JPS61238749A - ポリグリセリンの製造方法 - Google Patents
ポリグリセリンの製造方法Info
- Publication number
- JPS61238749A JPS61238749A JP60080087A JP8008785A JPS61238749A JP S61238749 A JPS61238749 A JP S61238749A JP 60080087 A JP60080087 A JP 60080087A JP 8008785 A JP8008785 A JP 8008785A JP S61238749 A JPS61238749 A JP S61238749A
- Authority
- JP
- Japan
- Prior art keywords
- aluminum oxide
- polyglycerin
- glycerol
- glycerin
- content
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000004519 manufacturing process Methods 0.000 title claims description 4
- 229920000223 polyglycerol Polymers 0.000 title abstract 3
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims abstract description 44
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims abstract description 17
- 239000003463 adsorbent Substances 0.000 claims abstract description 12
- 239000003054 catalyst Substances 0.000 claims abstract description 12
- 239000003513 alkali Substances 0.000 claims abstract description 9
- 235000011187 glycerol Nutrition 0.000 claims description 17
- 238000009833 condensation Methods 0.000 claims description 6
- 230000005494 condensation Effects 0.000 claims description 6
- 125000004122 cyclic group Chemical group 0.000 abstract description 9
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 abstract description 6
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 abstract description 6
- 235000013373 food additive Nutrition 0.000 abstract description 5
- 239000002778 food additive Substances 0.000 abstract description 5
- 239000002585 base Substances 0.000 abstract description 3
- 238000006243 chemical reaction Methods 0.000 abstract description 3
- 239000003153 chemical reaction reagent Substances 0.000 abstract description 3
- 229910000027 potassium carbonate Inorganic materials 0.000 abstract description 3
- 239000002994 raw material Substances 0.000 abstract description 3
- 229910000029 sodium carbonate Inorganic materials 0.000 abstract description 3
- 229910000288 alkali metal carbonate Inorganic materials 0.000 abstract description 2
- 150000008041 alkali metal carbonates Chemical class 0.000 abstract description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract description 2
- 239000002537 cosmetic Substances 0.000 abstract description 2
- 235000003084 food emulsifier Nutrition 0.000 abstract description 2
- 150000001875 compounds Chemical class 0.000 abstract 1
- 150000001923 cyclic compounds Chemical class 0.000 abstract 1
- 238000000034 method Methods 0.000 description 11
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 4
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 4
- 238000004458 analytical method Methods 0.000 description 4
- 238000006482 condensation reaction Methods 0.000 description 4
- 238000007796 conventional method Methods 0.000 description 4
- 239000000539 dimer Substances 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- -1 fatty acid ester Chemical class 0.000 description 4
- NWUYHJFMYQTDRP-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;1-ethenyl-2-ethylbenzene;styrene Chemical compound C=CC1=CC=CC=C1.CCC1=CC=CC=C1C=C.C=CC1=CC=CC=C1C=C NWUYHJFMYQTDRP-UHFFFAOYSA-N 0.000 description 3
- WMFOQBRAJBCJND-UHFFFAOYSA-M Lithium hydroxide Chemical compound [Li+].[OH-] WMFOQBRAJBCJND-UHFFFAOYSA-M 0.000 description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- 239000004927 clay Substances 0.000 description 3
- 235000014113 dietary fatty acids Nutrition 0.000 description 3
- 239000000194 fatty acid Substances 0.000 description 3
- 229930195729 fatty acid Natural products 0.000 description 3
- 239000007789 gas Substances 0.000 description 3
- 239000003456 ion exchange resin Substances 0.000 description 3
- 229920003303 ion-exchange polymer Polymers 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- BRLQWZUYTZBJKN-UHFFFAOYSA-N Epichlorohydrin Chemical compound ClCC1CO1 BRLQWZUYTZBJKN-UHFFFAOYSA-N 0.000 description 2
- WQDUMFSSJAZKTM-UHFFFAOYSA-N Sodium methoxide Chemical compound [Na+].[O-]C WQDUMFSSJAZKTM-UHFFFAOYSA-N 0.000 description 2
- 229910021536 Zeolite Inorganic materials 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- 239000012298 atmosphere Substances 0.000 description 2
- 239000001569 carbon dioxide Substances 0.000 description 2
- 229910002092 carbon dioxide Inorganic materials 0.000 description 2
- 229940105990 diglycerin Drugs 0.000 description 2
- GPLRAVKSCUXZTP-UHFFFAOYSA-N diglycerol Chemical compound OCC(O)COCC(O)CO GPLRAVKSCUXZTP-UHFFFAOYSA-N 0.000 description 2
- 229910001873 dinitrogen Inorganic materials 0.000 description 2
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 2
- 238000004821 distillation Methods 0.000 description 2
- 238000004817 gas chromatography Methods 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- XGZVUEUWXADBQD-UHFFFAOYSA-L lithium carbonate Chemical compound [Li+].[Li+].[O-]C([O-])=O XGZVUEUWXADBQD-UHFFFAOYSA-L 0.000 description 2
- 229910052808 lithium carbonate Inorganic materials 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- JCXJVPUVTGWSNB-UHFFFAOYSA-N nitrogen dioxide Inorganic materials O=[N]=O JCXJVPUVTGWSNB-UHFFFAOYSA-N 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- 238000007363 ring formation reaction Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000010457 zeolite Substances 0.000 description 2
- RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 description 1
- 241001550224 Apha Species 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- UIIMBOGNXHQVGW-DEQYMQKBSA-M Sodium bicarbonate-14C Chemical compound [Na+].O[14C]([O-])=O UIIMBOGNXHQVGW-DEQYMQKBSA-M 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 description 1
- 239000000292 calcium oxide Substances 0.000 description 1
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 1
- 238000003965 capillary gas chromatography Methods 0.000 description 1
- 239000012159 carrier gas Substances 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000004042 decolorization Methods 0.000 description 1
- 230000018044 dehydration Effects 0.000 description 1
- 238000006297 dehydration reaction Methods 0.000 description 1
- 238000004332 deodorization Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 239000001307 helium Substances 0.000 description 1
- 229910052734 helium Inorganic materials 0.000 description 1
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 1
- 238000004128 high performance liquid chromatography Methods 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 1
- 239000001095 magnesium carbonate Substances 0.000 description 1
- 229910000021 magnesium carbonate Inorganic materials 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 230000008520 organization Effects 0.000 description 1
- 229920001225 polyester resin Polymers 0.000 description 1
- 239000004645 polyester resin Substances 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 229960003656 ricinoleic acid Drugs 0.000 description 1
- FEUQNCSVHBHROZ-UHFFFAOYSA-N ricinoleic acid Natural products CCCCCCC(O[Si](C)(C)C)CC=CCCCCCCCC(=O)OC FEUQNCSVHBHROZ-UHFFFAOYSA-N 0.000 description 1
- 238000007086 side reaction Methods 0.000 description 1
- 239000011973 solid acid Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP60080087A JPS61238749A (ja) | 1985-04-17 | 1985-04-17 | ポリグリセリンの製造方法 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP60080087A JPS61238749A (ja) | 1985-04-17 | 1985-04-17 | ポリグリセリンの製造方法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS61238749A true JPS61238749A (ja) | 1986-10-24 |
| JPH0466464B2 JPH0466464B2 (enrdf_load_stackoverflow) | 1992-10-23 |
Family
ID=13708417
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP60080087A Granted JPS61238749A (ja) | 1985-04-17 | 1985-04-17 | ポリグリセリンの製造方法 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS61238749A (enrdf_load_stackoverflow) |
Cited By (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5198532A (en) * | 1991-03-19 | 1993-03-30 | Shell Oil Company | Polycondensation of epihalohydrin and polyhydric alcohols and thermal condensation to form polyethercyclicpolyols |
| US5204444A (en) * | 1991-03-19 | 1993-04-20 | Shell Oil Company | Polycondensation of epoxy alcohols with polyhdric alcohols and thermal condensation to form polyethercyclicpolyols |
| US5286882A (en) * | 1992-10-13 | 1994-02-15 | Shell Oil Company | Polyethercyclicpolyols from epihalohydrins, polyhydric alcohols and metal hydroxides or epoxy alcohol and optionally polyhydric alcohols with addition of epoxy resins |
| US5302728A (en) * | 1991-03-19 | 1994-04-12 | Shell Oil Company | Polycondensation of phenolic hydroxyl-containing compounds and polyhydric alcohols and thermal condensation to form polyethercyclipolyols |
| US5302695A (en) * | 1991-03-19 | 1994-04-12 | Shell Oil Company | Polycondensation of epoxy alcohols with polyhydric alcohols and thermal condensation to form polyethercyclicpolyols |
| US5338870A (en) * | 1991-03-19 | 1994-08-16 | Shell Oil Company | Thermal condensation of polyhydric alcohols to form polyethercyclicpolyols |
| WO1994018259A1 (en) * | 1993-02-10 | 1994-08-18 | Unichema Chemie B.V. | Polymerization of glycerol using a zeolite catalyst |
| US5371243A (en) * | 1992-10-13 | 1994-12-06 | Shell Oil Company | Polyethercyclicpolyols from epihalohydrins, polyhydric alcohols, and metal hydroxides |
| US5371244A (en) * | 1991-03-19 | 1994-12-06 | Shell Oil Company | Polycondensation of dihydric alcohols and polyhydric alcohols and thermal condensation to form polyethercyclicpolyols |
| US5401860A (en) * | 1991-03-19 | 1995-03-28 | Shell Oil Company | Copolymerization of polyethercyclicpolyols with epoxy resins |
| US5428178A (en) * | 1992-10-13 | 1995-06-27 | Shell Oil Company | Polyethercyclipolyols from epihalohydrins, polyhydric alcohols, and metal hydroxides or epoxy alcohols and optionally polyhydric alcohols with thermal condensation |
| EP0732318A1 (en) * | 1995-03-15 | 1996-09-18 | Nexus A/S | A process of preparing oligomeric and/or polymeric polyol compounds and their use in the production of emulsifying agents and surfactants |
| US5723696A (en) * | 1994-02-04 | 1998-03-03 | Unichema Chemie B.V. | Process for the production of polyglycerols |
| WO1999050213A1 (de) * | 1998-03-30 | 1999-10-07 | Cognis Deutschland Gmbh | Verfahren zur herstellung von dialkylethern |
| KR20020094254A (ko) * | 2001-06-08 | 2002-12-18 | 삼광 고하켐 주식회사 | 불균일 고체산 촉매를 이용한 폴리글리세롤의 제조방법 |
| US6620904B2 (en) | 2000-11-06 | 2003-09-16 | Lonza Inc. | Processes for preparing linear polyglycerols and polyglycerol esters |
| JP2008106012A (ja) * | 2006-10-26 | 2008-05-08 | Taiyo Kagaku Co Ltd | コエンザイムｑ１０含有化粧料用組成物およびそれを含有する化粧料 |
| JP2009513628A (ja) * | 2005-10-26 | 2009-04-02 | マレーシアン・パーム・オイル・ボード | 多価アルコールのポリマーの調製方法 |
| JP2013136521A (ja) * | 2011-12-28 | 2013-07-11 | Kao Corp | ポリグリセリンの製造方法 |
| US8821630B2 (en) | 2011-05-06 | 2014-09-02 | W. R. Grace & Co.-Conn. | Carboxylated-carboxylic polyglycerol compositions for use in cementitious compositions |
-
1985
- 1985-04-17 JP JP60080087A patent/JPS61238749A/ja active Granted
Cited By (24)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5371244A (en) * | 1991-03-19 | 1994-12-06 | Shell Oil Company | Polycondensation of dihydric alcohols and polyhydric alcohols and thermal condensation to form polyethercyclicpolyols |
| US5198532A (en) * | 1991-03-19 | 1993-03-30 | Shell Oil Company | Polycondensation of epihalohydrin and polyhydric alcohols and thermal condensation to form polyethercyclicpolyols |
| US5401860A (en) * | 1991-03-19 | 1995-03-28 | Shell Oil Company | Copolymerization of polyethercyclicpolyols with epoxy resins |
| US5302728A (en) * | 1991-03-19 | 1994-04-12 | Shell Oil Company | Polycondensation of phenolic hydroxyl-containing compounds and polyhydric alcohols and thermal condensation to form polyethercyclipolyols |
| US5302695A (en) * | 1991-03-19 | 1994-04-12 | Shell Oil Company | Polycondensation of epoxy alcohols with polyhydric alcohols and thermal condensation to form polyethercyclicpolyols |
| US5338870A (en) * | 1991-03-19 | 1994-08-16 | Shell Oil Company | Thermal condensation of polyhydric alcohols to form polyethercyclicpolyols |
| US5204444A (en) * | 1991-03-19 | 1993-04-20 | Shell Oil Company | Polycondensation of epoxy alcohols with polyhdric alcohols and thermal condensation to form polyethercyclicpolyols |
| US5371243A (en) * | 1992-10-13 | 1994-12-06 | Shell Oil Company | Polyethercyclicpolyols from epihalohydrins, polyhydric alcohols, and metal hydroxides |
| US5286882A (en) * | 1992-10-13 | 1994-02-15 | Shell Oil Company | Polyethercyclicpolyols from epihalohydrins, polyhydric alcohols and metal hydroxides or epoxy alcohol and optionally polyhydric alcohols with addition of epoxy resins |
| US5428178A (en) * | 1992-10-13 | 1995-06-27 | Shell Oil Company | Polyethercyclipolyols from epihalohydrins, polyhydric alcohols, and metal hydroxides or epoxy alcohols and optionally polyhydric alcohols with thermal condensation |
| US5367089A (en) * | 1992-10-13 | 1994-11-22 | Shell Oil Company | Polyethercyclicpolyols from epihalohydrins, polyhydric alcohols and metal hydroxides or epoxy alcohol and optionally polyhydric alcohols with addition of epoxy resins |
| WO1994018259A1 (en) * | 1993-02-10 | 1994-08-18 | Unichema Chemie B.V. | Polymerization of glycerol using a zeolite catalyst |
| US5635588A (en) * | 1993-02-10 | 1997-06-03 | Unichema Chemie B.V. | Polymerisation of glycerol using a zeolite catalyst |
| US5723696A (en) * | 1994-02-04 | 1998-03-03 | Unichema Chemie B.V. | Process for the production of polyglycerols |
| EP0732318A1 (en) * | 1995-03-15 | 1996-09-18 | Nexus A/S | A process of preparing oligomeric and/or polymeric polyol compounds and their use in the production of emulsifying agents and surfactants |
| WO1999050213A1 (de) * | 1998-03-30 | 1999-10-07 | Cognis Deutschland Gmbh | Verfahren zur herstellung von dialkylethern |
| US6620904B2 (en) | 2000-11-06 | 2003-09-16 | Lonza Inc. | Processes for preparing linear polyglycerols and polyglycerol esters |
| KR20020094254A (ko) * | 2001-06-08 | 2002-12-18 | 삼광 고하켐 주식회사 | 불균일 고체산 촉매를 이용한 폴리글리세롤의 제조방법 |
| JP2009513628A (ja) * | 2005-10-26 | 2009-04-02 | マレーシアン・パーム・オイル・ボード | 多価アルコールのポリマーの調製方法 |
| US8822736B2 (en) | 2005-10-26 | 2014-09-02 | Malaysian Palm Oil Board | Process for preparing polymers of polyhydric alcohols |
| DE112006002977B4 (de) | 2005-10-26 | 2017-10-05 | Malaysian Palm Oil Board | Verfahren zur Herstellung von Polymeren mehrwertiger Alkohole |
| JP2008106012A (ja) * | 2006-10-26 | 2008-05-08 | Taiyo Kagaku Co Ltd | コエンザイムｑ１０含有化粧料用組成物およびそれを含有する化粧料 |
| US8821630B2 (en) | 2011-05-06 | 2014-09-02 | W. R. Grace & Co.-Conn. | Carboxylated-carboxylic polyglycerol compositions for use in cementitious compositions |
| JP2013136521A (ja) * | 2011-12-28 | 2013-07-11 | Kao Corp | ポリグリセリンの製造方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0466464B2 (enrdf_load_stackoverflow) | 1992-10-23 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| LAPS | Cancellation because of no payment of annual fees |