JPS6077936A - 金属イオン抽出剤とその製造法及び抽出分離法 - Google Patents
金属イオン抽出剤とその製造法及び抽出分離法Info
- Publication number
- JPS6077936A JPS6077936A JP58186381A JP18638183A JPS6077936A JP S6077936 A JPS6077936 A JP S6077936A JP 58186381 A JP58186381 A JP 58186381A JP 18638183 A JP18638183 A JP 18638183A JP S6077936 A JPS6077936 A JP S6077936A
- Authority
- JP
- Japan
- Prior art keywords
- extractant
- acid
- formula
- secondary amine
- same
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 5
- 238000000926 separation method Methods 0.000 title claims description 5
- 150000001455 metallic ions Chemical class 0.000 title abstract 4
- 239000002253 acid Substances 0.000 claims abstract description 18
- 229910052500 inorganic mineral Inorganic materials 0.000 claims abstract description 14
- 239000011707 mineral Substances 0.000 claims abstract description 14
- 150000003335 secondary amines Chemical class 0.000 claims abstract description 11
- ISIJQEHRDSCQIU-UHFFFAOYSA-N tert-butyl 2,7-diazaspiro[4.5]decane-7-carboxylate Chemical compound C1N(C(=O)OC(C)(C)C)CCCC11CNCC1 ISIJQEHRDSCQIU-UHFFFAOYSA-N 0.000 claims abstract description 9
- 229910021645 metal ion Inorganic materials 0.000 claims description 27
- 238000000605 extraction Methods 0.000 claims description 10
- 238000000034 method Methods 0.000 claims description 9
- 239000007864 aqueous solution Substances 0.000 claims description 7
- 238000000638 solvent extraction Methods 0.000 claims description 7
- 239000003960 organic solvent Substances 0.000 claims description 6
- 239000012074 organic phase Substances 0.000 claims description 3
- 125000004432 carbon atom Chemical group C* 0.000 claims description 2
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 claims description 2
- 125000001183 hydrocarbyl group Chemical group 0.000 claims 1
- 238000000622 liquid--liquid extraction Methods 0.000 claims 1
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 abstract description 12
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 abstract description 12
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 abstract description 12
- 239000007788 liquid Substances 0.000 abstract description 6
- 238000003756 stirring Methods 0.000 abstract description 6
- 150000007513 acids Chemical class 0.000 abstract description 5
- 239000002994 raw material Substances 0.000 abstract description 2
- BDZBKCUKTQZUTL-UHFFFAOYSA-N triethyl phosphite Chemical compound CCOP(OCC)OCC BDZBKCUKTQZUTL-UHFFFAOYSA-N 0.000 abstract description 2
- LAWOZCWGWDVVSG-UHFFFAOYSA-N dioctylamine Chemical compound CCCCCCCCNCCCCCCCC LAWOZCWGWDVVSG-UHFFFAOYSA-N 0.000 abstract 1
- 230000001105 regulatory effect Effects 0.000 abstract 1
- 229910052770 Uranium Inorganic materials 0.000 description 14
- JFALSRSLKYAFGM-UHFFFAOYSA-N uranium(0) Chemical compound [U] JFALSRSLKYAFGM-UHFFFAOYSA-N 0.000 description 14
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 12
- 239000000243 solution Substances 0.000 description 11
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 9
- 229910052787 antimony Inorganic materials 0.000 description 9
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 9
- 229910052797 bismuth Inorganic materials 0.000 description 7
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 description 7
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 6
- 239000000203 mixture Substances 0.000 description 6
- 150000001875 compounds Chemical class 0.000 description 4
- IGFHQQFPSIBGKE-UHFFFAOYSA-N 4-nonylphenol Chemical compound CCCCCCCCCC1=CC=C(O)C=C1 IGFHQQFPSIBGKE-UHFFFAOYSA-N 0.000 description 3
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 3
- 229910052802 copper Inorganic materials 0.000 description 3
- 239000010949 copper Substances 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- -1 1-hydroxy-ethylhexyl phosphate Chemical compound 0.000 description 2
- YIWUKEYIRIRTPP-UHFFFAOYSA-N 2-ethylhexan-1-ol Chemical compound CCCCC(CC)CO YIWUKEYIRIRTPP-UHFFFAOYSA-N 0.000 description 2
- SAIKULLUBZKPDA-UHFFFAOYSA-N Bis(2-ethylhexyl) amine Chemical compound CCCCC(CC)CNCC(CC)CCCC SAIKULLUBZKPDA-UHFFFAOYSA-N 0.000 description 2
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 2
- CYTYCFOTNPOANT-UHFFFAOYSA-N Perchloroethylene Chemical group ClC(Cl)=C(Cl)Cl CYTYCFOTNPOANT-UHFFFAOYSA-N 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 229910052738 indium Inorganic materials 0.000 description 2
- APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 description 2
- 239000003350 kerosene Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- 229910017604 nitric acid Inorganic materials 0.000 description 2
- 238000010992 reflux Methods 0.000 description 2
- 229950011008 tetrachloroethylene Drugs 0.000 description 2
- VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- 239000003799 water insoluble solvent Substances 0.000 description 2
- FXZVACQCUNWYEK-UHFFFAOYSA-N 2,6,8-trimethyl-n-(2,6,8-trimethylnonan-4-yl)nonan-4-amine Chemical compound CC(C)CC(C)CC(CC(C)C)NC(CC(C)C)CC(C)CC(C)C FXZVACQCUNWYEK-UHFFFAOYSA-N 0.000 description 1
- PLLBRTOLHQQAQQ-UHFFFAOYSA-N 8-methylnonan-1-ol Chemical compound CC(C)CCCCCCCO PLLBRTOLHQQAQQ-UHFFFAOYSA-N 0.000 description 1
- AYHKQJXKSRSNRB-UHFFFAOYSA-N C(C)C(C[P])CCCC Chemical compound C(C)C(C[P])CCCC AYHKQJXKSRSNRB-UHFFFAOYSA-N 0.000 description 1
- MWZURXFBZKJJQI-UHFFFAOYSA-N C(C)C(C[P]CC(CCCC)CC)CCCC Chemical compound C(C)C(C[P]CC(CCCC)CC)CCCC MWZURXFBZKJJQI-UHFFFAOYSA-N 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 description 1
- 241000208202 Linaceae Species 0.000 description 1
- 235000004431 Linum usitatissimum Nutrition 0.000 description 1
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- 238000003723 Smelting Methods 0.000 description 1
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 1
- 239000008346 aqueous phase Substances 0.000 description 1
- 239000007810 chemical reaction solvent Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- SEGLCEQVOFDUPX-UHFFFAOYSA-N di-(2-ethylhexyl)phosphoric acid Chemical compound CCCCC(CC)COP(O)(=O)OCC(CC)CCCC SEGLCEQVOFDUPX-UHFFFAOYSA-N 0.000 description 1
- BVXOPEOQUQWRHQ-UHFFFAOYSA-N dibutyl phosphite Chemical compound CCCCOP([O-])OCCCC BVXOPEOQUQWRHQ-UHFFFAOYSA-N 0.000 description 1
- 229910052733 gallium Inorganic materials 0.000 description 1
- CYZASAMUYFRGTI-UHFFFAOYSA-N heptadecyl dihydrogen phosphate Chemical compound CCCCCCCCCCCCCCCCCOP(O)(O)=O CYZASAMUYFRGTI-UHFFFAOYSA-N 0.000 description 1
- 150000002430 hydrocarbons Chemical group 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- OYSOTUBAHIRSLX-UHFFFAOYSA-N n-benzyl-3,9-diethyltridecan-6-amine Chemical compound CCCCC(CC)CCC(CCC(CC)CC)NCC1=CC=CC=C1 OYSOTUBAHIRSLX-UHFFFAOYSA-N 0.000 description 1
- MJCJUDJQDGGKOX-UHFFFAOYSA-N n-dodecyldodecan-1-amine Chemical compound CCCCCCCCCCCCNCCCCCCCCCCCC MJCJUDJQDGGKOX-UHFFFAOYSA-N 0.000 description 1
- PZFYOFFTIYJCEW-UHFFFAOYSA-N n-tridecyltridecan-1-amine Chemical compound CCCCCCCCCCCCCNCCCCCCCCCCCCC PZFYOFFTIYJCEW-UHFFFAOYSA-N 0.000 description 1
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical class OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
Landscapes
- Physical Water Treatments (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
- Manufacture And Refinement Of Metals (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP58186381A JPS6077936A (ja) | 1983-10-04 | 1983-10-04 | 金属イオン抽出剤とその製造法及び抽出分離法 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP58186381A JPS6077936A (ja) | 1983-10-04 | 1983-10-04 | 金属イオン抽出剤とその製造法及び抽出分離法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS6077936A true JPS6077936A (ja) | 1985-05-02 |
| JPS6314054B2 JPS6314054B2 (enrdf_load_stackoverflow) | 1988-03-29 |
Family
ID=16187389
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP58186381A Granted JPS6077936A (ja) | 1983-10-04 | 1983-10-04 | 金属イオン抽出剤とその製造法及び抽出分離法 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS6077936A (enrdf_load_stackoverflow) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1996000309A1 (de) * | 1994-06-23 | 1996-01-04 | Basf Aktiengesellschaft | Verwendung von kohlenwasserstofflöslichen aminomethylenphosphonsäure-derivaten zur solventextraktiven abtrennung von eisenionen aus wässrigen lösungen |
| EP0834581A1 (en) * | 1996-09-30 | 1998-04-08 | Basf Aktiengesellschaft | Use of hydrocarbon-soluble aminomethylenephosphonic acid derivatives for the solvent extraction of metal ions from aqueous solutions |
| JP2012102062A (ja) * | 2010-11-12 | 2012-05-31 | Univ Of Miyazaki | アルキルアミノリン化合物及び金属抽出剤 |
-
1983
- 1983-10-04 JP JP58186381A patent/JPS6077936A/ja active Granted
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1996000309A1 (de) * | 1994-06-23 | 1996-01-04 | Basf Aktiengesellschaft | Verwendung von kohlenwasserstofflöslichen aminomethylenphosphonsäure-derivaten zur solventextraktiven abtrennung von eisenionen aus wässrigen lösungen |
| AU686409B2 (en) * | 1994-06-23 | 1998-02-05 | Basf Aktiengesellschaft | Use of hydrocarbon-soluble aminomethylene phosphonic acid derivatives in the solvent extraction of iron ions from aqueous solutions |
| EP0930372A1 (de) * | 1994-06-23 | 1999-07-21 | Basf Aktiengesellschaft | Verwendung von alkoxylierten Alkoholen oder Aminen als Modifier bei der solventextraktiven Abtrennung von Metallionen aus wässrigen Lösungen |
| EP0834581A1 (en) * | 1996-09-30 | 1998-04-08 | Basf Aktiengesellschaft | Use of hydrocarbon-soluble aminomethylenephosphonic acid derivatives for the solvent extraction of metal ions from aqueous solutions |
| WO1998014621A1 (en) * | 1996-09-30 | 1998-04-09 | Basf Aktiengesellschaft | Use of hydrocarbon-soluble aminomethylenephosphonic acid derivatives for the solvent extraction of metal ions from aqueous solutions |
| JP2012102062A (ja) * | 2010-11-12 | 2012-05-31 | Univ Of Miyazaki | アルキルアミノリン化合物及び金属抽出剤 |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS6314054B2 (enrdf_load_stackoverflow) | 1988-03-29 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP5578750B1 (ja) | アミド誘導体 | |
| JP2007327085A (ja) | 希土類金属の抽出剤と抽出方法 | |
| IE44327B1 (en) | Extracting metal values with o-hydroxyaryloximes | |
| CN105734287B (zh) | 一种分离四价铈、钍和稀土的方法 | |
| US4624704A (en) | Selective recovery of zinc from metal containing brines | |
| JPH0323229A (ja) | モノチオフオスフイン酸による金属の回収方法 | |
| JPH06228666A (ja) | 廃水素化処理触媒からの金属の分離回収方法 | |
| US3992507A (en) | Halidation of manganiferous ore to obtain metal values and recovery and recycle of halide values | |
| US4581220A (en) | Process for the extraction of metal values and novel metal extractants | |
| US5728853A (en) | Chemical process | |
| AU600339B2 (en) | Process for the recovery of metals | |
| FR2462481A1 (fr) | Procede d'extraction liquide-liquide de metaux en solution aqueuse au moyen de derives organophosphores | |
| JPS6077936A (ja) | 金属イオン抽出剤とその製造法及び抽出分離法 | |
| US3700415A (en) | Vanadium recovery from wet process phosphoric acid using neutral organophosphorus extractants | |
| JPH06192753A (ja) | 化学的方法 | |
| US3449066A (en) | Recovery of molybdenum values from aqueous solutions using alpha-hydroxy oximes | |
| CA1257260A (en) | Triazolopyrimidine extractants | |
| JPH0448733B2 (enrdf_load_stackoverflow) | ||
| Gotfryd et al. | The selective recovery of cadmium (II) from sulfate solutions by a counter-current extraction–stripping process using a mixture of diisopropylsalicylic acid and Cyanex® 471X | |
| CA1227321A (en) | Recovery of anhydrous zinc chloride | |
| US4836956A (en) | Extraction of polyvalent metals with organodiphosphonic acids | |
| EP2942409B1 (en) | Valuable-metal extraction method | |
| JPH09506349A (ja) | 化学化合物 | |
| JP3900254B2 (ja) | 鏡像異性体的に高純度の（５，５’−ジクロロ−６，６’−ジメトキシビフェニル−２，２’−ジイル）−ビス−（ジフェニルホスフィンオキサイド）の改良製造方法 | |
| US3443887A (en) | Recovery of pentavalent vanadium values from aqueous solutions using alpha-hydroxy oximes |