JPS6124675B2 - - Google Patents
Info
- Publication number
- JPS6124675B2 JPS6124675B2 JP50150093A JP15009375A JPS6124675B2 JP S6124675 B2 JPS6124675 B2 JP S6124675B2 JP 50150093 A JP50150093 A JP 50150093A JP 15009375 A JP15009375 A JP 15009375A JP S6124675 B2 JPS6124675 B2 JP S6124675B2
- Authority
- JP
- Japan
- Prior art keywords
- ammonia gas
- ammonia
- droplets
- particles
- solution
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 96
- 239000002245 particle Substances 0.000 claims description 67
- 239000000446 fuel Substances 0.000 claims description 22
- 235000011114 ammonium hydroxide Nutrition 0.000 claims description 19
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonium chloride Substances [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 claims description 18
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 claims description 18
- 238000004519 manufacturing process Methods 0.000 claims description 16
- 229910052776 Thorium Inorganic materials 0.000 claims description 11
- 239000007788 liquid Substances 0.000 claims description 11
- ZSLUVFAKFWKJRC-IGMARMGPSA-N 232Th Chemical compound [232Th] ZSLUVFAKFWKJRC-IGMARMGPSA-N 0.000 claims description 9
- 239000000463 material Substances 0.000 claims description 8
- 238000001035 drying Methods 0.000 claims description 3
- ZCUFMDLYAMJYST-UHFFFAOYSA-N thorium dioxide Chemical compound O=[Th]=O ZCUFMDLYAMJYST-UHFFFAOYSA-N 0.000 claims description 3
- 238000005245 sintering Methods 0.000 claims description 2
- 229910003452 thorium oxide Inorganic materials 0.000 claims description 2
- 239000000243 solution Substances 0.000 description 23
- 238000000034 method Methods 0.000 description 21
- 229910052770 Uranium Inorganic materials 0.000 description 10
- 229910021529 ammonia Inorganic materials 0.000 description 10
- 239000012798 spherical particle Substances 0.000 description 9
- 238000002347 injection Methods 0.000 description 8
- 239000007924 injection Substances 0.000 description 8
- JFALSRSLKYAFGM-UHFFFAOYSA-N uranium(0) Chemical compound [U] JFALSRSLKYAFGM-UHFFFAOYSA-N 0.000 description 8
- 239000007789 gas Substances 0.000 description 7
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 5
- 238000006243 chemical reaction Methods 0.000 description 5
- 239000004372 Polyvinyl alcohol Substances 0.000 description 4
- 229910052799 carbon Inorganic materials 0.000 description 4
- 229920002451 polyvinyl alcohol Polymers 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 239000012670 alkaline solution Substances 0.000 description 3
- 239000007864 aqueous solution Substances 0.000 description 3
- 230000004992 fission Effects 0.000 description 3
- 238000009776 industrial production Methods 0.000 description 3
- 239000011261 inert gas Substances 0.000 description 3
- 239000012071 phase Substances 0.000 description 3
- 230000001698 pyrogenic effect Effects 0.000 description 3
- 239000000725 suspension Substances 0.000 description 3
- VGBPIHVLVSGJGR-UHFFFAOYSA-N thorium(4+);tetranitrate Chemical compound [Th+4].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O VGBPIHVLVSGJGR-UHFFFAOYSA-N 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000000839 emulsion Substances 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 230000010355 oscillation Effects 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 description 2
- 229910010271 silicon carbide Inorganic materials 0.000 description 2
- 238000007619 statistical method Methods 0.000 description 2
- 229910002007 uranyl nitrate Inorganic materials 0.000 description 2
- NMRPBPVERJPACX-UHFFFAOYSA-N (3S)-octan-3-ol Natural products CCCCCC(O)CC NMRPBPVERJPACX-UHFFFAOYSA-N 0.000 description 1
- YIWUKEYIRIRTPP-UHFFFAOYSA-N 2-ethylhexan-1-ol Chemical compound CCCCC(CC)CO YIWUKEYIRIRTPP-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 239000005662 Paraffin oil Substances 0.000 description 1
- 229910004369 ThO2 Inorganic materials 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- WZECUPJJEIXUKY-UHFFFAOYSA-N [O-2].[O-2].[O-2].[U+6] Chemical compound [O-2].[O-2].[O-2].[U+6] WZECUPJJEIXUKY-UHFFFAOYSA-N 0.000 description 1
- GFRMDONOCHESDE-UHFFFAOYSA-N [Th].[U] Chemical compound [Th].[U] GFRMDONOCHESDE-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000007900 aqueous suspension Substances 0.000 description 1
- 230000001174 ascending effect Effects 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000018044 dehydration Effects 0.000 description 1
- 238000006297 dehydration reaction Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- FCTBKIHDJGHPPO-UHFFFAOYSA-N dioxouranium Chemical compound O=[U]=O FCTBKIHDJGHPPO-UHFFFAOYSA-N 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 238000005469 granulation Methods 0.000 description 1
- 230000003179 granulation Effects 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 150000001247 metal acetylides Chemical class 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 229910000069 nitrogen hydride Inorganic materials 0.000 description 1
- 239000003758 nuclear fuel Substances 0.000 description 1
- DNNLEMIRRGUGOZ-UHFFFAOYSA-N oxygen(2-);thorium(4+) Chemical class [O-2].[O-2].[Th+4] DNNLEMIRRGUGOZ-UHFFFAOYSA-N 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 238000005029 sieve analysis Methods 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- KKCBUQHMOMHUOY-UHFFFAOYSA-N sodium oxide Chemical compound [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 description 1
- 229910001948 sodium oxide Inorganic materials 0.000 description 1
- 238000003980 solgel method Methods 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 229910000439 uranium oxide Inorganic materials 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2/00—Processes or devices for granulating materials, e.g. fertilisers in general; Rendering particulate materials free flowing in general, e.g. making them hydrophobic
- B01J2/02—Processes or devices for granulating materials, e.g. fertilisers in general; Rendering particulate materials free flowing in general, e.g. making them hydrophobic by dividing the liquid material into drops, e.g. by spraying, and solidifying the drops
- B01J2/06—Processes or devices for granulating materials, e.g. fertilisers in general; Rendering particulate materials free flowing in general, e.g. making them hydrophobic by dividing the liquid material into drops, e.g. by spraying, and solidifying the drops in a liquid medium
- B01J2/08—Gelation of a colloidal solution
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/51—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on compounds of actinides
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Plasma & Fusion (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Dispersion Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19742459445 DE2459445C3 (de) | 1974-12-16 | Verfahren zur Herstelung von kugelförmigen Brenn- und Brutstoffpartikeln |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS5185097A JPS5185097A (US06582424-20030624-M00016.png) | 1976-07-26 |
| JPS6124675B2 true JPS6124675B2 (US06582424-20030624-M00016.png) | 1986-06-12 |
Family
ID=5933551
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP50150093A Expired JPS6124675B2 (US06582424-20030624-M00016.png) | 1974-12-16 | 1975-12-16 |
Country Status (5)
Families Citing this family (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2714873C2 (de) * | 1977-04-02 | 1979-04-26 | Kernforschungsanlage Juelich Gmbh, 5170 Juelich | Vorrichtung zur Herstellung kugelförmiger Teilchen aus Tropfen von wäßrigen Lösungen aus Nitraten von Uran, Plutonium oder Thorium sowie Mischungen dieser Stoffe für Brenn- und Brutstoffelemente für Kernreaktoren |
| DE2733384C2 (de) * | 1977-07-23 | 1982-02-25 | Kernforschungsanlage Jülich GmbH, 5170 Jülich | Verfahren zur Herstellung von Brutstoff- oder Brenn- und Brutstoffkernen für Brennelemente von Kernreaktoren |
| DE3035845C2 (de) * | 1980-09-23 | 1986-05-22 | Gesellschaft zur Förderung der industrieorientierten Forschung an den Schweizerischen Hochschulen und weiteren Institutionen, Bern | Verfahren und Vorrichtung zur Herstellung von Mikrokugeln durch interne Gelierung von Mischfeed-Tropfen |
| IT1136856B (it) * | 1981-03-06 | 1986-09-03 | Agip Nucleare Spa | Procedimento per la produzione di particelle di gel ed apparecchiatura per l'attuazione di detto procedimento |
| US4663093A (en) * | 1985-12-23 | 1987-05-05 | The United States Of America As Represented By The United States Department Of Energy | Preparation of nuclear fuel spheres by flotation-internal gelation |
| DE3632396A1 (de) * | 1986-09-24 | 1988-03-31 | Hoechst Ag | Verfahren zur herstellung von metalloxiden oder metallmischoxiden |
| DE3634111C1 (de) * | 1986-10-07 | 1988-01-07 | Kernforschungsanlage Juelich | Verfahren zum Einbinden von Stoffen in eine keramische Matrix mittels chemischer Faellung eines Hydrosols der Matrix |
| LU87434A1 (fr) * | 1989-01-18 | 1990-07-24 | Euratom | Procede de formation de particules granulees a partir d'une poudre |
| DE19627806A1 (de) * | 1996-07-11 | 1998-01-15 | Siemens Ag | Kernbrennstoffsinterkörper und Verfahren zum Herstellen eines Kernbrennstoffsinterkörpers |
| DE102007037473A1 (de) * | 2007-05-24 | 2008-11-27 | Nukem Technologies Gmbh | Verfahren zur Herstellung von kugelförmigen Brenn- oder Brutstoffpartikeln |
| DE102008055468B4 (de) * | 2008-12-01 | 2010-09-02 | Nukem Technologies Gmbh | Verfahren und Anordnung zur Herstellung von Brennstoffkernen |
| CN102693766B (zh) * | 2012-05-31 | 2014-07-30 | 清华大学 | 一种uo2核芯陈化洗涤干燥一体化系统 |
| US9896618B2 (en) | 2015-11-19 | 2018-02-20 | Schlumberger Technology Corporation | Method of making rod-shaped particles for use as proppant and anti-flowback additive |
| US9932519B2 (en) | 2015-11-19 | 2018-04-03 | Schlumberger Technology Corporation | Method of making particles having a ridge portion for use as proppant |
| US10369724B2 (en) | 2015-11-19 | 2019-08-06 | Schlumberger Technology Corporation | Method of making spheroidal particles |
| US10557079B2 (en) | 2016-07-22 | 2020-02-11 | Schlumberger Technology Corporation | Method of making rod-shaped particles for use as proppant and anti-flowback additive |
| US10391679B2 (en) * | 2016-07-22 | 2019-08-27 | Schlumberger Technology Corporation | Perforated membranes and methods of making the same |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3275744A (en) * | 1962-10-01 | 1966-09-27 | Spraying Systems Co | Apparatus for spray analysis |
| GB1395486A (en) | 1971-05-05 | 1975-05-29 | Atomic Energy Authority Uk | Formation of liquid droplets |
| GB1401962A (en) | 1971-06-24 | 1975-08-06 | Atomic Energy Authority Uk | Gelation |
| US3933679A (en) * | 1972-01-14 | 1976-01-20 | Gulf Oil Corporation | Uniform microspheroidal particle generating method |
-
1975
- 1975-12-03 IT IT69979/75A patent/IT1051330B/it active
- 1975-12-08 US US05/638,662 patent/US4060497A/en not_active Expired - Lifetime
- 1975-12-10 GB GB50579/75A patent/GB1525950A/en not_active Expired
- 1975-12-16 JP JP50150093A patent/JPS6124675B2/ja not_active Expired
- 1975-12-16 FR FR7538542A patent/FR2295534A1/fr active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| FR2295534B1 (US06582424-20030624-M00016.png) | 1979-02-02 |
| GB1525950A (en) | 1978-09-27 |
| IT1051330B (it) | 1981-04-21 |
| FR2295534A1 (fr) | 1976-07-16 |
| US4060497A (en) | 1977-11-29 |
| JPS5185097A (US06582424-20030624-M00016.png) | 1976-07-26 |
| DE2459445A1 (de) | 1976-07-08 |
| DE2459445B2 (de) | 1976-10-14 |
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