JPS63145203A - Insecticide - Google Patents
InsecticideInfo
- Publication number
- JPS63145203A JPS63145203A JP29190686A JP29190686A JPS63145203A JP S63145203 A JPS63145203 A JP S63145203A JP 29190686 A JP29190686 A JP 29190686A JP 29190686 A JP29190686 A JP 29190686A JP S63145203 A JPS63145203 A JP S63145203A
- Authority
- JP
- Japan
- Prior art keywords
- tiglic acid
- active ingredient
- insecticide
- acid
- case
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000002917 insecticide Substances 0.000 title abstract description 6
- 239000004480 active ingredient Substances 0.000 claims abstract 4
- 239000000077 insect repellent Substances 0.000 claims description 15
- UIERETOOQGIECD-UHFFFAOYSA-N Angelic acid Natural products CC=C(C)C(O)=O UIERETOOQGIECD-UHFFFAOYSA-N 0.000 abstract description 13
- UIERETOOQGIECD-ONEGZZNKSA-N tiglic acid Chemical compound C\C=C(/C)C(O)=O UIERETOOQGIECD-ONEGZZNKSA-N 0.000 abstract description 13
- UIERETOOQGIECD-ARJAWSKDSA-M 2-Methyl-2-butenoic acid Natural products C\C=C(\C)C([O-])=O UIERETOOQGIECD-ARJAWSKDSA-M 0.000 abstract description 12
- UAXOELSVPTZZQG-UHFFFAOYSA-N tiglic acid Natural products CC(C)=C(C)C(O)=O UAXOELSVPTZZQG-UHFFFAOYSA-N 0.000 abstract description 12
- 230000000694 effects Effects 0.000 abstract description 3
- 230000000749 insecticidal effect Effects 0.000 abstract description 3
- 239000007787 solid Substances 0.000 abstract description 3
- 238000000859 sublimation Methods 0.000 abstract description 3
- 230000008022 sublimation Effects 0.000 abstract description 3
- 229920000298 Cellophane Polymers 0.000 abstract description 2
- 150000002148 esters Chemical class 0.000 abstract description 2
- 238000002844 melting Methods 0.000 abstract description 2
- 230000008018 melting Effects 0.000 abstract description 2
- 239000008188 pellet Substances 0.000 abstract description 2
- 229920003023 plastic Polymers 0.000 abstract description 2
- 239000000843 powder Substances 0.000 abstract description 2
- 241000130771 Tinea pellionella Species 0.000 abstract 1
- 239000004615 ingredient Substances 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 description 3
- DSSYKIVIOFKYAU-XCBNKYQSSA-N (R)-camphor Chemical compound C1C[C@@]2(C)C(=O)C[C@@H]1C2(C)C DSSYKIVIOFKYAU-XCBNKYQSSA-N 0.000 description 2
- 241000723346 Cinnamomum camphora Species 0.000 description 2
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 2
- 229960000846 camphor Drugs 0.000 description 2
- 229930008380 camphor Natural products 0.000 description 2
- OCJBOOLMMGQPQU-UHFFFAOYSA-N 1,4-dichlorobenzene Chemical compound ClC1=CC=C(Cl)C=C1 OCJBOOLMMGQPQU-UHFFFAOYSA-N 0.000 description 1
- 241000238631 Hexapoda Species 0.000 description 1
- 230000034994 death Effects 0.000 description 1
- 231100000517 death Toxicity 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 244000144972 livestock Species 0.000 description 1
- 231100000053 low toxicity Toxicity 0.000 description 1
- 230000002093 peripheral effect Effects 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
Description
【発明の詳細な説明】 〔産業上の利用分野〕 本発明は新規な防虫剤に関する。[Detailed description of the invention] [Industrial application field] The present invention relates to a novel insect repellent.
従来防虫剤、殺虫剤として使用されているものは数多い
が、一般的農園芸用殺虫剤と異なり家庭内等の衣類収納
用家具、容器内で使用する衣類用防虫剤は多くはない。There are many insect repellents and insecticides that have been used in the past, but unlike general agricultural and horticultural insecticides, there are not many insect repellents for clothing that are used in clothing storage furniture and containers in the home.
それは人畜に対する毒性が低く、衣類等に対し汚染、損
傷を与えずに、イガ当特定の虫類に有効であること等の
制約を受けるためである。This is because it has low toxicity to humans and livestock, does not contaminate or damage clothing, etc., and is effective against specific insects such as burrs.
従ってナフタリン、樟脳、パラ−ジクロロベンゼン等の
古くから使用されている防虫剤が、それらが有する上記
特性の良さから今でも相当量使用されている。Therefore, insect repellents that have been used for a long time, such as naphthalene, camphor, and para-dichlorobenzene, are still used in considerable quantities because of their good properties.
しかしこれらの防虫剤は効力は弱く、比較的短時間で気
散するため長期間効果を持続できず、頻繁に薬剤の補充
が必要であり、従って使用量が多くなる。However, these insect repellents have low efficacy and are dispersed in a relatively short period of time, so they cannot maintain their effectiveness over a long period of time, require frequent replenishment, and therefore require a large amount of use.
比較的少量で効果が長期間持続し、且つ安全な新しい防
虫剤の開発が望まれていた。There has been a desire to develop a new insect repellent that is safe and effective for a long period of time with a relatively small amount.
本発明者は防虫剤として使用されている化合物の類縁あ
るいは周縁の化合物について種々研究した結果、(E)
−2−メチル−2−ブテノイック酸(以下これをチグリ
ン酸と呼ぶ。)が昇華性を有し、その気散ガスにによる
殺虫性が優れていることを見出し本発明に到達した。As a result of various studies on compounds related to or peripheral to compounds used as insect repellents, the present inventor found that (E)
The present invention was achieved by discovering that -2-methyl-2-butenoic acid (hereinafter referred to as tiglic acid) has sublimation properties and has excellent insecticidal properties due to its vaporized gas.
チグリン酸は融点63.5〜64.0℃の固体で天然に
遊離およびエステルとして得られる極めて安全性の高い
化合物である。Tiglic acid is a very safe compound that is a solid with a melting point of 63.5 to 64.0°C and is naturally obtained as a free substance or an ester.
チグリン酸をIQのビーカーに少量とり、イガの幼虫数
頭をいれて蓋をし数日放置したところ、チグリン酸から
揮散した蒸気によりその殆どが死滅した。When a small amount of tiglic acid was placed in an IQ beaker, several burr larvae were placed in the beaker, the beaker was covered with a lid, and left for several days, most of the larvae were killed by the vapor volatilized from the tiglic acid.
チグリン酸は常温で固体であるから従来の昇華性防虫剤
と同じように、粉末を和紙など通気性の袋に充填するか
、タブレットまたはペレットをプラスチックまたは防湿
セロファン等に適宜小さな孔を穿った袋に収納する。こ
れはチグリン酸単独でも、他の昇華性防虫剤との複合の
場合でも適用することができる。Tiglic acid is solid at room temperature, so just like conventional sublimation insect repellents, fill the powder into a breathable bag such as Japanese paper, or pack the tablets or pellets into a plastic or moisture-proof cellophane bag with appropriate small holes. Store it in. This can be applied to tiglic acid alone or in combination with other sublimable insect repellents.
内容積約IQの硝子製有蓋容器の底部に、チグリン酸/
樟脳=20/80の薬剤1gを置き、さらに羊毛と一緒
にイガ幼虫10頭を約0.089のステンレス網容器に
いれ、20℃(75%R9H)の恒温恒湿槽に1週間放
置した。Tiglic acid/
1 g of camphor = 20/80 drug was placed, and 10 bur larvae were placed in a stainless steel net container with a temperature of about 0.089, and left in a constant temperature and humidity bath at 20° C. (75% R9H) for one week.
試験結果は試験数5個の食害量と致死数の平均をもって
結果とした。The test results were taken as the average of the amount of feeding damage and the number of deaths for the 5 test specimens.
試験結果を第1表に示す。The test results are shown in Table 1.
第1表
〔発明の効果〕
本発明のチグリン酸は強力な防虫剤で少量でも優れた防
虫性を有し、しかも長期に亘って効果は持続する。Table 1 [Effects of the Invention] The tiglic acid of the present invention is a strong insect repellent and has excellent insect repellent properties even in small amounts, and its effect persists for a long period of time.
その地衣類用の防虫剤としての特性を有するので従来の
防虫剤にとって代る優れた防虫剤となるものと期待され
る。Since it has properties as an insect repellent for lichens, it is expected to be an excellent insect repellent to replace conventional insect repellents.
Claims (1)
して含有する防虫剤。(E) An insect repellent containing -2-methyl-2-butenoic acid as an active ingredient.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP29190686A JPS63145203A (en) | 1986-12-08 | 1986-12-08 | Insecticide |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP29190686A JPS63145203A (en) | 1986-12-08 | 1986-12-08 | Insecticide |
Publications (1)
Publication Number | Publication Date |
---|---|
JPS63145203A true JPS63145203A (en) | 1988-06-17 |
Family
ID=17774987
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP29190686A Pending JPS63145203A (en) | 1986-12-08 | 1986-12-08 | Insecticide |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS63145203A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1997048279A1 (en) * | 1996-06-21 | 1997-12-24 | University Of Alberta | Agents with antifungal activity and methods of use thereof |
-
1986
- 1986-12-08 JP JP29190686A patent/JPS63145203A/en active Pending
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1997048279A1 (en) * | 1996-06-21 | 1997-12-24 | University Of Alberta | Agents with antifungal activity and methods of use thereof |
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