JPS62256710A - シリコンカ−バイド繊維，フイルムの製造方法 - Google Patents
シリコンカ−バイド繊維，フイルムの製造方法Info
- Publication number
- JPS62256710A JPS62256710A JP61186981A JP18698186A JPS62256710A JP S62256710 A JPS62256710 A JP S62256710A JP 61186981 A JP61186981 A JP 61186981A JP 18698186 A JP18698186 A JP 18698186A JP S62256710 A JPS62256710 A JP S62256710A
- Authority
- JP
- Japan
- Prior art keywords
- temperature
- fiber
- fibers
- polysilastyrene
- film
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000835 fiber Substances 0.000 title claims abstract description 101
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 title claims abstract description 35
- 229910010271 silicon carbide Inorganic materials 0.000 title claims abstract description 34
- 238000004519 manufacturing process Methods 0.000 title claims description 18
- 229920001577 copolymer Polymers 0.000 claims abstract description 43
- 229920003203 poly(dimethylsilylene-co-phenylmethyl- silylene) polymer Polymers 0.000 claims abstract description 40
- 238000004132 cross linking Methods 0.000 claims abstract description 7
- 238000010438 heat treatment Methods 0.000 claims description 32
- 238000009281 ultraviolet germicidal irradiation Methods 0.000 claims description 3
- 238000001354 calcination Methods 0.000 claims 1
- 238000000034 method Methods 0.000 abstract description 50
- 230000004927 fusion Effects 0.000 abstract description 15
- 239000000463 material Substances 0.000 abstract description 3
- 230000008602 contraction Effects 0.000 abstract 1
- 238000009987 spinning Methods 0.000 description 40
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 32
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 17
- 239000012298 atmosphere Substances 0.000 description 13
- 239000011261 inert gas Substances 0.000 description 13
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 12
- 229920003257 polycarbosilane Polymers 0.000 description 12
- 239000003054 catalyst Substances 0.000 description 8
- 150000001875 compounds Chemical class 0.000 description 8
- GNEPOXWQWFSSOU-UHFFFAOYSA-N dichloro-methyl-phenylsilane Chemical compound C[Si](Cl)(Cl)C1=CC=CC=C1 GNEPOXWQWFSSOU-UHFFFAOYSA-N 0.000 description 7
- 229910001873 dinitrogen Inorganic materials 0.000 description 7
- 238000010304 firing Methods 0.000 description 7
- 238000000465 moulding Methods 0.000 description 7
- 229920001558 organosilicon polymer Polymers 0.000 description 7
- 229920000642 polymer Polymers 0.000 description 7
- LIKFHECYJZWXFJ-UHFFFAOYSA-N dimethyldichlorosilane Chemical compound C[Si](C)(Cl)Cl LIKFHECYJZWXFJ-UHFFFAOYSA-N 0.000 description 6
- 239000000203 mixture Substances 0.000 description 6
- 239000002904 solvent Substances 0.000 description 6
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 5
- 239000007789 gas Substances 0.000 description 5
- 238000002074 melt spinning Methods 0.000 description 5
- 229910052757 nitrogen Inorganic materials 0.000 description 5
- 239000002994 raw material Substances 0.000 description 5
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 4
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 4
- 238000002844 melting Methods 0.000 description 4
- 230000008018 melting Effects 0.000 description 4
- 230000000379 polymerizing effect Effects 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 3
- KEAYESYHFKHZAL-UHFFFAOYSA-N Sodium Chemical compound [Na] KEAYESYHFKHZAL-UHFFFAOYSA-N 0.000 description 3
- 238000002441 X-ray diffraction Methods 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 3
- 238000005229 chemical vapour deposition Methods 0.000 description 3
- 239000013078 crystal Substances 0.000 description 3
- -1 dimethyl methyl Chemical group 0.000 description 3
- 239000002243 precursor Substances 0.000 description 3
- 230000000717 retained effect Effects 0.000 description 3
- 150000003384 small molecules Chemical class 0.000 description 3
- 239000008096 xylene Substances 0.000 description 3
- VXEGSRKPIUDPQT-UHFFFAOYSA-N 4-[4-(4-methoxyphenyl)piperazin-1-yl]aniline Chemical compound C1=CC(OC)=CC=C1N1CCN(C=2C=CC(N)=CC=2)CC1 VXEGSRKPIUDPQT-UHFFFAOYSA-N 0.000 description 2
- 229920000049 Carbon (fiber) Polymers 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- 239000003570 air Substances 0.000 description 2
- 229910052786 argon Inorganic materials 0.000 description 2
- 239000004917 carbon fiber Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000001307 helium Substances 0.000 description 2
- 229910052734 helium Inorganic materials 0.000 description 2
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- 239000000155 melt Substances 0.000 description 2
- 230000001590 oxidative effect Effects 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 229910052710 silicon Inorganic materials 0.000 description 2
- 239000010703 silicon Substances 0.000 description 2
- 239000005049 silicon tetrachloride Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 238000007740 vapor deposition Methods 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- DBTDEFJAFBUGPP-UHFFFAOYSA-N Methanethial Chemical compound S=C DBTDEFJAFBUGPP-UHFFFAOYSA-N 0.000 description 1
- 235000003976 Ruta Nutrition 0.000 description 1
- 240000005746 Ruta graveolens Species 0.000 description 1
- 229910018540 Si C Inorganic materials 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 238000012993 chemical processing Methods 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- OSXYHAQZDCICNX-UHFFFAOYSA-N dichloro(diphenyl)silane Chemical compound C=1C=CC=CC=1[Si](Cl)(Cl)C1=CC=CC=C1 OSXYHAQZDCICNX-UHFFFAOYSA-N 0.000 description 1
- 238000000578 dry spinning Methods 0.000 description 1
- 238000010894 electron beam technology Methods 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 238000001879 gelation Methods 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 229920006158 high molecular weight polymer Polymers 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000012442 inert solvent Substances 0.000 description 1
- 238000002329 infrared spectrum Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000012299 nitrogen atmosphere Substances 0.000 description 1
- 238000011017 operating method Methods 0.000 description 1
- 229920000548 poly(silane) polymer Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- 230000002787 reinforcement Effects 0.000 description 1
- 235000005806 ruta Nutrition 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 230000002194 synthesizing effect Effects 0.000 description 1
- 238000005979 thermal decomposition reaction Methods 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
Landscapes
- Carbon And Carbon Compounds (AREA)
- Silicon Polymers (AREA)
- Inorganic Fibers (AREA)
- Treatments Of Macromolecular Shaped Articles (AREA)
- Processing And Handling Of Plastics And Other Materials For Molding In General (AREA)
- Ceramic Products (AREA)
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP17935985 | 1985-08-16 | ||
| JP60-179359 | 1985-08-16 | ||
| JP60-223839 | 1985-10-09 | ||
| JP60-275954 | 1985-12-10 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS62256710A true JPS62256710A (ja) | 1987-11-09 |
| JPH0417888B2 JPH0417888B2 (enrdf_load_stackoverflow) | 1992-03-26 |
Family
ID=16064468
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP61186981A Granted JPS62256710A (ja) | 1985-08-16 | 1986-08-11 | シリコンカ−バイド繊維，フイルムの製造方法 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS62256710A (enrdf_load_stackoverflow) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH02264017A (ja) * | 1989-03-31 | 1990-10-26 | Japan Atom Energy Res Inst | 放射線照射による高性質ケイ素系セラミック繊維の製造方法 |
| KR20220059003A (ko) * | 2020-11-02 | 2022-05-10 | 한국세라믹기술원 | PCS 섬유의 불융화 디바이스 및 이를 이용한 SiC 섬유의 제조 방법 |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS58215426A (ja) * | 1982-06-03 | 1983-12-14 | ウイスコンシン、アラムナイ、リサーチ、フアウンデーシヨン | 可溶性ポリシラスチレンの架橋法 |
-
1986
- 1986-08-11 JP JP61186981A patent/JPS62256710A/ja active Granted
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS58215426A (ja) * | 1982-06-03 | 1983-12-14 | ウイスコンシン、アラムナイ、リサーチ、フアウンデーシヨン | 可溶性ポリシラスチレンの架橋法 |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH02264017A (ja) * | 1989-03-31 | 1990-10-26 | Japan Atom Energy Res Inst | 放射線照射による高性質ケイ素系セラミック繊維の製造方法 |
| KR20220059003A (ko) * | 2020-11-02 | 2022-05-10 | 한국세라믹기술원 | PCS 섬유의 불융화 디바이스 및 이를 이용한 SiC 섬유의 제조 방법 |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0417888B2 (enrdf_load_stackoverflow) | 1992-03-26 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US4604367A (en) | Method for the preparation of an inorganic fiber containing silicon, carbon, boron and nitrogen | |
| US5171722A (en) | SiC fibers having low oxygen content and methods of preparation | |
| US4743411A (en) | Process for producing shaped silicon carbide article from a polycarbosilastyrene copolymer | |
| US4746480A (en) | Process for providing a protective oxide coating on ceramic fibers | |
| US5278110A (en) | SiC fibers having low oxygen content and methods of preparation | |
| Narisawa et al. | Use of blended precursors of poly (vinylsilane) in polycarbosilane for silicon carbide fiber synthesis with radiation curing | |
| JPS62256710A (ja) | シリコンカ−バイド繊維，フイルムの製造方法 | |
| EP0448236B1 (en) | Curing preceramic polymers by exposure to nitrogen dioxide | |
| EP0371846A1 (fr) | Procédé de préparation de carbonitrure de silicium à partir de polycarbosilanes | |
| JPH01156510A (ja) | シリコンカーバイド繊維の製造法 | |
| US5091271A (en) | Shaped silion carbide-eased ceramic article | |
| US4897229A (en) | Process for producing a shaped silicon carbide-based ceramic article | |
| Funayama et al. | Synthesis of thermosetting copolymer of polycarbosilane and perhydropolysilazane | |
| JP2514253B2 (ja) | シリコンカ―バイド系成形物及びその製造法 | |
| US5064915A (en) | Production of infusible polycarbosilanes convertible into silicon carbide ceramics | |
| JPH02184569A (ja) | シリコンカーバイド系成形物の製造法 | |
| JP2672106B2 (ja) | 窒化珪素質無機繊維及びその製造方法 | |
| JPH0737684B2 (ja) | ＳｉＣ−Ｃ系連続無機繊維およびその製造方法 | |
| JPH0384034A (ja) | 特にセラミック繊維を得るための湿式経路によるポリシラザンの架橋方法 | |
| JPH02188465A (ja) | シリコンカーバイド系成形体の製造方法 | |
| JPH02243567A (ja) | シリコンカーバイト系成形体の製造法 | |
| JPH0384035A (ja) | ほう素、窒素およびけい素を基剤とする有機金属セラミック先駆物質 | |
| JPH06146115A (ja) | 無機長繊維 | |
| JPH02293379A (ja) | シリコンカーバイド系成形物 | |
| FR2639933A1 (fr) | Procede de preparation de nitrure de silicium a partir de polycarbosilanes |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| LAPS | Cancellation because of no payment of annual fees |