JPS62124128A - 架橋型、親水性ポリスチレンの製造方法 - Google Patents
架橋型、親水性ポリスチレンの製造方法Info
- Publication number
- JPS62124128A JPS62124128A JP26325785A JP26325785A JPS62124128A JP S62124128 A JPS62124128 A JP S62124128A JP 26325785 A JP26325785 A JP 26325785A JP 26325785 A JP26325785 A JP 26325785A JP S62124128 A JPS62124128 A JP S62124128A
- Authority
- JP
- Japan
- Prior art keywords
- polyethylene oxide
- reaction
- styrene
- maleic anhydride
- water
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000004793 Polystyrene Substances 0.000 title claims abstract description 11
- 229920002223 polystyrene Polymers 0.000 title claims abstract description 11
- 238000004519 manufacturing process Methods 0.000 title claims description 6
- 238000006243 chemical reaction Methods 0.000 claims abstract description 34
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims abstract description 21
- 150000004985 diamines Chemical class 0.000 claims abstract description 21
- PYSRRFNXTXNWCD-UHFFFAOYSA-N 3-(2-phenylethenyl)furan-2,5-dione Chemical compound O=C1OC(=O)C(C=CC=2C=CC=CC=2)=C1 PYSRRFNXTXNWCD-UHFFFAOYSA-N 0.000 claims abstract description 14
- 229920000147 Styrene maleic anhydride Polymers 0.000 claims abstract description 14
- 150000008065 acid anhydrides Chemical class 0.000 claims abstract description 13
- 125000003277 amino group Chemical group 0.000 claims abstract description 10
- 150000001875 compounds Chemical class 0.000 claims abstract description 10
- 239000004593 Epoxy Substances 0.000 claims abstract description 9
- 239000003960 organic solvent Substances 0.000 claims abstract description 8
- 125000003700 epoxy group Chemical group 0.000 claims abstract 2
- 150000007824 aliphatic compounds Chemical class 0.000 claims description 3
- 150000001491 aromatic compounds Chemical class 0.000 claims 2
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 abstract description 16
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 16
- IDGUHHHQCWSQLU-UHFFFAOYSA-N ethanol;hydrate Chemical compound O.CCO IDGUHHHQCWSQLU-UHFFFAOYSA-N 0.000 abstract description 6
- 239000012528 membrane Substances 0.000 abstract description 6
- FALRKNHUBBKYCC-UHFFFAOYSA-N 2-(chloromethyl)pyridine-3-carbonitrile Chemical compound ClCC1=NC=CC=C1C#N FALRKNHUBBKYCC-UHFFFAOYSA-N 0.000 abstract description 3
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 abstract description 3
- 150000001412 amines Chemical class 0.000 abstract description 3
- 238000000465 moulding Methods 0.000 abstract description 3
- 238000000926 separation method Methods 0.000 abstract description 3
- 229940014800 succinic anhydride Drugs 0.000 abstract description 3
- 230000002035 prolonged effect Effects 0.000 abstract 1
- 239000011347 resin Substances 0.000 abstract 1
- 229920005989 resin Polymers 0.000 abstract 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 19
- 239000000243 solution Substances 0.000 description 14
- 238000010521 absorption reaction Methods 0.000 description 8
- 238000000034 method Methods 0.000 description 8
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 6
- 239000011521 glass Substances 0.000 description 6
- -1 reverse osmosis Substances 0.000 description 6
- SCYULBFZEHDVBN-UHFFFAOYSA-N 1,1-Dichloroethane Chemical compound CC(Cl)Cl SCYULBFZEHDVBN-UHFFFAOYSA-N 0.000 description 5
- 239000004698 Polyethylene Substances 0.000 description 5
- 229920000578 graft copolymer Polymers 0.000 description 5
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 5
- 229920000573 polyethylene Polymers 0.000 description 5
- 239000002904 solvent Substances 0.000 description 5
- 238000000862 absorption spectrum Methods 0.000 description 4
- 229920001577 copolymer Polymers 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- DLYUQMMRRRQYAE-UHFFFAOYSA-N tetraphosphorus decaoxide Chemical compound O1P(O2)(=O)OP3(=O)OP1(=O)OP2(=O)O3 DLYUQMMRRRQYAE-UHFFFAOYSA-N 0.000 description 4
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 3
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
- LGRFSURHDFAFJT-UHFFFAOYSA-N Phthalic anhydride Natural products C1=CC=C2C(=O)OC(=O)C2=C1 LGRFSURHDFAFJT-UHFFFAOYSA-N 0.000 description 3
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 3
- JHIWVOJDXOSYLW-UHFFFAOYSA-N butyl 2,2-difluorocyclopropane-1-carboxylate Chemical compound CCCCOC(=O)C1CC1(F)F JHIWVOJDXOSYLW-UHFFFAOYSA-N 0.000 description 3
- 238000004132 cross linking Methods 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 3
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 2
- 238000002441 X-ray diffraction Methods 0.000 description 2
- 150000001408 amides Chemical class 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 238000001514 detection method Methods 0.000 description 2
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 2
- 239000011976 maleic acid Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- 238000001228 spectrum Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 238000013268 sustained release Methods 0.000 description 2
- 239000012730 sustained-release form Substances 0.000 description 2
- 238000002076 thermal analysis method Methods 0.000 description 2
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 2
- UOCLXMDMGBRAIB-UHFFFAOYSA-N 1,1,1-trichloroethane Chemical compound CC(Cl)(Cl)Cl UOCLXMDMGBRAIB-UHFFFAOYSA-N 0.000 description 1
- 238000001644 13C nuclear magnetic resonance spectroscopy Methods 0.000 description 1
- 235000017166 Bambusa arundinacea Nutrition 0.000 description 1
- 235000017491 Bambusa tulda Nutrition 0.000 description 1
- 241001330002 Bambuseae Species 0.000 description 1
- BRLQWZUYTZBJKN-UHFFFAOYSA-N Epichlorohydrin Chemical compound ClCC1CO1 BRLQWZUYTZBJKN-UHFFFAOYSA-N 0.000 description 1
- 238000004566 IR spectroscopy Methods 0.000 description 1
- 241000824268 Kuma Species 0.000 description 1
- 235000015334 Phyllostachys viridis Nutrition 0.000 description 1
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 1
- 238000002083 X-ray spectrum Methods 0.000 description 1
- 239000008186 active pharmaceutical agent Substances 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000008064 anhydrides Chemical class 0.000 description 1
- 239000011425 bamboo Substances 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 239000002775 capsule Substances 0.000 description 1
- 238000001460 carbon-13 nuclear magnetic resonance spectrum Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000000499 gel Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 150000003949 imides Chemical group 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 239000011259 mixed solution Substances 0.000 description 1
- 239000012046 mixed solvent Substances 0.000 description 1
- 210000000056 organ Anatomy 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920005996 polystyrene-poly(ethylene-butylene)-polystyrene Polymers 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 238000001223 reverse osmosis Methods 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 238000010183 spectrum analysis Methods 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 238000009864 tensile test Methods 0.000 description 1
- 230000002747 voluntary effect Effects 0.000 description 1
Landscapes
- Other Resins Obtained By Reactions Not Involving Carbon-To-Carbon Unsaturated Bonds (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP26325785A JPS62124128A (ja) | 1985-11-22 | 1985-11-22 | 架橋型、親水性ポリスチレンの製造方法 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP26325785A JPS62124128A (ja) | 1985-11-22 | 1985-11-22 | 架橋型、親水性ポリスチレンの製造方法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS62124128A true JPS62124128A (ja) | 1987-06-05 |
| JPH045051B2 JPH045051B2 (enrdf_load_stackoverflow) | 1992-01-30 |
Family
ID=17386955
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP26325785A Granted JPS62124128A (ja) | 1985-11-22 | 1985-11-22 | 架橋型、親水性ポリスチレンの製造方法 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS62124128A (enrdf_load_stackoverflow) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2011506629A (ja) * | 2007-12-06 | 2011-03-03 | ビーエーエスエフ ソシエタス・ヨーロピア | 室温で架橋可能なイオン伝導性重合体系 |
-
1985
- 1985-11-22 JP JP26325785A patent/JPS62124128A/ja active Granted
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2011506629A (ja) * | 2007-12-06 | 2011-03-03 | ビーエーエスエフ ソシエタス・ヨーロピア | 室温で架橋可能なイオン伝導性重合体系 |
| US8623964B2 (en) | 2007-12-06 | 2014-01-07 | Basf Se | Room temperature crosslinkable ion conductive polymer system |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH045051B2 (enrdf_load_stackoverflow) | 1992-01-30 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP2980565B2 (ja) | イミドポリマーのブレンド | |
| Wu et al. | Deep eutectic supramolecular polymers: Bulk supramolecular materials | |
| Zhang et al. | Preparation and mechanical properties of composite of fibrous cellulose and maleated polyethylene | |
| JPS60203636A (ja) | コポリアミノ酸の製造法 | |
| JPS62124128A (ja) | 架橋型、親水性ポリスチレンの製造方法 | |
| Yeom et al. | Pervaporation separation of aqueous mixtures using crosslinked poly (vinyl alcohol), I. Characterization of the reaction between PVA and amic acid | |
| JPH0611771B2 (ja) | イソイミドを使用する共重合体及びその製造方法 | |
| US9556282B2 (en) | Modified cellulose and composite material using the same | |
| JPH10306191A (ja) | ポリビニルアルコール／エチレンービニルアルコール 共重合体のコンポジット | |
| JP2006022160A (ja) | 変性ポリビニルアルコール | |
| JPS62124103A (ja) | 架橋型、親水性、親アルコール性ポリスチレンの製造方法 | |
| Venkatanarasimhan et al. | A new route to polymeric materials derived from chitosan and natural rubber | |
| JPH03221505A (ja) | シクロデキストリンポリマーの合成方法及びシクロデキストリン膜の製造方法 | |
| JPH10120610A (ja) | 非晶性カリックスアレーン組成物およびそれを用いる膜製造方法 | |
| JPS6137892A (ja) | 液晶組成物 | |
| FR2460976A1 (fr) | Composition a base de resine styrenique | |
| JPS63273603A (ja) | ポリビニ−ルケタ−ルの製造法 | |
| JP2003073470A (ja) | 酸分解性ポリアゾメチン | |
| JPH05125101A (ja) | 澱粉エステルグラフト共重合体及びその製造方法 | |
| ATE91290T1 (de) | Polymere mit imid-gruppen ohne diamin und verfahren zu deren herstellung. | |
| JPH0718075A (ja) | 耐熱性樹脂、その製造法およびそれを含むワニス | |
| KR20180059643A (ko) | 폴리아세트산비닐/폴리메틸메타크릴레이트 블렌드 필름의 불균일계 비누화에 의해 제조된 폴리비닐알코올/폴리메틸메타크릴레이트 블렌드 필름 및 그의 제조방법 | |
| JP2931979B1 (ja) | 延伸可能な共重合ポリシラン及びそれからなる延伸フィルム | |
| NO844581L (no) | Polyimid og fremgangsmaate for fremstilling derav | |
| JPH01172454A (ja) | 放射線感応組成物 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EXPY | Cancellation because of completion of term |