[Cl-].[Ru+3] YBCAZPLXEGKKFM-UHFFFAOYSA-K 0.000 description 1
- 238000005245 sintering Methods 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000009628 steelmaking Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000002194 synthesizing effect Effects 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Industrial Gases (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP62147320A JPS6323742A (ja) | 1987-06-13 | 1987-06-13 | 還元触媒の製造方法 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP62147320A JPS6323742A (ja) | 1987-06-13 | 1987-06-13 | 還元触媒の製造方法 |
Related Parent Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP58023619A Division JPS59147641A (ja) | 1983-02-15 | 1983-02-15 | 還元触媒 |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS6323742A true JPS6323742A (ja) | 1988-02-01 |
JPH0558776B2 JPH0558776B2 (enrdf_load_stackoverflow) | 1993-08-27 |
Family
ID=15427518
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP62147320A Granted JPS6323742A (ja) | 1987-06-13 | 1987-06-13 | 還元触媒の製造方法 |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS6323742A (enrdf_load_stackoverflow) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5102851A (en) * | 1988-12-28 | 1992-04-07 | Den Norske Stats Oljeselskap A.S. | Supported catalyst for hydrocarbon synthesis |
JP2010149109A (ja) * | 2008-11-18 | 2010-07-08 | Osaka Gas Co Ltd | 高カロリーガス製造用触媒およびその製造方法および高カロリーガス製造用触媒を用いた高カロリーガス製造方法 |
-
1987
- 1987-06-13 JP JP62147320A patent/JPS6323742A/ja active Granted
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5102851A (en) * | 1988-12-28 | 1992-04-07 | Den Norske Stats Oljeselskap A.S. | Supported catalyst for hydrocarbon synthesis |
JP2010149109A (ja) * | 2008-11-18 | 2010-07-08 | Osaka Gas Co Ltd | 高カロリーガス製造用触媒およびその製造方法および高カロリーガス製造用触媒を用いた高カロリーガス製造方法 |
JP2014073492A (ja) * | 2008-11-18 | 2014-04-24 | Osaka Gas Co Ltd | 高カロリーガス製造用触媒およびその製造方法および高カロリーガス製造用触媒を用いた高カロリーガス製造方法 |
Also Published As
Publication number | Publication date |
---|---|
JPH0558776B2 (enrdf_load_stackoverflow) | 1993-08-27 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CA2550639A1 (en) | Process for autothermal generation of hydrogen | |
JPH09502414A (ja) | メタンから水素/一酸化炭素混合物または水素を製造する方法 | |
KR20070100962A (ko) | 이산화탄소 방출이 적은 합성가스 제조 방법 | |
Díaz et al. | Activated carbon supported Ni–Ca: influence of reaction parameters on activity and stability of catalyst on methane reformation | |
JP4330846B2 (ja) | 燃料電池システムにおいて用いられるための低硫黄改質油ガスを調製するプロセス | |
Koyano et al. | States of Pd in Pd/H–ZSM-5 and Pd/Na–ZSM-5 catalysts and catalytic activity for the reduction of NO by CH4 in the presence of O2 | |
JPS6323742A (ja) | 還元触媒の製造方法 | |
JPS58120501A (ja) | 合成ガスの製造法 | |
JPH0535018B2 (enrdf_load_stackoverflow) | ||
JP2885153B2 (ja) | Sng製造用触媒材料及びsng製造方法 | |
JPS5946133A (ja) | 還元触媒 | |
JPH0211306B2 (enrdf_load_stackoverflow) | ||
JPH0212143B2 (enrdf_load_stackoverflow) | ||
JPH0211305B2 (enrdf_load_stackoverflow) | ||
JPH08239201A (ja) | メタンの改質による水素の製造法 | |
JPH0212144B2 (enrdf_load_stackoverflow) | ||
JPH01148343A (ja) | 合成ガス製造用触媒 | |
JPH04331704A (ja) | 一酸化炭素および水素を含有する合成ガスの製造方法 | |
McClory et al. | Catalytic oxidation of carbon monoxide over ruthenium-rhodium (RuRh) silica bimetallic clusters | |
JP3963512B2 (ja) | 熱処理炉用炉内雰囲気ガスの調製方法および装置 | |
KR102579471B1 (ko) | 이산화탄소 건식 흡수제를 이용한 일산화탄소 및 합성가스 생성 공정 및 시스템 | |
CN1062240C (zh) | 一种由甲烷直接催化氧化制合成气的方法 | |
JP2005536421A5 (enrdf_load_stackoverflow) | ||
KR20180099060A (ko) | 메탄 개질용 촉매 및 이를 이용한 메탄의 개질 방법 | |
JPS593401B2 (ja) | カンゲンガスノセイゾウホウホウ |