JPS6226332B2 - - Google Patents
Info
- Publication number
- JPS6226332B2 JPS6226332B2 JP12290378A JP12290378A JPS6226332B2 JP S6226332 B2 JPS6226332 B2 JP S6226332B2 JP 12290378 A JP12290378 A JP 12290378A JP 12290378 A JP12290378 A JP 12290378A JP S6226332 B2 JPS6226332 B2 JP S6226332B2
- Authority
- JP
- Japan
- Prior art keywords
- parts
- exchange group
- ion exchange
- vinyl
- fibers
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000835 fiber Substances 0.000 claims description 21
- 125000003700 epoxy group Chemical group 0.000 claims description 16
- 238000005342 ion exchange Methods 0.000 claims description 14
- 238000004519 manufacturing process Methods 0.000 claims description 13
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 9
- 229920001577 copolymer Polymers 0.000 claims description 9
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 9
- 229920002554 vinyl polymer Polymers 0.000 claims description 9
- 239000000178 monomer Substances 0.000 claims description 8
- 239000011550 stock solution Substances 0.000 claims description 7
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims description 6
- 238000005349 anion exchange Methods 0.000 claims description 6
- 238000005341 cation exchange Methods 0.000 claims description 6
- 239000003960 organic solvent Substances 0.000 claims description 5
- 238000009987 spinning Methods 0.000 claims description 5
- LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical compound OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 claims description 3
- 150000001412 amines Chemical class 0.000 claims description 3
- 239000007864 aqueous solution Substances 0.000 claims description 3
- 239000000243 solution Substances 0.000 claims description 3
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 claims description 2
- 150000001768 cations Chemical class 0.000 claims description 2
- 229920001519 homopolymer Polymers 0.000 claims description 2
- 239000000203 mixture Substances 0.000 claims description 2
- 229940079826 hydrogen sulfite Drugs 0.000 claims 1
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 9
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 8
- 229920000642 polymer Polymers 0.000 description 7
- 238000006243 chemical reaction Methods 0.000 description 6
- 229920002994 synthetic fiber Polymers 0.000 description 6
- 239000012209 synthetic fiber Substances 0.000 description 6
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 4
- 229920000058 polyacrylate Polymers 0.000 description 4
- 230000009257 reactivity Effects 0.000 description 4
- WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 description 3
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 3
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 3
- -1 amine salts Chemical class 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 239000004745 nonwoven fabric Substances 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 description 2
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 2
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 2
- WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical compound C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 description 2
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 2
- 150000001450 anions Chemical class 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- 238000010828 elution Methods 0.000 description 2
- 238000010528 free radical solution polymerization reaction Methods 0.000 description 2
- VOZRXNHHFUQHIL-UHFFFAOYSA-N glycidyl methacrylate Chemical compound CC(=C)C(=O)OCC1CO1 VOZRXNHHFUQHIL-UHFFFAOYSA-N 0.000 description 2
- 230000007935 neutral effect Effects 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- 230000008961 swelling Effects 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- 239000002759 woven fabric Substances 0.000 description 2
- BXALRZFQYDYTGH-UHFFFAOYSA-N 1-oxoprop-2-ene-1-sulfonic acid Chemical class OS(=O)(=O)C(=O)C=C BXALRZFQYDYTGH-UHFFFAOYSA-N 0.000 description 1
- SXZSFWHOSHAKMN-UHFFFAOYSA-N 2,3,4,4',5-Pentachlorobiphenyl Chemical compound C1=CC(Cl)=CC=C1C1=CC(Cl)=C(Cl)C(Cl)=C1Cl SXZSFWHOSHAKMN-UHFFFAOYSA-N 0.000 description 1
- STMDPCBYJCIZOD-UHFFFAOYSA-N 2-(2,4-dinitroanilino)-4-methylpentanoic acid Chemical compound CC(C)CC(C(O)=O)NC1=CC=C([N+]([O-])=O)C=C1[N+]([O-])=O STMDPCBYJCIZOD-UHFFFAOYSA-N 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- LQZDDWKUQKQXGC-UHFFFAOYSA-N 2-(2-methylprop-2-enoxymethyl)oxirane Chemical compound CC(=C)COCC1CO1 LQZDDWKUQKQXGC-UHFFFAOYSA-N 0.000 description 1
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 description 1
- ZNQVEEAIQZEUHB-UHFFFAOYSA-N 2-ethoxyethanol Chemical compound CCOCCO ZNQVEEAIQZEUHB-UHFFFAOYSA-N 0.000 description 1
- XEEYSDHEOQHCDA-UHFFFAOYSA-N 2-methylprop-2-ene-1-sulfonic acid Chemical class CC(=C)CS(O)(=O)=O XEEYSDHEOQHCDA-UHFFFAOYSA-N 0.000 description 1
- KGIGUEBEKRSTEW-UHFFFAOYSA-N 2-vinylpyridine Chemical compound C=CC1=CC=CC=N1 KGIGUEBEKRSTEW-UHFFFAOYSA-N 0.000 description 1
- KFNGWPXYNSJXOP-UHFFFAOYSA-N 3-(2-methylprop-2-enoyloxy)propane-1-sulfonic acid Chemical class CC(=C)C(=O)OCCCS(O)(=O)=O KFNGWPXYNSJXOP-UHFFFAOYSA-N 0.000 description 1
- WGXMUJRZZXSPTF-UHFFFAOYSA-N 4-(2-methylprop-2-enoyloxy)benzenesulfonic acid Chemical class CC(=C)C(=O)OC1=CC=C(S(O)(=O)=O)C=C1 WGXMUJRZZXSPTF-UHFFFAOYSA-N 0.000 description 1
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
- DWAQJAXMDSEUJJ-UHFFFAOYSA-M Sodium bisulfite Chemical compound [Na+].OS([O-])=O DWAQJAXMDSEUJJ-UHFFFAOYSA-M 0.000 description 1
- INLLPKCGLOXCIV-UHFFFAOYSA-N bromoethene Chemical compound BrC=C INLLPKCGLOXCIV-UHFFFAOYSA-N 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 230000015271 coagulation Effects 0.000 description 1
- 238000005345 coagulation Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- HPNMFZURTQLUMO-UHFFFAOYSA-N diethylamine Chemical compound CCNCC HPNMFZURTQLUMO-UHFFFAOYSA-N 0.000 description 1
- 238000007720 emulsion polymerization reaction Methods 0.000 description 1
- 239000003456 ion exchange resin Substances 0.000 description 1
- 229920003303 ion-exchange polymer Polymers 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229910052751 metal Chemical class 0.000 description 1
- 239000002184 metal Chemical class 0.000 description 1
- FQPSGWSUVKBHSU-UHFFFAOYSA-N methacrylamide Chemical compound CC(=C)C(N)=O FQPSGWSUVKBHSU-UHFFFAOYSA-N 0.000 description 1
- 125000005395 methacrylic acid group Chemical group 0.000 description 1
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 1
- 238000006053 organic reaction Methods 0.000 description 1
- RPQRDASANLAFCM-UHFFFAOYSA-N oxiran-2-ylmethyl prop-2-enoate Chemical compound C=CC(=O)OCC1CO1 RPQRDASANLAFCM-UHFFFAOYSA-N 0.000 description 1
- 229920002239 polyacrylonitrile Polymers 0.000 description 1
- 239000003505 polymerization initiator Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 235000010267 sodium hydrogen sulphite Nutrition 0.000 description 1
- HHHFOFALLICHSO-UHFFFAOYSA-M sodium;2-(2-methylprop-2-enoyloxy)benzenesulfonate Chemical compound [Na+].CC(=C)C(=O)OC1=CC=CC=C1S([O-])(=O)=O HHHFOFALLICHSO-UHFFFAOYSA-M 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-L sulfite Chemical class [O-]S([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-L 0.000 description 1
- 230000002522 swelling effect Effects 0.000 description 1
- 238000002166 wet spinning Methods 0.000 description 1
Landscapes
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Artificial Filaments (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP12290378A JPS5550032A (en) | 1978-10-04 | 1978-10-04 | Manufacturing of ion exchange fiber |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP12290378A JPS5550032A (en) | 1978-10-04 | 1978-10-04 | Manufacturing of ion exchange fiber |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS5550032A JPS5550032A (en) | 1980-04-11 |
| JPS6226332B2 true JPS6226332B2 (en, 2012) | 1987-06-08 |
Family
ID=14847457
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP12290378A Granted JPS5550032A (en) | 1978-10-04 | 1978-10-04 | Manufacturing of ion exchange fiber |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS5550032A (en, 2012) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5743940A (en) * | 1988-04-07 | 1998-04-28 | Japan Atomic Energy Research Institute | Process for producing gas adsorbent |
| JP2522601B2 (ja) * | 1990-11-19 | 1996-08-07 | 大和紡績株式会社 | イオン交換性ポリマ、イオン交換繊維およびその製造方法並びにイオン交換不織布 |
| US9205422B2 (en) | 2011-04-27 | 2015-12-08 | Kaneka Corporation | Ion-exchange fibers and method for producing and using same |
| JP5940313B2 (ja) * | 2012-01-27 | 2016-06-29 | 日本フイルコン株式会社 | 高分子吸着体 |
| JP5954823B2 (ja) | 2012-09-05 | 2016-07-20 | 日本フイルコン株式会社 | 繊維状金属吸着材 |
| JP5896486B2 (ja) * | 2014-02-26 | 2016-03-30 | 日本フイルコン株式会社 | 不織布状金属吸着材およびその製造方法 |
-
1978
- 1978-10-04 JP JP12290378A patent/JPS5550032A/ja active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| JPS5550032A (en) | 1980-04-11 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US3553306A (en) | Films and filaments having ion-exchange properties and process for making same | |
| JPS6226332B2 (en, 2012) | ||
| SU806692A1 (ru) | Способ получени целлюлозных волок-НиСТыХ иОНиТОВ | |
| DE1918399A1 (de) | Verfahren zur Herstellung eines poroesen,vernetzten Mischpolymers,insbesondere zur Verwendung als Ionenaustauscherharz | |
| SE509894C2 (sv) | Användning av en linjär syntetisk polymer för att förbättra egenskaperna hos en formkropp av cellulosa framställd genom en tertiär aminoxidprocess | |
| US2587465A (en) | Solution polymerization of acrylonitrile polymers in aqueous alcohol mixtures | |
| EP0048846A2 (de) | Fäden und Fasern aus Carboxylgruppen haltigen Acrylpolymeren, ihre Verwendung und Verfahren zu ihrer Herstellung | |
| JP3728862B2 (ja) | 吸水性アクリル繊維 | |
| DE2550871A1 (de) | Verfahren zur herstellung einer flammhemmenden acrylsynthesefaser | |
| DE2213980B2 (de) | Verwendung von Acrylamidpolymerisaten als Dispergiermittel zur Papier- und Vliesstoffherstellung | |
| JP3041655B2 (ja) | アクリロニトリル系繊維及びその製造方法 | |
| JPS6044330B2 (ja) | カチオン交換性繊維の製造法 | |
| JP3085486B2 (ja) | 多孔質アクリロニトリル系繊維 | |
| JPS5857974B2 (ja) | 吸水・保水剤及びその製造法 | |
| US3878144A (en) | Method for preparing cellulose graft copolymers utilizing tervalent iron initiator | |
| DE2241914B2 (de) | Verfahren zur Herstellung von Mischpolymerisaten | |
| JP3172545B2 (ja) | アクリロニトリル系重合体の製造方法 | |
| DE2040618C2 (de) | Verfahren zur Herstellung eines schwach basischen Ionenaustauscherharzes mit tertiären Aminoxidgruppen | |
| KR890003541B1 (ko) | 고흡수성 폴리아크릴산 알카리금속염 수지의 제조방법 | |
| DE2104287C2 (de) | Verfahren zur Herstellung von Copolymerisaten von Acrylnitril | |
| JPS5947685B2 (ja) | 塩化ビニル共重合体の製造方法 | |
| JPS58462B2 (ja) | イオンコウカンセイセンジヨウブツノセイホウ | |
| DE1620904C (de) | Verfahren zur Herstellung von vernetz baren Acrylnitrilmischpolymeren | |
| JPS5865007A (ja) | ウイツグ用繊維 | |
| JPS5891711A (ja) | アクリロニトリル系重合体、その製造方法及びそれからなるモダクリル系合成繊維 |