JPS6155562B2 - - Google Patents
Info
- Publication number
- JPS6155562B2 JPS6155562B2 JP22556882A JP22556882A JPS6155562B2 JP S6155562 B2 JPS6155562 B2 JP S6155562B2 JP 22556882 A JP22556882 A JP 22556882A JP 22556882 A JP22556882 A JP 22556882A JP S6155562 B2 JPS6155562 B2 JP S6155562B2
- Authority
- JP
- Japan
- Prior art keywords
- copper
- particle size
- hydrazine
- powder
- copper powder
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 52
- 239000002245 particle Substances 0.000 claims description 52
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 claims description 42
- OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 claims description 31
- 239000000843 powder Substances 0.000 claims description 19
- 239000005751 Copper oxide Substances 0.000 claims description 16
- 238000006243 chemical reaction Methods 0.000 claims description 16
- 229910000431 copper oxide Inorganic materials 0.000 claims description 16
- 238000000034 method Methods 0.000 claims description 16
- 239000000084 colloidal system Substances 0.000 claims description 10
- 229910052802 copper Inorganic materials 0.000 claims description 10
- 239000010949 copper Substances 0.000 claims description 10
- 230000001681 protective effect Effects 0.000 claims description 10
- 239000002244 precipitate Substances 0.000 claims description 9
- -1 hydrazine compound Chemical class 0.000 claims description 7
- 238000004519 manufacturing process Methods 0.000 claims description 6
- 239000012736 aqueous medium Substances 0.000 claims description 4
- 229960004643 cupric oxide Drugs 0.000 description 24
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 21
- NWZSZGALRFJKBT-KNIFDHDWSA-N (2s)-2,6-diaminohexanoic acid;(2s)-2-hydroxybutanedioic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O.NCCCC[C@H](N)C(O)=O NWZSZGALRFJKBT-KNIFDHDWSA-N 0.000 description 17
- IKDUDTNKRLTJSI-UHFFFAOYSA-N hydrazine monohydrate Substances O.NN IKDUDTNKRLTJSI-UHFFFAOYSA-N 0.000 description 17
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 16
- 239000007864 aqueous solution Substances 0.000 description 15
- 229920000084 Gum arabic Polymers 0.000 description 9
- 241000978776 Senegalia senegal Species 0.000 description 9
- 239000000205 acacia gum Substances 0.000 description 9
- 235000010489 acacia gum Nutrition 0.000 description 9
- 239000000203 mixture Substances 0.000 description 9
- 238000003756 stirring Methods 0.000 description 9
- 239000003638 chemical reducing agent Substances 0.000 description 8
- 239000000243 solution Substances 0.000 description 7
- 230000001788 irregular Effects 0.000 description 4
- 239000003973 paint Substances 0.000 description 4
- 239000011164 primary particle Substances 0.000 description 4
- 238000005054 agglomeration Methods 0.000 description 3
- 230000002776 aggregation Effects 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 238000001816 cooling Methods 0.000 description 3
- XTVVROIMIGLXTD-UHFFFAOYSA-N copper(II) nitrate Chemical compound [Cu+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O XTVVROIMIGLXTD-UHFFFAOYSA-N 0.000 description 3
- 239000006185 dispersion Substances 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- 239000005749 Copper compound Substances 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 238000000889 atomisation Methods 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 229940116318 copper carbonate Drugs 0.000 description 2
- 150000001880 copper compounds Chemical class 0.000 description 2
- BERDEBHAJNAUOM-UHFFFAOYSA-N copper(I) oxide Inorganic materials [Cu]O[Cu] BERDEBHAJNAUOM-UHFFFAOYSA-N 0.000 description 2
- GEZOTWYUIKXWOA-UHFFFAOYSA-L copper;carbonate Chemical compound [Cu+2].[O-]C([O-])=O GEZOTWYUIKXWOA-UHFFFAOYSA-L 0.000 description 2
- KRFJLUBVMFXRPN-UHFFFAOYSA-N cuprous oxide Chemical compound [O-2].[Cu+].[Cu+] KRFJLUBVMFXRPN-UHFFFAOYSA-N 0.000 description 2
- 229940112669 cuprous oxide Drugs 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 238000005868 electrolysis reaction Methods 0.000 description 2
- 238000001704 evaporation Methods 0.000 description 2
- 230000008020 evaporation Effects 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- 150000002429 hydrazines Chemical class 0.000 description 2
- 239000011261 inert gas Substances 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 238000010298 pulverizing process Methods 0.000 description 2
- 238000006722 reduction reaction Methods 0.000 description 2
- FUSNOPLQVRUIIM-UHFFFAOYSA-N 4-amino-2-(4,4-dimethyl-2-oxoimidazolidin-1-yl)-n-[3-(trifluoromethyl)phenyl]pyrimidine-5-carboxamide Chemical compound O=C1NC(C)(C)CN1C(N=C1N)=NC=C1C(=O)NC1=CC=CC(C(F)(F)F)=C1 FUSNOPLQVRUIIM-UHFFFAOYSA-N 0.000 description 1
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
- JPVYNHNXODAKFH-UHFFFAOYSA-N Cu2+ Chemical compound [Cu+2] JPVYNHNXODAKFH-UHFFFAOYSA-N 0.000 description 1
- 229920001353 Dextrin Polymers 0.000 description 1
- 239000004375 Dextrin Substances 0.000 description 1
- 108010010803 Gelatin Proteins 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 1
- 241001424392 Lucia limbaria Species 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- BIVUUOPIAYRCAP-UHFFFAOYSA-N aminoazanium;chloride Chemical compound Cl.NN BIVUUOPIAYRCAP-UHFFFAOYSA-N 0.000 description 1
- 235000011114 ammonium hydroxide Nutrition 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 229910001431 copper ion Inorganic materials 0.000 description 1
- 229910000365 copper sulfate Inorganic materials 0.000 description 1
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 description 1
- 235000019425 dextrin Nutrition 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000010828 elution Methods 0.000 description 1
- 229920000159 gelatin Polymers 0.000 description 1
- 239000008273 gelatin Substances 0.000 description 1
- 235000019322 gelatine Nutrition 0.000 description 1
- 235000011852 gelatine desserts Nutrition 0.000 description 1
- ZGCHATBSUIJLRL-UHFFFAOYSA-N hydrazine sulfate Chemical compound NN.OS(O)(=O)=O ZGCHATBSUIJLRL-UHFFFAOYSA-N 0.000 description 1
- 239000012493 hydrazine sulfate Substances 0.000 description 1
- 229910000377 hydrazine sulfate Inorganic materials 0.000 description 1
- 239000002609 medium Substances 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 235000019422 polyvinyl alcohol Nutrition 0.000 description 1
- 238000009790 rate-determining step (RDS) Methods 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000004626 scanning electron microscopy Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229920003169 water-soluble polymer Polymers 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F9/00—Making metallic powder or suspensions thereof
- B22F9/16—Making metallic powder or suspensions thereof using chemical processes
- B22F9/18—Making metallic powder or suspensions thereof using chemical processes with reduction of metal compounds
- B22F9/20—Making metallic powder or suspensions thereof using chemical processes with reduction of metal compounds starting from solid metal compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Manufacture Of Metal Powder And Suspensions Thereof (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP22556882A JPS59116303A (ja) | 1982-12-22 | 1982-12-22 | 銅微粉末の製造方法 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP22556882A JPS59116303A (ja) | 1982-12-22 | 1982-12-22 | 銅微粉末の製造方法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS59116303A JPS59116303A (ja) | 1984-07-05 |
| JPS6155562B2 true JPS6155562B2 (zh) | 1986-11-28 |
Family
ID=16831340
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP22556882A Granted JPS59116303A (ja) | 1982-12-22 | 1982-12-22 | 銅微粉末の製造方法 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS59116303A (zh) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0620964U (ja) * | 1992-07-08 | 1994-03-18 | カミマル株式会社 | 高圧ガスバルブ |
| WO2006019144A1 (ja) * | 2004-08-20 | 2006-02-23 | Ishihara Sangyo Kaisha, Ltd. | 銅微粒子及びその製造方法 |
| US7651782B2 (en) | 2006-07-11 | 2010-01-26 | Fujifilm Corporation | Method for producing metallic nanoparticles, metallic nanoparticles, and dispersion of the same |
| WO2010024385A1 (ja) * | 2008-08-29 | 2010-03-04 | 石原産業株式会社 | 金属銅分散液及びその製造方法並びにそれを用いて形成した電極、配線パターン、塗膜、その塗膜を形成した装飾物品、抗菌性物品及びそれらの製造方法 |
| JP2010222706A (ja) * | 2010-05-10 | 2010-10-07 | Jx Nippon Mining & Metals Corp | 銅微粉の製造方法 |
| TWI647082B (zh) * | 2017-12-19 | 2019-01-11 | 康豪奈米應用材料有限公司 | 銅抗菌母粒製造方法 |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6227508A (ja) * | 1985-07-26 | 1987-02-05 | Tanaka Kikinzoku Kogyo Kk | 銅微粒子の製造方法 |
| JPS6240302A (ja) * | 1985-08-16 | 1987-02-21 | Tanaka Kikinzoku Kogyo Kk | 銅微粒子の製造方法 |
| JPS6277406A (ja) * | 1985-09-28 | 1987-04-09 | Tanaka Kikinzoku Kogyo Kk | 銅微粒子の製造方法 |
| JPS6277408A (ja) * | 1985-09-28 | 1987-04-09 | Tanaka Kikinzoku Kogyo Kk | 銅微粒子の製造方法 |
| JPS6277407A (ja) * | 1985-09-28 | 1987-04-09 | Tanaka Kikinzoku Kogyo Kk | 銅微粒子の製造方法 |
| JPH0774364B2 (ja) * | 1988-07-21 | 1995-08-09 | 福田金属箔粉工業株式会社 | 銅微粉末の製造方法 |
| JP3570591B2 (ja) * | 1996-03-22 | 2004-09-29 | 株式会社村田製作所 | 銅粉末の製造方法 |
| JP6004034B1 (ja) * | 2015-04-21 | 2016-10-05 | 住友金属鉱山株式会社 | 銅粉末 |
| JP6099160B2 (ja) * | 2015-09-18 | 2017-03-22 | 国立大学法人山形大学 | 複合化合物、及び懸濁液 |
| JP6914999B2 (ja) * | 2019-07-16 | 2021-08-04 | Ｊｘ金属株式会社 | 表面処理銅粉 |
| JP7026173B2 (ja) * | 2020-07-15 | 2022-02-25 | Ｄｏｗａエレクトロニクス株式会社 | 銅粉及び導電性ペースト |
-
1982
- 1982-12-22 JP JP22556882A patent/JPS59116303A/ja active Granted
Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0620964U (ja) * | 1992-07-08 | 1994-03-18 | カミマル株式会社 | 高圧ガスバルブ |
| JP2012162807A (ja) * | 2004-08-20 | 2012-08-30 | Ishihara Sangyo Kaisha Ltd | 銅微粒子及びその製造方法 |
| JPWO2006019144A1 (ja) * | 2004-08-20 | 2008-05-08 | 石原産業株式会社 | 銅微粒子及びその製造方法 |
| US7828872B2 (en) | 2004-08-20 | 2010-11-09 | Ishihara Sangyo Kaisha, Ltd. | Copper microparticle and process for producing the same |
| JP2012052240A (ja) * | 2004-08-20 | 2012-03-15 | Ishihara Sangyo Kaisha Ltd | 銅微粒子及びその製造方法 |
| EP2452767A1 (en) | 2004-08-20 | 2012-05-16 | Ishihara Sangyo Kaisha, Ltd. | Copper microparticle and process for producing the same |
| WO2006019144A1 (ja) * | 2004-08-20 | 2006-02-23 | Ishihara Sangyo Kaisha, Ltd. | 銅微粒子及びその製造方法 |
| JP5164379B2 (ja) * | 2004-08-20 | 2013-03-21 | 石原産業株式会社 | 銅微粒子及びその製造方法 |
| US7651782B2 (en) | 2006-07-11 | 2010-01-26 | Fujifilm Corporation | Method for producing metallic nanoparticles, metallic nanoparticles, and dispersion of the same |
| WO2010024385A1 (ja) * | 2008-08-29 | 2010-03-04 | 石原産業株式会社 | 金属銅分散液及びその製造方法並びにそれを用いて形成した電極、配線パターン、塗膜、その塗膜を形成した装飾物品、抗菌性物品及びそれらの製造方法 |
| US10071419B2 (en) | 2008-08-29 | 2018-09-11 | Ishihara Sangyo Kaisha, Ltd. | Metallic copper dispersion, process for producing the metallic copper dispersion, electrode, wiring pattern, and coating film formed using the metallic copper dispersion, decorative article and antimicrobial article with the coating film formed thereon, and processes for producing the decorative article and the antimicrobial article |
| JP2010222706A (ja) * | 2010-05-10 | 2010-10-07 | Jx Nippon Mining & Metals Corp | 銅微粉の製造方法 |
| TWI647082B (zh) * | 2017-12-19 | 2019-01-11 | 康豪奈米應用材料有限公司 | 銅抗菌母粒製造方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS59116303A (ja) | 1984-07-05 |
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