JPS6053116B2 - ニツケルの電解採取方法 - Google Patents
ニツケルの電解採取方法Info
- Publication number
- JPS6053116B2 JPS6053116B2 JP52078943A JP7894377A JPS6053116B2 JP S6053116 B2 JPS6053116 B2 JP S6053116B2 JP 52078943 A JP52078943 A JP 52078943A JP 7894377 A JP7894377 A JP 7894377A JP S6053116 B2 JPS6053116 B2 JP S6053116B2
- Authority
- JP
- Japan
- Prior art keywords
- electrolyte
- nickel
- sulfur
- catholyte
- zone
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 title claims description 72
- 229910052759 nickel Inorganic materials 0.000 title claims description 36
- 238000000034 method Methods 0.000 title claims description 26
- 238000005363 electrowinning Methods 0.000 title description 17
- 239000003792 electrolyte Substances 0.000 claims description 75
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 31
- 239000011593 sulfur Substances 0.000 claims description 31
- 229910052717 sulfur Inorganic materials 0.000 claims description 31
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 17
- 239000012528 membrane Substances 0.000 claims description 16
- -1 alkaline earth metal sulfates Chemical class 0.000 claims description 8
- 150000001875 compounds Chemical class 0.000 claims description 7
- 239000008151 electrolyte solution Substances 0.000 claims description 7
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 claims description 6
- 239000004327 boric acid Substances 0.000 claims description 6
- XTQHKBHJIVJGKJ-UHFFFAOYSA-N sulfur monoxide Chemical compound S=O XTQHKBHJIVJGKJ-UHFFFAOYSA-N 0.000 claims description 6
- 229910052783 alkali metal Inorganic materials 0.000 claims description 5
- 150000001340 alkali metals Chemical class 0.000 claims description 4
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims description 4
- UMGDCJDMYOKAJW-UHFFFAOYSA-N thiourea Chemical compound NC(N)=S UMGDCJDMYOKAJW-UHFFFAOYSA-N 0.000 claims description 4
- VEQPNABPJHWNSG-UHFFFAOYSA-N Nickel(2+) Chemical compound [Ni+2] VEQPNABPJHWNSG-UHFFFAOYSA-N 0.000 claims description 3
- LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical class OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 claims description 3
- 238000005868 electrolysis reaction Methods 0.000 claims description 3
- 229910001453 nickel ion Inorganic materials 0.000 claims description 3
- 150000004764 thiosulfuric acid derivatives Chemical class 0.000 claims description 3
- YCMLQMDWSXFTIF-UHFFFAOYSA-N 2-methylbenzenesulfonimidic acid Chemical compound CC1=CC=CC=C1S(N)(=O)=O YCMLQMDWSXFTIF-UHFFFAOYSA-N 0.000 claims description 2
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Natural products NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 2
- 150000001342 alkaline earth metals Chemical class 0.000 claims 1
- DHCDFWKWKRSZHF-UHFFFAOYSA-L thiosulfate(2-) Chemical compound [O-]S([S-])(=O)=O DHCDFWKWKRSZHF-UHFFFAOYSA-L 0.000 claims 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 19
- 239000000460 chlorine Substances 0.000 description 19
- 229910052801 chlorine Inorganic materials 0.000 description 19
- 238000012360 testing method Methods 0.000 description 10
- 238000001556 precipitation Methods 0.000 description 7
- 150000002500 ions Chemical class 0.000 description 6
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 5
- 238000004070 electrodeposition Methods 0.000 description 5
- 239000000203 mixture Substances 0.000 description 5
- 229910021586 Nickel(II) chloride Inorganic materials 0.000 description 4
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 4
- QMMRZOWCJAIUJA-UHFFFAOYSA-L nickel dichloride Chemical compound Cl[Ni]Cl QMMRZOWCJAIUJA-UHFFFAOYSA-L 0.000 description 4
- 230000008569 process Effects 0.000 description 4
- 239000010936 titanium Substances 0.000 description 4
- 229910052719 titanium Inorganic materials 0.000 description 4
- 239000003153 chemical reaction reagent Substances 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 238000009792 diffusion process Methods 0.000 description 3
- 229920002994 synthetic fiber Polymers 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 230000004913 activation Effects 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- 239000011152 fibreglass Substances 0.000 description 2
- 229910002804 graphite Inorganic materials 0.000 description 2
- 239000010439 graphite Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000007670 refining Methods 0.000 description 2
- AKHNMLFCWUSKQB-UHFFFAOYSA-L sodium thiosulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=S AKHNMLFCWUSKQB-UHFFFAOYSA-L 0.000 description 2
- 235000019345 sodium thiosulphate Nutrition 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- FZUJWWOKDIGOKH-UHFFFAOYSA-N sulfuric acid hydrochloride Chemical compound Cl.OS(O)(=O)=O FZUJWWOKDIGOKH-UHFFFAOYSA-N 0.000 description 2
- KZBUYRJDOAKODT-UHFFFAOYSA-N Chlorine Chemical compound ClCl KZBUYRJDOAKODT-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 229910001423 beryllium ion Inorganic materials 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000004891 communication Methods 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000000151 deposition Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 238000009713 electroplating Methods 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 230000002452 interceptive effect Effects 0.000 description 1
- 238000002386 leaching Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 230000005012 migration Effects 0.000 description 1
- 238000013508 migration Methods 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical group [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 238000000638 solvent extraction Methods 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 230000001629 suppression Effects 0.000 description 1
- 239000004758 synthetic textile Substances 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- 238000009423 ventilation Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
- C25C1/00—Electrolytic production, recovery or refining of metals by electrolysis of solutions
- C25C1/06—Electrolytic production, recovery or refining of metals by electrolysis of solutions or iron group metals, refractory metals or manganese
- C25C1/08—Electrolytic production, recovery or refining of metals by electrolysis of solutions or iron group metals, refractory metals or manganese of nickel or cobalt
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Electrolytic Production Of Metals (AREA)
- Secondary Cells (AREA)
- Primary Cells (AREA)
- Battery Electrode And Active Subsutance (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CA256,198A CA1062653A (en) | 1976-07-02 | 1976-07-02 | Electrowinning of sulfur-containing nickel |
| CA256198 | 1976-07-02 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS535019A JPS535019A (en) | 1978-01-18 |
| JPS6053116B2 true JPS6053116B2 (ja) | 1985-11-22 |
Family
ID=4106345
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP52078943A Expired JPS6053116B2 (ja) | 1976-07-02 | 1977-07-01 | ニツケルの電解採取方法 |
Country Status (7)
Families Citing this family (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA1092056A (en) * | 1977-10-11 | 1980-12-23 | Victor A. Ettel | Electrowinning cell with bagged anode |
| CA1125228A (en) * | 1979-10-10 | 1982-06-08 | Daniel P. Young | Process for electrowinning nickel or cobalt |
| ZA806966B (en) * | 1979-11-21 | 1981-10-28 | Falconbridge Nickel Mines Ltd | Electrodeposition of sulfur-bearing nickel |
| CA2392846C (en) * | 2002-07-09 | 2008-07-15 | Hatch Associates Ltd. | Recovery and re-use of anode oxygen from electrolytic cells |
| US6866766B2 (en) * | 2002-08-05 | 2005-03-15 | Alcoa Inc. | Methods and apparatus for reducing sulfur impurities and improving current efficiencies of inert anode aluminum production cells |
| RU2256729C1 (ru) * | 2003-10-09 | 2005-07-20 | Открытое акционерное общество "Горно-металлургическая компания "Норильский никель" | Способ изготовления диафрагменного элемента ячейки для электролитического извлечения металлов из водных растворов и диафрагменный элемент |
| RU2247796C1 (ru) * | 2003-11-11 | 2005-03-10 | ОАО "Горно-металлургическая компания "Норильский никель" | Способ электролитического получения никеля |
| WO2008124140A1 (en) * | 2007-04-05 | 2008-10-16 | Siemens Water Technologies Corp. | Method and system of electrolytic treatment |
| FI127028B (en) * | 2013-06-05 | 2017-09-29 | Outotec Finland Oy | Method and apparatus for electrolytic enrichment of metal |
| CN104213150A (zh) * | 2014-07-04 | 2014-12-17 | 襄阳化通化工有限责任公司 | 一种用电解法生产的含硫活性镍饼 |
| CN104532293B (zh) * | 2014-12-22 | 2017-06-09 | 无锡市瑞思科环保科技有限公司 | 化学镀镍废液中提纯镍的方法及镍提纯装置 |
| RU168849U1 (ru) * | 2016-05-24 | 2017-02-21 | Открытое акционерное общество "Тамбовское опытно-конструкторское технологическое бюро" (ОАО "Тамбовское ОКТБ") | Анодная ячейка для электровыделения цветных металлов из водных растворов |
| CN109023440A (zh) * | 2018-09-04 | 2018-12-18 | 中国科学院兰州化学物理研究所 | 利用无碳携硫剂制备含硫镍材料的方法 |
| CN112593273A (zh) * | 2020-12-07 | 2021-04-02 | 中国科学院宁波材料技术与工程研究所 | 一种金属/含硫镍复合材料及其制备方法与应用 |
| CN115430597B (zh) * | 2022-11-03 | 2023-03-07 | 中国科学院宁波材料技术与工程研究所 | 超亲水镍基多层复合膜材料及其制备方法与应用 |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2392708A (en) * | 1941-06-13 | 1946-01-08 | Int Nickel Co | Method of making sulphur-containing nickel anodes electrolytically |
| US2453757A (en) * | 1943-06-12 | 1948-11-16 | Int Nickel Co | Process for producing modified electronickel |
| GB576650A (en) * | 1943-06-12 | 1946-04-12 | Mond Nickel Co Ltd | Improvements relating to the production of massive nickel for use as anodes |
| US2480771A (en) * | 1946-04-12 | 1949-08-30 | Int Nickel Co | Process for the electrolytic recovery of nickel |
| GB992767A (en) * | 1962-02-01 | 1965-05-19 | Ionics | Process for electroplating of metals and apparatus for effecting the same |
| US3855089A (en) * | 1972-11-27 | 1974-12-17 | Deepsea Ventures Inc | Process for the electrolytic refining of heavy metals |
| FR2240765B1 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) * | 1973-08-16 | 1978-01-27 | Nickel Le | |
| GB1478502A (en) * | 1974-11-25 | 1977-07-06 | Falconbridge Nickel Mines Ltd | Electrowinning metal from chloride solution |
| GB1481663A (en) * | 1975-01-09 | 1977-08-03 | Parel S | Electrowinning of metals |
-
1976
- 1976-07-02 CA CA256,198A patent/CA1062653A/en not_active Expired
-
1977
- 1977-01-11 US US05/758,483 patent/US4087339A/en not_active Expired - Lifetime
- 1977-06-21 PH PH19896A patent/PH13006A/en unknown
- 1977-06-29 FR FR7719958A patent/FR2356746A1/fr active Granted
- 1977-06-30 NO NO772310A patent/NO148039C/no unknown
- 1977-06-30 FI FI772040A patent/FI63970C/fi not_active IP Right Cessation
- 1977-07-01 JP JP52078943A patent/JPS6053116B2/ja not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| PH13006A (en) | 1979-11-09 |
| FI772040A7 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1978-01-03 |
| FR2356746B1 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1981-08-28 |
| US4087339A (en) | 1978-05-02 |
| FR2356746A1 (fr) | 1978-01-27 |
| CA1062653A (en) | 1979-09-18 |
| FI63970C (fi) | 1983-09-12 |
| NO148039B (no) | 1983-04-18 |
| NO148039C (no) | 1983-08-10 |
| FI63970B (fi) | 1983-05-31 |
| NO772310L (no) | 1978-01-03 |
| JPS535019A (en) | 1978-01-18 |
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