JPS62250906A - 水―アルコール用分離膜の製造方法 - Google Patents
水―アルコール用分離膜の製造方法Info
- Publication number
- JPS62250906A JPS62250906A JP9595086A JP9595086A JPS62250906A JP S62250906 A JPS62250906 A JP S62250906A JP 9595086 A JP9595086 A JP 9595086A JP 9595086 A JP9595086 A JP 9595086A JP S62250906 A JPS62250906 A JP S62250906A
- Authority
- JP
- Japan
- Prior art keywords
- water
- membrane
- alcohol
- separation
- graft
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000012528 membrane Substances 0.000 title claims abstract description 67
- 238000000926 separation method Methods 0.000 claims abstract description 60
- 239000004372 Polyvinyl alcohol Substances 0.000 claims abstract description 14
- 229920002451 polyvinyl alcohol Polymers 0.000 claims abstract description 14
- 239000000178 monomer Substances 0.000 claims abstract description 11
- 238000010559 graft polymerization reaction Methods 0.000 claims abstract description 9
- 150000001732 carboxylic acid derivatives Chemical class 0.000 claims description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract description 48
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 33
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 abstract description 12
- 238000000034 method Methods 0.000 abstract description 11
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 abstract description 7
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 abstract description 7
- 239000003513 alkali Substances 0.000 abstract description 6
- 239000000758 substrate Substances 0.000 abstract description 6
- 239000003054 catalyst Substances 0.000 abstract description 4
- XMPZTFVPEKAKFH-UHFFFAOYSA-P ceric ammonium nitrate Chemical compound [NH4+].[NH4+].[Ce+4].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O XMPZTFVPEKAKFH-UHFFFAOYSA-P 0.000 abstract description 4
- 239000012466 permeate Substances 0.000 abstract description 4
- 239000000463 material Substances 0.000 abstract description 3
- 238000006116 polymerization reaction Methods 0.000 abstract description 3
- 150000001735 carboxylic acids Chemical class 0.000 abstract 2
- 238000002309 gasification Methods 0.000 abstract 1
- 230000003472 neutralizing effect Effects 0.000 abstract 1
- 230000003204 osmotic effect Effects 0.000 abstract 1
- 239000007864 aqueous solution Substances 0.000 description 14
- 238000005373 pervaporation Methods 0.000 description 11
- 238000002474 experimental method Methods 0.000 description 8
- 239000011259 mixed solution Substances 0.000 description 7
- 229920001577 copolymer Polymers 0.000 description 4
- 229920000578 graft copolymer Polymers 0.000 description 4
- 125000003010 ionic group Chemical group 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 239000000243 solution Substances 0.000 description 4
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 238000004821 distillation Methods 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 239000003014 ion exchange membrane Substances 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 238000006386 neutralization reaction Methods 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 238000005406 washing Methods 0.000 description 3
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 2
- 229920000557 Nafion® Polymers 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000005371 permeation separation Methods 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 238000000746 purification Methods 0.000 description 2
- -1 (p. 401) Substances 0.000 description 1
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 1
- 150000000703 Cerium Chemical class 0.000 description 1
- IMROMDMJAWUWLK-UHFFFAOYSA-N Ethenol Chemical compound OC=C IMROMDMJAWUWLK-UHFFFAOYSA-N 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 239000008280 blood Substances 0.000 description 1
- 210000004369 blood Anatomy 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 229920002301 cellulose acetate Polymers 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000010612 desalination reaction Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000000502 dialysis Methods 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000000855 fermentation Methods 0.000 description 1
- 230000004151 fermentation Effects 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 230000000977 initiatory effect Effects 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- FQPSGWSUVKBHSU-UHFFFAOYSA-N methacrylamide Chemical compound CC(=C)C(N)=O FQPSGWSUVKBHSU-UHFFFAOYSA-N 0.000 description 1
- SYSQUGFVNFXIIT-UHFFFAOYSA-N n-[4-(1,3-benzoxazol-2-yl)phenyl]-4-nitrobenzenesulfonamide Chemical class C1=CC([N+](=O)[O-])=CC=C1S(=O)(=O)NC1=CC=C(C=2OC3=CC=CC=C3N=2)C=C1 SYSQUGFVNFXIIT-UHFFFAOYSA-N 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 229920005597 polymer membrane Polymers 0.000 description 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000004627 regenerated cellulose Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000001223 reverse osmosis Methods 0.000 description 1
- 239000013535 sea water Substances 0.000 description 1
- 239000004065 semiconductor Substances 0.000 description 1
- 229910021642 ultra pure water Inorganic materials 0.000 description 1
- 238000000108 ultra-filtration Methods 0.000 description 1
- 239000012498 ultrapure water Substances 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
Landscapes
- Separation Using Semi-Permeable Membranes (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP9595086A JPS62250906A (ja) | 1986-04-25 | 1986-04-25 | 水―アルコール用分離膜の製造方法 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP9595086A JPS62250906A (ja) | 1986-04-25 | 1986-04-25 | 水―アルコール用分離膜の製造方法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS62250906A true JPS62250906A (ja) | 1987-10-31 |
| JPH046411B2 JPH046411B2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1992-02-05 |
Family
ID=14151537
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP9595086A Granted JPS62250906A (ja) | 1986-04-25 | 1986-04-25 | 水―アルコール用分離膜の製造方法 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS62250906A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5015268A (en) * | 1988-10-13 | 1991-05-14 | Exxon Research And Engineering Co. | Polymeric membrane and process for separating aliphatically unsaturated hydrocarbons |
| WO1999064129A3 (en) * | 1998-06-10 | 2000-04-13 | Korea Res Inst Chem Tech | Process for preparing hydroxylated aromatics by hydrogen and oxygen |
| JP2014113522A (ja) * | 2012-12-06 | 2014-06-26 | Molecular Gate Membrane Module Technology Research Association | ガス分離膜 |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5840104A (ja) * | 1981-08-31 | 1983-03-09 | Kuraray Co Ltd | 混合液体の分離方法 |
-
1986
- 1986-04-25 JP JP9595086A patent/JPS62250906A/ja active Granted
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5840104A (ja) * | 1981-08-31 | 1983-03-09 | Kuraray Co Ltd | 混合液体の分離方法 |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5015268A (en) * | 1988-10-13 | 1991-05-14 | Exxon Research And Engineering Co. | Polymeric membrane and process for separating aliphatically unsaturated hydrocarbons |
| WO1999064129A3 (en) * | 1998-06-10 | 2000-04-13 | Korea Res Inst Chem Tech | Process for preparing hydroxylated aromatics by hydrogen and oxygen |
| JP2014113522A (ja) * | 2012-12-06 | 2014-06-26 | Molecular Gate Membrane Module Technology Research Association | ガス分離膜 |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH046411B2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1992-02-05 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EXPY | Cancellation because of completion of term |