JPS6252694B2 - - Google Patents
Info
- Publication number
- JPS6252694B2 JPS6252694B2 JP53156343A JP15634378A JPS6252694B2 JP S6252694 B2 JPS6252694 B2 JP S6252694B2 JP 53156343 A JP53156343 A JP 53156343A JP 15634378 A JP15634378 A JP 15634378A JP S6252694 B2 JPS6252694 B2 JP S6252694B2
- Authority
- JP
- Japan
- Prior art keywords
- resin
- vinyl monomer
- frp
- mold
- foamed
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229920005989 resin Polymers 0.000 claims description 41
- 239000011347 resin Substances 0.000 claims description 41
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 34
- 229920002554 vinyl polymer Polymers 0.000 claims description 34
- 239000000178 monomer Substances 0.000 claims description 30
- 239000006260 foam Substances 0.000 claims description 21
- 239000004793 Polystyrene Substances 0.000 claims description 20
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical group C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 20
- 229920002223 polystyrene Polymers 0.000 claims description 20
- 229920006337 unsaturated polyester resin Polymers 0.000 claims description 17
- 239000004698 Polyethylene Substances 0.000 claims description 15
- 229920000573 polyethylene Polymers 0.000 claims description 15
- 239000000835 fiber Substances 0.000 claims description 13
- 239000002245 particle Substances 0.000 claims description 13
- -1 polyethylene Polymers 0.000 claims description 12
- 229920000180 alkyd Polymers 0.000 claims description 11
- 239000011324 bead Substances 0.000 claims description 11
- 238000006116 polymerization reaction Methods 0.000 claims description 10
- 239000000805 composite resin Substances 0.000 claims description 7
- 238000004519 manufacturing process Methods 0.000 claims description 7
- 239000012736 aqueous medium Substances 0.000 claims description 6
- 239000000203 mixture Substances 0.000 claims description 3
- 238000010526 radical polymerization reaction Methods 0.000 description 48
- 239000010410 layer Substances 0.000 description 47
- 239000000047 product Substances 0.000 description 32
- 238000000034 method Methods 0.000 description 23
- 229920006327 polystyrene foam Polymers 0.000 description 20
- 239000000243 solution Substances 0.000 description 17
- 238000010097 foam moulding Methods 0.000 description 15
- 238000000465 moulding Methods 0.000 description 15
- 239000002131 composite material Substances 0.000 description 9
- 238000002347 injection Methods 0.000 description 9
- 239000007924 injection Substances 0.000 description 9
- 239000003365 glass fiber Substances 0.000 description 5
- 239000003505 polymerization initiator Substances 0.000 description 5
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 4
- 230000000694 effects Effects 0.000 description 3
- 229920006248 expandable polystyrene Polymers 0.000 description 3
- 238000001746 injection moulding Methods 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 230000002265 prevention Effects 0.000 description 3
- 239000003381 stabilizer Substances 0.000 description 3
- 239000000725 suspension Substances 0.000 description 3
- 230000008961 swelling Effects 0.000 description 3
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 2
- 239000004604 Blowing Agent Substances 0.000 description 2
- 239000007900 aqueous suspension Substances 0.000 description 2
- 238000004090 dissolution Methods 0.000 description 2
- 239000003822 epoxy resin Substances 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 238000009787 hand lay-up Methods 0.000 description 2
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 2
- 238000005470 impregnation Methods 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000035515 penetration Effects 0.000 description 2
- 229920000647 polyepoxide Polymers 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 150000007519 polyprotic acids Polymers 0.000 description 2
- 239000002243 precursor Substances 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- 238000010557 suspension polymerization reaction Methods 0.000 description 2
- 229920006305 unsaturated polyester Polymers 0.000 description 2
- 239000011800 void material Substances 0.000 description 2
- SBYMUDUGTIKLCR-UHFFFAOYSA-N 2-chloroethenylbenzene Chemical compound ClC=CC1=CC=CC=C1 SBYMUDUGTIKLCR-UHFFFAOYSA-N 0.000 description 1
- 239000004925 Acrylic resin Substances 0.000 description 1
- 229920000049 Carbon (fiber) Polymers 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000008065 acid anhydrides Chemical class 0.000 description 1
- 238000012644 addition polymerization Methods 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000004917 carbon fiber Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 150000001991 dicarboxylic acids Chemical class 0.000 description 1
- 125000003700 epoxy group Chemical group 0.000 description 1
- 239000011152 fibreglass Substances 0.000 description 1
- 239000002657 fibrous material Substances 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 210000000497 foam cell Anatomy 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 239000004088 foaming agent Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 230000000977 initiatory effect Effects 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- GEMHFKXPOCTAIP-UHFFFAOYSA-N n,n-dimethyl-n'-phenylcarbamimidoyl chloride Chemical compound CN(C)C(Cl)=NC1=CC=CC=C1 GEMHFKXPOCTAIP-UHFFFAOYSA-N 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- 239000012466 permeate Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 230000002028 premature Effects 0.000 description 1
- KCTAWXVAICEBSD-UHFFFAOYSA-N prop-2-enoyloxy prop-2-eneperoxoate Chemical compound C=CC(=O)OOOC(=O)C=C KCTAWXVAICEBSD-UHFFFAOYSA-N 0.000 description 1
- HJWLCRVIBGQPNF-UHFFFAOYSA-N prop-2-enylbenzene Chemical compound C=CCC1=CC=CC=C1 HJWLCRVIBGQPNF-UHFFFAOYSA-N 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 239000002356 single layer Substances 0.000 description 1
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 1
Landscapes
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
- Laminated Bodies (AREA)
- Casting Or Compression Moulding Of Plastics Or The Like (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP15634378A JPS5582612A (en) | 1978-12-20 | 1978-12-20 | Production of foam resin composite molded body |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP15634378A JPS5582612A (en) | 1978-12-20 | 1978-12-20 | Production of foam resin composite molded body |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS5582612A JPS5582612A (en) | 1980-06-21 |
| JPS6252694B2 true JPS6252694B2 (zh) | 1987-11-06 |
Family
ID=15625686
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP15634378A Granted JPS5582612A (en) | 1978-12-20 | 1978-12-20 | Production of foam resin composite molded body |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS5582612A (zh) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5952640A (ja) * | 1982-09-20 | 1984-03-27 | 三菱油化株式会社 | Ｆｒｐ／発泡樹脂複合成形体の製造方法 |
| JPH0725098B2 (ja) * | 1987-08-27 | 1995-03-22 | 難波プレス工業株式会社 | リム成形サンドイッチ構造物の製造方法 |
| JP2662038B2 (ja) * | 1989-07-14 | 1997-10-08 | 帝人株式会社 | 複合成形品の製造方法 |
| JP2731006B2 (ja) * | 1989-12-14 | 1998-03-25 | 帝人株式会社 | 複合成形品の製造法 |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS50145473A (zh) * | 1974-05-16 | 1975-11-21 | ||
| JPS5232972A (en) * | 1975-09-08 | 1977-03-12 | Badische Yuka Co Ltd | Process for producing expandable polystyrene particles |
| JPS54155265A (en) * | 1978-05-30 | 1979-12-07 | Mitsubishi Petrochem Co Ltd | Composite article made of foamed resin |
-
1978
- 1978-12-20 JP JP15634378A patent/JPS5582612A/ja active Granted
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS50145473A (zh) * | 1974-05-16 | 1975-11-21 | ||
| JPS5232972A (en) * | 1975-09-08 | 1977-03-12 | Badische Yuka Co Ltd | Process for producing expandable polystyrene particles |
| JPS54155265A (en) * | 1978-05-30 | 1979-12-07 | Mitsubishi Petrochem Co Ltd | Composite article made of foamed resin |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS5582612A (en) | 1980-06-21 |
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