JPS6146427B2 - - Google Patents
Info
- Publication number
- JPS6146427B2 JPS6146427B2 JP57080078A JP8007882A JPS6146427B2 JP S6146427 B2 JPS6146427 B2 JP S6146427B2 JP 57080078 A JP57080078 A JP 57080078A JP 8007882 A JP8007882 A JP 8007882A JP S6146427 B2 JPS6146427 B2 JP S6146427B2
- Authority
- JP
- Japan
- Prior art keywords
- nitrogen
- granular
- resin
- weight
- powdered
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 112
- 239000000203 mixture Substances 0.000 claims description 112
- 229920005989 resin Polymers 0.000 claims description 111
- 239000011347 resin Substances 0.000 claims description 111
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 77
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 claims description 75
- 239000000843 powder Substances 0.000 claims description 46
- 229910010272 inorganic material Inorganic materials 0.000 claims description 37
- 239000011147 inorganic material Substances 0.000 claims description 34
- -1 nitrogen-containing compound Chemical class 0.000 claims description 33
- 239000002245 particle Substances 0.000 claims description 32
- 238000010521 absorption reaction Methods 0.000 claims description 29
- 238000000034 method Methods 0.000 claims description 27
- 229910052751 metal Inorganic materials 0.000 claims description 23
- 239000002184 metal Substances 0.000 claims description 23
- 238000000862 absorption spectrum Methods 0.000 claims description 22
- 239000000463 material Substances 0.000 claims description 20
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 15
- 239000011164 primary particle Substances 0.000 claims description 14
- 238000010438 heat treatment Methods 0.000 claims description 11
- 230000004927 fusion Effects 0.000 claims description 9
- 229910044991 metal oxide Inorganic materials 0.000 claims description 9
- 150000004706 metal oxides Chemical class 0.000 claims description 9
- 150000003839 salts Chemical class 0.000 claims description 8
- 238000000691 measurement method Methods 0.000 claims description 7
- 239000000919 ceramic Substances 0.000 claims description 6
- 150000002739 metals Chemical class 0.000 claims description 6
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 5
- 229910052757 nitrogen Inorganic materials 0.000 claims description 5
- 150000001299 aldehydes Chemical class 0.000 claims description 4
- 229910000000 metal hydroxide Inorganic materials 0.000 claims description 4
- 150000004692 metal hydroxides Chemical class 0.000 claims description 4
- 229910052976 metal sulfide Inorganic materials 0.000 claims description 4
- 150000004767 nitrides Chemical class 0.000 claims description 4
- 239000002994 raw material Substances 0.000 claims description 4
- 238000010992 reflux Methods 0.000 claims description 4
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 3
- 229910021432 inorganic complex Inorganic materials 0.000 claims description 3
- 238000004811 liquid chromatography Methods 0.000 claims description 3
- 229910052749 magnesium Inorganic materials 0.000 claims description 3
- 239000011777 magnesium Substances 0.000 claims description 3
- 239000000956 alloy Substances 0.000 claims description 2
- 229910045601 alloy Inorganic materials 0.000 claims description 2
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 95
- 239000000047 product Substances 0.000 description 59
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 39
- 150000002989 phenols Chemical group 0.000 description 39
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 38
- 238000006243 chemical reaction Methods 0.000 description 30
- 239000007864 aqueous solution Substances 0.000 description 28
- 238000003756 stirring Methods 0.000 description 27
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 21
- 229920003986 novolac Polymers 0.000 description 20
- 239000000243 solution Substances 0.000 description 20
- 239000007787 solid Substances 0.000 description 19
- 239000007795 chemical reaction product Substances 0.000 description 17
- 238000001723 curing Methods 0.000 description 17
- RCHKEJKUUXXBSM-UHFFFAOYSA-N n-benzyl-2-(3-formylindol-1-yl)acetamide Chemical compound C12=CC=CC=C2C(C=O)=CN1CC(=O)NCC1=CC=CC=C1 RCHKEJKUUXXBSM-UHFFFAOYSA-N 0.000 description 17
- QGZKDVFQNNGYKY-UHFFFAOYSA-N ammonia Natural products N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 13
- WTDFFADXONGQOM-UHFFFAOYSA-N formaldehyde;hydrochloride Chemical compound Cl.O=C WTDFFADXONGQOM-UHFFFAOYSA-N 0.000 description 13
- 239000011230 binding agent Substances 0.000 description 12
- 238000010304 firing Methods 0.000 description 12
- 239000007789 gas Substances 0.000 description 11
- 238000004519 manufacturing process Methods 0.000 description 11
- 229920003987 resole Polymers 0.000 description 11
- 239000004202 carbamide Substances 0.000 description 10
- 150000001875 compounds Chemical class 0.000 description 10
- 238000002156 mixing Methods 0.000 description 10
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 9
- VKYKSIONXSXAKP-UHFFFAOYSA-N hexamethylenetetramine Chemical compound C1N(C2)CN3CN1CN2C3 VKYKSIONXSXAKP-UHFFFAOYSA-N 0.000 description 9
- 239000000126 substance Substances 0.000 description 8
- 239000000835 fiber Substances 0.000 description 7
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 6
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 6
- 239000000945 filler Substances 0.000 description 6
- 239000008187 granular material Substances 0.000 description 6
- 229910021529 ammonia Inorganic materials 0.000 description 5
- 238000010586 diagram Methods 0.000 description 5
- 229910001873 dinitrogen Inorganic materials 0.000 description 5
- 238000002474 experimental method Methods 0.000 description 5
- 239000011521 glass Substances 0.000 description 5
- 239000004312 hexamethylene tetramine Substances 0.000 description 5
- 235000010299 hexamethylene tetramine Nutrition 0.000 description 5
- 238000005259 measurement Methods 0.000 description 5
- 239000000377 silicon dioxide Substances 0.000 description 5
- 239000002904 solvent Substances 0.000 description 5
- 235000011114 ammonium hydroxide Nutrition 0.000 description 4
- 235000014633 carbohydrates Nutrition 0.000 description 4
- 150000001720 carbohydrates Chemical class 0.000 description 4
- 239000004927 clay Substances 0.000 description 4
- 229920001477 hydrophilic polymer Polymers 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- RLSSMJSEOOYNOY-UHFFFAOYSA-N m-cresol Chemical compound CC1=CC=CC(O)=C1 RLSSMJSEOOYNOY-UHFFFAOYSA-N 0.000 description 4
- QWVGKYWNOKOFNN-UHFFFAOYSA-N o-cresol Chemical compound CC1=CC=CC=C1O QWVGKYWNOKOFNN-UHFFFAOYSA-N 0.000 description 4
- IWDCLRJOBJJRNH-UHFFFAOYSA-N p-cresol Chemical compound CC1=CC=C(O)C=C1 IWDCLRJOBJJRNH-UHFFFAOYSA-N 0.000 description 4
- GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 description 4
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 description 3
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 3
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 3
- 238000005452 bending Methods 0.000 description 3
- 238000007664 blowing Methods 0.000 description 3
- 239000003085 diluting agent Substances 0.000 description 3
- 230000005484 gravity Effects 0.000 description 3
- 238000000227 grinding Methods 0.000 description 3
- IXCSERBJSXMMFS-UHFFFAOYSA-N hcl hcl Chemical compound Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 description 3
- 150000002484 inorganic compounds Chemical class 0.000 description 3
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 3
- 229920001568 phenolic resin Polymers 0.000 description 3
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Substances [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 3
- 239000002243 precursor Substances 0.000 description 3
- 229910010271 silicon carbide Inorganic materials 0.000 description 3
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 description 3
- 238000005245 sintering Methods 0.000 description 3
- 239000011343 solid material Substances 0.000 description 3
- 229920001187 thermosetting polymer Polymers 0.000 description 3
- QTWJRLJHJPIABL-UHFFFAOYSA-N 2-methylphenol;3-methylphenol;4-methylphenol Chemical compound CC1=CC=C(O)C=C1.CC1=CC=CC(O)=C1.CC1=CC=CC=C1O QTWJRLJHJPIABL-UHFFFAOYSA-N 0.000 description 2
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- ZRALSGWEFCBTJO-UHFFFAOYSA-N Guanidine Chemical compound NC(N)=N ZRALSGWEFCBTJO-UHFFFAOYSA-N 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 2
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 2
- 239000004952 Polyamide Substances 0.000 description 2
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- 229920002472 Starch Polymers 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- DIZPMCHEQGEION-UHFFFAOYSA-H aluminium sulfate (anhydrous) Chemical compound [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 description 2
- 239000012752 auxiliary agent Substances 0.000 description 2
- QVQLCTNNEUAWMS-UHFFFAOYSA-N barium oxide Chemical compound [Ba]=O QVQLCTNNEUAWMS-UHFFFAOYSA-N 0.000 description 2
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 2
- YXVFYQXJAXKLAK-UHFFFAOYSA-N biphenyl-4-ol Chemical compound C1=CC(O)=CC=C1C1=CC=CC=C1 YXVFYQXJAXKLAK-UHFFFAOYSA-N 0.000 description 2
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 2
- 229910052796 boron Inorganic materials 0.000 description 2
- 239000011449 brick Substances 0.000 description 2
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 2
- 238000011088 calibration curve Methods 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 239000004568 cement Substances 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 239000000084 colloidal system Substances 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 229930003836 cresol Natural products 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 230000001747 exhibiting effect Effects 0.000 description 2
- 235000013312 flour Nutrition 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 238000001879 gelation Methods 0.000 description 2
- 238000013007 heat curing Methods 0.000 description 2
- 238000004128 high performance liquid chromatography Methods 0.000 description 2
- 239000010903 husk Substances 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 description 2
- 239000000155 melt Substances 0.000 description 2
- 150000001247 metal acetylides Chemical class 0.000 description 2
- 125000001570 methylene group Chemical group [H]C([H])([*:1])[*:2] 0.000 description 2
- 235000010755 mineral Nutrition 0.000 description 2
- 239000011707 mineral Substances 0.000 description 2
- 238000000465 moulding Methods 0.000 description 2
- 229930014626 natural product Natural products 0.000 description 2
- 230000003287 optical effect Effects 0.000 description 2
- 235000006408 oxalic acid Nutrition 0.000 description 2
- 230000000737 periodic effect Effects 0.000 description 2
- 229910052697 platinum Inorganic materials 0.000 description 2
- 229920002647 polyamide Polymers 0.000 description 2
- 230000002265 prevention Effects 0.000 description 2
- 230000001681 protective effect Effects 0.000 description 2
- 229910052710 silicon Inorganic materials 0.000 description 2
- 239000002002 slurry Substances 0.000 description 2
- 239000010935 stainless steel Substances 0.000 description 2
- 229910001220 stainless steel Inorganic materials 0.000 description 2
- 239000008107 starch Substances 0.000 description 2
- 235000019698 starch Nutrition 0.000 description 2
- UBXAKNTVXQMEAG-UHFFFAOYSA-L strontium sulfate Chemical compound [Sr+2].[O-]S([O-])(=O)=O UBXAKNTVXQMEAG-UHFFFAOYSA-L 0.000 description 2
- 229920001169 thermoplastic Polymers 0.000 description 2
- 239000004416 thermosoftening plastic Substances 0.000 description 2
- UMGDCJDMYOKAJW-UHFFFAOYSA-N thiourea Chemical compound NC(N)=S UMGDCJDMYOKAJW-UHFFFAOYSA-N 0.000 description 2
- 238000002834 transmittance Methods 0.000 description 2
- 125000002256 xylenyl group Chemical class C1(C(C=CC=C1)C)(C)* 0.000 description 2
- 229910052984 zinc sulfide Inorganic materials 0.000 description 2
- VZXTWGWHSMCWGA-UHFFFAOYSA-N 1,3,5-triazine-2,4-diamine Chemical compound NC1=NC=NC(N)=N1 VZXTWGWHSMCWGA-UHFFFAOYSA-N 0.000 description 1
- INZDTEICWPZYJM-UHFFFAOYSA-N 1-(chloromethyl)-4-[4-(chloromethyl)phenyl]benzene Chemical compound C1=CC(CCl)=CC=C1C1=CC=C(CCl)C=C1 INZDTEICWPZYJM-UHFFFAOYSA-N 0.000 description 1
- IRPGOXJVTQTAAN-UHFFFAOYSA-N 2,2,3,3,3-pentafluoropropanal Chemical compound FC(F)(F)C(F)(F)C=O IRPGOXJVTQTAAN-UHFFFAOYSA-N 0.000 description 1
- OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 description 1
- JKFYKCYQEWQPTM-UHFFFAOYSA-N 2-azaniumyl-2-(4-fluorophenyl)acetate Chemical compound OC(=O)C(N)C1=CC=C(F)C=C1 JKFYKCYQEWQPTM-UHFFFAOYSA-N 0.000 description 1
- WUPHOULIZUERAE-UHFFFAOYSA-N 3-(oxolan-2-yl)propanoic acid Chemical compound OC(=O)CCC1CCCO1 WUPHOULIZUERAE-UHFFFAOYSA-N 0.000 description 1
- BTXXTMOWISPQSJ-UHFFFAOYSA-N 4,4,4-trifluorobutan-2-one Chemical compound CC(=O)CC(F)(F)F BTXXTMOWISPQSJ-UHFFFAOYSA-N 0.000 description 1
- BQACOLQNOUYJCE-FYZZASKESA-N Abietic acid Natural products CC(C)C1=CC2=CC[C@]3(C)[C@](C)(CCC[C@@]3(C)C(=O)O)[C@H]2CC1 BQACOLQNOUYJCE-FYZZASKESA-N 0.000 description 1
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 1
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 1
- 229910018626 Al(OH) Inorganic materials 0.000 description 1
- 239000005995 Aluminium silicate Substances 0.000 description 1
- KLZUFWVZNOTSEM-UHFFFAOYSA-K Aluminum fluoride Inorganic materials F[Al](F)F KLZUFWVZNOTSEM-UHFFFAOYSA-K 0.000 description 1
- 229910052580 B4C Inorganic materials 0.000 description 1
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- 235000013162 Cocos nucifera Nutrition 0.000 description 1
- 244000060011 Cocos nucifera Species 0.000 description 1
- JJLJMEJHUUYSSY-UHFFFAOYSA-L Copper hydroxide Chemical compound [OH-].[OH-].[Cu+2] JJLJMEJHUUYSSY-UHFFFAOYSA-L 0.000 description 1
- 239000005750 Copper hydroxide Substances 0.000 description 1
- 239000001856 Ethyl cellulose Substances 0.000 description 1
- ZZSNKZQZMQGXPY-UHFFFAOYSA-N Ethyl cellulose Chemical compound CCOCC1OC(OC)C(OCC)C(OCC)C1OC1C(O)C(O)C(OC)C(CO)O1 ZZSNKZQZMQGXPY-UHFFFAOYSA-N 0.000 description 1
- MBMLMWLHJBBADN-UHFFFAOYSA-N Ferrous sulfide Chemical compound [Fe]=S MBMLMWLHJBBADN-UHFFFAOYSA-N 0.000 description 1
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 1
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 1
- 238000004566 IR spectroscopy Methods 0.000 description 1
- 239000005909 Kieselgur Substances 0.000 description 1
- 229920000877 Melamine resin Polymers 0.000 description 1
- CHJJGSNFBQVOTG-UHFFFAOYSA-N N-methyl-guanidine Natural products CNC(N)=N CHJJGSNFBQVOTG-UHFFFAOYSA-N 0.000 description 1
- 229910002651 NO3 Inorganic materials 0.000 description 1
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 1
- 229920000784 Nomex Polymers 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- 229930040373 Paraformaldehyde Natural products 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- 229920000297 Rayon Polymers 0.000 description 1
- 241000220317 Rosa Species 0.000 description 1
- 229910052581 Si3N4 Inorganic materials 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 229910021607 Silver chloride Inorganic materials 0.000 description 1
- 229910021612 Silver iodide Inorganic materials 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- NRTOMJZYCJJWKI-UHFFFAOYSA-N Titanium nitride Chemical compound [Ti]#N NRTOMJZYCJJWKI-UHFFFAOYSA-N 0.000 description 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
- 239000005083 Zinc sulfide Substances 0.000 description 1
- 229910026551 ZrC Inorganic materials 0.000 description 1
- SMEGJBVQLJJKKX-HOTMZDKISA-N [(2R,3S,4S,5R,6R)-5-acetyloxy-3,4,6-trihydroxyoxan-2-yl]methyl acetate Chemical compound CC(=O)OC[C@@H]1[C@H]([C@@H]([C@H]([C@@H](O1)O)OC(=O)C)O)O SMEGJBVQLJJKKX-HOTMZDKISA-N 0.000 description 1
- TZHYBRCGYCPGBQ-UHFFFAOYSA-N [B].[N] Chemical compound [B].[N] TZHYBRCGYCPGBQ-UHFFFAOYSA-N 0.000 description 1
- OTCHGXYCWNXDOA-UHFFFAOYSA-N [C].[Zr] Chemical compound [C].[Zr] OTCHGXYCWNXDOA-UHFFFAOYSA-N 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 239000003082 abrasive agent Substances 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 239000011358 absorbing material Substances 0.000 description 1
- 229910052946 acanthite Inorganic materials 0.000 description 1
- 229940081735 acetylcellulose Drugs 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000003377 acid catalyst Substances 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 239000004840 adhesive resin Substances 0.000 description 1
- 229920006223 adhesive resin Polymers 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 1
- ILRRQNADMUWWFW-UHFFFAOYSA-K aluminium phosphate Chemical compound O1[Al]2OP1(=O)O2 ILRRQNADMUWWFW-UHFFFAOYSA-K 0.000 description 1
- 235000011126 aluminium potassium sulphate Nutrition 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 125000003368 amide group Chemical group 0.000 description 1
- 125000003277 amino group Chemical group 0.000 description 1
- 229910000410 antimony oxide Inorganic materials 0.000 description 1
- 239000010425 asbestos Substances 0.000 description 1
- 239000010426 asphalt Substances 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- CFJRGWXELQQLSA-UHFFFAOYSA-N azanylidyneniobium Chemical compound [Nb]#N CFJRGWXELQQLSA-UHFFFAOYSA-N 0.000 description 1
- SKKMWRVAJNPLFY-UHFFFAOYSA-N azanylidynevanadium Chemical compound [V]#N SKKMWRVAJNPLFY-UHFFFAOYSA-N 0.000 description 1
- 238000010533 azeotropic distillation Methods 0.000 description 1
- WDIHJSXYQDMJHN-UHFFFAOYSA-L barium chloride Chemical compound [Cl-].[Cl-].[Ba+2] WDIHJSXYQDMJHN-UHFFFAOYSA-L 0.000 description 1
- 229910001626 barium chloride Inorganic materials 0.000 description 1
- RQPZNWPYLFFXCP-UHFFFAOYSA-L barium dihydroxide Chemical compound [OH-].[OH-].[Ba+2] RQPZNWPYLFFXCP-UHFFFAOYSA-L 0.000 description 1
- 229910001863 barium hydroxide Inorganic materials 0.000 description 1
- CJDPJFRMHVXWPT-UHFFFAOYSA-N barium sulfide Chemical compound [S-2].[Ba+2] CJDPJFRMHVXWPT-UHFFFAOYSA-N 0.000 description 1
- WAKZZMMCDILMEF-UHFFFAOYSA-H barium(2+);diphosphate Chemical compound [Ba+2].[Ba+2].[Ba+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O WAKZZMMCDILMEF-UHFFFAOYSA-H 0.000 description 1
- AYJRCSIUFZENHW-DEQYMQKBSA-L barium(2+);oxomethanediolate Chemical compound [Ba+2].[O-][14C]([O-])=O AYJRCSIUFZENHW-DEQYMQKBSA-L 0.000 description 1
- 239000011324 bead Substances 0.000 description 1
- 239000000440 bentonite Substances 0.000 description 1
- 229910000278 bentonite Inorganic materials 0.000 description 1
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
- 229910052614 beryl Inorganic materials 0.000 description 1
- INAHAJYZKVIDIZ-UHFFFAOYSA-N boron carbide Chemical compound B12B3B4C32B41 INAHAJYZKVIDIZ-UHFFFAOYSA-N 0.000 description 1
- 229910052810 boron oxide Inorganic materials 0.000 description 1
- QCUOBSQYDGUHHT-UHFFFAOYSA-L cadmium sulfate Chemical compound [Cd+2].[O-]S([O-])(=O)=O QCUOBSQYDGUHHT-UHFFFAOYSA-L 0.000 description 1
- 229910000331 cadmium sulfate Inorganic materials 0.000 description 1
- 229910052980 cadmium sulfide Inorganic materials 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- WUKWITHWXAAZEY-UHFFFAOYSA-L calcium difluoride Chemical compound [F-].[F-].[Ca+2] WUKWITHWXAAZEY-UHFFFAOYSA-L 0.000 description 1
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 1
- 229910001634 calcium fluoride Inorganic materials 0.000 description 1
- 239000000920 calcium hydroxide Substances 0.000 description 1
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 1
- 239000001506 calcium phosphate Substances 0.000 description 1
- 229910000389 calcium phosphate Inorganic materials 0.000 description 1
- 235000011010 calcium phosphates Nutrition 0.000 description 1
- HHSPVTKDOHQBKF-UHFFFAOYSA-J calcium;magnesium;dicarbonate Chemical compound [Mg+2].[Ca+2].[O-]C([O-])=O.[O-]C([O-])=O HHSPVTKDOHQBKF-UHFFFAOYSA-J 0.000 description 1
- 239000003990 capacitor Substances 0.000 description 1
- 150000001719 carbohydrate derivatives Chemical class 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 238000003763 carbonization Methods 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 229920002301 cellulose acetate Polymers 0.000 description 1
- 229910001567 cementite Inorganic materials 0.000 description 1
- 235000013339 cereals Nutrition 0.000 description 1
- TYAVIWGEVOBWDZ-UHFFFAOYSA-K cerium(3+);phosphate Chemical compound [Ce+3].[O-]P([O-])([O-])=O TYAVIWGEVOBWDZ-UHFFFAOYSA-K 0.000 description 1
- 239000012295 chemical reaction liquid Substances 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- XHFVDZNDZCNTLT-UHFFFAOYSA-H chromium(3+);tricarbonate Chemical compound [Cr+3].[Cr+3].[O-]C([O-])=O.[O-]C([O-])=O.[O-]C([O-])=O XHFVDZNDZCNTLT-UHFFFAOYSA-H 0.000 description 1
- 229910021446 cobalt carbonate Inorganic materials 0.000 description 1
- GVPFVAHMJGGAJG-UHFFFAOYSA-L cobalt dichloride Chemical compound [Cl-].[Cl-].[Co+2] GVPFVAHMJGGAJG-UHFFFAOYSA-L 0.000 description 1
- ZOTKGJBKKKVBJZ-UHFFFAOYSA-L cobalt(2+);carbonate Chemical compound [Co+2].[O-]C([O-])=O ZOTKGJBKKKVBJZ-UHFFFAOYSA-L 0.000 description 1
- INPLXZPZQSLHBR-UHFFFAOYSA-N cobalt(2+);sulfide Chemical compound [S-2].[Co+2] INPLXZPZQSLHBR-UHFFFAOYSA-N 0.000 description 1
- 239000000571 coke Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000000748 compression moulding Methods 0.000 description 1
- 239000004567 concrete Substances 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 239000004035 construction material Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 229910001956 copper hydroxide Inorganic materials 0.000 description 1
- ORTQZVOHEJQUHG-UHFFFAOYSA-L copper(II) chloride Chemical compound Cl[Cu]Cl ORTQZVOHEJQUHG-UHFFFAOYSA-L 0.000 description 1
- OMZSGWSJDCOLKM-UHFFFAOYSA-N copper(II) sulfide Chemical compound [S-2].[Cu+2] OMZSGWSJDCOLKM-UHFFFAOYSA-N 0.000 description 1
- GBRBMTNGQBKBQE-UHFFFAOYSA-L copper;diiodide Chemical compound I[Cu]I GBRBMTNGQBKBQE-UHFFFAOYSA-L 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 239000003431 cross linking reagent Substances 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 230000018044 dehydration Effects 0.000 description 1
- 238000006297 dehydration reaction Methods 0.000 description 1
- 230000003111 delayed effect Effects 0.000 description 1
- 239000005548 dental material Substances 0.000 description 1
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 description 1
- JKWMSGQKBLHBQQ-UHFFFAOYSA-N diboron trioxide Chemical compound O=BOB=O JKWMSGQKBLHBQQ-UHFFFAOYSA-N 0.000 description 1
- QGBSISYHAICWAH-UHFFFAOYSA-N dicyandiamide Chemical compound NC(N)=NC#N QGBSISYHAICWAH-UHFFFAOYSA-N 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 150000004683 dihydrates Chemical class 0.000 description 1
- SWSQBOPZIKWTGO-UHFFFAOYSA-N dimethylaminoamidine Natural products CN(C)C(N)=N SWSQBOPZIKWTGO-UHFFFAOYSA-N 0.000 description 1
- KZHJGOXRZJKJNY-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Si]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O KZHJGOXRZJKJNY-UHFFFAOYSA-N 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 239000010459 dolomite Substances 0.000 description 1
- 229910000514 dolomite Inorganic materials 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000003480 eluent Substances 0.000 description 1
- 229920001249 ethyl cellulose Polymers 0.000 description 1
- 235000019325 ethyl cellulose Nutrition 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 239000010433 feldspar Substances 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 239000008098 formaldehyde solution Substances 0.000 description 1
- 239000002783 friction material Substances 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- XLXSAKCOAKORKW-AQJXLSMYSA-N gonadorelin Chemical compound C([C@@H](C(=O)NCC(=O)N[C@@H](CC(C)C)C(=O)N[C@@H](CCCNC(N)=N)C(=O)N1[C@@H](CCC1)C(=O)NCC(N)=O)NC(=O)[C@H](CO)NC(=O)[C@H](CC=1C2=CC=CC=C2NC=1)NC(=O)[C@H](CC=1N=CNC=1)NC(=O)[C@H]1NC(=O)CC1)C1=CC=C(O)C=C1 XLXSAKCOAKORKW-AQJXLSMYSA-N 0.000 description 1
- 238000009499 grossing Methods 0.000 description 1
- 229910052735 hafnium Inorganic materials 0.000 description 1
- WHJFNYXPKGDKBB-UHFFFAOYSA-N hafnium;methane Chemical compound C.[Hf] WHJFNYXPKGDKBB-UHFFFAOYSA-N 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- 229910052595 hematite Inorganic materials 0.000 description 1
- 239000011019 hematite Substances 0.000 description 1
- 238000007731 hot pressing Methods 0.000 description 1
- 229910000041 hydrogen chloride Inorganic materials 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 1
- BDAGIHXWWSANSR-NJFSPNSNSA-N hydroxyformaldehyde Chemical compound O[14CH]=O BDAGIHXWWSANSR-NJFSPNSNSA-N 0.000 description 1
- 229910003437 indium oxide Inorganic materials 0.000 description 1
- PJXISJQVUVHSOJ-UHFFFAOYSA-N indium(iii) oxide Chemical compound [O-2].[O-2].[O-2].[In+3].[In+3] PJXISJQVUVHSOJ-UHFFFAOYSA-N 0.000 description 1
- 239000012770 industrial material Substances 0.000 description 1
- 239000011810 insulating material Substances 0.000 description 1
- 239000012212 insulator Substances 0.000 description 1
- 229910052741 iridium Inorganic materials 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 1
- FBAFATDZDUQKNH-UHFFFAOYSA-M iron chloride Chemical compound [Cl-].[Fe] FBAFATDZDUQKNH-UHFFFAOYSA-M 0.000 description 1
- 235000014413 iron hydroxide Nutrition 0.000 description 1
- 229910000398 iron phosphate Inorganic materials 0.000 description 1
- WBJZTOZJJYAKHQ-UHFFFAOYSA-K iron(3+) phosphate Chemical compound [Fe+3].[O-]P([O-])([O-])=O WBJZTOZJJYAKHQ-UHFFFAOYSA-K 0.000 description 1
- LIKBJVNGSGBSGK-UHFFFAOYSA-N iron(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Fe+3].[Fe+3] LIKBJVNGSGBSGK-UHFFFAOYSA-N 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- NCNCGGDMXMBVIA-UHFFFAOYSA-L iron(ii) hydroxide Chemical compound [OH-].[OH-].[Fe+2] NCNCGGDMXMBVIA-UHFFFAOYSA-L 0.000 description 1
- ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Chemical compound OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 239000004922 lacquer Substances 0.000 description 1
- PIJPYDMVFNTHIP-UHFFFAOYSA-L lead sulfate Chemical compound [PbH4+2].[O-]S([O-])(=O)=O PIJPYDMVFNTHIP-UHFFFAOYSA-L 0.000 description 1
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 1
- 239000001095 magnesium carbonate Substances 0.000 description 1
- 229910000021 magnesium carbonate Inorganic materials 0.000 description 1
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 1
- 239000000347 magnesium hydroxide Substances 0.000 description 1
- 229910001862 magnesium hydroxide Inorganic materials 0.000 description 1
- HCWCAKKEBCNQJP-UHFFFAOYSA-N magnesium orthosilicate Chemical compound [Mg+2].[Mg+2].[O-][Si]([O-])([O-])[O-] HCWCAKKEBCNQJP-UHFFFAOYSA-N 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
- GVALZJMUIHGIMD-UHFFFAOYSA-H magnesium phosphate Chemical compound [Mg+2].[Mg+2].[Mg+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O GVALZJMUIHGIMD-UHFFFAOYSA-H 0.000 description 1
- 239000004137 magnesium phosphate Substances 0.000 description 1
- 229960002261 magnesium phosphate Drugs 0.000 description 1
- 229910000157 magnesium phosphate Inorganic materials 0.000 description 1
- 235000010994 magnesium phosphates Nutrition 0.000 description 1
- 239000000391 magnesium silicate Substances 0.000 description 1
- 229910052919 magnesium silicate Inorganic materials 0.000 description 1
- 235000019792 magnesium silicate Nutrition 0.000 description 1
- 229910052943 magnesium sulfate Inorganic materials 0.000 description 1
- 235000019341 magnesium sulphate Nutrition 0.000 description 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 239000012567 medical material Substances 0.000 description 1
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 description 1
- 238000002074 melt spinning Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- 239000011859 microparticle Substances 0.000 description 1
- 239000012778 molding material Substances 0.000 description 1
- 229910000476 molybdenum oxide Inorganic materials 0.000 description 1
- 239000011823 monolithic refractory Substances 0.000 description 1
- 229910052901 montmorillonite Inorganic materials 0.000 description 1
- 229910052863 mullite Inorganic materials 0.000 description 1
- 229910021382 natural graphite Inorganic materials 0.000 description 1
- 230000003472 neutralizing effect Effects 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 239000012299 nitrogen atmosphere Substances 0.000 description 1
- 239000004763 nomex Substances 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- 238000000879 optical micrograph Methods 0.000 description 1
- 150000007530 organic bases Chemical class 0.000 description 1
- 229910052762 osmium Inorganic materials 0.000 description 1
- VTRUBDSFZJNXHI-UHFFFAOYSA-N oxoantimony Chemical compound [Sb]=O VTRUBDSFZJNXHI-UHFFFAOYSA-N 0.000 description 1
- PQQKPALAQIIWST-UHFFFAOYSA-N oxomolybdenum Chemical compound [Mo]=O PQQKPALAQIIWST-UHFFFAOYSA-N 0.000 description 1
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- 229920002866 paraformaldehyde Polymers 0.000 description 1
- 238000005192 partition Methods 0.000 description 1
- 239000005011 phenolic resin Substances 0.000 description 1
- 125000002467 phosphate group Chemical group [H]OP(=O)(O[H])O[*] 0.000 description 1
- 239000010665 pine oil Substances 0.000 description 1
- 239000011297 pine tar Substances 0.000 description 1
- 229940068124 pine tar Drugs 0.000 description 1
- CLSUSRZJUQMOHH-UHFFFAOYSA-L platinum dichloride Chemical compound Cl[Pt]Cl CLSUSRZJUQMOHH-UHFFFAOYSA-L 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- 229920002037 poly(vinyl butyral) polymer Polymers 0.000 description 1
- 229920006350 polyacrylonitrile resin Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920002689 polyvinyl acetate Polymers 0.000 description 1
- 239000011118 polyvinyl acetate Substances 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 239000001103 potassium chloride Substances 0.000 description 1
- 235000011164 potassium chloride Nutrition 0.000 description 1
- 239000012254 powdered material Substances 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 238000010298 pulverizing process Methods 0.000 description 1
- 239000008262 pumice Substances 0.000 description 1
- 229910052903 pyrophyllite Inorganic materials 0.000 description 1
- 239000002964 rayon Substances 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 229910052703 rhodium Inorganic materials 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 229910052895 riebeckite Inorganic materials 0.000 description 1
- 239000011435 rock Substances 0.000 description 1
- 238000010079 rubber tapping Methods 0.000 description 1
- 229910052707 ruthenium Inorganic materials 0.000 description 1
- 238000005070 sampling Methods 0.000 description 1
- 239000013049 sediment Substances 0.000 description 1
- 238000010008 shearing Methods 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 description 1
- 229910052851 sillimanite Inorganic materials 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000010944 silver (metal) Substances 0.000 description 1
- ADZWSOLPGZMUMY-UHFFFAOYSA-M silver bromide Chemical compound [Ag]Br ADZWSOLPGZMUMY-UHFFFAOYSA-M 0.000 description 1
- 229940096017 silver fluoride Drugs 0.000 description 1
- 229940045105 silver iodide Drugs 0.000 description 1
- HKZLPVFGJNLROG-UHFFFAOYSA-M silver monochloride Chemical compound [Cl-].[Ag+] HKZLPVFGJNLROG-UHFFFAOYSA-M 0.000 description 1
- REYHXKZHIMGNSE-UHFFFAOYSA-M silver monofluoride Chemical compound [F-].[Ag+] REYHXKZHIMGNSE-UHFFFAOYSA-M 0.000 description 1
- 229940056910 silver sulfide Drugs 0.000 description 1
- XUARKZBEFFVFRG-UHFFFAOYSA-N silver sulfide Chemical compound [S-2].[Ag+].[Ag+] XUARKZBEFFVFRG-UHFFFAOYSA-N 0.000 description 1
- 235000011127 sodium aluminium sulphate Nutrition 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 239000011973 solid acid Substances 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 229910000018 strontium carbonate Inorganic materials 0.000 description 1
- 235000000346 sugar Nutrition 0.000 description 1
- YPMOSINXXHVZIL-UHFFFAOYSA-N sulfanylideneantimony Chemical compound [Sb]=S YPMOSINXXHVZIL-UHFFFAOYSA-N 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 125000001391 thioamide group Chemical group 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 150000004992 toluidines Chemical class 0.000 description 1
- QORWJWZARLRLPR-UHFFFAOYSA-H tricalcium bis(phosphate) Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O QORWJWZARLRLPR-UHFFFAOYSA-H 0.000 description 1
- 239000013638 trimer Substances 0.000 description 1
- MTPVUVINMAGMJL-UHFFFAOYSA-N trimethyl(1,1,2,2,2-pentafluoroethyl)silane Chemical compound C[Si](C)(C)C(F)(F)C(F)(F)F MTPVUVINMAGMJL-UHFFFAOYSA-N 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- UONOETXJSWQNOL-UHFFFAOYSA-N tungsten carbide Chemical compound [W+]#[C-] UONOETXJSWQNOL-UHFFFAOYSA-N 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000003643 water by type Substances 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
- LRXTYHSAJDENHV-UHFFFAOYSA-H zinc phosphate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O LRXTYHSAJDENHV-UHFFFAOYSA-H 0.000 description 1
- 229910000165 zinc phosphate Inorganic materials 0.000 description 1
- DRDVZXDWVBGGMH-UHFFFAOYSA-N zinc;sulfide Chemical compound [S-2].[Zn+2] DRDVZXDWVBGGMH-UHFFFAOYSA-N 0.000 description 1
- 229910052845 zircon Inorganic materials 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
- ZVWKZXLXHLZXLS-UHFFFAOYSA-N zirconium nitride Chemical compound [Zr]#N ZVWKZXLXHLZXLS-UHFFFAOYSA-N 0.000 description 1
- 229910001928 zirconium oxide Inorganic materials 0.000 description 1
- GFQYVLUOOAAOGM-UHFFFAOYSA-N zirconium(iv) silicate Chemical compound [Zr+4].[O-][Si]([O-])([O-])[O-] GFQYVLUOOAAOGM-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Compositions Of Oxide Ceramics (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Description
æ¬çºæã¯ç¡æ©è³ªææç²æ«ãå«æããçµæç©ã«é¢
ãããããã«è©³ããã¯ãç¡æ©è³ªææç²æ«ãšå ±ã«ã
æµãç¹æ§ãè¯å¥œã§äžã€åå¿æ§ãæãããèªäœã§ã
ãããã¯çš®ã ã®ç¡æ©è³ªææç²æ«ãšæ··åããŠåªãã
æ圢æ§ããã³çååçã瀺ãæ°èŠãªç²ç¶ãªããç²
æ«ç¶å«çªçŽ ããšããŒã«ã»ã¢ã«ãããæš¹èãå«æ
ãããããŠåªããæ©æ¢°çæ§è³ªçã®çš®ã ã®åªããæ§
質ã瀺ãã»ã©ããã¯ã¹çã®ç¡æ©è³ªæ圢äœã補é ã
ãã«å¥œé©ãªãåªããæ圢æ§ãæããçµæç©ã«é¢ã
ãã åŸæ¥ãããšããŒã«ã»ã¢ã«ãããæš¹èã®ä»£è¡šçãª
ãã®ãšããŠããã©ãã¯æš¹èãšã¬ãŸãŒã«æš¹èãšãç¥
ãããŠãããããã©ãã¯æš¹èã¯ãéåžžãããšããŒ
ã«å¯Ÿãã«ã ã¢ã«ãããã®ã¢ã«æ¯ãäŸãã°ïŒå¯Ÿ0.7
ã0.9ãšãªããããªããšããŒã«éå°ã®æ¡ä»¶äžã§ã
äŸãã°ã·ãŠãŠé žã®åŠãé žè§Šåªã®ååšäžïŒéåžž0.2
ãïŒïŒ ïŒã§ããšããŒã«ãšãã«ããªã³ãšãåå¿ãã
ãããšã«ãã€ãŠè£œé ããããããããªæ¹æ³ã§åŸã
ããããã©ãã¯æš¹èã¯ãããšããŒã«ãäž»ãšããŠã¡
ãã¬ã³åºã«ãã€ãŠçµåãããïŒãïŒéäœãäž»æå
ããªããéé¢ã¡ãããŒã«åºãæ®ãã©å«æãããåŸ
ã€ãŠããèªäœã§ã¯èªå·±æ¶æ©æ§ãæãããç±å¯å¡æ§
ãæããã ããã§ããã©ãã¯æš¹èã¯ãäŸãã°ãããµã¡ãã¬
ã³ããã©ãã³ïŒãããµãã³ïŒã®åŠãããèªäœãã«
ã ã¢ã«ãããçºçå€ã§ãããšå ±ã«ææ©å¡©åºïŒè§Š
åªïŒçºçå€ã§ããæ¶æ©å€ãšå ç±äžã§åå¿ããã
ããåã¯äŸãã°åºäœé žè§Šåªãšãã©ãã«ã ã¢ã«ãã
ãçãšæ··åããå ç±åå¿ãããããšã«ãã€ãŠã硬
åæš¹èãšããããšãã§ããã ããã©ãã¯æš¹èã¯ç²æ«ç¶ã§åæ±ãã容æã§ãã
ããç¡æ©è³ªææç²æ«ãå€éã«å«ãæ圢äœãå ç±ç¡¬
åãããéæ圢äœã®è¡šé¢ããå éšã«åã€ãŠç¡¬åå
å¿ãé²è¡ãããã°ãã°å éšãå åã«ç¡¬åããŠããª
ã硬åç©ãäžããããŸããã®ããããã®ãããªç¡¬
åç©ãããã«é«æž©åºŠã«å ç±ããŠçŒæã«ä»ããšãã«
ã¯ãå éšã«ãããŠã¬ã¹ãçºçããŠæ圢åã«äºè£ã
ã¬ã¹ã¶ãããçããçŒæãé²ãã«ã€ããŠãã®äºè£
ãã¬ã¹ã¶ãããæŽã«é¡èãšãªããæºè¶³ãªå質ã®ç¡
æ©è³ªæ圢äœã補é ããããšã¯éåžžã«å°é£ã§ããã ãŸããã¬ãŸãŒã«æš¹èã¯é垞溶液ãšããŠäŸçµŠãã
åŸã€ãŠãè±æº¶åªãããèªäœã§æ圢åãšããããšã¯
è±æº¶åªã®éã²ã«ååå¿ãæ¥æ¿ã«é²è¡ãçºæ³¡ããã®
ã§éåžžã«å°é£ã§ããããã®ãããå å¡«ç©è³ªãçšã
ãŠè±æº¶åªããŠæ圢ããããšãæ®éè¡ãªãããŠã
ããç¡æ©è³ªææç²æ«ãçšããå Žåã«ã¯ããæ è±æº¶
åªãæ¯èŒç容æã«è¡ãªããããããããªãããã
ã®ãããªæ圢åãå ç±ããŠã硬åãããã¯çŒæã«
ä»ããšãã«ã¯äŸç¶ãšããŠã²ã«ååå¿ãæ¥æ¿ã«é²è¡
ãããããäžèšããã©ãã¯æš¹èã®å Žåãšåæ§ã«ã¬
ã¹ã¶ãããäºè£ãçãã匷床ãããã¯ç¡¬åºŠã®ç¹ã§
æºè¶³ãªå質ã®ç¡æ©è³ªæ圢äœã補é ããããšã¯éåžž
ã«å°é£ã§ããã ãŸããæ¯èŒçè¿å¹Žã«è³ã€ãŠãããã©ãã¯æš¹èã
é«æž©äžã§å ç±ããŠå¯æãçž®å床ã®å€§ããªãã®ã
åŸãããã粟補ããŠäœçž®åç©ãåé¢ãé€å»ããŠã
ãšããŒã«åºãïŒã10åã¡ãã¬ã³åºã§çµåãããæ¯
èŒçé«çž®åäœãåŸããããå ç±æº¶è玡糞ããŠãã
ã©ãã¯æš¹èç¹ç¶ã圢æããããã®å¡©é žã»ãã«ã ã¢
ã«ãããæ··å氎溶液äžã«æµžæŒ¬ããŠã宀枩ããåŸã
ã«å æž©ããŠé·æéãããŠè©²ç¹ç¶ã®å€éšãã硬åå
å¿ãé²è¡ãããããšã«ãã硬åããã©ãã¯æš¹èç¹
ç¶ã補é ããæ¹æ³ãææ¡ãããïŒç¹å ¬æ48â
11284å·ïŒã ããããªãããäžèšã®åŠãããŠè£œé ãã硬åã
ãã©ãã¯ç¹ç¶ãæªæåã¯ç²ç ãããã®ã¯é«äŸ¡ãªã
ã®ãšãªãã°ããã§ãªããæ圢ææãšããŠæµãç¹æ§
ã®ããç²ç¶åã¯ç²æ«ç¶ã®ãã®ãšããããšãã§ããª
ãã®ã§è©²ç¹ç¶ãåäžã«åæ£ããæåäœã補é ãã
ããšã¯å°é£ã§ããã ãŸãè¿å¹Žã«ããã€ãŠãããšããŒã«é¡ãšãã«ã ã¢
ã«ããããšãå°ããšãå«çªçŽ ç³»ååç©ã®ååšäžã§
åå¿ãããŠåŸãããçž®åç©ã«èŠªæ°Žæ§é«ååååç©
ãæ·»å ããåå¿ãããŠç²ç¶ãªããç²æ«ç¶æš¹èã補
é ããæ¹æ³ãçºè¡šãããŠãããïŒç¹å ¬æ53â
42077å·ïŒããã®æ¹æ³ã§åŸãããæš¹èã®éã²ã«åç©
ã¯çŽïŒãïŒïŒ ãšããå€éã®éé¢ããšããŒã«ãå«æ
ãïŒåå®æœäŸïŒãïŒïŒããã®ã²ã«åç©ïŒåå®æœäŸ
ïŒïŒã¯æ¥µããŠç¡¬ãéåå¿æ§æš¹èãšãªãã°ããã§ãª
ãã芪氎æ§é«ååååç©ãå«æããããã®ããã
ããå å¡«å€ãšããŠçšããŠåŸãããæ圢åã硬åã
ããã¯çŒæããŠåŸãããç¡æ©è³ªæ圢äœã«äºè£ãã¬
ã¹ã¶ãããçããæ¬ ç¹ãããã ããã«ãããšããŒã«ãšãã«ã ã¢ã«ããããå¡©åº
æ§æ°Žæº¶æ¶²äžã§åå¿ãããŠåŸããããã¬ããªããŒã
ä¿è·ã³ãã€ããšæ··åããé žæ§äžã§äžæŽ»æ§åºåœ¢ããŒ
ãºç¶ã«ååºãããæ¹æ³ãå ¬ç¥ã§ãããïŒç¹å ¬æ51
â13491å·ïŒãããã¯æè¬ã¬ãŸãŒã«æš¹è硬åç©ã«çž
åœããåå¿æ§ãæããããã®äžå¡©é¡ãé žããã®ä»
ä¿è·ã³ãã€ããå«æããããã«åæ§ã«ãããå å¡«
å€ãšããŠçšããŠåŸãããæ圢åã硬åãããã¯çŒ
æããŠåŸãããç¡æ©è³ªæ圢äœã«äºè£ãã¬ã¹ã¶ãã
ãçããæ¬ ç¹ãããã äžèšã®åŠããåŸæ¥ããšããŒã«ã»ã¢ã«ãããæš¹è
ãæ圢åã®å å¡«å€ãšããŠäœ¿çšããè©Šã¿ã¯ãªãããŠ
ããããæ圢åã®å å¡«å€ãšããŠèŠããšãããšããŒ
ã«ã»ã¢ã«ãããæš¹èãå å¡«å€ã«é©ãã圢ç¶ããã
ã¯åœ¢æ ã®ãã®ãšããŠååŸããããšèªäœã第ïŒã«å°
é£ã§ããããŸã硬åãããã¯çŒæã®éã«æ圢åã«
察ãæãŸãããªã圱é¿ãäžããç©è³ªãå«æãããš
ããåé¡ãæããŠããã æ¬çºæè ãã¯ãå ã«äžèšã®åŠãæ¬ ç¹ãæããªã
æ°èŠãªå«çªçŽ ããšããŒã«ã»ã¢ã«ãããæš¹èã®ç²ç¶
ãªããç²æ«ç¶äœããã³ãã®è£œé æ¹æ³ãæäŸããã ããæ ãæ¬çºæã®ç®çã¯ãæ°èŠãªç²ç¶ãªããç²
æ«ç¶å«çªçŽ æš¹èãšç¡æ©è³ªææç²æ«ãšãå«æããŠæ
ãçµæç©ãæäŸããããšã«ããã æ¬çºæã®ä»ã®ç®çã¯ãç²ç¶ãªããç²æ«ç¶ã§ãã€
ãŠæµãç¹æ§ãè¯å¥œãªç²ç¶ãªããç²æ«ç¶å«çªçŽ æš¹è
ã®å°ããå²åããç¡æ©è³ªææç²äœã®å€§ããªå²åãš
å ±ã«å«æãããæ圢æ§ã®è¯å¥œãªçµæç©ãæäŸãã
ããšã«ããã æ¬çºæã®æŽã«ä»ã®ç®çã¯ãããåç¬ã§åã¯ä»ã®
æš¹èãšã®åå¿æ§ãæããç²ç¶ãªããç²æ«ç¶å«çªçŽ
æš¹èãçšããããšã«ãã€ãŠã硬åãããã¯çŒæã«
ãã€ãŠäºè£ãã¬ã¹ã¶ãããå°ãªãäžã€å éšãšå€éš
ãšã§å質ããã®æ®ãã©ãªãå質ãªç¡æ©è³ªæ圢äœã
äžãåŸãçµæç©ãæäŸããããšã«ããã æ¬çºæã®æŽã«ä»ã®ç®çã¯ãåªããè¡ææ§ã®åŠã
æ©æ¢°çæ§è³ªãæããããã¯åªããé»æ°çç¹æ§ã瀺
ãç¡æ©è³ªæ圢äœãäžãããçµæç©ãæäŸããããš
ã«ããã æ¬çºæã®æŽã«ä»ã®ç®çã¯ãåªããæ©æ¢°çæ§è³ªã
æããããã¯åªããèç±æ§ãæºåç¹æ§ãããã¯è
ååŠè¬åæ§ã瀺ãç¡æ©è³ªæ圢äœãäžãããçµæç©
ãæäŸããããšã«ããã æ¬çºæã®æŽã«ä»ã®ç®çããã³å©ç¹ã¯ä»¥äžã®èª¬æ
ããæãããšãªãã æ¬çºæã®ãããç®çããã³å©ç¹ã¯ãæ¬çºæã«ã
ãã°ã (1) ããšããŒã«é¡ãå°ããšãïŒåã®æŽ»æ§æ°ŽçŽ ãæ
ããå«çªçŽ ååç©ããã³ã¢ã«ããããšã®çž®åç©
ããæãç²ç¶ãªããç²æ«ç¶æš¹èã§ãã€ãŠã (A) 該ç²ç¶ãªããç²æ«ç¶æš¹èã¯ç²åŸ0.1ã100ã
ã¯ãã³ã®çç¶äžæ¬¡ç²åããã³ãã®äºæ¬¡åéç©
ãå«æãããã㊠(B) 該暹èã®KBré å€æ³ã«ããèµ€å€ç·åžåã¹ã
ã¯ãã«ã«ãããŠã 1450ã1500cm-1ã®ç¯å²ã®æã倧ããªåžå匷
床ã1450ã1500ããã㊠960ã1020cm-1ã®ç¯å²ã®æã倧ããªåžå匷
床ã960ã1020ã ã§è¡šãããå Žåã 960ã1020ïŒïŒ€1450ã1500ïŒ0.1ã2.0ã§ã
ãã ã®ç²ç¶ãªããç²æ«ç¶ã®å«çªçŽ ããšããŒã«ã»ã¢ã«
ãããæš¹èãšã (2) ç¡æ©è³ªææç²äœã ãšãå«æããäžã€ äžèšå«çªçŽ ããšããŒã«ã»ã¢ã«ãããæš¹èãã該
å«çªçŽ ããšããŒã«ã»ã¢ã«ãããæš¹èãšè©²ç¡æ©è³ª
ææç²äœã®åèšéã«åºã¥ããŠ11ééïŒ ããå°ã
éã§å«æãããããšãç¹åŸŽãšããçµæç©ã«ãã€
ãŠéæãããã æ¬çºæã«ãããŠçšãããããããç²ç¶ãªããç²
æ«ç¶å«çªçŽ ããšããŒã«ã»ã¢ã«ãããæš¹èã¯ãããš
ããŒã«ãåã¯å°ããšã50ééïŒ ç¹ã«å°ããšã70é
éïŒ ã®ããšããŒã«ãå«æããããšããŒã«ãšäŸãã°
ïœâã¯ã¬ãŸãŒã«ãïœâã¯ã¬ãŸãŒã«ãïœâã¯ã¬ãŸãŒ
ã«ããã¹âããšããŒã«ïŒ¡ãïœâãïœâåã¯ïœâ
C2ãC4ã¢ã«ãã«ããšããŒã«ãïœâããšãã«ããš
ããŒã«ããã·ã¬ããŒã«ãã¬ãŸã«ã·ããŒã«çå ¬ç¥ã®
ããšããŒã«èªå°äœã®ïŒçš®åã¯ãã以äžãšã®æ··åç©
ãšãå°ãªããšãïŒåã®æŽ»æ§æ°ŽçŽ ãæããå«çªçŽ å
åç©ããã³ã¢ã«ããããšã®çž®åç©ãå å«ããã æ¬çºæã®çµæç©ã«ãããäžèšç²ç¶ãªããç²æ«ç¶
å«çªçŽ æš¹èã¯äžèšãã(A)ããã³(B)ã®ç¹æ§ãæã
ããåèš(A)ããã³(B)ã®ç¹å®ã«ãããŠã (A)ã®çç¶äžæ¬¡ç²åããã³ãã®äºæ¬¡åéç©ã®ç²åŸ
ã0.1ã100ãã¯ãã³ã§ãããšããç¹å®ã (B)ã®ïŒ€960ã1020ïŒïŒ€1450ã1500ïŒ0.1ã2.0ãšãã
ç¹å®ã ã¯ããããåŸè¿°ãã枬å®æ³ã«åºã¥ããã®ã§ããã äžèšç²ç¶ãªããç²æ«ç¶å«çªçŽ æš¹èã®ç¬¬ïŒã®ç¹åŸŽ
ã¯ãåŸæ¥å ¬ç¥ã®ããã©ãã¯æš¹èã®ç¡¬å補ååã¯ã¬
ãŸãŒã«æš¹èã®ç¡¬å補åãç²ç ããããšã¯æ¥µããŠå°
é£ã§ãããããã匷ãã§ç²ç ãããã®ãæã¯åŸæ¥
å ¬ç¥ã®ç¡¬åããã©ãã¯æš¹èç¹ç¶ãç²ç ãããã®ç
ãšã¯å šãç°ã€ãŠãåèš(A)ã«ç¹å®ãããšããããã
ã®æ®ãã©ãçç¶äžæ¬¡ç²åããã³ãã®äºæ¬¡åéç©
ã§ãç²åŸã0.1ã100ãã¯ãã³ã®ãã®ã奜ãŸããã¯
0.1ã50ãã¯ãã³ã®ãã®ãå«æããã äžèšç²ç¶ãªããç²æ«ç¶å«çªçŽ æš¹èã¯ãéåžžãã®
å°ããšã30ïŒ ã奜ãŸããã¯å°ããšã50ïŒ ãç²åŸ
0.1ã100ãã¯ãã³ãããã«å¥œãŸããã¯0.1ã50ã
ã¯ãã³ã®çç¶äžæ¬¡ç²åããã³ãã®äºæ¬¡åéç©ãã
æãããã®30ïŒ åã¯50ïŒ ãšãã衚瀺ã¯ãåŸèšã®ç²
åŸæž¬å®æ³ã«ãããŠå®çŸ©ãããšãããåçã100ã
1000åã®å åŠé¡åŸ®é¡ã®ïŒã€ã®èŠéã«ãããå šäœã®
ç²åïŒäºæ¬¡åéç©ãå«ãïŒã®æ°ã®30ïŒ åã¯50ïŒ ãš
ããæå³ã§ãããç¹ã«å¥œãŸãããã®ã¯ã該ç²ç¶ãª
ããç²æ«ç¶å«çªçŽ æš¹èã®70ä¹è³å®è³ªçã«100ïŒ ã
ç²åŸ0.1ã100ãã¯ãã³ã®çç¶äžæ¬¡ç²åããã³ãã®
äºæ¬¡åéç©ããæããã®ã§ããã ç¹ã«å¥œãŸãããã®ã¯ãäžèšå®çŸ©ã«ããå åŠé¡åŸ®
é¡åçã®èŠéã®ç²åã®æ°ïŒïŒã€ã®èŠéã®å¹³åå€ãš
ããŠïŒã®å°ããšã30ïŒ ãç¹ã«å°ããšã50ïŒ å°±äž70
ä¹è³å®è³ªçã«100ïŒ ã0.1ã50ãã¯ãã³ããã奜ãŸ
ããã¯0.1ã20ãã¯ãã³ã®ç¯å²ã®çç¶äžæ¬¡ç²åã
ãã³ãã®äºæ¬¡åéç©ããæãã äžèšã®ç²ç¶ãªããç²æ«ç¶å«çªçŽ æš¹èã¯ã以äžã®
ãšãããäžèšã®çç¶äžæ¬¡ç²åããã³ãã®äºæ¬¡åé
ç©ã®åŸ®å°ç²åãäžå¿ãšãªã€ãŠåœ¢æããããã®ã§ã
ããã極ããŠåŸ®å°ã§ãã€ãŠãå šäœã®å°ããšã50é
éïŒ ã奜ãŸããã¯70ééïŒ ãç¹ã«å¥œãŸããã¯å šäœ
ã®å°ããšã80ééïŒ ã¯150ã¿ã€ã©ãŒã¡ãã·ãŠã®ç¯©
ãééããããã®ãããªç¯©ãééãããšãã衚瀺
ã¯ãæ¬çºæã«ãããŠçšããããç²ç¶ãªããç²æ«ç¶
補åã該篩ã§ç¯ãæäœã«ãããŠã該ç²ç¶ãªããç²
æ«ç¶è£œåã軜ãæã§ãã¿ã»ãããšããã¯ãæ§ã®ã
ã®ã§ç¯©ç®äžã®ç²åã軜ãæŒãããããªããããã
ããšããæã¯æã§è»œãå©ãçã®è©²ç²åïŒäºæ¬¡åé
ç©ãå«ãïŒã匷å¶çã«ç Žå£ãããããªãã®ã§ãªã
åãå ããããšãäœçæé€ãããã®ã§ã¯ãªãã äžèšã®ç²ç¶ãªããç²æ«ç¶å«çªçŽ æš¹èã¯ããã«ã
åèš(B)ã§ç¹å®ãããŠãããšãããèµ€å€ç·åžåã¹ã
ã¯ãã«ã«ãããŠã 960ã1020ïŒïŒ€1450ã1500ïŒ0.1ã2.0 奜ãŸããã¯ãæŽã« 1280ã1360ïŒïŒ€1450ã1500ïŒ0.15ã3.0ãšããç¹
æ§ãæããã ãŸããæ¬çºæã«çšããããç²ç¶ãªããç²æ«ç¶ã®
å«çªçŽ æš¹èã®å¥œãŸãããã®ã¯ã 960ã1020ïŒïŒ€1450ã1500ïŒ0.15ã0.6 奜ãŸããã¯ãæŽã« 1280ã1360ïŒïŒ€1450ã1500ïŒ0.2ã2.0ãšããç¹æ§
ãæããç¹ã«å¥œãŸãããã®ã¯ã 960ã1020ïŒïŒ€1450ã1500ïŒ0.2ã0.4 奜ãŸããã¯ãæŽã« 1280ã1360ïŒïŒ€1450ã1500ïŒ0.3ã1.5ãšããç¹æ§
ãæããã ãŸããæ¬çºæã«çšããããç²ç¶ãªããç²æ«ç¶ã®
å«çªçŽ æš¹èã¯ãæŽã«ã KBré å€æ³ã«ããèµ€å€ç·åžåã¹ãã¯ãã«ã«ãã
ãŠã1580ã1650cm-1ã®ç¯å²ã®æã倧ããªåžå匷床
ã1580ã1650ã§è¡šãããå Žåã 1580ã1650ïŒïŒ€1450ã1500ïŒ0.3ã4.5 ïŒå¥œãŸããã¯0.75ã2.0ãç¹ã«å¥œãŸããã¯1.0ã
1.5ïŒ ã§ãããèµ€å€ç·åžåã¹ãã¯ãã«ã«ãããç¹åŸŽãæ
ããŠããã äžè¬ã«ãäžæ¬¡å æ¶æ©æ§é ãæããç©è³ªã®åçš®å®
èœåºã®åž°å±ãèµ€å€ç·åžåã¹ãã¯ãã«ã§ç¢ºå®ããã
ãšã¯é£ãããããªãã¡èµ€å€ç·åžåã¹ãã¯ãã«å³ã«
ãããããŒã¯ã倧ããã·ããããããšãå€ããã
ã§ããã ããããªãããããšããŒã«ã»ã¢ã«ãããæš¹èã
çš®ã ã®å«çªçŽ ååç©ã®èµ€å€ç·åžåã¹ãã¯ãã«ã
ããæ¬çºæã«ãããèµ€å€ç·åžåã¹ãã¯ãã«ã«ãã
ãäžèšåžåã¯ã 960ã1020cm-1ã®åžåã¯ã¡ãããŒã«åºã«åž°å±ã
ãããŒã¯ã§ããã1280ã1360cm-1ã®åžåã¯ççŽ çª
çŽ çµåã«åž°å±ããããŒã¯ã§ããããããŠ1450ã
1500cm-1ã®åžåã¯è³éŠæäºéçµåã«åž°å±ããããŒ
ã¯ã§ãããšæ±ºããããã ãŸãã1580ã1650cm-1ã®åžåã®åž°å±ã«æ確ã«ã
é£ããããã®åžåã®åŒ·åºŠãçšããäžèšæ¯ç1580
ãïŒïŒïŒïŒïŒïŒ€1450ã1500ã®å€ã¯ãçªçŽ ãå«æããªãã
ãšããŒã«ã»ãã«ã ã¢ã«ããã系暹èã«ããããã®
æ¯çãšæ確ã«åºå¥ãåŸãå€ã瀺ããããæ¬çºæã®
æš¹èãç¹å®ããããã«åæ§ãªç¹åŸŽçãªåžåãšããŠ
èªèã§ããã æ¬çºæã«çšããããç²ç¶ãªããç²æ«ç¶å«çªçŽ æš¹
èãç¹å®ããããã®ïŒã€ã®ãã©ã¡ãŒã¿ãŒã§ããã
èµ€å€ç·åžåã¹ãã¯ãã«ã«ãããäžèšã®åŠãåžå匷
床ã®æ¯ãäŸãã°ïŒ€960ã1020ïŒïŒ€1450ã1500ïŒ0.1ã
2.0ãšããç¯å²ã¯æ¬çºæã«çšããããå«çªçŽ æš¹è
ãããªãã®çšåºŠã®éã§ã¡ãããŒã«åºãå«æããŠã
ããããããã®ã¡ãããŒã«åºã®å«éãããçšåºŠã®
ç¯å²ã§èª¿æŽãåŸããã®ã§ããããšãããããªæ§é
ãšçµã³ã€ããç¹æ§å€ãè¡šãããŠãããšç解ã§ã
ãã æ¬çºæã§çšããããç²ç¶ãªããç²æ«ç¶å«çªçŽ æš¹
èã¯æ¶²äœã¯ãããã°ã©ãã€ãŒã«ãã枬å®å€ãšããŠ
éé¢ããšããŒã«å«æéãéåžž500ppm以äžã§ã
ããããã«å¥œé©ãªè£œåã¯è©²éé¢ããšããŒã«å«æé
ã300ppm以äžãå°±äž100ppm以äžã§ãããåèš
ç¹å ¬æ53â42077å·ã«é瀺ãããæ¹æ³ã«ããåŸã
ããç²ç¶ãªããç²æ«ç¶æš¹èã¯0.3ãçŽïŒééïŒ ãš
ãã極ããŠå€éã®éé¢ããšããŒã«ãå«æããã®ã«
察ããŠãæ¬çºæã§çšããããç²ç¶ãªããç²æ«ç¶å«
çªçŽ æš¹èã®éé¢ããšããŒã«å«æéã¯æ¥µããŠå°éã§
ããããã®äºå®ã¯ãã®çš®ç²ç¶ãªããç²æ«ç¶æš¹èã«
ãšã€ãŠäœ¿çšäžã®éèŠãªå©ç¹ãšãªãã æ¬çºæã§çšããããç²ç¶ãªããç²æ«ç¶å«çªçŽ æš¹
èã¯ãå€ãã®ãã®ããå°ããšãïŒééïŒ å¥œãŸãã
ã¯ïŒã30ééïŒ ã®çªçŽ ãå«æããããšãæãããš
ãããŠããã æ¬çºæã§çšããããç²ç¶ãªããç²æ«ç¶å«çªçŽ æš¹
èã¯ãåŸã«èšè¿°ãã補é æ¹æ³ã«åŸã€ãŠç¡¬ååå¿ã
ããçšå åã«é²è¡ããŠããªããã®ãæãã¯ç¡¬åå
å¿ãæ¯èŒçé²è¡ãããã®ã®ãããã®ç¶æ ããšãã
ãšãã§ããããã®çµæãæ¬çºæã§çšããããç²ç¶
ãªããç²æ«ç¶å«çªçŽ æš¹èã«ã¯ãç±çã«ã¯ãåŸã«èš
èŒããå ç±èç枬å®æ³ã«åŸã€ãŠ100âã®æž©åºŠã§ïŒ
åéå å§ããå Žåã«ã(a)å°ããšããã®ïŒéšãèç
ããŠå¡ç¶ãªããæ¿ç¶äœãšãªããã®ãåã³(b)å®è³ªç
ã«æº¶èåã¯èçããã«ç²ç¶ãªããç²æ«ç¶ã®åœ¢æ ã
ãšããã®ã®åæ¹ãå«ãŸããã äžèš(a)ã®æ¯èŒçèçæ§ã®å€§ããªæš¹èã«ã¯ãåŸã«
èšèŒããè©Šéšæ¹æ³ã«åŸã€ãŠã¡ã¿ããŒã«ã«å¯Ÿãã溶
解æ§ã枬å®ãããš20ééïŒ ä»¥äžãããã«ã¯30éé
ïŒ ä»¥äžãå€ããã®ã§ã¯40ééïŒ ä»¥äžã®ã¡ã¿ããŒã«
溶解æ§ã瀺ãæš¹èãå å«ãããã ãŸããæ¬çºæã§çšããããç²ç¶ãªããç²æ«ç¶å«
çªçŽ æš¹èã¯ãåŸè¿°ãã補é æ¹æ³ããæãããªãšã
ããåå¿ç³»å ã«èŠªæ°Žæ§é«ååååç©ãå®è³ªçã«å«
æããªã補é æ¹æ³ã«ãã補é ããããããé垞芪
æ°Žæ§é«ååååç©ãå®è³ªçã«å«æããŠããªããã
ã®ãããªå«çªçŽ å¡©åºæ§ååç©ã芪氎æ§é«åååå
ç©ã¯ã硬åãããã¯çŒæã®éãã°ãã°æçµæ圢äœ
ã«ã¯ã©ãã¯ãã¬ã¹ã¶ãããçºçãããåå ãšãª
ãã æ¬çºæã«ãããŠçšããããäžèšç²ç¶ãªããç²æ«
ç¶å«çªçŽ æš¹èã¯ã (1) äžèšçµæ ã€ å¡©é žïŒHClïŒæ¿åºŠãïŒã28ééïŒ ã ã ãã«ã ã¢ã«ãããïŒHCHOïŒæ¿åºŠãïŒã
25ééïŒ ããã³ãã«ã ã¢ã«ããã以å€ã®ã¢ã«
ãããã®æ¿åºŠãïŒã10ééïŒ ãäžã€ ã å¡©é žãšãã«ã ã¢ã«ãããã®åèšæ¿åºŠã10ã
40ééïŒ ã ã§ããå¡©é žâã¢ã«ã ã¢ã«ããã济ã«ã (2) ããšããŒã«é¡ãšå°ããšãïŒåã®æŽ»æ§æ°ŽçŽ ãæ
ããå«çªçŽ ååç©ãšããäžèšåŒïŒïŒã 济æ¯ïŒäžèšå¡©é žâãã«ã ã¢ã«ããã济ã®ééïŒäžèšããšããŒã«é¡ã®ééïŒäžèšå«çªçŽ ååç©ã®éé ã§è¡šãããã济æ¯ãå°ããšãïŒä»¥äžãšãªããã
ã«ç¶æããŠãæ¥è§Šãããããšã«ãã€ãŠè£œé ãã
ããšãã§ããã äžèš(1)ã®å¡©é žâãã«ã ã¢ã«ããã济ã®çµæãšã
ãŠã¯ãäžèšã€ïŒïŒãïŒïŒãïŒã®ïŒæ¡ä»¶ã®ä»ã«ããã
ã«æ¡ä»¶ãïŒãšã㊠該济äžã®ãã«ã ã¢ã«ãããïŒã¢ã«ïŒïŒè©²æµŽã«æ¥è§ŠããããšããŒã«é¡ïŒã¢ã«ïŒãšå«çªçŽ ååç©ïŒã¢ã«ïŒãšã®åèšã®ã¢ã«
æ¯ ãå°ããšãïŒä»¥äžãæ®ã«2.5以äžãå°±äžïŒä»¥äžãš
ãªãããã«ããããšã奜é©ã§ãããäžèšæ¡ä»¶ãã®
ã¢ã«æ¯ã®äžéã¯ç¹ã«éå®ãããªããã20以äžããª
ãããã«ããããšã奜é©ã§ãããäžèšæ¡ä»¶ãïŒã®
ã¢ã«æ¯ã®äžéã¯ç¹ã«éå®ãããªããã20以äžãç¹
ã«15以äžã奜é©ã§ãããäžèšã¢ã«æ¯ã¯ç¹ã«ïŒã
15ãå°±äžïŒã10ã奜é©ã§ãããäžèšè£œé æ³ã®ç¹åŸŽ
ã¯ããããã«å¡©é žïŒHClïŒæ¿åºŠãå¯æãé«æ¿åºŠã§
ãããããšããŒã«é¡ãšå«çªçŽ ååç©ãšã«å¯ŸããŠã
ã«ã ã¢ã«ããããéå°ã«å«æããå¡©é žâãã«ã ã¢
ã«ããã氎溶液ã®æµŽãã济æ¯ãïŒä»¥äžã奜ãŸãã
ã¯10以äžãšãã倧ããªæ¯çã§ããšããŒã«é¡ããã³
å«çªçŽ ååç©ãšæ¥è§Šãããããšã«ããã ããªãã¡ãæŽã«èª¬æãããšãäžèšæ¹æ³ã¯äžèšã®
åŠãå¡©é žãšãã«ã ã¢ã«ãããã®ããããã®æ¿åºŠã
ïŒééïŒ ä»¥äžã§ããã济æ¯ãïŒä»¥äžãšããæ¡ä»¶äž
ã§è¡ãªãããã®ã§ãããšããŒã«é¡ãšå«çªçŽ ååç©
ãšã®åèšééã«å¯Ÿããå¡©é žåã³ãã«ã ã¢ã«ããã
ã®ééæ¯çã¯ããããå°ããšã24ééïŒ ãšãªãã
ãŸããäžèšæ¹æ³ã¯äžèšã®åŠãå¡©é žãšãã«ã ã¢ã«ã
ãããšã®åèšæ¿åºŠã10ééïŒ ä»¥äžã§è¡ãªãããã®
ã§ãããšããŒã«é¡ãšå«çªçŽ ååç©ãšã®åèšééã«
察ããå¡©é žãšãã«ã ã¢ã«ãããã®åèšééã¯80é
éïŒ ä»¥äžãšãªããããããªåå¿æ¡ä»¶ã¯æ¢è¿°ã®ãšã
ãåŸæ¥å ¬ç¥ã®ããã©ãã¯æš¹èããã³ã¬ãŸãŒã«æš¹è
補é ã®åå¿æ¡ä»¶ãšã¯æ ¹æ¬çã«ç°ã€ãŠããã å¡©é žâãã«ã ã¢ã«ããã济ã«ããšããŒã«é¡ãšå«
çªçŽ ååç©ãšãæ¥è§Šãããéã®åèšåŒïŒïŒã§è¡š
ãããã济æ¯ã¯ã10以äžãæ®ã«15ã40ãšããããš
ã奜ãŸããã å¡©é žâãã«ã ã¢ã«ããã济ã«ããšããŒã«é¡ãšå«
çªçŽ ååç©ãšãæ¥è§Šãããã«ã¯ããšããŒã«é¡ã該
济ãšæ¥è§ŠããåŸçœæ¿ãçæããç¶ãåŸç²ç¶ãªãã
ç²æ«ç¶ã®åºåœ¢ç©ã圢æãããããã«è¡ããè©²å¡©é ž
âãã«ã ã¢ã«ããã济ãšããšããŒã«é¡ããã³å«çª
çŽ ååç©ãšã®æ¥è§Šã¯ãè©²å¡©é žâãã«ã ã¢ã«ããã
济äžã«ããšããŒã«é¡ãšå«çªçŽ ååç©ãšãäžç·ã«æ·»
å ãããåã¯å«çªçŽ ååç©ãæ·»å ããã®ã¡ããšã
ãŒã«ãæ·»å ããŠæåã«éæ溶液ã圢æãã次ãã§
çœæ¿ãçæããããããåŸç²ç¶ãªããç²æ«ç¶ã®åº
圢ç©ã圢æãããããã«è¡ãããšã奜é©ã§ããã
ãã®éã該济ã«ããšããŒã«é¡ãæ·»å ããŠçœæ¿ãç
æããåã®æ®µéã«ãããŠã¯ã該济ãæ¹æããŠæ·»å
ããããšããŒã«é¡ãšå«çªçŽ ååç©ãšã該济ãšãªã
ã¹ãåäžãªéæ溶液ã圢æããããã«ãããŸãçœ
æ¿ãçæããæç¹ä»¥éåºåœ¢ç©ã圢æããããŸã§ã®
æéã¯ããšããŒã«é¡ãšå«çªçŽ ååç©ãšã®å²åãå
å¿æ¡ä»¶ã«ãã€ãŠã¯è©²æµŽïŒåå¿æ¶²ïŒã«äŸãã°æ¹æã®
åŠãæ©æ¢°çåªæåãäžããªãããã«ããããšã奜
ãŸããã æ·»å ããããšããŒã«é¡ã¯ãããšããŒã«é¡ãã®ã
ã®ã§ãããããããšããŒã«ããã«ããªã³ãå¡©é žæ°Ž
溶液æã¯æ°Žçã§åžéãããã®ã§ãããã ãŸããããšããŒã«é¡åã¯ãããšããŒã«é¡ãšå«çª
çŽ ååç©ïŒåã¯ãããã®åžé溶液ïŒãæ·»å ããé
ã®ãå¡©é žâãã«ã ã¢ã«ãããåç©æµŽã®æž©åºŠåã¯äº
ãå«çªçŽ ååç©ã溶解ããããå¡©é žâãã«ã ã¢ã«
ããã济ã®æž©åºŠã¯ã90â以äžãç¹ã«70â以äžã®æž©
床ã奜é©ã§ããã該济ã®æž©åºŠã40â以äžãæ®ã«50
â以äžã«é«ãå Žåã¯ãããšããŒã«é¡ããã³å«çªçŽ
ååç©ãšãã«ã ã¢ã«ããããšã®åå¿é床ã¯å€§ãšãª
ããããããšããŒã«é¡ãåã¯ããšããŒã«é¡ãšå«çª
çŽ ååç©ãšãæ®ã«è©²ãã«ããªã³æº¶æ¶²ã§åžéããŠåž
é溶液ãšããŠè©²æµŽã«æ·»å ããã®ã奜é©ã§ããããŸ
ããã®å Žåã«ã¯ãåå¿é床ã倧ã§ãããããããš
ããŒã«é¡ãåã¯ããšããŒã«é¡ãšå«çªçŽ ååç©ãšã
æ®ã«ãããã®åžé溶液ã®çŽ°æµåã¯ãªãã¹ã埮å°ã®
现滎ã®åœ¢ã§è©²æµŽã«æ·»å ãæ¥è§Šããããã®ã奜ãŸã
ãã 該济枩ã40â以äžãæ®ã«50â以äžã«é«ãå Žåã«
ã¯ããã®æµŽã«ããšããŒã«é¡ãåã¯ããšããŒã«é¡ãš
å«çªçŽ ååç©ãåã¯ãããã®åžé溶液ãæ¥è§Šãã
ãããšã該济枩ãé«ããã°é«ãçšããšããŒã«é¡ãš
å«çªçŽ ååç©ãšã®åå¿é床ã¯å€§ãšãªãã該æ¥è§Šã®
åŸæ°å以å ã®çæéæã¯ç¬æã«çœæ¿ãçæããäž
ã€æ¥éã«ç²ç¶ãªããç²æ«ç¶ã®åºåœ¢ç©ã圢æãã
ãã å¡©é žâãã«ã ã¢ã«ããã济ã®æž©åºŠã40â以äžã
奜ãŸããã¯ïŒâã35âãç¹ã«å¥œãŸããã¯10ã30â
ã«ä¿ã¡ããã®æµŽã«ããšããŒã«é¡ãšå«çªçŽ ååç©ãš
ããã®ãŸãŸåã¯ãã®åèšåžé溶液ã奜ãŸããã¯ã
ãšããŒã«ãšå«çªçŽ ååç©ãšã®æ°Žåžé溶液ãæ·»å
ããçœæ¿ãçæããåŸã»ãŒ50â以äžã奜ãŸããã¯
45â以äžã®æž©åºŠã§ææã®åå¿ãå®äºããç²ç¶ãªã
ãç²æ«ç¶åºåœ¢ç©ã¯ã硬ååå¿ãããçšå åã«é²è¡
ããŠããªããããäžè¬ã«åŸè¿°ãã100âç±èçè©Š
éšã«ãããŠç±èçæ§ã瀺ããã®ãšãªãã ä»æ¹ãè©²å¡©é žâãã«ã ã¢ã«ããã济ã®æž©åºŠã40
â以äžã奜ãŸããã¯15ãã35âã«ä¿ã¡ããã®æµŽã«
æ·»å ãã¹ãããšããŒã«é¡ãšå«çªçŽ ååç©ãšããã®
ãŸãŸåã¯ãã®åèšåžé溶液ã®å®è³ªçå šéãæ¹æäž
ã«æ·»å ããŠéæ溶液ã圢æããããããåŸéæ¹æ
ç¶æ ã§çœæ¿ãçæããã次ãã§ææž©åã¯ææž©ãã
ããšãªãæ·¡ãã³ã¯è²ã®ç²ç¶ãªããç²æ«ç¶ã®åºåœ¢ç©
ãçæããããã®åºåœ¢ç©ã50âãããé«ã枩床ã
奜ãŸããã¯70ãã95âã®æž©åºŠã«å ç±ããŠææã®å
å¿ãå®äºãããã®ã¯ã硬ååå¿ãããé²è¡ããã
ãã100âã®ç±èçæ§ã¯äœäžãããåã¯å®è³ªçã«
ãªããªããæã¯ããé«æž©äŸãã°200âã«ãããç±
èçæ§ã瀺ããã®åã¯ãã®ãããªé«æž©ã«ãããŠã
ç±èçæ§ãå®è³ªçã«æããªããã®ãšãªãã äžèšã®ãããã®å Žåãäºãå¡©é žâãã«ã ã¢ã«ã
ãã济äžã«å«çªçŽ ååç©ãæ·»å ã次ãã§ããšããŒ
ã«é¡ã®ã¿ãæ·»å ããããšãã§ããã äžèšæ¹æ³ã§çšããããšããŒã«é¡ãšããŠã¯ãããš
ããŒã«ãæã奜é©ã§ããããå°ããšã50ééïŒ ç¹
ã«å°ããšã70ééïŒ ã®ããšããŒã«ãå«æãããã®
ã§ããã°ïœâã¯ã¬ãŸãŒã«ãïœâã¯ã¬ãŸãŒã«ãïœâ
ã¯ã¬ãŸãŒã«ããã¹âããšããŒã«ïŒ¡ãïœâãïœâå
ã¯ïœâC2ãC4ã¢ã«ãã«ããšããŒã«ãïœâããšã
ã«ããšããŒã«ããã·ã¬ããŒã«ãã¬ãŸã«ã·ããŒã«ç
å ¬ç¥ã®ããšããŒã«èªå°äœã®ïŒçš®åã¯ãã以äžãšã®
æ··åç©ã§ãã€ãŠããã äžèšæ¹æ³ã§çšããå«çªçŽ ååç©ãšããŠã¯ãå°ã
ãšãïŒåã®æŽ»æ§æ°ŽçŽ ãååå ã«æããååç©ã奜
ãŸããã¯ååå ã«ã掻æ§æ°ŽçŽ ãæããã¢ããåºã
ã¢ããåºãããªã¢ããåºããŠã¬ã€ã³åºãåã³ããª
ãŠã¬ã€ã³åºããæã矀ããéžã°ããåºãå°ããšã
ïŒåæããååç©ãçšããããã ãããå«çªçŽ ååç©ãšããŠã¯ãäŸãã°ãå°¿çŽ ã
ããªå°¿çŽ ãå°¿çŽ ãããã¯ããªå°¿çŽ ã®ã¡ãããŒã«èª
å°äœãã¢ããªã³ãã¡ã©ãã³ãã°ã¢ããžã³ãã°ã¢ã
ãã³ããžã·ã¢ã³ãžã¢ãããèèªé žã¢ãããããªã¢
ããããã«ã€ãžã³ãã·ã¢ããŒã«é žåã¯ãããã®æ©
械çèªå°äœãæããããããããã¯ïŒçš®åã¯ïŒçš®
以äžã§çšããããšãã§ããã 以äžã®åŠãããŠè©²æµŽäžã«çæããææã®åå¿ã
å®äºããç²ç¶ãªããç²æ«ç¶å«çªçŽ ããšããŒã«ã»ã¢
ã«ãããæš¹èã®åºåœ¢ç©ã¯ãè©²å¡©é žâãã«ã ã¢ã«ã
ãã济ããåé¢ãããããæ°ŽæŽãã奜ãŸããã¯ä»
çããå¡©é žãã¢ã«ã«ãªæ°Žæº¶æ¶²ãäŸãã°ã¢ã³ã¢ãã¢
æ°Žåã¯ã¡ã¿ããŒã«æ§ã¢ã³ã¢ãã¢æ°Žã§äžåãæŽã«æ°Ž
æŽããããšã«ãã€ãŠææã®è£œåãšããããšãã§ã
ãããã®å Žååœç¶ã®ããšãªããã¡ã¿ããŒã«æº¶è§£æ§
ãæ¯èŒçé«ãæš¹èã«ãã€ãŠã¯ã¢ã«ã«ãªæ°Žæº¶æ¶²ã§äž
åãè¡ãã®ãããã æ¬çºæã®ç¡æ©è³ªææç²äœãå«æããçµæç©ã¯ã
äžèšç²ç¶ãªããç²æ«ç¶å«çªçŽ ããšããŒã«ã»ã¢ã«ã
ããæš¹èãšç¡æ©è³ªææç²äœãšãå«æããã æ¬çºæã«ãããŠçšããããç²ç¶ãªããç²æ«ç¶å«
çªçŽ ããšããŒã«ã»ã¢ã«ãããæš¹èã¯ãäžèšã®ãšã
ããç²åŸ0.1ã100ãã¯ãã³ã®çç¶äžæ¬¡ç²åããã³
ãã®äºæ¬¡åéç©ã®åŠãéåžžã«åŸ®çŽ°ãªç²åãå«æã
ãŠæãã®ã§ãç¡æ©è³ªææç²äœãšã®æ··åæ§ãè¯ãã æ¬çºæã®çµæç©ã¯ãäžèšç²ç¶ãªããç²æ«ç¶ã®å«
çªçŽ ããšããŒã«ã»ã¢ã«ãããæš¹èããç¡æ©è³ªææ
ç²äœãšç²ç¶ãªããç²æ«ç¶å«çªçŽ ããšããŒã«ã»ã¢ã«
ãããæš¹èãšã®åèšéã«å¯ŸããŠ11ééïŒ ããå°ãª
ãéã奜ãŸããã¯0.2ãïŒééïŒ ãç¹ã«å¥œãŸãã
ã¯0.4ãïŒééïŒ ã®éã§å«æããã æ¬çºæã®çµæç©ã¯ãã®ããã«æ¯èŒçå°ãªãå²å
ã§ç²ç¶ãªããç²æ«ç¶å«çªçŽ ããšããŒã«ã»ã¢ã«ãã
ãæš¹èãå«æãããã該埮现ãªæš¹èã¯ç¡æ©è³ªææ
ç²äœãšã®æ··åæ§ã«åªããŠãããããç·å¯ãªæ··åç©
ãšããŠæäŸããããšãã§ããã ç²ç¶ãªããç²æ«ç¶å«çªçŽ ããšããŒã«ã»ã¢ã«ãã
ãæš¹èãšããŠã¯ãå ç±èç枬å®æ³ã«åŸã€ãŠ100â
ã®æž©åºŠã§ïŒåéä¿æããå Žåã«å°ããšããã®äžéš
ãèçãããã®ã§ããåèšãã(a)ã®ããšããŒã«ã»
ã¢ã«ãããæš¹èåã¯å ç±èç枬å®æ³ã«åŸã€ãŠå®è³ª
çã«æº¶èåã¯èçããªããã®ã§ããåèšãã(b)ã®
ããšããŒã«ã»ã¢ã«ãããæš¹èã®ãããã䜿çšãã
ããšãã§ãããæ¬çºæã®ç²ç¶ãªããç²æ«ç¶å«çªçŽ
ããšããŒã«ã»ã¢ã«ãããæš¹èãšããŠã¯ã奜ãŸãã
ã¯ãäžèš(a)ã®å ç±èçåã®æš¹èåã¯äžèš(a)ã®å ç±
èçåã®æš¹èãšäžèš(b)ã®å ç±äžèçåã®æš¹èãšã®
æ··åç©ãçšãããããå ç±èçåã®æš¹èãå«æã
ãæ¬çºæã®çµæç©ã¯ãããæ圢åãšããå Žåã«ã
該暹èãå ç±ã«ãã€ãŠæº¶èããŠç¡æ©è³ªææç²æ«ã®
ãã€ã³ããŒãšãªããããããç¹ã«ãããŠæ¬çºæã®
奜é©ãªçµæç©ãæ§æããã æ¬çºæã®çµæç©ã«ãããç¡æ©è³ªææç²äœãšã¯ã
äžè¬ã«ç¡æ©ç©ãšåŒã°ããŠããååç©ããæããç²
æ«ã®åœ¢æ ã«ããææç©è³ªã§ãããäŸãã°ã»ã©ãã
ã¯ã¹ã®åææãšãªãåŸãç¡æ©ååç©ã®ç²äœããã
ã¯ãã°ãã·ãŠã ãããã€ãªã³ååŸåã®å°ããéå±
ãäŸç€ºããããšãã§ããã ãããã®ç¡æ©è³ªææã¯ïŒçš®åã¯ïŒçš®ä»¥äžäžç·ã«
çšããããšãã§ãããŸãéå±ã¯æ··åç©ã§ãã€ãŠã
åéã§ãã€ãŠãããã ã»ã©ããã¯ã®åææãšãªãåŸãç¡æ©ååç©ãšã
ãŠã¯ãäŸãã°ãéå±é žåç©ãéå±é žåç©ãäž»æå
ãšããçµæç©ãéå±æ°Žé žåç©ãéå±ç¡«åç©ãéå±
çåç©ãéå±çªåç©ãéå±ã®ç¡æ©é žå¡©åã¯éå±ã®
ç¡æ©é¯å¡©ãããã¯è€å¡©çããããããšãã§ããã
ãããç¡æ©ååç©ã«ãããéå±ãšã¯ãåšæåŸè¡šã®
第ã第æã®ç¬¬ïŒã第ïŒåšæã®å çŽ ã第æã®
第ïŒãïŒåšæã®å çŽ ã第ã第æã®ç¬¬ïŒãïŒåš
æã®å çŽ ã第ïœæã®ç¬¬ïŒãïŒåšæã®å çŽ ããã³
第æã®å çŽ ãèšããã®ãšãæãåºãæå³ã«è§£é
ãããã¹ãã§ããã éå±é žåç©ãšããŠã¯ãäŸãã°é žåããªãŠã ãé ž
åããŠçŽ ãé žåãã°ãã·ãŠã ãé žåããªãŠã ãã¢
ã«ãããã·ãªã«ãã·ãªã«ã»ã¢ã«ããïŒåçš®ãŒãªã©
ã€ããå«ãïŒãé žåäºéãé žåãã¿ã³ãé žåãžã«
ã³ããŠã ãé žåã€ã³ãžãŠã ãé žåã¢ã³ãã¢ã³ãé ž
åã¢ãªããã³çãæããããšãã§ããã éå±é žåç©ãäž»æåãšããçµæç©ãšããŠã¯ãäŸ
ãã°ãç²åãã«ãªãªã³ãèããç³ïŒãã€ããã€ã©
ã€ãïŒãã¢ã³ã¢ãªããã€ãïŒãã³ããã€ãïŒãç²å
ç¶é²æ¯ãæ»ç³ããã³ã¬ã©ãé·ç³é¡ãé¶ç³ã軜ç³ã
ç«å±±ç°ãã·ã©ã¹ãã«ãŒã³ãç«å±±å²©ãã·ãªããã€
ããã ã©ã€ãããžã«ã³ã³ãã«ã¿ã«ãã¢ãã¿ãŒãŒã
ãã«ãŒã«ã€ããèµ€éé±ãç·æ±ç³ãç³ç¶¿ãã¬ã©ã¹ã
ã»ã¡ã³ããçãæããããšãã§ããã éå±æ°Žé žåç©ãšããŠã¯ãäŸãã°ãæ°Žé žåã¢ã«ã
ããŠã ãæ°Žé žåã«ã«ã·ãŠã ãæ°Žé žåç°é žé ïŒã¯ãž
ã€ã¯ç³ïŒãæ°Žé žåã±ã€é žãã°ãã·ãŠã ãæ°Žé žå
éãæ°Žé žåããªãŠã ãæ°Žé žåãã°ãã·ãŠã çãæ
ããããšãã§ããã éå±ç¡«åç©ãšããŠã¯ãäŸãã°ç¡«åäºéïŒã»ã³ã¢
ãšã³é±åã¯ãŠã«ãé±ïŒãç¡«åã¢ã³ãã¢ã³ïŒãã¢ã³
é±ïŒãç¡«åã«ãããŠã ãç¡«åéãç¡«åã³ãã«ãã
ç¡«åéãç¡«åé ãç¡«åããªãŠã çãæããããšã
ã§ããã éå±çåç©ãšããŠã¯ãäŸãã°ãçåã±ã€çŽ ãç
åãžã«ã³ããŠã ãçåã¿ã³ã°ã¹ãã³ãçåãã¿
ã³ãçåéãçåãããžãŠã ãçåããããŠã ã
çåããŠçŽ çãæããããšãã§ããã éå±çªåç©ãšããŠã¯ãäŸãã°ãçªåã±ã€çŽ ãçª
åã«ã«ã·ãŠã ãçªåãžã«ã³ããŠã ãçªåãã¿ã³ã
çªåããªããçªåãããžãŠã ãçªçŽ ããŠçŽ çãæ
ããããšãã§ããã éå±ã®ç¡æ©é žå¡©ãç¡æ©é¯å¡©ãããã¯è€å¡©ãšããŠ
ã¯ãäŸãã°ãç¡«é žã¢ã«ãããŠã ãã«ãªãŠã âåã¯
ãããªãŠã âããšãŠãã³ãç¡«é žã«ãããŠã ãç¡«é ž
ã«ã«ã·ãŠã ïŒç¡æ°Žç©ãåæ°Žåç©ãïŒæ°Žåç©ïŒãç¡«
é žã¹ããã³ããŠã ãããŠç¡ãç¡«é žéãç¡«é žããªãŠ
ã ãç¡«é žãã°ãã·ãŠã ã®åŠãç¡«é žæ ¹ãå«ãå¡©ïŒäŸ
ãã°å¡©åãããªãŠã ãå¡©åéãå¡©åã«ãªãŠã ãå¡©
åã³ãã«ããå¡©åéãå¡©åé ãå¡©åçœéãå¡©åã
ãªãŠã ãããåã¢ã«ãããŠã ãããåã«ã«ã·ãŠ
ã ãããåéãèåéãæ²åéãæ²åé ã®åŠãã
ãã²ã³åç©ïŒãªã³é žäºéããªã³é žã¢ã«ãããŠã ã
ãªã³é žã«ã«ã·ãŠã ããªã³é žã»ãªãŠã ããªã³é žéã
ãªã³é žãã°ãã·ãŠã ããªã³é žããªãŠã ã®åŠããªã³
é žæ ¹ãå«ãå¡©ïŒãããã¯çé žã«ã«ã·ãŠã ãçé žã¯
ãã ãçé žã³ãã«ããçé žãã°ãã·ãŠã ãçé žã
ã°ãã·ãŠã ã«ã«ã·ãŠã ïŒãããã€ãïŒãçé žããª
ãŠã ãçé žã¹ããã³ããŠã ã®åŠãçé žå¡©ãæãã
ããšãã§ããã ãŸãããã°ãã·ãŠã ãããã€ãªã³ååŸåã®å°ã
ãéå±ãšããŠã¯ãäŸãã°ãCuïŒAgïŒAuïŒZnïŒ
ïŒAlïŒSiïŒTiïŒZrïŒHfïŒSnïŒïŒ·ïŒMnïŒFeïŒ
CoïŒNiïŒRuïŒRhïŒPdïŒOsïŒIrïŒPtïŒçãæã
ãããšãã§ããã æ¬çºæã§çšãããããããã®ç¡æ©è³ªææç²äœ
ã¯ãéåžžã¿ã€ã©ãŒïŒTylerïŒã®20ã¡ãã·ãŠãã«ã€
ãééãã倧ããã奜ãŸããã¯ã¿ã€ã©ãŒã®32ã¡ã
ã·ãŠãã«ã€ãééãã倧ããããã奜ãŸããã¯ã¿
ã€ã©ãŒã®100ã¡ãã·ãŠãã«ã€ãééãã倧ããã§
ããã æ¬çºæã®çµæç©ã¯ãäžèšç²ç¶ãªããç²æ«ç¶ã®å«
çªçŽ ããšããŒã«ã»ã¢ã«ãããæš¹èã®æå®éãšäžèš
ç¡æ©è³ªææç²äœã®æå®éãšããç©ççã«æ··åãã
ããšã«ãã€ãŠèª¿è£œããããšãã§ããããã®éã該
æš¹èãšç¡æ©è³ªææç²äœãšããã®ãŸãŸäŸãã°ïŒ¶åã
ã¬ã³ããŒãçšããŠä¹ŸåŒæ··åããŠãããããŸãã該
æš¹èãšç¡æ©è³ªææç²äœãšãè£å©ææã®ååšäžã«æ··
åããŠãããã 以äžæ¬çºæã®çµæç©ã説æã®äŸ¿ã®ããå®æœæ æ§
ã«åããŠèšè¿°ããã æ¬çºæã®çµæç©ã¯ãäžè¬ã«ãã®ãŸãŸã®ç¶æ ã§ã¯
æçµçãªçšéã«äœ¿çšããããšãã§ãããæçµçãª
çšéã«é©ãã圢æ ã«æ圢ããäžã€å¿ èŠã«ãã硬å
ãããã¯çŒæããããããæçµçãªçšéã«é©ãã
補åã«å€æããããããæ ãæ¬çºæã®çµæç©ã¯ç²
ç¶ãªããç²æ«ç¶ã®å«çªçŽ æš¹èãšç¡æ©è³ªææç²äœãš
ã®æ··åæäœãæ圢æäœããã³å Žåã«ãã硬åãã
ãã¯çŒææäœçã«äŸåããŠçš®ã ã®æ æ§ãå å«ã
ãã æ¬çºæã®çµæç©ã¯ãäžè¬ã«ãç²ç¶ãªããç²æ«ç¶
å«çªçŽ æš¹èãšç¡æ©è³ªææç²äœãšã®æå®éãæ··åã
ãããšã«ãã€ãŠè£œé ããããæ¬çºæã«çšãããã
ç²ç¶ãªããç²æ«ç¶å«çªçŽ æš¹èã¯ç²åŸ0.1ã100ãã¯
ãã³ã®çç¶äžæ¬¡ç²åããæã極ããŠçŽ°ããªç²æ«ã
ãæ§æãããŠããããããã®äœ¿çšéãå°ãªãã«ã
ãããããæ¯èŒçåäžã«åæ£ãããçµæç©ãäžã
ããæ··åæäœã®ã¿ãèæ ®ããã®ã§ããã°ã也åŒå
ã¯æ¹¿åŒæ··åã«ãã€ãŠåäžã«æ··åãããæ¬çºæã®çµ
æç©ã補é ããããšãã§ããã ããããªãããæ¬çºæã®çµæç©ã¯æ··åæäœä»¥å€
ã®æ圢æäœçãèæ ®ããã°ã奜ãŸããã¯æ··åæäœ
ãè£å©å€ã®ååšäžã§å®æœãããæ è£å©å€ãå å«ã
ãç¶æ ã®ãã®ãšããŠæäŸããããšãã§ãããŸãã
ã®ãããªç¶æ ã®ãã®ãšããŠæäŸããããšã奜ãŸã
ãããšãããã æ¬çºæã®çµæç©ã®ç¬¬ïŒã®æ æ§ã¯ãå ç±ã«ãã€ãŠ
ç±èçæ§ã瀺ãç²ç¶ãªããç²æ«ç¶å«çªçŽ æš¹èãå«
æã該暹è以å€ã«ã¯å®è³ªçã«ãã€ã³ããŒãšãªãæ
åãå«æããªãçµæç©ã§ããããã®ãããªçµæç©
ã¯ãäŸãã°ãã®æå®éãäžå®ã®åœ¢ç¶ã®åå ã«å å¡«
ããäŸãã°50ã1000KgïŒcm2ã®å å§äžã§è©²æš¹èã溶
èãã枩床以äžã®æž©åºŠäŸãã°60â以äžã®æž©åºŠã«å
ç±ããããšã«ãã€ãŠã該暹èããã€ã³ããŒãšããŠ
äœçšããçµæèªç«æ§ã®ããäžå®ã®åœ¢ç¶ãæããæ
圢äœã«å€æããããåŸãããæ圢äœã¯è©²æš¹èã®ç¡¬
ååå¿ããã§ã«å åã«é²è¡ããŠããå Žåã«ã¯ãã®
ãŸãŸããŸã該暹èã®ç¡¬ååå¿ãæªã å åã«é²è¡ã
ãŠããªãå Žåã«ã¯ç¡¬åããããã®ã¡ã硬åããã
補åãšããŠæäŸãããããŸããæ圢äœåã¯ç¡¬åäœ
ã¯ããã«çŒæã«ä»ãããšã«ãããçŒæããã補å
ãšããŠæäŸããããšãã§ããã 硬åããã補åãæäŸããã«å¥œé©ãªæ¬çºæã®ç¬¬
ïŒã®æ æ§ã®çµæç©ã¯ãç¡æ©è³ªææãäŸãã°éå±é ž
åç©ãéå±é žåç©ãäž»æåãšããé±ç©ãéå±æ°Žé ž
åç©ãéå±ç¡«åç©ãããã¯éå±ã§ããçµæç©ã§ã
ãããŸãçŒæããã補åãæäŸããã«å¥œé©ãªæ¬çº
æã®ç¬¬ïŒã®æ æ§ã®çµæç©ã¯ç¡æ©è³ªææãäŸãã°é
å±é žåç©ãäž»æåãšããé±ç©ãéå±çåç©ãéå±
çªåç©ãããã¯éå±ã§ããçµæç©ã§ããã æ¬çºæã®çµæç©ã®ç¬¬ïŒã®æ æ§ã¯ãå ç±ã«ãã€ãŠ
ç±èçæ§ã瀺ããªãç²ç¶ãªããç²æ«ç¶å«çªçŽ æš¹è
ãå«æãããããå®è³ªçã«ãã€ã³ããŒãšãªãæå
ãå«æããªãçµæç©ã§ããããã®ãããªçµæç©
ã¯ã該暹èãå ç±ã«ãã€ãŠç±èçæ§ã瀺ããªãã®
ã§ãéåžžç±ã®ã¿ã«ãã€ãŠèªç«æ§ã®ããäžå®ã®åœ¢æ
ãæããæ圢äœã«å€æããããšã¯å°é£ã§ããã ããããªãããæ¬çºæã®çµæç©ã¯ãç²åŸ0.1ã
100ãã¯ãã³ã®äžæ¬¡ç²åããæã極ããŠçŽ°ããªç²
æ«ã®ç²ç¶ãªããç²æ«ç¶å«çªçŽ æš¹èãšç¡æ©è³ªææç²
äœãšããæãã®ã§ããããéåžžã«é«å§ã§å§çž®ãã
ã°èªç«æ§ã®ããäžå®ã®åœ¢ç¶ãæããæ圢äœã«å€æ
ããããšãã§ãããããªãã¡ã該çµæç©ã®äžå®é
ãäŸãã°äžå®ã®åœ¢ç¶ã®åå ã«å å¡«ããäŸãã°æ°çŸ
Kgãæ°10tonïŒcm2ã®å§åãå Žåã«ããå ç±ããªã
ããè² è·ããããããšã«ãã€ãŠèªç«æ§ã®ããäžå®
ã®åœ¢ç¶ãæããæ圢äœã«å€æããããšãã§ããã åŸãããæ圢äœã¯å¿ èŠã«ããçŒæãããããé
åžžçŒæããã補åãšããŠæäŸãããã奜é©ãªæ¬çº
æã®ç¬¬ïŒã®æ æ§ã®çµæç©ãšããŠã¯ãäžèšç¬¬ïŒã®æ
æ§ã®çµæç©ã«ã€ããŠäŸç€ºãããã®ãšåããã®ãäŸ
瀺ããããšãã§ããã æ¬çºæã®çµæç©ã®ç¬¬ïŒã®æ æ§ã¯ãç²ç¶ãªããç²
æ«ç¶å«çªçŽ æš¹èã¯å ç±ã«ãã€ãŠç±èçæ§ã瀺ãã
ã®ãããã¯ããã§ãªããã®ã®ãããã§ãã€ãŠãã
ããã該暹èãç±èçæ§ã瀺ããã®ã§ãã€ãŠãã
該暹è以å€ã«ãã€ã³ããŒãšãªãè£å©æåãå«æã
ãçµæç©ã§ããã ãã®ãããªçµæç©ã¯ãã€ã³ããŒãšãªãè£å©æå
ãå«æãããããäžè¬ã«ãç¹å¥ã«å ç±ãããã¯å
å§ããªããšãäžå®ã®åœ¢ç¶ãæã€èªç«æ§ã®ããæ圢
äœã«å€æããããšãã§ããã ãã®ãããªãã€ã³ããŒãšãªãè£å©æåãšããŠ
ã¯ãäŸãã°æ°Žã奜ãŸããçšãããããæ¬çºæã§çš
ããããç²ç¶ãªããç²æ«ç¶å«çªçŽ æš¹èã®æ¯éã¯äœ¿
çšããç¡æ©è³ªææç²äœã®æ¯éãããäžè¬ã«å°ãã
ããã該暹èã該ç²äœãšã®åé¢ã容æã«èµ·ããã
ãªããŸãã«ãå€éã®æ°Žã䜿çšããããšãæãŸãã
ãªããé©åãªæ°Žã®äœ¿çšéã¯äœ¿çšãã該ç²äœã®çš®é¡
ãšéããã³äœ¿çšãã該暹èã®éã«äŸåããããçµ
æç©ãèªç«æ§ã瀺ãã¹ã©ãªãŒç¶æ ã瀺ããããªé
ã§æ°Žã䜿çšããã®ãæãŸããããã®ãããªæ°Žã®é
ã¯ãäžã€ã®ç®ãããšãã䜿çšããåºäœææã®å®å®¹
ç©ïŒååºäœã®äœ¿çšéïŒïœïŒãååºäœã®å¯åºŠïŒïœïŒ
c.c.ïŒã§å²ã€ãå€ã®åèšã®å€ïŒc.c.ïŒïŒã®ïŒåããã
å°ããå€ïŒc.c.ïŒã®å®¹ç©ãšããããšãã§ããã ãã€ã³ããŒãšãªãè£å©æåãšããŠã¯ãæ°Žã®ä»
ã«ãäŸãã°ã¢ã¹ãã¢ã«ããåæã©ãã¯ãã¹ãã¢ãª
ã³é žããã€ã³æ²¹ããããµããã€ã³ã»ã¿ãŒã«ãã°ãª
ã»ãªã³ããšãã«ã»ã«ããŒãºãã¢ããšãã³é žã¬ãž
ã³ãããªããã«ã»ããã©ãŒã«ã殿ç²ã®åŠããã»ã©
ããã¯ã¹ã®æè¡åéã«ãããŠããç¥ãããŠãã
çš®ã ã®çµåæã䜿çšããããšãã§ããããããã®
çµåæã¯ã䜿çšããåºäœææ100éééšåœãéåžž
ïŒéééšä»¥äžã®å²åã§äœ¿çšããããšãã§ããã æ¬çºæã®çµæç©ãã硬åãããæ圢äœã補é ã
ãéã«ãäŸãã°ç¡æ©è³ªææç²äœãšããŠé¶ç£åšãã
ãã¯ã¬ã³ã¬ã®åŠãèç«ç©çŽ åæåã¯ã»ã¡ã³ãã®åŠ
ãç²äœãçšããå Žåã«ã¯ã硬ååå¿ã®é²è¡ã«ãšã€
ãŠæ°Žãå¿ é ã®æåãšãªããããè£å©æåãšããŠæ°Ž
ãçšããããšãå¿ èŠãšãªãããšãç解ãããã æ¬çºæã®çµæç©ããçŒæãããæ圢äœã補é ã
ãå Žåã«ã¯ãçŒæäœã補é ããããã«èŠæ±ããã
çŒçµå©å€äŸãã°çåã±ã€çŽ çŒçµäœã補é ãããã
ã«çšããããããŠçŽ çãçšããããšãæãŸããã
æ¬çºæã®çµæç©ã¯ãã®ãããªçŒçµå©å€ãå«æãã
ããšãã§ããããããã®çŒçµå©å€ã¯åœè©²æè¡åé
ã«ãããŠããç¥ãããŠããã ãŸããæ¬çºæã®çµæç©ããçŒæãããæ圢å€å
äœã補é ããå Žåã«ã¯ãçŒæã®éç±å解ãæãå€
ååå€äŸãã°ãçæ°Žåç©ãçæ°Žåç©ã®èªå°äœåã¯
çæ°Žåç©ãäž»æåãšãã倩ç¶ç©äŸãã°ã»ã«ããŒãº
ïŒã¬ãŒãšã³ïŒããã³ãã³ãç³ã®åŠãçæ°Žåç©ãã«ã«
ããã·ã¡ãã«ã»ã«ããŒãºãããããã·ãšãã«ã»ã«
ããŒãºãã¢ã»ãã«ã»ã«ããŒãºã®åŠãçæ°Žåç©ã®èª
å°äœãããã¯æšç²ããªã³ã¿ãŒãã€ã·ã¬ã©ãã¢ãã¬
ã©ãç©ç©ç²ã®åŠãçæ°Žåç©ãäž»æåãšãã倩ç¶
ç©ïŒç±å¯å¡æ§æš¹èäŸãã°ããªã¢ãããããªããã«
ã¢ã»ããŒããå¡©åããã«ãå¡©åãããªãã³åã¯ã
ãªã¢ã¯ãªããããªã«ç³»æš¹èããããã¯ç±äžèæ§æš¹
èäŸãã°ããªããã«ã¢ã«ã³ãŒã«åã¯ããªããã«ã
ã«ããŒã«çãå«æããããããšã奜ãŸãããæ¬çº
æã®çµæç©ã¯ãã®ãããªå€ååå€ãå«æããããš
ãã§ãããæ¬çºæã®çµæç©ã¯ãããèªäœã§åã¯ä»
ã®æš¹èãšåå¿æ§ãæãäžã€éåžžã«å°ç²ã§å€§ããè¡š
é¢ç©ãæããç²ç¶ãªããç²æ«ç¶å«çªçŽ ããšããŒ
ã«ã»ã¢ã«ãããæš¹èãå«æããŠããããã«ãç¡æ©
質ææç²äœãšçžäºã«åäžã«åæ£ãåãäžã€å ç±ã«
ããç±ç¡¬ååãã€ã³ããŒãšããŠãããã¯çŒææã®
ççŽ æºãšããŠäœçšãããããå éšãŸã§å®è³ªçã«å
äžã«ç¡¬åãããããã硬åããã補åãäžãããŸ
ãã¯ã©ãã¯ãã¬ã¹ã¶ãããæããçŒæããã補å
ãäžãããããªããšã¯å°ãªãã æ¬çºæã®çµæç©ããåŸãããç¡æ©è³ªæ圢äœã¯ã
åªããè¡ææ§ã®åŠãæ©æ¢°çæ§è³ªãããã¯åªããé»
æ°çç¹æ§ãæããŸãåªããèç±æ§ãèæ©èæ§ãæº
åç¹æ§ãããã¯èååŠè¬åæ§ã瀺ãã æ¬çºæã®çµæç©ããåŸããã硬åäœããã³çŒæ
äœã¯ãäŸãã°è»èŒãèªç©ºæ©ãè¹è¶ççšã®éšåäŸã
ã°ãã¬ãŒãããã©ã°ãã®ã€ã軞åïŒé»æ°ã»ãšãã«
ã®ãŒæ©åšçšéšåäŸãã°é»æ³¢åžåäœãã³ã³ãã³ãµ
ãŒãé»æ°æµæäœãé»æ± çšçµ¶çžäœãçºç±äœãã»ã³ãµ
ãŒã®ä¿è·ç®¡ãæç±æïŒäžå®åœ¢èç«ç©äŸãã°é«çã
転ççã®åçš®çã®å£æãé²ç«å¡æãé²ç«çšãã
ãïŒå»ççšçŽ æäŸãã°æ¯ç§ææã骚æïŒæ©æ¢°éšå
äŸãã°åçš®å·¥å ·ãæºåéšæïŒäŸãã°ã軞åã糞
éãã·ãŒã«çïŒãæ©æŠææïŒäŸãã°ãç 磚å€ãã¿
ããç²ããã¬ãŒãçïŒãèèæïŒåæšå»ºç¯çšæäŸ
ãã°æ©ãšããããã©ããããææšãéåºããã€
ã«ãALCïŒautoclaved lightweight concreatïŒã
èç«ã»æç±ã»ä¿æž©ã»åžæ¹¿ææãããŒããéä»åã
å£ïŒå·¥æ¥çšæäŸãã°é»æ¥µãèç«ã¬ã³ã¬ãåºéæšæ
çã«çšããããšãã§ããã 以äžå®æœäŸã«ããæ¬çºæãæŽã«å ·äœçã«è©³è¿°ã
ãã ïŒ 0.1ã100ÎŒç²åã®æž¬å®æ³ ïŒã€ã®è©ŠæããçŽ0.1ïœã®ãµã³ãã«ããµã³ããª
ã³ã°ããããã®ãããªãµã³ããªã³ã°ãïŒã€ã®è©Šæ
ã«ã€ããŠç°ãªãå ŽæããïŒåè¡ãªãã ãµã³ããªã³ã°ããåçŽ0.1ïœã®ãµã³ãã«ã®åïŒ
éšããããããé¡åŸ®é¡èŠ³å¯çšã¹ã©ã€ãã°ã©ã¹äžã«
èŒãããã¹ã©ã€ãã°ã©ã¹äžã«èŒãããµã³ãã«ã¯èŠ³
å¯ã容æãšãããããã§ããã ãç²ååå¿ãéãª
ãåããªãããã«æ¡ããã é¡åŸ®é¡èŠ³å¯ã¯ãå åŠé¡åŸ®é¡äžèŠéã«ç²ç¶ãªãã
ç²æ«ç¶ç©ããã³ïŒãŸãã¯ãã®äºæ¬¡åéç©ã10ã50
åçšåºŠååšããç®æã«ã€ããŠè¡ãããã«ãããé
åžžåç102ã103åã§èŠ³å¯ããã®ãæãŸãããå åŠ
é¡åŸ®é¡äžèŠéã«ååšããå šãŠã®ç²åã®å€§ãããå
åŠé¡åŸ®é¡äžèŠéäžã®ã¡ãžã€ãŒã«ããèªã¿ãšãèšé²
ããã 0.1ã100ÎŒã®ç²åã®å«æçïŒïŒ ïŒã¯æ¬¡åŒã«ãŠæ±
ããããã 0.1ã100ÎŒç²åã®å«æçïŒïŒ ïŒïŒïŒ®ïŒïŒïŒ®ïŒÃ100 N0ïŒé¡åŸ®é¡äžèŠéã§å¯žæ³ãèªã¿ãšã€ãç²åã®
å šåæ° N1ïŒN0ã®ãã¡0.1ã100ÎŒã®å¯žæ³ãæããç²åã®
åæ° ïŒã€ã®è©Šæã«ã€ããŠã®ïŒã€ã®ãµã³ãã«ã®çµæã®
å¹³åå€ãšããŠ0.1ã100ÎŒã®ç²åã®å«æçãè¡šã
ãã ïŒ 150ã¿ã€ã©ãŒã¡ãã·ãŠç¯©ééé 也ç¥è©Šæããå¿ èŠã«ããååã«æã§è»œããã¿ã»
ãããã®ã¡ããã®çŽ10ïœã粟秀ããïŒåéã§å°é
ãã€150ã¿ã€ã©ãŒã¡ãã·ã®ç¯©æ¯ãšãæ©ïŒç¯©ã®å¯ž
æ³ïŒ200mmÏãæ¯ãšãæ¡ä»¶ïŒ200RPMïŒã«æå ¥
ããè©Šææå ¥åŸæŽã«10åéæ¯ãšããããã150ã¿
ã€ã©ãŒã¡ãã·ãŠéééã¯æ¬¡åŒã«ãŠæ±ããã 150ã¿ã€ã©ãŒã¡ãã·ãŠéééïŒééïŒ ïŒ ïŒÏïŒâÏïŒïŒÏïŒÃ100 ÏïŒïŒæå ¥éïŒïœïŒ ÏïŒïŒ150ã¿ã€ã©ãŒã¡ãã·ãŠç¯©ãééããã«ç¯©
äžã«æ®åããéïŒïœïŒ ïŒ èµ€å€ç·åžåã¹ãã¯ãã«ã®æž¬å®ããã³åžå匷床
ã®æ±ãæ¹ïŒæ·»ä»å³é¢ã®ç¬¬ïŒå³åç §ïŒ æ ªåŒäŒç€Ÿæ¥ç«è£œäœæ補ã®èµ€å€ç·åå å 床èš
ïŒ225åïŒãçšããéåžžã®KBré å€æ³ã«ãã調補ã
ã枬å®çšè©Šæã«ã€ããŠèµ€å€ç·åžåã¹ãã¯ãã«ã枬
å®ããã ç¹å®æ³¢é·ã«ãããåžå匷床ã¯æ¬¡ã®ããã«ããŠæ±
ããã枬å®ããèµ€å€ç·åžåã¹ãã¯ãã«å³ã«ãã
ããåžå匷床ãæ±ããããšããããŒã¯ã«ããŒã¹ã©
ã€ã³ãåŒãããã®ããŒã¯ã®é ç¹ã®ééçãtpã§è¡š
ããããã®æ³¢é·ã«ãããããŒã¹ã©ã€ã³ã®ééçã
tbã§è¡šãããšããã®ç¹å®æ³¢é·ã«ãããåžå匷床
ã¯äžèšåŒã§äžããããã ïŒlogïœïœïŒïœïœ åŸã€ãŠãäŸãã°960ã1020cm-1ã®ããŒã¯ã®åžå
匷床ãš1450ã1500ã®ããŒã¯ã®åžå匷床ãšã®æ¯ã¯ã
äžèšåŒã§æ±ããããããã®åžå匷床ã®æ¯ïŒïŒ€960
ãïŒïŒïŒïŒïŒïŒ€1450ã1500ïŒãšããŠäžããããã ïŒ 100âã«ãããç±èçæ§ 150ã¿ã€ã©ãŒã¡ãã·ãŠééã®è©ŠæçŽïŒïœãïŒæ
ã®0.2mmåã¹ãã³ã¬ã¹æ¿ã®éã«æ¿å ¥ãããã®ãæº
åãããããäºã100âã«å æž©ããç±ãã¬ã¹æ©
ïŒ(æ ª)ç¥è€éå±å·¥æ¥æ補ãååå§çž®æ圢æ©ïŒã§ïŒå
éãåå§50Kgã§ãã¬ã¹ããããã¬ã¹ã解æŸããã®
ã¡ãïŒæã®ã¹ãã³ã¬ã¹æ¿ã®éããç±ãã¬ã¹ããã
è©Šæãåãåºãããåãåºããè©Šæã溶èãŸãã¯
èçã«ããæããã«åºçããŠå¹³æ¿ã圢æããŠãã
ãã®ãè©Šæãèçæ§ãæããŠãããšå€å®ããç±ã
ã¬ã¹ååŸã§ã»ãšãã©å·®ç°ãã¿ãããªããã®ãè©Šæ
ãäžèæ§ãæãããšå€å®ããã ïŒ ã¡ã¿ããŒã«æº¶è§£æ§ è©ŠæçŽ10ïœã粟秀ãïŒãã®ç²Ÿç§€ééãW0ãšã
ãïŒãå®è³ªçã«ç¡æ°Žã®ã¡ã¿ããŒã«çŽ500mläžã§30å
ééæµäžã«å ç±åŠçãããã¬ã©ã¹ãã€ã«ã¿ãŒïŒNo.
ïŒïŒã§éããæŽã«ãã€ã«ã¿ãŒæ®è©Šæããã€ã«ã¿
ãŒäžã§çŽ100mlã®ã¡ã¿ããŒã«ã§æŽæµãã次ãã§ã
ã€ã«ã¿ãŒæ®è©Šæã40âã®æž©åºŠã§ïŒæé也ç¥ãã
ïŒãã®ç²Ÿç§€ééãW1ãšããïŒã次åŒã«ãŠã¡ã¿ããŒ
ã«æº¶è§£åºŠïŒS1ïŒ ïŒãæ±ããã ã¡ã¿ããŒã«æº¶è§£åºŠïŒS1ééïŒ ïŒ ïŒïŒ·ïŒâïŒïŒïŒ·ïŒÃ100 ïŒ éé¢ããšããŒã«å«éã®å®é 150ã¿ã€ã©ãŒã¡ãã·ãŠééã®è©ŠæçŽ10ïœã粟秀
ããå®è³ªçã«ç¡æ°Žã®ã¡ã¿ããŒã«190ïœäžã§30åé
éæµäžã«å ç±åŠçãããã¬ã©ã¹ãã€ã«ã¿ãŒïŒNo.
ïŒïŒã§éãã液ããé«é液äœã¯ãããã°ã©ã
ã€ãŒïŒç±³åœããŠãªãŒã¿ãŒãºç€Ÿè£œ6000AïŒã«ãã
液äžã®ããšããŒã«å«éãå®éããå¥åã«äœæãã
æ€éç·ãã該詊æäžã®éé¢ããšããŒã«å«éãæ±ã
ãã é«é液äœã¯ãããã°ã©ãã€ãŒã®æäœæ¡ä»¶ã¯æ¬¡ã®
ãšããã§ããã ç¹ çœ®ïŒç±³åœãŠãªãŒã¿ãŒãºç€Ÿè£œ6000A ã«ã©ã æ äœïŒÎŒâBondapakC18 ã«ã©ã ïŒåŸ1/4ã€ã³ãÃé·ãïŒãã€ãŒã ã«ã©ã 枩床ïŒå®€æž© 溶é¢æ¶²ïŒã¡ã¿ããŒã«ïŒæ°ŽïŒïŒïŒïŒã容ç©æ¯ïŒ æµ éïŒ0.5mlïŒå ãã€ãã¯ã¿ãŒïŒUVïŒ254nmïŒãRange0.01ïŒïŒïœ
ïŒ¶ïŒ æ¶²äžã®ããšããŒã«å«éã¯ãäºãäœæããæ€é
ç·ïŒããšããŒã«å«éãšããšããŒã«ã«åºã¥ãããŒã¯
ã®é«ããšã®é¢ä¿ïŒããæ±ããã ïŒ åµ©å¯åºŠ 100mlã®ææšã®ãšããã§ããåã«ãªã€ãŠãã100
mlã®ã¡ã¹ã·ãªã³ããŒã«ãã¡ã¹ã·ãªã³ããŒã®ãµã¡äž
æ¹ïŒcmã®ãšããããã100ã¿ã€ã©ãŒã¡ãã·ãŠéé
ã®è©Šæã泚ã蟌ãã次åŒã«ãã€ãŠåµ©å¯åºŠãæ±ã
ãã 嵩å¯åºŠïŒïœïŒmlïŒïŒïŒ·ïŒïœïŒïŒïŒïŒïŒïŒmlïŒ ïŒ·ïŒ100mlåœãã®ééïŒïœïŒ ïŒ çŒæåã®ç¡¬åºŠ ããã«ãŒãºæ³åŸ®å°ç¡¬åºŠèšã§è·é500Kgã§æž¬å®ã
ãã ïŒ æ²ã匷床ããã³å§çž®åŒ·åºŠ JISââ6911â1979ã«æºããŠæž¬å®ããã 10 ç±äŒå°çã®æž¬å® JISââ1412â1968ã«æºããŠæž¬å®ããã 11 é»æ°æ¯æµæ JISââ7202ã«æºããé»æ°éäžæ³ã§æž¬å®ã
ãã 12 èŠæå¯åºŠ æ圢åã®å¯žæ³ããã®ã¹ã§æž¬å®ããŠæ±ããäœç©ãš
æ圢åã®ééããç®åºããã åèäŸ ïŒ (1) ïŒã®ã»ãã©ãã«ãã©ã¹ã³ã«ãå¡©é žãšãã«ã
ã¢ã«ãããã®åçš®çµæïŒç¬¬ïŒè¡šã«èšèŒïŒãããª
ã25âã®æ··å氎溶液åã 1500ïœãå ¥ããããã«
98ééïŒ ã®ããšããŒã«ïŒæ®ãïŒééïŒ ã¯æ°ŽïŒã
å°¿çŽ ããã³37ééïŒ ã®ãã«ããªã³äžŠã³ã«æ°Žãçš
ããŠèª¿æŽããã20ééïŒ ã®ããšããŒã«ã20éé
ïŒ ã®å°¿çŽ ããã³14.6ééïŒ ã®ãã«ã ã¢ã«ããã
ãšãå«ãæ··å氎溶液ïŒ25âïŒãåã 125ïœæ·»å
ãããæ·»å ããŠ15ç§éæ¹æããåŸã60åéé眮
ããã60åéã®é眮ããŠããéãåã ã®ã»ãã©
ãã«ãã©ã¹ã³å ã®å 容ç©ã¯ããããã®ã¯éæãª
ç¶æ ã®ãŸãŸã§ããïŒç¬¬ïŒè¡šã®RunNo.ïŒããã³
20ïŒãåãããã®ã¯éæããçœæ¿ã«ç§»ãçœæ¿ã®
ãŸãŸã§ããïŒç¬¬ïŒè¡šã®RunNo.ïŒïŒïŒããã³
18ïŒãåãããã®ã¯éæç¶æ ããçœæ¿ããŠçœè²
ã®æ²éç©ãäžããïŒç¬¬ïŒè¡šã®RunNo.ïŒïŒïŒã
ïŒã10ã17ããã³19ïŒããã®çœè²æ²éç©ã«ã¯ã
é¡åŸ®é¡èŠ³å¯ãããšæ¢ã«çç¶ç©ãçç¶ç©ã®åéäœ
ããã³å°éã®ç²ç¶ç©ãã¿ãããã次ã«åã ã®ã»
ãã©ãã«ãã©ã¹ã³ã®å 容ç©ãæã æ¹æããªã
ããããã«60åéã§80âã«ãŸã§ææž©ãã次ãã§
80ã82âã®æž©åºŠã§15åéåå¿çæç©ã40ã45â
ã®æž©æ°Žã§æŽæµãã0.5ééïŒ ã®ã¢ã³ã¢ãã¢ãš50
ééïŒ ã®ã¡ã¿ããŒã«ãããªãæ··å氎溶液äžã60
âã®æž©åºŠã§30åéåŠçããå床40ã45âã®æž©æ°Ž
ã§æŽã次ãã§80âã§ïŒæé也ç¥ãããåçš®çµæ
ã®å¡©é žãšãã«ã ã¢ã«ããããããªãæ··å氎溶液
ããåŸãããåå¿çæç©ã®æ§è³ªã第ïŒè¡šã«èšèŒ
ããã (2) äžæ¹ãæ¯èŒã®ãã以äžã®å®éšãè¡ã€ããïŒ
ã®ã»ãã©ãã«ãã©ã¹ã³ã«ãèžçããããšããŒã«
282ïœãš37ééïŒ ã®ãã«ããªã³369ïœããã³26é
éïŒ ã®ã¢ã³ã¢ãã¢æ°Ž150ïœãå ¥ããæ¹æããªã
ã宀枩ãã70âã«ãŸã§60åéã§ææž©ããããã«
70ã72âã®æž©åºŠã§90åéæ¹æã»å ç±ããã次ã
ã§æŸå·ãã300ïœã®ã¡ã¿ããŒã«ãå°éãã€å ã
ãªãã40mmHgã®æžå§äžã«å ±æ²žèžçã«ããè±æ°Ž
ãè¡ãªãã溶å€ãšããŠã¡ã¿ããŒã«ã700ïœå ã
ãŠé»è€è²éæã®ã¬ãŸãŒã«æš¹è溶液ãåãåºã
ãã ããããŠåŸãã¬ãŸãŒã«æš¹èã®äžéšãæžå§äžã«
è±æº¶åªãããšãæ¿ããçºæ³¡ããŠã²ã«åãããã
ã®ã²ã«åç©ãæŽã«çªçŽ ã¬ã¹äžã160âã®æž©åºŠã§
60åéç±ç¡¬åããåŸããã硬åçºæ³¡äœãç²ç ã
ãŠã150ã¿ã€ã©ãŒã¡ãã·ãŠã®ç¯©ãééããç²æ«
ãå°éåŸãããã®å Žåãç±ç¡¬åã¬ãŸãŒã«æš¹èã¯
極ããŠç¡¬ããåçš®ã®ç²ç æ©ãããŒã«ãã«ããã
ã¯è¢å ç·çšã®æ¯åãã«ãçšããŠã150ã¡ãã·
ãŠãã¹ã®ç²æ«ãåŸãã®ã¯éåžžã«å°é£ã§ãã€ãã
ããããŠåŸãç±ç¡¬åã¬ãŸãŒã«æš¹èç²æ«ãäžè¿°ã
ãã®ãšåäžæ¡ä»¶ã§ã0.5ééïŒ ã®ã¢ã³ã¢ãã¢ãš
50ééïŒ ã®ã¡ã¿ããŒã«ãããªãæ··å氎溶液ã§åŠ
çããæž©æ°Žã§æŽãã次ãã§ä¹Ÿç¥ãããããããŠ
åŸãè©Šæã®æ§è³ªã第ïŒè¡šã«RunNo.21ãšããŠèšèŒ
ããã 次ã«ãïŒã®ã»ãã©ãã«ãã©ã¹ã³ã«ãããšã
ãŒã«390ïœã37ééïŒ ã®ãã«ããªã³ã370ïœãã·
ãŠãŠé ž1.5ïœããã³æ°Ž390ïœãå ¥ããæ¹æããªã
ã60åéã§90âã«ãŸã§ææž©ãã90ã92âã®æž©åºŠ
ã§60åéæ¹æã»å ç±ããã次ã«35ééïŒ ã®å¡©é ž
1.0ïœãå ããæŽã«90ã92âã®æž©åºŠã§60åéæ¹
æãå ç±ããã次ãã§ãæ°Žã500ïœå ããŠå·åŽ
ãããµã€ãã³ã«ããæ°Žãé€ãã30mmHgã®æžå§
äžã«å ç±ããŠã100âã®æž©åºŠã§ïŒæéãæŽã«æ
æž©ããŠ180âã®æž©åºŠã§ïŒæéæžå§ãå ç±ããã
åŸãããããã©ãã¯æš¹èã¯å·åŽãããšé»è€è²ã®
åºäœãšããŠåŸãããããã®ãã®ã¯è»å枩床ã78
ã80âã§ããã液äœã¯ãããã°ã©ãã€ãŒã«ãã
å®éããéé¢ããšããŒã«å«éã0.76ééïŒ ã®ã
ã®ã§ãã€ãã äžèšã®ããã©ãã¯æš¹èãç²ç ããŠããããµã¡
ãã¬ã³ããã©ãã³15ééïŒ ãæ··åããæ··åç©ã
çªçŽ ã¬ã¹äžã160âã®æž©åºŠã§120åéç±ç¡¬åã次
ãã§ãããŒã«ãã«ã§ç²ç ããŠ150ã¿ã€ã©ãŒã¡ã
ã·ãŠã®ç¯©ãééãããããããããŠåŸãç²æ«
ã¯ãäžè¿°ããã®ãšåäžã®æ¡ä»¶ã§ã0.5ééïŒ ã®
ã¢ã³ã¢ãã¢ãš50ééïŒ ã®ã¡ã¿ããŒã«ãããªãæ··
å氎溶液ã§åŠçããæž©æ°Žã§æŽãã次ãã§ä¹Ÿç¥ã
ããããããŠåŸãè©Šæã®æ§è³ªãRunNo.22ãšããŠ
第ïŒè¡šã«èšèŒããã æŽã«ãäžèšããã©ãã¯æš¹èãååŸ0.25mmÏã
åæ°120ã®çŽ¡ç³žå£éãçšããŠã136ã138âã®æž©
床ã§æº¶è玡糞ãè¡ãªã€ããåŸãããå¹³åç¹ç¶21
ãããŒã«ã®çŽ¡åºç³žãå¡©é žæ¿åºŠ18ééïŒ ãšãã«ã
ã¢ã«ãããæ¿åºŠ18ééïŒ ãããªãæ··å氎溶液ã«
20ã21âã®æž©åºŠã§60åé浞挬ãã次ãã§97âã®
枩床ã«ãŸã§ïŒæéãèŠããŠææž©ãã9.7ã98â
ã®æž©åºŠã§10æéä¿æãããããããŠåŸã硬åã
ãã©ãã¯ç¹ç¶ãäžè¿°ããã®ãšåäžã®æ¡ä»¶ã§æž©æ°Ž
æŽåŸ0.5ééïŒ ã®ã¢ã³ã¢ãã¢ãš50ééïŒ ã®ã¡ã¿
ããŒã«ãããªãæ··å氎溶液ã§åŠçããæž©æ°Žã§æŽ
ãã次ãã§ä¹Ÿç¥ããããã®ãã®ãããŒã«ãã«ã§
ç²ç ããã150ã¿ã€ã©ãŒã¡ãã·ãŠã®ç¯©ãééã
ããã®ã®æ§è³ªãRunNo.23ãšããŠç¬¬ïŒè¡šã«èšèŒã
ãã (3) 第ïŒè¡šã«ã¯äœ¿çšããå¡©é žããã«ã ã¢ã«ããã
ããã³å¡©é žãšãã«ã ã¢ã«ãããã®åèšæ¿åºŠãã
ãšããŒã«ãšå°¿çŽ ãšã®åèšééã«å¯Ÿããå¡©é žâã
ã«ã ã¢ã«ããã溶液ã®ééã®å²åããã³ãã«ã
ã¢ã«ãããïŒã¢ã«ïŒå¯ŸããšããŒã«ïŒã¢ã«ïŒãšå°¿
çŽ ïŒã¢ã«ïŒãšã®åèšã®ã¢ã«æ¯ã瀺ããããŸãã
第ïŒè¡šã«ã¯åŸãããè©Šæã®é¡åŸ®é¡èŠ³å¯ã«ãã
0.1ã50ÎŒããã³0.1ã100ÎŒã®ç²åã®å«æçã
åŸãããè©Šæã150ã¿ã€ã©ãŒã¡ãã·ãŠã®ç¯©ã«ã
ããå Žåã®ç¯©éééïŒ150ã¡ãã·ãŠãã¹ïŒãã
ã³åŸãããè©Šæã®èµ€å€åžåã¹ãã¯ãã«æ³ã«ãã
960ã1020cm-1ã1280ã1360cm-1ããã³1580ã
1650cm-1ã«ãããåžå匷床ã®1450ã1500cm-1ã®
åžå匷床ã«å¯Ÿããåžåæ³¢é·åŒ·åºŠæ¯ïŒIR匷床
æ¯ïŒã瀺ããã
ãããããã«è©³ããã¯ãç¡æ©è³ªææç²æ«ãšå ±ã«ã
æµãç¹æ§ãè¯å¥œã§äžã€åå¿æ§ãæãããèªäœã§ã
ãããã¯çš®ã ã®ç¡æ©è³ªææç²æ«ãšæ··åããŠåªãã
æ圢æ§ããã³çååçã瀺ãæ°èŠãªç²ç¶ãªããç²
æ«ç¶å«çªçŽ ããšããŒã«ã»ã¢ã«ãããæš¹èãå«æ
ãããããŠåªããæ©æ¢°çæ§è³ªçã®çš®ã ã®åªããæ§
質ã瀺ãã»ã©ããã¯ã¹çã®ç¡æ©è³ªæ圢äœã補é ã
ãã«å¥œé©ãªãåªããæ圢æ§ãæããçµæç©ã«é¢ã
ãã åŸæ¥ãããšããŒã«ã»ã¢ã«ãããæš¹èã®ä»£è¡šçãª
ãã®ãšããŠããã©ãã¯æš¹èãšã¬ãŸãŒã«æš¹èãšãç¥
ãããŠãããããã©ãã¯æš¹èã¯ãéåžžãããšããŒ
ã«å¯Ÿãã«ã ã¢ã«ãããã®ã¢ã«æ¯ãäŸãã°ïŒå¯Ÿ0.7
ã0.9ãšãªããããªããšããŒã«éå°ã®æ¡ä»¶äžã§ã
äŸãã°ã·ãŠãŠé žã®åŠãé žè§Šåªã®ååšäžïŒéåžž0.2
ãïŒïŒ ïŒã§ããšããŒã«ãšãã«ããªã³ãšãåå¿ãã
ãããšã«ãã€ãŠè£œé ããããããããªæ¹æ³ã§åŸã
ããããã©ãã¯æš¹èã¯ãããšããŒã«ãäž»ãšããŠã¡
ãã¬ã³åºã«ãã€ãŠçµåãããïŒãïŒéäœãäž»æå
ããªããéé¢ã¡ãããŒã«åºãæ®ãã©å«æãããåŸ
ã€ãŠããèªäœã§ã¯èªå·±æ¶æ©æ§ãæãããç±å¯å¡æ§
ãæããã ããã§ããã©ãã¯æš¹èã¯ãäŸãã°ãããµã¡ãã¬
ã³ããã©ãã³ïŒãããµãã³ïŒã®åŠãããèªäœãã«
ã ã¢ã«ãããçºçå€ã§ãããšå ±ã«ææ©å¡©åºïŒè§Š
åªïŒçºçå€ã§ããæ¶æ©å€ãšå ç±äžã§åå¿ããã
ããåã¯äŸãã°åºäœé žè§Šåªãšãã©ãã«ã ã¢ã«ãã
ãçãšæ··åããå ç±åå¿ãããããšã«ãã€ãŠã硬
åæš¹èãšããããšãã§ããã ããã©ãã¯æš¹èã¯ç²æ«ç¶ã§åæ±ãã容æã§ãã
ããç¡æ©è³ªææç²æ«ãå€éã«å«ãæ圢äœãå ç±ç¡¬
åãããéæ圢äœã®è¡šé¢ããå éšã«åã€ãŠç¡¬åå
å¿ãé²è¡ãããã°ãã°å éšãå åã«ç¡¬åããŠããª
ã硬åç©ãäžããããŸããã®ããããã®ãããªç¡¬
åç©ãããã«é«æž©åºŠã«å ç±ããŠçŒæã«ä»ããšãã«
ã¯ãå éšã«ãããŠã¬ã¹ãçºçããŠæ圢åã«äºè£ã
ã¬ã¹ã¶ãããçããçŒæãé²ãã«ã€ããŠãã®äºè£
ãã¬ã¹ã¶ãããæŽã«é¡èãšãªããæºè¶³ãªå質ã®ç¡
æ©è³ªæ圢äœã補é ããããšã¯éåžžã«å°é£ã§ããã ãŸããã¬ãŸãŒã«æš¹èã¯é垞溶液ãšããŠäŸçµŠãã
åŸã€ãŠãè±æº¶åªãããèªäœã§æ圢åãšããããšã¯
è±æº¶åªã®éã²ã«ååå¿ãæ¥æ¿ã«é²è¡ãçºæ³¡ããã®
ã§éåžžã«å°é£ã§ããããã®ãããå å¡«ç©è³ªãçšã
ãŠè±æº¶åªããŠæ圢ããããšãæ®éè¡ãªãããŠã
ããç¡æ©è³ªææç²æ«ãçšããå Žåã«ã¯ããæ è±æº¶
åªãæ¯èŒç容æã«è¡ãªããããããããªãããã
ã®ãããªæ圢åãå ç±ããŠã硬åãããã¯çŒæã«
ä»ããšãã«ã¯äŸç¶ãšããŠã²ã«ååå¿ãæ¥æ¿ã«é²è¡
ãããããäžèšããã©ãã¯æš¹èã®å Žåãšåæ§ã«ã¬
ã¹ã¶ãããäºè£ãçãã匷床ãããã¯ç¡¬åºŠã®ç¹ã§
æºè¶³ãªå質ã®ç¡æ©è³ªæ圢äœã補é ããããšã¯éåžž
ã«å°é£ã§ããã ãŸããæ¯èŒçè¿å¹Žã«è³ã€ãŠãããã©ãã¯æš¹èã
é«æž©äžã§å ç±ããŠå¯æãçž®å床ã®å€§ããªãã®ã
åŸãããã粟補ããŠäœçž®åç©ãåé¢ãé€å»ããŠã
ãšããŒã«åºãïŒã10åã¡ãã¬ã³åºã§çµåãããæ¯
èŒçé«çž®åäœãåŸããããå ç±æº¶è玡糞ããŠãã
ã©ãã¯æš¹èç¹ç¶ã圢æããããã®å¡©é žã»ãã«ã ã¢
ã«ãããæ··å氎溶液äžã«æµžæŒ¬ããŠã宀枩ããåŸã
ã«å æž©ããŠé·æéãããŠè©²ç¹ç¶ã®å€éšãã硬åå
å¿ãé²è¡ãããããšã«ãã硬åããã©ãã¯æš¹èç¹
ç¶ã補é ããæ¹æ³ãææ¡ãããïŒç¹å ¬æ48â
11284å·ïŒã ããããªãããäžèšã®åŠãããŠè£œé ãã硬åã
ãã©ãã¯ç¹ç¶ãæªæåã¯ç²ç ãããã®ã¯é«äŸ¡ãªã
ã®ãšãªãã°ããã§ãªããæ圢ææãšããŠæµãç¹æ§
ã®ããç²ç¶åã¯ç²æ«ç¶ã®ãã®ãšããããšãã§ããª
ãã®ã§è©²ç¹ç¶ãåäžã«åæ£ããæåäœã補é ãã
ããšã¯å°é£ã§ããã ãŸãè¿å¹Žã«ããã€ãŠãããšããŒã«é¡ãšãã«ã ã¢
ã«ããããšãå°ããšãå«çªçŽ ç³»ååç©ã®ååšäžã§
åå¿ãããŠåŸãããçž®åç©ã«èŠªæ°Žæ§é«ååååç©
ãæ·»å ããåå¿ãããŠç²ç¶ãªããç²æ«ç¶æš¹èã補
é ããæ¹æ³ãçºè¡šãããŠãããïŒç¹å ¬æ53â
42077å·ïŒããã®æ¹æ³ã§åŸãããæš¹èã®éã²ã«åç©
ã¯çŽïŒãïŒïŒ ãšããå€éã®éé¢ããšããŒã«ãå«æ
ãïŒåå®æœäŸïŒãïŒïŒããã®ã²ã«åç©ïŒåå®æœäŸ
ïŒïŒã¯æ¥µããŠç¡¬ãéåå¿æ§æš¹èãšãªãã°ããã§ãª
ãã芪氎æ§é«ååååç©ãå«æããããã®ããã
ããå å¡«å€ãšããŠçšããŠåŸãããæ圢åã硬åã
ããã¯çŒæããŠåŸãããç¡æ©è³ªæ圢äœã«äºè£ãã¬
ã¹ã¶ãããçããæ¬ ç¹ãããã ããã«ãããšããŒã«ãšãã«ã ã¢ã«ããããå¡©åº
æ§æ°Žæº¶æ¶²äžã§åå¿ãããŠåŸããããã¬ããªããŒã
ä¿è·ã³ãã€ããšæ··åããé žæ§äžã§äžæŽ»æ§åºåœ¢ããŒ
ãºç¶ã«ååºãããæ¹æ³ãå ¬ç¥ã§ãããïŒç¹å ¬æ51
â13491å·ïŒãããã¯æè¬ã¬ãŸãŒã«æš¹è硬åç©ã«çž
åœããåå¿æ§ãæããããã®äžå¡©é¡ãé žããã®ä»
ä¿è·ã³ãã€ããå«æããããã«åæ§ã«ãããå å¡«
å€ãšããŠçšããŠåŸãããæ圢åã硬åãããã¯çŒ
æããŠåŸãããç¡æ©è³ªæ圢äœã«äºè£ãã¬ã¹ã¶ãã
ãçããæ¬ ç¹ãããã äžèšã®åŠããåŸæ¥ããšããŒã«ã»ã¢ã«ãããæš¹è
ãæ圢åã®å å¡«å€ãšããŠäœ¿çšããè©Šã¿ã¯ãªãããŠ
ããããæ圢åã®å å¡«å€ãšããŠèŠããšãããšããŒ
ã«ã»ã¢ã«ãããæš¹èãå å¡«å€ã«é©ãã圢ç¶ããã
ã¯åœ¢æ ã®ãã®ãšããŠååŸããããšèªäœã第ïŒã«å°
é£ã§ããããŸã硬åãããã¯çŒæã®éã«æ圢åã«
察ãæãŸãããªã圱é¿ãäžããç©è³ªãå«æãããš
ããåé¡ãæããŠããã æ¬çºæè ãã¯ãå ã«äžèšã®åŠãæ¬ ç¹ãæããªã
æ°èŠãªå«çªçŽ ããšããŒã«ã»ã¢ã«ãããæš¹èã®ç²ç¶
ãªããç²æ«ç¶äœããã³ãã®è£œé æ¹æ³ãæäŸããã ããæ ãæ¬çºæã®ç®çã¯ãæ°èŠãªç²ç¶ãªããç²
æ«ç¶å«çªçŽ æš¹èãšç¡æ©è³ªææç²æ«ãšãå«æããŠæ
ãçµæç©ãæäŸããããšã«ããã æ¬çºæã®ä»ã®ç®çã¯ãç²ç¶ãªããç²æ«ç¶ã§ãã€
ãŠæµãç¹æ§ãè¯å¥œãªç²ç¶ãªããç²æ«ç¶å«çªçŽ æš¹è
ã®å°ããå²åããç¡æ©è³ªææç²äœã®å€§ããªå²åãš
å ±ã«å«æãããæ圢æ§ã®è¯å¥œãªçµæç©ãæäŸãã
ããšã«ããã æ¬çºæã®æŽã«ä»ã®ç®çã¯ãããåç¬ã§åã¯ä»ã®
æš¹èãšã®åå¿æ§ãæããç²ç¶ãªããç²æ«ç¶å«çªçŽ
æš¹èãçšããããšã«ãã€ãŠã硬åãããã¯çŒæã«
ãã€ãŠäºè£ãã¬ã¹ã¶ãããå°ãªãäžã€å éšãšå€éš
ãšã§å質ããã®æ®ãã©ãªãå質ãªç¡æ©è³ªæ圢äœã
äžãåŸãçµæç©ãæäŸããããšã«ããã æ¬çºæã®æŽã«ä»ã®ç®çã¯ãåªããè¡ææ§ã®åŠã
æ©æ¢°çæ§è³ªãæããããã¯åªããé»æ°çç¹æ§ã瀺
ãç¡æ©è³ªæ圢äœãäžãããçµæç©ãæäŸããããš
ã«ããã æ¬çºæã®æŽã«ä»ã®ç®çã¯ãåªããæ©æ¢°çæ§è³ªã
æããããã¯åªããèç±æ§ãæºåç¹æ§ãããã¯è
ååŠè¬åæ§ã瀺ãç¡æ©è³ªæ圢äœãäžãããçµæç©
ãæäŸããããšã«ããã æ¬çºæã®æŽã«ä»ã®ç®çããã³å©ç¹ã¯ä»¥äžã®èª¬æ
ããæãããšãªãã æ¬çºæã®ãããç®çããã³å©ç¹ã¯ãæ¬çºæã«ã
ãã°ã (1) ããšããŒã«é¡ãå°ããšãïŒåã®æŽ»æ§æ°ŽçŽ ãæ
ããå«çªçŽ ååç©ããã³ã¢ã«ããããšã®çž®åç©
ããæãç²ç¶ãªããç²æ«ç¶æš¹èã§ãã€ãŠã (A) 該ç²ç¶ãªããç²æ«ç¶æš¹èã¯ç²åŸ0.1ã100ã
ã¯ãã³ã®çç¶äžæ¬¡ç²åããã³ãã®äºæ¬¡åéç©
ãå«æãããã㊠(B) 該暹èã®KBré å€æ³ã«ããèµ€å€ç·åžåã¹ã
ã¯ãã«ã«ãããŠã 1450ã1500cm-1ã®ç¯å²ã®æã倧ããªåžå匷
床ã1450ã1500ããã㊠960ã1020cm-1ã®ç¯å²ã®æã倧ããªåžå匷
床ã960ã1020ã ã§è¡šãããå Žåã 960ã1020ïŒïŒ€1450ã1500ïŒ0.1ã2.0ã§ã
ãã ã®ç²ç¶ãªããç²æ«ç¶ã®å«çªçŽ ããšããŒã«ã»ã¢ã«
ãããæš¹èãšã (2) ç¡æ©è³ªææç²äœã ãšãå«æããäžã€ äžèšå«çªçŽ ããšããŒã«ã»ã¢ã«ãããæš¹èãã該
å«çªçŽ ããšããŒã«ã»ã¢ã«ãããæš¹èãšè©²ç¡æ©è³ª
ææç²äœã®åèšéã«åºã¥ããŠ11ééïŒ ããå°ã
éã§å«æãããããšãç¹åŸŽãšããçµæç©ã«ãã€
ãŠéæãããã æ¬çºæã«ãããŠçšãããããããç²ç¶ãªããç²
æ«ç¶å«çªçŽ ããšããŒã«ã»ã¢ã«ãããæš¹èã¯ãããš
ããŒã«ãåã¯å°ããšã50ééïŒ ç¹ã«å°ããšã70é
éïŒ ã®ããšããŒã«ãå«æããããšããŒã«ãšäŸãã°
ïœâã¯ã¬ãŸãŒã«ãïœâã¯ã¬ãŸãŒã«ãïœâã¯ã¬ãŸãŒ
ã«ããã¹âããšããŒã«ïŒ¡ãïœâãïœâåã¯ïœâ
C2ãC4ã¢ã«ãã«ããšããŒã«ãïœâããšãã«ããš
ããŒã«ããã·ã¬ããŒã«ãã¬ãŸã«ã·ããŒã«çå ¬ç¥ã®
ããšããŒã«èªå°äœã®ïŒçš®åã¯ãã以äžãšã®æ··åç©
ãšãå°ãªããšãïŒåã®æŽ»æ§æ°ŽçŽ ãæããå«çªçŽ å
åç©ããã³ã¢ã«ããããšã®çž®åç©ãå å«ããã æ¬çºæã®çµæç©ã«ãããäžèšç²ç¶ãªããç²æ«ç¶
å«çªçŽ æš¹èã¯äžèšãã(A)ããã³(B)ã®ç¹æ§ãæã
ããåèš(A)ããã³(B)ã®ç¹å®ã«ãããŠã (A)ã®çç¶äžæ¬¡ç²åããã³ãã®äºæ¬¡åéç©ã®ç²åŸ
ã0.1ã100ãã¯ãã³ã§ãããšããç¹å®ã (B)ã®ïŒ€960ã1020ïŒïŒ€1450ã1500ïŒ0.1ã2.0ãšãã
ç¹å®ã ã¯ããããåŸè¿°ãã枬å®æ³ã«åºã¥ããã®ã§ããã äžèšç²ç¶ãªããç²æ«ç¶å«çªçŽ æš¹èã®ç¬¬ïŒã®ç¹åŸŽ
ã¯ãåŸæ¥å ¬ç¥ã®ããã©ãã¯æš¹èã®ç¡¬å補ååã¯ã¬
ãŸãŒã«æš¹èã®ç¡¬å補åãç²ç ããããšã¯æ¥µããŠå°
é£ã§ãããããã匷ãã§ç²ç ãããã®ãæã¯åŸæ¥
å ¬ç¥ã®ç¡¬åããã©ãã¯æš¹èç¹ç¶ãç²ç ãããã®ç
ãšã¯å šãç°ã€ãŠãåèš(A)ã«ç¹å®ãããšããããã
ã®æ®ãã©ãçç¶äžæ¬¡ç²åããã³ãã®äºæ¬¡åéç©
ã§ãç²åŸã0.1ã100ãã¯ãã³ã®ãã®ã奜ãŸããã¯
0.1ã50ãã¯ãã³ã®ãã®ãå«æããã äžèšç²ç¶ãªããç²æ«ç¶å«çªçŽ æš¹èã¯ãéåžžãã®
å°ããšã30ïŒ ã奜ãŸããã¯å°ããšã50ïŒ ãç²åŸ
0.1ã100ãã¯ãã³ãããã«å¥œãŸããã¯0.1ã50ã
ã¯ãã³ã®çç¶äžæ¬¡ç²åããã³ãã®äºæ¬¡åéç©ãã
æãããã®30ïŒ åã¯50ïŒ ãšãã衚瀺ã¯ãåŸèšã®ç²
åŸæž¬å®æ³ã«ãããŠå®çŸ©ãããšãããåçã100ã
1000åã®å åŠé¡åŸ®é¡ã®ïŒã€ã®èŠéã«ãããå šäœã®
ç²åïŒäºæ¬¡åéç©ãå«ãïŒã®æ°ã®30ïŒ åã¯50ïŒ ãš
ããæå³ã§ãããç¹ã«å¥œãŸãããã®ã¯ã該ç²ç¶ãª
ããç²æ«ç¶å«çªçŽ æš¹èã®70ä¹è³å®è³ªçã«100ïŒ ã
ç²åŸ0.1ã100ãã¯ãã³ã®çç¶äžæ¬¡ç²åããã³ãã®
äºæ¬¡åéç©ããæããã®ã§ããã ç¹ã«å¥œãŸãããã®ã¯ãäžèšå®çŸ©ã«ããå åŠé¡åŸ®
é¡åçã®èŠéã®ç²åã®æ°ïŒïŒã€ã®èŠéã®å¹³åå€ãš
ããŠïŒã®å°ããšã30ïŒ ãç¹ã«å°ããšã50ïŒ å°±äž70
ä¹è³å®è³ªçã«100ïŒ ã0.1ã50ãã¯ãã³ããã奜ãŸ
ããã¯0.1ã20ãã¯ãã³ã®ç¯å²ã®çç¶äžæ¬¡ç²åã
ãã³ãã®äºæ¬¡åéç©ããæãã äžèšã®ç²ç¶ãªããç²æ«ç¶å«çªçŽ æš¹èã¯ã以äžã®
ãšãããäžèšã®çç¶äžæ¬¡ç²åããã³ãã®äºæ¬¡åé
ç©ã®åŸ®å°ç²åãäžå¿ãšãªã€ãŠåœ¢æããããã®ã§ã
ããã極ããŠåŸ®å°ã§ãã€ãŠãå šäœã®å°ããšã50é
éïŒ ã奜ãŸããã¯70ééïŒ ãç¹ã«å¥œãŸããã¯å šäœ
ã®å°ããšã80ééïŒ ã¯150ã¿ã€ã©ãŒã¡ãã·ãŠã®ç¯©
ãééããããã®ãããªç¯©ãééãããšãã衚瀺
ã¯ãæ¬çºæã«ãããŠçšããããç²ç¶ãªããç²æ«ç¶
補åã該篩ã§ç¯ãæäœã«ãããŠã該ç²ç¶ãªããç²
æ«ç¶è£œåã軜ãæã§ãã¿ã»ãããšããã¯ãæ§ã®ã
ã®ã§ç¯©ç®äžã®ç²åã軜ãæŒãããããªããããã
ããšããæã¯æã§è»œãå©ãçã®è©²ç²åïŒäºæ¬¡åé
ç©ãå«ãïŒã匷å¶çã«ç Žå£ãããããªãã®ã§ãªã
åãå ããããšãäœçæé€ãããã®ã§ã¯ãªãã äžèšã®ç²ç¶ãªããç²æ«ç¶å«çªçŽ æš¹èã¯ããã«ã
åèš(B)ã§ç¹å®ãããŠãããšãããèµ€å€ç·åžåã¹ã
ã¯ãã«ã«ãããŠã 960ã1020ïŒïŒ€1450ã1500ïŒ0.1ã2.0 奜ãŸããã¯ãæŽã« 1280ã1360ïŒïŒ€1450ã1500ïŒ0.15ã3.0ãšããç¹
æ§ãæããã ãŸããæ¬çºæã«çšããããç²ç¶ãªããç²æ«ç¶ã®
å«çªçŽ æš¹èã®å¥œãŸãããã®ã¯ã 960ã1020ïŒïŒ€1450ã1500ïŒ0.15ã0.6 奜ãŸããã¯ãæŽã« 1280ã1360ïŒïŒ€1450ã1500ïŒ0.2ã2.0ãšããç¹æ§
ãæããç¹ã«å¥œãŸãããã®ã¯ã 960ã1020ïŒïŒ€1450ã1500ïŒ0.2ã0.4 奜ãŸããã¯ãæŽã« 1280ã1360ïŒïŒ€1450ã1500ïŒ0.3ã1.5ãšããç¹æ§
ãæããã ãŸããæ¬çºæã«çšããããç²ç¶ãªããç²æ«ç¶ã®
å«çªçŽ æš¹èã¯ãæŽã«ã KBré å€æ³ã«ããèµ€å€ç·åžåã¹ãã¯ãã«ã«ãã
ãŠã1580ã1650cm-1ã®ç¯å²ã®æã倧ããªåžå匷床
ã1580ã1650ã§è¡šãããå Žåã 1580ã1650ïŒïŒ€1450ã1500ïŒ0.3ã4.5 ïŒå¥œãŸããã¯0.75ã2.0ãç¹ã«å¥œãŸããã¯1.0ã
1.5ïŒ ã§ãããèµ€å€ç·åžåã¹ãã¯ãã«ã«ãããç¹åŸŽãæ
ããŠããã äžè¬ã«ãäžæ¬¡å æ¶æ©æ§é ãæããç©è³ªã®åçš®å®
èœåºã®åž°å±ãèµ€å€ç·åžåã¹ãã¯ãã«ã§ç¢ºå®ããã
ãšã¯é£ãããããªãã¡èµ€å€ç·åžåã¹ãã¯ãã«å³ã«
ãããããŒã¯ã倧ããã·ããããããšãå€ããã
ã§ããã ããããªãããããšããŒã«ã»ã¢ã«ãããæš¹èã
çš®ã ã®å«çªçŽ ååç©ã®èµ€å€ç·åžåã¹ãã¯ãã«ã
ããæ¬çºæã«ãããèµ€å€ç·åžåã¹ãã¯ãã«ã«ãã
ãäžèšåžåã¯ã 960ã1020cm-1ã®åžåã¯ã¡ãããŒã«åºã«åž°å±ã
ãããŒã¯ã§ããã1280ã1360cm-1ã®åžåã¯ççŽ çª
çŽ çµåã«åž°å±ããããŒã¯ã§ããããããŠ1450ã
1500cm-1ã®åžåã¯è³éŠæäºéçµåã«åž°å±ããããŒ
ã¯ã§ãããšæ±ºããããã ãŸãã1580ã1650cm-1ã®åžåã®åž°å±ã«æ確ã«ã
é£ããããã®åžåã®åŒ·åºŠãçšããäžèšæ¯ç1580
ãïŒïŒïŒïŒïŒïŒ€1450ã1500ã®å€ã¯ãçªçŽ ãå«æããªãã
ãšããŒã«ã»ãã«ã ã¢ã«ããã系暹èã«ããããã®
æ¯çãšæ確ã«åºå¥ãåŸãå€ã瀺ããããæ¬çºæã®
æš¹èãç¹å®ããããã«åæ§ãªç¹åŸŽçãªåžåãšããŠ
èªèã§ããã æ¬çºæã«çšããããç²ç¶ãªããç²æ«ç¶å«çªçŽ æš¹
èãç¹å®ããããã®ïŒã€ã®ãã©ã¡ãŒã¿ãŒã§ããã
èµ€å€ç·åžåã¹ãã¯ãã«ã«ãããäžèšã®åŠãåžå匷
床ã®æ¯ãäŸãã°ïŒ€960ã1020ïŒïŒ€1450ã1500ïŒ0.1ã
2.0ãšããç¯å²ã¯æ¬çºæã«çšããããå«çªçŽ æš¹è
ãããªãã®çšåºŠã®éã§ã¡ãããŒã«åºãå«æããŠã
ããããããã®ã¡ãããŒã«åºã®å«éãããçšåºŠã®
ç¯å²ã§èª¿æŽãåŸããã®ã§ããããšãããããªæ§é
ãšçµã³ã€ããç¹æ§å€ãè¡šãããŠãããšç解ã§ã
ãã æ¬çºæã§çšããããç²ç¶ãªããç²æ«ç¶å«çªçŽ æš¹
èã¯æ¶²äœã¯ãããã°ã©ãã€ãŒã«ãã枬å®å€ãšããŠ
éé¢ããšããŒã«å«æéãéåžž500ppm以äžã§ã
ããããã«å¥œé©ãªè£œåã¯è©²éé¢ããšããŒã«å«æé
ã300ppm以äžãå°±äž100ppm以äžã§ãããåèš
ç¹å ¬æ53â42077å·ã«é瀺ãããæ¹æ³ã«ããåŸã
ããç²ç¶ãªããç²æ«ç¶æš¹èã¯0.3ãçŽïŒééïŒ ãš
ãã極ããŠå€éã®éé¢ããšããŒã«ãå«æããã®ã«
察ããŠãæ¬çºæã§çšããããç²ç¶ãªããç²æ«ç¶å«
çªçŽ æš¹èã®éé¢ããšããŒã«å«æéã¯æ¥µããŠå°éã§
ããããã®äºå®ã¯ãã®çš®ç²ç¶ãªããç²æ«ç¶æš¹èã«
ãšã€ãŠäœ¿çšäžã®éèŠãªå©ç¹ãšãªãã æ¬çºæã§çšããããç²ç¶ãªããç²æ«ç¶å«çªçŽ æš¹
èã¯ãå€ãã®ãã®ããå°ããšãïŒééïŒ å¥œãŸãã
ã¯ïŒã30ééïŒ ã®çªçŽ ãå«æããããšãæãããš
ãããŠããã æ¬çºæã§çšããããç²ç¶ãªããç²æ«ç¶å«çªçŽ æš¹
èã¯ãåŸã«èšè¿°ãã補é æ¹æ³ã«åŸã€ãŠç¡¬ååå¿ã
ããçšå åã«é²è¡ããŠããªããã®ãæãã¯ç¡¬åå
å¿ãæ¯èŒçé²è¡ãããã®ã®ãããã®ç¶æ ããšãã
ãšãã§ããããã®çµæãæ¬çºæã§çšããããç²ç¶
ãªããç²æ«ç¶å«çªçŽ æš¹èã«ã¯ãç±çã«ã¯ãåŸã«èš
èŒããå ç±èç枬å®æ³ã«åŸã€ãŠ100âã®æž©åºŠã§ïŒ
åéå å§ããå Žåã«ã(a)å°ããšããã®ïŒéšãèç
ããŠå¡ç¶ãªããæ¿ç¶äœãšãªããã®ãåã³(b)å®è³ªç
ã«æº¶èåã¯èçããã«ç²ç¶ãªããç²æ«ç¶ã®åœ¢æ ã
ãšããã®ã®åæ¹ãå«ãŸããã äžèš(a)ã®æ¯èŒçèçæ§ã®å€§ããªæš¹èã«ã¯ãåŸã«
èšèŒããè©Šéšæ¹æ³ã«åŸã€ãŠã¡ã¿ããŒã«ã«å¯Ÿãã溶
解æ§ã枬å®ãããš20ééïŒ ä»¥äžãããã«ã¯30éé
ïŒ ä»¥äžãå€ããã®ã§ã¯40ééïŒ ä»¥äžã®ã¡ã¿ããŒã«
溶解æ§ã瀺ãæš¹èãå å«ãããã ãŸããæ¬çºæã§çšããããç²ç¶ãªããç²æ«ç¶å«
çªçŽ æš¹èã¯ãåŸè¿°ãã補é æ¹æ³ããæãããªãšã
ããåå¿ç³»å ã«èŠªæ°Žæ§é«ååååç©ãå®è³ªçã«å«
æããªã補é æ¹æ³ã«ãã補é ããããããé垞芪
æ°Žæ§é«ååååç©ãå®è³ªçã«å«æããŠããªããã
ã®ãããªå«çªçŽ å¡©åºæ§ååç©ã芪氎æ§é«åååå
ç©ã¯ã硬åãããã¯çŒæã®éãã°ãã°æçµæ圢äœ
ã«ã¯ã©ãã¯ãã¬ã¹ã¶ãããçºçãããåå ãšãª
ãã æ¬çºæã«ãããŠçšããããäžèšç²ç¶ãªããç²æ«
ç¶å«çªçŽ æš¹èã¯ã (1) äžèšçµæ ã€ å¡©é žïŒHClïŒæ¿åºŠãïŒã28ééïŒ ã ã ãã«ã ã¢ã«ãããïŒHCHOïŒæ¿åºŠãïŒã
25ééïŒ ããã³ãã«ã ã¢ã«ããã以å€ã®ã¢ã«
ãããã®æ¿åºŠãïŒã10ééïŒ ãäžã€ ã å¡©é žãšãã«ã ã¢ã«ãããã®åèšæ¿åºŠã10ã
40ééïŒ ã ã§ããå¡©é žâã¢ã«ã ã¢ã«ããã济ã«ã (2) ããšããŒã«é¡ãšå°ããšãïŒåã®æŽ»æ§æ°ŽçŽ ãæ
ããå«çªçŽ ååç©ãšããäžèšåŒïŒïŒã 济æ¯ïŒäžèšå¡©é žâãã«ã ã¢ã«ããã济ã®ééïŒäžèšããšããŒã«é¡ã®ééïŒäžèšå«çªçŽ ååç©ã®éé ã§è¡šãããã济æ¯ãå°ããšãïŒä»¥äžãšãªããã
ã«ç¶æããŠãæ¥è§Šãããããšã«ãã€ãŠè£œé ãã
ããšãã§ããã äžèš(1)ã®å¡©é žâãã«ã ã¢ã«ããã济ã®çµæãšã
ãŠã¯ãäžèšã€ïŒïŒãïŒïŒãïŒã®ïŒæ¡ä»¶ã®ä»ã«ããã
ã«æ¡ä»¶ãïŒãšã㊠該济äžã®ãã«ã ã¢ã«ãããïŒã¢ã«ïŒïŒè©²æµŽã«æ¥è§ŠããããšããŒã«é¡ïŒã¢ã«ïŒãšå«çªçŽ ååç©ïŒã¢ã«ïŒãšã®åèšã®ã¢ã«
æ¯ ãå°ããšãïŒä»¥äžãæ®ã«2.5以äžãå°±äžïŒä»¥äžãš
ãªãããã«ããããšã奜é©ã§ãããäžèšæ¡ä»¶ãã®
ã¢ã«æ¯ã®äžéã¯ç¹ã«éå®ãããªããã20以äžããª
ãããã«ããããšã奜é©ã§ãããäžèšæ¡ä»¶ãïŒã®
ã¢ã«æ¯ã®äžéã¯ç¹ã«éå®ãããªããã20以äžãç¹
ã«15以äžã奜é©ã§ãããäžèšã¢ã«æ¯ã¯ç¹ã«ïŒã
15ãå°±äžïŒã10ã奜é©ã§ãããäžèšè£œé æ³ã®ç¹åŸŽ
ã¯ããããã«å¡©é žïŒHClïŒæ¿åºŠãå¯æãé«æ¿åºŠã§
ãããããšããŒã«é¡ãšå«çªçŽ ååç©ãšã«å¯ŸããŠã
ã«ã ã¢ã«ããããéå°ã«å«æããå¡©é žâãã«ã ã¢
ã«ããã氎溶液ã®æµŽãã济æ¯ãïŒä»¥äžã奜ãŸãã
ã¯10以äžãšãã倧ããªæ¯çã§ããšããŒã«é¡ããã³
å«çªçŽ ååç©ãšæ¥è§Šãããããšã«ããã ããªãã¡ãæŽã«èª¬æãããšãäžèšæ¹æ³ã¯äžèšã®
åŠãå¡©é žãšãã«ã ã¢ã«ãããã®ããããã®æ¿åºŠã
ïŒééïŒ ä»¥äžã§ããã济æ¯ãïŒä»¥äžãšããæ¡ä»¶äž
ã§è¡ãªãããã®ã§ãããšããŒã«é¡ãšå«çªçŽ ååç©
ãšã®åèšééã«å¯Ÿããå¡©é žåã³ãã«ã ã¢ã«ããã
ã®ééæ¯çã¯ããããå°ããšã24ééïŒ ãšãªãã
ãŸããäžèšæ¹æ³ã¯äžèšã®åŠãå¡©é žãšãã«ã ã¢ã«ã
ãããšã®åèšæ¿åºŠã10ééïŒ ä»¥äžã§è¡ãªãããã®
ã§ãããšããŒã«é¡ãšå«çªçŽ ååç©ãšã®åèšééã«
察ããå¡©é žãšãã«ã ã¢ã«ãããã®åèšééã¯80é
éïŒ ä»¥äžãšãªããããããªåå¿æ¡ä»¶ã¯æ¢è¿°ã®ãšã
ãåŸæ¥å ¬ç¥ã®ããã©ãã¯æš¹èããã³ã¬ãŸãŒã«æš¹è
補é ã®åå¿æ¡ä»¶ãšã¯æ ¹æ¬çã«ç°ã€ãŠããã å¡©é žâãã«ã ã¢ã«ããã济ã«ããšããŒã«é¡ãšå«
çªçŽ ååç©ãšãæ¥è§Šãããéã®åèšåŒïŒïŒã§è¡š
ãããã济æ¯ã¯ã10以äžãæ®ã«15ã40ãšããããš
ã奜ãŸããã å¡©é žâãã«ã ã¢ã«ããã济ã«ããšããŒã«é¡ãšå«
çªçŽ ååç©ãšãæ¥è§Šãããã«ã¯ããšããŒã«é¡ã該
济ãšæ¥è§ŠããåŸçœæ¿ãçæããç¶ãåŸç²ç¶ãªãã
ç²æ«ç¶ã®åºåœ¢ç©ã圢æãããããã«è¡ããè©²å¡©é ž
âãã«ã ã¢ã«ããã济ãšããšããŒã«é¡ããã³å«çª
çŽ ååç©ãšã®æ¥è§Šã¯ãè©²å¡©é žâãã«ã ã¢ã«ããã
济äžã«ããšããŒã«é¡ãšå«çªçŽ ååç©ãšãäžç·ã«æ·»
å ãããåã¯å«çªçŽ ååç©ãæ·»å ããã®ã¡ããšã
ãŒã«ãæ·»å ããŠæåã«éæ溶液ã圢æãã次ãã§
çœæ¿ãçæããããããåŸç²ç¶ãªããç²æ«ç¶ã®åº
圢ç©ã圢æãããããã«è¡ãããšã奜é©ã§ããã
ãã®éã該济ã«ããšããŒã«é¡ãæ·»å ããŠçœæ¿ãç
æããåã®æ®µéã«ãããŠã¯ã該济ãæ¹æããŠæ·»å
ããããšããŒã«é¡ãšå«çªçŽ ååç©ãšã該济ãšãªã
ã¹ãåäžãªéæ溶液ã圢æããããã«ãããŸãçœ
æ¿ãçæããæç¹ä»¥éåºåœ¢ç©ã圢æããããŸã§ã®
æéã¯ããšããŒã«é¡ãšå«çªçŽ ååç©ãšã®å²åãå
å¿æ¡ä»¶ã«ãã€ãŠã¯è©²æµŽïŒåå¿æ¶²ïŒã«äŸãã°æ¹æã®
åŠãæ©æ¢°çåªæåãäžããªãããã«ããããšã奜
ãŸããã æ·»å ããããšããŒã«é¡ã¯ãããšããŒã«é¡ãã®ã
ã®ã§ãããããããšããŒã«ããã«ããªã³ãå¡©é žæ°Ž
溶液æã¯æ°Žçã§åžéãããã®ã§ãããã ãŸããããšããŒã«é¡åã¯ãããšããŒã«é¡ãšå«çª
çŽ ååç©ïŒåã¯ãããã®åžé溶液ïŒãæ·»å ããé
ã®ãå¡©é žâãã«ã ã¢ã«ãããåç©æµŽã®æž©åºŠåã¯äº
ãå«çªçŽ ååç©ã溶解ããããå¡©é žâãã«ã ã¢ã«
ããã济ã®æž©åºŠã¯ã90â以äžãç¹ã«70â以äžã®æž©
床ã奜é©ã§ããã該济ã®æž©åºŠã40â以äžãæ®ã«50
â以äžã«é«ãå Žåã¯ãããšããŒã«é¡ããã³å«çªçŽ
ååç©ãšãã«ã ã¢ã«ããããšã®åå¿é床ã¯å€§ãšãª
ããããããšããŒã«é¡ãåã¯ããšããŒã«é¡ãšå«çª
çŽ ååç©ãšãæ®ã«è©²ãã«ããªã³æº¶æ¶²ã§åžéããŠåž
é溶液ãšããŠè©²æµŽã«æ·»å ããã®ã奜é©ã§ããããŸ
ããã®å Žåã«ã¯ãåå¿é床ã倧ã§ãããããããš
ããŒã«é¡ãåã¯ããšããŒã«é¡ãšå«çªçŽ ååç©ãšã
æ®ã«ãããã®åžé溶液ã®çŽ°æµåã¯ãªãã¹ã埮å°ã®
现滎ã®åœ¢ã§è©²æµŽã«æ·»å ãæ¥è§Šããããã®ã奜ãŸã
ãã 該济枩ã40â以äžãæ®ã«50â以äžã«é«ãå Žåã«
ã¯ããã®æµŽã«ããšããŒã«é¡ãåã¯ããšããŒã«é¡ãš
å«çªçŽ ååç©ãåã¯ãããã®åžé溶液ãæ¥è§Šãã
ãããšã該济枩ãé«ããã°é«ãçšããšããŒã«é¡ãš
å«çªçŽ ååç©ãšã®åå¿é床ã¯å€§ãšãªãã該æ¥è§Šã®
åŸæ°å以å ã®çæéæã¯ç¬æã«çœæ¿ãçæããäž
ã€æ¥éã«ç²ç¶ãªããç²æ«ç¶ã®åºåœ¢ç©ã圢æãã
ãã å¡©é žâãã«ã ã¢ã«ããã济ã®æž©åºŠã40â以äžã
奜ãŸããã¯ïŒâã35âãç¹ã«å¥œãŸããã¯10ã30â
ã«ä¿ã¡ããã®æµŽã«ããšããŒã«é¡ãšå«çªçŽ ååç©ãš
ããã®ãŸãŸåã¯ãã®åèšåžé溶液ã奜ãŸããã¯ã
ãšããŒã«ãšå«çªçŽ ååç©ãšã®æ°Žåžé溶液ãæ·»å
ããçœæ¿ãçæããåŸã»ãŒ50â以äžã奜ãŸããã¯
45â以äžã®æž©åºŠã§ææã®åå¿ãå®äºããç²ç¶ãªã
ãç²æ«ç¶åºåœ¢ç©ã¯ã硬ååå¿ãããçšå åã«é²è¡
ããŠããªããããäžè¬ã«åŸè¿°ãã100âç±èçè©Š
éšã«ãããŠç±èçæ§ã瀺ããã®ãšãªãã ä»æ¹ãè©²å¡©é žâãã«ã ã¢ã«ããã济ã®æž©åºŠã40
â以äžã奜ãŸããã¯15ãã35âã«ä¿ã¡ããã®æµŽã«
æ·»å ãã¹ãããšããŒã«é¡ãšå«çªçŽ ååç©ãšããã®
ãŸãŸåã¯ãã®åèšåžé溶液ã®å®è³ªçå šéãæ¹æäž
ã«æ·»å ããŠéæ溶液ã圢æããããããåŸéæ¹æ
ç¶æ ã§çœæ¿ãçæããã次ãã§ææž©åã¯ææž©ãã
ããšãªãæ·¡ãã³ã¯è²ã®ç²ç¶ãªããç²æ«ç¶ã®åºåœ¢ç©
ãçæããããã®åºåœ¢ç©ã50âãããé«ã枩床ã
奜ãŸããã¯70ãã95âã®æž©åºŠã«å ç±ããŠææã®å
å¿ãå®äºãããã®ã¯ã硬ååå¿ãããé²è¡ããã
ãã100âã®ç±èçæ§ã¯äœäžãããåã¯å®è³ªçã«
ãªããªããæã¯ããé«æž©äŸãã°200âã«ãããç±
èçæ§ã瀺ããã®åã¯ãã®ãããªé«æž©ã«ãããŠã
ç±èçæ§ãå®è³ªçã«æããªããã®ãšãªãã äžèšã®ãããã®å Žåãäºãå¡©é žâãã«ã ã¢ã«ã
ãã济äžã«å«çªçŽ ååç©ãæ·»å ã次ãã§ããšããŒ
ã«é¡ã®ã¿ãæ·»å ããããšãã§ããã äžèšæ¹æ³ã§çšããããšããŒã«é¡ãšããŠã¯ãããš
ããŒã«ãæã奜é©ã§ããããå°ããšã50ééïŒ ç¹
ã«å°ããšã70ééïŒ ã®ããšããŒã«ãå«æãããã®
ã§ããã°ïœâã¯ã¬ãŸãŒã«ãïœâã¯ã¬ãŸãŒã«ãïœâ
ã¯ã¬ãŸãŒã«ããã¹âããšããŒã«ïŒ¡ãïœâãïœâå
ã¯ïœâC2ãC4ã¢ã«ãã«ããšããŒã«ãïœâããšã
ã«ããšããŒã«ããã·ã¬ããŒã«ãã¬ãŸã«ã·ããŒã«ç
å ¬ç¥ã®ããšããŒã«èªå°äœã®ïŒçš®åã¯ãã以äžãšã®
æ··åç©ã§ãã€ãŠããã äžèšæ¹æ³ã§çšããå«çªçŽ ååç©ãšããŠã¯ãå°ã
ãšãïŒåã®æŽ»æ§æ°ŽçŽ ãååå ã«æããååç©ã奜
ãŸããã¯ååå ã«ã掻æ§æ°ŽçŽ ãæããã¢ããåºã
ã¢ããåºãããªã¢ããåºããŠã¬ã€ã³åºãåã³ããª
ãŠã¬ã€ã³åºããæã矀ããéžã°ããåºãå°ããšã
ïŒåæããååç©ãçšããããã ãããå«çªçŽ ååç©ãšããŠã¯ãäŸãã°ãå°¿çŽ ã
ããªå°¿çŽ ãå°¿çŽ ãããã¯ããªå°¿çŽ ã®ã¡ãããŒã«èª
å°äœãã¢ããªã³ãã¡ã©ãã³ãã°ã¢ããžã³ãã°ã¢ã
ãã³ããžã·ã¢ã³ãžã¢ãããèèªé žã¢ãããããªã¢
ããããã«ã€ãžã³ãã·ã¢ããŒã«é žåã¯ãããã®æ©
械çèªå°äœãæããããããããã¯ïŒçš®åã¯ïŒçš®
以äžã§çšããããšãã§ããã 以äžã®åŠãããŠè©²æµŽäžã«çæããææã®åå¿ã
å®äºããç²ç¶ãªããç²æ«ç¶å«çªçŽ ããšããŒã«ã»ã¢
ã«ãããæš¹èã®åºåœ¢ç©ã¯ãè©²å¡©é žâãã«ã ã¢ã«ã
ãã济ããåé¢ãããããæ°ŽæŽãã奜ãŸããã¯ä»
çããå¡©é žãã¢ã«ã«ãªæ°Žæº¶æ¶²ãäŸãã°ã¢ã³ã¢ãã¢
æ°Žåã¯ã¡ã¿ããŒã«æ§ã¢ã³ã¢ãã¢æ°Žã§äžåãæŽã«æ°Ž
æŽããããšã«ãã€ãŠææã®è£œåãšããããšãã§ã
ãããã®å Žååœç¶ã®ããšãªããã¡ã¿ããŒã«æº¶è§£æ§
ãæ¯èŒçé«ãæš¹èã«ãã€ãŠã¯ã¢ã«ã«ãªæ°Žæº¶æ¶²ã§äž
åãè¡ãã®ãããã æ¬çºæã®ç¡æ©è³ªææç²äœãå«æããçµæç©ã¯ã
äžèšç²ç¶ãªããç²æ«ç¶å«çªçŽ ããšããŒã«ã»ã¢ã«ã
ããæš¹èãšç¡æ©è³ªææç²äœãšãå«æããã æ¬çºæã«ãããŠçšããããç²ç¶ãªããç²æ«ç¶å«
çªçŽ ããšããŒã«ã»ã¢ã«ãããæš¹èã¯ãäžèšã®ãšã
ããç²åŸ0.1ã100ãã¯ãã³ã®çç¶äžæ¬¡ç²åããã³
ãã®äºæ¬¡åéç©ã®åŠãéåžžã«åŸ®çŽ°ãªç²åãå«æã
ãŠæãã®ã§ãç¡æ©è³ªææç²äœãšã®æ··åæ§ãè¯ãã æ¬çºæã®çµæç©ã¯ãäžèšç²ç¶ãªããç²æ«ç¶ã®å«
çªçŽ ããšããŒã«ã»ã¢ã«ãããæš¹èããç¡æ©è³ªææ
ç²äœãšç²ç¶ãªããç²æ«ç¶å«çªçŽ ããšããŒã«ã»ã¢ã«
ãããæš¹èãšã®åèšéã«å¯ŸããŠ11ééïŒ ããå°ãª
ãéã奜ãŸããã¯0.2ãïŒééïŒ ãç¹ã«å¥œãŸãã
ã¯0.4ãïŒééïŒ ã®éã§å«æããã æ¬çºæã®çµæç©ã¯ãã®ããã«æ¯èŒçå°ãªãå²å
ã§ç²ç¶ãªããç²æ«ç¶å«çªçŽ ããšããŒã«ã»ã¢ã«ãã
ãæš¹èãå«æãããã該埮现ãªæš¹èã¯ç¡æ©è³ªææ
ç²äœãšã®æ··åæ§ã«åªããŠãããããç·å¯ãªæ··åç©
ãšããŠæäŸããããšãã§ããã ç²ç¶ãªããç²æ«ç¶å«çªçŽ ããšããŒã«ã»ã¢ã«ãã
ãæš¹èãšããŠã¯ãå ç±èç枬å®æ³ã«åŸã€ãŠ100â
ã®æž©åºŠã§ïŒåéä¿æããå Žåã«å°ããšããã®äžéš
ãèçãããã®ã§ããåèšãã(a)ã®ããšããŒã«ã»
ã¢ã«ãããæš¹èåã¯å ç±èç枬å®æ³ã«åŸã€ãŠå®è³ª
çã«æº¶èåã¯èçããªããã®ã§ããåèšãã(b)ã®
ããšããŒã«ã»ã¢ã«ãããæš¹èã®ãããã䜿çšãã
ããšãã§ãããæ¬çºæã®ç²ç¶ãªããç²æ«ç¶å«çªçŽ
ããšããŒã«ã»ã¢ã«ãããæš¹èãšããŠã¯ã奜ãŸãã
ã¯ãäžèš(a)ã®å ç±èçåã®æš¹èåã¯äžèš(a)ã®å ç±
èçåã®æš¹èãšäžèš(b)ã®å ç±äžèçåã®æš¹èãšã®
æ··åç©ãçšãããããå ç±èçåã®æš¹èãå«æã
ãæ¬çºæã®çµæç©ã¯ãããæ圢åãšããå Žåã«ã
該暹èãå ç±ã«ãã€ãŠæº¶èããŠç¡æ©è³ªææç²æ«ã®
ãã€ã³ããŒãšãªããããããç¹ã«ãããŠæ¬çºæã®
奜é©ãªçµæç©ãæ§æããã æ¬çºæã®çµæç©ã«ãããç¡æ©è³ªææç²äœãšã¯ã
äžè¬ã«ç¡æ©ç©ãšåŒã°ããŠããååç©ããæããç²
æ«ã®åœ¢æ ã«ããææç©è³ªã§ãããäŸãã°ã»ã©ãã
ã¯ã¹ã®åææãšãªãåŸãç¡æ©ååç©ã®ç²äœããã
ã¯ãã°ãã·ãŠã ãããã€ãªã³ååŸåã®å°ããéå±
ãäŸç€ºããããšãã§ããã ãããã®ç¡æ©è³ªææã¯ïŒçš®åã¯ïŒçš®ä»¥äžäžç·ã«
çšããããšãã§ãããŸãéå±ã¯æ··åç©ã§ãã€ãŠã
åéã§ãã€ãŠãããã ã»ã©ããã¯ã®åææãšãªãåŸãç¡æ©ååç©ãšã
ãŠã¯ãäŸãã°ãéå±é žåç©ãéå±é žåç©ãäž»æå
ãšããçµæç©ãéå±æ°Žé žåç©ãéå±ç¡«åç©ãéå±
çåç©ãéå±çªåç©ãéå±ã®ç¡æ©é žå¡©åã¯éå±ã®
ç¡æ©é¯å¡©ãããã¯è€å¡©çããããããšãã§ããã
ãããç¡æ©ååç©ã«ãããéå±ãšã¯ãåšæåŸè¡šã®
第ã第æã®ç¬¬ïŒã第ïŒåšæã®å çŽ ã第æã®
第ïŒãïŒåšæã®å çŽ ã第ã第æã®ç¬¬ïŒãïŒåš
æã®å çŽ ã第ïœæã®ç¬¬ïŒãïŒåšæã®å çŽ ããã³
第æã®å çŽ ãèšããã®ãšãæãåºãæå³ã«è§£é
ãããã¹ãã§ããã éå±é žåç©ãšããŠã¯ãäŸãã°é žåããªãŠã ãé ž
åããŠçŽ ãé žåãã°ãã·ãŠã ãé žåããªãŠã ãã¢
ã«ãããã·ãªã«ãã·ãªã«ã»ã¢ã«ããïŒåçš®ãŒãªã©
ã€ããå«ãïŒãé žåäºéãé žåãã¿ã³ãé žåãžã«
ã³ããŠã ãé žåã€ã³ãžãŠã ãé žåã¢ã³ãã¢ã³ãé ž
åã¢ãªããã³çãæããããšãã§ããã éå±é žåç©ãäž»æåãšããçµæç©ãšããŠã¯ãäŸ
ãã°ãç²åãã«ãªãªã³ãèããç³ïŒãã€ããã€ã©
ã€ãïŒãã¢ã³ã¢ãªããã€ãïŒãã³ããã€ãïŒãç²å
ç¶é²æ¯ãæ»ç³ããã³ã¬ã©ãé·ç³é¡ãé¶ç³ã軜ç³ã
ç«å±±ç°ãã·ã©ã¹ãã«ãŒã³ãç«å±±å²©ãã·ãªããã€
ããã ã©ã€ãããžã«ã³ã³ãã«ã¿ã«ãã¢ãã¿ãŒãŒã
ãã«ãŒã«ã€ããèµ€éé±ãç·æ±ç³ãç³ç¶¿ãã¬ã©ã¹ã
ã»ã¡ã³ããçãæããããšãã§ããã éå±æ°Žé žåç©ãšããŠã¯ãäŸãã°ãæ°Žé žåã¢ã«ã
ããŠã ãæ°Žé žåã«ã«ã·ãŠã ãæ°Žé žåç°é žé ïŒã¯ãž
ã€ã¯ç³ïŒãæ°Žé žåã±ã€é žãã°ãã·ãŠã ãæ°Žé žå
éãæ°Žé žåããªãŠã ãæ°Žé žåãã°ãã·ãŠã çãæ
ããããšãã§ããã éå±ç¡«åç©ãšããŠã¯ãäŸãã°ç¡«åäºéïŒã»ã³ã¢
ãšã³é±åã¯ãŠã«ãé±ïŒãç¡«åã¢ã³ãã¢ã³ïŒãã¢ã³
é±ïŒãç¡«åã«ãããŠã ãç¡«åéãç¡«åã³ãã«ãã
ç¡«åéãç¡«åé ãç¡«åããªãŠã çãæããããšã
ã§ããã éå±çåç©ãšããŠã¯ãäŸãã°ãçåã±ã€çŽ ãç
åãžã«ã³ããŠã ãçåã¿ã³ã°ã¹ãã³ãçåãã¿
ã³ãçåéãçåãããžãŠã ãçåããããŠã ã
çåããŠçŽ çãæããããšãã§ããã éå±çªåç©ãšããŠã¯ãäŸãã°ãçªåã±ã€çŽ ãçª
åã«ã«ã·ãŠã ãçªåãžã«ã³ããŠã ãçªåãã¿ã³ã
çªåããªããçªåãããžãŠã ãçªçŽ ããŠçŽ çãæ
ããããšãã§ããã éå±ã®ç¡æ©é žå¡©ãç¡æ©é¯å¡©ãããã¯è€å¡©ãšããŠ
ã¯ãäŸãã°ãç¡«é žã¢ã«ãããŠã ãã«ãªãŠã âåã¯
ãããªãŠã âããšãŠãã³ãç¡«é žã«ãããŠã ãç¡«é ž
ã«ã«ã·ãŠã ïŒç¡æ°Žç©ãåæ°Žåç©ãïŒæ°Žåç©ïŒãç¡«
é žã¹ããã³ããŠã ãããŠç¡ãç¡«é žéãç¡«é žããªãŠ
ã ãç¡«é žãã°ãã·ãŠã ã®åŠãç¡«é žæ ¹ãå«ãå¡©ïŒäŸ
ãã°å¡©åãããªãŠã ãå¡©åéãå¡©åã«ãªãŠã ãå¡©
åã³ãã«ããå¡©åéãå¡©åé ãå¡©åçœéãå¡©åã
ãªãŠã ãããåã¢ã«ãããŠã ãããåã«ã«ã·ãŠ
ã ãããåéãèåéãæ²åéãæ²åé ã®åŠãã
ãã²ã³åç©ïŒãªã³é žäºéããªã³é žã¢ã«ãããŠã ã
ãªã³é žã«ã«ã·ãŠã ããªã³é žã»ãªãŠã ããªã³é žéã
ãªã³é žãã°ãã·ãŠã ããªã³é žããªãŠã ã®åŠããªã³
é žæ ¹ãå«ãå¡©ïŒãããã¯çé žã«ã«ã·ãŠã ãçé žã¯
ãã ãçé žã³ãã«ããçé žãã°ãã·ãŠã ãçé žã
ã°ãã·ãŠã ã«ã«ã·ãŠã ïŒãããã€ãïŒãçé žããª
ãŠã ãçé žã¹ããã³ããŠã ã®åŠãçé žå¡©ãæãã
ããšãã§ããã ãŸãããã°ãã·ãŠã ãããã€ãªã³ååŸåã®å°ã
ãéå±ãšããŠã¯ãäŸãã°ãCuïŒAgïŒAuïŒZnïŒ
ïŒAlïŒSiïŒTiïŒZrïŒHfïŒSnïŒïŒ·ïŒMnïŒFeïŒ
CoïŒNiïŒRuïŒRhïŒPdïŒOsïŒIrïŒPtïŒçãæã
ãããšãã§ããã æ¬çºæã§çšãããããããã®ç¡æ©è³ªææç²äœ
ã¯ãéåžžã¿ã€ã©ãŒïŒTylerïŒã®20ã¡ãã·ãŠãã«ã€
ãééãã倧ããã奜ãŸããã¯ã¿ã€ã©ãŒã®32ã¡ã
ã·ãŠãã«ã€ãééãã倧ããããã奜ãŸããã¯ã¿
ã€ã©ãŒã®100ã¡ãã·ãŠãã«ã€ãééãã倧ããã§
ããã æ¬çºæã®çµæç©ã¯ãäžèšç²ç¶ãªããç²æ«ç¶ã®å«
çªçŽ ããšããŒã«ã»ã¢ã«ãããæš¹èã®æå®éãšäžèš
ç¡æ©è³ªææç²äœã®æå®éãšããç©ççã«æ··åãã
ããšã«ãã€ãŠèª¿è£œããããšãã§ããããã®éã該
æš¹èãšç¡æ©è³ªææç²äœãšããã®ãŸãŸäŸãã°ïŒ¶åã
ã¬ã³ããŒãçšããŠä¹ŸåŒæ··åããŠãããããŸãã該
æš¹èãšç¡æ©è³ªææç²äœãšãè£å©ææã®ååšäžã«æ··
åããŠãããã 以äžæ¬çºæã®çµæç©ã説æã®äŸ¿ã®ããå®æœæ æ§
ã«åããŠèšè¿°ããã æ¬çºæã®çµæç©ã¯ãäžè¬ã«ãã®ãŸãŸã®ç¶æ ã§ã¯
æçµçãªçšéã«äœ¿çšããããšãã§ãããæçµçãª
çšéã«é©ãã圢æ ã«æ圢ããäžã€å¿ èŠã«ãã硬å
ãããã¯çŒæããããããæçµçãªçšéã«é©ãã
補åã«å€æããããããæ ãæ¬çºæã®çµæç©ã¯ç²
ç¶ãªããç²æ«ç¶ã®å«çªçŽ æš¹èãšç¡æ©è³ªææç²äœãš
ã®æ··åæäœãæ圢æäœããã³å Žåã«ãã硬åãã
ãã¯çŒææäœçã«äŸåããŠçš®ã ã®æ æ§ãå å«ã
ãã æ¬çºæã®çµæç©ã¯ãäžè¬ã«ãç²ç¶ãªããç²æ«ç¶
å«çªçŽ æš¹èãšç¡æ©è³ªææç²äœãšã®æå®éãæ··åã
ãããšã«ãã€ãŠè£œé ããããæ¬çºæã«çšãããã
ç²ç¶ãªããç²æ«ç¶å«çªçŽ æš¹èã¯ç²åŸ0.1ã100ãã¯
ãã³ã®çç¶äžæ¬¡ç²åããæã極ããŠçŽ°ããªç²æ«ã
ãæ§æãããŠããããããã®äœ¿çšéãå°ãªãã«ã
ãããããæ¯èŒçåäžã«åæ£ãããçµæç©ãäžã
ããæ··åæäœã®ã¿ãèæ ®ããã®ã§ããã°ã也åŒå
ã¯æ¹¿åŒæ··åã«ãã€ãŠåäžã«æ··åãããæ¬çºæã®çµ
æç©ã補é ããããšãã§ããã ããããªãããæ¬çºæã®çµæç©ã¯æ··åæäœä»¥å€
ã®æ圢æäœçãèæ ®ããã°ã奜ãŸããã¯æ··åæäœ
ãè£å©å€ã®ååšäžã§å®æœãããæ è£å©å€ãå å«ã
ãç¶æ ã®ãã®ãšããŠæäŸããããšãã§ãããŸãã
ã®ãããªç¶æ ã®ãã®ãšããŠæäŸããããšã奜ãŸã
ãããšãããã æ¬çºæã®çµæç©ã®ç¬¬ïŒã®æ æ§ã¯ãå ç±ã«ãã€ãŠ
ç±èçæ§ã瀺ãç²ç¶ãªããç²æ«ç¶å«çªçŽ æš¹èãå«
æã該暹è以å€ã«ã¯å®è³ªçã«ãã€ã³ããŒãšãªãæ
åãå«æããªãçµæç©ã§ããããã®ãããªçµæç©
ã¯ãäŸãã°ãã®æå®éãäžå®ã®åœ¢ç¶ã®åå ã«å å¡«
ããäŸãã°50ã1000KgïŒcm2ã®å å§äžã§è©²æš¹èã溶
èãã枩床以äžã®æž©åºŠäŸãã°60â以äžã®æž©åºŠã«å
ç±ããããšã«ãã€ãŠã該暹èããã€ã³ããŒãšããŠ
äœçšããçµæèªç«æ§ã®ããäžå®ã®åœ¢ç¶ãæããæ
圢äœã«å€æããããåŸãããæ圢äœã¯è©²æš¹èã®ç¡¬
ååå¿ããã§ã«å åã«é²è¡ããŠããå Žåã«ã¯ãã®
ãŸãŸããŸã該暹èã®ç¡¬ååå¿ãæªã å åã«é²è¡ã
ãŠããªãå Žåã«ã¯ç¡¬åããããã®ã¡ã硬åããã
補åãšããŠæäŸãããããŸããæ圢äœåã¯ç¡¬åäœ
ã¯ããã«çŒæã«ä»ãããšã«ãããçŒæããã補å
ãšããŠæäŸããããšãã§ããã 硬åããã補åãæäŸããã«å¥œé©ãªæ¬çºæã®ç¬¬
ïŒã®æ æ§ã®çµæç©ã¯ãç¡æ©è³ªææãäŸãã°éå±é ž
åç©ãéå±é žåç©ãäž»æåãšããé±ç©ãéå±æ°Žé ž
åç©ãéå±ç¡«åç©ãããã¯éå±ã§ããçµæç©ã§ã
ãããŸãçŒæããã補åãæäŸããã«å¥œé©ãªæ¬çº
æã®ç¬¬ïŒã®æ æ§ã®çµæç©ã¯ç¡æ©è³ªææãäŸãã°é
å±é žåç©ãäž»æåãšããé±ç©ãéå±çåç©ãéå±
çªåç©ãããã¯éå±ã§ããçµæç©ã§ããã æ¬çºæã®çµæç©ã®ç¬¬ïŒã®æ æ§ã¯ãå ç±ã«ãã€ãŠ
ç±èçæ§ã瀺ããªãç²ç¶ãªããç²æ«ç¶å«çªçŽ æš¹è
ãå«æãããããå®è³ªçã«ãã€ã³ããŒãšãªãæå
ãå«æããªãçµæç©ã§ããããã®ãããªçµæç©
ã¯ã該暹èãå ç±ã«ãã€ãŠç±èçæ§ã瀺ããªãã®
ã§ãéåžžç±ã®ã¿ã«ãã€ãŠèªç«æ§ã®ããäžå®ã®åœ¢æ
ãæããæ圢äœã«å€æããããšã¯å°é£ã§ããã ããããªãããæ¬çºæã®çµæç©ã¯ãç²åŸ0.1ã
100ãã¯ãã³ã®äžæ¬¡ç²åããæã極ããŠçŽ°ããªç²
æ«ã®ç²ç¶ãªããç²æ«ç¶å«çªçŽ æš¹èãšç¡æ©è³ªææç²
äœãšããæãã®ã§ããããéåžžã«é«å§ã§å§çž®ãã
ã°èªç«æ§ã®ããäžå®ã®åœ¢ç¶ãæããæ圢äœã«å€æ
ããããšãã§ãããããªãã¡ã該çµæç©ã®äžå®é
ãäŸãã°äžå®ã®åœ¢ç¶ã®åå ã«å å¡«ããäŸãã°æ°çŸ
Kgãæ°10tonïŒcm2ã®å§åãå Žåã«ããå ç±ããªã
ããè² è·ããããããšã«ãã€ãŠèªç«æ§ã®ããäžå®
ã®åœ¢ç¶ãæããæ圢äœã«å€æããããšãã§ããã åŸãããæ圢äœã¯å¿ èŠã«ããçŒæãããããé
åžžçŒæããã補åãšããŠæäŸãããã奜é©ãªæ¬çº
æã®ç¬¬ïŒã®æ æ§ã®çµæç©ãšããŠã¯ãäžèšç¬¬ïŒã®æ
æ§ã®çµæç©ã«ã€ããŠäŸç€ºãããã®ãšåããã®ãäŸ
瀺ããããšãã§ããã æ¬çºæã®çµæç©ã®ç¬¬ïŒã®æ æ§ã¯ãç²ç¶ãªããç²
æ«ç¶å«çªçŽ æš¹èã¯å ç±ã«ãã€ãŠç±èçæ§ã瀺ãã
ã®ãããã¯ããã§ãªããã®ã®ãããã§ãã€ãŠãã
ããã該暹èãç±èçæ§ã瀺ããã®ã§ãã€ãŠãã
該暹è以å€ã«ãã€ã³ããŒãšãªãè£å©æåãå«æã
ãçµæç©ã§ããã ãã®ãããªçµæç©ã¯ãã€ã³ããŒãšãªãè£å©æå
ãå«æãããããäžè¬ã«ãç¹å¥ã«å ç±ãããã¯å
å§ããªããšãäžå®ã®åœ¢ç¶ãæã€èªç«æ§ã®ããæ圢
äœã«å€æããããšãã§ããã ãã®ãããªãã€ã³ããŒãšãªãè£å©æåãšããŠ
ã¯ãäŸãã°æ°Žã奜ãŸããçšãããããæ¬çºæã§çš
ããããç²ç¶ãªããç²æ«ç¶å«çªçŽ æš¹èã®æ¯éã¯äœ¿
çšããç¡æ©è³ªææç²äœã®æ¯éãããäžè¬ã«å°ãã
ããã該暹èã該ç²äœãšã®åé¢ã容æã«èµ·ããã
ãªããŸãã«ãå€éã®æ°Žã䜿çšããããšãæãŸãã
ãªããé©åãªæ°Žã®äœ¿çšéã¯äœ¿çšãã該ç²äœã®çš®é¡
ãšéããã³äœ¿çšãã該暹èã®éã«äŸåããããçµ
æç©ãèªç«æ§ã瀺ãã¹ã©ãªãŒç¶æ ã瀺ããããªé
ã§æ°Žã䜿çšããã®ãæãŸããããã®ãããªæ°Žã®é
ã¯ãäžã€ã®ç®ãããšãã䜿çšããåºäœææã®å®å®¹
ç©ïŒååºäœã®äœ¿çšéïŒïœïŒãååºäœã®å¯åºŠïŒïœïŒ
c.c.ïŒã§å²ã€ãå€ã®åèšã®å€ïŒc.c.ïŒïŒã®ïŒåããã
å°ããå€ïŒc.c.ïŒã®å®¹ç©ãšããããšãã§ããã ãã€ã³ããŒãšãªãè£å©æåãšããŠã¯ãæ°Žã®ä»
ã«ãäŸãã°ã¢ã¹ãã¢ã«ããåæã©ãã¯ãã¹ãã¢ãª
ã³é žããã€ã³æ²¹ããããµããã€ã³ã»ã¿ãŒã«ãã°ãª
ã»ãªã³ããšãã«ã»ã«ããŒãºãã¢ããšãã³é žã¬ãž
ã³ãããªããã«ã»ããã©ãŒã«ã殿ç²ã®åŠããã»ã©
ããã¯ã¹ã®æè¡åéã«ãããŠããç¥ãããŠãã
çš®ã ã®çµåæã䜿çšããããšãã§ããããããã®
çµåæã¯ã䜿çšããåºäœææ100éééšåœãéåžž
ïŒéééšä»¥äžã®å²åã§äœ¿çšããããšãã§ããã æ¬çºæã®çµæç©ãã硬åãããæ圢äœã補é ã
ãéã«ãäŸãã°ç¡æ©è³ªææç²äœãšããŠé¶ç£åšãã
ãã¯ã¬ã³ã¬ã®åŠãèç«ç©çŽ åæåã¯ã»ã¡ã³ãã®åŠ
ãç²äœãçšããå Žåã«ã¯ã硬ååå¿ã®é²è¡ã«ãšã€
ãŠæ°Žãå¿ é ã®æåãšãªããããè£å©æåãšããŠæ°Ž
ãçšããããšãå¿ èŠãšãªãããšãç解ãããã æ¬çºæã®çµæç©ããçŒæãããæ圢äœã補é ã
ãå Žåã«ã¯ãçŒæäœã補é ããããã«èŠæ±ããã
çŒçµå©å€äŸãã°çåã±ã€çŽ çŒçµäœã補é ãããã
ã«çšããããããŠçŽ çãçšããããšãæãŸããã
æ¬çºæã®çµæç©ã¯ãã®ãããªçŒçµå©å€ãå«æãã
ããšãã§ããããããã®çŒçµå©å€ã¯åœè©²æè¡åé
ã«ãããŠããç¥ãããŠããã ãŸããæ¬çºæã®çµæç©ããçŒæãããæ圢å€å
äœã補é ããå Žåã«ã¯ãçŒæã®éç±å解ãæãå€
ååå€äŸãã°ãçæ°Žåç©ãçæ°Žåç©ã®èªå°äœåã¯
çæ°Žåç©ãäž»æåãšãã倩ç¶ç©äŸãã°ã»ã«ããŒãº
ïŒã¬ãŒãšã³ïŒããã³ãã³ãç³ã®åŠãçæ°Žåç©ãã«ã«
ããã·ã¡ãã«ã»ã«ããŒãºãããããã·ãšãã«ã»ã«
ããŒãºãã¢ã»ãã«ã»ã«ããŒãºã®åŠãçæ°Žåç©ã®èª
å°äœãããã¯æšç²ããªã³ã¿ãŒãã€ã·ã¬ã©ãã¢ãã¬
ã©ãç©ç©ç²ã®åŠãçæ°Žåç©ãäž»æåãšãã倩ç¶
ç©ïŒç±å¯å¡æ§æš¹èäŸãã°ããªã¢ãããããªããã«
ã¢ã»ããŒããå¡©åããã«ãå¡©åãããªãã³åã¯ã
ãªã¢ã¯ãªããããªã«ç³»æš¹èããããã¯ç±äžèæ§æš¹
èäŸãã°ããªããã«ã¢ã«ã³ãŒã«åã¯ããªããã«ã
ã«ããŒã«çãå«æããããããšã奜ãŸãããæ¬çº
æã®çµæç©ã¯ãã®ãããªå€ååå€ãå«æããããš
ãã§ãããæ¬çºæã®çµæç©ã¯ãããèªäœã§åã¯ä»
ã®æš¹èãšåå¿æ§ãæãäžã€éåžžã«å°ç²ã§å€§ããè¡š
é¢ç©ãæããç²ç¶ãªããç²æ«ç¶å«çªçŽ ããšããŒ
ã«ã»ã¢ã«ãããæš¹èãå«æããŠããããã«ãç¡æ©
質ææç²äœãšçžäºã«åäžã«åæ£ãåãäžã€å ç±ã«
ããç±ç¡¬ååãã€ã³ããŒãšããŠãããã¯çŒææã®
ççŽ æºãšããŠäœçšãããããå éšãŸã§å®è³ªçã«å
äžã«ç¡¬åãããããã硬åããã補åãäžãããŸ
ãã¯ã©ãã¯ãã¬ã¹ã¶ãããæããçŒæããã補å
ãäžãããããªããšã¯å°ãªãã æ¬çºæã®çµæç©ããåŸãããç¡æ©è³ªæ圢äœã¯ã
åªããè¡ææ§ã®åŠãæ©æ¢°çæ§è³ªãããã¯åªããé»
æ°çç¹æ§ãæããŸãåªããèç±æ§ãèæ©èæ§ãæº
åç¹æ§ãããã¯èååŠè¬åæ§ã瀺ãã æ¬çºæã®çµæç©ããåŸããã硬åäœããã³çŒæ
äœã¯ãäŸãã°è»èŒãèªç©ºæ©ãè¹è¶ççšã®éšåäŸã
ã°ãã¬ãŒãããã©ã°ãã®ã€ã軞åïŒé»æ°ã»ãšãã«
ã®ãŒæ©åšçšéšåäŸãã°é»æ³¢åžåäœãã³ã³ãã³ãµ
ãŒãé»æ°æµæäœãé»æ± çšçµ¶çžäœãçºç±äœãã»ã³ãµ
ãŒã®ä¿è·ç®¡ãæç±æïŒäžå®åœ¢èç«ç©äŸãã°é«çã
転ççã®åçš®çã®å£æãé²ç«å¡æãé²ç«çšãã
ãïŒå»ççšçŽ æäŸãã°æ¯ç§ææã骚æïŒæ©æ¢°éšå
äŸãã°åçš®å·¥å ·ãæºåéšæïŒäŸãã°ã軞åã糞
éãã·ãŒã«çïŒãæ©æŠææïŒäŸãã°ãç 磚å€ãã¿
ããç²ããã¬ãŒãçïŒãèèæïŒåæšå»ºç¯çšæäŸ
ãã°æ©ãšããããã©ããããææšãéåºããã€
ã«ãALCïŒautoclaved lightweight concreatïŒã
èç«ã»æç±ã»ä¿æž©ã»åžæ¹¿ææãããŒããéä»åã
å£ïŒå·¥æ¥çšæäŸãã°é»æ¥µãèç«ã¬ã³ã¬ãåºéæšæ
çã«çšããããšãã§ããã 以äžå®æœäŸã«ããæ¬çºæãæŽã«å ·äœçã«è©³è¿°ã
ãã ïŒ 0.1ã100ÎŒç²åã®æž¬å®æ³ ïŒã€ã®è©ŠæããçŽ0.1ïœã®ãµã³ãã«ããµã³ããª
ã³ã°ããããã®ãããªãµã³ããªã³ã°ãïŒã€ã®è©Šæ
ã«ã€ããŠç°ãªãå ŽæããïŒåè¡ãªãã ãµã³ããªã³ã°ããåçŽ0.1ïœã®ãµã³ãã«ã®åïŒ
éšããããããé¡åŸ®é¡èŠ³å¯çšã¹ã©ã€ãã°ã©ã¹äžã«
èŒãããã¹ã©ã€ãã°ã©ã¹äžã«èŒãããµã³ãã«ã¯èŠ³
å¯ã容æãšãããããã§ããã ãç²ååå¿ãéãª
ãåããªãããã«æ¡ããã é¡åŸ®é¡èŠ³å¯ã¯ãå åŠé¡åŸ®é¡äžèŠéã«ç²ç¶ãªãã
ç²æ«ç¶ç©ããã³ïŒãŸãã¯ãã®äºæ¬¡åéç©ã10ã50
åçšåºŠååšããç®æã«ã€ããŠè¡ãããã«ãããé
åžžåç102ã103åã§èŠ³å¯ããã®ãæãŸãããå åŠ
é¡åŸ®é¡äžèŠéã«ååšããå šãŠã®ç²åã®å€§ãããå
åŠé¡åŸ®é¡äžèŠéäžã®ã¡ãžã€ãŒã«ããèªã¿ãšãèšé²
ããã 0.1ã100ÎŒã®ç²åã®å«æçïŒïŒ ïŒã¯æ¬¡åŒã«ãŠæ±
ããããã 0.1ã100ÎŒç²åã®å«æçïŒïŒ ïŒïŒïŒ®ïŒïŒïŒ®ïŒÃ100 N0ïŒé¡åŸ®é¡äžèŠéã§å¯žæ³ãèªã¿ãšã€ãç²åã®
å šåæ° N1ïŒN0ã®ãã¡0.1ã100ÎŒã®å¯žæ³ãæããç²åã®
åæ° ïŒã€ã®è©Šæã«ã€ããŠã®ïŒã€ã®ãµã³ãã«ã®çµæã®
å¹³åå€ãšããŠ0.1ã100ÎŒã®ç²åã®å«æçãè¡šã
ãã ïŒ 150ã¿ã€ã©ãŒã¡ãã·ãŠç¯©ééé 也ç¥è©Šæããå¿ èŠã«ããååã«æã§è»œããã¿ã»
ãããã®ã¡ããã®çŽ10ïœã粟秀ããïŒåéã§å°é
ãã€150ã¿ã€ã©ãŒã¡ãã·ã®ç¯©æ¯ãšãæ©ïŒç¯©ã®å¯ž
æ³ïŒ200mmÏãæ¯ãšãæ¡ä»¶ïŒ200RPMïŒã«æå ¥
ããè©Šææå ¥åŸæŽã«10åéæ¯ãšããããã150ã¿
ã€ã©ãŒã¡ãã·ãŠéééã¯æ¬¡åŒã«ãŠæ±ããã 150ã¿ã€ã©ãŒã¡ãã·ãŠéééïŒééïŒ ïŒ ïŒÏïŒâÏïŒïŒÏïŒÃ100 ÏïŒïŒæå ¥éïŒïœïŒ ÏïŒïŒ150ã¿ã€ã©ãŒã¡ãã·ãŠç¯©ãééããã«ç¯©
äžã«æ®åããéïŒïœïŒ ïŒ èµ€å€ç·åžåã¹ãã¯ãã«ã®æž¬å®ããã³åžå匷床
ã®æ±ãæ¹ïŒæ·»ä»å³é¢ã®ç¬¬ïŒå³åç §ïŒ æ ªåŒäŒç€Ÿæ¥ç«è£œäœæ補ã®èµ€å€ç·åå å 床èš
ïŒ225åïŒãçšããéåžžã®KBré å€æ³ã«ãã調補ã
ã枬å®çšè©Šæã«ã€ããŠèµ€å€ç·åžåã¹ãã¯ãã«ã枬
å®ããã ç¹å®æ³¢é·ã«ãããåžå匷床ã¯æ¬¡ã®ããã«ããŠæ±
ããã枬å®ããèµ€å€ç·åžåã¹ãã¯ãã«å³ã«ãã
ããåžå匷床ãæ±ããããšããããŒã¯ã«ããŒã¹ã©
ã€ã³ãåŒãããã®ããŒã¯ã®é ç¹ã®ééçãtpã§è¡š
ããããã®æ³¢é·ã«ãããããŒã¹ã©ã€ã³ã®ééçã
tbã§è¡šãããšããã®ç¹å®æ³¢é·ã«ãããåžå匷床
ã¯äžèšåŒã§äžããããã ïŒlogïœïœïŒïœïœ åŸã€ãŠãäŸãã°960ã1020cm-1ã®ããŒã¯ã®åžå
匷床ãš1450ã1500ã®ããŒã¯ã®åžå匷床ãšã®æ¯ã¯ã
äžèšåŒã§æ±ããããããã®åžå匷床ã®æ¯ïŒïŒ€960
ãïŒïŒïŒïŒïŒïŒ€1450ã1500ïŒãšããŠäžããããã ïŒ 100âã«ãããç±èçæ§ 150ã¿ã€ã©ãŒã¡ãã·ãŠééã®è©ŠæçŽïŒïœãïŒæ
ã®0.2mmåã¹ãã³ã¬ã¹æ¿ã®éã«æ¿å ¥ãããã®ãæº
åãããããäºã100âã«å æž©ããç±ãã¬ã¹æ©
ïŒ(æ ª)ç¥è€éå±å·¥æ¥æ補ãååå§çž®æ圢æ©ïŒã§ïŒå
éãåå§50Kgã§ãã¬ã¹ããããã¬ã¹ã解æŸããã®
ã¡ãïŒæã®ã¹ãã³ã¬ã¹æ¿ã®éããç±ãã¬ã¹ããã
è©Šæãåãåºãããåãåºããè©Šæã溶èãŸãã¯
èçã«ããæããã«åºçããŠå¹³æ¿ã圢æããŠãã
ãã®ãè©Šæãèçæ§ãæããŠãããšå€å®ããç±ã
ã¬ã¹ååŸã§ã»ãšãã©å·®ç°ãã¿ãããªããã®ãè©Šæ
ãäžèæ§ãæãããšå€å®ããã ïŒ ã¡ã¿ããŒã«æº¶è§£æ§ è©ŠæçŽ10ïœã粟秀ãïŒãã®ç²Ÿç§€ééãW0ãšã
ãïŒãå®è³ªçã«ç¡æ°Žã®ã¡ã¿ããŒã«çŽ500mläžã§30å
ééæµäžã«å ç±åŠçãããã¬ã©ã¹ãã€ã«ã¿ãŒïŒNo.
ïŒïŒã§éããæŽã«ãã€ã«ã¿ãŒæ®è©Šæããã€ã«ã¿
ãŒäžã§çŽ100mlã®ã¡ã¿ããŒã«ã§æŽæµãã次ãã§ã
ã€ã«ã¿ãŒæ®è©Šæã40âã®æž©åºŠã§ïŒæé也ç¥ãã
ïŒãã®ç²Ÿç§€ééãW1ãšããïŒã次åŒã«ãŠã¡ã¿ããŒ
ã«æº¶è§£åºŠïŒS1ïŒ ïŒãæ±ããã ã¡ã¿ããŒã«æº¶è§£åºŠïŒS1ééïŒ ïŒ ïŒïŒ·ïŒâïŒïŒïŒ·ïŒÃ100 ïŒ éé¢ããšããŒã«å«éã®å®é 150ã¿ã€ã©ãŒã¡ãã·ãŠééã®è©ŠæçŽ10ïœã粟秀
ããå®è³ªçã«ç¡æ°Žã®ã¡ã¿ããŒã«190ïœäžã§30åé
éæµäžã«å ç±åŠçãããã¬ã©ã¹ãã€ã«ã¿ãŒïŒNo.
ïŒïŒã§éãã液ããé«é液äœã¯ãããã°ã©ã
ã€ãŒïŒç±³åœããŠãªãŒã¿ãŒãºç€Ÿè£œ6000AïŒã«ãã
液äžã®ããšããŒã«å«éãå®éããå¥åã«äœæãã
æ€éç·ãã該詊æäžã®éé¢ããšããŒã«å«éãæ±ã
ãã é«é液äœã¯ãããã°ã©ãã€ãŒã®æäœæ¡ä»¶ã¯æ¬¡ã®
ãšããã§ããã ç¹ çœ®ïŒç±³åœãŠãªãŒã¿ãŒãºç€Ÿè£œ6000A ã«ã©ã æ äœïŒÎŒâBondapakC18 ã«ã©ã ïŒåŸ1/4ã€ã³ãÃé·ãïŒãã€ãŒã ã«ã©ã 枩床ïŒå®€æž© 溶é¢æ¶²ïŒã¡ã¿ããŒã«ïŒæ°ŽïŒïŒïŒïŒã容ç©æ¯ïŒ æµ éïŒ0.5mlïŒå ãã€ãã¯ã¿ãŒïŒUVïŒ254nmïŒãRange0.01ïŒïŒïœ
ïŒ¶ïŒ æ¶²äžã®ããšããŒã«å«éã¯ãäºãäœæããæ€é
ç·ïŒããšããŒã«å«éãšããšããŒã«ã«åºã¥ãããŒã¯
ã®é«ããšã®é¢ä¿ïŒããæ±ããã ïŒ åµ©å¯åºŠ 100mlã®ææšã®ãšããã§ããåã«ãªã€ãŠãã100
mlã®ã¡ã¹ã·ãªã³ããŒã«ãã¡ã¹ã·ãªã³ããŒã®ãµã¡äž
æ¹ïŒcmã®ãšããããã100ã¿ã€ã©ãŒã¡ãã·ãŠéé
ã®è©Šæã泚ã蟌ãã次åŒã«ãã€ãŠåµ©å¯åºŠãæ±ã
ãã 嵩å¯åºŠïŒïœïŒmlïŒïŒïŒ·ïŒïœïŒïŒïŒïŒïŒïŒmlïŒ ïŒ·ïŒ100mlåœãã®ééïŒïœïŒ ïŒ çŒæåã®ç¡¬åºŠ ããã«ãŒãºæ³åŸ®å°ç¡¬åºŠèšã§è·é500Kgã§æž¬å®ã
ãã ïŒ æ²ã匷床ããã³å§çž®åŒ·åºŠ JISââ6911â1979ã«æºããŠæž¬å®ããã 10 ç±äŒå°çã®æž¬å® JISââ1412â1968ã«æºããŠæž¬å®ããã 11 é»æ°æ¯æµæ JISââ7202ã«æºããé»æ°éäžæ³ã§æž¬å®ã
ãã 12 èŠæå¯åºŠ æ圢åã®å¯žæ³ããã®ã¹ã§æž¬å®ããŠæ±ããäœç©ãš
æ圢åã®ééããç®åºããã åèäŸ ïŒ (1) ïŒã®ã»ãã©ãã«ãã©ã¹ã³ã«ãå¡©é žãšãã«ã
ã¢ã«ãããã®åçš®çµæïŒç¬¬ïŒè¡šã«èšèŒïŒãããª
ã25âã®æ··å氎溶液åã 1500ïœãå ¥ããããã«
98ééïŒ ã®ããšããŒã«ïŒæ®ãïŒééïŒ ã¯æ°ŽïŒã
å°¿çŽ ããã³37ééïŒ ã®ãã«ããªã³äžŠã³ã«æ°Žãçš
ããŠèª¿æŽããã20ééïŒ ã®ããšããŒã«ã20éé
ïŒ ã®å°¿çŽ ããã³14.6ééïŒ ã®ãã«ã ã¢ã«ããã
ãšãå«ãæ··å氎溶液ïŒ25âïŒãåã 125ïœæ·»å
ãããæ·»å ããŠ15ç§éæ¹æããåŸã60åéé眮
ããã60åéã®é眮ããŠããéãåã ã®ã»ãã©
ãã«ãã©ã¹ã³å ã®å 容ç©ã¯ããããã®ã¯éæãª
ç¶æ ã®ãŸãŸã§ããïŒç¬¬ïŒè¡šã®RunNo.ïŒããã³
20ïŒãåãããã®ã¯éæããçœæ¿ã«ç§»ãçœæ¿ã®
ãŸãŸã§ããïŒç¬¬ïŒè¡šã®RunNo.ïŒïŒïŒããã³
18ïŒãåãããã®ã¯éæç¶æ ããçœæ¿ããŠçœè²
ã®æ²éç©ãäžããïŒç¬¬ïŒè¡šã®RunNo.ïŒïŒïŒã
ïŒã10ã17ããã³19ïŒããã®çœè²æ²éç©ã«ã¯ã
é¡åŸ®é¡èŠ³å¯ãããšæ¢ã«çç¶ç©ãçç¶ç©ã®åéäœ
ããã³å°éã®ç²ç¶ç©ãã¿ãããã次ã«åã ã®ã»
ãã©ãã«ãã©ã¹ã³ã®å 容ç©ãæã æ¹æããªã
ããããã«60åéã§80âã«ãŸã§ææž©ãã次ãã§
80ã82âã®æž©åºŠã§15åéåå¿çæç©ã40ã45â
ã®æž©æ°Žã§æŽæµãã0.5ééïŒ ã®ã¢ã³ã¢ãã¢ãš50
ééïŒ ã®ã¡ã¿ããŒã«ãããªãæ··å氎溶液äžã60
âã®æž©åºŠã§30åéåŠçããå床40ã45âã®æž©æ°Ž
ã§æŽã次ãã§80âã§ïŒæé也ç¥ãããåçš®çµæ
ã®å¡©é žãšãã«ã ã¢ã«ããããããªãæ··å氎溶液
ããåŸãããåå¿çæç©ã®æ§è³ªã第ïŒè¡šã«èšèŒ
ããã (2) äžæ¹ãæ¯èŒã®ãã以äžã®å®éšãè¡ã€ããïŒ
ã®ã»ãã©ãã«ãã©ã¹ã³ã«ãèžçããããšããŒã«
282ïœãš37ééïŒ ã®ãã«ããªã³369ïœããã³26é
éïŒ ã®ã¢ã³ã¢ãã¢æ°Ž150ïœãå ¥ããæ¹æããªã
ã宀枩ãã70âã«ãŸã§60åéã§ææž©ããããã«
70ã72âã®æž©åºŠã§90åéæ¹æã»å ç±ããã次ã
ã§æŸå·ãã300ïœã®ã¡ã¿ããŒã«ãå°éãã€å ã
ãªãã40mmHgã®æžå§äžã«å ±æ²žèžçã«ããè±æ°Ž
ãè¡ãªãã溶å€ãšããŠã¡ã¿ããŒã«ã700ïœå ã
ãŠé»è€è²éæã®ã¬ãŸãŒã«æš¹è溶液ãåãåºã
ãã ããããŠåŸãã¬ãŸãŒã«æš¹èã®äžéšãæžå§äžã«
è±æº¶åªãããšãæ¿ããçºæ³¡ããŠã²ã«åãããã
ã®ã²ã«åç©ãæŽã«çªçŽ ã¬ã¹äžã160âã®æž©åºŠã§
60åéç±ç¡¬åããåŸããã硬åçºæ³¡äœãç²ç ã
ãŠã150ã¿ã€ã©ãŒã¡ãã·ãŠã®ç¯©ãééããç²æ«
ãå°éåŸãããã®å Žåãç±ç¡¬åã¬ãŸãŒã«æš¹èã¯
極ããŠç¡¬ããåçš®ã®ç²ç æ©ãããŒã«ãã«ããã
ã¯è¢å ç·çšã®æ¯åãã«ãçšããŠã150ã¡ãã·
ãŠãã¹ã®ç²æ«ãåŸãã®ã¯éåžžã«å°é£ã§ãã€ãã
ããããŠåŸãç±ç¡¬åã¬ãŸãŒã«æš¹èç²æ«ãäžè¿°ã
ãã®ãšåäžæ¡ä»¶ã§ã0.5ééïŒ ã®ã¢ã³ã¢ãã¢ãš
50ééïŒ ã®ã¡ã¿ããŒã«ãããªãæ··å氎溶液ã§åŠ
çããæž©æ°Žã§æŽãã次ãã§ä¹Ÿç¥ãããããããŠ
åŸãè©Šæã®æ§è³ªã第ïŒè¡šã«RunNo.21ãšããŠèšèŒ
ããã 次ã«ãïŒã®ã»ãã©ãã«ãã©ã¹ã³ã«ãããšã
ãŒã«390ïœã37ééïŒ ã®ãã«ããªã³ã370ïœãã·
ãŠãŠé ž1.5ïœããã³æ°Ž390ïœãå ¥ããæ¹æããªã
ã60åéã§90âã«ãŸã§ææž©ãã90ã92âã®æž©åºŠ
ã§60åéæ¹æã»å ç±ããã次ã«35ééïŒ ã®å¡©é ž
1.0ïœãå ããæŽã«90ã92âã®æž©åºŠã§60åéæ¹
æãå ç±ããã次ãã§ãæ°Žã500ïœå ããŠå·åŽ
ãããµã€ãã³ã«ããæ°Žãé€ãã30mmHgã®æžå§
äžã«å ç±ããŠã100âã®æž©åºŠã§ïŒæéãæŽã«æ
æž©ããŠ180âã®æž©åºŠã§ïŒæéæžå§ãå ç±ããã
åŸãããããã©ãã¯æš¹èã¯å·åŽãããšé»è€è²ã®
åºäœãšããŠåŸãããããã®ãã®ã¯è»å枩床ã78
ã80âã§ããã液äœã¯ãããã°ã©ãã€ãŒã«ãã
å®éããéé¢ããšããŒã«å«éã0.76ééïŒ ã®ã
ã®ã§ãã€ãã äžèšã®ããã©ãã¯æš¹èãç²ç ããŠããããµã¡
ãã¬ã³ããã©ãã³15ééïŒ ãæ··åããæ··åç©ã
çªçŽ ã¬ã¹äžã160âã®æž©åºŠã§120åéç±ç¡¬åã次
ãã§ãããŒã«ãã«ã§ç²ç ããŠ150ã¿ã€ã©ãŒã¡ã
ã·ãŠã®ç¯©ãééãããããããããŠåŸãç²æ«
ã¯ãäžè¿°ããã®ãšåäžã®æ¡ä»¶ã§ã0.5ééïŒ ã®
ã¢ã³ã¢ãã¢ãš50ééïŒ ã®ã¡ã¿ããŒã«ãããªãæ··
å氎溶液ã§åŠçããæž©æ°Žã§æŽãã次ãã§ä¹Ÿç¥ã
ããããããŠåŸãè©Šæã®æ§è³ªãRunNo.22ãšããŠ
第ïŒè¡šã«èšèŒããã æŽã«ãäžèšããã©ãã¯æš¹èãååŸ0.25mmÏã
åæ°120ã®çŽ¡ç³žå£éãçšããŠã136ã138âã®æž©
床ã§æº¶è玡糞ãè¡ãªã€ããåŸãããå¹³åç¹ç¶21
ãããŒã«ã®çŽ¡åºç³žãå¡©é žæ¿åºŠ18ééïŒ ãšãã«ã
ã¢ã«ãããæ¿åºŠ18ééïŒ ãããªãæ··å氎溶液ã«
20ã21âã®æž©åºŠã§60åé浞挬ãã次ãã§97âã®
枩床ã«ãŸã§ïŒæéãèŠããŠææž©ãã9.7ã98â
ã®æž©åºŠã§10æéä¿æãããããããŠåŸã硬åã
ãã©ãã¯ç¹ç¶ãäžè¿°ããã®ãšåäžã®æ¡ä»¶ã§æž©æ°Ž
æŽåŸ0.5ééïŒ ã®ã¢ã³ã¢ãã¢ãš50ééïŒ ã®ã¡ã¿
ããŒã«ãããªãæ··å氎溶液ã§åŠçããæž©æ°Žã§æŽ
ãã次ãã§ä¹Ÿç¥ããããã®ãã®ãããŒã«ãã«ã§
ç²ç ããã150ã¿ã€ã©ãŒã¡ãã·ãŠã®ç¯©ãééã
ããã®ã®æ§è³ªãRunNo.23ãšããŠç¬¬ïŒè¡šã«èšèŒã
ãã (3) 第ïŒè¡šã«ã¯äœ¿çšããå¡©é žããã«ã ã¢ã«ããã
ããã³å¡©é žãšãã«ã ã¢ã«ãããã®åèšæ¿åºŠãã
ãšããŒã«ãšå°¿çŽ ãšã®åèšééã«å¯Ÿããå¡©é žâã
ã«ã ã¢ã«ããã溶液ã®ééã®å²åããã³ãã«ã
ã¢ã«ãããïŒã¢ã«ïŒå¯ŸããšããŒã«ïŒã¢ã«ïŒãšå°¿
çŽ ïŒã¢ã«ïŒãšã®åèšã®ã¢ã«æ¯ã瀺ããããŸãã
第ïŒè¡šã«ã¯åŸãããè©Šæã®é¡åŸ®é¡èŠ³å¯ã«ãã
0.1ã50ÎŒããã³0.1ã100ÎŒã®ç²åã®å«æçã
åŸãããè©Šæã150ã¿ã€ã©ãŒã¡ãã·ãŠã®ç¯©ã«ã
ããå Žåã®ç¯©éééïŒ150ã¡ãã·ãŠãã¹ïŒãã
ã³åŸãããè©Šæã®èµ€å€åžåã¹ãã¯ãã«æ³ã«ãã
960ã1020cm-1ã1280ã1360cm-1ããã³1580ã
1650cm-1ã«ãããåžå匷床ã®1450ã1500cm-1ã®
åžå匷床ã«å¯Ÿããåžåæ³¢é·åŒ·åºŠæ¯ïŒIR匷床
æ¯ïŒã瀺ããã
ãè¡šã
ãè¡šã
第ïŒè¡šã«ãããRunNo.ïŒïŒïŒïŒïŒïŒ17ããã³20
ã®å®éšã§ã¯ã»ãã©ãã«ãã©ã¹ã³ã®åºã«ç²çæ§ã®æš¹
èã硬ã倧ããªå¡ç¶ç©åã¯æ¿ç¶ç©ãå€ãçæã
ãã ãŸããRunNo.ïŒïŒïŒããã³20ã®å®éšã§ã¯ã䜿çš
ãã25ïœã®ããšããŒã«ãš25ïœã®å°¿çŽ ãšããåºåœ¢ç©
ã49ïœããå°ãéã§åŸãããã«ãããªãã€ãã RunNo.ïŒïŒïŒïŒïŒïŒïŒïŒ17ããã³20ã«ã€ããŠç¬¬
ïŒè¡šã«èšèŒãã0.1ã50ÎŒããã³0.1ã100ÎŒç²å
ã®å«æçïŒïŒ ïŒããã³150ã¡ãã·ãŠãã¹ïŒéé
ïŒ ïŒã®æ°å€ã¯ãç²çæ§æš¹èãå¡ç¶ç©åã³æ¿ç¶ç©ã
å«ããå šåºåœ¢ç©ã«å¯Ÿããç²ç¶ãªããç²æ«ç¶ç©ã«ã€
ããŠã®å€ã§ãããããããªããããããã®å®éšã«
ãããŠçæããåºåœ¢ç©ã®å ã®ç²ç¶ãªããç²æ«ç¶ç©
ã®ã¿ã®äžã®0.1ã50ÎŒããã³0.1ã100ÎŒç²åã®å«
æçïŒïŒ ïŒããã³150ã¡ãã·ãŠãã¹ïŒééïŒ ïŒã®
æ°å€ã¯ãããã第ïŒè¡šã«ã«ãã³ã§éããŠç€ºããå€
ã§ãã€ãã 第ïŒè¡šã«èšèŒããçµæããå«ããäžèšå®éšäºå®
ãããRunNo.ïŒïŒïŒïŒïŒïŒïŒïŒ17ããã³20ã¯è£œé
æ¹æ³ãšããŠã¯æšå¥šã§ããªããããããªããããã
ãã®è£œé æ¹æ³ã§ãã€ãŠãçæãããç²ç¶ãªããç²
æ«ç¶ç©ã«éã€ãŠã¿ãã°ãããã®ç²ç¶ãªããç²æ«ç¶
ç©ã¯æ¬çºæã§çšããããç²ç¶ãªããç²æ«ç¶å«çªçŽ
æš¹èãšããŠå åã«å¥œé©ã«äœ¿çšãããç¹æ§ãæããŠ
ããã æ·»ä»å³é¢ã®ç¬¬ïŒå³ã«ã¯ãRunNo.12ã§åŸãããç²
ç¶ãªããç²æ«ç¶ç©ã®èµ€å€ç·åžåã¹ãã¯ãã«å³ã瀺
ããããŸããå第ïŒå³ã«ã¯èµ€å€ç·åžåã¹ãã¯ãã«
å³ããåžå匷床ãæ±ããéã«å¿ èŠãšããããtp
ããã³tbã®æ±ãæ¹ãå³è§£ãããããããŒã¯ã«ããŒ
ã¹ã©ã€ã³ãåŒãããã®æ³¢é·ã«ãããŠtpããã³tbã
å³è§£ããããã«ããŠæ±ããããã åèäŸ ïŒ å®€æž©ã21ã22âã®å®€å ã§20ã®åå¿å®¹åšïŒåã®
倫ã ã«ã18ééïŒ ã®å¡©é žã®11ééïŒ ã®ãã«ã ã¢ã«
ããããããªãæ··å氎溶液ã10Kgå ¥ãããããã
ãã®ãã©ã¹ã³ã«ã23âã®æž©åºŠã§æ¹æããªãããã
ãšããŒã«30ééïŒ ãå°¿çŽ 20ééïŒ ããã³ãã«ã ã¢
ã«ããã11ééïŒ ãããªãæ··å氎溶液ãåã 3.34
Kgã2.26Kgã1.60Kgã1.06Kgã0.74Kgããã³0.45
Kgå ããããã®å Žåã®æµŽæ¯ã¯åã 7.0ïŒ8.5ïŒ
13.5ïŒ20.0ïŒ28.0ããã³45.0ã§ãã€ãããããã®
å Žåã該混å氎溶液ãæå ¥åŸæŽã«æ¹æãç¶ããŠã
ããšã10ã60ç§éã§æ¥æ¿ã«çœæ¿ãããçœæ¿ãšåæ
ã«æ¹æãäžæ¢ãããã®ãŸãŸïŒæéé眮ãããå æž©
ãåŸã ã«äžæããçœæ¿ããŠãã30ååŸã«ã¯ããã
ã«ãçœè²ã®ã¹ã©ãªãŒç¶ãããã¯æš¹èç¶ç©ã®çæã
ã¿ãããã次ãã§åã ã®å 容ç©ãæ¹æããªããæ°Ž
æŽããããã®å Žåã济æ¯7.0ã®ç³»ã¯æ¹ææ£ã«æš¹è
ç¶ã®ç¡¬åç©ã倧éã«èçããæ¹æãéåžžã«å°é£ãš
ãªã€ãã 次ãã§å 容ç©ã0.3ééïŒ ã®ã¢ã³ã¢ãã¢æ°Žæº¶æ¶²
äžã30âã®æž©åºŠã§ãã€ããæ¹æããªããïŒæéåŠ
çããæ°ŽæŽåŸè±æ°ŽãããåŸãããç²ç¶ãªããç²ç¶
ç©ãŸãã¯å¡ç¶ç©ãæã§è»œããã¿ã»ãã40âã®æž©åºŠ
ã§ïŒæé也ç¥ããã也ç¥åŸã®æ°Žåã¯ãããã0.5
ééïŒ ä»¥äžã§ãã€ããå 容ç©ã¯åå¿ã®æµŽæ¯ãå°ã
ãæ¹ããé ã«RunNo.31ïŒ32ïŒ33ïŒ34ïŒ35ããã³36
ãšããã 第ïŒè¡šã«ã¯ãåå¿éå§ããçœæ¿ããŠïŒæéåŸãŸ
ã§ã®éã®åå¿ç³»å ã®æé«å°é枩床ãåå¿çæç©ã®
åçãé¡åŸ®é¡èŠ³å¯ã«ããçç¶äžæ¬¡ç²åã®æç¡ãå
å¿çæç©ã«å ãã150ã¿ã€ã©ãŒã¡ãã·ãŠééåã®
å«æçã150ã¡ãã·ãŠãã¹åã®åµ©å¯åºŠãåå¿çæ
ç©ã®100âã§ã®ç±èçæ§ãã¡ã¿ããŒã«æº¶è§£åºŠãã
ã³éé¢ããšããŒã«å«æéã瀺ããã
ã®å®éšã§ã¯ã»ãã©ãã«ãã©ã¹ã³ã®åºã«ç²çæ§ã®æš¹
èã硬ã倧ããªå¡ç¶ç©åã¯æ¿ç¶ç©ãå€ãçæã
ãã ãŸããRunNo.ïŒïŒïŒããã³20ã®å®éšã§ã¯ã䜿çš
ãã25ïœã®ããšããŒã«ãš25ïœã®å°¿çŽ ãšããåºåœ¢ç©
ã49ïœããå°ãéã§åŸãããã«ãããªãã€ãã RunNo.ïŒïŒïŒïŒïŒïŒïŒïŒ17ããã³20ã«ã€ããŠç¬¬
ïŒè¡šã«èšèŒãã0.1ã50ÎŒããã³0.1ã100ÎŒç²å
ã®å«æçïŒïŒ ïŒããã³150ã¡ãã·ãŠãã¹ïŒéé
ïŒ ïŒã®æ°å€ã¯ãç²çæ§æš¹èãå¡ç¶ç©åã³æ¿ç¶ç©ã
å«ããå šåºåœ¢ç©ã«å¯Ÿããç²ç¶ãªããç²æ«ç¶ç©ã«ã€
ããŠã®å€ã§ãããããããªããããããã®å®éšã«
ãããŠçæããåºåœ¢ç©ã®å ã®ç²ç¶ãªããç²æ«ç¶ç©
ã®ã¿ã®äžã®0.1ã50ÎŒããã³0.1ã100ÎŒç²åã®å«
æçïŒïŒ ïŒããã³150ã¡ãã·ãŠãã¹ïŒééïŒ ïŒã®
æ°å€ã¯ãããã第ïŒè¡šã«ã«ãã³ã§éããŠç€ºããå€
ã§ãã€ãã 第ïŒè¡šã«èšèŒããçµæããå«ããäžèšå®éšäºå®
ãããRunNo.ïŒïŒïŒïŒïŒïŒïŒïŒ17ããã³20ã¯è£œé
æ¹æ³ãšããŠã¯æšå¥šã§ããªããããããªããããã
ãã®è£œé æ¹æ³ã§ãã€ãŠãçæãããç²ç¶ãªããç²
æ«ç¶ç©ã«éã€ãŠã¿ãã°ãããã®ç²ç¶ãªããç²æ«ç¶
ç©ã¯æ¬çºæã§çšããããç²ç¶ãªããç²æ«ç¶å«çªçŽ
æš¹èãšããŠå åã«å¥œé©ã«äœ¿çšãããç¹æ§ãæããŠ
ããã æ·»ä»å³é¢ã®ç¬¬ïŒå³ã«ã¯ãRunNo.12ã§åŸãããç²
ç¶ãªããç²æ«ç¶ç©ã®èµ€å€ç·åžåã¹ãã¯ãã«å³ã瀺
ããããŸããå第ïŒå³ã«ã¯èµ€å€ç·åžåã¹ãã¯ãã«
å³ããåžå匷床ãæ±ããéã«å¿ èŠãšããããtp
ããã³tbã®æ±ãæ¹ãå³è§£ãããããããŒã¯ã«ããŒ
ã¹ã©ã€ã³ãåŒãããã®æ³¢é·ã«ãããŠtpããã³tbã
å³è§£ããããã«ããŠæ±ããããã åèäŸ ïŒ å®€æž©ã21ã22âã®å®€å ã§20ã®åå¿å®¹åšïŒåã®
倫ã ã«ã18ééïŒ ã®å¡©é žã®11ééïŒ ã®ãã«ã ã¢ã«
ããããããªãæ··å氎溶液ã10Kgå ¥ãããããã
ãã®ãã©ã¹ã³ã«ã23âã®æž©åºŠã§æ¹æããªãããã
ãšããŒã«30ééïŒ ãå°¿çŽ 20ééïŒ ããã³ãã«ã ã¢
ã«ããã11ééïŒ ãããªãæ··å氎溶液ãåã 3.34
Kgã2.26Kgã1.60Kgã1.06Kgã0.74Kgããã³0.45
Kgå ããããã®å Žåã®æµŽæ¯ã¯åã 7.0ïŒ8.5ïŒ
13.5ïŒ20.0ïŒ28.0ããã³45.0ã§ãã€ãããããã®
å Žåã該混å氎溶液ãæå ¥åŸæŽã«æ¹æãç¶ããŠã
ããšã10ã60ç§éã§æ¥æ¿ã«çœæ¿ãããçœæ¿ãšåæ
ã«æ¹æãäžæ¢ãããã®ãŸãŸïŒæéé眮ãããå æž©
ãåŸã ã«äžæããçœæ¿ããŠãã30ååŸã«ã¯ããã
ã«ãçœè²ã®ã¹ã©ãªãŒç¶ãããã¯æš¹èç¶ç©ã®çæã
ã¿ãããã次ãã§åã ã®å 容ç©ãæ¹æããªããæ°Ž
æŽããããã®å Žåã济æ¯7.0ã®ç³»ã¯æ¹ææ£ã«æš¹è
ç¶ã®ç¡¬åç©ã倧éã«èçããæ¹æãéåžžã«å°é£ãš
ãªã€ãã 次ãã§å 容ç©ã0.3ééïŒ ã®ã¢ã³ã¢ãã¢æ°Žæº¶æ¶²
äžã30âã®æž©åºŠã§ãã€ããæ¹æããªããïŒæéåŠ
çããæ°ŽæŽåŸè±æ°ŽãããåŸãããç²ç¶ãªããç²ç¶
ç©ãŸãã¯å¡ç¶ç©ãæã§è»œããã¿ã»ãã40âã®æž©åºŠ
ã§ïŒæé也ç¥ããã也ç¥åŸã®æ°Žåã¯ãããã0.5
ééïŒ ä»¥äžã§ãã€ããå 容ç©ã¯åå¿ã®æµŽæ¯ãå°ã
ãæ¹ããé ã«RunNo.31ïŒ32ïŒ33ïŒ34ïŒ35ããã³36
ãšããã 第ïŒè¡šã«ã¯ãåå¿éå§ããçœæ¿ããŠïŒæéåŸãŸ
ã§ã®éã®åå¿ç³»å ã®æé«å°é枩床ãåå¿çæç©ã®
åçãé¡åŸ®é¡èŠ³å¯ã«ããçç¶äžæ¬¡ç²åã®æç¡ãå
å¿çæç©ã«å ãã150ã¿ã€ã©ãŒã¡ãã·ãŠééåã®
å«æçã150ã¡ãã·ãŠãã¹åã®åµ©å¯åºŠãåå¿çæ
ç©ã®100âã§ã®ç±èçæ§ãã¡ã¿ããŒã«æº¶è§£åºŠãã
ã³éé¢ããšããŒã«å«æéã瀺ããã
ãè¡šã
第ïŒè¡šã«ãããŠãRunNo.21ïŒ22ããã³23ïŒç¬¬ïŒ
è¡šåç §æ¯èŒäŸïŒã®éé¢ããšããŒã«å«æéã¯ããã
ãå ç±ç¡¬åããåã®ã¬ãŸãŒã«æš¹èãšããã©ãã¯æš¹
èã«ã€ããŠæž¬å®ããå€ã§ïŒ ïŒå ã«ç€ºããã 第ïŒè¡šã«ãããŠRunNo.31ã®å®éšã§ã¯ããã©ã¹ã³
ã®åºã«çæããåºåœ¢ç©å šäœã®çŽ80ïŒ ã«éããç²ç
æš¹èããã³å¡ç¶ç©ãçæãããç²ç¶ãªããç²æ«ç¶
ç©ã¯çæããåºåœ¢ç©å šäœã®çŽ20ïŒ ã«ãããªãã€ã
ãããã®ãã¡ã®çŽ85ïŒ ã¯100ã¡ãã·ãŠã®ç¯©ãéé
ããããªããRunNo.31ã«ãããçç¶äžæ¬¡ç²åã®æ
ç¡ãå°ããšããã®ã¯ãç²ç¶ãªããç²æ«ç¶ç©ã®åºåœ¢
ç©ã«å ããå²åãçŽ20ïŒ ãšå°ããããšã«ãããåŸ
ã€ãŠãRunNo.31ã®æ¹æ³ã¯è£œé æ¹æ³ãšããŠã¯æšå¥šã§
ããªãããçæããç²ç¶ãªããç²æ«ç¶ç©ã¯æ¬çºæ
ã«ãããŠå¥œé©ã«çšããããç²ç¶ãªããç²æ«ç¶ç©ã®
ç¹æ§ãå åã«åããŠããããªãRunNo.31ã36ã®ç²
ç¶ãªããç²æ«ç¶ç©ã¯å šãŠããã®ã»ãŒå šéã0.1ã
100ÎŒã®ç²åŸã®ãã®ã§ãã€ãã åèäŸ ïŒ ïŒã®ã»ãã©ãã«ãã©ã¹ã³ã«å ¥ãã20ééïŒ ã®
å¡©é žãšïŒééïŒ ã®ãã«ã ã¢ã«ããããããªã24â
ã®æ··å氎溶液1250ïœãæ¹æããªããã37ééïŒ ã®
ãã«ããªã³ã§20ã80ééïŒ ã«åžéããããšããŒã«
é¡ãšå«çªçŽ ååç©ãšã®æº¶æ¶²ããããšããŒã«é¡ãšå«
çªçŽ ååç©ãšã®åèšéã50ïœã«ãªãããã«èª¿æŽã
ãŠè©²æµŽã«å ããã該溶液ã®æ·»å ãšåæã«çœæ¿ãã
ç¬æã«çœè²åã¯ãã³ã¯è²ãããã¯è¶è²ã«å€è²ãã
ãã®ã§ããã該溶液ãæå ¥åŸ10ç§éã§æ¹æãåæ¢
ãããæ¹æåæ¢åŸ60åéé眮ããåã³æ¹æããªã
ã30åéã«75âã«ãŸã§ææž©åŸã73ã76âã®æž©åºŠã§
60åéä¿æãããåã ã®åå¿çæç©ãæ°ŽæŽãã次
ãã§0.3ééïŒ ã®ã¢ã³ã¢ãã¢ãš60ééïŒ ã®ã¡ã¿ã
ãŒã«ãããªãæ··å氎溶液äžã45âã®æž©åºŠã§60åé
åŠçãæ°ŽæŽåŸ80âã®æž©åºŠã§ïŒæé也ç¥ããã 第ïŒè¡šã«ã¯äœ¿çšããããšããŒã«é¡ãšå«çªçŽ åå
ç©ã®çš®é¡ãšå²åãçšããããšããŒã«é¡ãšå«çªçŽ å
åç©ãšã®åèšãã«ããªã³ã«ããåžé溶液ã®æ¿åºŠã
ãã®åžé溶液添å 60ååŸã®åå¿çæç©ã®è²ãåå¿
çæç©ã®äœ¿çšããããšããŒã«é¡ãšå«çªçŽ ååç©ãš
ã®åèšéã«å¯Ÿããåçãåå¿çæç©äžã«å ãã
0.1ã50ÎŒç²åã®å«æçãåå¿çæç©ã®150ã¡ãã·
ãŠãã¹éããã³èµ€å€åžåã¹ãã¯ãã«åŒ·åºŠæ¯ã瀺ã
ãã
è¡šåç §æ¯èŒäŸïŒã®éé¢ããšããŒã«å«æéã¯ããã
ãå ç±ç¡¬åããåã®ã¬ãŸãŒã«æš¹èãšããã©ãã¯æš¹
èã«ã€ããŠæž¬å®ããå€ã§ïŒ ïŒå ã«ç€ºããã 第ïŒè¡šã«ãããŠRunNo.31ã®å®éšã§ã¯ããã©ã¹ã³
ã®åºã«çæããåºåœ¢ç©å šäœã®çŽ80ïŒ ã«éããç²ç
æš¹èããã³å¡ç¶ç©ãçæãããç²ç¶ãªããç²æ«ç¶
ç©ã¯çæããåºåœ¢ç©å šäœã®çŽ20ïŒ ã«ãããªãã€ã
ãããã®ãã¡ã®çŽ85ïŒ ã¯100ã¡ãã·ãŠã®ç¯©ãéé
ããããªããRunNo.31ã«ãããçç¶äžæ¬¡ç²åã®æ
ç¡ãå°ããšããã®ã¯ãç²ç¶ãªããç²æ«ç¶ç©ã®åºåœ¢
ç©ã«å ããå²åãçŽ20ïŒ ãšå°ããããšã«ãããåŸ
ã€ãŠãRunNo.31ã®æ¹æ³ã¯è£œé æ¹æ³ãšããŠã¯æšå¥šã§
ããªãããçæããç²ç¶ãªããç²æ«ç¶ç©ã¯æ¬çºæ
ã«ãããŠå¥œé©ã«çšããããç²ç¶ãªããç²æ«ç¶ç©ã®
ç¹æ§ãå åã«åããŠããããªãRunNo.31ã36ã®ç²
ç¶ãªããç²æ«ç¶ç©ã¯å šãŠããã®ã»ãŒå šéã0.1ã
100ÎŒã®ç²åŸã®ãã®ã§ãã€ãã åèäŸ ïŒ ïŒã®ã»ãã©ãã«ãã©ã¹ã³ã«å ¥ãã20ééïŒ ã®
å¡©é žãšïŒééïŒ ã®ãã«ã ã¢ã«ããããããªã24â
ã®æ··å氎溶液1250ïœãæ¹æããªããã37ééïŒ ã®
ãã«ããªã³ã§20ã80ééïŒ ã«åžéããããšããŒã«
é¡ãšå«çªçŽ ååç©ãšã®æº¶æ¶²ããããšããŒã«é¡ãšå«
çªçŽ ååç©ãšã®åèšéã50ïœã«ãªãããã«èª¿æŽã
ãŠè©²æµŽã«å ããã該溶液ã®æ·»å ãšåæã«çœæ¿ãã
ç¬æã«çœè²åã¯ãã³ã¯è²ãããã¯è¶è²ã«å€è²ãã
ãã®ã§ããã該溶液ãæå ¥åŸ10ç§éã§æ¹æãåæ¢
ãããæ¹æåæ¢åŸ60åéé眮ããåã³æ¹æããªã
ã30åéã«75âã«ãŸã§ææž©åŸã73ã76âã®æž©åºŠã§
60åéä¿æãããåã ã®åå¿çæç©ãæ°ŽæŽãã次
ãã§0.3ééïŒ ã®ã¢ã³ã¢ãã¢ãš60ééïŒ ã®ã¡ã¿ã
ãŒã«ãããªãæ··å氎溶液äžã45âã®æž©åºŠã§60åé
åŠçãæ°ŽæŽåŸ80âã®æž©åºŠã§ïŒæé也ç¥ããã 第ïŒè¡šã«ã¯äœ¿çšããããšããŒã«é¡ãšå«çªçŽ åå
ç©ã®çš®é¡ãšå²åãçšããããšããŒã«é¡ãšå«çªçŽ å
åç©ãšã®åèšãã«ããªã³ã«ããåžé溶液ã®æ¿åºŠã
ãã®åžé溶液添å 60ååŸã®åå¿çæç©ã®è²ãåå¿
çæç©ã®äœ¿çšããããšããŒã«é¡ãšå«çªçŽ ååç©ãš
ã®åèšéã«å¯Ÿããåçãåå¿çæç©äžã«å ãã
0.1ã50ÎŒç²åã®å«æçãåå¿çæç©ã®150ã¡ãã·
ãŠãã¹éããã³èµ€å€åžåã¹ãã¯ãã«åŒ·åºŠæ¯ã瀺ã
ãã
ãè¡šã
ãè¡šã
åèäŸ ïŒ
ïŒåã®ïŒã®ã»ãã©ãã«ãã©ã¹ã³ã®å€«ã
ã«ã18
ééïŒ ã®å¡©é žãšïŒééïŒ ã®ãã«ã ã¢ã«ããããšã
å«ã18âã®æ··å氎溶液1000ïœãå ¥ããã宀枩ã¯15
âã§ãã€ãããããã®å€«ã ãæ¹æããªãããå ã
å°¿çŽ 15ïœã溶解ãã次ãã§ããšããŒã«80ééïŒ ãš
ãã«ã ã¢ã«ãããïŒééïŒ ãšãå«ãæ··ååžé液25
ïœãåã ã«äžåºŠã«æå ¥ããããããã®å Žåããåž
é液ãæå ¥åŸ10ç§éã§æ¹æãåæ¢ããŠéæ¢ãã
ãã倫ã æ¹æåæ¢åŸ18ã19ç§ã§æ¥æ¿ã«çœæ¿ããä¹³
çœè²ã®çæç©ã芳å¯ãããã倫ã ã®æ¶²æž©ã¯18âã
ãåŸã ã«äžããåžé液æå ¥åŸïŒãïŒåéã§31ã32
âã®ããŒã¯ã«éããåã³éäžãããåžé液ãæå ¥
åŸã0.5æéïŒRunNo.61ïŒãïŒæéïŒRunNo.62ïŒãïŒ
æéïŒRunNo.63ïŒãïŒæéïŒRunNo.64ïŒã24æé
ïŒRunNo.65ïŒã72æéïŒRunNo.66ïŒå®€æž©äžã«æŸçœ®
åŸãå 容ç©ãæ°ŽæŽãã0.75ééïŒ ã®ã¢ã³ã¢ãã¢æ°Ž
äžã15ã17âã®æž©åºŠã§ïŒæéåŠçåŸãæ°ŽæŽã次ã
ã§è±æ°Žãã40âã®æž©åºŠã§ïŒæé也ç¥ããã 第ïŒè¡šã«ã¯ãåŸããã也ç¥è©Šæã®150ã¿ã€ã©ãŒ
ã¡ãã·ãŠç¯©ééçã960ã1020cm-1ã®IR匷床æ¯ã
ã¡ã¿ããŒã«æº¶è§£éãéé¢ããšããŒã«å«éã瀺ã
ããå°ãRunNo.61ãRunNo.66ã®è©Šæã¯ããããç±
èçè©Šéšã«ãããŠã100âãïŒåã§èçããã
ééïŒ ã®å¡©é žãšïŒééïŒ ã®ãã«ã ã¢ã«ããããšã
å«ã18âã®æ··å氎溶液1000ïœãå ¥ããã宀枩ã¯15
âã§ãã€ãããããã®å€«ã ãæ¹æããªãããå ã
å°¿çŽ 15ïœã溶解ãã次ãã§ããšããŒã«80ééïŒ ãš
ãã«ã ã¢ã«ãããïŒééïŒ ãšãå«ãæ··ååžé液25
ïœãåã ã«äžåºŠã«æå ¥ããããããã®å Žåããåž
é液ãæå ¥åŸ10ç§éã§æ¹æãåæ¢ããŠéæ¢ãã
ãã倫ã æ¹æåæ¢åŸ18ã19ç§ã§æ¥æ¿ã«çœæ¿ããä¹³
çœè²ã®çæç©ã芳å¯ãããã倫ã ã®æ¶²æž©ã¯18âã
ãåŸã ã«äžããåžé液æå ¥åŸïŒãïŒåéã§31ã32
âã®ããŒã¯ã«éããåã³éäžãããåžé液ãæå ¥
åŸã0.5æéïŒRunNo.61ïŒãïŒæéïŒRunNo.62ïŒãïŒ
æéïŒRunNo.63ïŒãïŒæéïŒRunNo.64ïŒã24æé
ïŒRunNo.65ïŒã72æéïŒRunNo.66ïŒå®€æž©äžã«æŸçœ®
åŸãå 容ç©ãæ°ŽæŽãã0.75ééïŒ ã®ã¢ã³ã¢ãã¢æ°Ž
äžã15ã17âã®æž©åºŠã§ïŒæéåŠçåŸãæ°ŽæŽã次ã
ã§è±æ°Žãã40âã®æž©åºŠã§ïŒæé也ç¥ããã 第ïŒè¡šã«ã¯ãåŸããã也ç¥è©Šæã®150ã¿ã€ã©ãŒ
ã¡ãã·ãŠç¯©ééçã960ã1020cm-1ã®IR匷床æ¯ã
ã¡ã¿ããŒã«æº¶è§£éãéé¢ããšããŒã«å«éã瀺ã
ããå°ãRunNo.61ãRunNo.66ã®è©Šæã¯ããããç±
èçè©Šéšã«ãããŠã100âãïŒåã§èçããã
ãè¡šã
åèäŸ ïŒ
æ¹ææ£ã®ä»ãã1000ã®åå¿å®¹åšã«ã18.5éé
ïŒ ã®å¡©é žãš8.5ééïŒ ã®ãã«ã ã¢ã«ããããããª
ã22.5âã®æž©å氎溶液ã800Kgå ¥ãã該混å氎溶
液ãæ¹æããªãã20âã®20ééïŒ ããšããŒã«ãš10
ééïŒ ã®ãã€ããããã³ããã³20ééïŒ ã®å°¿çŽ ã
ããªãæ··å氎溶液ã40Kgæå ¥ããã 該混å氎溶液ãå šéæå ¥ããŠ20ç§éæ¹æãã
åŸãæ¹æãåæ¢ããŠïŒæéé眮ãããåå¿å®¹åšå
ã§ã¯è©²æ··å氎溶液ãå šéæå ¥åŸ35ç§åŸã«æ¥æ¿ãªçœ
æ¿ãã¿ããã次第ã«çœè²ã®ç²ç¶ç©ãçæãããšå ±
ã«å æž©ãåŸã ã«35.5âã«è¿äžæããåã³éäžã
ãã次ãã§ãåå¿çæç©ã®çæããæ··å氎溶液ã®
ç³»ãå床æ¹æããªããåå¿å®¹åšã®åºéšã«åãä»ã
ããã«ããéããŠå 容ç©ãåãåºããããŒã¡ãã¯
ã¹ã®äžç¹åžãçšããŠãåå¿çæç©ãšè©²å¡©é žãšãã«
ã ã¢ã«ããããããªãæ··å氎溶液ãšãåé¢ããã
ããããŠåŸãåå¿çæç©ãæ°ŽæŽãè±æ°ŽããåŸ18â
ã®0.5ééïŒ ã¢ã³ã¢ãã¢æ°Žæº¶æ¶²ã«äžæŒå€æµžæŒ¬ãã
åŸåã³æ°ŽæŽãè±æ°ŽããŠå«æ°Žçã15ééïŒ ã®åå¿ç
æç©ã29.9KgåŸãã äžèšæ¹æ³ã§åŸãåå¿çæç©ã®2.0Kgã40âã®æž©
床ã§ïŒæé也ç¥ããŠè©Šæ1.7KgãåŸãïŒRunNo.
67ïŒã 第ïŒè¡šã«ã¯ãããããŠåŸã也ç¥è©Šæã®é¡åŸ®é¡èŠ³
å¯ã«ãã0.1ã50ÎŒãš0.1ã100ÎŒç²åã®å«æçã
150ã¿ã€ã©ãŒã¡ãã·ãŠã®ç¯©ã«ãããå Žåã®ééé
ïŒ150ã¡ãã·ãŠãã¹ïŒããã³ã¡ã¿ããŒã«æº¶è§£åºŠã瀺
ããã
ïŒ ã®å¡©é žãš8.5ééïŒ ã®ãã«ã ã¢ã«ããããããª
ã22.5âã®æž©å氎溶液ã800Kgå ¥ãã該混å氎溶
液ãæ¹æããªãã20âã®20ééïŒ ããšããŒã«ãš10
ééïŒ ã®ãã€ããããã³ããã³20ééïŒ ã®å°¿çŽ ã
ããªãæ··å氎溶液ã40Kgæå ¥ããã 該混å氎溶液ãå šéæå ¥ããŠ20ç§éæ¹æãã
åŸãæ¹æãåæ¢ããŠïŒæéé眮ãããåå¿å®¹åšå
ã§ã¯è©²æ··å氎溶液ãå šéæå ¥åŸ35ç§åŸã«æ¥æ¿ãªçœ
æ¿ãã¿ããã次第ã«çœè²ã®ç²ç¶ç©ãçæãããšå ±
ã«å æž©ãåŸã ã«35.5âã«è¿äžæããåã³éäžã
ãã次ãã§ãåå¿çæç©ã®çæããæ··å氎溶液ã®
ç³»ãå床æ¹æããªããåå¿å®¹åšã®åºéšã«åãä»ã
ããã«ããéããŠå 容ç©ãåãåºããããŒã¡ãã¯
ã¹ã®äžç¹åžãçšããŠãåå¿çæç©ãšè©²å¡©é žãšãã«
ã ã¢ã«ããããããªãæ··å氎溶液ãšãåé¢ããã
ããããŠåŸãåå¿çæç©ãæ°ŽæŽãè±æ°ŽããåŸ18â
ã®0.5ééïŒ ã¢ã³ã¢ãã¢æ°Žæº¶æ¶²ã«äžæŒå€æµžæŒ¬ãã
åŸåã³æ°ŽæŽãè±æ°ŽããŠå«æ°Žçã15ééïŒ ã®åå¿ç
æç©ã29.9KgåŸãã äžèšæ¹æ³ã§åŸãåå¿çæç©ã®2.0Kgã40âã®æž©
床ã§ïŒæé也ç¥ããŠè©Šæ1.7KgãåŸãïŒRunNo.
67ïŒã 第ïŒè¡šã«ã¯ãããããŠåŸã也ç¥è©Šæã®é¡åŸ®é¡èŠ³
å¯ã«ãã0.1ã50ÎŒãš0.1ã100ÎŒç²åã®å«æçã
150ã¿ã€ã©ãŒã¡ãã·ãŠã®ç¯©ã«ãããå Žåã®ééé
ïŒ150ã¡ãã·ãŠãã¹ïŒããã³ã¡ã¿ããŒã«æº¶è§£åºŠã瀺
ããã
ãè¡šã
å®æœäŸ ïŒ
åžè²©ã®ç²åïŒä»æž
åãæ°Žåå«æ34ééïŒ
ïŒåç¬
ïŒRunNo.70ïŒãããã³äžèšã®ç²å134éééšã«å¯Ÿã
ãŠãäžèšRunNo.12ã§åŸãç²ç¶ãªããç²æ«ç¶æš¹èã
åã 0.3éééšïŒRunNo.71ïŒãïŒéééšïŒRunNo.
72ïŒãïŒéééšïŒRunNo.73ïŒãïŒéééšïŒRunNo.
74ïŒã10éééšïŒRunNo.75ïŒããã³20éééš
ïŒRunNo.76ïŒé åãããã®ãæã§ååæ··ç·Žããã
ãããã®ç²åºŠåç¬ããã³æ··ç·Žç©ã寞æ³ãå¹ 15mmã
åã¿10mmãé·ã100mmã®æšåœ¢ãçšããŠãåã ã«ã€
ããŠïŒåã®æ圢åãæ圢ããã次ãã§ããããã®
æ圢åã宀枩äžã«ïŒæ¥é也ç¥ããåŸã寞æ³ãå¹ 13
mmãåã¿ïŒmmãé·ã80mmã®åœ¢ç¶ã«ãŸã§ç åã次ã
ã§50âã®ä¹Ÿç¥åšäžã§ïŒæé也ç¥ããŠãçŒæçšã®å
é§äœãšããããããã®åé§äœãã¢ã«ããã»ã·ãªã«
çå¿ç®¡ã®äžå¿éšã«é眮ããŠãçã®æé¢ã«å¯ŸãïŒå
éã«ïŒmlïŒcm2ã®çªçŽ ã¬ã¹ãæµéããããªãã宀枩
ãã1600âã®æž©åºŠãŸã§ïŒæéãèŠããŠææž©ãã
1600âã®æž©åºŠã§ïŒæéä¿æãã次ãã§åŸå·ããŠçŒ
æè©Šéšçãååºããã 第ïŒè¡šã«ã¯ãçšããRunNo.12ã®çæç©ã®é åé
䞊ã³ã«çŒæè©Šéšçã«ã€ããŠã®å€èŠ³ãé·ãä¿æç
ïŒåé§äœã«å¯ŸããŠïŒããã³æ²ã匷床ã瀺ããã
ïŒRunNo.70ïŒãããã³äžèšã®ç²å134éééšã«å¯Ÿã
ãŠãäžèšRunNo.12ã§åŸãç²ç¶ãªããç²æ«ç¶æš¹èã
åã 0.3éééšïŒRunNo.71ïŒãïŒéééšïŒRunNo.
72ïŒãïŒéééšïŒRunNo.73ïŒãïŒéééšïŒRunNo.
74ïŒã10éééšïŒRunNo.75ïŒããã³20éééš
ïŒRunNo.76ïŒé åãããã®ãæã§ååæ··ç·Žããã
ãããã®ç²åºŠåç¬ããã³æ··ç·Žç©ã寞æ³ãå¹ 15mmã
åã¿10mmãé·ã100mmã®æšåœ¢ãçšããŠãåã ã«ã€
ããŠïŒåã®æ圢åãæ圢ããã次ãã§ããããã®
æ圢åã宀枩äžã«ïŒæ¥é也ç¥ããåŸã寞æ³ãå¹ 13
mmãåã¿ïŒmmãé·ã80mmã®åœ¢ç¶ã«ãŸã§ç åã次ã
ã§50âã®ä¹Ÿç¥åšäžã§ïŒæé也ç¥ããŠãçŒæçšã®å
é§äœãšããããããã®åé§äœãã¢ã«ããã»ã·ãªã«
çå¿ç®¡ã®äžå¿éšã«é眮ããŠãçã®æé¢ã«å¯ŸãïŒå
éã«ïŒmlïŒcm2ã®çªçŽ ã¬ã¹ãæµéããããªãã宀枩
ãã1600âã®æž©åºŠãŸã§ïŒæéãèŠããŠææž©ãã
1600âã®æž©åºŠã§ïŒæéä¿æãã次ãã§åŸå·ããŠçŒ
æè©Šéšçãååºããã 第ïŒè¡šã«ã¯ãçšããRunNo.12ã®çæç©ã®é åé
䞊ã³ã«çŒæè©Šéšçã«ã€ããŠã®å€èŠ³ãé·ãä¿æç
ïŒåé§äœã«å¯ŸããŠïŒããã³æ²ã匷床ã瀺ããã
ãè¡šã
ãè¡šã
å®æœäŸ ïŒ
é»èã¢ã«ãã75éééšãçåã±ã€çŽ 15éééšã
倩ç¶é»éïŒéééšãšéå±ã±ã€çŽ ïŒéééšã®çµæã
ããªãæ··åç©100éééšã«å¯ŸããŠïŒéééšã®æ°Žã
é åãããã®ïŒRunNo.77ïŒã䞊ã³ã«äžèšã®æ··åç©
100éééšã«å¯ŸããŠïŒéééšã®æ°ŽãšRunNo.47ã®å
å¿çæç©ïŒäºã200ã¡ãã·ãŠã®ç¯©ãééãããã
ãã®ïŒïŒéééšãšãé åãããã®ïŒRunNo.78ïŒã
æºåããããããã®é åç©ãåã ïŒãã³ïŒcm2ã®å
å§äžã«éåæåããŠã寞æ³ãå¹ ïŒmmãåã¿ïŒãïŒ
mmãé·ã50mmã®è©Šéšçãåé åç©ã«ã€ããŠåã 15
åäœæããã次ã«ããããã®è©Šéšçãã³ãŒã¯ã¹ç²
æ«ãæºããã³ãŒã¯ã¹çã®äž800âã®æž©åºŠã§ïŒæé
çŒæããã 第ïŒè¡šã«ã¯ãäžèšæ¹æ³ã§åŸãïŒçš®é¡ã®è©Šéšçã«
ã€ããŠæ±ããå§çž®åŒ·åºŠããã³ã¯ã©ãã¯çºççã瀺
ãããå§çž®åŒ·åºŠã¯ããããã®è©ŠéšçåïŒåããå
åã€ãè©Šæã«ã€ããŠæ±ããå¹³åå€ãšããŠããŸãã¯
ã©ãã¯çºççã¯åã ã®è©Šéšçå10åããã³ãŒã³ã
ãŒãã§èµ€ç±åŸãæ°Žã®äžãžæå ¥ããå Žåã«ã¯ã©ãã¯
ãçºçããè©Šéšçã®æ°ãšããŠç€ºããã
倩ç¶é»éïŒéééšãšéå±ã±ã€çŽ ïŒéééšã®çµæã
ããªãæ··åç©100éééšã«å¯ŸããŠïŒéééšã®æ°Žã
é åãããã®ïŒRunNo.77ïŒã䞊ã³ã«äžèšã®æ··åç©
100éééšã«å¯ŸããŠïŒéééšã®æ°ŽãšRunNo.47ã®å
å¿çæç©ïŒäºã200ã¡ãã·ãŠã®ç¯©ãééãããã
ãã®ïŒïŒéééšãšãé åãããã®ïŒRunNo.78ïŒã
æºåããããããã®é åç©ãåã ïŒãã³ïŒcm2ã®å
å§äžã«éåæåããŠã寞æ³ãå¹ ïŒmmãåã¿ïŒãïŒ
mmãé·ã50mmã®è©Šéšçãåé åç©ã«ã€ããŠåã 15
åäœæããã次ã«ããããã®è©Šéšçãã³ãŒã¯ã¹ç²
æ«ãæºããã³ãŒã¯ã¹çã®äž800âã®æž©åºŠã§ïŒæé
çŒæããã 第ïŒè¡šã«ã¯ãäžèšæ¹æ³ã§åŸãïŒçš®é¡ã®è©Šéšçã«
ã€ããŠæ±ããå§çž®åŒ·åºŠããã³ã¯ã©ãã¯çºççã瀺
ãããå§çž®åŒ·åºŠã¯ããããã®è©ŠéšçåïŒåããå
åã€ãè©Šæã«ã€ããŠæ±ããå¹³åå€ãšããŠããŸãã¯
ã©ãã¯çºççã¯åã ã®è©Šéšçå10åããã³ãŒã³ã
ãŒãã§èµ€ç±åŸãæ°Žã®äžãžæå ¥ããå Žåã«ã¯ã©ãã¯
ãçºçããè©Šéšçã®æ°ãšããŠç€ºããã
ãè¡šã
å®æœäŸ ïŒ
ã±ã€ãœãŠå100éééšã«å¯ŸããŠãçµåæãšããŠ
RunNo.67ã®çæç©ïŒRunNo.79ïŒãRunNo.22ã§åŸãæª
硬åã®ããã©ãã¯æš¹èã«ãããµã¡ãã¬ã³ããã©ã
ã³15ééïŒ é åãããã®ïŒRunNo.80ïŒãïŒâãã€
ãã³ç²æ«ïŒRunNo.81ïŒããã³éå±ã¢ã«ãããŠã ç²
æ«ïŒRunNo.82ïŒãåã ïŒéééšé åãããã®ãæº
åããããããã®é åç©ãå ç±ãã¬ã¹æãçšã
ãŠã200ã500KgïŒcm2ã®å å§äžã250âã®æž©åºŠã§æ
圢ããåã ã®é åç©ã«ã€ããŠå¯žæ³ãå¹ 100mmãé·
ã100mmãåã¿ïŒã10mmã®æ圢æ¿ãïŒåäœæã
ãã 第ïŒè¡šã«ã¯çµåæã®çš®é¡äžŠã³ã«åŸãããæ圢æ¿
ã®åµ©æ¯éãå§çž®åŒ·åºŠãç±äŒå°çã瀺ããããŸã第
ïŒè¡šã«ã¯åã ã®æ圢æ¿ãçªçŽ ã¬ã¹é°å²æ°äž650â
ã®æž©åºŠã§ïŒåéç±åŠçããããããåŸã®æ圢æ¿ã®
å§çž®åŒ·åºŠãšç±äŒå°çããåããŠç€ºããã
RunNo.67ã®çæç©ïŒRunNo.79ïŒãRunNo.22ã§åŸãæª
硬åã®ããã©ãã¯æš¹èã«ãããµã¡ãã¬ã³ããã©ã
ã³15ééïŒ é åãããã®ïŒRunNo.80ïŒãïŒâãã€
ãã³ç²æ«ïŒRunNo.81ïŒããã³éå±ã¢ã«ãããŠã ç²
æ«ïŒRunNo.82ïŒãåã ïŒéééšé åãããã®ãæº
åããããããã®é åç©ãå ç±ãã¬ã¹æãçšã
ãŠã200ã500KgïŒcm2ã®å å§äžã250âã®æž©åºŠã§æ
圢ããåã ã®é åç©ã«ã€ããŠå¯žæ³ãå¹ 100mmãé·
ã100mmãåã¿ïŒã10mmã®æ圢æ¿ãïŒåäœæã
ãã 第ïŒè¡šã«ã¯çµåæã®çš®é¡äžŠã³ã«åŸãããæ圢æ¿
ã®åµ©æ¯éãå§çž®åŒ·åºŠãç±äŒå°çã瀺ããããŸã第
ïŒè¡šã«ã¯åã ã®æ圢æ¿ãçªçŽ ã¬ã¹é°å²æ°äž650â
ã®æž©åºŠã§ïŒåéç±åŠçããããããåŸã®æ圢æ¿ã®
å§çž®åŒ·åºŠãšç±äŒå°çããåããŠç€ºããã
ãè¡šã
å°ãRunNo.81ã®ç±åŠçåã¯ããããŸãå€åœ¢ããŠ
ããããã®å§çž®åŒ·åºŠããã³ç±äŒå°çã¯ç¬¬ïŒè¡šã«ç€º
ãããšãã枬å®ã§ããªãã€ãã å®æœäŸ ïŒ äžèšïŒ¡è¡šã«ç€ºãé åç©ã«å¯ŸããŠRunNo.21ã§åŸã
ã¬ãŸãŒã«æº¶æ¶²ãRunNo.22ã§åŸãããã©ãã¯æš¹è
ïŒãããµã¡ãã¬ã³ããã©ãã³15ééïŒ é ååïŒã
ãã³RunNo.64ã®çæç©ãããããæš¹èåºåœ¢åæç®
ã§10éééšé åãããåŸãããé åç©ãéåã«å
äžã«å å¡«ãã枩床155âãå§å400KgïŒcm2ã§30åé
å§çž®æåãããè±æ åŸ170âã§24æéä¿æããŠç¡¬
åãå®äºãã寞æ³ãå€åŸ510mmãåã¿204mmãååŸ
304mmã®ç åç ¥ç³ã補é ããã
ããããã®å§çž®åŒ·åºŠããã³ç±äŒå°çã¯ç¬¬ïŒè¡šã«ç€º
ãããšãã枬å®ã§ããªãã€ãã å®æœäŸ ïŒ äžèšïŒ¡è¡šã«ç€ºãé åç©ã«å¯ŸããŠRunNo.21ã§åŸã
ã¬ãŸãŒã«æº¶æ¶²ãRunNo.22ã§åŸãããã©ãã¯æš¹è
ïŒãããµã¡ãã¬ã³ããã©ãã³15ééïŒ é ååïŒã
ãã³RunNo.64ã®çæç©ãããããæš¹èåºåœ¢åæç®
ã§10éééšé åãããåŸãããé åç©ãéåã«å
äžã«å å¡«ãã枩床155âãå§å400KgïŒcm2ã§30åé
å§çž®æåãããè±æ åŸ170âã§24æéä¿æããŠç¡¬
åãå®äºãã寞æ³ãå€åŸ510mmãåã¿204mmãååŸ
304mmã®ç åç ¥ç³ã補é ããã
ãè¡šã
ãè¡šã
第10è¡šã«ã¯ãçšããããšããŒã«æš¹èã®çš®é¡ãšåŸ
ãããç ¥ç³ãç ¥ç³åšé4800ïœïŒåãæŒä»å§å500
Kgã®æ¡ä»¶äžã§è©Šéšã«ä»ããå Žåã«ããããè©²ç ¥ç³
ã®æ§èœã瀺ããã
ãããç ¥ç³ãç ¥ç³åšé4800ïœïŒåãæŒä»å§å500
Kgã®æ¡ä»¶äžã§è©Šéšã«ä»ããå Žåã«ããããè©²ç ¥ç³
ã®æ§èœã瀺ããã
ãè¡šã
å®æœäŸ ïŒ
300ã¡ãã·ãŠã®ç¯©ãééããããåžè²©ç¹çŽã®
CrïŒAl2O3ïŒAlïŒOHïŒ3ãåã 30ïŒ50ããã³20é
ééšã®å²åã§ä¹ŸåŒæ··åãããã®ã«ã¡ãã«ã¢ã«ã³ãŒ
ã«ãçéå ããæ¯åãã«ãçšããŠæ¹¿åŒç²ç æ··åã
ãã湿åŒæ··åã®éäžã§ãäžèšä¹ŸåŒæ··åç©100éé
éšã«å¯ŸããŠã0.25éééšã®ããïŒRunNo.86ïŒåã¯
äºã300ã¡ãã·ãŠã®ç¯©ãééããããRunNo.40ã®
çæç©0.25éééšïŒRunNo.87ïŒãããããæ·»å ã
ããåŸãããæ··åç©ã次ãã§æžå§ä¹Ÿç¥ããæŽã«
100âã®æž©åºŠã§24æéç±åŠçããã次ã«åã ã®æ··
åç©ãïŒãã³ïŒcm2ã®å å§äžã§æ圢ããŠã寞æ³ãïŒ
mmÃïŒmmÃ50mmã®è©ŠéšçãäœæãããããããŠåŸ
ãåã ã®è©Šéšçã«ã80âã«å ç±ããç±æ°Žäžãéé
ããããæ°ŽçŽ ãéå ¥ãç¶ããªããã宀枩ãã1650
âã®æž©åºŠã«ãŸã§24æéãèŠããŠææž©ããå枩床ã§
ïŒæéä¿æã次ãã§æŸå·ããŠçŒæè©ŠéšçãåŸãã 第11è¡šã«ã¯ãäžèšæ¹æ³ã«ãŠåŸãïŒçš®é¡ã®æ圢å
ã«çšããæ·»å ç©ã®çš®é¡äžŠã³ã«çŒæè©Šéšçã®èŠæå¯
床ãæ²ã匷床ããã³700âãš1000âã«ãããé»æ°
æ¯æµæã瀺ããã
CrïŒAl2O3ïŒAlïŒOHïŒ3ãåã 30ïŒ50ããã³20é
ééšã®å²åã§ä¹ŸåŒæ··åãããã®ã«ã¡ãã«ã¢ã«ã³ãŒ
ã«ãçéå ããæ¯åãã«ãçšããŠæ¹¿åŒç²ç æ··åã
ãã湿åŒæ··åã®éäžã§ãäžèšä¹ŸåŒæ··åç©100éé
éšã«å¯ŸããŠã0.25éééšã®ããïŒRunNo.86ïŒåã¯
äºã300ã¡ãã·ãŠã®ç¯©ãééããããRunNo.40ã®
çæç©0.25éééšïŒRunNo.87ïŒãããããæ·»å ã
ããåŸãããæ··åç©ã次ãã§æžå§ä¹Ÿç¥ããæŽã«
100âã®æž©åºŠã§24æéç±åŠçããã次ã«åã ã®æ··
åç©ãïŒãã³ïŒcm2ã®å å§äžã§æ圢ããŠã寞æ³ãïŒ
mmÃïŒmmÃ50mmã®è©ŠéšçãäœæãããããããŠåŸ
ãåã ã®è©Šéšçã«ã80âã«å ç±ããç±æ°Žäžãéé
ããããæ°ŽçŽ ãéå ¥ãç¶ããªããã宀枩ãã1650
âã®æž©åºŠã«ãŸã§24æéãèŠããŠææž©ããå枩床ã§
ïŒæéä¿æã次ãã§æŸå·ããŠçŒæè©ŠéšçãåŸãã 第11è¡šã«ã¯ãäžèšæ¹æ³ã«ãŠåŸãïŒçš®é¡ã®æ圢å
ã«çšããæ·»å ç©ã®çš®é¡äžŠã³ã«çŒæè©Šéšçã®èŠæå¯
床ãæ²ã匷床ããã³700âãš1000âã«ãããé»æ°
æ¯æµæã瀺ããã
ãè¡šã
第11è¡šäžã700âãš1000âã®é»æ°æ¯æµæã¯ãè©Š
éšçã®äž¡ç«¯ã«ãªãŒãç·ïŒçœéç·ïŒãåãä»ããã
ããçªçŽ é°å²æ°äžã®ã¢ã«ããã»ã·ãªã«çã®äžå¿éš
ã«é眮ããŠçã®æž©åºŠã700âåã¯1000âã«ä¿æã
ãŠæž¬å®ããããã®æž¬å®æ¡ä»¶ä»¥å€ã¯ãéåžžã®é»æ°æ¯
æµæ枬å®æ³ã«æºããŠè¡ã€ãã å®æœäŸ ïŒ å®æœäŸïŒã§çšãããšåãç²å134éééšãš100ã¡
ãã·ãŠã®ç¯©ãééããããã·ãªã«ç²æ«100éééš
ãããªãæ··åç©ãæºåããããã®æ··åç©ãã®ãã®
ïŒRunNo.88ïŒããã³ãã®æ··åç©ã«RunNo.35ã®çæ
ç©ã15éééšæ·»å ãããã®ïŒRunNo.89ïŒã«ã€ããŠ
å®æœäŸïŒãšåæ§ã«ããŠæ圢åãåŸããåã ã®æ圢
åãïŒæ¥é颚也åŸ50âã®æž©åºŠã§24æé也ç¥ããã
次ãã§åŸãããåã ã®è©Šéšçãçã«å ¥ãã20容ç©
ïŒ ã®å¡©åæ°ŽçŽ ãš80容ç©ïŒ ã®çªçŽ ãããªãæ··åã¬ã¹
ãé颚ããªããçã®æž©åºŠã宀枩ãã1600âã«ãŸã§
ïŒæéãèŠããŠææž©ããå枩床ã«ïŒæéä¿æãã
次ãã§é颚ã¬ã¹ãçªçŽ ã¬ã¹ã®ã¿ã«åæ¿ããŠé颚ã
ã€ã¥ããªããå·åŽããçŒæè©ŠéšçãåŸãã 第12è¡šã«ã¯åŸãããçŒæè©Šéšçã®è²èª¿ã硬床ã
ãã³å§çž®åŒ·åºŠã瀺ããã
éšçã®äž¡ç«¯ã«ãªãŒãç·ïŒçœéç·ïŒãåãä»ããã
ããçªçŽ é°å²æ°äžã®ã¢ã«ããã»ã·ãªã«çã®äžå¿éš
ã«é眮ããŠçã®æž©åºŠã700âåã¯1000âã«ä¿æã
ãŠæž¬å®ããããã®æž¬å®æ¡ä»¶ä»¥å€ã¯ãéåžžã®é»æ°æ¯
æµæ枬å®æ³ã«æºããŠè¡ã€ãã å®æœäŸ ïŒ å®æœäŸïŒã§çšãããšåãç²å134éééšãš100ã¡
ãã·ãŠã®ç¯©ãééããããã·ãªã«ç²æ«100éééš
ãããªãæ··åç©ãæºåããããã®æ··åç©ãã®ãã®
ïŒRunNo.88ïŒããã³ãã®æ··åç©ã«RunNo.35ã®çæ
ç©ã15éééšæ·»å ãããã®ïŒRunNo.89ïŒã«ã€ããŠ
å®æœäŸïŒãšåæ§ã«ããŠæ圢åãåŸããåã ã®æ圢
åãïŒæ¥é颚也åŸ50âã®æž©åºŠã§24æé也ç¥ããã
次ãã§åŸãããåã ã®è©Šéšçãçã«å ¥ãã20容ç©
ïŒ ã®å¡©åæ°ŽçŽ ãš80容ç©ïŒ ã®çªçŽ ãããªãæ··åã¬ã¹
ãé颚ããªããçã®æž©åºŠã宀枩ãã1600âã«ãŸã§
ïŒæéãèŠããŠææž©ããå枩床ã«ïŒæéä¿æãã
次ãã§é颚ã¬ã¹ãçªçŽ ã¬ã¹ã®ã¿ã«åæ¿ããŠé颚ã
ã€ã¥ããªããå·åŽããçŒæè©ŠéšçãåŸãã 第12è¡šã«ã¯åŸãããçŒæè©Šéšçã®è²èª¿ã硬床ã
ãã³å§çž®åŒ·åºŠã瀺ããã
æ·»ä»å³é¢ã®ç¬¬ïŒå³ã¯ãæ¬çºæã«çšããããç²ç¶
ãªããç²æ«ç¶ã®å«çªçŽ ããšããŒã«ã»ãã«ã ã¢ã«ã
ããæš¹èã®ïŒäŸã®èµ€å€ç·åžåã¹ãã¯ãã«å³ã§ã
ãã第ïŒå³äžã«ã¯ããã®ããŒã¯ã®ç¹å®æ³¢é·ã«ãã
ãåžå匷床ãæ±ããæ¹æ³ãå³è§£ããŠããã
ãªããç²æ«ç¶ã®å«çªçŽ ããšããŒã«ã»ãã«ã ã¢ã«ã
ããæš¹èã®ïŒäŸã®èµ€å€ç·åžåã¹ãã¯ãã«å³ã§ã
ãã第ïŒå³äžã«ã¯ããã®ããŒã¯ã®ç¹å®æ³¢é·ã«ãã
ãåžå匷床ãæ±ããæ¹æ³ãå³è§£ããŠããã
Claims (1)
- ãç¹èš±è«æ±ã®ç¯å²ã ïŒ (1) ããšããŒã«é¡ãå°ããšãïŒåã®æŽ»æ§æ°ŽçŽ
ãæããå«çªçŽ ååç©ããã³ã¢ã«ããããšã®çž®
åç©ããæãç²ç¶ãªããç²æ«ç¶æš¹èã§ãã€ãŠã (A) 該ç²ç¶ãªããç²æ«ç¶æš¹èã¯ç²åŸ0.1ã100ã
ã¯ãã³ã®çç¶äžæ¬¡ç²åããã³ãã®äºæ¬¡åéç©
ãå«æãããã㊠(B) 該暹èã®KBré å€æ³ã«ããèµ€å€ç·åžåã¹ã
ã¯ãã«ã«ãããŠã 1450ã1500cm-1ã®ç¯å²ã®æã倧ããªåžå匷
床ã1450ã1500ããã㊠960ã1020cm-1ã®ç¯å²ã®æã倧ããªåžå匷
床ã960ã1020ã ã§è¡šãããå Žåã 960ã1020ïŒïŒ€1450ã1500ïŒ0.1ã2.0ã§ã
ãã ã®ç²ç¶ãªããç²æ«ç¶ã®å«çªçŽ ããšããŒã«ã»ã¢ã«
ãããæš¹èãšã (2) ç¡æ©è³ªææç²äœ ãšãå«æããäžã€ äžèšå«çªçŽ ããšããŒã«ã»ã¢ã«ãããæš¹èãã該
å«çªçŽ ããšããŒã«ã»ã¢ã«ãããæš¹èãšè©²ç¡æ©è³ª
ææç²äœã®åèšéã«åºã¥ããŠ11ééïŒ ããå°ãª
ãéã§å«æããã ããšãç¹åŸŽãšããçµæç©ã ïŒ è©²ç²ç¶ãªããç²æ«ç¶å«çªçŽ æš¹èã®å°ããšã30
ïŒ ãç²åŸ0.1ã100ãã¯ãã³ã®çç¶äžæ¬¡ç²åããã³
ãã®äºæ¬¡åéç©ããæãç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé ã«
èšèŒã®çµæç©ã ïŒ è©²ç²ç¶ãªããç²æ«ç¶å«çªçŽ æš¹èã¯ãKBré å€
æ³ã«ããèµ€å€ç·åžåã¹ãã¯ãã«ã«ãããŠã 1280ã1360cm-1ïŒççŽ âçªçŽ çµåã«åž°å±ããåž
åããŒã¯ïŒã®ç¯å²ã®æã倧ããªåžå匷床ã1280
ãïŒïŒïŒïŒ ã§è¡šãããå Žåã 1280ã1360ïŒïŒ€1450ã1500ïŒ0.15ã3.0ã§ããã ç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒåã¯ïŒé ã«èšèŒã®çµæç©ã ïŒ è©²ç²ç¶ãªããç²æ«ç¶å«çªçŽ æš¹èã¯ãKBré å€
æ³ã«ããèµ€å€ç·åžåã¹ãã¯ãã«ã«ãããŠã 960ã1020ïŒïŒ€1450ã1500ã0.15ã0.6 ã§ããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒãïŒé ã®ããããã«èš
èŒã®çµæç©ã ïŒ è©²ç²ç¶ãªããç²æ«ç¶å«çªçŽ æš¹èã¯ãKBré å€
æ³ã«ããèµ€å€ç·åžåã¹ãã¯ãã«ã«ãããŠã 1280ã1360ïŒïŒ€1450ã1500ã0.2ã2.0 ã§ããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒãïŒé ã®ããããã«èš
èŒã®çµæç©ã ïŒ è©²ç²ç¶ãªããç²æ«ç¶å«çªçŽ æš¹èã¯ãKBré å€
æ³ã«ããèµ€å€ç·åžåã¹ãã¯ãã«ã«ãããŠã 1280ã1360ïŒïŒ€1450ã1500ã0.3ã1.5 ã§ããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒãïŒé ã®ããããã«èš
èŒã®çµæç©ã ïŒ è©²ç²ç¶ãªããç²æ«ç¶å«çªçŽ æš¹èã¯å°ããšãå š
äœã®50ééïŒ ã150ã¿ã€ã©ãŒã¡ãã·ãŠã®ç¯©ãéé
ããã倧ããã§ããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒãïŒé ã®
ããããã«èšèŒã®çµæç©ã ïŒ è©²ç²ç¶ãªããç²æ«ç¶å«çªçŽ æš¹èã¯æ¶²äœã¯ãã
ãã°ã©ãã€ãŒã«ãã枬å®å€ãšããŠéé¢ããšããŒã«
å«æéã500ppm以äžã§ããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒ
ãïŒé ã®ããããã«èšèŒã®çµæç©ã ïŒ è©²ç²ç¶ãªããç²æ«ç¶å«çªçŽ æš¹èã¯ãçªçŽ ãå°
ããšãïŒééïŒ å«æãããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒã
ïŒé ã®ããããã«èšèŒã®çµæç©ã ïŒïŒ 該ç²ç¶ãªããç²æ«ç¶å«çªçŽ æš¹èã¯çªçŽ ãïŒ
ã30ééïŒ å«æãããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒãïŒé
ã®ããããã«èšèŒã®çµæç©ã ïŒïŒ 該ç²ç¶ãªããç²æ«ç¶å«çªçŽ æš¹èã¯ãæ¬æã«
èšèŒããå ç±èç枬å®æ³ã«åŸã€ãŠ100âã®æž©åºŠã«
ïŒåéä¿æããå Žåã«ãå°ããšããã®äžéšãèç
ãããã®ã§ããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒãïŒïŒé ã®ã
ãããã«èšèŒã®çµæç©ã ïŒïŒ 該ç²ç¶ãªããç²æ«ç¶å«çªçŽ æš¹è10ïœããå®
質çã«ç¡æ°Žã®ã¡ã¿ããŒã«500mläžã§ãå ç±éæµã
ãå Žåã«ãäžèšåŒ ïŒïŒ·ïŒâïŒïŒïŒ·ïŒÃ100 åŒäžãW0ã¯äœ¿çšãã該暹èã®ééïŒïœïŒã W1ã¯å ç±éæµåŸã«æ®åãã該暹èã®é
éïŒïœïŒã ã¯è©²æš¹èã®ã¡ã¿ããŒã«æº¶è§£åºŠïŒéé
ïŒ ïŒã瀺ãã ã§è¡šããããã¡ã¿ããŒã«æº¶è§£åºŠã20ééïŒ ä»¥äžã§
ãããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒãïŒïŒé ã®ããããã«
èšèŒã®çµæç©ã ïŒïŒ 該ç²ç¶ãªããç²æ«ç¶å«çªçŽ æš¹èã¯ãæ¬æã«
èšèŒããå ç±èç枬å®æ³ã«åŸã€ãŠ100âã®æž©åºŠã«
ïŒåéä¿æããå Žåã«ãå®è³ªçã«æº¶èåã¯èçã
ãªãç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒãïŒïŒé ã®ããããã«èš
èŒã®çµæç©ã ïŒïŒ äžèšç¡æ©è³ªææãã»ã©ããã¯ã®åææãšãª
ãåŸãç¡æ©ææã§ãããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé ã«
èšèŒã®çµæç©ã ïŒïŒ äžèšç¡æ©è³ªææããã°ãã·ãŠã ãããã€ãª
ã³ååŸåã®å°ããéå±ããã®ãããªéå±ã®æ··åç©
åã¯åéã§ãããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé ã«èšèŒã®
çµæç©ã ïŒïŒ äžèšç¡æ©ææãéå±é žåç©ãéå±é žåç©ã
äž»æåãšããçµæç©ãéå±æ°Žé žåç©ãéå±ç¡«å
ç©ãéå±çåç©ãéå±çªåç©ãéå±ã®ç¡æ©é žå¡©å
ã¯éå±ã®ç¡æ©é¯å¡©ãããã¯è€å¡©ã§ãããç¹èš±è«æ±
ã®ç¯å²ç¬¬ïŒé åã¯ç¬¬ïŒïŒé ã«èšèŒã®çµæç©ã ïŒïŒ äžèšçµæç©ãè£å©ææãããã«å«æããã
ç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé ã第ïŒïŒé ã®ããããã«èš
èŒã®çµæç©ã ïŒïŒ äžèšçµæç©ãæ圢ããã圢æ ã«ãããç¹èš±
è«æ±ã®ç¯å²ç¬¬ïŒé ã第ïŒïŒé ã®ããããã«èšèŒã®
çµæç©ã
Priority Applications (6)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP57080078A JPS58199771A (ja) | 1982-05-14 | 1982-05-14 | ç¡æ©è³ªææç²äœãå«ãçµæç© |
| DE8383104450T DE3372100D1 (en) | 1982-05-14 | 1983-05-05 | Composition containing a phenol-aldehyde resin and a powder of an inorganic material |
| EP83104450A EP0098360B1 (en) | 1982-05-14 | 1983-05-05 | Composition containing a phenol-aldehyde resin and a powder of an inorganic material |
| CA000427832A CA1224585A (en) | 1982-05-14 | 1983-05-10 | High content inorganic material in granular phenoplast |
| US06/494,437 US4460730A (en) | 1982-05-14 | 1983-05-13 | Composition containing a powder of an inorganic material |
| KR1019830002091A KR870001949B1 (ko) | 1982-05-14 | 1983-05-14 | ë¬Žêž°ì§ ì¬ë£ ë¶ë§ì íšì íë íë-ìë°íë ìì§ ì¡°ì±ë¬Œ |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP57080078A JPS58199771A (ja) | 1982-05-14 | 1982-05-14 | ç¡æ©è³ªææç²äœãå«ãçµæç© |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS58199771A JPS58199771A (ja) | 1983-11-21 |
| JPS6146427B2 true JPS6146427B2 (ja) | 1986-10-14 |
Family
ID=13708173
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP57080078A Granted JPS58199771A (ja) | 1982-05-14 | 1982-05-14 | ç¡æ©è³ªææç²äœãå«ãçµæç© |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS58199771A (ja) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP4511811B2 (ja) * | 2003-06-24 | 2010-07-28 | æ¥æ¬é»æ°æ ªåŒäŒç€Ÿ | ãªããŠã ã€ãªã³äºæ¬¡é»æ± ã®è² 極掻ç©è³ªçšæš¹èçµæç©ãè² æ¥µæŽ»ç©è³ªçšççŽ æããã®è£œé æ¹æ³ãããã³ãªããŠã ã€ãªã³äºæ¬¡é»æ± |
-
1982
- 1982-05-14 JP JP57080078A patent/JPS58199771A/ja active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| JPS58199771A (ja) | 1983-11-21 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| KR870001275B1 (ko) | íì ì±í첎ì ì ì¡°ë°©ë² | |
| JP2827176B2 (ja) | å å¡«å€ããã³æ·»å å€ãªãã³ã«ççŽ åœ¢ææ§çµåå€ãå«æããèç±æ§æ圢ææãã補é ãããèç«æ§è£œå | |
| KR870001949B1 (ko) | ë¬Žêž°ì§ ì¬ë£ ë¶ë§ì íšì íë íë-ìë°íë ìì§ ì¡°ì±ë¬Œ | |
| CZ300723B6 (cs) | Filtr vhodnÜ pro filtrovánà roztaveného kovu a zpusob jeho vÜroby | |
| EP2359957A1 (en) | Method and composition for the preparation of foundry moulds and cores | |
| JP3228701B2 (ja) | ã»ã¡ã³ãæ··åçšæŽ»æ§ã«ãªãªã³ç²æ«ç©è³ªåã³ãã®è£œé æ¹æ³ | |
| CN102585127A (zh) | å¹²åŒæçšæ¹æ§é éæ èãå ¶å¶å€æ¹æ³åå¹²åŒæ | |
| CN108698931A (zh) | èç«çæåäœåç©æ以åç²åååå®ä»¬çå¶é æ¹æ³ | |
| JP2003505334A (ja) | ãã§ããŒã«ã§ã³ãŒããããèç«æ§éªšæ | |
| JPS6230210B2 (ja) | ||
| Li et al. | Effect of reclaimed sand additions on mechanical properties and fracture behavior of furan no-bake resin sand | |
| JPS6230212B2 (ja) | ||
| JPS6146427B2 (ja) | ||
| JPS6238382B2 (ja) | ||
| JP2732898B2 (ja) | ç²ç²ç¶éå±ã®å¡æåæ¹æ³ | |
| US6710101B2 (en) | High surface area magnesia curing agent | |
| JPS6132247B2 (ja) | ||
| JPS6059167B2 (ja) | ççŽ æ圢äœã®è£œé æ¹æ³ | |
| RU2010818C1 (ru) | СвÑзÑÑÑее | |
| JPS6235419B2 (ja) | ||
| JPS58172209A (ja) | ççŽ å€åäœã®è£œé æ³ | |
| JP3151202B2 (ja) | èç«ç©çšææ | |
| JP2001247377A (ja) | çªåçªçŽ éç²æ«ããã®è©äŸ¡æ¹æ³ãåã³çšé | |
| JPS6235417B2 (ja) | ||
| JPS6230213B2 (ja) |