JPS62500941A - 鉄―亜鉛合金被覆の電着方法及び該方法に使用する電解液 - Google Patents
鉄―亜鉛合金被覆の電着方法及び該方法に使用する電解液Info
- Publication number
- JPS62500941A JPS62500941A JP60503318A JP50331885A JPS62500941A JP S62500941 A JPS62500941 A JP S62500941A JP 60503318 A JP60503318 A JP 60503318A JP 50331885 A JP50331885 A JP 50331885A JP S62500941 A JPS62500941 A JP S62500941A
- Authority
- JP
- Japan
- Prior art keywords
- iron
- electrolyte
- current density
- electrodeposition
- polyethylene glycol
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000000576 coating method Methods 0.000 title claims description 32
- 239000003792 electrolyte Substances 0.000 title claims description 24
- 239000011248 coating agent Substances 0.000 title claims description 19
- 238000004070 electrodeposition Methods 0.000 title claims description 13
- 238000000034 method Methods 0.000 title claims description 12
- 229910001297 Zn alloy Inorganic materials 0.000 title description 9
- KFZAUHNPPZCSCR-UHFFFAOYSA-N iron zinc Chemical compound [Fe].[Zn] KFZAUHNPPZCSCR-UHFFFAOYSA-N 0.000 title description 6
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 36
- 229910052742 iron Inorganic materials 0.000 claims description 20
- 239000011701 zinc Substances 0.000 claims description 14
- 229910052725 zinc Inorganic materials 0.000 claims description 11
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 10
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 9
- 239000002202 Polyethylene glycol Substances 0.000 claims description 6
- 239000002738 chelating agent Substances 0.000 claims description 6
- 229920001223 polyethylene glycol Polymers 0.000 claims description 6
- 229910000831 Steel Inorganic materials 0.000 claims description 5
- 239000008151 electrolyte solution Substances 0.000 claims description 5
- 229920001515 polyalkylene glycol Polymers 0.000 claims description 5
- 239000010959 steel Substances 0.000 claims description 5
- KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical group [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 claims description 4
- 230000015572 biosynthetic process Effects 0.000 claims description 3
- 238000010992 reflux Methods 0.000 claims description 3
- -1 iron ion Chemical class 0.000 claims description 2
- 229920001281 polyalkylene Polymers 0.000 claims description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims 2
- 239000000956 alloy Substances 0.000 claims 2
- 229910045601 alloy Inorganic materials 0.000 claims 2
- 239000002244 precipitate Substances 0.000 claims 2
- 239000000463 material Substances 0.000 claims 1
- 238000007747 plating Methods 0.000 description 11
- 238000009713 electroplating Methods 0.000 description 5
- 230000007797 corrosion Effects 0.000 description 4
- 238000005260 corrosion Methods 0.000 description 4
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 230000007423 decrease Effects 0.000 description 3
- 238000009533 lab test Methods 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 2
- 230000002159 abnormal effect Effects 0.000 description 2
- 230000003278 mimic effect Effects 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- 241000282994 Cervidae Species 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- 229910000640 Fe alloy Inorganic materials 0.000 description 1
- 101000941926 Saccharomyces cerevisiae (strain ATCC 204508 / S288c) Carboxypeptidase Y inhibitor Proteins 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- GXUPZLPBJDKHFI-UHFFFAOYSA-J [Cl-].[Cl-].[Cl-].[Cl-].[Fe++].[Zn++] Chemical compound [Cl-].[Cl-].[Cl-].[Cl-].[Fe++].[Zn++] GXUPZLPBJDKHFI-UHFFFAOYSA-J 0.000 description 1
- 230000005856 abnormality Effects 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 230000002547 anomalous effect Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 150000003841 chloride salts Chemical class 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000013013 elastic material Substances 0.000 description 1
- 239000002659 electrodeposit Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- JQJCSZOEVBFDKO-UHFFFAOYSA-N lead zinc Chemical compound [Zn].[Pb] JQJCSZOEVBFDKO-UHFFFAOYSA-N 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 229910001510 metal chloride Inorganic materials 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 239000010970 precious metal Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-L succinate(2-) Chemical compound [O-]C(=O)CCC([O-])=O KDYFGRWQOYBRFD-UHFFFAOYSA-L 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
- 239000011135 tin Substances 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D3/00—Electroplating: Baths therefor
- C25D3/02—Electroplating: Baths therefor from solutions
- C25D3/56—Electroplating: Baths therefor from solutions of alloys
- C25D3/565—Electroplating: Baths therefor from solutions of alloys containing more than 50% by weight of zinc
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Electroplating And Plating Baths Therefor (AREA)
- Electroplating Methods And Accessories (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US06/677,423 US4540472A (en) | 1984-12-03 | 1984-12-03 | Method for the electrodeposition of an iron-zinc alloy coating and bath therefor |
| US677423 | 2003-10-02 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS62500941A true JPS62500941A (ja) | 1987-04-16 |
| JPH0585640B2 JPH0585640B2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1993-12-08 |
Family
ID=24718644
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP60503318A Granted JPS62500941A (ja) | 1984-12-03 | 1985-07-24 | 鉄―亜鉛合金被覆の電着方法及び該方法に使用する電解液 |
Country Status (9)
Families Citing this family (29)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3619385A1 (de) * | 1986-06-09 | 1987-12-10 | Elektro Brite Gmbh | Saures sulfathaltiges bad fuer die galvanische abscheidung von zn-fe-legierungen |
| DE3619384A1 (de) * | 1986-06-09 | 1987-12-10 | Elektro Brite Gmbh | Saures chloridhaltiges bad fuer die galvanische abscheidung von zn-fe-legierungen |
| GB2212816B (en) * | 1987-11-26 | 1992-04-08 | Nippon Steel Corp | Zn-ni based composite electroplated material and multi-layer composite plated material |
| US5316653A (en) * | 1992-07-30 | 1994-05-31 | Usx Corporation | Minimization of mounds in iron-zinc electrogalvanized sheet |
| US5628044A (en) * | 1995-06-02 | 1997-05-06 | Old Dominion University | Pure iron-zinc intermetallic galvanneal calibration standards |
| US6096183A (en) * | 1997-12-05 | 2000-08-01 | Ak Steel Corporation | Method of reducing defects caused by conductor roll surface anomalies using high volume bottom sprays |
| US6143160A (en) * | 1998-09-18 | 2000-11-07 | Pavco, Inc. | Method for improving the macro throwing power for chloride zinc electroplating baths |
| CN1300382C (zh) * | 2004-04-12 | 2007-02-14 | 昆明理工大学 | Zn－Fe－RE镀层钢铁零部件及电镀方法与电解液 |
| CA2619509C (en) | 2005-08-12 | 2015-01-06 | Modumetal, Llc. | Compositionally modulated composite materials and methods for making the same |
| BR122013014464B1 (pt) | 2009-06-08 | 2020-10-20 | Modumetal, Inc | revestimento de multicamadas resistente à corrosão em um substrato e método de eletrodepósito para produção de um revestimento |
| JP5591256B2 (ja) * | 2009-11-18 | 2014-09-17 | Ｊｘ日鉱日石金属株式会社 | 二価鉄イオン含有水溶液 |
| JP5492221B2 (ja) * | 2009-11-26 | 2014-05-14 | パナソニック株式会社 | アルミニウム電解コンデンサ用電解液、およびそれを用いたアルミニウム電解コンデンサ |
| EP2489763A1 (en) * | 2011-02-15 | 2012-08-22 | Atotech Deutschland GmbH | Zinc-iron alloy layer material |
| CN102337567B (zh) * | 2011-11-02 | 2013-12-11 | 西南交通大学 | 有层次结构的纳米铁立方体和纳米铁花状结构的制备方法 |
| DE102012110972B3 (de) * | 2012-11-14 | 2014-03-06 | Muhr Und Bender Kg | Verfahren zum Herstellen eines Erzeugnisses aus flexibel gewalztem Bandmaterial und Erzeugnis aus flexibel gewalztem Bandmaterial |
| BR112015022020A8 (pt) | 2013-03-15 | 2019-12-10 | Modumetal Inc | objeto ou revestimento e seu processo de fabricação |
| HK1220744A1 (zh) | 2013-03-15 | 2017-05-12 | Modumetal, Inc. | 用於通过添加制造工艺制备之制品的电沉积的组合物和纳米层压合金 |
| US10472727B2 (en) | 2013-03-15 | 2019-11-12 | Modumetal, Inc. | Method and apparatus for continuously applying nanolaminate metal coatings |
| BR112015022235A2 (pt) | 2013-03-15 | 2017-07-18 | Modumetal Inc | revestimentos nanolaminados |
| CN105143521B (zh) | 2013-03-15 | 2020-07-10 | 莫杜美拓有限公司 | 用于连续施加纳米叠层金属涂层的方法和装置 |
| CN106795645B (zh) | 2014-09-18 | 2020-03-27 | 莫杜美拓有限公司 | 用于连续施加纳米层压金属涂层的方法和装置 |
| EA201790644A1 (ru) | 2014-09-18 | 2017-08-31 | Модьюметал, Инк. | Способы изготовления изделий электроосаждением и процессами послойного синтеза |
| US11365488B2 (en) | 2016-09-08 | 2022-06-21 | Modumetal, Inc. | Processes for providing laminated coatings on workpieces, and articles made therefrom |
| TW201821649A (zh) | 2016-09-09 | 2018-06-16 | 美商馬杜合金股份有限公司 | 層合物與奈米層合物材料於工具及模製方法之應用 |
| US20190360116A1 (en) | 2016-09-14 | 2019-11-28 | Modumetal, Inc. | System for reliable, high throughput, complex electric field generation, and method for producing coatings therefrom |
| CN110114210B (zh) | 2016-11-02 | 2022-03-04 | 莫杜美拓有限公司 | 拓扑优化的高界面填充结构 |
| CN110637107B (zh) | 2017-03-24 | 2022-08-19 | 莫杜美拓有限公司 | 具有电镀层的升降柱塞以及用于生产其的系统和方法 |
| CN110770372B (zh) | 2017-04-21 | 2022-10-11 | 莫杜美拓有限公司 | 具有电沉积涂层的管状制品及其生产系统和方法 |
| US11519093B2 (en) | 2018-04-27 | 2022-12-06 | Modumetal, Inc. | Apparatuses, systems, and methods for producing a plurality of articles with nanolaminated coatings using rotation |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2778787A (en) * | 1954-03-15 | 1957-01-22 | British Iron Steel Research | Electrodeposition of iron zinc alloys |
| JPS569386A (en) * | 1979-07-02 | 1981-01-30 | Nippon Kokan Kk <Nkk> | Production of electro-zinc plated steel plate |
| JPS5751283A (en) * | 1980-09-12 | 1982-03-26 | Nippon Steel Corp | Electroplating method for zinc-iron alloy |
| US4488942A (en) * | 1983-08-05 | 1984-12-18 | Omi International Corporation | Zinc and zinc alloy electroplating bath and process |
-
1984
- 1984-12-03 US US06/677,423 patent/US4540472A/en not_active Expired - Lifetime
-
1985
- 1985-07-24 JP JP60503318A patent/JPS62500941A/ja active Granted
- 1985-07-24 EP EP85903781A patent/EP0204708B1/en not_active Expired - Lifetime
- 1985-07-24 WO PCT/US1985/001413 patent/WO1986003522A1/en active IP Right Grant
- 1985-07-24 DE DE8585903781T patent/DE3580358D1/de not_active Expired - Lifetime
- 1985-08-05 ZA ZA855908A patent/ZA855908B/xx unknown
- 1985-08-20 CA CA000489078A patent/CA1254168A/en not_active Expired
- 1985-08-23 ES ES546397A patent/ES8606914A1/es not_active Expired
- 1985-08-30 CN CN85106516.3A patent/CN1004972B/zh not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| ES8606914A1 (es) | 1986-05-01 |
| DE3580358D1 (de) | 1990-12-06 |
| ES546397A0 (es) | 1986-05-01 |
| CN85106516A (zh) | 1986-05-10 |
| CA1254168A (en) | 1989-05-16 |
| EP0204708B1 (en) | 1990-10-31 |
| EP0204708A1 (en) | 1986-12-17 |
| US4540472A (en) | 1985-09-10 |
| ZA855908B (en) | 1986-03-26 |
| JPH0585640B2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1993-12-08 |
| CN1004972B (zh) | 1989-08-09 |
| WO1986003522A1 (en) | 1986-06-19 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| LAPS | Cancellation because of no payment of annual fees |