JPS6236022A - 新規セリウム(4)化合物およびその製造方法 - Google Patents
新規セリウム(4)化合物およびその製造方法Info
- Publication number
- JPS6236022A JPS6236022A JP61141539A JP14153986A JPS6236022A JP S6236022 A JPS6236022 A JP S6236022A JP 61141539 A JP61141539 A JP 61141539A JP 14153986 A JP14153986 A JP 14153986A JP S6236022 A JPS6236022 A JP S6236022A
- Authority
- JP
- Japan
- Prior art keywords
- cerium
- manufacturing
- compound
- sol
- aqueous
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000004519 manufacturing process Methods 0.000 title claims description 28
- -1 cerium (iv) compound Chemical class 0.000 title claims description 16
- 229910052684 Cerium Inorganic materials 0.000 claims abstract description 49
- GWXLDORMOJMVQZ-UHFFFAOYSA-N cerium Chemical compound [Ce] GWXLDORMOJMVQZ-UHFFFAOYSA-N 0.000 claims abstract description 49
- 229910052783 alkali metal Inorganic materials 0.000 claims abstract description 3
- 150000001340 alkali metals Chemical class 0.000 claims abstract description 3
- ITZXULOAYIAYNU-UHFFFAOYSA-N cerium(4+) Chemical class [Ce+4] ITZXULOAYIAYNU-UHFFFAOYSA-N 0.000 claims description 33
- 239000000084 colloidal system Substances 0.000 claims description 32
- 239000000243 solution Substances 0.000 claims description 29
- 239000006185 dispersion Substances 0.000 claims description 26
- 238000006386 neutralization reaction Methods 0.000 claims description 22
- 239000007864 aqueous solution Substances 0.000 claims description 19
- 239000002585 base Substances 0.000 claims description 19
- 238000001246 colloidal dispersion Methods 0.000 claims description 19
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 claims description 15
- 238000000034 method Methods 0.000 claims description 15
- 238000010438 heat treatment Methods 0.000 claims description 14
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 14
- 239000012266 salt solution Substances 0.000 claims description 12
- 239000002244 precipitate Substances 0.000 claims description 10
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 9
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims description 7
- 238000003756 stirring Methods 0.000 claims description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 4
- 239000012736 aqueous medium Substances 0.000 claims description 4
- HSJPMRKMPBAUAU-UHFFFAOYSA-N cerium(3+);trinitrate Chemical compound [Ce+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O HSJPMRKMPBAUAU-UHFFFAOYSA-N 0.000 claims description 4
- 238000004455 differential thermal analysis Methods 0.000 claims description 4
- 238000009826 distribution Methods 0.000 claims description 4
- XMPZTFVPEKAKFH-UHFFFAOYSA-P ceric ammonium nitrate Chemical compound [NH4+].[NH4+].[Ce+4].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O XMPZTFVPEKAKFH-UHFFFAOYSA-P 0.000 claims description 3
- 238000006243 chemical reaction Methods 0.000 claims description 3
- 238000000926 separation method Methods 0.000 claims description 3
- 229910021529 ammonia Inorganic materials 0.000 claims description 2
- 125000001453 quaternary ammonium group Chemical group 0.000 claims description 2
- 238000001035 drying Methods 0.000 claims 2
- 230000003247 decreasing effect Effects 0.000 claims 1
- 239000007787 solid Substances 0.000 claims 1
- 150000001875 compounds Chemical class 0.000 abstract description 24
- 239000000047 product Substances 0.000 description 19
- 150000001785 cerium compounds Chemical class 0.000 description 13
- 238000009792 diffusion process Methods 0.000 description 13
- 150000000703 Cerium Chemical class 0.000 description 12
- 229910002651 NO3 Inorganic materials 0.000 description 12
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 12
- 235000011114 ammonium hydroxide Nutrition 0.000 description 12
- 239000000126 substance Substances 0.000 description 11
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonium chloride Substances [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 10
- CETPSERCERDGAM-UHFFFAOYSA-N ceric oxide Chemical compound O=[Ce]=O CETPSERCERDGAM-UHFFFAOYSA-N 0.000 description 8
- 229910000422 cerium(IV) oxide Inorganic materials 0.000 description 7
- 239000000203 mixture Substances 0.000 description 6
- 238000012360 testing method Methods 0.000 description 6
- 238000004458 analytical method Methods 0.000 description 5
- 239000012153 distilled water Substances 0.000 description 5
- 239000002245 particle Substances 0.000 description 5
- 230000000875 corresponding effect Effects 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- 150000003839 salts Chemical class 0.000 description 4
- 238000002441 X-ray diffraction Methods 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 238000010908 decantation Methods 0.000 description 3
- 239000000376 reactant Substances 0.000 description 3
- 238000003860 storage Methods 0.000 description 3
- 238000004448 titration Methods 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 2
- 238000007605 air drying Methods 0.000 description 2
- 150000001450 anions Chemical class 0.000 description 2
- QIICBUVIQUVXPN-UHFFFAOYSA-N cerium(4+);oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[Ce+4] QIICBUVIQUVXPN-UHFFFAOYSA-N 0.000 description 2
- 238000006253 efflorescence Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 229910017604 nitric acid Inorganic materials 0.000 description 2
- 238000001556 precipitation Methods 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 239000006228 supernatant Substances 0.000 description 2
- 238000005199 ultracentrifugation Methods 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 1
- 241000894006 Bacteria Species 0.000 description 1
- 229910004664 Cerium(III) chloride Inorganic materials 0.000 description 1
- VTLYFUHAOXGGBS-UHFFFAOYSA-N Fe3+ Chemical compound [Fe+3] VTLYFUHAOXGGBS-UHFFFAOYSA-N 0.000 description 1
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 1
- GCIFFQSMYPWPSG-UHFFFAOYSA-L O.[Ce+2].CC([O-])=O.CC([O-])=O Chemical compound O.[Ce+2].CC([O-])=O.CC([O-])=O GCIFFQSMYPWPSG-UHFFFAOYSA-L 0.000 description 1
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 150000001447 alkali salts Chemical class 0.000 description 1
- 239000000908 ammonium hydroxide Substances 0.000 description 1
- 239000003637 basic solution Substances 0.000 description 1
- 238000001354 calcination Methods 0.000 description 1
- 238000005119 centrifugation Methods 0.000 description 1
- 229910000420 cerium oxide Inorganic materials 0.000 description 1
- VYLVYHXQOHJDJL-UHFFFAOYSA-K cerium trichloride Chemical compound Cl[Ce](Cl)Cl VYLVYHXQOHJDJL-UHFFFAOYSA-K 0.000 description 1
- XQTIWNLDFPPCIU-UHFFFAOYSA-N cerium(3+) Chemical compound [Ce+3] XQTIWNLDFPPCIU-UHFFFAOYSA-N 0.000 description 1
- GHLITDDQOMIBFS-UHFFFAOYSA-H cerium(3+);tricarbonate Chemical compound [Ce+3].[Ce+3].[O-]C([O-])=O.[O-]C([O-])=O.[O-]C([O-])=O GHLITDDQOMIBFS-UHFFFAOYSA-H 0.000 description 1
- DPUCLPLBKVSJIB-UHFFFAOYSA-N cerium;tetrahydrate Chemical compound O.O.O.O.[Ce] DPUCLPLBKVSJIB-UHFFFAOYSA-N 0.000 description 1
- 230000001112 coagulating effect Effects 0.000 description 1
- 230000000536 complexating effect Effects 0.000 description 1
- 230000002596 correlated effect Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 229910001873 dinitrogen Inorganic materials 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000002609 medium Substances 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 238000011017 operating method Methods 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- BMMGVYCKOGBVEV-UHFFFAOYSA-N oxo(oxoceriooxy)cerium Chemical compound [Ce]=O.O=[Ce]=O BMMGVYCKOGBVEV-UHFFFAOYSA-N 0.000 description 1
- 229940072033 potash Drugs 0.000 description 1
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Substances [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 1
- 235000015320 potassium carbonate Nutrition 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 230000004580 weight loss Effects 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
- C01F17/00—Compounds of rare earth metals
- C01F17/20—Compounds containing only rare earth metals as the metal element
- C01F17/206—Compounds containing only rare earth metals as the metal element oxide or hydroxide being the only anion
- C01F17/224—Oxides or hydroxides of lanthanides
- C01F17/235—Cerium oxides or hydroxides
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
- C01F17/00—Compounds of rare earth metals
- C01F17/30—Compounds containing rare earth metals and at least one element other than a rare earth metal, oxygen or hydrogen, e.g. La4S3Br6
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2002/00—Crystal-structural characteristics
- C01P2002/60—Compounds characterised by their crystallite size
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2002/00—Crystal-structural characteristics
- C01P2002/80—Crystal-structural characteristics defined by measured data other than those specified in group C01P2002/70
- C01P2002/88—Crystal-structural characteristics defined by measured data other than those specified in group C01P2002/70 by thermal analysis data, e.g. TGA, DTA, DSC
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/60—Particles characterised by their size
- C01P2004/64—Nanometer sized, i.e. from 1-100 nanometer
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S516/00—Colloid systems and wetting agents; subcombinations thereof; processes of
- Y10S516/922—Colloid systems having specified particle size, range, or distribution, e.g. bimodal particle distribution
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S516/00—Colloid systems and wetting agents; subcombinations thereof; processes of
- Y10S516/924—Significant dispersive or manipulative operation or step in making or stabilizing colloid system
- Y10S516/928—Mixing combined with non-mixing operation or step, successively or simultaneously, e.g. heating, cooling, ph change, ageing, milling
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Nanotechnology (AREA)
- Inorganic Chemistry (AREA)
- Geology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Physics & Mathematics (AREA)
- Composite Materials (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- General Physics & Mathematics (AREA)
- Materials Engineering (AREA)
- Crystallography & Structural Chemistry (AREA)
- Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
- Catalysts (AREA)
- Colloid Chemistry (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR8509374 | 1985-06-20 | ||
FR8509374A FR2583736B1 (fr) | 1985-06-20 | 1985-06-20 | Nouveau compose de cerium iv et son procede de preparation. |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS6236022A true JPS6236022A (ja) | 1987-02-17 |
JPH0519488B2 JPH0519488B2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1993-03-16 |
Family
ID=9320465
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP61141539A Granted JPS6236022A (ja) | 1985-06-20 | 1986-06-19 | 新規セリウム(4)化合物およびその製造方法 |
Country Status (7)
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH01148710A (ja) * | 1987-12-02 | 1989-06-12 | Taki Chem Co Ltd | 結晶質酸化第二セリウムゾルの製造法 |
Families Citing this family (30)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2583735B1 (fr) * | 1985-06-20 | 1990-11-23 | Rhone Poulenc Spec Chim | Nouvelles dispersions colloidales d'un compose de cerium iv en milieu aqueux et leur procede d'obtention. |
FR2596381B1 (fr) * | 1986-03-26 | 1988-05-27 | Rhone Poulenc Chimie | Oxydes ceriques a nouvelles caracteristiques morphologiques et leur procede d'obtention |
FR2596382B1 (fr) * | 1986-03-26 | 1988-05-27 | Rhone Poulenc Chimie | Dispersions aqueuses colloidales d'un compose de cerium iv et leur procede d'obtention |
FR2632945B1 (fr) * | 1988-06-15 | 1991-02-08 | Rhone Poulenc Chimie | Procede d'obtention d'un oxyde cerique de grande surface specifique |
FR2617154B1 (fr) * | 1987-06-29 | 1990-11-30 | Rhone Poulenc Chimie | Procede d'obtention d'oxyde cerique et oxyde cerique a nouvelles caracteristiques morphologiques |
ES2024666B3 (es) * | 1987-06-29 | 1992-03-01 | Rhone-Poulenc Chimie | Procedimiento para la obtencion de un oxido cerico. |
FR2640954B1 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) * | 1988-12-23 | 1991-03-29 | Rhone Poulenc Chimie | |
FR2640953B1 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) * | 1988-12-23 | 1991-02-08 | Rhone Poulenc Chimie | |
US5279789A (en) * | 1988-12-23 | 1994-01-18 | Rhone-Poulenc Chimie | Ceric oxide particulates having improved morphology |
FR2724331B1 (fr) | 1994-09-12 | 1996-12-13 | Rhone Poulenc Chimie | Dispersions colloidales d'un compose de cerium a ph eleve et leurs procedes de preparation |
EP1285956A4 (en) * | 2000-05-16 | 2004-09-29 | Mitsui Mining & Smelting Co | CERIUM BASED ABRASIVE, RAW MATERIAL AND MANUFACTURING PROCESS |
FR2831177B1 (fr) | 2001-10-22 | 2005-02-18 | Rhodia Elect & Catalysis | Dispersion colloidale et poudre colorees de cerium ou de cerium et de titane, de zirconium, d'aluminium ou d'une terre rare, leur procede de preparation et leur utilisation |
FR2840313B1 (fr) | 2002-05-28 | 2004-08-27 | Rhodia Elect & Catalysis | Composition a base d'une peinture aqueuse, notamment d'une lasure ou d'un vernis, et d'une dispersion colloidale aqueuse de cerium |
EP1858989B1 (fr) | 2005-01-07 | 2015-12-09 | Rhodia Chimie | Compositions de peintures aqueuses comprenant une dispersion colloïdale de cerium |
WO2006105322A2 (en) * | 2005-03-31 | 2006-10-05 | Rhodia Inc. | Mineral particle dispersions stabilized with a poly (oxyalkene) phosphonate |
WO2008008354A2 (en) * | 2006-07-11 | 2008-01-17 | Rhodia Inc. | Aqueous dispersions of hybrid coacervates delivering specific properties onto solid surfaces and comprising inorganic solid particles and a copolymer |
US10435639B2 (en) | 2006-09-05 | 2019-10-08 | Cerion, Llc | Fuel additive containing lattice engineered cerium dioxide nanoparticles |
US8883865B2 (en) | 2006-09-05 | 2014-11-11 | Cerion Technology, Inc. | Cerium-containing nanoparticles |
WO2008030813A1 (en) | 2006-09-05 | 2008-03-13 | Cerion Technology, Inc. | Method of conditioning an internal combustion engine |
EP2288449B1 (en) * | 2008-05-09 | 2020-09-02 | Rhodia Opérations | Hybrid nanoscale particles |
US8679344B2 (en) | 2008-12-17 | 2014-03-25 | Cerion Technology, Inc. | Process for solvent shifting a nanoparticle dispersion |
US8617502B2 (en) | 2011-02-07 | 2013-12-31 | Cristal Usa Inc. | Ce containing, V-free mobile denox catalyst |
US20150129796A1 (en) * | 2012-05-22 | 2015-05-14 | Hitachi Chemical Company, Ltd. | Abrasive grains, slurry, polishing solution, and manufacturing methods therefor |
SG11201407084QA (en) * | 2012-05-22 | 2014-12-30 | Hitachi Chemical Co Ltd | Abrasive particles, slurry, polishing solution, and manufacturing methods therefor |
US10143661B2 (en) | 2013-10-17 | 2018-12-04 | Cerion, Llc | Malic acid stabilized nanoceria particles |
FR3047737A1 (fr) * | 2016-02-17 | 2017-08-18 | Rhodia Operations | Composition fluide pour proteger le bois |
FR3047736A1 (fr) * | 2016-02-17 | 2017-08-18 | Rhodia Operations | Composition de peinture formulee en phase aqueuse |
WO2018100324A1 (fr) | 2016-12-02 | 2018-06-07 | Rhodia Operations | Suspension d'oxyde de cerium |
KR20210084570A (ko) * | 2018-11-02 | 2021-07-07 | 로디아 오퍼레이션스 | 이트륨, 세륨 및 유기 화합물에 기초한 조성물, 및 이의 스탑-오프 용도 |
WO2023242394A1 (en) | 2022-06-17 | 2023-12-21 | Rhodia Operations | Suspension of cerium oxide particles |
Family Cites Families (19)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2364613A (en) * | 1942-02-05 | 1944-12-12 | Eastman Kodak Co | Purification of lanthanum salts |
US3024199A (en) * | 1958-09-02 | 1962-03-06 | Du Pont | Stable aquasols of hydrous rare earth oxides and their preparation |
US3148151A (en) * | 1962-02-22 | 1964-09-08 | Grace W R & Co | Method of preparing rare earthactinide metal oxide sols |
US3359213A (en) * | 1963-01-31 | 1967-12-19 | Nat Lead Co | Production of aqueous suspension of colloidal, crystalline, hydrous oxides of zirconium and hafnium |
US3442817A (en) * | 1966-04-15 | 1969-05-06 | Du Pont | Preparation of zirconia and hafnia sols |
GB1181794A (en) * | 1966-06-09 | 1970-02-18 | Atomic Energy Authority Uk | Improvements in or relating to Zirconium Compounds |
US3761571A (en) * | 1970-02-10 | 1973-09-25 | Atomic Energy Authority Uk | Production of ceria |
JPS53112299A (en) * | 1977-03-02 | 1978-09-30 | Sumitomo Alum Smelt Co Ltd | Production of alumina sol |
DE2857146T1 (de) * | 1977-11-01 | 1980-12-04 | Atomic Energy Authority Uk | Production of dispersions |
US4244835A (en) * | 1978-12-14 | 1981-01-13 | W. R. Grace & Co. | Method of dispersing alpha alumina monohydrate |
US4356106A (en) * | 1980-05-09 | 1982-10-26 | United Kingdom Atomic Energy Authority | Cerium compounds |
GB2075478B (en) * | 1980-05-09 | 1983-10-12 | Atomic Energy Authority Uk | Improvements in or relating to cerium compounds |
DE3271142D1 (en) * | 1981-08-07 | 1986-06-19 | Atomic Energy Authority Uk | Cerium compounds |
GB2102780B (en) * | 1981-08-07 | 1985-04-03 | Atomic Energy Authority Uk | Improvements in or relating to compounds |
US4545923A (en) * | 1982-06-11 | 1985-10-08 | Rhone-Poulenc Inc. | Process for preparing colloidal ceric oxide and complexes thereof with free organic acids |
DE3378530D1 (en) * | 1982-08-13 | 1988-12-29 | Atomic Energy Authority Uk | Process for the preparation of dispersions and gels |
FR2559754A1 (fr) * | 1984-02-20 | 1985-08-23 | Rhone Poulenc Spec Chim | Oxyde cerique a nouvelles caracteristiques morphologiques et son procede d'obtention |
GB8430244D0 (en) * | 1984-11-30 | 1985-01-09 | Atomic Energy Authority Uk | Preparation of materials |
FR2583735B1 (fr) * | 1985-06-20 | 1990-11-23 | Rhone Poulenc Spec Chim | Nouvelles dispersions colloidales d'un compose de cerium iv en milieu aqueux et leur procede d'obtention. |
-
1985
- 1985-06-20 FR FR8509374A patent/FR2583736B1/fr not_active Expired
-
1986
- 1986-06-11 EP EP86401272A patent/EP0208580B1/fr not_active Expired - Lifetime
- 1986-06-11 AT AT86401272T patent/ATE49582T1/de active
- 1986-06-11 DE DE8686401272T patent/DE3668315D1/de not_active Expired - Fee Related
- 1986-06-19 JP JP61141539A patent/JPS6236022A/ja active Granted
- 1986-06-19 AU AU59000/86A patent/AU578368B2/en not_active Ceased
-
1991
- 1991-08-21 US US07/750,750 patent/US5344588A/en not_active Expired - Fee Related
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH01148710A (ja) * | 1987-12-02 | 1989-06-12 | Taki Chem Co Ltd | 結晶質酸化第二セリウムゾルの製造法 |
Also Published As
Publication number | Publication date |
---|---|
FR2583736B1 (fr) | 1987-08-14 |
JPH0519488B2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1993-03-16 |
US5344588A (en) | 1994-09-06 |
EP0208580A1 (fr) | 1987-01-14 |
AU5900086A (en) | 1986-12-24 |
FR2583736A1 (fr) | 1986-12-26 |
EP0208580B1 (fr) | 1990-01-17 |
ATE49582T1 (de) | 1990-02-15 |
AU578368B2 (en) | 1988-10-20 |
DE3668315D1 (de) | 1990-02-22 |
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