JPS635006A - Insecticide - Google Patents
InsecticideInfo
- Publication number
- JPS635006A JPS635006A JP61147566A JP14756686A JPS635006A JP S635006 A JPS635006 A JP S635006A JP 61147566 A JP61147566 A JP 61147566A JP 14756686 A JP14756686 A JP 14756686A JP S635006 A JPS635006 A JP S635006A
- Authority
- JP
- Japan
- Prior art keywords
- camphene
- insecticide
- clothes
- insecticides
- long period
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000002917 insecticide Substances 0.000 title abstract description 11
- CRPUJAZIXJMDBK-UHFFFAOYSA-N camphene Chemical compound C1CC2C(=C)C(C)(C)C1C2 CRPUJAZIXJMDBK-UHFFFAOYSA-N 0.000 claims abstract description 22
- PXRCIOIWVGAZEP-UHFFFAOYSA-N Primaeres Camphenhydrat Natural products C1CC2C(O)(C)C(C)(C)C1C2 PXRCIOIWVGAZEP-UHFFFAOYSA-N 0.000 claims abstract description 11
- XCPQUQHBVVXMRQ-UHFFFAOYSA-N alpha-Fenchene Natural products C1CC2C(=C)CC1C2(C)C XCPQUQHBVVXMRQ-UHFFFAOYSA-N 0.000 claims abstract description 11
- 229930006739 camphene Natural products 0.000 claims abstract description 11
- ZYPYEBYNXWUCEA-UHFFFAOYSA-N camphenilone Natural products C1CC2C(=O)C(C)(C)C1C2 ZYPYEBYNXWUCEA-UHFFFAOYSA-N 0.000 claims abstract description 11
- 239000004480 active ingredient Substances 0.000 claims abstract 3
- 239000000077 insect repellent Substances 0.000 claims description 16
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 abstract description 4
- 230000000694 effects Effects 0.000 abstract description 4
- 230000000749 insecticidal effect Effects 0.000 abstract description 3
- 239000007787 solid Substances 0.000 abstract description 3
- 238000000859 sublimation Methods 0.000 abstract description 3
- 230000008022 sublimation Effects 0.000 abstract description 3
- DSSYKIVIOFKYAU-XCBNKYQSSA-N (R)-camphor Chemical compound C1C[C@@]2(C)C(=O)C[C@@H]1C2(C)C DSSYKIVIOFKYAU-XCBNKYQSSA-N 0.000 abstract description 2
- OCJBOOLMMGQPQU-UHFFFAOYSA-N 1,4-dichlorobenzene Chemical compound ClC1=CC=C(Cl)C=C1 OCJBOOLMMGQPQU-UHFFFAOYSA-N 0.000 abstract description 2
- 241000723346 Cinnamomum camphora Species 0.000 abstract description 2
- 229960000846 camphor Drugs 0.000 abstract description 2
- 229930008380 camphor Natural products 0.000 abstract description 2
- 231100000053 low toxicity Toxicity 0.000 abstract description 2
- 241000238631 Hexapoda Species 0.000 abstract 1
- 241001465754 Metazoa Species 0.000 abstract 1
- 238000010186 staining Methods 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 description 3
- 239000011521 glass Substances 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 235000019198 oils Nutrition 0.000 description 2
- 229920000298 Cellophane Polymers 0.000 description 1
- 239000001293 FEMA 3089 Substances 0.000 description 1
- 235000019501 Lemon oil Nutrition 0.000 description 1
- 239000010624 camphor oil Substances 0.000 description 1
- 229960000411 camphor oil Drugs 0.000 description 1
- 239000010632 citronella oil Substances 0.000 description 1
- 230000034994 death Effects 0.000 description 1
- 231100000517 death Toxicity 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 238000003898 horticulture Methods 0.000 description 1
- 239000010501 lemon oil Substances 0.000 description 1
- 244000144972 livestock Species 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- 230000002093 peripheral effect Effects 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 239000000341 volatile oil Substances 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
- Y02A50/30—Against vector-borne diseases, e.g. mosquito-borne, fly-borne, tick-borne or waterborne diseases whose impact is exacerbated by climate change
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
Description
【発明の詳細な説明】 C産業上の利用分野〕 本発明は新規な防虫剤に関する。[Detailed description of the invention] C Industrial application field] The present invention relates to a novel insect repellent.
従来防虫剤、殺虫剤として使用されているものは数多い
が、−般的農園芸用殺虫剤と異なり家庭内等の衣類収納
用家具、容器内で使用する衣類用防虫剤は多くはない。There are many insect repellents and insecticides that have been used in the past, but unlike insecticides for general agriculture and horticulture, there are not many insect repellents for clothing that are used in clothing storage furniture and containers in the home.
それは人畜に対する毒性が低く、衣類等に対し汚染、損
傷を与えずに、イガ等特定の土類に有効であること等の
制約を受けるためである。This is because it has low toxicity to humans and livestock, does not contaminate or damage clothing, etc., and is effective against specific soils such as burrs.
従ってナフタリン、樟脳、パラ−ジクロールベンゼン等
の古くから使用されている防虫剤が、それらが有する上
記特性の良さから今でも相当量使用されている。Therefore, insect repellents that have been used for a long time, such as naphthalene, camphor, and para-dichlorobenzene, are still used in considerable quantities because of their good properties.
しかしこれらの防虫剤は効力が弱く、比較的短時間で気
散するため長期間効果を持続できず、頻繁に薬剤の補充
が必要であり、従って使用量が多くなる。However, these insect repellents have low efficacy and dissipate in a relatively short period of time, so they do not maintain their effectiveness over a long period of time, require frequent replenishment, and therefore require a large amount of use.
比較的少量で効果が長期間持続し、且つ安全な新しい防
虫剤の開発が望まれていた。It has been desired to develop a new insect repellent that is safe and effective for a long period of time with a relatively small amount.
本発明者は防虫剤として使用されている化合物の類縁あ
るいは周縁の化合物について種々研究した結果、カンフ
エンが昇華性を有し、その気散ガスによる殺虫性が優れ
ていることを見出し本発明に到達した。As a result of various studies on compounds related to or peripheral to compounds used as insect repellents, the present inventor discovered that camphene has sublimation properties and has excellent insecticidal properties due to its vaporized gas, and has thus arrived at the present invention. did.
カンフエンはα−体、Q−体、及び准−体ともに融点5
2℃の固体で、それぞれ天然に得られる精油、例えばテ
レピン油、シブレス油、ショウノウ油、アビニス油、レ
モン油、シトロネラ油などに含まれている極めて安全性
の高い化合物である。Camphene has a melting point of 5 for both α-form, Q-form, and quasi-form.
It is a highly safe compound that is a solid at 2°C and is contained in naturally occurring essential oils such as turpentine oil, ciblet oil, camphor oil, avinis oil, lemon oil, and citronella oil.
又、ピネンを原料として工業的に製造さ九でいる6カン
フエンをIQのビーカーに少量とり、イガの幼虫数頭を
入れて蓋をし数日放置した所、カンフエンから気散した
蒸気によりその殆どが死滅した。In addition, when a small amount of camphuene, which is produced industrially from pinene as a raw material, was placed in an IQ beaker, several burr larvae were added, the lid was covered, and the mixture was left for several days. died out.
カンフエンは固体であるから従来の昇華性防虫剤と同じ
ように、粉末を和紙など通気性の袋に充填するか、タブ
レットまたはペレットをプラスチックまたは防湿セロフ
ァン等に適宜小さな孔を穿った袋に収納する。これはカ
ンフエン単独でも、他の昇華性防虫剤との複合の場合で
も適用することができる。Kangfuen is a solid, so just like conventional sublimation insect repellents, the powder is packed into a breathable bag such as Japanese paper, or the tablets or pellets are stored in a plastic or moisture-proof cellophane bag with appropriate small holes punched in it. . This can be applied either alone or in combination with other sublimable insect repellents.
内容積約IQの硝子製有蓋容器に1gの薬剤を秤量し、
容器底部に置き、さらに羊毛と一緒にイガ幼虫10頭を
約0.1212の硝子容器に納めて、20℃(75%R
,H)の恒温恒湿槽に1週間放置した。Weigh 1 g of drug into a glass lidded container with an internal volume of approximately IQ,
10 bur larvae were placed at the bottom of the container, and then placed in a glass container with a diameter of about 0.1212, and heated at 20℃ (75%R).
, H) was left in a constant temperature and humidity chamber for one week.
試験結果は試験数5個の食害量と致死数の平均をもって
結果とした。The test results were taken as the average of the amount of feeding damage and the number of deaths for the five tested specimens.
試験結果を第1表に示す。The test results are shown in Table 1.
第1表
〔発明の効果〕
本発明のカンフエンは強力な防虫剤で少量でも優れた防
虫性を有し、しかも長期に亘って効果は持続する。Table 1 [Effects of the Invention] The camphene of the present invention is a strong insect repellent and has excellent insect repellent properties even in small amounts, and the effect remains for a long period of time.
そのほか衣類用の防虫剤としての特性を有するので従来
の防虫剤にとって代る優れた防虫剤となるものと期待さ
れる。In addition, since it has properties as an insect repellent for clothing, it is expected to be an excellent insect repellent that can replace conventional insect repellents.
特許出願人 エステ−化学株式会社
手続補正書(方式)
%式%
工、事件の表示
昭和61年特許願代第147566号
2、発明の名称
防虫剤
3、補正をする者
事件との関係 特許出願人
住所 東京都新宿区下落合1丁目4番1o号名称
エステ−化学株式会社
昭和61年8月26日(発送臼)
5、補正の対象
願書及び明細書(タイプ浄書)
6、補正の内容
別紙のとおり(内容変更なし)Patent applicant Esthe Kagaku Co., Ltd. Procedural amendment (method) % formula % Engineering, case indication 1985 Patent application fee No. 147566 2, name of invention Insect repellent 3, person making the amendment Relationship with the case Patent application Address: 1-4-1o Shimoai, Shinjuku-ku, Tokyo Name
Esthe Kagaku Co., Ltd. August 26, 1985 (Shipping) 5. Application and specification subject to amendment (type engraving) 6. Contents of amendment as attached (no change in content)
Claims (1)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP61147566A JPS635006A (en) | 1986-06-24 | 1986-06-24 | Insecticide |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP61147566A JPS635006A (en) | 1986-06-24 | 1986-06-24 | Insecticide |
Publications (1)
Publication Number | Publication Date |
---|---|
JPS635006A true JPS635006A (en) | 1988-01-11 |
Family
ID=15433245
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP61147566A Pending JPS635006A (en) | 1986-06-24 | 1986-06-24 | Insecticide |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS635006A (en) |
-
1986
- 1986-06-24 JP JP61147566A patent/JPS635006A/en active Pending
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