JPS6142378B2 - - Google Patents
Info
- Publication number
- JPS6142378B2 JPS6142378B2 JP53100911A JP10091178A JPS6142378B2 JP S6142378 B2 JPS6142378 B2 JP S6142378B2 JP 53100911 A JP53100911 A JP 53100911A JP 10091178 A JP10091178 A JP 10091178A JP S6142378 B2 JPS6142378 B2 JP S6142378B2
- Authority
- JP
- Japan
- Prior art keywords
- graphite
- discharge
- electrode
- potential
- pole
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical class [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 21
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims description 13
- 229910052731 fluorine Inorganic materials 0.000 claims description 13
- 239000011737 fluorine Substances 0.000 claims description 13
- 239000011149 active material Substances 0.000 claims description 12
- 238000010438 heat treatment Methods 0.000 claims description 5
- 239000011229 interlayer Substances 0.000 claims description 4
- 239000010410 layer Substances 0.000 claims description 2
- 229920000642 polymer Polymers 0.000 claims description 2
- QLOAVXSYZAJECW-UHFFFAOYSA-N methane;molecular fluorine Chemical compound C.FF QLOAVXSYZAJECW-UHFFFAOYSA-N 0.000 description 13
- 229910002804 graphite Inorganic materials 0.000 description 8
- 239000010439 graphite Substances 0.000 description 8
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 6
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 6
- 229910052744 lithium Inorganic materials 0.000 description 6
- 229910021382 natural graphite Inorganic materials 0.000 description 6
- 238000000354 decomposition reaction Methods 0.000 description 5
- 239000000203 mixture Substances 0.000 description 5
- 239000002994 raw material Substances 0.000 description 5
- 229910052799 carbon Inorganic materials 0.000 description 4
- 239000003792 electrolyte Substances 0.000 description 4
- 229910001416 lithium ion Inorganic materials 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 3
- 230000007423 decrease Effects 0.000 description 3
- 229910052759 nickel Inorganic materials 0.000 description 3
- 230000010287 polarization Effects 0.000 description 3
- RUOJZAUFBMNUDX-UHFFFAOYSA-N propylene carbonate Chemical compound CC1COC(=O)O1 RUOJZAUFBMNUDX-UHFFFAOYSA-N 0.000 description 3
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 239000006258 conductive agent Substances 0.000 description 2
- 238000009792 diffusion process Methods 0.000 description 2
- 125000001153 fluoro group Chemical group F* 0.000 description 2
- 238000005755 formation reaction Methods 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- MHCFAGZWMAWTNR-UHFFFAOYSA-M lithium perchlorate Chemical compound [Li+].[O-]Cl(=O)(=O)=O MHCFAGZWMAWTNR-UHFFFAOYSA-M 0.000 description 2
- 229910001486 lithium perchlorate Inorganic materials 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000002808 molecular sieve Substances 0.000 description 2
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 229920006361 Polyflon Polymers 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 1
- 150000001342 alkaline earth metals Chemical class 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 239000002519 antifouling agent Substances 0.000 description 1
- 239000012300 argon atmosphere Substances 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 150000001721 carbon Chemical group 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- YWEUIGNSBFLMFL-UHFFFAOYSA-N diphosphonate Chemical compound O=P(=O)OP(=O)=O YWEUIGNSBFLMFL-UHFFFAOYSA-N 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000003411 electrode reaction Methods 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- WABPQHHGFIMREM-UHFFFAOYSA-N lead(0) Chemical compound [Pb] WABPQHHGFIMREM-UHFFFAOYSA-N 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 239000011255 nonaqueous electrolyte Substances 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- 239000002006 petroleum coke Substances 0.000 description 1
- DLYUQMMRRRQYAE-UHFFFAOYSA-N phosphorus pentoxide Inorganic materials O1P(O2)(=O)OP3(=O)OP1(=O)OP2(=O)O3 DLYUQMMRRRQYAE-UHFFFAOYSA-N 0.000 description 1
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 1
- -1 polyethylene Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 239000005871 repellent Substances 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000005292 vacuum distillation Methods 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
- H01M4/583—Carbonaceous material, e.g. graphite-intercalation compounds or CFx
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B32/00—Carbon; Compounds thereof
- C01B32/10—Carbon fluorides, e.g. [CF]nor [C2F]n
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
- H01M4/583—Carbonaceous material, e.g. graphite-intercalation compounds or CFx
- H01M4/5835—Comprising fluorine or fluoride salts
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
- H01M4/583—Carbonaceous material, e.g. graphite-intercalation compounds or CFx
- H01M4/587—Carbonaceous material, e.g. graphite-intercalation compounds or CFx for inserting or intercalating light metals
Landscapes
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Electrochemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- Battery Electrode And Active Subsutance (AREA)
- Primary Cells (AREA)
- Secondary Cells (AREA)
- Carbon And Carbon Compounds (AREA)
Priority Applications (11)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP10091178A JPS5528246A (en) | 1978-08-21 | 1978-08-21 | Active material for battery |
| DE2933497A DE2933497C3 (de) | 1978-08-21 | 1979-08-18 | Galvanische Zelle |
| NL7906307A NL7906307A (nl) | 1978-08-21 | 1979-08-20 | Elektrolytische hoogspanningscel. |
| US06/067,822 US4247608A (en) | 1978-08-21 | 1979-08-20 | Electrolytic cell of high voltage |
| FR7921017A FR2434492A1 (fr) | 1978-08-21 | 1979-08-20 | Cellule electrolytique a haute tension |
| SU792805307A SU867333A3 (ru) | 1978-08-21 | 1979-08-20 | Первичный химический источник тока |
| GB7928932A GB2028570B (en) | 1978-08-21 | 1979-08-20 | Electrolytic cell |
| CH763179A CH628775B (de) | 1978-08-21 | 1979-08-21 | Elektrolytische zelle. |
| CA000334221A CA1121449A (en) | 1978-08-21 | 1979-08-21 | High voltage electrolytic cell with positive electrode mainly polydicarbon monofluoride |
| IN865/CAL/79A IN152156B (US07714131-20100511-C00038.png) | 1978-08-21 | 1979-08-21 | |
| IT25224/79A IT1162573B (it) | 1978-08-21 | 1979-08-21 | Cella elettrolitica di elevata tensione |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP10091178A JPS5528246A (en) | 1978-08-21 | 1978-08-21 | Active material for battery |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS5528246A JPS5528246A (en) | 1980-02-28 |
| JPS6142378B2 true JPS6142378B2 (US07714131-20100511-C00038.png) | 1986-09-20 |
Family
ID=14286514
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP10091178A Granted JPS5528246A (en) | 1978-08-21 | 1978-08-21 | Active material for battery |
Country Status (11)
Families Citing this family (44)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS56125498A (en) * | 1980-03-06 | 1981-10-01 | Gosei Kagaku Kenkyusho:Kk | Lubricant for hot forging |
| US4327166A (en) * | 1980-09-29 | 1982-04-27 | Union Carbide Corporation | Nonaqueous cell having a MNO2 /poly-carbon fluoride cathode |
| JPS5784570A (en) * | 1980-11-14 | 1982-05-26 | Matsushita Electric Ind Co Ltd | Battery |
| JPS5816468A (ja) * | 1981-07-22 | 1983-01-31 | Central Glass Co Ltd | 電池活物質 |
| JPS5845104A (ja) * | 1981-09-10 | 1983-03-16 | Oyo Kagaku Kenkyusho | （Ｃ↓２Ｆ）ｎを主成分とするフツ化黒船の製造方法 |
| JPS5887766A (ja) * | 1981-11-17 | 1983-05-25 | Matsushita Electric Ind Co Ltd | 有機電解質電池の製造法 |
| US4578327A (en) * | 1983-04-05 | 1986-03-25 | Asahikasei Kabushiki Kaisha | Electric cells using fluorinated graphite as active material of positive electrode |
| DE3466837D1 (en) * | 1983-05-19 | 1987-11-19 | Lorraine Carbone | Graphite intercalation compounds with improved performance, and electrochemical application of these compounds |
| FR2546153B1 (fr) * | 1983-05-19 | 1990-05-04 | Lorraine Carbone | Composes d'insertion du graphite a performances ameliorees et applications electrochimiques de ces composes |
| DE3479696D1 (en) * | 1983-06-09 | 1989-10-12 | Daikin Ind Ltd | Active materials for batteries |
| US4524119A (en) * | 1983-07-25 | 1985-06-18 | Allied Corporation | Electrophotographic carriers incorporating fluorinated carbon and process of using same |
| JPH0677458B2 (ja) * | 1984-11-12 | 1994-09-28 | 信淳 渡辺 | 電池活物質 |
| US4548881A (en) * | 1985-02-08 | 1985-10-22 | Allied Corporation | High energy density battery with cathode composition |
| US4618548A (en) * | 1985-03-18 | 1986-10-21 | Combustion Engineering, Inc. | Electrolyte additive |
| US4770797A (en) * | 1986-03-31 | 1988-09-13 | Allied-Signal Inc. | Carbon fluoride chloride lubricant |
| US4681823A (en) * | 1986-05-19 | 1987-07-21 | Allied Corporation | Lithium/fluorinated carbon battery with no voltage delay |
| US6180311B1 (en) | 1994-09-19 | 2001-01-30 | Xerox Corporation | Carrier particles with halosilanated pigments |
| US5484675A (en) * | 1994-09-19 | 1996-01-16 | Xerox Corporation | Toner compositions with halosilanated pigments |
| US5849399A (en) * | 1996-04-19 | 1998-12-15 | Xerox Corporation | Bias transfer members with fluorinated carbon filled fluoroelastomer outer layer |
| JP4423699B2 (ja) * | 1999-05-27 | 2010-03-03 | ソニー株式会社 | 半導体レーザ素子及びその作製方法 |
| US6406741B1 (en) | 2000-11-28 | 2002-06-18 | Xerox Corporation | Method of making a polyimide layer containing fluorinated carbon material |
| US6670071B2 (en) | 2002-01-15 | 2003-12-30 | Quallion Llc | Electric storage battery construction and method of manufacture |
| US6677076B2 (en) * | 2002-01-15 | 2004-01-13 | Quallion Llc | Electric storage battery construction and method of manufacture |
| AU2003251798A1 (en) * | 2003-01-15 | 2005-10-07 | Quallion Llc | Battery |
| WO2005089422A2 (en) | 2004-03-17 | 2005-09-29 | California Institute Of Technology | Methods for purifying carbon materials |
| US8080329B1 (en) | 2004-03-25 | 2011-12-20 | Quallion Llc | Uniformly wound battery |
| US8232007B2 (en) | 2005-10-05 | 2012-07-31 | California Institute Of Technology | Electrochemistry of carbon subfluorides |
| US8377586B2 (en) | 2005-10-05 | 2013-02-19 | California Institute Of Technology | Fluoride ion electrochemical cell |
| US7563542B2 (en) | 2005-10-05 | 2009-07-21 | California Institute Of Technology | Subfluorinated graphite fluorides as electrode materials |
| US7794880B2 (en) | 2005-11-16 | 2010-09-14 | California Institute Of Technology | Fluorination of multi-layered carbon nanomaterials |
| US20070218364A1 (en) * | 2005-10-05 | 2007-09-20 | Whitacre Jay F | Low temperature electrochemical cell |
| US20100221603A1 (en) * | 2006-03-03 | 2010-09-02 | Rachid Yazami | Lithium ion fluoride battery |
| US8658309B2 (en) * | 2006-08-11 | 2014-02-25 | California Institute Of Technology | Dissociating agents, formulations and methods providing enhanced solubility of fluorides |
| CN101632189A (zh) * | 2007-03-14 | 2010-01-20 | 加州理工学院 | 高放电率的电池 |
| EP2167228B1 (en) | 2007-05-09 | 2015-07-08 | California Institute of Technology | Lithium fluoropolymer and fluoro-organic batteries |
| US9029019B2 (en) * | 2007-08-17 | 2015-05-12 | Nanotek Instruments, Inc. | Carbon anode compositions for lithium ion batteries |
| US7993780B2 (en) | 2007-10-05 | 2011-08-09 | Nanotek Instruments, Inc. | Process for producing carbon anode compositions for lithium ion batteries |
| EP2304827A1 (en) * | 2008-06-20 | 2011-04-06 | Max-Planck-Gesellschaft zur Förderung der Wissenschaften e.V. | Use of a superfine expanded graphite and preparation thereof |
| US20100141211A1 (en) * | 2008-11-04 | 2010-06-10 | Rachid Yazami | Hybrid electrochemical generator with a soluble anode |
| CN103619954B (zh) | 2011-06-21 | 2016-09-14 | 陶氏环球技术有限责任公司 | 具有改善的绝热性质的异氰酸酯基聚合物泡沫 |
| JP5922771B2 (ja) | 2011-07-26 | 2016-05-24 | ダウ グローバル テクノロジーズ エルエルシー | 断熱特性を改良したイソシアネート系ポリマーフォーム複合材 |
| CN103022493A (zh) * | 2012-12-14 | 2013-04-03 | 天津大学 | 氟化石墨/聚噻吩复合材料及其制备方法 |
| GB2532035B (en) | 2014-11-06 | 2018-01-10 | Schlumberger Holdings | Lithium carbon fluoride primary battery |
| CN104538580B (zh) * | 2014-12-18 | 2017-01-11 | 复旦大学 | 一种基于氟碳化物电极的一次热电池及其制备方法 |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS4825565A (US07714131-20100511-C00038.png) * | 1971-08-03 | 1973-04-03 |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| IT500097A (US07714131-20100511-C00038.png) * | 1968-04-12 | |||
| JPS4825566B1 (US07714131-20100511-C00038.png) * | 1968-04-17 | 1973-07-30 | ||
| US3956018A (en) * | 1974-12-30 | 1976-05-11 | Union Carbide Corporation | Primary electric current-producing dry cell using a (CFx)n cathode and an aqueous alkaline electrolyte |
| US4166888A (en) * | 1978-10-30 | 1979-09-04 | Exxon Research & Engineering Co. | Cell having an alkali metal anode, a fluorinated carbon cathode and an electrolyte which includes an alkali metal halide salt and a solvent system containing a substituted amide solvent and a cyclic carbonate cosolvent |
-
1978
- 1978-08-21 JP JP10091178A patent/JPS5528246A/ja active Granted
-
1979
- 1979-08-18 DE DE2933497A patent/DE2933497C3/de not_active Expired
- 1979-08-20 NL NL7906307A patent/NL7906307A/nl not_active Application Discontinuation
- 1979-08-20 FR FR7921017A patent/FR2434492A1/fr active Granted
- 1979-08-20 GB GB7928932A patent/GB2028570B/en not_active Expired
- 1979-08-20 US US06/067,822 patent/US4247608A/en not_active Expired - Lifetime
- 1979-08-20 SU SU792805307A patent/SU867333A3/ru active
- 1979-08-21 CH CH763179A patent/CH628775B/de unknown
- 1979-08-21 IT IT25224/79A patent/IT1162573B/it active
- 1979-08-21 IN IN865/CAL/79A patent/IN152156B/en unknown
- 1979-08-21 CA CA000334221A patent/CA1121449A/en not_active Expired
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS4825565A (US07714131-20100511-C00038.png) * | 1971-08-03 | 1973-04-03 |
Also Published As
| Publication number | Publication date |
|---|---|
| CH628775GA3 (US07714131-20100511-C00038.png) | 1982-03-31 |
| IN152156B (US07714131-20100511-C00038.png) | 1983-11-05 |
| GB2028570A (en) | 1980-03-05 |
| FR2434492A1 (fr) | 1980-03-21 |
| SU867333A3 (ru) | 1981-09-23 |
| JPS5528246A (en) | 1980-02-28 |
| IT7925224A0 (it) | 1979-08-21 |
| DE2933497B2 (de) | 1981-02-19 |
| DE2933497A1 (de) | 1980-03-13 |
| US4247608A (en) | 1981-01-27 |
| CA1121449A (en) | 1982-04-06 |
| DE2933497C3 (de) | 1982-02-04 |
| CH628775B (de) | |
| FR2434492B1 (US07714131-20100511-C00038.png) | 1984-03-30 |
| NL7906307A (nl) | 1980-02-25 |
| GB2028570B (en) | 1982-09-29 |
| IT1162573B (it) | 1987-04-01 |
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