JPS6137276B2 - - Google Patents
Info
- Publication number
- JPS6137276B2 JPS6137276B2 JP9668477A JP9668477A JPS6137276B2 JP S6137276 B2 JPS6137276 B2 JP S6137276B2 JP 9668477 A JP9668477 A JP 9668477A JP 9668477 A JP9668477 A JP 9668477A JP S6137276 B2 JPS6137276 B2 JP S6137276B2
- Authority
- JP
- Japan
- Prior art keywords
- group
- general formula
- atom
- azide
- sio
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 125000004122 cyclic group Chemical group 0.000 claims description 52
- IVRMZWNICZWHMI-UHFFFAOYSA-N azide group Chemical group [N-]=[N+]=[N-] IVRMZWNICZWHMI-UHFFFAOYSA-N 0.000 claims description 43
- -1 aromatic carboxylic acid alkenyl ester Chemical class 0.000 claims description 38
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical group [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 19
- 229910052710 silicon Inorganic materials 0.000 claims description 17
- 125000004432 carbon atom Chemical group C* 0.000 claims description 15
- 238000004519 manufacturing process Methods 0.000 claims description 15
- 125000000217 alkyl group Chemical group 0.000 claims description 11
- 229910052799 carbon Inorganic materials 0.000 claims description 11
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 11
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 11
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 claims description 10
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 10
- 125000001931 aliphatic group Chemical group 0.000 claims description 7
- 125000003545 alkoxy group Chemical group 0.000 claims description 7
- 125000005843 halogen group Chemical group 0.000 claims description 7
- 125000000962 organic group Chemical group 0.000 claims description 7
- 229930195734 saturated hydrocarbon Natural products 0.000 claims description 7
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 claims description 6
- 125000003342 alkenyl group Chemical group 0.000 claims description 4
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 3
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 3
- 125000001183 hydrocarbyl group Chemical group 0.000 claims 8
- 238000006243 chemical reaction Methods 0.000 description 26
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 24
- 238000000034 method Methods 0.000 description 23
- 238000007639 printing Methods 0.000 description 19
- 239000000203 mixture Substances 0.000 description 16
- 239000010410 layer Substances 0.000 description 15
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 12
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 12
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 12
- 239000000126 substance Substances 0.000 description 12
- 239000002904 solvent Substances 0.000 description 11
- 239000000047 product Substances 0.000 description 10
- 230000008901 benefit Effects 0.000 description 8
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 8
- 230000009102 absorption Effects 0.000 description 7
- 238000010521 absorption reaction Methods 0.000 description 7
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 7
- 230000015572 biosynthetic process Effects 0.000 description 7
- 150000002430 hydrocarbons Chemical group 0.000 description 7
- 238000003786 synthesis reaction Methods 0.000 description 7
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 6
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 6
- 239000000463 material Substances 0.000 description 6
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 6
- 229910052753 mercury Inorganic materials 0.000 description 6
- 239000003208 petroleum Substances 0.000 description 6
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 6
- 239000002994 raw material Substances 0.000 description 6
- 239000000243 solution Substances 0.000 description 6
- 239000008096 xylene Substances 0.000 description 6
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 5
- 241000779819 Syncarpia glomulifera Species 0.000 description 5
- 238000000862 absorption spectrum Methods 0.000 description 5
- 150000001721 carbon Chemical group 0.000 description 5
- 239000007795 chemical reaction product Substances 0.000 description 5
- 238000000354 decomposition reaction Methods 0.000 description 5
- 230000007062 hydrolysis Effects 0.000 description 5
- 238000006460 hydrolysis reaction Methods 0.000 description 5
- 239000001739 pinus spp. Substances 0.000 description 5
- 229940036248 turpentine Drugs 0.000 description 5
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 5
- XXKYTTAVNYTVFC-UHFFFAOYSA-N 4-azidobenzoyl chloride Chemical compound ClC(=O)C1=CC=C(N=[N+]=[N-])C=C1 XXKYTTAVNYTVFC-UHFFFAOYSA-N 0.000 description 4
- 206010034972 Photosensitivity reaction Diseases 0.000 description 4
- 239000002253 acid Substances 0.000 description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 4
- 239000003054 catalyst Substances 0.000 description 4
- 238000002329 infrared spectrum Methods 0.000 description 4
- 239000001301 oxygen Substances 0.000 description 4
- 229910052760 oxygen Inorganic materials 0.000 description 4
- 230000036211 photosensitivity Effects 0.000 description 4
- 229910052697 platinum Inorganic materials 0.000 description 4
- 239000000758 substrate Substances 0.000 description 4
- 238000005406 washing Methods 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 3
- 229910052782 aluminium Inorganic materials 0.000 description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 3
- 229920005601 base polymer Polymers 0.000 description 3
- DDJSWKLBKSLAAZ-UHFFFAOYSA-N cyclotetrasiloxane Chemical compound O1[SiH2]O[SiH2]O[SiH2]O[SiH2]1 DDJSWKLBKSLAAZ-UHFFFAOYSA-N 0.000 description 3
- 229910001873 dinitrogen Inorganic materials 0.000 description 3
- 238000000921 elemental analysis Methods 0.000 description 3
- 230000008014 freezing Effects 0.000 description 3
- 238000007710 freezing Methods 0.000 description 3
- 239000003504 photosensitizing agent Substances 0.000 description 3
- 229920001296 polysiloxane Polymers 0.000 description 3
- 230000035945 sensitivity Effects 0.000 description 3
- FZOJLVMQAKLXSQ-UHFFFAOYSA-N 3-azidobenzoyl chloride Chemical compound ClC(=O)C1=CC=CC(N=[N+]=[N-])=C1 FZOJLVMQAKLXSQ-UHFFFAOYSA-N 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- ACIAHEMYLLBZOI-ZZXKWVIFSA-N Unsaturated alcohol Chemical compound CC\C(CO)=C/C ACIAHEMYLLBZOI-ZZXKWVIFSA-N 0.000 description 2
- ZOIORXHNWRGPMV-UHFFFAOYSA-N acetic acid;zinc Chemical compound [Zn].CC(O)=O.CC(O)=O ZOIORXHNWRGPMV-UHFFFAOYSA-N 0.000 description 2
- 150000001540 azides Chemical class 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 238000004132 cross linking Methods 0.000 description 2
- 238000005886 esterification reaction Methods 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 description 2
- 229910000041 hydrogen chloride Inorganic materials 0.000 description 2
- 230000003301 hydrolyzing effect Effects 0.000 description 2
- 238000006459 hydrosilylation reaction Methods 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- 125000004368 propenyl group Chemical group C(=CC)* 0.000 description 2
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 238000010992 reflux Methods 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 239000012261 resinous substance Substances 0.000 description 2
- 238000005809 transesterification reaction Methods 0.000 description 2
- 239000004246 zinc acetate Substances 0.000 description 2
- SNYNNFDVNITLRQ-UHFFFAOYSA-N 2,2,4,4,6,6,8-heptamethyl-1,3,5,7,2,4,6,8$l^{3}-tetraoxatetrasilocane Chemical compound C[Si]1O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O1 SNYNNFDVNITLRQ-UHFFFAOYSA-N 0.000 description 1
- ANZPUCVQARFCDW-UHFFFAOYSA-N 2,2,4,4,6,6-hexamethyl-1,3,5,7,2,4,6,8-tetraoxatetrasilocane Chemical compound C[Si]1(C)O[SiH2]O[Si](C)(C)O[Si](C)(C)O1 ANZPUCVQARFCDW-UHFFFAOYSA-N 0.000 description 1
- ZAKUVHZFBNPFNP-UHFFFAOYSA-N 2,2,4,4,6-pentamethyl-1,3,5,7,2,4,6,8-tetraoxatetrasilocane Chemical compound C[SiH]1O[SiH2]O[Si](C)(C)O[Si](C)(C)O1 ZAKUVHZFBNPFNP-UHFFFAOYSA-N 0.000 description 1
- WZJUBBHODHNQPW-UHFFFAOYSA-N 2,4,6,8-tetramethyl-1,3,5,7,2$l^{3},4$l^{3},6$l^{3},8$l^{3}-tetraoxatetrasilocane Chemical compound C[Si]1O[Si](C)O[Si](C)O[Si](C)O1 WZJUBBHODHNQPW-UHFFFAOYSA-N 0.000 description 1
- VLQZJOLYNOGECD-UHFFFAOYSA-N 2,4,6-trimethyl-1,3,5,2,4,6-trioxatrisilinane Chemical compound C[SiH]1O[SiH](C)O[SiH](C)O1 VLQZJOLYNOGECD-UHFFFAOYSA-N 0.000 description 1
- NGNBDVOYPDDBFK-UHFFFAOYSA-N 2-[2,4-di(pentan-2-yl)phenoxy]acetyl chloride Chemical group CCCC(C)C1=CC=C(OCC(Cl)=O)C(C(C)CCC)=C1 NGNBDVOYPDDBFK-UHFFFAOYSA-N 0.000 description 1
- NKKFLGZTMQFTCA-UHFFFAOYSA-N 2-azidobenzoyl chloride Chemical compound ClC(=O)C1=CC=CC=C1N=[N+]=[N-] NKKFLGZTMQFTCA-UHFFFAOYSA-N 0.000 description 1
- GPZXFICWCMCQPF-UHFFFAOYSA-N 2-methylbenzoyl chloride Chemical compound CC1=CC=CC=C1C(Cl)=O GPZXFICWCMCQPF-UHFFFAOYSA-N 0.000 description 1
- XLPOEXQVZPLZKZ-UHFFFAOYSA-N 3-[2-(3-hydroxypropyl)-4,4,6,6,8,8-hexamethyl-1,3,5,7,2,4,6,8-tetraoxatetrasilocan-2-yl]propan-1-ol Chemical compound C[Si]1(C)O[Si](C)(C)O[Si](CCCO)(CCCO)O[Si](C)(C)O1 XLPOEXQVZPLZKZ-UHFFFAOYSA-N 0.000 description 1
- APQZIVNHLRXBAY-UHFFFAOYSA-N 3-[4,6,8,10-tetrakis(3-hydroxypropyl)-2,4,6,8,10-pentamethyl-1,3,5,7,9,2,4,6,8,10-pentaoxapentasilecan-2-yl]propan-1-ol Chemical compound OCCC[Si]1(C)O[Si](C)(CCCO)O[Si](C)(CCCO)O[Si](C)(CCCO)O[Si](C)(CCCO)O1 APQZIVNHLRXBAY-UHFFFAOYSA-N 0.000 description 1
- ZLBRZCPFVDEGOK-UHFFFAOYSA-N 3-[4,6,8-tris(3-hydroxypropyl)-2,4,6,8-tetramethyl-1,3,5,7,2,4,6,8-tetraoxatetrasilocan-2-yl]propan-1-ol Chemical compound OCCC[Si]1(C)O[Si](C)(CCCO)O[Si](C)(CCCO)O[Si](C)(CCCO)O1 ZLBRZCPFVDEGOK-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- VCUFZILGIRCDQQ-KRWDZBQOSA-N N-[[(5S)-2-oxo-3-(2-oxo-3H-1,3-benzoxazol-6-yl)-1,3-oxazolidin-5-yl]methyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical group O=C1O[C@H](CN1C1=CC2=C(NC(O2)=O)C=C1)CNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F VCUFZILGIRCDQQ-KRWDZBQOSA-N 0.000 description 1
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 1
- DSVGQVZAZSZEEX-UHFFFAOYSA-N [C].[Pt] Chemical compound [C].[Pt] DSVGQVZAZSZEEX-UHFFFAOYSA-N 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 125000000852 azido group Chemical group *N=[N+]=[N-] 0.000 description 1
- 125000004369 butenyl group Chemical group C(=CCC)* 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 125000001309 chloro group Chemical group Cl* 0.000 description 1
- WBYWAXJHAXSJNI-UHFFFAOYSA-N cinnamic acid group Chemical group C(C=CC1=CC=CC=C1)(=O)O WBYWAXJHAXSJNI-UHFFFAOYSA-N 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- 229920006037 cross link polymer Polymers 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000006356 dehydrogenation reaction Methods 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 230000032050 esterification Effects 0.000 description 1
- 125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 description 1
- 125000004494 ethyl ester group Chemical group 0.000 description 1
- 125000000816 ethylene group Chemical group [H]C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 238000005194 fractionation Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 125000004836 hexamethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[*:1] 0.000 description 1
- 125000006038 hexenyl group Chemical group 0.000 description 1
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 238000006713 insertion reaction Methods 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 230000031700 light absorption Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 230000005923 long-lasting effect Effects 0.000 description 1
- 239000002075 main ingredient Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 125000005395 methacrylic acid group Chemical group 0.000 description 1
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 description 1
- RULRGDSQDQHZOK-UHFFFAOYSA-N methyl 4-azidobenzoate Chemical compound COC(=O)C1=CC=C(N=[N+]=[N-])C=C1 RULRGDSQDQHZOK-UHFFFAOYSA-N 0.000 description 1
- 150000004702 methyl esters Chemical class 0.000 description 1
- 125000001570 methylene group Chemical group [H]C([H])([*:1])[*:2] 0.000 description 1
- 239000011259 mixed solution Substances 0.000 description 1
- 239000012046 mixed solvent Substances 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 238000007645 offset printing Methods 0.000 description 1
- 150000007530 organic bases Chemical class 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 230000002165 photosensitisation Effects 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 239000011241 protective layer Substances 0.000 description 1
- AOJFQRQNPXYVLM-UHFFFAOYSA-N pyridin-1-ium;chloride Chemical compound [Cl-].C1=CC=[NH+]C=C1 AOJFQRQNPXYVLM-UHFFFAOYSA-N 0.000 description 1
- 150000003222 pyridines Chemical class 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 239000005871 repellent Substances 0.000 description 1
- 239000012260 resinous material Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
- 238000004448 titration Methods 0.000 description 1
- ZQTYRTSKQFQYPQ-UHFFFAOYSA-N trisiloxane Chemical compound [SiH3]O[SiH2]O[SiH3] ZQTYRTSKQFQYPQ-UHFFFAOYSA-N 0.000 description 1
- 229920001567 vinyl ester resin Polymers 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- CHJMFFKHPHCQIJ-UHFFFAOYSA-L zinc;octanoate Chemical compound [Zn+2].CCCCCCCC([O-])=O.CCCCCCCC([O-])=O CHJMFFKHPHCQIJ-UHFFFAOYSA-L 0.000 description 1
Landscapes
- Silicon Polymers (AREA)
Description
æ¬çºæã¯ã湿ãæ°Žãå¿
èŠãšããªãå¹³çå°å·çšãš
ããŠæçšãªãæ°èŠãªã¢ãžãåºå«æç°ç¶ããªãªã«ã¬
ãã·ãããµã³ãæäŸãããã®ã§ããããŸãæ¬çºæ
ã¯ããããããªãªã«ã¬ãã·ãããµã³ã®è£œé æ³ãæ
äŸãããã®ã§ããã 湿ãæ°Žãå¿ èŠãšããªãå¹³çå°å·çã¯ãåŸæ¥ã®ãª
ãã»ããå°å·ã®ç°¡çŽ åãç®æããã®ã§ãããåŸæ¥
ã®å¹³çå°å·ã¯ãå€èŠäžåäžå¹³é¢äžã«ç»ç·ãšéç»ç·
ãšãæããçã䜿çšãããã®ã§ãæ°Žãšèèªãšãäº
ã«åæ¥ããæ§è³ªãå©çšããŠãããããªãã¡ãååŠ
çãŸãã¯æ©æ¢°çåŠçã«ãã€ãŠèŠªæ°Žåãããåºæ¿äž
ã«ã芪油æ§ã®æå å±€ãèšããåé²å ããåŸãé©åœ
ãªåŠç液ã«ãŠåºæ¿äžã«èŠªæ°Žæ§éšåãšèŠªæ²¹æ§éšåãš
ã圢æãããŠå°å·çãšãããå°å·ã«ããã€ãŠãç
é¢ã«æ°Žã転移ãããšãæ°Žã¯èŠªæ°Žæ§éšåã«ä»çããŠ
芪油æ§éšåã«ã¯ä»çããªãã次ã«ã€ã³ãã転移ã
ããšãã€ã³ãã¯æ°Žãååšããéšåã«ã¯ä»çããã
芪油æ§éšåã®ã¿ã«ä»çãããã®ã€ã³ããçŽãªã©ã®
被å°å·äœã«è»¢ç§»ãããããšã«ãããå°å·ãè¡ãã
ãšãã§ããã ãã®æ¹åŒã®æ¬ é¥ã¯ã湿ãæ°Žæäœãéåžžã«å°é£ã§
ããããŸã湿ãæ°Žã®ããã«ã€ã³ãã®ä¹³åã被å°å·
äœã®å¯žæ³å€åãªã©ãæ§ã ãªåé¡ç¹ãæããŠããã ãããã®åé¡ç¹ãæ¹è¯ãã¹ãã湿ãæ°Žãçšããª
ãå¹³çå°å·æ³ã®ç 究ãå€ããªãããŠããããçŸåš
ãŸã ååã«æºè¶³ããããã®ã¯ãªããããšãã°ãåº
æã«æå æ§ç©è³ªã®å±€ãšæ¥æ²¹æ§æš¹èã®å±€ãšãããªã
å€éå±€ã圢æããããå¹³çãçšããæ¹æ³ã¯ãå€é
å±€ã®åœ¢æãç ©éã§ããããã€è§£ååãå£ã€ããã
çã®èå·æ§ãå£ããšããæ¬ ç¹ããããããªãªã«ã¬
ãã·ãããµã³è¡šé¢ãçšããããšã¯ããã®ãããã
æ¥æ²¹æ§ããçç®ãããŠããããããªãªã«ã¬ãã·ã
ããµã³ãçšããå€é局圢åŒã¯ãåè¿°ã®æ¬ ç¹ããã€
ããã«å®çšæ§ã«ä¹ãããããã§ãããªãªã«ã¬ãã·
ãããµã³ã«ã¢ãŸååç©ãã¢ãžãååç©ã®ãããªæ
å æ§ç©è³ªãé åããŠããã®é²å ã«ããã©ãžã«ã«ã
çºçããããããªãªã«ã¬ãã·ãããµã³ãæ¶æ©ãã
ãŠäžæº¶æ§ããªããŒã圢æããæ¹æ³ãèæ¡ãããŠã
ãããæå æ§ç©è³ªãåäžã«é åããããšãããã
ããããã€ãæå æ§ç©è³ªãæ¶åºãããããŠãç®è
ã®åŒ·åºŠã解åãäœäžãããšããåé¡ç¹ãããã ãã®ãããªåé¡ç¹ã解決ããããã«ãã¢ã¯ãªã«
é žæ®åºãã¡ã¿ã¯ãªã«é žæ®åºãæ¡ç®é žæ®åºã®ãããª
äžé£œååºãå«æããããªãªã«ã¬ãã·ãããµã³ã®æ
å æ§ãå©çšããŠãåäžã®æå å±€ãäœãæ¹æ³ãææ¡
ãããŠãããããããäžè¬çã«ããã®ãããªã¢ã¯
ãªã«ç³»äžé£œååºã«ããæå å±€ã¯ãããããæå å¹
æããã€åé¢ãé žçŽ ã®åœ±é¿ãåãããããæå æ§
ã®çµæå€åããã³ææžè¡šã倧ãããšããæ¬ ç¹ãã
ãããŸãã空æ°äžã®é žçŽ ã®åœ±é¿ãé¿ããããã«ã
æå å±€ã®äžã«éæãªä¿è·å±€ãæœãããé žçŽ ã®ååš
ããªãç¶æ ã§é²å ãããå¿ èŠãããããåè ã®æ¹
æ³ã¯å¹³çã®è£œé ãç ©éã«ãªãããåŸè ã®æ¹æ³ã¯é²
å ã«ç¹å¥ãªè£ 眮ãå¿ èŠãšããé²å æäœãé¢åã§ã
ãã æ¬çºæè ãã¯ãåè¿°ã®ãããªåé¡ãèµ·ããåå
ãšãªã€ãŠãã湿ãæ°Žãå¿ èŠãšããªãå¹³çå°å·æ¹åŒ
ãªãã³ã«ææãæäŸãã¹ããéæç 究ãè¡ã€ãçµ
æãããã«ãéç»ç·éšã«çŽéç¶ã®ã¢ãžãåããªãª
ã«ã¬ãã·ãããµã³ãäž»æåãšããæå æ§çµæç©ã
çšããŠæå å±€ã圢æããããšã«ããã湿ãæ°Žãçš
ããªãå¹³çå°å·ãå¯èœãªããããããšãèŠåºãã
ïŒç¹é¡æ51â56355å·ïŒããã®çºæã«ãããæå å€
ãåºããªããŒã«æ··åããæ¹æ³ã«æ¯ã¹ãŠãæå å€ã
åºããªããŒããåé¢ãæ¶åºããããšããªããä¿å
æ§ãæ床ãçŸåæ§ã«ãããããã€ãã¢ã¯ãªã«ç³»äž
飜ååºã®æå æ§ã«åºãæ¹æ³ã«ããåè¿°ã®æ¬ ç¹ãæ
é€ããããããã湿ãæ°ŽäžèŠå¹³çãåŸãããšãã§
ããããããããã®æ¹æ³ã«ãããŠãæ床ãè¯ãã
ãããã«ãæå å±€ãåããããšå ã®å éšæ£ä¹±ãåº
æ¿ããã®åå°ã®åœ±é¿ãåããŠã解ååãäœäžãã
ãšããåé¡ãæ®ãã解ååãå¢ãããã«æå å±€ã
èããããšãäžæºè¶³ãªèå·åããåŸãããªãã®
ã§ããã®çšéã«å¶çŽããã€ãã æ¬çºæè ãã¯ããã®ç¹ãæ¹è¯ãã¹ãããã«ç 究
ãé²ããæå æ§çµæç©ã®äž»å€ãšããŠãããã«ææ¡
ãè¡ã€ãã¢ãžãåããªãªã«ã¬ãã·ãããµã³ïŒç¹é¡
æ51â56354å·ïŒã®ãã¡ãç¹ã«å®æœäŸçã«èšèŒã
ããŠããªãæ°èŠãªç©è³ªã§ããã¢ãžãåºå«æç°ç¶ã
ãªãªã«ã¬ãã·ãããµã³ããã³ãã®è£œé æ³ãèŠåº
ãããã®ç©è³ªãçšããããšã«ãããæå å±€ãåã
ããŠããããã解ååãæããæå æ§çµæç©ãåŸ
ãããšãã§ããã ããªãã¡æ¬çºæã¯ãäžè¬åŒ ãR1 aR2 2-aSiOão ïŒãã ãR1ã¯äžè¬åŒ
ããŠæçšãªãæ°èŠãªã¢ãžãåºå«æç°ç¶ããªãªã«ã¬
ãã·ãããµã³ãæäŸãããã®ã§ããããŸãæ¬çºæ
ã¯ããããããªãªã«ã¬ãã·ãããµã³ã®è£œé æ³ãæ
äŸãããã®ã§ããã 湿ãæ°Žãå¿ èŠãšããªãå¹³çå°å·çã¯ãåŸæ¥ã®ãª
ãã»ããå°å·ã®ç°¡çŽ åãç®æããã®ã§ãããåŸæ¥
ã®å¹³çå°å·ã¯ãå€èŠäžåäžå¹³é¢äžã«ç»ç·ãšéç»ç·
ãšãæããçã䜿çšãããã®ã§ãæ°Žãšèèªãšãäº
ã«åæ¥ããæ§è³ªãå©çšããŠãããããªãã¡ãååŠ
çãŸãã¯æ©æ¢°çåŠçã«ãã€ãŠèŠªæ°Žåãããåºæ¿äž
ã«ã芪油æ§ã®æå å±€ãèšããåé²å ããåŸãé©åœ
ãªåŠç液ã«ãŠåºæ¿äžã«èŠªæ°Žæ§éšåãšèŠªæ²¹æ§éšåãš
ã圢æãããŠå°å·çãšãããå°å·ã«ããã€ãŠãç
é¢ã«æ°Žã転移ãããšãæ°Žã¯èŠªæ°Žæ§éšåã«ä»çããŠ
芪油æ§éšåã«ã¯ä»çããªãã次ã«ã€ã³ãã転移ã
ããšãã€ã³ãã¯æ°Žãååšããéšåã«ã¯ä»çããã
芪油æ§éšåã®ã¿ã«ä»çãããã®ã€ã³ããçŽãªã©ã®
被å°å·äœã«è»¢ç§»ãããããšã«ãããå°å·ãè¡ãã
ãšãã§ããã ãã®æ¹åŒã®æ¬ é¥ã¯ã湿ãæ°Žæäœãéåžžã«å°é£ã§
ããããŸã湿ãæ°Žã®ããã«ã€ã³ãã®ä¹³åã被å°å·
äœã®å¯žæ³å€åãªã©ãæ§ã ãªåé¡ç¹ãæããŠããã ãããã®åé¡ç¹ãæ¹è¯ãã¹ãã湿ãæ°Žãçšããª
ãå¹³çå°å·æ³ã®ç 究ãå€ããªãããŠããããçŸåš
ãŸã ååã«æºè¶³ããããã®ã¯ãªããããšãã°ãåº
æã«æå æ§ç©è³ªã®å±€ãšæ¥æ²¹æ§æš¹èã®å±€ãšãããªã
å€éå±€ã圢æããããå¹³çãçšããæ¹æ³ã¯ãå€é
å±€ã®åœ¢æãç ©éã§ããããã€è§£ååãå£ã€ããã
çã®èå·æ§ãå£ããšããæ¬ ç¹ããããããªãªã«ã¬
ãã·ãããµã³è¡šé¢ãçšããããšã¯ããã®ãããã
æ¥æ²¹æ§ããçç®ãããŠããããããªãªã«ã¬ãã·ã
ããµã³ãçšããå€é局圢åŒã¯ãåè¿°ã®æ¬ ç¹ããã€
ããã«å®çšæ§ã«ä¹ãããããã§ãããªãªã«ã¬ãã·
ãããµã³ã«ã¢ãŸååç©ãã¢ãžãååç©ã®ãããªæ
å æ§ç©è³ªãé åããŠããã®é²å ã«ããã©ãžã«ã«ã
çºçããããããªãªã«ã¬ãã·ãããµã³ãæ¶æ©ãã
ãŠäžæº¶æ§ããªããŒã圢æããæ¹æ³ãèæ¡ãããŠã
ãããæå æ§ç©è³ªãåäžã«é åããããšãããã
ããããã€ãæå æ§ç©è³ªãæ¶åºãããããŠãç®è
ã®åŒ·åºŠã解åãäœäžãããšããåé¡ç¹ãããã ãã®ãããªåé¡ç¹ã解決ããããã«ãã¢ã¯ãªã«
é žæ®åºãã¡ã¿ã¯ãªã«é žæ®åºãæ¡ç®é žæ®åºã®ãããª
äžé£œååºãå«æããããªãªã«ã¬ãã·ãããµã³ã®æ
å æ§ãå©çšããŠãåäžã®æå å±€ãäœãæ¹æ³ãææ¡
ãããŠãããããããäžè¬çã«ããã®ãããªã¢ã¯
ãªã«ç³»äžé£œååºã«ããæå å±€ã¯ãããããæå å¹
æããã€åé¢ãé žçŽ ã®åœ±é¿ãåãããããæå æ§
ã®çµæå€åããã³ææžè¡šã倧ãããšããæ¬ ç¹ãã
ãããŸãã空æ°äžã®é žçŽ ã®åœ±é¿ãé¿ããããã«ã
æå å±€ã®äžã«éæãªä¿è·å±€ãæœãããé žçŽ ã®ååš
ããªãç¶æ ã§é²å ãããå¿ èŠãããããåè ã®æ¹
æ³ã¯å¹³çã®è£œé ãç ©éã«ãªãããåŸè ã®æ¹æ³ã¯é²
å ã«ç¹å¥ãªè£ 眮ãå¿ èŠãšããé²å æäœãé¢åã§ã
ãã æ¬çºæè ãã¯ãåè¿°ã®ãããªåé¡ãèµ·ããåå
ãšãªã€ãŠãã湿ãæ°Žãå¿ èŠãšããªãå¹³çå°å·æ¹åŒ
ãªãã³ã«ææãæäŸãã¹ããéæç 究ãè¡ã€ãçµ
æãããã«ãéç»ç·éšã«çŽéç¶ã®ã¢ãžãåããªãª
ã«ã¬ãã·ãããµã³ãäž»æåãšããæå æ§çµæç©ã
çšããŠæå å±€ã圢æããããšã«ããã湿ãæ°Žãçš
ããªãå¹³çå°å·ãå¯èœãªããããããšãèŠåºãã
ïŒç¹é¡æ51â56355å·ïŒããã®çºæã«ãããæå å€
ãåºããªããŒã«æ··åããæ¹æ³ã«æ¯ã¹ãŠãæå å€ã
åºããªããŒããåé¢ãæ¶åºããããšããªããä¿å
æ§ãæ床ãçŸåæ§ã«ãããããã€ãã¢ã¯ãªã«ç³»äž
飜ååºã®æå æ§ã«åºãæ¹æ³ã«ããåè¿°ã®æ¬ ç¹ãæ
é€ããããããã湿ãæ°ŽäžèŠå¹³çãåŸãããšãã§
ããããããããã®æ¹æ³ã«ãããŠãæ床ãè¯ãã
ãããã«ãæå å±€ãåããããšå ã®å éšæ£ä¹±ãåº
æ¿ããã®åå°ã®åœ±é¿ãåããŠã解ååãäœäžãã
ãšããåé¡ãæ®ãã解ååãå¢ãããã«æå å±€ã
èããããšãäžæºè¶³ãªèå·åããåŸãããªãã®
ã§ããã®çšéã«å¶çŽããã€ãã æ¬çºæè ãã¯ããã®ç¹ãæ¹è¯ãã¹ãããã«ç 究
ãé²ããæå æ§çµæç©ã®äž»å€ãšããŠãããã«ææ¡
ãè¡ã€ãã¢ãžãåããªãªã«ã¬ãã·ãããµã³ïŒç¹é¡
æ51â56354å·ïŒã®ãã¡ãç¹ã«å®æœäŸçã«èšèŒã
ããŠããªãæ°èŠãªç©è³ªã§ããã¢ãžãåºå«æç°ç¶ã
ãªãªã«ã¬ãã·ãããµã³ããã³ãã®è£œé æ³ãèŠåº
ãããã®ç©è³ªãçšããããšã«ãããæå å±€ãåã
ããŠããããã解ååãæããæå æ§çµæç©ãåŸ
ãããšãã§ããã ããªãã¡æ¬çºæã¯ãäžè¬åŒ ãR1 aR2 2-aSiOão ïŒãã ãR1ã¯äžè¬åŒ
ãåŒãã§ç€º
ããããççŽ ååã«ãã€ãŠã±ã€çŽ ååã«çµåãã
ïŒäŸ¡ã®ã¢ãžãåºå«æææ©åºãã¯æ°ŽçŽ ååãã¢ã«
ãã«åºãã¢ã«ã³ãã·åºããããåºããã³ããã²ã³
ååããéžã°ããïŒäŸ¡ã®åºãR2ã¯ïŒäŸ¡ã®çåæ°Ž
çŽ åºãR3ã¯ïŒäŸ¡ã®èèªæ飜åçåæ°ŽçŽ åºãïœã¯
ïŒä»¥äžã®æ£ã®æ°ãïœã¯ïŒãïŒã瀺ãïŒã§è¡šããã
ãã¢ãžãåºå«æç°ç¶ããªãªã«ã¬ãã·ãããµã³ã«é¢
ããããŸãæ¬çºæã¯ã äžè¬åŒ ãïŒHOR3ïŒaR2 2-aSiOão âŠâŠâŠ(1) ïŒãã ãR2ãR3ãïœããã³ïœã¯åè¿°ã®éãïŒã§è¡š
ãããããå°ããšãïŒåã®ççŽ ååãä»ããŠã±ã€
çŽ ååã«çµåããæ°Žé žåºãæããç°ç¶ããªãªã«ã¬
ãã·ãããµã³ãšã äžè¬åŒ ïŒãã ãã¯åè¿°ã®éãïŒã§è¡šããããã¢ãžãå
è³éŠæé žå¡©åç© ãåå¿ããããå㯠äžè¬åŒ ãïŒHOR3ïŒaR2 2-aSiOão âŠâŠâŠ(1) ïŒãã ãR2ãR3ãïœããã³ïœã¯åè¿°ã®éãïŒã§è¡š
ãããããå°ããšãïŒåã®ççŽ ååãä»ããŠã±ã€
çŽ ååã«çµåããæ°Žé žåºãæããç°ç¶ããªãªã«ã¬
ãã·ãããµã³ãšã äžè¬åŒ ïŒãã ãã¯åè¿°ã®éããR4ã¯ççŽ æ°ïŒã10ã®ã¢
ã«ãã«åºã瀺ãïŒã§è¡šããããã¢ãžãåè³éŠæã«
ã«ãã³é žã¢ã«ãã«ãšã¹ãã« ãåå¿ãããããæŽã«å äžè¬åŒ ãaR2 2-aSiOão âŠâŠâŠ(4) ïŒãã ãR2ãïœããã³ïœã¯åè¿°ã®éãïŒã§è¡šãã
ãããã±ã€çŽ ååã«çµåããæ°ŽçŽ ååãæããç°
ç¶ããªãªã«ã¬ãã·ãããµã³ãšã äžè¬åŒ ïŒãã ãã¯åè¿°ã®éããã¯ççŽ æ°ïŒã10ã®ã¢
ã«ã±ãã«åºã瀺ãïŒã§è¡šããããã¢ãžãåè³éŠæ
ã«ã«ãã³é žã¢ã«ã±ãã«ãšã¹ãã« ãåå¿ãããããšãç¹åŸŽãšãããåèšäžè¬åŒ ãR1 aR2 2-aSiOão ïŒãã ãR1ãR2ãïœããã³ïœã¯åè¿°ã®éãïŒã§è¡š
ããããã¢ãžãåºå«æç°ç¶ããªãªã«ã¬ãã·ãããµ
ã³ã®è£œé æ³ã«é¢ãããã®ã§ããã æ¬çºæã®ã¢ãžãåºå«æç°ç¶ããªãªã«ã¬ãã·ãã
ãµã³ã¯ãç°ç¶ããªãªã«ã¬ãã·ãããµã³ã®åŽéã«ïŒ
䟡ã®ã¢ãžãåºå«æææ©åºR1ïŒãã ãR1ã¯åè¿°ã®
éãïŒãæã€ãã®ã§ãããç°ç¶ããªãªã«ã¬ãã·ã
ããµã³ã®éå床ïœã¯ïŒãïŒã®ç¯å²ããéžã°ãã
ããåæã·ãããµã³ã®åæã®å®¹æããããéå床
ïŒã®ãã®ãæãæšå¥šããããïœã¯ïŒä»¥äžã®æ£ã®æ°
ããéžã°ãããé²å ã«ããæ¶æ©ããŠç¶²ç¶ããªããŒ
ã圢æããããã«ã¯ãïŒååäžã«å¹³åïŒå以äžã®
R1ãæããããšãå¿ èŠã§ãããæ¶æ©ããªããŒã«
é©åºŠã®åŒ·éæ§ãäžããã«ã¯ãïœã®å¹³åå€ã¯0.55ã
ïŒã®ç¯å²ã§ããããšã奜ãŸããããæ¬çºæã®ç©è³ª
ãšããŠã¯ãç¹ã«éå®ããããã®ã§ã¯ãªãã åŒäžã®R2ã¯ïŒäŸ¡ã®çåæ°ŽçŽ åºã§ãããã¡ãã«
åºããšãã«åºããããã«åºãããã«åºãããã·ã«
åºã®ãããªã¢ã«ãã«åºãããã«åºãããããã«åº
ã®ãããªã¢ã«ã±ãã«åºãããšãã«åºãβâããšã
ã«ãšãã«åºãªã©ãäŸç€ºãããããåæã®å®¹æã
ããçæããã¢ãžãåç°ç¶ããªãªã«ã¬ãã·ãããµ
ã³ã®åæ±ã®å®¹æãããããã®50ïŒ ä»¥äžãã¡ãã«åº
ã§ããããšã奜ãŸãããå®è³ªçã«R2ã®ãã¹ãŠã
ã¡ãã«åºã§ããããšãããã«å¥œãŸããã åŒäžã®R3ã¯ïŒäŸ¡ã®èèªæ飜åçåæ°ŽçŽ åºã§ã
ããåæã®å®¹æããçæç©ã®ç²åºŠãåæ±ãã®å®¹æ
ããããç¹ã«ççŽ æ°ïŒã10ã®ïŒäŸ¡ã®èèªæ飜åç
åæ°ŽçŽ ã§ããããšã奜ãŸãããããªãã¡ãã¡ãã¬
ã³åºããšãã¬ã³åºããããã¬ã³åºãããã¬ã³åºã
ããã·ã¬ã³åºãªã©ãäŸç€ºããããäžè¬ã«ããªãªã«
ã¬ãã·ãããµã³ã®åŽéã«ã€ãããšã¹ãã«çµåã®å
æ°Žå解ã«å¯Ÿããå®å®æ§ã¯ããšã¹ãã«çµåãççŽ å
åïŒãïŒåãä»ããŠã±ã€çŽ ååã«çµåããŠãããš
ãã«ã¯åŒ±ããé žæ§ãªããã¢ã«ã«ãªæ§ã®ç°å¢ã§ãå
ããªããå æ°Žå解ãåããåŸåããããççŽ åå
ïŒåãŸãã¯ãã以äžãä»ããŠã±ã€çŽ ååã«çµåã
ãŠãããšãã¯å®å®ã§ããã®ãããªå æ°Žå解ãåã
ãªããäžæ¹ãR3ã倧ãããªããšçæç©ã®ç²åºŠã
äžæããŠåæ±ãã«ãããªãã®ã§å®çšäžãR3ãšã
ãŠã¯ççŽ æ°ïŒãïŒã®éç¶ã®ãã®ã®ãç¹ã«ãããã¬
ã³åºãæå©ã§ããã ã¯åè¿°ã®ç¯å²ã«ãã€ãŠãã¢ã«ãã«åºãšããŠã¯
ã¡ãã«åºããšãã«åºãªã©ããã¢ã«ã³ãã·ã«åºãšã
ãŠã¯ã¡ããã·åºããšããã·åºãªã©ããåããã²ã³
ååãšããŠã¯å¡©çŽ ååãäŸç€ºãããããããã®ã¢
ã«ãã«åºãã¢ã«ã³ãã·åºãããã²ã³ååãããã
åºçã®çœ®æåºã¯ã¢ãžãåºå«æç°ç¶ããªãªã«ã¬ãã·
ãããµã³ã®å åžåããŒã¯ã®æ³¢é·ã移åãããå¹æ
ãæãããããã³ã¢ãžãåºã¯ã«ã«ããã·ã«åºã«
察ããŠä»»æã®äœçœ®ãšãšãããšãã§ããç¹ã«å¶éã¯
ãªãããåæã®å®¹æããããã¢ãžãåºãã«ã«ãã
ã·ã«åºã«å¯ŸããŠãã©äœçœ®ã«ãããã®ãæå©ã§ã
ãã äžè¬åŒ ãïŒHOR3ïŒaR2 2-aSiOão âŠâŠâŠ(1) ïŒãã ãR2ãR3ãïœããã³ïœã¯åè¿°ã®éãïŒã§è¡š
ãããããå°ããšãïŒåã®ççŽ ååãä»ããŠã±ã€
çŽ ååã«çµåããæ°Žé žåºãæããç°ç¶ããªãªã«ã¬
ãã·ãããµã³ãšã äžè¬åŒ ïŒãããã¯åè¿°ã®éãïŒã§è¡šããããã¢ãžãå
è³éŠæé žå¡©åç© ãåå¿ãããããšãç¹åŸŽãšããã äžè¬åŒ(1)ã§è¡šããããæ°Žé žåºãæããããªãªã«
ã¬ãã·ãããµã³ã¯ãã±ã€çŽ ååã¯çµåããŠæ°ŽçŽ å
åããã€ç°ç¶ããªãªã«ã¬ãã·ãããµã³ã«äžé£œåã¢
ã«ã³ãŒã«ãä»å ããæ¹æ³ãåæ§ãªç°ç¶ããªãªã«ã¬
ãã·ãããµã³ã«å¡©çŽ åäžé£œåçåæ°ŽçŽ ãä»å ããŠ
å æ°Žå解ããæ¹æ³ãã¢ã«ãã«ç°ç¶ããªãªã«ã¬ãã·
ãããµã³ãå¡©çŽ åããŠå æ°Žå解ãããªã©å ¬ç¥ã®æ¹
æ³ã«ãã€ãŠåŸããããã®äŸãšããŠã¯ãããªã¡ãã«
ããªã¹ïŒÎ³âããããã·ãããã«ïŒã·ã¯ãããªã·
ãããµã³ãããã©ã¡ãã«ããã©ãã¹ïŒÎ³âããã
ãã·ã¡ãã«ïŒã·ã¯ãããã©ã·ãããµã³ãããã©ã¡
ãã«ããã©ãã¹ïŒÎ³âããããã·ãããã«ïŒã·ã¯
ãããã©ã·ãããµã³ãããã©ã¡ãã«ããã©ãã¹
ïŒÎ³âããããã·ããã«ïŒã·ã¯ãããã©ã·ãããµ
ã³ããã³ã¿ã¡ãã«ããªã¹ïŒÎ³âããããã·ããã
ã«ïŒã·ã¯ãããã©ã·ãããµã³ããããµã¡ãã«ãã¹
ïŒÎ³âããããã·ãããã«ïŒã·ã¯ãããã©ã·ãã
ãµã³ãããã¿ã¡ãã«ïŒÎ³âããããã·ãããã«ïŒ
ã·ã¯ãããã©ã·ãããµã³ããã³ã¿ã¡ãã«ãã³ã¿ã
ã¹ïŒÎ³âããããã·ãããã«ïŒã·ã¯ããã³ã¿ã·ã
ããµã³ãªã©ãäŸç€ºãããã äžè¬åŒ(2)ã§è¡šããããã¢ãžãåè³éŠæé žåç©ã®
äŸãšããŠã¯ãïœâã¢ãžãå®æ¯éŠæã¯ãã©ã€ããïœ
âã¢ãžãâïœâã¡ãã«å®æ¯éŠé žã¯ãã©ã€ããïœâ
ã¢ãžãâïœâãšãã«å®æ¯éŠé žã¯ãã©ã€ããïœâã¢
ãžãâïœâãããå®æ¯éŠé žã¯ãã©ã€ããïœâã¢ãž
ãâïœâã¡ããã·å®éŠé žã¯ãã©ã€ããïœâã¢ãžã
âïœâã¯ããå®æ¯éŠé žã¯ãã©ã€ããïœâã¢ãžãå®
æ¯éŠé žã¯ãã©ã€ããïœâã¢ãžãå®æ¯éŠé žã¯ãã©ã€
ããªã©ãããã ã¢ãžãåºå«æç°ç¶ããªãªã«ã¬ãã·ãããµã³ã®å
æã¯ãäžè¬åŒ(1)ã§è¡šããããã·ãããµã³ãšäžè¬åŒ
(2)ã§è¡šããããã¢ãžãåè³éŠæé žå¡©åç©ããã®ãš
ã¹ãã«ååå¿ã«ãã€ãŠè¡ããããäžè¬åŒ(1)ã«æŒã
ãæ°Žé žåºïŒåã«å¯ŸããŠäžè¬åŒ(2)ã«æŒããé žã¯ãã©
ã€ãåºã奜ãŸããã¯å®è³ªäžïŒåã®å²åã«ãªããã
ã«é åããŠè¡ãããäºãäžè¬åŒ(1)ãŸãã¯(2)ã®åå
ç©ã«ãå¯çããå¡©åæ°ŽçŽ ã®å容äœãšããŠãããªãž
ã³ã®ãããªææ©å¡©åºãå ±åãããããŸã溶å€ãšã
ãŠãéå°éã®ããªãžã³ããŸãã¯ãã«ãšã³ããã·ã¬
ã³ããã³ã¡ãã«ãšãã«ã±ãã³ãªã©ããéžã°ããæ
æ©æº¶å€ã«ãŠåžéããããšããåå¿ãåæ»ã«é²ãã
ããã«å¥œãŸãããåå¿æž©åºŠã¯å®€æž©ã120âã奜ãŸ
ããã¯60ã90âãåå¿æéã¯ïŒã48æéã劥åœã§
ããããã¢ãžãååç©ã®å解枩床以äžã§ããã°ã
ç¹ã«å¶éããããã®ã§ã¯ãªããåå¿çµäºåŸã溶液
ã倧éå°ã®æ°Žã«èœãšããŠãã¢ãžãåºå«æããªãªã«
ã¬ãã·ãããµã³ãåå¥ãããšãšãã«ãæªåå¿ã®ã¢
ãžãåè³éŠæé žå¡©åç©ãå解ããã¢ãžãåºå«æç°
ç¶ããªãªã«ã¬ãã·ãããµã³ãæ°ŽæŽã粟補ããã ãã®ããã«ããŠåŸãããã¢ãžãåºå«æç°ç¶ããª
ãªã«ã¬ãã·ãããµã³ã®èµ€å€åžåã¹ãã¯ãã«ãåæ
ïŒãšæ¯èŒãããšã第ïŒå³ã®ããã«ãªããããªã
ã¡ãïŒã®èµ€å€åžåã¹ãã¯ãã«ïŒç¬¬ïŒå³ã®ïŒïŒã«èª
ããããç¶æ ã«åºã¥ã3200ã3600cm-1ã®åžåãã
ã¢ãžãåºå«æç°ç¶ããªãªã«ã¬ãã·ãããµã³ã®èµ€å€
åžåã¹ãã¯ãã«ïŒç¬¬ïŒå³ã®ïŒïŒã§ã¯æ¶æ» ããŠã
ããããã«ããã€ãŠæ°ããããšã¹ãã«çµåã«åºã¥
ã1735cm-1ã®åžåãã¢ãžãåºã«åºã¥ã1300cm-1ã
ãã³2150cm-1ã®åžåãçããŠããããšãããåå¿
ãé²è¡ããŠããããšã確èªãããã ããã«ã觊ããããã«ãåå¿çæç©ã倧éå°ã®
æ°Žã«èœãšããŠã¢ãžãåºå«æããªãªã«ã¬ãã·ãããµ
ã³ãåå¥ããéãæªåå¿ã®ã¢ãžãåè³éŠæé žå¡©å
ç©ã¯å æ°Žå解ãåããŠã¢ãžãåè³éŠæã«ã«ãã³é ž
ã«ãªãããããã¯æ°Žã«å¯æº¶ã§ãããæ°ŽæŽåŸã®ã¢ãž
ãåºå«æç°ç¶ããªãªã«ã¬ãã·ãããµã³å±€ã«ã¯ãæª
åå¿ã®ã¢ãžãååç©ããã³ããã«ç±æ¥ããä»ã®ã¢
ãžãååç©ã¯æ··å ¥ããŠããªããããã粟補ããã·
ãããµã³å±€ã粟補ãããã®ã«ã€ããŠå çŽ åæãè¡
ã€ããšãããã¢ãžãåºã«èµ·å ããçªçŽ ã®ååšã確
èªãããããã®ã¢ãžãåºå«æç°ç¶ããªãªã«ã¬ãã·
ãããµã³ã«æ°Žéç¯ç §å°ãè¡ã€ããšãããåºæã®å
解åå¿ãè¡ã€ãŠãã€ãã¬ã³ã©ãžã«ã«ãçããã±ã€
çŽ ååã«çµåããã¡ãã«åºããã®æ°ŽçŽ åŒæåå¿ã
ããã«åºïŒååšããå ŽåïŒã®äºéçµåãžã®æ¿å ¥å
å¿ããã€ãã¬ã³ã©ããã®ã«ãããªã³ã°åå¿ã«ãã€
ãŠæ¶æ©ãçããäžæº¶äžèã®éåäœãåŸããããã
ã®ãããªæ°Žéç¯ç §å°ãã¢ãŸãã¡ãŒã¿ãŒäžã§è¡ã€ã
ãšãããçè«éã®çªçŽ ã¬ã¹ã®çºçãèªããããã æ¬çºæã«ãããã第ïŒã®è£œé æ³ã¯ã äžè¬åŒ ãïŒHOR3ïŒaR2 2-aSiOão âŠâŠâŠ(1) ïŒãããR2ãR3ãïœããã³ïœã¯åè¿°ã®éãïŒã§è¡š
ãããããå°ããšãïŒäŸ¡ã®ççŽ ååãä»ããŠã±ã€
çŽ ååã«çµåããæ°Žé žåºãæããç°ç¶ããªãªã«ã¬
ãã·ãããµã³ãšã äžè¬åŒ ïŒãããã¯åè¿°ã®éããR4ã¯ççŽ æ°ïŒã10ã®ã¢
ã«ãã«åºã瀺ãïŒã§è¡šããããã¢ãžãåè³éŠæã«
ã«ãã³é žã¢ã«ãã«ãšã¹ãã« ãåå¿ãããããšãç¹åŸŽãšããã äžè¬åŒ(1)ã§è¡šããããæ°Žé žåºãæããããªãªã«
ã¬ãã·ãããµã³ã«ã€ããŠã¯ã第ïŒã®è£œé æ³ã§è§Šã
ãéãã§ããã äžè¬åŒ(3)ã§è¡šããããã¢ãžãåè³éŠæã«ã«ãã³
é žã¢ã«ãã«ãšã¹ãã«ã®äŸãšããŠã¯ãåèšäžè¬åŒ(2)
ã§è¡šããããã¢ãžãåè³éŠæé žå¡©åç©ã«å¯Ÿå¿ãã
é žã®ã¡ãã«ãšã¹ãã«ãšããšãã«ãšã¹ãã«ãããã
ã«ãšã¹ãã«ãã€ãœãããã«ãšã¹ãã«ãªã©ãããã«
å ·äœçã«ã¯ãïœâã¢ãžãå®æ¯éŠé žã¡ãã«ãïœâã¢
ãžãå®æ¯éŠé žãšãã«ãïœâã¢ãžãâïœâã¡ãã«å®
æ¯éŠé žã¡ãã«ãªã©ãæããããã ã¢ãžãåºå«æç°ç¶ããªãªã«ã¬ãã·ãããµã³ã®å
æã¯äžè¬åŒ(1)ã§è¡šããããã·ãããµã³ãšäžè¬åŒ(3)
ã§è¡šãããããšã¹ãã«ããã®ãšã¹ãã«äº€æåå¿ã«
ãã€ãŠè¡ããããäžè¬åŒ(1)ã«æŒããæ°Žé žåºïŒåã«
察ããŠäžè¬åŒ(3)ã§è¡šãããããšã¹ãã«ã奜ãŸãã
ã¯å®è³ªäžïŒåã«ãªãããã«ã溶å€äžã§äžè¬åŒ(1)ã§
è¡šããããã·ãããµã³ãšäžè¬åŒ(3)ã§è¡šãããããš
ã¹ãã«ãé åããã溶å€ãšããŠã¯ãã«ãšã³ããã·
ã¬ã³ãç³æ²¹ç³»æº¶å€ããã³ã¡ãã«ãšãã«ã±ãã³ãªã©
ããéžã°ããææ©æº¶å€ãçšãããããåå¿æž©åºŠã¯
100ã150âã®éãããããã¢ãžãååç©ã®å解枩
床ãäœããšãã¯ããã®æž©åºŠä»¥äžã§ãªããã°ãªããª
ããåå¿ã®éã«ãåå¿ãä¿é²ããããã«ãé ¢é žäº
éããªã¯ãã«é žäºéã®ãããªéå±èèªé žå¡©ãæ·»å
ããããšã奜ãŸããã溶å€ã®éæµäžã«åå¿ãè¡ã€
ãŠãçæããã¢ã«ã³ãŒã«çå»ããŠããã®ãå®éç
ã§ãããåå¿çµäºåŸã溶å€ãçå»ããæªåå¿ç©ã
åå¥ã«ãã€ãŠé€å»ããã°ãç®çãšããã¢ãžãåºå«
æç°ç¶ããªãªã«ã¬ãã·ãããµã³ãåŸãããã æ¬çºæã«ãããã第ïŒã®è£œé æ³ã¯ã äžè¬åŒ ãaR2 2-aSiOão âŠâŠâŠ(4) ïŒãããR2ãïœããã³ïœã¯åè¿°ã®éãïŒã§è¡šãã
ãããã±ã€çŽ ååã«çµåããæ°ŽçŽ ååãæããç°
ç¶ããªãªã«ã¬ãã·ãããµã³ãšã äžè¬åŒ ïŒãããã¯åè¿°ã®éããã¯ççŽ æ°ïŒã10ã®ã¢
ã«ã±ãã«åºã瀺ãïŒã§è¡šããããã¢ãžãåè³éŠæ
ã«ã«ãã³é žã¢ã«ã±ãã«ãšã¹ãã« ãåå¿ãããããšãç¹åŸŽãšããã äžè¬åŒ(4)ã§è¡šããããã±ã€çŽ ååã«çµåããæ°Ž
çŽ ååãå«æããç°ç¶ããªãªã«ã¬ãã·ãããµã³ã®
äŸãšããŠã¯ãããªã¡ãã«ã·ã¯ãããªã·ãããµã³ã®
ãããªç°ç¶ããªã·ãããµã³ãããã¿ã¡ãã«ã·ã¯ã
ããã©ã·ãããµã³ããããµã¡ãã«ã·ã¯ãããã©ã·
ãããµã³ããã³ã¿ã¡ãã«ã·ã¯ãããã©ã·ãããµ
ã³ãããã©ã¡ãã«ã·ã¯ãããã©ã·ãããµã³ããã
ã©ã¡ãã«ãžããã«ã·ã¯ãããã©ã·ãããµã³ããã
ã©ã¡ãã«ããã«ã·ã¯ãããã©ã·ãããµã³ãããã©
ã¡ãã«ãžããã·ã«ã¯ãããã©ã·ãããµã³ãããã©
ã¡ãã«ããã·ã«ã·ã¯ãããã©ã·ãããµã³ã®ãããª
ç°ç¶ããã©ã·ãããµã³ããã³ã¿ã¡ãã«ã·ã¯ããã³
ã¿ã·ãããµã³ããã³ã¿ã¡ãã«ãžããã·ã«ã·ã¯ãã
ã³ã¿ã·ãããµã³ã®ãããªç°ç¶ãã³ã¿ã·ãããµã³ã
ããã äžè¬åŒ(5)ã§è¡šããããã¢ãžãåè³éŠæã«ã«ãã³
é žã¢ã«ã±ãã«ãšã¹ãã«ã®äŸãšããŠã¯ãåèšäžè¬åŒ
(2)ã§è¡šããããã¢ãžãåè³éŠæé žå¡©åç©ã«å¯Ÿå¿ã
ãé žã®ããã«ãšã¹ãã«ãããããã«ãšã¹ãã«ãã
ããã«ãšã¹ãã«ãããã»ãã«ãšã¹ãã«ãªã©ãæã
ãããããã«å ·äœçã«ã¯ãïœâã¢ãžãå®æ¯éŠé žã
ãã«ãïœâã¢ãžãå®æ¯éŠé žããããã«ãïœâã¢ãž
ãâïœâã¡ãã«å®æ¯éŠé žããããã«ãªã©ãæãã
ããã ã¢ãžãåºå«æç°ç¶ããªãªã«ã¬ãã·ãããµã³ã®å
æã¯ãäžè¬åŒ(4)ã§è¡šããããã·ãããµã³äžè¬åŒ(5)
ã§è¡šããããã¢ã«ã±ãã«ãšã¹ãã«ããã®ãããã·
ãªã«ååå¿ã«ãã€ãŠè¡ããããSiâçµåïŒåã«
察ããŠãäžè¬åŒ(5)ã®ã¢ã«ã±ãã«ãšã¹ãã«ã奜ãŸã
ãã¯å®è³ªäžïŒåã®å²åã«ãªãããã«é åããçå
æ°ŽçŽ æº¶å€äžã§ãã«ãŒãã³æ æçœéãå¡©åçœéé žã
ãã³ãã®é¯äœã®ãããªãçœé系觊åªã®ååšäžã«å
å¿ãè¡ããåå¿æž©åºŠã¯100ã150âãé©ããŠãã
ããã¢ãžãååç©ã®å解枩床ãäœããšãã¯ããã®
枩床以äžã§ãªããã°ãªããªããåå¿çµäºåŸã觊åª
ãå¥ãªããæ°ŽæŽé€å»ãã溶å€ãçå»ããã°ãç®
çç©ã§ããã¢ãžãåºå«æç°ç¶ããªãªã«ã¬ãã·ãã
ãµã³ãåŸãããšãã§ããã ãããã®è£œé æ³ã«ãããã¢ãžãåºå«æç°ç¶ããª
ãªã«ã¬ãã·ãããµã³ãåŸãããšãã§ãããããã
ã®è£œé æ³ãæ¯èŒãããšã第ïŒã®è£œé æ³ã§ãããšã¹
ãã«åæ³ã¯ãåå¿ãæ¯èŒçäœæž©ãçæéã§èµ·ã
ãã奜åéã§ç®çãšããã¢ãžãåºå«æç°ç¶ããªãª
ã«ã¬ãã·ãããµã³ãåŸãããããšãæªåå¿ç©ã®é€
å»ã容æã§ããããšãåå¿æž©åºŠãäœããã¢ãžãåº
ã®å解ãã»ãšãã©ãªãããšãåæããªã·ãããµã³
ã®ææ©åºãä»»æã«éžã¹ãããšãªã©ã®å©ç¹ãããã
第ïŒã®è£œé æ³ã§ãããšã¹ãã«äº€ææ³ã¯ã第ïŒã®è£œ
é æ³ã«æ¯ã¹ãŠããåå¿æž©åºŠãé«ãããè±ã¢ã«ã³ãŒ
ã«ã«ãã€ãŠæ¯èŒç奜åçã§ç®çç©ãåŸãããã
ãšãå¿ èŠãšããåæããã¹ãŠå®¹æã«åŸãããã
ãšãããªãžã³ã®ãããªé«äŸ¡ãªæº¶å€ãå¿ èŠãšããªã
ããšãªã©ã®å©ç¹ãããã第ïŒã®è£œé æ³ã§ãããã
ãã·ãªã«åæ³ã¯ãåå¿æž©åºŠãé«ãããšãR3ãšã
ãŠççŽ æ°ïŒã®ãã®ãåŸãããªãããšãªã©ã®äžå©ãª
ç¹ã¯ããããåæããªãªã«ã¬ãã·ãããµã³ãšã
ãŠãæãäžè¬åŒãªãã®ã®äžã€ã§ãããã±ã€çŽ åå
ã«çµåããæ°ŽçŽ ååããã€ç°ç¶ããªãªã«ã¬ãã·ã
ããµã³ããã®ãŸãŸçšãåŸãå©ç¹ãããã æ¬çºæã«ããæ°èŠç©è³ªã§ããã¢ãžãåºå«æç°ç¶
ããªãªã«ã¬ãã·ãããµã³ã¯ã溶å€ã«æº¶è§£ããå¿ èŠ
ã«å¿ããŠå¢æå€ããã³ïŒãŸãã¯ããã«åºå«æããª
ãªã«ã¬ãã·ãããµã³ãæ·»å ããããšã«ããããã
ããæå æ§çµæç©ãåŸãããšãã§ãããããªã
ã¡ãæå å€ãåºããªããŒããåé¢ãçµæ¶åããã
ãšããªãã®ã§ã次ã®ãããªå©ç¹ãããã 補ç
å·¥çšãç°¡åã§ããã å®å®æ§ã«ããããä¿åæ§
ãè¯ãã æ床ãé«ãã çŸåæ§ãè¯ãã
å 硬åéšãšæ¯æäœãšã®æ¥çæ§ããå 硬åéšã®æ©
械ç匷床ãããããŠããããŸããæ¬çºæã®çµæç©
ã¯ãã¢ã¯ãªã«ç³»æå æã«ãããã®ã«æ¯ã¹ãŠããæ§
é ãç°¡åã§è£œçã容æã§ãããæå æ§ã®æç¶æ§ã«
ããããææžè¡°ããªããé žçŽ ãé®æããããã®ä¿
è·å±€ãèšããå¿ èŠããªããããã«ãçŽéç¶ã®ã¢ãž
ãåããªãªã«ã¬ãã·ãããµã³ãçšããæ¹æ³ã«æ¯ã¹
ãŠã解ååã«ããããæå å±€ã®åããå¢ããŠã解
ååãè¯ãããã®äžã€ã³ãå¥é¢æ§ãè溶å€æ§ãã
ãããŠããã®ã§ãäžèšã®æå å±€ãåããåŸãããš
ãšçžãŸã€ãŠãèå·åãäžæ®µãšæ¹åãããŠããã ãã®ããã«ãæ¬çºæã®æ°èŠç©è³ªããã³è£œé æ³
ã¯ãããããå¹³çå°å·æ¹æ³ãæäŸãããã®ã§ã
ããããã«æ¬çºæã®çµæç©ã®çšéã¯ãå¹³çå°å·ã«
éå®ããããã®ã§ã¯ãªãããã®ããããæå ç¹æ§
ãçãããŠãå 硬åæ§ã®å¡èãçŽãã®ä»ã®åºæã«
äžããããšãã°ããã®é¢åæ§ãå©çšããå¥é¢çšå¡
èãšããŠçšããããšãã§ããã 以äžãæ¬çºæã®å®æœäŸã瀺ããå®æœäŸã«ãã
ãŠãéšã¯ãã¹ãŠéééšãè¡šããã å®æœäŸ ïŒ ïœâã¢ãžãå®æ¯éŠé žã¯ãã©ã€ã54éšã«ããªãžã³
200éšãå ããã€ãã§åŒ ã§è¡šããããç°ç¶ããªãªã«ã¬ãã·ãããµã³43éšã
å ããŠååã«æ¹æãè¡ããåäžãªæº¶æ¶²ãšãããã
ãã80âã«ææž©ããŠïŒæéã®å ç±æ¹äŒŽãè¡ããšã
å¡©åæ°ŽçŽ ã®ããªãžã³å¡©ãçºçãã€ã€åå¿ãé²è¡ã
ãããã®åå¿ç©ã1000éšã®æ°Žã«æ»Žäžãããšãå¡©å
æ°ŽçŽ ããªãžã³å¡©ãšæªåå¿ã®ïœâã¢ãžãå®æ¯éŠé žã¯
ãã©ã€ãã¯æ°Žã«æº¶ããåå¿çæç©ãæ°Žã«äžæº¶æ§ã®
æš¹èç¶ç©ãšããŠåŸãããããããããªãžã³èããª
ããªããŸã§ååã«æŽæ»ããã®ã¡ã20éšã¢ã»ãã³ã«
溶ãããåã³æ°Žãå ããŠçæç©ãæåºããããã
ç¡æ°Žç¡«é žãœãŒãã§è±æ°Žããæ®åããã¢ã»ãã³ããš
ããã¬ãŒã¿ãŒã§çå»ããŠãæ·¡é»è²ã®ç²çš ãªæš¹èç¶
ã®ã¢ãžãåºå«æç°ç¶ããªãªã«ã¬ãã·ãããµã³75éš
ãåŸãããã㯠ãšããŠçè«åéã®87ïŒ ã§ãã€ãããã®ãã®ã®èµ€å€
åå ã¹ãã¯ãã«ããåæç°ç¶ããªãªã«ã¬ãã·ãã
ãµã³ãšæ¯èŒããŠç¬¬ïŒå³ã«ç€ºããåå¿ã«ãã€ãŠãæ°Ž
é žåºã«åºã¥ã3400cm-1ã®åžåãæ¶æ» ãããšã¹ãã«
çµåã«åºã¥ã1735cm-1ã®åžåãšãã¢ãžãåºã«åºã¥
ã1300cm-1ããã³2150cm-1ã®åžåãèªããããã
ãŸããçæç©ã®å çŽ åæããã³æ°·ç¹éäžæ³ã«ãã€
ãŠåŸãããååéã¯ç¬¬ïŒè¡šã®éãã§ãåèšã¢ãžã
åºå«æç°ç¶ããªãªã«ã¬ãã·ãããµã³ã®çè«å€ãšã
ãäžèŽããããŸããããã0.1ïŒ ã®ãã³ãŒã³æº¶æ¶²
ã«ããŠã¢ãŸãã¡ãŒã¿ãŒã«å ¥ããŠé«å§æ°Žéç¯ã«ãã
玫å€ç·ç §å°ãè¡ããçºçããçªçŽ ã¬ã¹ã®éã容é
åæãããšããã9.5ééïŒ ã®çªçŽ ã¬ã¹ã®çºçã
ã¿ããããã¯14.3ééïŒ ã®ã¢ãžãåºã®ååšã«çžåœ
ããçè«é14.59ïŒ ãšã»ãäžèŽããããããã®ã
ãšãããåå¿çæç©ã¯åŒ ã§ããããšã確èªãããã玫å€ç·ç §å°ã«ãã€ãŠç
æããç®èã®èµ€å€åå ã¹ãã¯ãã«ã第ïŒå³ã«èšã
ããã¢ãžãåºã«åºã¥ãåžåãæžå°ããŠããããšã
èªããããã
ïŒäŸ¡ã®ã¢ãžãåºå«æææ©åºãã¯æ°ŽçŽ ååãã¢ã«
ãã«åºãã¢ã«ã³ãã·åºããããåºããã³ããã²ã³
ååããéžã°ããïŒäŸ¡ã®åºãR2ã¯ïŒäŸ¡ã®çåæ°Ž
çŽ åºãR3ã¯ïŒäŸ¡ã®èèªæ飜åçåæ°ŽçŽ åºãïœã¯
ïŒä»¥äžã®æ£ã®æ°ãïœã¯ïŒãïŒã瀺ãïŒã§è¡šããã
ãã¢ãžãåºå«æç°ç¶ããªãªã«ã¬ãã·ãããµã³ã«é¢
ããããŸãæ¬çºæã¯ã äžè¬åŒ ãïŒHOR3ïŒaR2 2-aSiOão âŠâŠâŠ(1) ïŒãã ãR2ãR3ãïœããã³ïœã¯åè¿°ã®éãïŒã§è¡š
ãããããå°ããšãïŒåã®ççŽ ååãä»ããŠã±ã€
çŽ ååã«çµåããæ°Žé žåºãæããç°ç¶ããªãªã«ã¬
ãã·ãããµã³ãšã äžè¬åŒ ïŒãã ãã¯åè¿°ã®éãïŒã§è¡šããããã¢ãžãå
è³éŠæé žå¡©åç© ãåå¿ããããå㯠äžè¬åŒ ãïŒHOR3ïŒaR2 2-aSiOão âŠâŠâŠ(1) ïŒãã ãR2ãR3ãïœããã³ïœã¯åè¿°ã®éãïŒã§è¡š
ãããããå°ããšãïŒåã®ççŽ ååãä»ããŠã±ã€
çŽ ååã«çµåããæ°Žé žåºãæããç°ç¶ããªãªã«ã¬
ãã·ãããµã³ãšã äžè¬åŒ ïŒãã ãã¯åè¿°ã®éããR4ã¯ççŽ æ°ïŒã10ã®ã¢
ã«ãã«åºã瀺ãïŒã§è¡šããããã¢ãžãåè³éŠæã«
ã«ãã³é žã¢ã«ãã«ãšã¹ãã« ãåå¿ãããããæŽã«å äžè¬åŒ ãaR2 2-aSiOão âŠâŠâŠ(4) ïŒãã ãR2ãïœããã³ïœã¯åè¿°ã®éãïŒã§è¡šãã
ãããã±ã€çŽ ååã«çµåããæ°ŽçŽ ååãæããç°
ç¶ããªãªã«ã¬ãã·ãããµã³ãšã äžè¬åŒ ïŒãã ãã¯åè¿°ã®éããã¯ççŽ æ°ïŒã10ã®ã¢
ã«ã±ãã«åºã瀺ãïŒã§è¡šããããã¢ãžãåè³éŠæ
ã«ã«ãã³é žã¢ã«ã±ãã«ãšã¹ãã« ãåå¿ãããããšãç¹åŸŽãšãããåèšäžè¬åŒ ãR1 aR2 2-aSiOão ïŒãã ãR1ãR2ãïœããã³ïœã¯åè¿°ã®éãïŒã§è¡š
ããããã¢ãžãåºå«æç°ç¶ããªãªã«ã¬ãã·ãããµ
ã³ã®è£œé æ³ã«é¢ãããã®ã§ããã æ¬çºæã®ã¢ãžãåºå«æç°ç¶ããªãªã«ã¬ãã·ãã
ãµã³ã¯ãç°ç¶ããªãªã«ã¬ãã·ãããµã³ã®åŽéã«ïŒ
䟡ã®ã¢ãžãåºå«æææ©åºR1ïŒãã ãR1ã¯åè¿°ã®
éãïŒãæã€ãã®ã§ãããç°ç¶ããªãªã«ã¬ãã·ã
ããµã³ã®éå床ïœã¯ïŒãïŒã®ç¯å²ããéžã°ãã
ããåæã·ãããµã³ã®åæã®å®¹æããããéå床
ïŒã®ãã®ãæãæšå¥šããããïœã¯ïŒä»¥äžã®æ£ã®æ°
ããéžã°ãããé²å ã«ããæ¶æ©ããŠç¶²ç¶ããªããŒ
ã圢æããããã«ã¯ãïŒååäžã«å¹³åïŒå以äžã®
R1ãæããããšãå¿ èŠã§ãããæ¶æ©ããªããŒã«
é©åºŠã®åŒ·éæ§ãäžããã«ã¯ãïœã®å¹³åå€ã¯0.55ã
ïŒã®ç¯å²ã§ããããšã奜ãŸããããæ¬çºæã®ç©è³ª
ãšããŠã¯ãç¹ã«éå®ããããã®ã§ã¯ãªãã åŒäžã®R2ã¯ïŒäŸ¡ã®çåæ°ŽçŽ åºã§ãããã¡ãã«
åºããšãã«åºããããã«åºãããã«åºãããã·ã«
åºã®ãããªã¢ã«ãã«åºãããã«åºãããããã«åº
ã®ãããªã¢ã«ã±ãã«åºãããšãã«åºãβâããšã
ã«ãšãã«åºãªã©ãäŸç€ºãããããåæã®å®¹æã
ããçæããã¢ãžãåç°ç¶ããªãªã«ã¬ãã·ãããµ
ã³ã®åæ±ã®å®¹æãããããã®50ïŒ ä»¥äžãã¡ãã«åº
ã§ããããšã奜ãŸãããå®è³ªçã«R2ã®ãã¹ãŠã
ã¡ãã«åºã§ããããšãããã«å¥œãŸããã åŒäžã®R3ã¯ïŒäŸ¡ã®èèªæ飜åçåæ°ŽçŽ åºã§ã
ããåæã®å®¹æããçæç©ã®ç²åºŠãåæ±ãã®å®¹æ
ããããç¹ã«ççŽ æ°ïŒã10ã®ïŒäŸ¡ã®èèªæ飜åç
åæ°ŽçŽ ã§ããããšã奜ãŸãããããªãã¡ãã¡ãã¬
ã³åºããšãã¬ã³åºããããã¬ã³åºãããã¬ã³åºã
ããã·ã¬ã³åºãªã©ãäŸç€ºããããäžè¬ã«ããªãªã«
ã¬ãã·ãããµã³ã®åŽéã«ã€ãããšã¹ãã«çµåã®å
æ°Žå解ã«å¯Ÿããå®å®æ§ã¯ããšã¹ãã«çµåãççŽ å
åïŒãïŒåãä»ããŠã±ã€çŽ ååã«çµåããŠãããš
ãã«ã¯åŒ±ããé žæ§ãªããã¢ã«ã«ãªæ§ã®ç°å¢ã§ãå
ããªããå æ°Žå解ãåããåŸåããããççŽ åå
ïŒåãŸãã¯ãã以äžãä»ããŠã±ã€çŽ ååã«çµåã
ãŠãããšãã¯å®å®ã§ããã®ãããªå æ°Žå解ãåã
ãªããäžæ¹ãR3ã倧ãããªããšçæç©ã®ç²åºŠã
äžæããŠåæ±ãã«ãããªãã®ã§å®çšäžãR3ãšã
ãŠã¯ççŽ æ°ïŒãïŒã®éç¶ã®ãã®ã®ãç¹ã«ãããã¬
ã³åºãæå©ã§ããã ã¯åè¿°ã®ç¯å²ã«ãã€ãŠãã¢ã«ãã«åºãšããŠã¯
ã¡ãã«åºããšãã«åºãªã©ããã¢ã«ã³ãã·ã«åºãšã
ãŠã¯ã¡ããã·åºããšããã·åºãªã©ããåããã²ã³
ååãšããŠã¯å¡©çŽ ååãäŸç€ºãããããããã®ã¢
ã«ãã«åºãã¢ã«ã³ãã·åºãããã²ã³ååãããã
åºçã®çœ®æåºã¯ã¢ãžãåºå«æç°ç¶ããªãªã«ã¬ãã·
ãããµã³ã®å åžåããŒã¯ã®æ³¢é·ã移åãããå¹æ
ãæãããããã³ã¢ãžãåºã¯ã«ã«ããã·ã«åºã«
察ããŠä»»æã®äœçœ®ãšãšãããšãã§ããç¹ã«å¶éã¯
ãªãããåæã®å®¹æããããã¢ãžãåºãã«ã«ãã
ã·ã«åºã«å¯ŸããŠãã©äœçœ®ã«ãããã®ãæå©ã§ã
ãã äžè¬åŒ ãïŒHOR3ïŒaR2 2-aSiOão âŠâŠâŠ(1) ïŒãã ãR2ãR3ãïœããã³ïœã¯åè¿°ã®éãïŒã§è¡š
ãããããå°ããšãïŒåã®ççŽ ååãä»ããŠã±ã€
çŽ ååã«çµåããæ°Žé žåºãæããç°ç¶ããªãªã«ã¬
ãã·ãããµã³ãšã äžè¬åŒ ïŒãããã¯åè¿°ã®éãïŒã§è¡šããããã¢ãžãå
è³éŠæé žå¡©åç© ãåå¿ãããããšãç¹åŸŽãšããã äžè¬åŒ(1)ã§è¡šããããæ°Žé žåºãæããããªãªã«
ã¬ãã·ãããµã³ã¯ãã±ã€çŽ ååã¯çµåããŠæ°ŽçŽ å
åããã€ç°ç¶ããªãªã«ã¬ãã·ãããµã³ã«äžé£œåã¢
ã«ã³ãŒã«ãä»å ããæ¹æ³ãåæ§ãªç°ç¶ããªãªã«ã¬
ãã·ãããµã³ã«å¡©çŽ åäžé£œåçåæ°ŽçŽ ãä»å ããŠ
å æ°Žå解ããæ¹æ³ãã¢ã«ãã«ç°ç¶ããªãªã«ã¬ãã·
ãããµã³ãå¡©çŽ åããŠå æ°Žå解ãããªã©å ¬ç¥ã®æ¹
æ³ã«ãã€ãŠåŸããããã®äŸãšããŠã¯ãããªã¡ãã«
ããªã¹ïŒÎ³âããããã·ãããã«ïŒã·ã¯ãããªã·
ãããµã³ãããã©ã¡ãã«ããã©ãã¹ïŒÎ³âããã
ãã·ã¡ãã«ïŒã·ã¯ãããã©ã·ãããµã³ãããã©ã¡
ãã«ããã©ãã¹ïŒÎ³âããããã·ãããã«ïŒã·ã¯
ãããã©ã·ãããµã³ãããã©ã¡ãã«ããã©ãã¹
ïŒÎ³âããããã·ããã«ïŒã·ã¯ãããã©ã·ãããµ
ã³ããã³ã¿ã¡ãã«ããªã¹ïŒÎ³âããããã·ããã
ã«ïŒã·ã¯ãããã©ã·ãããµã³ããããµã¡ãã«ãã¹
ïŒÎ³âããããã·ãããã«ïŒã·ã¯ãããã©ã·ãã
ãµã³ãããã¿ã¡ãã«ïŒÎ³âããããã·ãããã«ïŒ
ã·ã¯ãããã©ã·ãããµã³ããã³ã¿ã¡ãã«ãã³ã¿ã
ã¹ïŒÎ³âããããã·ãããã«ïŒã·ã¯ããã³ã¿ã·ã
ããµã³ãªã©ãäŸç€ºãããã äžè¬åŒ(2)ã§è¡šããããã¢ãžãåè³éŠæé žåç©ã®
äŸãšããŠã¯ãïœâã¢ãžãå®æ¯éŠæã¯ãã©ã€ããïœ
âã¢ãžãâïœâã¡ãã«å®æ¯éŠé žã¯ãã©ã€ããïœâ
ã¢ãžãâïœâãšãã«å®æ¯éŠé žã¯ãã©ã€ããïœâã¢
ãžãâïœâãããå®æ¯éŠé žã¯ãã©ã€ããïœâã¢ãž
ãâïœâã¡ããã·å®éŠé žã¯ãã©ã€ããïœâã¢ãžã
âïœâã¯ããå®æ¯éŠé žã¯ãã©ã€ããïœâã¢ãžãå®
æ¯éŠé žã¯ãã©ã€ããïœâã¢ãžãå®æ¯éŠé žã¯ãã©ã€
ããªã©ãããã ã¢ãžãåºå«æç°ç¶ããªãªã«ã¬ãã·ãããµã³ã®å
æã¯ãäžè¬åŒ(1)ã§è¡šããããã·ãããµã³ãšäžè¬åŒ
(2)ã§è¡šããããã¢ãžãåè³éŠæé žå¡©åç©ããã®ãš
ã¹ãã«ååå¿ã«ãã€ãŠè¡ããããäžè¬åŒ(1)ã«æŒã
ãæ°Žé žåºïŒåã«å¯ŸããŠäžè¬åŒ(2)ã«æŒããé žã¯ãã©
ã€ãåºã奜ãŸããã¯å®è³ªäžïŒåã®å²åã«ãªããã
ã«é åããŠè¡ãããäºãäžè¬åŒ(1)ãŸãã¯(2)ã®åå
ç©ã«ãå¯çããå¡©åæ°ŽçŽ ã®å容äœãšããŠãããªãž
ã³ã®ãããªææ©å¡©åºãå ±åãããããŸã溶å€ãšã
ãŠãéå°éã®ããªãžã³ããŸãã¯ãã«ãšã³ããã·ã¬
ã³ããã³ã¡ãã«ãšãã«ã±ãã³ãªã©ããéžã°ããæ
æ©æº¶å€ã«ãŠåžéããããšããåå¿ãåæ»ã«é²ãã
ããã«å¥œãŸãããåå¿æž©åºŠã¯å®€æž©ã120âã奜ãŸ
ããã¯60ã90âãåå¿æéã¯ïŒã48æéã劥åœã§
ããããã¢ãžãååç©ã®å解枩床以äžã§ããã°ã
ç¹ã«å¶éããããã®ã§ã¯ãªããåå¿çµäºåŸã溶液
ã倧éå°ã®æ°Žã«èœãšããŠãã¢ãžãåºå«æããªãªã«
ã¬ãã·ãããµã³ãåå¥ãããšãšãã«ãæªåå¿ã®ã¢
ãžãåè³éŠæé žå¡©åç©ãå解ããã¢ãžãåºå«æç°
ç¶ããªãªã«ã¬ãã·ãããµã³ãæ°ŽæŽã粟補ããã ãã®ããã«ããŠåŸãããã¢ãžãåºå«æç°ç¶ããª
ãªã«ã¬ãã·ãããµã³ã®èµ€å€åžåã¹ãã¯ãã«ãåæ
ïŒãšæ¯èŒãããšã第ïŒå³ã®ããã«ãªããããªã
ã¡ãïŒã®èµ€å€åžåã¹ãã¯ãã«ïŒç¬¬ïŒå³ã®ïŒïŒã«èª
ããããç¶æ ã«åºã¥ã3200ã3600cm-1ã®åžåãã
ã¢ãžãåºå«æç°ç¶ããªãªã«ã¬ãã·ãããµã³ã®èµ€å€
åžåã¹ãã¯ãã«ïŒç¬¬ïŒå³ã®ïŒïŒã§ã¯æ¶æ» ããŠã
ããããã«ããã€ãŠæ°ããããšã¹ãã«çµåã«åºã¥
ã1735cm-1ã®åžåãã¢ãžãåºã«åºã¥ã1300cm-1ã
ãã³2150cm-1ã®åžåãçããŠããããšãããåå¿
ãé²è¡ããŠããããšã確èªãããã ããã«ã觊ããããã«ãåå¿çæç©ã倧éå°ã®
æ°Žã«èœãšããŠã¢ãžãåºå«æããªãªã«ã¬ãã·ãããµ
ã³ãåå¥ããéãæªåå¿ã®ã¢ãžãåè³éŠæé žå¡©å
ç©ã¯å æ°Žå解ãåããŠã¢ãžãåè³éŠæã«ã«ãã³é ž
ã«ãªãããããã¯æ°Žã«å¯æº¶ã§ãããæ°ŽæŽåŸã®ã¢ãž
ãåºå«æç°ç¶ããªãªã«ã¬ãã·ãããµã³å±€ã«ã¯ãæª
åå¿ã®ã¢ãžãååç©ããã³ããã«ç±æ¥ããä»ã®ã¢
ãžãååç©ã¯æ··å ¥ããŠããªããããã粟補ããã·
ãããµã³å±€ã粟補ãããã®ã«ã€ããŠå çŽ åæãè¡
ã€ããšãããã¢ãžãåºã«èµ·å ããçªçŽ ã®ååšã確
èªãããããã®ã¢ãžãåºå«æç°ç¶ããªãªã«ã¬ãã·
ãããµã³ã«æ°Žéç¯ç §å°ãè¡ã€ããšãããåºæã®å
解åå¿ãè¡ã€ãŠãã€ãã¬ã³ã©ãžã«ã«ãçããã±ã€
çŽ ååã«çµåããã¡ãã«åºããã®æ°ŽçŽ åŒæåå¿ã
ããã«åºïŒååšããå ŽåïŒã®äºéçµåãžã®æ¿å ¥å
å¿ããã€ãã¬ã³ã©ããã®ã«ãããªã³ã°åå¿ã«ãã€
ãŠæ¶æ©ãçããäžæº¶äžèã®éåäœãåŸããããã
ã®ãããªæ°Žéç¯ç §å°ãã¢ãŸãã¡ãŒã¿ãŒäžã§è¡ã€ã
ãšãããçè«éã®çªçŽ ã¬ã¹ã®çºçãèªããããã æ¬çºæã«ãããã第ïŒã®è£œé æ³ã¯ã äžè¬åŒ ãïŒHOR3ïŒaR2 2-aSiOão âŠâŠâŠ(1) ïŒãããR2ãR3ãïœããã³ïœã¯åè¿°ã®éãïŒã§è¡š
ãããããå°ããšãïŒäŸ¡ã®ççŽ ååãä»ããŠã±ã€
çŽ ååã«çµåããæ°Žé žåºãæããç°ç¶ããªãªã«ã¬
ãã·ãããµã³ãšã äžè¬åŒ ïŒãããã¯åè¿°ã®éããR4ã¯ççŽ æ°ïŒã10ã®ã¢
ã«ãã«åºã瀺ãïŒã§è¡šããããã¢ãžãåè³éŠæã«
ã«ãã³é žã¢ã«ãã«ãšã¹ãã« ãåå¿ãããããšãç¹åŸŽãšããã äžè¬åŒ(1)ã§è¡šããããæ°Žé žåºãæããããªãªã«
ã¬ãã·ãããµã³ã«ã€ããŠã¯ã第ïŒã®è£œé æ³ã§è§Šã
ãéãã§ããã äžè¬åŒ(3)ã§è¡šããããã¢ãžãåè³éŠæã«ã«ãã³
é žã¢ã«ãã«ãšã¹ãã«ã®äŸãšããŠã¯ãåèšäžè¬åŒ(2)
ã§è¡šããããã¢ãžãåè³éŠæé žå¡©åç©ã«å¯Ÿå¿ãã
é žã®ã¡ãã«ãšã¹ãã«ãšããšãã«ãšã¹ãã«ãããã
ã«ãšã¹ãã«ãã€ãœãããã«ãšã¹ãã«ãªã©ãããã«
å ·äœçã«ã¯ãïœâã¢ãžãå®æ¯éŠé žã¡ãã«ãïœâã¢
ãžãå®æ¯éŠé žãšãã«ãïœâã¢ãžãâïœâã¡ãã«å®
æ¯éŠé žã¡ãã«ãªã©ãæããããã ã¢ãžãåºå«æç°ç¶ããªãªã«ã¬ãã·ãããµã³ã®å
æã¯äžè¬åŒ(1)ã§è¡šããããã·ãããµã³ãšäžè¬åŒ(3)
ã§è¡šãããããšã¹ãã«ããã®ãšã¹ãã«äº€æåå¿ã«
ãã€ãŠè¡ããããäžè¬åŒ(1)ã«æŒããæ°Žé žåºïŒåã«
察ããŠäžè¬åŒ(3)ã§è¡šãããããšã¹ãã«ã奜ãŸãã
ã¯å®è³ªäžïŒåã«ãªãããã«ã溶å€äžã§äžè¬åŒ(1)ã§
è¡šããããã·ãããµã³ãšäžè¬åŒ(3)ã§è¡šãããããš
ã¹ãã«ãé åããã溶å€ãšããŠã¯ãã«ãšã³ããã·
ã¬ã³ãç³æ²¹ç³»æº¶å€ããã³ã¡ãã«ãšãã«ã±ãã³ãªã©
ããéžã°ããææ©æº¶å€ãçšãããããåå¿æž©åºŠã¯
100ã150âã®éãããããã¢ãžãååç©ã®å解枩
床ãäœããšãã¯ããã®æž©åºŠä»¥äžã§ãªããã°ãªããª
ããåå¿ã®éã«ãåå¿ãä¿é²ããããã«ãé ¢é žäº
éããªã¯ãã«é žäºéã®ãããªéå±èèªé žå¡©ãæ·»å
ããããšã奜ãŸããã溶å€ã®éæµäžã«åå¿ãè¡ã€
ãŠãçæããã¢ã«ã³ãŒã«çå»ããŠããã®ãå®éç
ã§ãããåå¿çµäºåŸã溶å€ãçå»ããæªåå¿ç©ã
åå¥ã«ãã€ãŠé€å»ããã°ãç®çãšããã¢ãžãåºå«
æç°ç¶ããªãªã«ã¬ãã·ãããµã³ãåŸãããã æ¬çºæã«ãããã第ïŒã®è£œé æ³ã¯ã äžè¬åŒ ãaR2 2-aSiOão âŠâŠâŠ(4) ïŒãããR2ãïœããã³ïœã¯åè¿°ã®éãïŒã§è¡šãã
ãããã±ã€çŽ ååã«çµåããæ°ŽçŽ ååãæããç°
ç¶ããªãªã«ã¬ãã·ãããµã³ãšã äžè¬åŒ ïŒãããã¯åè¿°ã®éããã¯ççŽ æ°ïŒã10ã®ã¢
ã«ã±ãã«åºã瀺ãïŒã§è¡šããããã¢ãžãåè³éŠæ
ã«ã«ãã³é žã¢ã«ã±ãã«ãšã¹ãã« ãåå¿ãããããšãç¹åŸŽãšããã äžè¬åŒ(4)ã§è¡šããããã±ã€çŽ ååã«çµåããæ°Ž
çŽ ååãå«æããç°ç¶ããªãªã«ã¬ãã·ãããµã³ã®
äŸãšããŠã¯ãããªã¡ãã«ã·ã¯ãããªã·ãããµã³ã®
ãããªç°ç¶ããªã·ãããµã³ãããã¿ã¡ãã«ã·ã¯ã
ããã©ã·ãããµã³ããããµã¡ãã«ã·ã¯ãããã©ã·
ãããµã³ããã³ã¿ã¡ãã«ã·ã¯ãããã©ã·ãããµ
ã³ãããã©ã¡ãã«ã·ã¯ãããã©ã·ãããµã³ããã
ã©ã¡ãã«ãžããã«ã·ã¯ãããã©ã·ãããµã³ããã
ã©ã¡ãã«ããã«ã·ã¯ãããã©ã·ãããµã³ãããã©
ã¡ãã«ãžããã·ã«ã¯ãããã©ã·ãããµã³ãããã©
ã¡ãã«ããã·ã«ã·ã¯ãããã©ã·ãããµã³ã®ãããª
ç°ç¶ããã©ã·ãããµã³ããã³ã¿ã¡ãã«ã·ã¯ããã³
ã¿ã·ãããµã³ããã³ã¿ã¡ãã«ãžããã·ã«ã·ã¯ãã
ã³ã¿ã·ãããµã³ã®ãããªç°ç¶ãã³ã¿ã·ãããµã³ã
ããã äžè¬åŒ(5)ã§è¡šããããã¢ãžãåè³éŠæã«ã«ãã³
é žã¢ã«ã±ãã«ãšã¹ãã«ã®äŸãšããŠã¯ãåèšäžè¬åŒ
(2)ã§è¡šããããã¢ãžãåè³éŠæé žå¡©åç©ã«å¯Ÿå¿ã
ãé žã®ããã«ãšã¹ãã«ãããããã«ãšã¹ãã«ãã
ããã«ãšã¹ãã«ãããã»ãã«ãšã¹ãã«ãªã©ãæã
ãããããã«å ·äœçã«ã¯ãïœâã¢ãžãå®æ¯éŠé žã
ãã«ãïœâã¢ãžãå®æ¯éŠé žããããã«ãïœâã¢ãž
ãâïœâã¡ãã«å®æ¯éŠé žããããã«ãªã©ãæãã
ããã ã¢ãžãåºå«æç°ç¶ããªãªã«ã¬ãã·ãããµã³ã®å
æã¯ãäžè¬åŒ(4)ã§è¡šããããã·ãããµã³äžè¬åŒ(5)
ã§è¡šããããã¢ã«ã±ãã«ãšã¹ãã«ããã®ãããã·
ãªã«ååå¿ã«ãã€ãŠè¡ããããSiâçµåïŒåã«
察ããŠãäžè¬åŒ(5)ã®ã¢ã«ã±ãã«ãšã¹ãã«ã奜ãŸã
ãã¯å®è³ªäžïŒåã®å²åã«ãªãããã«é åããçå
æ°ŽçŽ æº¶å€äžã§ãã«ãŒãã³æ æçœéãå¡©åçœéé žã
ãã³ãã®é¯äœã®ãããªãçœé系觊åªã®ååšäžã«å
å¿ãè¡ããåå¿æž©åºŠã¯100ã150âãé©ããŠãã
ããã¢ãžãååç©ã®å解枩床ãäœããšãã¯ããã®
枩床以äžã§ãªããã°ãªããªããåå¿çµäºåŸã觊åª
ãå¥ãªããæ°ŽæŽé€å»ãã溶å€ãçå»ããã°ãç®
çç©ã§ããã¢ãžãåºå«æç°ç¶ããªãªã«ã¬ãã·ãã
ãµã³ãåŸãããšãã§ããã ãããã®è£œé æ³ã«ãããã¢ãžãåºå«æç°ç¶ããª
ãªã«ã¬ãã·ãããµã³ãåŸãããšãã§ãããããã
ã®è£œé æ³ãæ¯èŒãããšã第ïŒã®è£œé æ³ã§ãããšã¹
ãã«åæ³ã¯ãåå¿ãæ¯èŒçäœæž©ãçæéã§èµ·ã
ãã奜åéã§ç®çãšããã¢ãžãåºå«æç°ç¶ããªãª
ã«ã¬ãã·ãããµã³ãåŸãããããšãæªåå¿ç©ã®é€
å»ã容æã§ããããšãåå¿æž©åºŠãäœããã¢ãžãåº
ã®å解ãã»ãšãã©ãªãããšãåæããªã·ãããµã³
ã®ææ©åºãä»»æã«éžã¹ãããšãªã©ã®å©ç¹ãããã
第ïŒã®è£œé æ³ã§ãããšã¹ãã«äº€ææ³ã¯ã第ïŒã®è£œ
é æ³ã«æ¯ã¹ãŠããåå¿æž©åºŠãé«ãããè±ã¢ã«ã³ãŒ
ã«ã«ãã€ãŠæ¯èŒç奜åçã§ç®çç©ãåŸãããã
ãšãå¿ èŠãšããåæããã¹ãŠå®¹æã«åŸãããã
ãšãããªãžã³ã®ãããªé«äŸ¡ãªæº¶å€ãå¿ èŠãšããªã
ããšãªã©ã®å©ç¹ãããã第ïŒã®è£œé æ³ã§ãããã
ãã·ãªã«åæ³ã¯ãåå¿æž©åºŠãé«ãããšãR3ãšã
ãŠççŽ æ°ïŒã®ãã®ãåŸãããªãããšãªã©ã®äžå©ãª
ç¹ã¯ããããåæããªãªã«ã¬ãã·ãããµã³ãšã
ãŠãæãäžè¬åŒãªãã®ã®äžã€ã§ãããã±ã€çŽ åå
ã«çµåããæ°ŽçŽ ååããã€ç°ç¶ããªãªã«ã¬ãã·ã
ããµã³ããã®ãŸãŸçšãåŸãå©ç¹ãããã æ¬çºæã«ããæ°èŠç©è³ªã§ããã¢ãžãåºå«æç°ç¶
ããªãªã«ã¬ãã·ãããµã³ã¯ã溶å€ã«æº¶è§£ããå¿ èŠ
ã«å¿ããŠå¢æå€ããã³ïŒãŸãã¯ããã«åºå«æããª
ãªã«ã¬ãã·ãããµã³ãæ·»å ããããšã«ããããã
ããæå æ§çµæç©ãåŸãããšãã§ãããããªã
ã¡ãæå å€ãåºããªããŒããåé¢ãçµæ¶åããã
ãšããªãã®ã§ã次ã®ãããªå©ç¹ãããã 補ç
å·¥çšãç°¡åã§ããã å®å®æ§ã«ããããä¿åæ§
ãè¯ãã æ床ãé«ãã çŸåæ§ãè¯ãã
å 硬åéšãšæ¯æäœãšã®æ¥çæ§ããå 硬åéšã®æ©
械ç匷床ãããããŠããããŸããæ¬çºæã®çµæç©
ã¯ãã¢ã¯ãªã«ç³»æå æã«ãããã®ã«æ¯ã¹ãŠããæ§
é ãç°¡åã§è£œçã容æã§ãããæå æ§ã®æç¶æ§ã«
ããããææžè¡°ããªããé žçŽ ãé®æããããã®ä¿
è·å±€ãèšããå¿ èŠããªããããã«ãçŽéç¶ã®ã¢ãž
ãåããªãªã«ã¬ãã·ãããµã³ãçšããæ¹æ³ã«æ¯ã¹
ãŠã解ååã«ããããæå å±€ã®åããå¢ããŠã解
ååãè¯ãããã®äžã€ã³ãå¥é¢æ§ãè溶å€æ§ãã
ãããŠããã®ã§ãäžèšã®æå å±€ãåããåŸãããš
ãšçžãŸã€ãŠãèå·åãäžæ®µãšæ¹åãããŠããã ãã®ããã«ãæ¬çºæã®æ°èŠç©è³ªããã³è£œé æ³
ã¯ãããããå¹³çå°å·æ¹æ³ãæäŸãããã®ã§ã
ããããã«æ¬çºæã®çµæç©ã®çšéã¯ãå¹³çå°å·ã«
éå®ããããã®ã§ã¯ãªãããã®ããããæå ç¹æ§
ãçãããŠãå 硬åæ§ã®å¡èãçŽãã®ä»ã®åºæã«
äžããããšãã°ããã®é¢åæ§ãå©çšããå¥é¢çšå¡
èãšããŠçšããããšãã§ããã 以äžãæ¬çºæã®å®æœäŸã瀺ããå®æœäŸã«ãã
ãŠãéšã¯ãã¹ãŠéééšãè¡šããã å®æœäŸ ïŒ ïœâã¢ãžãå®æ¯éŠé žã¯ãã©ã€ã54éšã«ããªãžã³
200éšãå ããã€ãã§åŒ ã§è¡šããããç°ç¶ããªãªã«ã¬ãã·ãããµã³43éšã
å ããŠååã«æ¹æãè¡ããåäžãªæº¶æ¶²ãšãããã
ãã80âã«ææž©ããŠïŒæéã®å ç±æ¹äŒŽãè¡ããšã
å¡©åæ°ŽçŽ ã®ããªãžã³å¡©ãçºçãã€ã€åå¿ãé²è¡ã
ãããã®åå¿ç©ã1000éšã®æ°Žã«æ»Žäžãããšãå¡©å
æ°ŽçŽ ããªãžã³å¡©ãšæªåå¿ã®ïœâã¢ãžãå®æ¯éŠé žã¯
ãã©ã€ãã¯æ°Žã«æº¶ããåå¿çæç©ãæ°Žã«äžæº¶æ§ã®
æš¹èç¶ç©ãšããŠåŸãããããããããªãžã³èããª
ããªããŸã§ååã«æŽæ»ããã®ã¡ã20éšã¢ã»ãã³ã«
溶ãããåã³æ°Žãå ããŠçæç©ãæåºããããã
ç¡æ°Žç¡«é žãœãŒãã§è±æ°Žããæ®åããã¢ã»ãã³ããš
ããã¬ãŒã¿ãŒã§çå»ããŠãæ·¡é»è²ã®ç²çš ãªæš¹èç¶
ã®ã¢ãžãåºå«æç°ç¶ããªãªã«ã¬ãã·ãããµã³75éš
ãåŸãããã㯠ãšããŠçè«åéã®87ïŒ ã§ãã€ãããã®ãã®ã®èµ€å€
åå ã¹ãã¯ãã«ããåæç°ç¶ããªãªã«ã¬ãã·ãã
ãµã³ãšæ¯èŒããŠç¬¬ïŒå³ã«ç€ºããåå¿ã«ãã€ãŠãæ°Ž
é žåºã«åºã¥ã3400cm-1ã®åžåãæ¶æ» ãããšã¹ãã«
çµåã«åºã¥ã1735cm-1ã®åžåãšãã¢ãžãåºã«åºã¥
ã1300cm-1ããã³2150cm-1ã®åžåãèªããããã
ãŸããçæç©ã®å çŽ åæããã³æ°·ç¹éäžæ³ã«ãã€
ãŠåŸãããååéã¯ç¬¬ïŒè¡šã®éãã§ãåèšã¢ãžã
åºå«æç°ç¶ããªãªã«ã¬ãã·ãããµã³ã®çè«å€ãšã
ãäžèŽããããŸããããã0.1ïŒ ã®ãã³ãŒã³æº¶æ¶²
ã«ããŠã¢ãŸãã¡ãŒã¿ãŒã«å ¥ããŠé«å§æ°Žéç¯ã«ãã
玫å€ç·ç §å°ãè¡ããçºçããçªçŽ ã¬ã¹ã®éã容é
åæãããšããã9.5ééïŒ ã®çªçŽ ã¬ã¹ã®çºçã
ã¿ããããã¯14.3ééïŒ ã®ã¢ãžãåºã®ååšã«çžåœ
ããçè«é14.59ïŒ ãšã»ãäžèŽããããããã®ã
ãšãããåå¿çæç©ã¯åŒ ã§ããããšã確èªãããã玫å€ç·ç §å°ã«ãã€ãŠç
æããç®èã®èµ€å€åå ã¹ãã¯ãã«ã第ïŒå³ã«èšã
ããã¢ãžãåºã«åºã¥ãåžåãæžå°ããŠããããšã
èªããããã
ãè¡šã
åèäŸ ïŒ
å®æœäŸïŒã§åæããã¢ãžãåºå«æããªãªã«ã¬ã
ã·ãããµã³10éšãå¹³åååéã40000ã§å«ææ©åº
äžã®ïŒã¢ã«ïŒ ãããã«åºã§ããããªã¡ãã«ããã«
ã·ãããµã³40éšãïŒâãããã¢ã»ãããã³ïŒéšã
ãã«ãšã³800éšã®æ··å液ãæ·»å ããŠæå æ§çµæç©
ã調補ããããã®çµæç©ãããã©ã·ç 磚ããã¢ã«
ãæ¿ã«å転å¡åžãã也ç¥ããŠåãïŒÎŒã®æå å±€ã
圢æããããã®äžã«ããžãã€ã«ã ãå¯çãã
3KWã®é«å§æ°Žéç¯ã§ïŒåéé²å ããã®ã¡ããã·
ã¬ã³ã§æªé²å éšåã®çµæç©ãæŽãæµããããã«æº¶
å€ãé€å»ãã也ç¥åŸã150âãïŒåéã®å ç±ãè¡
ã€ãŠçãåŸãããã®çãã湿ãæ°ŽäŸçµŠè£ 眮ãã¯ã
ããå°å·æ©ã«ã»ããããæ±æŽã€ã³ãæ ªåŒäŒç€Ÿè£œã¹
ããŒããã³ã°âçŽ âã€ã³ããçšããŠ15000æå°å·
ãããšããã解ååã®è¯å¥œãªå°å·ç©ãåŸãããŸ
ããå°å·ã®ååŸã«ãããŠãçã®ç¶æ ã«å€åãã¿ã
ããªãã€ãã å®æœäŸ ïŒ å®æœäŸïŒã® ã®ãããã«ãïŒCH3ïŒïŒHOC3H6ïŒSiOã4ã§è¡šãã
ããç°ç¶ããªãªã«ã¬ãã·ãããµã³35éšãçšããã»
ãã¯ãå®æœäŸïŒãšåæ§ã®åå¿ãè¡ã€ãçµæã86éš
ã®ã¢ãžãåºå«æç°ç¶ããªãªã«ã¬ãã·ãããµã³ ãåŸãããã®ãã®ã¯ãç²çš ãªæ·¡é»è²æš¹èç¶ç©ã§ã
ãã®å çŽ åæããã³æ°·ç¹éäžæ³ã«ããååéã¯ç¬¬
ïŒè¡šã®éãã§ãããçè«å€ãšããäžèŽããŠããã
ã·ãããµã³10éšãå¹³åååéã40000ã§å«ææ©åº
äžã®ïŒã¢ã«ïŒ ãããã«åºã§ããããªã¡ãã«ããã«
ã·ãããµã³40éšãïŒâãããã¢ã»ãããã³ïŒéšã
ãã«ãšã³800éšã®æ··å液ãæ·»å ããŠæå æ§çµæç©
ã調補ããããã®çµæç©ãããã©ã·ç 磚ããã¢ã«
ãæ¿ã«å転å¡åžãã也ç¥ããŠåãïŒÎŒã®æå å±€ã
圢æããããã®äžã«ããžãã€ã«ã ãå¯çãã
3KWã®é«å§æ°Žéç¯ã§ïŒåéé²å ããã®ã¡ããã·
ã¬ã³ã§æªé²å éšåã®çµæç©ãæŽãæµããããã«æº¶
å€ãé€å»ãã也ç¥åŸã150âãïŒåéã®å ç±ãè¡
ã€ãŠçãåŸãããã®çãã湿ãæ°ŽäŸçµŠè£ 眮ãã¯ã
ããå°å·æ©ã«ã»ããããæ±æŽã€ã³ãæ ªåŒäŒç€Ÿè£œã¹
ããŒããã³ã°âçŽ âã€ã³ããçšããŠ15000æå°å·
ãããšããã解ååã®è¯å¥œãªå°å·ç©ãåŸãããŸ
ããå°å·ã®ååŸã«ãããŠãçã®ç¶æ ã«å€åãã¿ã
ããªãã€ãã å®æœäŸ ïŒ å®æœäŸïŒã® ã®ãããã«ãïŒCH3ïŒïŒHOC3H6ïŒSiOã4ã§è¡šãã
ããç°ç¶ããªãªã«ã¬ãã·ãããµã³35éšãçšããã»
ãã¯ãå®æœäŸïŒãšåæ§ã®åå¿ãè¡ã€ãçµæã86éš
ã®ã¢ãžãåºå«æç°ç¶ããªãªã«ã¬ãã·ãããµã³ ãåŸãããã®ãã®ã¯ãç²çš ãªæ·¡é»è²æš¹èç¶ç©ã§ã
ãã®å çŽ åæããã³æ°·ç¹éäžæ³ã«ããååéã¯ç¬¬
ïŒè¡šã®éãã§ãããçè«å€ãšããäžèŽããŠããã
ãè¡šã
å®æœäŸ ïŒ
ãïŒCH3ïŒïŒHOC3H6ïŒSiOã3ã§ç€ºãããç°ç¶ã
ãªãªã«ã¬ãã·ãããµã³36éšãããªãžã³100éšãšã
ã«ãšã³80éšã®æ··å溶å€ã«æº¶ãããïœâã¢ãžãâïœ
âã¡ãã«å®æ¯éŠé žã¯ãã©ã€ã60éšãå ããŠã80â
ã§15æéæ¹æãè¡ã€ãããã®åŸã倧éå°ã®æ°Žã«èœ
ãšããååã«æ°ŽæŽããã®ã¡ã¢ã»ãã³ã«æº¶è§£ããå
ã³æ°Žãå ããŠçæç©ãæåºãããããæåºç©ãã¡
ãã«ãšãã«ã±ãã³ã«æº¶è§£ããç¡æ°Žç¡«é žãããªãŠã
ã§è±æ°Žãè¡ã€ããéåŸãã¡ãã«ãšãã«ã±ãã³ã
æžå§äžã«çå»ããŠãé«ç²æ§æš¹èç¶ã®ã¢ãžãåºå«æ
ç°ç¶ããªãªã«ã¬ãã·ãããµã³ãåŸãããã®ãã®
ã¯ã第ïŒå³ã®ïŒã«ã»ãé¡äŒŒããèµ€å€åå ã¹ãã¯ã
ã«ãåŸãããããšãããåååŒã¯ ãšæšå®ãããã å®æœäŸ ïŒ ã¢ãžãååç©ãšããŠïœâã¢ãžãå®æ¯éŠé žã¯ãã©
ã€ã56éšãç°ç¶ããªãªã«ã¬ãã·ãããµã³ãšããŠ
ãïŒCH3ïŒïŒHOC4H8ïŒSiOã440éšãçšããåå¿æ¡ä»¶
ã70âã12æéãšããã»ãã¯å®æœäŸïŒãšåæ§ã«ã
ãŠåå¿ãè¡ã€ããšããã次ã®åååŒããã€æå æ§
ã®ã¢ãžãåºå«æç°ç¶ããªãªã«ã¬ãã·ãããµã³ãåŸ
ãã å®æœäŸ ïŒ ãïŒCH3ïŒïŒHOC3H6ïŒSiOã4ã§ç€ºãããç°ç¶ã
ãªãªã«ã¬ãã·ãããµã³36éšããã·ã¬ã³200éšã«æº¶
解ããïœâã¢ãžãå®æ¯éŠé žã¡ãã«53éšãå ããé ¢
é žäºé0.1éšãå ããŠããã·ã¬ã³ã®ç°æµäžã«å ç±
ããçæããã¡ã¿ããŒã«ãé€ãã€ã€ãåå¿ã10æ
éç¶ç¶ãããã¡ã¿ããŒã«ã®çåºãèªããããªããª
ã€ãŠãããæžå§äžã«ãã·ã¬ã³ãçå»ããŠãæ·¡è€è²
ç²çš ãªã¢ãžãåºå«æç°ç¶ããªãªã«ã¬ãã·ãããµã³
78éšãåŸãããã®ãã®ã®èµ€å€åå ã¹ãã¯ãã«ã¯ã
å®æœäŸïŒã®çæç©ã®ãããšå šãäžèŽããŠãããæ°·
ç¹éäžæ³ã«ãã€åŸãããååéã¯1040ïŒçè«é
1052ïŒã§ãã€ãŠãååæ§é 㯠ãšå€æãããããã®ãã®ãçšããŠãåèäŸïŒãšå
æ§ã®çµæç©ãäœããã¢ã«ãæ¿ã«å¡åžããŠé«å§æ°Žé
ç¯ã«ããé²å ãè¡ã€ããšãããåæ§ã«è¯å¥œãªä¹ŸåŒ
å¹³æ¿ãåŸãããã å®æœäŸ ïŒ ç°ç¶ããªãªã«ã¬ãã·ãããµã³ãšããŠ25éšã®
ãïŒCH3ïŒïŒHOCH2ïŒSiOã4ãã¢ãžãååç©ãšããŠ
71éšã®ïœâã¢ãžãâïœâãããå®æ¯éŠé žãšãã«ã
çšãã以å€ã¯å®æœäŸïŒãšåæ§ã«åå¿ãè¡ã€ãŠã ãåŸãããã®ãã®ãçŽã«å¡åžããŠçŽ«å€ç·ç §å°ãè¡
ã€ããšãããäžæº¶äžèã®ç®èãåŸãã å®æœäŸ ïŒ ãïŒCH3ïŒHSiOã412éšãç³æ²¹ã¿ãŒãã³160éšã«
溶解ããïœâã¢ãžãå®æ¯éŠé žãããã«43éšã«å
ããïŒééïŒ ã®çœéãã«ãŒãã³ãã©ãã¯ã«æ æã
ãçœéã«ãŒãã³0.2éšãæ·»å ããŠã120âã§24æé
ã®å ç±æ¹æãè¡ã€ããåå¿çµäºåŸè§Šåªãå¥ãã
æžå§äžã«ç³æ²¹ã¿ãŒãã³ãçå»ããŠã52éšã®ç²çš ãª
æš¹èç¶ç©ãåŸãããã®ãã®ã®èµ€å€åžåã¹ãã¯ãã«
ã¯å®æœäŸïŒã§åŸãã¢ãžãåºå«æç°ç¶ããªãªã«ã¬ã
ã·ãããµã³ãšã»ãŒäžèŽãã滲éå§æ³ã§åŸãååé
ã¯1080ïŒçè«é1104ïŒã§ãã€ãããããã®ããšã
ããçæããã¢ãžãåºå«æç°ç¶ããªãªã«ã¬ãã·ã
ããµã³ã¯ã ã§ããããšã確èªãããããããã¢ã«ãæ¿ã«å¡åž
ããŠçŽ«å€ç·ç §å°ãè¡ã€ããšãããè¯å¥œãªå 硬åæ§
ãèªããããã å®æœäŸ ïŒ 20éšãšïœâã¢ãžãâïœâã¡ããã·å®æ¯éŠé žããã
ãã«47éšãç³æ²¹ã¿ãŒãã³200éšã«æº¶è§£ããå¡©åçœ
éé žã®ã€ãœãããã«ã¢ã«ã³ãŒã«æº¶æ¶²ïŒçœéãšããŠ
0.5ééïŒ ïŒ0.2éšãå ããŠ110âã§24æéã®å ç±
æ¹æãè¡ã€ããåå¿çµäºåŸãæ°ŽæŽããŠè§Šåªãé€å»
ããç¡æ°Žç¡«é žãœãŒãã§è±æ°ŽããŠãããæžå§äžã«ç³
æ²¹ã¿ãŒãã³ãçå»ãããšããã65éšã®æ·¡è€è²ã§ç²
çš ãªæ²¹ç¶ç©ãåŸãããã®ãã®ã®åååŒã¯æ¬¡ã®éã
ã§ãã€ãã
ãªãªã«ã¬ãã·ãããµã³36éšãããªãžã³100éšãšã
ã«ãšã³80éšã®æ··å溶å€ã«æº¶ãããïœâã¢ãžãâïœ
âã¡ãã«å®æ¯éŠé žã¯ãã©ã€ã60éšãå ããŠã80â
ã§15æéæ¹æãè¡ã€ãããã®åŸã倧éå°ã®æ°Žã«èœ
ãšããååã«æ°ŽæŽããã®ã¡ã¢ã»ãã³ã«æº¶è§£ããå
ã³æ°Žãå ããŠçæç©ãæåºãããããæåºç©ãã¡
ãã«ãšãã«ã±ãã³ã«æº¶è§£ããç¡æ°Žç¡«é žãããªãŠã
ã§è±æ°Žãè¡ã€ããéåŸãã¡ãã«ãšãã«ã±ãã³ã
æžå§äžã«çå»ããŠãé«ç²æ§æš¹èç¶ã®ã¢ãžãåºå«æ
ç°ç¶ããªãªã«ã¬ãã·ãããµã³ãåŸãããã®ãã®
ã¯ã第ïŒå³ã®ïŒã«ã»ãé¡äŒŒããèµ€å€åå ã¹ãã¯ã
ã«ãåŸãããããšãããåååŒã¯ ãšæšå®ãããã å®æœäŸ ïŒ ã¢ãžãååç©ãšããŠïœâã¢ãžãå®æ¯éŠé žã¯ãã©
ã€ã56éšãç°ç¶ããªãªã«ã¬ãã·ãããµã³ãšããŠ
ãïŒCH3ïŒïŒHOC4H8ïŒSiOã440éšãçšããåå¿æ¡ä»¶
ã70âã12æéãšããã»ãã¯å®æœäŸïŒãšåæ§ã«ã
ãŠåå¿ãè¡ã€ããšããã次ã®åååŒããã€æå æ§
ã®ã¢ãžãåºå«æç°ç¶ããªãªã«ã¬ãã·ãããµã³ãåŸ
ãã å®æœäŸ ïŒ ãïŒCH3ïŒïŒHOC3H6ïŒSiOã4ã§ç€ºãããç°ç¶ã
ãªãªã«ã¬ãã·ãããµã³36éšããã·ã¬ã³200éšã«æº¶
解ããïœâã¢ãžãå®æ¯éŠé žã¡ãã«53éšãå ããé ¢
é žäºé0.1éšãå ããŠããã·ã¬ã³ã®ç°æµäžã«å ç±
ããçæããã¡ã¿ããŒã«ãé€ãã€ã€ãåå¿ã10æ
éç¶ç¶ãããã¡ã¿ããŒã«ã®çåºãèªããããªããª
ã€ãŠãããæžå§äžã«ãã·ã¬ã³ãçå»ããŠãæ·¡è€è²
ç²çš ãªã¢ãžãåºå«æç°ç¶ããªãªã«ã¬ãã·ãããµã³
78éšãåŸãããã®ãã®ã®èµ€å€åå ã¹ãã¯ãã«ã¯ã
å®æœäŸïŒã®çæç©ã®ãããšå šãäžèŽããŠãããæ°·
ç¹éäžæ³ã«ãã€åŸãããååéã¯1040ïŒçè«é
1052ïŒã§ãã€ãŠãååæ§é 㯠ãšå€æãããããã®ãã®ãçšããŠãåèäŸïŒãšå
æ§ã®çµæç©ãäœããã¢ã«ãæ¿ã«å¡åžããŠé«å§æ°Žé
ç¯ã«ããé²å ãè¡ã€ããšãããåæ§ã«è¯å¥œãªä¹ŸåŒ
å¹³æ¿ãåŸãããã å®æœäŸ ïŒ ç°ç¶ããªãªã«ã¬ãã·ãããµã³ãšããŠ25éšã®
ãïŒCH3ïŒïŒHOCH2ïŒSiOã4ãã¢ãžãååç©ãšããŠ
71éšã®ïœâã¢ãžãâïœâãããå®æ¯éŠé žãšãã«ã
çšãã以å€ã¯å®æœäŸïŒãšåæ§ã«åå¿ãè¡ã€ãŠã ãåŸãããã®ãã®ãçŽã«å¡åžããŠçŽ«å€ç·ç §å°ãè¡
ã€ããšãããäžæº¶äžèã®ç®èãåŸãã å®æœäŸ ïŒ ãïŒCH3ïŒHSiOã412éšãç³æ²¹ã¿ãŒãã³160éšã«
溶解ããïœâã¢ãžãå®æ¯éŠé žãããã«43éšã«å
ããïŒééïŒ ã®çœéãã«ãŒãã³ãã©ãã¯ã«æ æã
ãçœéã«ãŒãã³0.2éšãæ·»å ããŠã120âã§24æé
ã®å ç±æ¹æãè¡ã€ããåå¿çµäºåŸè§Šåªãå¥ãã
æžå§äžã«ç³æ²¹ã¿ãŒãã³ãçå»ããŠã52éšã®ç²çš ãª
æš¹èç¶ç©ãåŸãããã®ãã®ã®èµ€å€åžåã¹ãã¯ãã«
ã¯å®æœäŸïŒã§åŸãã¢ãžãåºå«æç°ç¶ããªãªã«ã¬ã
ã·ãããµã³ãšã»ãŒäžèŽãã滲éå§æ³ã§åŸãååé
ã¯1080ïŒçè«é1104ïŒã§ãã€ãããããã®ããšã
ããçæããã¢ãžãåºå«æç°ç¶ããªãªã«ã¬ãã·ã
ããµã³ã¯ã ã§ããããšã確èªãããããããã¢ã«ãæ¿ã«å¡åž
ããŠçŽ«å€ç·ç §å°ãè¡ã€ããšãããè¯å¥œãªå 硬åæ§
ãèªããããã å®æœäŸ ïŒ 20éšãšïœâã¢ãžãâïœâã¡ããã·å®æ¯éŠé žããã
ãã«47éšãç³æ²¹ã¿ãŒãã³200éšã«æº¶è§£ããå¡©åçœ
éé žã®ã€ãœãããã«ã¢ã«ã³ãŒã«æº¶æ¶²ïŒçœéãšããŠ
0.5ééïŒ ïŒ0.2éšãå ããŠ110âã§24æéã®å ç±
æ¹æãè¡ã€ããåå¿çµäºåŸãæ°ŽæŽããŠè§Šåªãé€å»
ããç¡æ°Žç¡«é žãœãŒãã§è±æ°ŽããŠãããæžå§äžã«ç³
æ²¹ã¿ãŒãã³ãçå»ãããšããã65éšã®æ·¡è€è²ã§ç²
çš ãªæ²¹ç¶ç©ãåŸãããã®ãã®ã®åååŒã¯æ¬¡ã®éã
ã§ãã€ãã
第ïŒå³ã¯ãäžèšããªã·ãããµã³ã®èµ€å€åžåã¹ã
ã¯ãã«ã瀺ãã ïŒïŒãïŒCH3ïŒïŒHOC3H6ïŒSiOã3ãïŒCH3ïŒ
SiOããïŒïŒåå¿çæç© ãïŒïŒïŒã«é«å§æ°Žéç¯ãç §å°ããã®ã¡ã®ç¡¬åããª
ã·ãããµã³ã
ã¯ãã«ã瀺ãã ïŒïŒãïŒCH3ïŒïŒHOC3H6ïŒSiOã3ãïŒCH3ïŒ
SiOããïŒïŒåå¿çæç© ãïŒïŒïŒã«é«å§æ°Žéç¯ãç §å°ããã®ã¡ã®ç¡¬åããª
ã·ãããµã³ã
Claims (1)
- ãç¹èš±è«æ±ã®ç¯å²ã ïŒ äžè¬åŒ ãR1 aR2 2-aSiOão ïŒãã ãR1ã¯äžè¬åŒãåŒãã§ç€º ããããççŽ ååã«ãã€ãŠã±ã€çŽ ååã«çµåãã
ïŒäŸ¡ã®ã¢ãžãåºå«æææ©åºãã¯æ°ŽçŽ ååãã¢ã«
ãã«åºãã¢ã«ã³ãã·åºããããåºããã³ããã²ã³
ååããéžã°ããïŒäŸ¡ã®åºãR2ã¯ïŒäŸ¡ã®çåæ°Ž
çŽ åºãR3ã¯ïŒäŸ¡ã®èèªæ飜åçåæ°ŽçŽ åºãïœã¯
ïŒä»¥äžã®æ£ã®æ°ãïœã¯ïŒãïŒã瀺ãïŒã§è¡šããã
ãã¢ãžãåºå«æç°ç¶ããªãªã«ã¬ãã·ãããµã³ã ïŒ ïœãïŒã§ãããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé èšèŒã®
ã·ãããµã³ã ïŒ R1ã®ã¢ãžãåºãã«ã«ããã·ã«åºã«å¯ŸããŠã
ã©äœçœ®ã«ãããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé èšèŒã®ã·ã
ããµã³ã ïŒ R2ãã¡ãã«åºã§ãããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒ
é èšèŒã®ã·ãããµã³ã ïŒ R3ããããã¬ã³åºã§ãããç¹èš±è«æ±ã®ç¯å²
第ïŒé èšèŒã®ã·ãããµã³ã ïŒ äžè¬åŒ ãïŒHOR3ïŒaR2 2-aSiOão âŠâŠâŠ(1) ïŒãã ãR2ã¯ïŒäŸ¡ã®çåæ°ŽçŽ åºãR3ã¯ïŒäŸ¡ã®èèª
æ飜åçåæ°ŽçŽ åºãïœã¯ïŒä»¥äžã®æ£ã®æ°ãïœã¯ïŒ
ãïŒã瀺ãïŒã§è¡šãããããå°ããšãïŒåã®ççŽ
ååãä»ããŠã±ã€çŽ ååã«çµåããæ°Žé žåºãæã
ãç°ç¶ããªãªã«ã¬ãã·ãããµã³ãšã äžè¬åŒ ïŒãã ãã¯æ°ŽçŽ ååãã¢ã«ãã«åºãã¢ã«ã³ãã·
åºããããåºããã³ããã²ã³ååããéžã°ããïŒ
䟡ã®åºã瀺ãïŒã§è¡šããããã¢ãžãåè³éŠæé žå¡©
åç© ãåå¿ãããããšãç¹åŸŽãšãããäžè¬åŒ ãR1 aR2 2-aSiOão ïŒãã ãR1ã¯äžè¬åŒãåŒãã§ç€º ããããççŽ ååã«ãã€ãŠã±ã€çŽ ååã«çµåãã
ïŒäŸ¡ã®ã¢ãžãåºå«æææ©åºã瀺ããR2ãïœã
ïœãR3ããã³ïŒ¹ã¯åè¿°ã®éãïŒã§è¡šããããã
ã¢ãžãåºå«æç°ç¶ããªãªã«ã¬ãã·ãããµã³ã®è£œé
æ³ã ïŒ äžè¬åŒ ãïŒHOR3ïŒaR2 2-aSiOão âŠâŠâŠ(1) ïŒãã ãR2ã¯ïŒäŸ¡ã®çåæ°ŽçŽ åºãR3ã¯ïŒäŸ¡ã®èèª
æ飜åçåæ°ŽçŽ åºãïœã¯ïŒä»¥äžã®æ£ã®æ°ãïœã¯ïŒ
ãïŒã瀺ãïŒã§è¡šãããããå°ããšãïŒåã®ççŽ
ååãä»ããŠã±ã€çŽ ååã«çµåããæ°Žé žåºãæã
ãç°ç¶ããªãªã«ã¬ãã·ãããµã³ãšã äžè¬åŒ ïŒãã ãã¯æ°ŽçŽ ååãã¢ã«ãã«åºãã¢ã«ã³ãã·
åºããããåºããã³ããã²ã³ååããéžã°ããïŒ
䟡ã®åºãR4ã¯ççŽ æ°ïŒã10ã®ã¢ã«ãã«åºã瀺
ãïŒã§è¡šããããã¢ãžãåè³éŠæã«ã«ãã³é žã¢ã«
ãã«ãšã¹ãã« ãåå¿ãããããšãç¹åŸŽãšãããäžè¬åŒ ãR1 aR2 2-aSiOão ïŒãã ãR1ã¯äžè¬åŒãåŒãã§ç€º ããããççŽ ååã«ãã€ãŠã±ã€çŽ ååã«çµåãã
ïŒäŸ¡ã®ã¢ãžãåºå«æææ©åºã瀺ããR2ãïœã
ïœãR3ããã³ïŒ¹ã¯åè¿°ã®éãïŒã§è¡šããããã¢
ãžãåºå«æç°ç¶ããªãªã«ã¬ãã·ãããµã³ã®è£œé
æ³ã ïŒ äžè¬åŒ ãaR2 2-aSiOão âŠâŠâŠ(4) ïŒãã ãR2ã¯ïŒäŸ¡ã®çåæ°ŽçŽ åºãïœã¯ïŒä»¥äžã®æ£
ã®æ°ãïœã¯ïŒãïŒã瀺ãïŒã§è¡šãããããã±ã€çŽ
ååã«çµåããæ°ŽçŽ ååãæããç°ç¶ããªãªã«ã¬
ãã·ãããµã³ãšã äžè¬åŒ ïŒãã ãã¯æ°ŽçŽ ååãã¢ã«ãã«åºãã¢ã«ã³ãã·
åºããããåºããã³ããã²ã³ååããéžã°ããïŒ
䟡ã®åºãã¯ççŽ æ°ïŒã10ã®ã¢ã«ã±ãã«åºã瀺
ãïŒã§è¡šããããã¢ãžãåè³éŠæã«ã«ãã³é žã¢ã«
ã±ãã«ãšã¹ãã« ãåå¿ãããããšãç¹åŸŽãšãããäžè¬åŒ ãR1 aR2 2-aSiOão ïŒãã ãR1ã¯äžè¬åŒãåŒãã§ç€º ããããççŽ ååã«ãã€ãŠã±ã€çŽ ååã«çµåãã
ïŒäŸ¡ã®ã¢ãžãåºå«æææ©åºã瀺ããR3ã¯ïŒäŸ¡ã®
èèªæ飜åçåæ°ŽçŽ åºã瀺ããR2ãïœãïœãã
ãã³ïŒ¹ã¯åè¿°ã®éãïŒã§è¡šããããã¢ãžãåºå«æ
ç°ç¶ããªãªã«ã¬ãã·ãããµã³ã®è£œé æ³ã
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP9668477A JPS5430300A (en) | 1977-08-12 | 1977-08-12 | Azide grouppcontaining cyclic polyorganosiloxane and preparation thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP9668477A JPS5430300A (en) | 1977-08-12 | 1977-08-12 | Azide grouppcontaining cyclic polyorganosiloxane and preparation thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS5430300A JPS5430300A (en) | 1979-03-06 |
| JPS6137276B2 true JPS6137276B2 (ja) | 1986-08-22 |
Family
ID=14171608
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP9668477A Granted JPS5430300A (en) | 1977-08-12 | 1977-08-12 | Azide grouppcontaining cyclic polyorganosiloxane and preparation thereof |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS5430300A (ja) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7105622B2 (en) * | 2004-06-02 | 2006-09-12 | The University Of Akron | Hybrid polyurethanes |
| KR102149134B1 (ko) * | 2013-03-29 | 2020-08-28 | ìŽë°ë¯žì° ê³ ì° ê°ë¶ìí€ê°ìŽì€ | íŽëŠ¬ì€ë¥Žê°ë žì€ë¡ì° ë° íŽëŠ¬ì¹Žë³Žë€ìŽíž-íŽëŠ¬ì€ë¥Žê°ë žì€ë¡ì° ê³µì€í©ì²Ž |
-
1977
- 1977-08-12 JP JP9668477A patent/JPS5430300A/ja active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| JPS5430300A (en) | 1979-03-06 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| EP0725106B1 (en) | Radiation curable compositions | |
| US6258506B1 (en) | Ultraviolet-curable polysiloxane composition and method for the formation of cured patterns therefrom | |
| DE2246020C3 (de) | Verfahren zur Herstellung von ReliefoberflÀchen und Verwendung des Verfahrens zur Herstellung von Druckformen | |
| US5017453A (en) | A silicone resist materials containing a polysiloxane and a photo-sensitive agent | |
| US4042613A (en) | Benzophenone derivatives and their preparation and application | |
| US6902875B2 (en) | Photosensitive polysilazane composition, method of forming pattern therefrom, and method of burning coating film thereof | |
| JPS596222A (ja) | ãªã«ã¬ãããªã·ãããµã³ããã®è£œæ³ããã³é«ãšãã«ã®âæŸå°ç·ã«ãã€ãŠæ©ããå¯èœãªè¢«èã®è£œæ³ | |
| KR980002109A (ko) | ê°êŽì± íŽëŠ¬ìŽë¯žë ì 구첎 ì¡°ì±ë¬Œ, ë° ìŽê²ì ì¬ì©í íšíŽ íì± ë°©ë² | |
| JPS6272711A (ja) | ã¢ã¯ãªã¬âãæ©èœã®ææ©ããªã·ãããµã³çµæç©ããã®çææ¹æ³åã³äœ¿çšæ¹æ³ | |
| JPS6136872B2 (ja) | ||
| CN103781814A (zh) | å åºåæ§æ èç»åç©ä»¥åæ°åç¡ æ°§ç·ååç© | |
| JPH08198882A (ja) | ã·ãªã³ãŒã³çžå®¹æ§å åå¿éå§å€ãããã³ãããå«ãã§ãªãæå æ§æ··åç© | |
| JP2011505448A (ja) | æ°èŠã·ãããµã³ããªããŒçµæç© | |
| FR2472592A1 (fr) | Compositions de polyorganosiloxanes durcissables sous l'action d'un rayonnement | |
| JPS6137276B2 (ja) | ||
| WO2024034385A1 (ja) | ãã§ããŒã«æ§æ°Žé žåºå«æåå²ç¶ãªã«ã¬ãããªã·ãããµã³ã®è£œé æ¹æ³ | |
| JPS62177559A (ja) | 湿ãæ°ŽäžèŠæå æ§å¹³çå°å·ç | |
| KR100316735B1 (ko) | 칎륎볎ë€ìŽíž ìž¡ì륌 í¬íšíë íŽëŠ¬ì믞ë ì€í©ì²Žì ê°êŽì±ëŽìŽì ì°ì²Ž ì¡°ì±ë¬Œ | |
| JPS5811458B2 (ja) | ã¢ãžãåããªãªã«ã¬ãã·ãããµã³ããã³ãã®è£œé æ³ | |
| EP0542485B1 (en) | Radiation curable compositions | |
| JPS6037457B2 (ja) | æå æ§çµæç© | |
| JPS6260418B2 (ja) | ||
| JPS6038692B2 (ja) | æå æ§çµæç© | |
| JPS6038693B2 (ja) | ã¢ãžãåºå«æããªãªã«ã¬ãã·ãããµã³çµæç© | |
| JPH0656491B2 (ja) | æå æ§ã·ãªã³âã³æš¹èçµæç© |