JPS63131796U - - Google Patents
Info
- Publication number
- JPS63131796U JPS63131796U JP1987151760U JP15176087U JPS63131796U JP S63131796 U JPS63131796 U JP S63131796U JP 1987151760 U JP1987151760 U JP 1987151760U JP 15176087 U JP15176087 U JP 15176087U JP S63131796 U JPS63131796 U JP S63131796U
- Authority
- JP
- Japan
- Prior art keywords
- composite material
- cathode
- base
- utility
- respect
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229920000049 Carbon (fiber) Polymers 0.000 claims description 5
- 239000004917 carbon fiber Substances 0.000 claims description 5
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 3
- 239000002131 composite material Substances 0.000 claims 3
- 239000008151 electrolyte solution Substances 0.000 claims 2
- 239000000463 material Substances 0.000 claims 2
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims 2
- 150000001412 amines Chemical class 0.000 claims 1
- 239000003822 epoxy resin Substances 0.000 claims 1
- 229920000647 polyepoxide Polymers 0.000 claims 1
- 239000000835 fiber Substances 0.000 description 5
- 238000001228 spectrum Methods 0.000 description 4
- 229940075397 calomel Drugs 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- ZOMNIUBKTOKEHS-UHFFFAOYSA-L dimercury dichloride Chemical compound Cl[Hg][Hg]Cl ZOMNIUBKTOKEHS-UHFFFAOYSA-L 0.000 description 2
- 239000003792 electrolyte Substances 0.000 description 2
- 238000001941 electron spectroscopy Methods 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- 150000002500 ions Chemical group 0.000 description 1
- 238000004949 mass spectrometry Methods 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F11/00—Chemical after-treatment of artificial filaments or the like during manufacture
- D01F11/10—Chemical after-treatment of artificial filaments or the like during manufacture of carbon
- D01F11/16—Chemical after-treatment of artificial filaments or the like during manufacture of carbon by physicochemical methods
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K9/00—Use of pretreated ingredients
- C08K9/02—Ingredients treated with inorganic substances
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F11/00—Chemical after-treatment of artificial filaments or the like during manufacture
- D01F11/10—Chemical after-treatment of artificial filaments or the like during manufacture of carbon
- D01F11/12—Chemical after-treatment of artificial filaments or the like during manufacture of carbon with inorganic substances ; Intercalation
- D01F11/122—Oxygen, oxygen-generating compounds
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F11/00—Chemical after-treatment of artificial filaments or the like during manufacture
- D01F11/10—Chemical after-treatment of artificial filaments or the like during manufacture of carbon
- D01F11/14—Chemical after-treatment of artificial filaments or the like during manufacture of carbon with organic compounds, e.g. macromolecular compounds
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31511—Of epoxy ether
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Textile Engineering (AREA)
- Engineering & Computer Science (AREA)
- Medicinal Chemistry (AREA)
- Organic Chemistry (AREA)
- Polymers & Plastics (AREA)
- Health & Medical Sciences (AREA)
- Inorganic Chemistry (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
- Reinforced Plastic Materials (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Description
第1図は、本考案の炭素繊維表面を処理するた
めの実験装置を示す概略図である。第2図は、繊
維電位の関数として電流が変化する様子を示す特
性曲線である。第3図は、本考案の炭素繊維表面
を処理するために用いられる工業段階での装置を
示す略図である。第4a図および第4b図は、未
処理繊維に対し、電子分光法を用いて得られたス
ペクトルである。第5a図乃至第5c図は、処理
繊維に対し、電子分光法を用いて得られたスペク
トルである。第6図は、未処理繊維から得られる
2次イオンの質量分析を行なつた結果のスペクト
ルである。第7図は、処理繊維について、第6図
と同じ要領によつて得られたスペクトルである。 1……タンク、2……電解液、3……炭素繊維
、4……支持体、5……白金陰極、6……カロメ
ル基準電極、7…………電源、8……パイプ、1
0……粗糸、11……ローラー、12……電解液
、13……タンク、14……ローラー、15……
ローラー、16……供給源、17……ステンレス
鋼陰極、18……カロメル基準電極、19……制
御端子、50,51,52,53……曲線。
めの実験装置を示す概略図である。第2図は、繊
維電位の関数として電流が変化する様子を示す特
性曲線である。第3図は、本考案の炭素繊維表面
を処理するために用いられる工業段階での装置を
示す略図である。第4a図および第4b図は、未
処理繊維に対し、電子分光法を用いて得られたス
ペクトルである。第5a図乃至第5c図は、処理
繊維に対し、電子分光法を用いて得られたスペク
トルである。第6図は、未処理繊維から得られる
2次イオンの質量分析を行なつた結果のスペクト
ルである。第7図は、処理繊維について、第6図
と同じ要領によつて得られたスペクトルである。 1……タンク、2……電解液、3……炭素繊維
、4……支持体、5……白金陰極、6……カロメ
ル基準電極、7…………電源、8……パイプ、1
0……粗糸、11……ローラー、12……電解液
、13……タンク、14……ローラー、15……
ローラー、16……供給源、17……ステンレス
鋼陰極、18……カロメル基準電極、19……制
御端子、50,51,52,53……曲線。
Claims (1)
- 【実用新案登録請求の範囲】 (1) 弱アミノ塩基からなる電解質溶液に接触さ
せ、それを陰極に対して正に分極させて処理した
炭素繊維を、弱アミノ塩基からなる電解質溶液に
接触させ、かつそれを、陰極に対して正に分極さ
せて行なう処理方法によつて得られた炭素繊維を
用いて強化した母材からなることを特徴とする複
合材料。 (2) 母材が、アミンによつて硬化されたエポキ
シ樹脂であることを特徴とする実用新案登録請求
の範囲第(1)項に記載の複合材料。
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR8407814A FR2564489B1 (fr) | 1984-05-18 | 1984-05-18 | Procede electrochimique de traitement de surface de fibres de carbone, fibre traitee par ce procede et materiau composite comportant de telles fibres |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS63131796U true JPS63131796U (ja) | 1988-08-29 |
JPH0322314Y2 JPH0322314Y2 (ja) | 1991-05-15 |
Family
ID=9304170
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP60106803A Pending JPS60252770A (ja) | 1984-05-18 | 1985-05-18 | 炭素繊維、その処理方法、および処理済炭素繊維を使用する複合材料 |
JP1987151760U Expired JPH0322314Y2 (ja) | 1984-05-18 | 1987-10-05 |
Family Applications Before (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP60106803A Pending JPS60252770A (ja) | 1984-05-18 | 1985-05-18 | 炭素繊維、その処理方法、および処理済炭素繊維を使用する複合材料 |
Country Status (6)
Country | Link |
---|---|
US (1) | US4690738A (ja) |
JP (2) | JPS60252770A (ja) |
CA (1) | CA1256395A (ja) |
DE (1) | DE3517657C2 (ja) |
FR (1) | FR2564489B1 (ja) |
GB (1) | GB2159178B (ja) |
Families Citing this family (30)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH0621420B2 (ja) * | 1985-08-20 | 1994-03-23 | 東燃株式会社 | 炭素繊維の表面処理法 |
JPS6385167A (ja) * | 1986-09-22 | 1988-04-15 | 東レ株式会社 | 表面改質炭素繊維とその製造方法 |
FR2607528B1 (fr) * | 1986-12-02 | 1989-03-17 | Onera (Off Nat Aerospatiale) | Procede electrochimique de traitement de surface de carbone; carbone, notamment fibres de carbone, traite par ce procede et materiau composite comportant de telles fibres |
JPH01168963A (ja) * | 1987-12-22 | 1989-07-04 | Toray Ind Inc | 炭素繊維の表面処理方法 |
US5462799A (en) * | 1993-08-25 | 1995-10-31 | Toray Industries, Inc. | Carbon fibers and process for preparing same |
JP3415274B2 (ja) * | 1994-07-05 | 2003-06-09 | 三菱レイヨン株式会社 | 樹脂補強用炭素繊維の製造方法 |
IL116378A (en) | 1994-12-15 | 2003-05-29 | Cabot Corp | Non-aqueous coating or ink composition with improved optical properties containing modified carbon product and method of preparation of the composition |
US5559169A (en) | 1994-12-15 | 1996-09-24 | Cabot Corporation | EPDM, HNBR and Butyl rubber compositions containing carbon black products |
US5575845A (en) | 1994-12-15 | 1996-11-19 | Cabot Corporation | Carbon black products for coloring mineral binders |
IL116379A (en) | 1994-12-15 | 2003-12-10 | Cabot Corp | Aqueous inks and coatings containing modified carbon products |
US5554739A (en) | 1994-12-15 | 1996-09-10 | Cabot Corporation | Process for preparing carbon materials with diazonium salts and resultant carbon products |
US5571311A (en) | 1994-12-15 | 1996-11-05 | Cabot Corporation | Ink jet ink formulations containing carbon black products |
IL154538A (en) | 1994-12-15 | 2009-12-24 | Cabot Corp | The reaction of carbon black with diazonium salts, the resulting carbon black products |
IL116376A (en) | 1994-12-15 | 2001-03-19 | Cabot Corp | Aqueous ink jet ink compositions containing modified carbon products |
US6028137A (en) | 1995-05-22 | 2000-02-22 | Cabot Corporation | Elastomeric compounds incorporating silicon-treated carbon blacks |
US6323273B1 (en) | 1995-05-22 | 2001-11-27 | Cabot Corporation | Elastomeric compounds incorporating silicon-treated carbon blacks |
TW440594B (en) | 1995-05-22 | 2001-06-16 | Cabot Corp | Elastomeric compounds incorporating partially coated carbon blacks |
US5958999A (en) | 1996-04-05 | 1999-09-28 | Cabot Corporation | Ink compositions and method for generating images produced therefrom |
US6273830B1 (en) * | 1996-04-19 | 2001-08-14 | Nippon Mitsubishi Oil Corporation | Tapered hollow shaft |
US5747562A (en) | 1996-06-14 | 1998-05-05 | Cabot Corporation | Ink and coating compositions containing silicon-treated carbon black |
US5707432A (en) | 1996-06-14 | 1998-01-13 | Cabot Corporation | Modified carbon products and inks and coatings containing modified carbon products |
US5698016A (en) | 1996-06-14 | 1997-12-16 | Cabot Corporation | Compositions of modified carbon products and amphiphilic ions and methods of using the same |
US5919855A (en) | 1997-02-11 | 1999-07-06 | Cabot Corporation | Use of modified carbon black in gas-phase polymerizations |
KR100866777B1 (ko) * | 2006-12-28 | 2008-11-04 | 전자부품연구원 | 탄소 재료의 활성화 장치 및 탄소 재료의 활성화 방법 |
US9018344B2 (en) | 2011-03-28 | 2015-04-28 | Hitachi Chemical Company, Ltd | Polymers for thin film coatings |
WO2016104467A1 (ja) * | 2014-12-26 | 2016-06-30 | 乗明 伊集院 | 炭素繊維、その製造方法及び炭素繊維強化樹脂組成物 |
US20180023244A1 (en) * | 2016-07-19 | 2018-01-25 | Hexcel Corporation | Composite carbon fibers |
CN106319933B (zh) * | 2016-08-17 | 2019-06-07 | 山东大学 | 用于表面生长碳纳米管的碳纤维电化学处理方法 |
EP3631058A1 (en) | 2017-05-26 | 2020-04-08 | Dow Global Technologies LLC | Electrochemical grafting of carbon fibers with aliphatic amines for improved composite strength |
US10894868B2 (en) | 2017-12-21 | 2021-01-19 | Hexcel Corporation | Composite carbon fibers |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5982467A (ja) * | 1982-10-29 | 1984-05-12 | 三菱レイヨン株式会社 | 炭素繊維の表面処理方法 |
Family Cites Families (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3776829A (en) * | 1971-10-26 | 1973-12-04 | Great Lakes Carbon Corp | Aminated carbon fibers |
FR2180617B1 (ja) * | 1972-04-21 | 1974-09-13 | Rhone Progil | |
US3859187A (en) * | 1972-09-25 | 1975-01-07 | Celanese Corp | Electrolytic process for the surface modification of high modulus carbon fibers |
GB1433712A (en) * | 1974-06-06 | 1976-04-28 | Hercules Inc | Electrolytic treatment of graphite fibres |
JPS585288B2 (ja) * | 1978-04-12 | 1983-01-29 | 東レ株式会社 | 炭素繊維の表面電解処理法及びその電解槽 |
JPS56128362A (en) * | 1980-03-05 | 1981-10-07 | Toho Beslon Co | Production of carbon fiber |
JPS5835881A (ja) * | 1981-08-27 | 1983-03-02 | Kao Corp | 電気化学電池 |
-
1984
- 1984-05-18 FR FR8407814A patent/FR2564489B1/fr not_active Expired
-
1985
- 1985-05-08 CA CA000481065A patent/CA1256395A/en not_active Expired
- 1985-05-10 US US06/733,227 patent/US4690738A/en not_active Expired - Lifetime
- 1985-05-15 DE DE3517657A patent/DE3517657C2/de not_active Expired - Lifetime
- 1985-05-17 GB GB08512509A patent/GB2159178B/en not_active Expired
- 1985-05-18 JP JP60106803A patent/JPS60252770A/ja active Pending
-
1987
- 1987-10-05 JP JP1987151760U patent/JPH0322314Y2/ja not_active Expired
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5982467A (ja) * | 1982-10-29 | 1984-05-12 | 三菱レイヨン株式会社 | 炭素繊維の表面処理方法 |
Also Published As
Publication number | Publication date |
---|---|
DE3517657C2 (de) | 1991-02-14 |
DE3517657A1 (de) | 1985-11-21 |
FR2564489A1 (fr) | 1985-11-22 |
GB8512509D0 (en) | 1985-06-19 |
JPS60252770A (ja) | 1985-12-13 |
US4690738A (en) | 1987-09-01 |
FR2564489B1 (fr) | 1986-10-10 |
GB2159178A (en) | 1985-11-27 |
JPH0322314Y2 (ja) | 1991-05-15 |
GB2159178B (en) | 1987-12-23 |
CA1256395A (en) | 1989-06-27 |
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