JPS6314703A - Insecticide - Google Patents
InsecticideInfo
- Publication number
- JPS6314703A JPS6314703A JP15738486A JP15738486A JPS6314703A JP S6314703 A JPS6314703 A JP S6314703A JP 15738486 A JP15738486 A JP 15738486A JP 15738486 A JP15738486 A JP 15738486A JP S6314703 A JPS6314703 A JP S6314703A
- Authority
- JP
- Japan
- Prior art keywords
- alpha
- insecticide
- pinene oxide
- pinene
- active ingredient
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000002917 insecticide Substances 0.000 title abstract description 7
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000004480 active ingredient Substances 0.000 claims abstract 3
- 239000000077 insect repellent Substances 0.000 claims description 14
- NQFUSWIGRKFAHK-BDNRQGISSA-N alpha-Pinene epoxide Natural products C([C@@H]1O[C@@]11C)[C@@H]2C(C)(C)[C@H]1C2 NQFUSWIGRKFAHK-BDNRQGISSA-N 0.000 abstract description 11
- 229930006723 alpha-pinene oxide Natural products 0.000 abstract description 11
- 239000007788 liquid Substances 0.000 abstract description 4
- GRWFGVWFFZKLTI-IUCAKERBSA-N 1S,5S-(-)-alpha-Pinene Natural products CC1=CC[C@@H]2C(C)(C)[C@H]1C2 GRWFGVWFFZKLTI-IUCAKERBSA-N 0.000 abstract description 3
- 150000001875 compounds Chemical class 0.000 abstract description 3
- 230000000694 effects Effects 0.000 abstract description 3
- GRWFGVWFFZKLTI-UHFFFAOYSA-N α-pinene Chemical compound CC1=CCC2C(C)(C)C1C2 GRWFGVWFFZKLTI-UHFFFAOYSA-N 0.000 abstract description 3
- MVNCAPSFBDBCGF-UHFFFAOYSA-N alpha-pinene Natural products CC1=CCC23C1CC2C3(C)C MVNCAPSFBDBCGF-UHFFFAOYSA-N 0.000 abstract description 2
- 238000009835 boiling Methods 0.000 abstract description 2
- 239000003795 chemical substances by application Substances 0.000 abstract description 2
- 230000000749 insecticidal effect Effects 0.000 abstract description 2
- 239000011148 porous material Substances 0.000 abstract description 2
- 239000002994 raw material Substances 0.000 abstract description 2
- 125000003425 alpha-pinene oxide group Chemical group 0.000 abstract 4
- 239000000203 mixture Substances 0.000 abstract 1
- 239000000123 paper Substances 0.000 abstract 1
- 239000000758 substrate Substances 0.000 abstract 1
- 239000002759 woven fabric Substances 0.000 abstract 1
- NQFUSWIGRKFAHK-UHFFFAOYSA-N 2,3-epoxypinane Chemical compound CC12OC1CC1C(C)(C)C2C1 NQFUSWIGRKFAHK-UHFFFAOYSA-N 0.000 description 7
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- DSSYKIVIOFKYAU-XCBNKYQSSA-N (R)-camphor Chemical compound C1C[C@@]2(C)C(=O)C[C@@H]1C2(C)C DSSYKIVIOFKYAU-XCBNKYQSSA-N 0.000 description 1
- OCJBOOLMMGQPQU-UHFFFAOYSA-N 1,4-dichlorobenzene Chemical compound ClC1=CC=C(Cl)C=C1 OCJBOOLMMGQPQU-UHFFFAOYSA-N 0.000 description 1
- 241000723346 Cinnamomum camphora Species 0.000 description 1
- 229930008380 camphor Natural products 0.000 description 1
- 229960000846 camphor Drugs 0.000 description 1
- 230000034994 death Effects 0.000 description 1
- 231100000517 death Toxicity 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000003349 gelling agent Substances 0.000 description 1
- 244000144972 livestock Species 0.000 description 1
- 231100000053 low toxicity Toxicity 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 230000002093 peripheral effect Effects 0.000 description 1
- 238000000859 sublimation Methods 0.000 description 1
- 230000008022 sublimation Effects 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
Description
【発明の詳細な説明】 〔産業上の利用分野〕 本発明は新規な防虫剤に関する。[Detailed description of the invention] [Industrial application field] The present invention relates to a novel insect repellent.
従来防虫剤、殺虫剤として使用されているものは数多い
が、一般的農園芸用殺虫剤と異なり家庭内等の衣類収納
用家具、容器内で使用する衣類用防虫剤は多くはない。There are many insect repellents and insecticides that have been used in the past, but unlike general agricultural and horticultural insecticides, there are not many insect repellents for clothing that are used in clothing storage furniture and containers in the home.
それは人畜に対する毒性が低く、衣類等に対し汚染、損
傷を与えずに、イガ当特定の生類に有効であること等の
制約を受けるためである。This is because it has low toxicity to humans and livestock, does not contaminate or damage clothing, etc., and is effective against specific organisms such as burrs.
従ってナフタリン、樟脳、パラ−ジクロロベンゼン等の
古くから使用されている防虫剤が、それらが有する上記
特性の良さから今でも相当量使用されている。Therefore, insect repellents that have been used for a long time, such as naphthalene, camphor, and para-dichlorobenzene, are still used in considerable quantities because of their good properties.
しかしこれらの防虫剤は効力は弱く、比較的短時間で気
散するため長期間効果を持続できず、頻繁に薬剤の補充
が必要であり、従って使用量が多くなる。However, these insect repellents have low efficacy and are dispersed in a relatively short period of time, so they cannot maintain their effectiveness over a long period of time, require frequent replenishment, and therefore require a large amount of use.
比較的少量で効果が長期間持続し、且つ安全な新しい防
虫剤の開発が望まれていた。It has been desired to develop a new insect repellent that is safe and effective for a long period of time with a relatively small amount.
本発明者は防虫剤として使用されている化合物の類縁あ
るいは周縁の化合物について種々研究した結果、２，６
．６−ドリメチルー２，３−エポキシビシクロ ［３，
１，１］ヘプタン（以下これをα−ピネンオキシドと呼
ぶ。）が昇華性を有し、その気散ガスにによる殺虫性が
優れていることを見出し本発明に到達した。As a result of various studies on compounds related to or peripheral to compounds used as insect repellents, the present inventor found that 2,6
．． 6-drimethyl-2,3-epoxybicyclo [3,
The present invention was achieved by discovering that 1,1]heptane (hereinafter referred to as α-pinene oxide) has sublimation properties and has excellent insecticidal properties due to its vaporized gas.
α−ピネンオキシドは沸点１０２〜１０３℃（５０ｍｎ
Ｈｇ）の液体でα−ピネンを原料として製造される。α-pinene oxide has a boiling point of 102-103℃ (50mn
Hg) is a liquid produced from α-pinene as a raw material.
α−ピネンオキシドをＩＱのビーカーに少量とリ、イガ
の幼虫数頭をいれて蓋をし数日放置したところ、α−ピ
ネンオキシドから気散した蒸気によりその殆どが死滅し
た。When a small amount of α-pinene oxide was placed in an IQ beaker, several burr larvae were placed in the beaker, the beaker was covered and left for several days, most of them were killed by the vapor released from the α-pinene oxide.
α−ピネンオキシドは常温で液体であるから適当な保持
剤、例えば厚紙、織布、多孔性素材に含浸させ、または
ゲル化剤等で固形化して使用する。Since α-pinene oxide is liquid at room temperature, it is used by impregnating it into a suitable holding agent, such as cardboard, woven cloth, or porous material, or by solidifying it with a gelling agent.
これはα−ピネンオキシド単独でも、他の防虫剤との複
合の場合でも適用することができる。This can be applied to α-pinene oxide alone or in combination with other insect repellents.
内容積約ＩＱの硝子製有蓋容器の底部に、薬剤１ｇを含
浸させた厚紙を置き、さらに羊毛と一緒にイガ幼虫１０
頭を約０．１．２Ｑの硝子容器に納めて、２０°Ｃ（７
５％Ｒ，Ｈ）の恒温恒湿槽に１週間放置した。A piece of cardboard impregnated with 1 g of the drug was placed at the bottom of a glass container with an internal volume of approximately IQ, and 10 bur larvae were placed along with the wool.
Place the head in a glass container of approximately 0.1.2Q and heat at 20°C (7
It was left in a constant temperature and humidity chamber (5% R, H) for one week.
試験結果は試験数５個の食害量と致死数の平均をもって
結果とした。The test results were taken as the average of the amount of feeding damage and the number of deaths for the five tested specimens.
試験結果を第１表に示す。The test results are shown in Table 1.
第１表
〔発明の効果〕
本発明のα−ピネンオキシドは強力な防虫剤で少量でも
優れた防虫性を有し、しかも長期に亘って効果は持続す
る。Table 1 [Effects of the Invention] The α-pinene oxide of the present invention is a strong insect repellent and has excellent insect repellent properties even in small amounts, and its effect persists for a long period of time.
その他人類用の防虫剤としての特性を有するので従来の
防虫剤にとって代る優れた防虫剤となるものと期待され
る。Since it has other properties as an insect repellent for humans, it is expected to be an excellent insect repellent to replace conventional insect repellents.
特許出願人 エステ−化学株式会社
手 続 補 正 書（方式）
％式％
１、事件の表示
昭和６１年特許願代第１５７３８４号
２、発明の名称
１丁１゛ワ イ、リ 寸４
防虫剤
３、補正をする者
事件との関係 特許出願人
住所 東京都薊宿区下落合１丁目４番１ｏ号昭和６１
年９月３０日（発送日）
５、補正の対象
願書及び明細書（タイプ浄書）
６、補正の内容
別紙のとおり（内容変更なし）Patent applicant Esthe Chemical Co., Ltd. Procedural amendment (method) % formula % 1. Indication of the case Patent application fee No. 157384 of 1988 2. Title of the invention 1. 3. Relationship with the case of the person making the amendment Patent applicant address: 1-4-1o, Shimoai, Ashinyuku-ku, Tokyo 1986
September 30, 2019 (shipment date) 5. Application and specification subject to amendment (type engraving) 6. Contents of amendment as attached (no change in content)
Claims (1)
３．１．１］ヘプタンを有効成分として含有する防虫剤
。2,6,6-trimethyl-2,3-epoxybicyclo[
3.1.1] Insect repellent containing heptane as an active ingredient.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP15738486A JPS6314703A (en) | 1986-07-03 | 1986-07-03 | Insecticide |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP15738486A JPS6314703A (en) | 1986-07-03 | 1986-07-03 | Insecticide |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS6314703A true JPS6314703A (en) | 1988-01-21 |
Family
ID=15648466
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP15738486A Pending JPS6314703A (en) | 1986-07-03 | 1986-07-03 | Insecticide |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS6314703A (en) |
-
1986
- 1986-07-03 JP JP15738486A patent/JPS6314703A/en active Pending
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