JPS6314004B2 - - Google Patents
Info
- Publication number
- JPS6314004B2 JPS6314004B2 JP53100467A JP10046778A JPS6314004B2 JP S6314004 B2 JPS6314004 B2 JP S6314004B2 JP 53100467 A JP53100467 A JP 53100467A JP 10046778 A JP10046778 A JP 10046778A JP S6314004 B2 JPS6314004 B2 JP S6314004B2
- Authority
- JP
- Japan
- Prior art keywords
- stage
- mixture
- acrylate
- weight
- polymer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000178 monomer Substances 0.000 claims description 32
- 239000000203 mixture Substances 0.000 claims description 25
- 229920000642 polymer Polymers 0.000 claims description 18
- 239000000839 emulsion Substances 0.000 claims description 14
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 13
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 11
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 10
- 238000000034 method Methods 0.000 claims description 10
- 150000001412 amines Chemical class 0.000 claims description 8
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 claims description 7
- 239000006185 dispersion Substances 0.000 claims description 7
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 6
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 claims description 5
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims description 5
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims description 4
- 150000008065 acid anhydrides Chemical class 0.000 claims description 4
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 claims description 4
- 239000011976 maleic acid Substances 0.000 claims description 4
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 claims description 4
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 3
- 150000001732 carboxylic acid derivatives Chemical class 0.000 claims description 3
- -1 oxyalkyl ester Chemical class 0.000 claims description 3
- 125000000217 alkyl group Chemical group 0.000 claims description 2
- 150000008064 anhydrides Chemical class 0.000 claims description 2
- 150000002148 esters Chemical class 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 claims description 2
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 claims 4
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 claims 1
- 238000010438 heat treatment Methods 0.000 claims 1
- FQPSGWSUVKBHSU-UHFFFAOYSA-N methacrylamide Chemical compound CC(=C)C(N)=O FQPSGWSUVKBHSU-UHFFFAOYSA-N 0.000 claims 1
- 239000002685 polymerization catalyst Substances 0.000 claims 1
- 230000000379 polymerizing effect Effects 0.000 claims 1
- 238000000576 coating method Methods 0.000 description 10
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 9
- 239000011248 coating agent Substances 0.000 description 7
- 239000002245 particle Substances 0.000 description 5
- JHPBZFOKBAGZBL-UHFFFAOYSA-N (3-hydroxy-2,2,4-trimethylpentyl) 2-methylprop-2-enoate Chemical compound CC(C)C(O)C(C)(C)COC(=O)C(C)=C JHPBZFOKBAGZBL-UHFFFAOYSA-N 0.000 description 3
- 239000008199 coating composition Substances 0.000 description 3
- 239000003431 cross linking reagent Substances 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 238000006116 polymerization reaction Methods 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- 239000004094 surface-active agent Substances 0.000 description 3
- 239000004908 Emulsion polymer Substances 0.000 description 2
- YNAVUWVOSKDBBP-UHFFFAOYSA-N Morpholine Chemical compound C1COCCN1 YNAVUWVOSKDBBP-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- HQABUPZFAYXKJW-UHFFFAOYSA-N butan-1-amine Chemical compound CCCCN HQABUPZFAYXKJW-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 2
- 125000005395 methacrylic acid group Chemical group 0.000 description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 238000009736 wetting Methods 0.000 description 2
- RSNDTPFSMDVWCS-UHFFFAOYSA-N 2-(butoxymethyl)prop-2-enamide Chemical compound CCCCOCC(=C)C(N)=O RSNDTPFSMDVWCS-UHFFFAOYSA-N 0.000 description 1
- 229940058020 2-amino-2-methyl-1-propanol Drugs 0.000 description 1
- BFSVOASYOCHEOV-UHFFFAOYSA-N 2-diethylaminoethanol Chemical compound CCN(CC)CCO BFSVOASYOCHEOV-UHFFFAOYSA-N 0.000 description 1
- NPSJHQMIVNJLNN-UHFFFAOYSA-N 2-ethylhexyl 4-nitrobenzoate Chemical compound CCCCC(CC)COC(=O)C1=CC=C([N+]([O-])=O)C=C1 NPSJHQMIVNJLNN-UHFFFAOYSA-N 0.000 description 1
- 239000004808 2-ethylhexylester Substances 0.000 description 1
- CBEABRXUHNPKFM-UHFFFAOYSA-N 2-methylprop-2-enamide;styrene Chemical compound CC(=C)C(N)=O.C=CC1=CC=CC=C1 CBEABRXUHNPKFM-UHFFFAOYSA-N 0.000 description 1
- BNCADMBVWNPPIZ-UHFFFAOYSA-N 2-n,2-n,4-n,4-n,6-n,6-n-hexakis(methoxymethyl)-1,3,5-triazine-2,4,6-triamine Chemical compound COCN(COC)C1=NC(N(COC)COC)=NC(N(COC)COC)=N1 BNCADMBVWNPPIZ-UHFFFAOYSA-N 0.000 description 1
- 229920000178 Acrylic resin Polymers 0.000 description 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- UEEJHVSXFDXPFK-UHFFFAOYSA-N N-dimethylaminoethanol Chemical compound CN(C)CCO UEEJHVSXFDXPFK-UHFFFAOYSA-N 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 238000003915 air pollution Methods 0.000 description 1
- 229920000180 alkyd Polymers 0.000 description 1
- 125000003368 amide group Chemical group 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 229920003180 amino resin Polymers 0.000 description 1
- CBTVGIZVANVGBH-UHFFFAOYSA-N aminomethyl propanol Chemical compound CC(C)(N)CO CBTVGIZVANVGBH-UHFFFAOYSA-N 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 238000012662 bulk polymerization Methods 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 238000004581 coalescence Methods 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 239000006184 cosolvent Substances 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 229960002887 deanol Drugs 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 1
- 239000012972 dimethylethanolamine Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000010528 free radical solution polymerization reaction Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 239000003999 initiator Substances 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- 230000003472 neutralizing effect Effects 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 238000006068 polycondensation reaction Methods 0.000 description 1
- 229920001225 polyester resin Polymers 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 150000003077 polyols Chemical class 0.000 description 1
- 150000007519 polyprotic acids Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- ARJOQCYCJMAIFR-UHFFFAOYSA-N prop-2-enoyl prop-2-enoate Chemical compound C=CC(=O)OC(=O)C=C ARJOQCYCJMAIFR-UHFFFAOYSA-N 0.000 description 1
- HJWLCRVIBGQPNF-UHFFFAOYSA-N prop-2-enylbenzene Chemical compound C=CCC1=CC=CC=C1 HJWLCRVIBGQPNF-UHFFFAOYSA-N 0.000 description 1
- 150000003254 radicals Chemical class 0.000 description 1
- 230000003381 solubilizing effect Effects 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 229920003169 water-soluble polymer Polymers 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D151/00—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers
- C09D151/003—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers grafted on to macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F265/00—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00
- C08F265/04—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00 on to polymers of esters
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Polymers & Plastics (AREA)
- Medicinal Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Paints Or Removers (AREA)
- Polymerisation Methods In General (AREA)
- Graft Or Block Polymers (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US05/826,207 US4151143A (en) | 1977-08-19 | 1977-08-19 | Surfactant-free polymer emulsion coating composition and method for preparing same |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS5443286A JPS5443286A (en) | 1979-04-05 |
| JPS6314004B2 true JPS6314004B2 (enExample) | 1988-03-29 |
Family
ID=25245974
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP10046778A Granted JPS5443286A (en) | 1977-08-19 | 1978-08-19 | Twoostage preparation of polymer emulsion product containing no surfaceeactive agent |
Country Status (3)
| Country | Link |
|---|---|
| US (1) | US4151143A (enExample) |
| JP (1) | JPS5443286A (enExample) |
| CA (1) | CA1116773A (enExample) |
Families Citing this family (100)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5632513A (en) * | 1979-06-26 | 1981-04-02 | Rohm & Haas | Manufacture of aqueous dispersion of nonnwatersoluble core*sheath pigment like polymer granular body |
| CA1180474A (en) * | 1979-06-26 | 1985-01-02 | Alexander Kowalski | Sequential heteropolymer dispersion and a particulate material obtainable therefrom useful in coating compositions as a thickening and/or opacifying agent |
| US4325856A (en) * | 1980-01-02 | 1982-04-20 | The Dow Chemical Company | Sequential emulsion polymerization process |
| US4468498A (en) * | 1980-06-12 | 1984-08-28 | Rohm And Haas Company | Sequential heteropolymer dispersion and a particulate materal obtainable therefrom, useful in coating compositions as a thickening and/or opacifying agent |
| US4427836A (en) | 1980-06-12 | 1984-01-24 | Rohm And Haas Company | Sequential heteropolymer dispersion and a particulate material obtainable therefrom, useful in coating compositions as a thickening and/or opacifying agent |
| US4294741A (en) * | 1980-06-23 | 1981-10-13 | Ppg Industries, Inc. | Cationic polymers and their use in electrodeposition |
| US4297261A (en) * | 1980-06-23 | 1981-10-27 | Ppg Industries, Inc. | Cationic polymers and their use in electrodeposition |
| US4304703A (en) * | 1980-06-23 | 1981-12-08 | Ppg Industries, Inc. | Cationic polymer dispersions and their method of preparation |
| US4440897A (en) * | 1982-06-01 | 1984-04-03 | Ppg Industries, Inc. | Process of making substantially external surfactant-free vinyl polymer emulsion products |
| FR2557574B1 (fr) * | 1983-12-30 | 1986-11-21 | Norsolor Sa | Dispersion aqueuse de polymere de stabilite amelioree, son procede de fabrication et son application a la formulation de peintures |
| AU557547B2 (en) * | 1984-08-29 | 1986-12-24 | National Starch & Chemical Corporation | Aqueous coating for meatllised paper |
| US4594363A (en) * | 1985-01-11 | 1986-06-10 | Rohm And Haas Company | Production of core-sheath polymer particles containing voids, resulting product and use |
| DE3543361A1 (de) * | 1985-12-07 | 1987-06-11 | Basf Ag | Verfahren zur herstellung waessriger polymerdispersionen und deren verwendung |
| US4642323A (en) * | 1985-12-30 | 1987-02-10 | Ppg Industries, Inc. | Process for preparing latex polymers from gaseous monomers |
| US4692491A (en) * | 1985-12-30 | 1987-09-08 | Ppg Industries, Inc. | Polymer emulsion products |
| US4791151A (en) * | 1986-07-14 | 1988-12-13 | Rohm And Haas Company | Multilobals |
| US4845149A (en) * | 1986-08-22 | 1989-07-04 | S. C. Johnson & Son, Inc. | Pressure sensitive adhesive compositions |
| US4839413A (en) * | 1986-08-22 | 1989-06-13 | S.C. Johnson & Son, Inc. | Resin-fortified emulsion polymers and methods of preparing the same |
| CA1318433C (en) † | 1986-08-22 | 1993-05-25 | S. C. Johnson & Son, Inc. | Pressure sensitive adhesive compositions |
| US4820762A (en) * | 1986-08-22 | 1989-04-11 | S.C. Johnson & Son, Inc. | Resin-fortified emulsion polymers and methods of preparing the same |
| US5047454A (en) * | 1987-02-03 | 1991-09-10 | Basf Corporation | Waterborne pigmented acrylic hydrosol coating composition |
| US4797444A (en) * | 1987-02-03 | 1989-01-10 | Basf Corporation | Waterborne pigmented acrylic hydrosol coating composition and process |
| US4758641A (en) * | 1987-02-24 | 1988-07-19 | The B F Goodrich Company | Polycarboxylic acids with small amount of residual monomer |
| US4973621A (en) * | 1987-04-07 | 1990-11-27 | Akzo N.V. | Aqueous coating composition based on a dispersion of an addition polymer, especially suited to be used in an aqueous base coat |
| NO172967C (no) * | 1987-11-06 | 1993-10-06 | Rohm & Haas | Fremgangsmaate til innkapsling eller til aa bringe i fast tilstand et produkt som omfatter en stort sett kontinuerligvandig fase og loeste eller suspenderte stoffer |
| DE3743040A1 (de) * | 1987-12-18 | 1989-07-13 | Basf Ag | Verfahren zur herstellung von waessrigen polymerdispersionen |
| US5081166A (en) * | 1988-04-21 | 1992-01-14 | S. C. Johnson & Son, Inc. | Process for producing a stabilized latex emulsion adhesive |
| US4894397A (en) * | 1988-04-21 | 1990-01-16 | S. C. Johnson & Son, Inc. | Stable emulsion polymers and methods of preparing same |
| US5045435A (en) * | 1988-11-25 | 1991-09-03 | Armstrong World Industries, Inc. | Water-borne, alkali-developable, photoresist coating compositions and their preparation |
| JPH0655923B2 (ja) * | 1989-04-05 | 1994-07-27 | ユシロ化学工業株式会社 | 水性保護用組成物 |
| DE3942804A1 (de) * | 1989-12-23 | 1991-06-27 | Basf Lacke & Farben | Verfahren zur herstellung eines mehrschichtigen ueberzuges |
| JPH0733410B2 (ja) * | 1990-08-03 | 1995-04-12 | 東洋シール工業株式会社 | 架橋可能なアクリルゴムの製造方法 |
| US5641829A (en) * | 1991-12-30 | 1997-06-24 | Ppg Industries, Inc. | Coating compositions prepared from base neutralized, stable aqueous dispersion of hydroxyl functional acrylic polymers |
| US5464897A (en) * | 1991-12-30 | 1995-11-07 | Ppg Industries, Inc. | Aqueous fluoropolymer dispersions |
| US5342878A (en) * | 1991-12-30 | 1994-08-30 | Ppg Industries, Inc. | Base neutralized, stable, aqueous dispersion of a hydroxyl functional acrylic polymer and coating compositions prepared therefrom |
| DE4220807A1 (de) * | 1992-06-25 | 1994-01-05 | Basf Ag | In Zweistufenfahrweise hergestellte Vinylpolymerisate und ihre Verwendung als Lackbindemittel |
| US5286778A (en) * | 1992-09-28 | 1994-02-15 | Ppg Industries, Inc. | Latices and waterborne compositions for wood stains, sealers, and the like |
| US5461103A (en) * | 1993-05-11 | 1995-10-24 | Air Products And Chemicals, Inc. | Process for producing a stable aqueous pressure sensitive adhesive polymer emulsion |
| GB9316221D0 (en) * | 1993-08-05 | 1993-09-22 | Zeneca Ltd | Production of polymer emulsions |
| DE4330767A1 (de) * | 1993-09-10 | 1995-03-16 | Hoechst Ag | Polymermischungen mit Wasser |
| US5395877A (en) * | 1993-12-20 | 1995-03-07 | Sun Chemical Corporation | Process for the production of stable high wax content vinyl latices |
| EP0675177A3 (en) * | 1994-03-25 | 1998-02-25 | The B.F. Goodrich Company | Heat resistant coating composition |
| GB9408725D0 (en) * | 1994-05-03 | 1994-06-22 | Zeneca Resins Bv | Production of aqueous polymer compositions |
| US6258888B1 (en) * | 1994-12-21 | 2001-07-10 | Zeneca Resins Bv | Aqueous polymer emulsions |
| DE19505039A1 (de) * | 1995-02-15 | 1996-08-22 | Basf Ag | Verfahren zur Herstellung von emulgatorfreien wäßrigen Polymerdispersionen |
| DE19508191A1 (de) * | 1995-03-09 | 1996-09-12 | Hoechst Ag | Anionische Polymermischungen mit reduzierter Schaumbildung in Wasser |
| US5591489A (en) * | 1995-05-04 | 1997-01-07 | Sequa Chemicals, Inc. | Process for surface sizing paper or paperboard |
| US5512607A (en) * | 1995-06-06 | 1996-04-30 | W. R. Grace & Co.-Conn. | Unsaturated epoxy ester with quaternary ammonium and phosphate groups |
| WO1996041240A1 (en) * | 1995-06-07 | 1996-12-19 | W.R. Grace & Co.-Conn. | Water photoresist emulsions and methods of preparation thereof |
| US5739196A (en) * | 1995-11-30 | 1998-04-14 | Union Carbide Chemicals & Plastics Technology Corporation | Latex compositions having wet adhesion and other improved rheological properties and methods of producing same |
| DE19600405A1 (de) | 1996-01-08 | 1997-07-10 | Basf Ag | Verfahren zur Herstellung von wasserunlöslichen Polymerisaten |
| DE19625773A1 (de) * | 1996-06-27 | 1998-01-02 | Hoechst Ag | Dispersionen oder Lösungen von Polymeren und Polymermischungen in Wasser |
| DE19814061A1 (de) | 1998-03-30 | 1999-10-07 | Bayer Ag | Copolymerisatdispersionen, Bindemittelkombinationen auf Basis der Copolymerisatdispersionen, ein Verfahren zu deren Herstellung und deren Verwendung |
| US6020438A (en) * | 1998-06-09 | 2000-02-01 | The B. F. Goodrich Company | Supported vinyl chloride emulsion (co) polymers and process for making the same |
| DE19903391A1 (de) | 1999-01-29 | 2000-08-03 | Bayer Ag | Wäßriges Überzugsmittel, Verfahren zu seiner Herstellung und seine Verwendung |
| US6683129B1 (en) * | 2000-03-31 | 2004-01-27 | National Starch And Chemical Investment Holding Corporation | Salt sensitive aqueous emulsions |
| US7749540B2 (en) * | 2000-10-11 | 2010-07-06 | Cephalon, Inc. | Compositions comprising modafinil compounds |
| US20030008591A1 (en) * | 2001-06-18 | 2003-01-09 | Parsons John C. | Water dispersible, salt sensitive nonwoven materials |
| DK1298174T3 (da) * | 2001-09-28 | 2006-11-27 | Ostendorf J W Gmbh & Co Kg | Laksammensætning på vandbasis |
| CN100412114C (zh) * | 2003-04-02 | 2008-08-20 | 瓦尔斯帕供应公司 | 水性分散体和涂料 |
| ES2367516T3 (es) * | 2004-10-20 | 2011-11-04 | Valspar Sourcing, Inc. | Composiciones de recubrimiento para latas y métodos de recubrimiento. |
| US7320831B2 (en) * | 2005-05-03 | 2008-01-22 | Celanese International Corporation | Salt-sensitive vinyl acetate binder compositions and fibrous article incorporating same |
| US7329705B2 (en) | 2005-05-03 | 2008-02-12 | Celanese International Corporation | Salt-sensitive binder compositions with N-alkyl acrylamide and fibrous articles incorporating same |
| US20070015873A1 (en) * | 2005-07-13 | 2007-01-18 | Fenn David R | Electrodepositable aqueous resinous dispersions and methods for their preparation |
| US7589158B2 (en) * | 2005-11-30 | 2009-09-15 | Columbia Insurance Company | Polymers with improved shelf stability |
| US7989545B2 (en) * | 2006-01-25 | 2011-08-02 | Celanese International Corporations | Salt-sensitive binders for nonwoven webs and method of making same |
| EP1975185B1 (en) * | 2007-03-30 | 2010-10-13 | M-real Oyj | Grafted interpolymer latex and method of preparing thereof |
| GB0822674D0 (en) * | 2008-12-12 | 2009-01-21 | Nuplex Resins Bv | A crosslinkable polymer binder |
| CN102387924B (zh) | 2009-04-09 | 2014-10-15 | 威士伯采购公司 | 具有不饱和脂环官能团的聚合物以及由其形成的涂料组合物 |
| TWI483953B (zh) | 2009-06-30 | 2015-05-11 | Lubrizol Advanced Mat Inc | 複合聚合物乳化液 |
| US8486574B2 (en) * | 2009-07-14 | 2013-07-16 | Ford Global Technologies, Llc | Method and system for power control in an automotive vehicle |
| US8754614B2 (en) * | 2009-07-17 | 2014-06-17 | Tesla Motors, Inc. | Fast charging of battery using adjustable voltage control |
| WO2011009040A1 (en) | 2009-07-17 | 2011-01-20 | Valspar Sourcing, Inc. | Coating composition and articles coated therewith |
| AU2010295405B2 (en) | 2009-09-18 | 2015-09-24 | Swimc Llc | Polyurethane coating composition |
| CN102464754B (zh) * | 2010-11-03 | 2013-10-23 | 展华化学工业股份有限公司 | 一种无乳化剂的丙烯酸酯乳液聚合方法 |
| US8343601B1 (en) | 2011-07-06 | 2013-01-01 | Bayer Materialscience Llc | Waterborne polyurethane coating compositions |
| WO2013092515A2 (en) * | 2011-12-22 | 2013-06-27 | Bayer Intellectual Property Gmbh | Fluorescent polyacrylate dispersions |
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| CN106133051A (zh) | 2014-01-30 | 2016-11-16 | 巴斯夫欧洲公司 | 疏水性单体的树脂载体乳液聚合 |
| EP4155356B1 (en) | 2014-12-24 | 2024-09-11 | Swimc Llc | Coating compositions for packaging articles such as food and beverage containers |
| US11059989B2 (en) | 2017-06-30 | 2021-07-13 | Valspar Sourcing, Inc. | Crosslinked coating compositions for packaging articles such as food and beverage containers |
| US11981822B2 (en) | 2014-12-24 | 2024-05-14 | Swimc Llc | Crosslinked coating compositions for packaging articles such as food and beverage containers |
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| JP6812642B2 (ja) * | 2016-03-01 | 2021-01-13 | 三菱ケミカル株式会社 | 水性分散体の製造方法 |
| TWI610992B (zh) * | 2016-11-22 | 2018-01-11 | 南亞塑膠工業股份有限公司 | 一種具高硬度高密著特性的水性環保塗料及其製造方法 |
| KR102042782B1 (ko) * | 2017-03-15 | 2019-11-27 | 한화케미칼 주식회사 | 에멀젼, 에멀젼의 제조 방법 및 에멀젼을 이용한 코팅막 형성 방법 |
| WO2019241209A1 (en) * | 2018-06-11 | 2019-12-19 | Swimc Llc | Packaging coating containing water-dispersible acrylic block copolymer |
| US10947408B2 (en) | 2018-06-27 | 2021-03-16 | Prc-Desoto International, Inc. | Electrodepositable coating composition |
| CN109608612B (zh) * | 2018-11-25 | 2021-03-09 | 中国海洋石油集团有限公司 | 水性抗流挂聚合物及其制备方法 |
| EP3670552B8 (en) | 2018-12-19 | 2023-07-12 | Organik Kimya Sanayi Ve Tic. A.S. | Polymodal and alkali soluble resin supported emulsion polymers |
| US11485874B2 (en) | 2019-06-27 | 2022-11-01 | Prc-Desoto International, Inc. | Addition polymer for electrodepositable coating compositions |
| US11313048B2 (en) | 2019-06-27 | 2022-04-26 | Prc-Desoto International, Inc. | Addition polymer for electrodepositable coating compositions |
| US11274167B2 (en) | 2019-06-27 | 2022-03-15 | Prc-Desoto International, Inc. | Carbamate functional monomers and polymers and use thereof |
| WO2021197883A1 (en) | 2020-04-01 | 2021-10-07 | Covestro (Netherlands) B.V. | Process for preparing aqueous polymer dispersions |
| CN117222711A (zh) * | 2021-03-05 | 2023-12-12 | Ppg工业俄亥俄公司 | 可电沉积的涂料组合物 |
| EP4444766B1 (en) | 2021-12-09 | 2025-10-15 | Covestro (Netherlands) B.V. | Aqueous binder composition |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2987493A (en) * | 1956-07-04 | 1961-06-06 | British Celanese | Emulsion polymerization using copolymer of a salt of methacrylic acid and vinyl acetate |
| US2906724A (en) * | 1957-03-21 | 1959-09-29 | American Cyanamid Co | Composition containing polymethylol melamine and an ammonium salt of a copolymer of an unsaturated monocarboxylic acid and an alkyl ester of such an acid |
| US3313755A (en) * | 1962-03-09 | 1967-04-11 | Knomark Inc | Aqueous polymer latices containing an emulsifier of a partial ester of a styrene-maleic acid anhydride copolymer |
| US3218280A (en) * | 1963-05-16 | 1965-11-16 | American Cyanamid Co | Aqueous blend of an emulsion copolymer, an ammoniated copolymer and the hexamethyl ether of hexamethylol melamine |
| US3396135A (en) * | 1964-07-02 | 1968-08-06 | Monsanto Co | Coating composition containing styrenemaleic anhydride partial ester copolymer as emulsifier |
| US3457324A (en) * | 1966-06-10 | 1969-07-22 | Desoto Inc | Thermosetting coating compositions comprising hydroxy-functional interpolymers |
| US3880793A (en) * | 1972-03-30 | 1975-04-29 | Kansai Paint Co Ltd | Emulsifiers for emulsion polymerization of vinyl monomers |
| US3821145A (en) * | 1972-12-22 | 1974-06-28 | Du Pont | Aqueous coating composition of an acrylic graft copolymer,a linear acrylic polymer and a cross-linking agent |
| JPS5425530B2 (enExample) * | 1974-03-28 | 1979-08-29 | ||
| JPS5922722B2 (ja) * | 1975-09-12 | 1984-05-29 | 関西ペイント株式会社 | エマルジヨン組成物 |
| US4064087A (en) * | 1976-01-05 | 1977-12-20 | Ppg Industries, Inc. | Method for preparing polymers in aqueous medium |
-
1977
- 1977-08-19 US US05/826,207 patent/US4151143A/en not_active Expired - Lifetime
-
1978
- 1978-07-17 CA CA000307509A patent/CA1116773A/en not_active Expired
- 1978-08-19 JP JP10046778A patent/JPS5443286A/ja active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| JPS5443286A (en) | 1979-04-05 |
| CA1116773A (en) | 1982-01-19 |
| US4151143A (en) | 1979-04-24 |
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