JPS6128074A - 炭素繊維用水性サイジング剤 - Google Patents
炭素繊維用水性サイジング剤Info
- Publication number
- JPS6128074A JPS6128074A JP14517984A JP14517984A JPS6128074A JP S6128074 A JPS6128074 A JP S6128074A JP 14517984 A JP14517984 A JP 14517984A JP 14517984 A JP14517984 A JP 14517984A JP S6128074 A JPS6128074 A JP S6128074A
- Authority
- JP
- Japan
- Prior art keywords
- tables
- formulas
- general formula
- group
- sizing agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229920000049 Carbon (fiber) Polymers 0.000 title claims description 44
- 239000004917 carbon fiber Substances 0.000 title claims description 44
- 239000003795 chemical substances by application Substances 0.000 title claims description 35
- 238000004513 sizing Methods 0.000 title claims description 35
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 title description 13
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 24
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 claims description 12
- 150000001875 compounds Chemical class 0.000 claims description 10
- 229920001281 polyalkylene Polymers 0.000 claims description 10
- 239000000126 substance Substances 0.000 claims description 10
- 239000004593 Epoxy Substances 0.000 claims description 9
- 125000000816 ethylene group Chemical group [H]C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 9
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 8
- 229930185605 Bisphenol Natural products 0.000 claims description 5
- 125000004432 carbon atom Chemical group C* 0.000 claims description 3
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 3
- 125000000217 alkyl group Chemical group 0.000 claims description 2
- 125000002947 alkylene group Chemical group 0.000 claims description 2
- 125000003055 glycidyl group Chemical group C(C1CO1)* 0.000 claims description 2
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 claims description 2
- 125000003342 alkenyl group Chemical group 0.000 claims 1
- 239000002131 composite material Substances 0.000 description 16
- 230000000694 effects Effects 0.000 description 12
- -1 aromatic glycidyl ethers Chemical class 0.000 description 10
- 229920005989 resin Polymers 0.000 description 9
- 239000011347 resin Substances 0.000 description 9
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 8
- 239000011159 matrix material Substances 0.000 description 8
- 239000000203 mixture Substances 0.000 description 8
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 7
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 6
- LCFVJGUPQDGYKZ-UHFFFAOYSA-N Bisphenol A diglycidyl ether Chemical compound C=1C=C(OCC2OC2)C=CC=1C(C)(C)C(C=C1)=CC=C1OCC1CO1 LCFVJGUPQDGYKZ-UHFFFAOYSA-N 0.000 description 6
- 239000000839 emulsion Substances 0.000 description 6
- 239000004480 active ingredient Substances 0.000 description 5
- 239000003995 emulsifying agent Substances 0.000 description 5
- 230000001988 toxicity Effects 0.000 description 5
- 231100000419 toxicity Toxicity 0.000 description 5
- 238000009941 weaving Methods 0.000 description 5
- 238000005299 abrasion Methods 0.000 description 4
- 239000000835 fiber Substances 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 239000003960 organic solvent Substances 0.000 description 4
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 4
- 238000001308 synthesis method Methods 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
- 239000005977 Ethylene Substances 0.000 description 3
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- 239000011229 interlayer Substances 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical group C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 2
- CTKINSOISVBQLD-UHFFFAOYSA-N Glycidol Chemical compound OCC1CO1 CTKINSOISVBQLD-UHFFFAOYSA-N 0.000 description 2
- 238000012644 addition polymerization Methods 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 238000007598 dipping method Methods 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 239000000178 monomer Substances 0.000 description 2
- 239000002736 nonionic surfactant Substances 0.000 description 2
- GSGDTSDELPUTKU-UHFFFAOYSA-N nonoxybenzene Chemical compound CCCCCCCCCOC1=CC=CC=C1 GSGDTSDELPUTKU-UHFFFAOYSA-N 0.000 description 2
- XHXFXVLFKHQFAL-UHFFFAOYSA-N phosphoryl trichloride Chemical compound ClP(Cl)(Cl)=O XHXFXVLFKHQFAL-UHFFFAOYSA-N 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 239000007858 starting material Substances 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- 238000003786 synthesis reaction Methods 0.000 description 2
- SCYULBFZEHDVBN-UHFFFAOYSA-N 1,1-Dichloroethane Chemical compound CC(Cl)Cl SCYULBFZEHDVBN-UHFFFAOYSA-N 0.000 description 1
- CMCBDXRRFKYBDG-UHFFFAOYSA-N 1-dodecoxydodecane Chemical compound CCCCCCCCCCCCOCCCCCCCCCCCC CMCBDXRRFKYBDG-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- BRLQWZUYTZBJKN-UHFFFAOYSA-N Epichlorohydrin Chemical compound ClCC1CO1 BRLQWZUYTZBJKN-UHFFFAOYSA-N 0.000 description 1
- WOBQSJVYSADMHV-UHFFFAOYSA-N NC.FB(F)F Chemical compound NC.FB(F)F WOBQSJVYSADMHV-UHFFFAOYSA-N 0.000 description 1
- 229920000297 Rayon Polymers 0.000 description 1
- LLEMOWNGBBNAJR-UHFFFAOYSA-N biphenyl-2-ol Chemical compound OC1=CC=CC=C1C1=CC=CC=C1 LLEMOWNGBBNAJR-UHFFFAOYSA-N 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- GYZLOYUZLJXAJU-UHFFFAOYSA-N diglycidyl ether Chemical compound C1OC1COCC1CO1 GYZLOYUZLJXAJU-UHFFFAOYSA-N 0.000 description 1
- LIKFHECYJZWXFJ-UHFFFAOYSA-N dimethyldichlorosilane Chemical compound C[Si](C)(Cl)Cl LIKFHECYJZWXFJ-UHFFFAOYSA-N 0.000 description 1
- USIUVYZYUHIAEV-UHFFFAOYSA-N diphenyl ether Chemical class C=1C=CC=CC=1OC1=CC=CC=C1 USIUVYZYUHIAEV-UHFFFAOYSA-N 0.000 description 1
- JRTVEUGOGWTHTR-UHFFFAOYSA-N dodecyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCCCCCCCCCCCC JRTVEUGOGWTHTR-UHFFFAOYSA-N 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 125000003700 epoxy group Chemical group 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 238000009499 grossing Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 229920003986 novolac Polymers 0.000 description 1
- TZXYSEYEGNHPQI-UHFFFAOYSA-N octadecyl dodecanoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CCCCCCCCCCC TZXYSEYEGNHPQI-UHFFFAOYSA-N 0.000 description 1
- BARWIPMJPCRCTP-UHFFFAOYSA-N oleic acid oleyl ester Natural products CCCCCCCCC=CCCCCCCCCOC(=O)CCCCCCCC=CCCCCCCCC BARWIPMJPCRCTP-UHFFFAOYSA-N 0.000 description 1
- BARWIPMJPCRCTP-CLFAGFIQSA-N oleyl oleate Chemical compound CCCCCCCC\C=C/CCCCCCCCOC(=O)CCCCCCC\C=C/CCCCCCCC BARWIPMJPCRCTP-CLFAGFIQSA-N 0.000 description 1
- 230000001151 other effect Effects 0.000 description 1
- 238000007747 plating Methods 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 239000002964 rayon Substances 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- 239000012779 reinforcing material Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000013112 stability test Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 230000001629 suppression Effects 0.000 description 1
- 125000001302 tertiary amino group Chemical group 0.000 description 1
- YMBCJWGVCUEGHA-UHFFFAOYSA-M tetraethylammonium chloride Chemical compound [Cl-].CC[N+](CC)(CC)CC YMBCJWGVCUEGHA-UHFFFAOYSA-M 0.000 description 1
Landscapes
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP14517984A JPS6128074A (ja) | 1984-07-12 | 1984-07-12 | 炭素繊維用水性サイジング剤 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP14517984A JPS6128074A (ja) | 1984-07-12 | 1984-07-12 | 炭素繊維用水性サイジング剤 |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS6128074A true JPS6128074A (ja) | 1986-02-07 |
JPH048542B2 JPH048542B2 (enrdf_load_stackoverflow) | 1992-02-17 |
Family
ID=15379252
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP14517984A Granted JPS6128074A (ja) | 1984-07-12 | 1984-07-12 | 炭素繊維用水性サイジング剤 |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS6128074A (enrdf_load_stackoverflow) |
Cited By (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH01272867A (ja) * | 1988-04-22 | 1989-10-31 | Toray Ind Inc | 高次加工性の優れた炭素繊維 |
US4944932A (en) * | 1985-12-27 | 1990-07-31 | Toray Industries Inc. | Process for producing carbon fiber |
US7094468B2 (en) | 2001-05-25 | 2006-08-22 | Mitsubishi Rayon Co., Ltd. | Sizing agent for carbon fiber, aqueous dispersion thereof, carbon fiber treated by sizing sheet-form object comprising the carbon fiber, and carbon fiber-reinforced coposite material |
US7135516B2 (en) | 2001-07-31 | 2006-11-14 | Mitsubishi Rayon Co., Ltd. | Sizing agent for carbon fiber, method for sizing carbon fiber by said sizing agent, sized carbon fiber and knitted or woven fabric using said carbon fiber |
US7150913B2 (en) | 2001-07-24 | 2006-12-19 | Mitsubishi Rayon Co., Ltd. | Sizing agent for carbon fiber, aqueous dispersion of the same, carbon fiber treated by sizing, sheet comprising the carbon fiber, and carbon fiber-reinforced composite material |
JP2009144303A (ja) * | 2007-12-18 | 2009-07-02 | Mitsubishi Rayon Co Ltd | サイジング剤およびサイジング処理炭素繊維束 |
WO2012002266A1 (ja) | 2010-06-30 | 2012-01-05 | 東レ株式会社 | サイジング剤塗布炭素繊維の製造方法およびサイジング剤塗布炭素繊維 |
WO2013051404A1 (ja) | 2011-10-04 | 2013-04-11 | 東レ株式会社 | 炭素繊維強化熱可塑性樹脂組成物、成形材料、プリプレグ、およびそれらの製造方法 |
WO2013084669A1 (ja) | 2011-12-05 | 2013-06-13 | 東レ株式会社 | 炭素繊維成形素材、成形材料および炭素繊維強化複合材料 |
WO2013099707A1 (ja) | 2011-12-27 | 2013-07-04 | 東レ株式会社 | サイジング剤塗布炭素繊維、サイジング剤塗布炭素繊維の製造方法、プリプレグおよび炭素繊維強化複合材料 |
WO2013172200A1 (ja) | 2012-05-16 | 2013-11-21 | 株式会社ダイセル | エポキシ-アミン付加物、樹脂組成物、サイジング剤、サイジング剤塗布炭素繊維、及び繊維強化複合材料 |
WO2014061336A1 (ja) | 2012-10-18 | 2014-04-24 | 東レ株式会社 | 炭素繊維強化樹脂組成物、炭素繊維強化樹脂組成物の製造方法、成形材料、成形材料の製造方法および炭素繊維強化樹脂成形品 |
KR20200111411A (ko) | 2019-03-19 | 2020-09-29 | 한국과학기술연구원 | 벤젠 고리를 가지는 화합물로 코팅된 탄소섬유의 급속 플라즈마 처리를 통한 표면 처리 방법 및 장치, 이에 따른 탄소 섬유의 물성 향상 방법 및 물성이 향상된 탄소 섬유 |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS50160380A (enrdf_load_stackoverflow) * | 1974-04-27 | 1975-12-25 | ||
JPS5277289A (en) * | 1975-12-19 | 1977-06-29 | Asahi Chemical Ind | Carbon fibre use sizing agent |
-
1984
- 1984-07-12 JP JP14517984A patent/JPS6128074A/ja active Granted
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS50160380A (enrdf_load_stackoverflow) * | 1974-04-27 | 1975-12-25 | ||
JPS5277289A (en) * | 1975-12-19 | 1977-06-29 | Asahi Chemical Ind | Carbon fibre use sizing agent |
Cited By (21)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4944932A (en) * | 1985-12-27 | 1990-07-31 | Toray Industries Inc. | Process for producing carbon fiber |
JPH01272867A (ja) * | 1988-04-22 | 1989-10-31 | Toray Ind Inc | 高次加工性の優れた炭素繊維 |
US7094468B2 (en) | 2001-05-25 | 2006-08-22 | Mitsubishi Rayon Co., Ltd. | Sizing agent for carbon fiber, aqueous dispersion thereof, carbon fiber treated by sizing sheet-form object comprising the carbon fiber, and carbon fiber-reinforced coposite material |
US7150913B2 (en) | 2001-07-24 | 2006-12-19 | Mitsubishi Rayon Co., Ltd. | Sizing agent for carbon fiber, aqueous dispersion of the same, carbon fiber treated by sizing, sheet comprising the carbon fiber, and carbon fiber-reinforced composite material |
US7135516B2 (en) | 2001-07-31 | 2006-11-14 | Mitsubishi Rayon Co., Ltd. | Sizing agent for carbon fiber, method for sizing carbon fiber by said sizing agent, sized carbon fiber and knitted or woven fabric using said carbon fiber |
JP2009144303A (ja) * | 2007-12-18 | 2009-07-02 | Mitsubishi Rayon Co Ltd | サイジング剤およびサイジング処理炭素繊維束 |
WO2012002266A1 (ja) | 2010-06-30 | 2012-01-05 | 東レ株式会社 | サイジング剤塗布炭素繊維の製造方法およびサイジング剤塗布炭素繊維 |
WO2013051404A1 (ja) | 2011-10-04 | 2013-04-11 | 東レ株式会社 | 炭素繊維強化熱可塑性樹脂組成物、成形材料、プリプレグ、およびそれらの製造方法 |
KR20150055089A (ko) | 2011-10-04 | 2015-05-20 | 도레이 카부시키가이샤 | 탄소 섬유 강화 열가소성 수지 조성물, 성형 재료, 프리프레그, 및 이들의 제조 방법 |
WO2013084669A1 (ja) | 2011-12-05 | 2013-06-13 | 東レ株式会社 | 炭素繊維成形素材、成形材料および炭素繊維強化複合材料 |
US10184034B2 (en) | 2011-12-05 | 2019-01-22 | Toray Industries, Inc. | Carbon fiber forming raw material, formed material, and carbon fiber-reinforced composite material |
WO2013099707A1 (ja) | 2011-12-27 | 2013-07-04 | 東レ株式会社 | サイジング剤塗布炭素繊維、サイジング剤塗布炭素繊維の製造方法、プリプレグおよび炭素繊維強化複合材料 |
US10138593B2 (en) | 2011-12-27 | 2018-11-27 | Toray Industries, Inc. | Sizing agent-coated carbon fibers, process for producing sizing agent-coated carbon fibers, prepreg, and carbon fiber reinforced composite material |
WO2013172200A1 (ja) | 2012-05-16 | 2013-11-21 | 株式会社ダイセル | エポキシ-アミン付加物、樹脂組成物、サイジング剤、サイジング剤塗布炭素繊維、及び繊維強化複合材料 |
US9388294B2 (en) | 2012-05-16 | 2016-07-12 | Daicel Corporation | Epoxy-amine adduct, resin composition, sizing agent, carbon fiber coated with sizing agent, and fiber-reinforced composite material |
US9777135B2 (en) | 2012-05-16 | 2017-10-03 | Daicel Corporation | Epoxy-amine adduct, resin composition, sizing agent, carbon fiber coated with sizing agent, and fiber-reinforced composite material |
EP3287478A1 (en) | 2012-05-16 | 2018-02-28 | Daicel Corporation | Epoxy-amine adduct, resin composition, sizing agent, carbon fiber coated with sizing agent, and fiber-reinforced composite material |
KR20150047638A (ko) | 2012-10-18 | 2015-05-04 | 도레이 카부시키가이샤 | 탄소 섬유 강화 수지 조성물, 탄소 섬유 강화 수지 조성물의 제조 방법, 성형 재료, 성형 재료의 제조 방법 및 탄소 섬유 강화 수지 성형품 |
WO2014061336A1 (ja) | 2012-10-18 | 2014-04-24 | 東レ株式会社 | 炭素繊維強化樹脂組成物、炭素繊維強化樹脂組成物の製造方法、成形材料、成形材料の製造方法および炭素繊維強化樹脂成形品 |
US10501605B2 (en) | 2012-10-18 | 2019-12-10 | Toray Industries, Inc. | Carbon fiber-reinforced resin composition, method for manufacturing carbon fiber-reinforced resin composition, molding material, method for manufacturing molding material, and carbon fiber-reinforced resin molded article |
KR20200111411A (ko) | 2019-03-19 | 2020-09-29 | 한국과학기술연구원 | 벤젠 고리를 가지는 화합물로 코팅된 탄소섬유의 급속 플라즈마 처리를 통한 표면 처리 방법 및 장치, 이에 따른 탄소 섬유의 물성 향상 방법 및 물성이 향상된 탄소 섬유 |
Also Published As
Publication number | Publication date |
---|---|
JPH048542B2 (enrdf_load_stackoverflow) | 1992-02-17 |
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