JPS6327406A - Insect repellent - Google Patents
Insect repellentInfo
- Publication number
- JPS6327406A JPS6327406A JP17031186A JP17031186A JPS6327406A JP S6327406 A JPS6327406 A JP S6327406A JP 17031186 A JP17031186 A JP 17031186A JP 17031186 A JP17031186 A JP 17031186A JP S6327406 A JPS6327406 A JP S6327406A
- Authority
- JP
- Japan
- Prior art keywords
- insect
- compound
- epoxybicyclo
- dimethyl
- heptane
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000077 insect repellent Substances 0.000 title claims abstract description 17
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000004480 active ingredient Substances 0.000 claims abstract 3
- 150000001875 compounds Chemical class 0.000 abstract description 6
- 241000238631 Hexapoda Species 0.000 abstract description 4
- 239000007788 liquid Substances 0.000 abstract description 3
- 239000004744 fabric Substances 0.000 abstract description 2
- 239000003349 gelling agent Substances 0.000 abstract description 2
- 230000000749 insecticidal effect Effects 0.000 abstract description 2
- 239000011148 porous material Substances 0.000 abstract description 2
- 241001465754 Metazoa Species 0.000 abstract 1
- 238000011109 contamination Methods 0.000 abstract 1
- 230000001846 repelling effect Effects 0.000 abstract 1
- 239000007787 solid Substances 0.000 abstract 1
- 230000001988 toxicity Effects 0.000 abstract 1
- 231100000419 toxicity Toxicity 0.000 abstract 1
- OUXAABAEPHHZPC-UHFFFAOYSA-N 6,6-dimethylspiro[bicyclo[3.1.1]heptane-4,2'-oxirane] Chemical compound CC1(C)C(CC2)CC1C12CO1 OUXAABAEPHHZPC-UHFFFAOYSA-N 0.000 description 6
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 239000002917 insecticide Substances 0.000 description 2
- WTARULDDTDQWMU-RKDXNWHRSA-N (+)-β-pinene Chemical compound C1[C@H]2C(C)(C)[C@@H]1CCC2=C WTARULDDTDQWMU-RKDXNWHRSA-N 0.000 description 1
- WTARULDDTDQWMU-IUCAKERBSA-N (-)-Nopinene Natural products C1[C@@H]2C(C)(C)[C@H]1CCC2=C WTARULDDTDQWMU-IUCAKERBSA-N 0.000 description 1
- DSSYKIVIOFKYAU-XCBNKYQSSA-N (R)-camphor Chemical compound C1C[C@@]2(C)C(=O)C[C@@H]1C2(C)C DSSYKIVIOFKYAU-XCBNKYQSSA-N 0.000 description 1
- OCJBOOLMMGQPQU-UHFFFAOYSA-N 1,4-dichlorobenzene Chemical compound ClC1=CC=C(Cl)C=C1 OCJBOOLMMGQPQU-UHFFFAOYSA-N 0.000 description 1
- 241000723346 Cinnamomum camphora Species 0.000 description 1
- WTARULDDTDQWMU-UHFFFAOYSA-N Pseudopinene Natural products C1C2C(C)(C)C1CCC2=C WTARULDDTDQWMU-UHFFFAOYSA-N 0.000 description 1
- 241000220317 Rosa Species 0.000 description 1
- XCPQUQHBVVXMRQ-UHFFFAOYSA-N alpha-Fenchene Natural products C1CC2C(=C)CC1C2(C)C XCPQUQHBVVXMRQ-UHFFFAOYSA-N 0.000 description 1
- 229930006722 beta-pinene Natural products 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 229930008380 camphor Natural products 0.000 description 1
- 229960000846 camphor Drugs 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 230000034994 death Effects 0.000 description 1
- 231100000517 death Toxicity 0.000 description 1
- 229940117389 dichlorobenzene Drugs 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- LCWMKIHBLJLORW-UHFFFAOYSA-N gamma-carene Natural products C1CC(=C)CC2C(C)(C)C21 LCWMKIHBLJLORW-UHFFFAOYSA-N 0.000 description 1
- 244000144972 livestock Species 0.000 description 1
- 231100000053 low toxicity Toxicity 0.000 description 1
- 230000002093 peripheral effect Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000008022 sublimation Effects 0.000 description 1
- 238000000859 sublimation Methods 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
Description
【発明の詳細な説明】
〔産業上の利用分野〕
本発明は新規な防虫剤に関する
〔従来の技術〕
従来防虫剤、殺虫剤として使用されているものは数多い
が、一般的農園芸用殺虫剤と異なり家庭内等の衣類収納
用家具、容器内で使用する衣類用防虫剤は多くはない。[Detailed Description of the Invention] [Field of Industrial Application] The present invention relates to a novel insect repellent [Prior Art] There are many insect repellents and insecticides that have been used in the past, but they are not applicable to general agricultural and horticultural insecticides. In contrast, there are not many insect repellents for clothing that are used in clothing storage furniture or containers at home.
それは人畜に対する毒性が低く、衣類等に対し汚染、損
傷を与えずに、イガ等特定の虫類に有効であること等の
制約を受けるためである。This is because it has low toxicity to humans and livestock, does not contaminate or damage clothing, etc., and is effective against specific insects such as burrs.
従ってナフタリン、樟脳、バラ−ジクロロベンゼン等の
古くから使用されている防虫剤が、それらが有する上記
特性の良さから今でも相当量使用されている。Therefore, insect repellents that have been used for a long time, such as naphthalene, camphor, and rose dichlorobenzene, are still used in considerable quantities because of the above-mentioned properties.
しかしこれらの防虫剤は効力が弱く、比較的短時間で気
散するため長期間効果を持続できず、頻繁に薬剤の補充
が必要であり、従って使用量が多くなる。However, these insect repellents have low efficacy and dissipate in a relatively short period of time, so they do not maintain their effectiveness over a long period of time, require frequent replenishment, and therefore require a large amount of use.
比較的少量で効果が長期間持続し、且つ安全な新しい防
虫剤の開発が望まれていた。It has been desired to develop a new insect repellent that is safe and effective for a long period of time with a relatively small amount.
本発明者は防虫剤として使用されている化合物の類縁あ
るいは周縁の化合物について種々研究した結果、６．６
−ジメチル−２．１０−エポキシビシクロ（３，１，１
：ｌヘプタン（以下これをβ−ピネンオキシドと呼ぶ）
が昇華性を有し、その気散ガスによる殺虫性が優れてい
ることを見出し本発明に到達した。As a result of various studies on compounds related to or peripheral to compounds used as insect repellents, the present inventor found that 6.6
-dimethyl-2.10-epoxybicyclo(3,1,1
:l heptane (hereinafter referred to as β-pinene oxide)
The present invention was achieved based on the discovery that the compound has sublimation properties and has excellent insecticidal properties due to its diffused gas.
β−ピネンオキシドは沸点９８〜１００℃（２７龍Ｈｇ
）の液体で、β−ピネンを原料として製造される。β-pinene oxide has a boiling point of 98-100°C (27 Hg
) is a liquid produced using β-pinene as a raw material.
β−ピネンオキシドを１１のビーカーに少量とり、イガ
の幼虫数頭を入れて蓋をし数日放置した所、β−ピネン
オキシドから気散した蒸気によシその殆どが死滅した〇
β−ピネンオキシドは常温で液体であるから適当な保持
剤１例えば厚紙、織布、多孔性素材に含浸させ、または
ゲル化剤等で固形化して使用する。A small amount of β-pinene oxide was placed in a beaker No. 11, several burr larvae were placed in the lid, and the lid was left for several days. Most of the larvae were killed by the steam released from the β-pinene oxide. Since the oxide is liquid at room temperature, it is used by impregnating it into a suitable holding agent 1, such as cardboard, woven cloth, or porous material, or by solidifying it with a gelling agent or the like.
これはβ−ピネンオキシド単独でも、他の防虫剤との複
合の場合でも適用することができる。This can be applied to β-pinene oxide alone or in combination with other insect repellents.
内容積約１ｊの硝子製有蓋容器の底部に、薬剤１ｆを含
浸させた厚紙を置き、さらに羊毛と一緒にイガ幼虫１０
頭を約０．１２ｊの硝子容器に納めて、２０℃（７５１
１Ｒ，Ｈ）の恒温恒湿槽に１週間放置した。A piece of cardboard impregnated with 1f of the drug was placed at the bottom of a glass container with an internal volume of about 1j, and 10 burr larvae were placed along with the wool.
Place the head in a glass container of approximately 0.12J and heat at 20℃ (751℃).
The sample was left in a constant temperature and humidity chamber (1R, H) for one week.
試験結果は試験数５回の食害量と致死数の平均をもって
結果とした。The test results were taken as the average of the amount of feeding damage and the number of deaths from five tests.
試験結果を第１表に示す。The test results are shown in Table 1.
第 １ 表
〔発明の効果〕
本発明のβ−ピネンオキシドは強力な防虫剤で少量でも
優れた防虫性を有し、しかも長期に亘って効果は持続す
る。Table 1 [Effects of the Invention] The β-pinene oxide of the present invention is a strong insect repellent and has excellent insect repellent properties even in small amounts, and the effect remains for a long period of time.
そのほか衣類用の防虫剤としての特性を有するので従来
の防虫剤にとって代る優れた防虫剤となるものと期待さ
れる。In addition, since it has properties as an insect repellent for clothing, it is expected to be an excellent insect repellent that can replace conventional insect repellents.
Claims (1)
１，１〕ヘプタンを有効成分として含有する防虫剤。[Claims] 6,6-dimethyl-2,10-epoxybicyclo[3,
1,1] Insect repellent containing heptane as an active ingredient.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP17031186A JPS6327406A (en) | 1986-07-18 | 1986-07-18 | Insect repellent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP17031186A JPS6327406A (en) | 1986-07-18 | 1986-07-18 | Insect repellent |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPS6327406A true JPS6327406A (en) | 1988-02-05 |
Family
ID=15902617
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP17031186A Pending JPS6327406A (en) | 1986-07-18 | 1986-07-18 | Insect repellent |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS6327406A (en) |
-
1986
- 1986-07-18 JP JP17031186A patent/JPS6327406A/en active Pending
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