JPS60501927A - Shallow junction semiconductor devices - Google Patents
Shallow junction semiconductor devicesInfo
- Publication number
- JPS60501927A JPS60501927A JP59502397A JP50239784A JPS60501927A JP S60501927 A JPS60501927 A JP S60501927A JP 59502397 A JP59502397 A JP 59502397A JP 50239784 A JP50239784 A JP 50239784A JP S60501927 A JPS60501927 A JP S60501927A
- Authority
- JP
- Japan
- Prior art keywords
- depth
- substrate
- species
- junction
- neutral species
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000004065 semiconductor Substances 0.000 title claims description 12
- 230000007935 neutral effect Effects 0.000 claims description 34
- 239000000758 substrate Substances 0.000 claims description 23
- 238000000034 method Methods 0.000 claims description 17
- 238000000137 annealing Methods 0.000 claims description 12
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 10
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 6
- 229910052799 carbon Inorganic materials 0.000 claims description 6
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 5
- 229910052757 nitrogen Inorganic materials 0.000 claims description 5
- 229910052710 silicon Inorganic materials 0.000 claims description 5
- 239000010703 silicon Substances 0.000 claims description 5
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 4
- 229910052732 germanium Inorganic materials 0.000 claims description 4
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 claims description 4
- 238000004519 manufacturing process Methods 0.000 claims description 4
- 239000001301 oxygen Substances 0.000 claims description 4
- 229910052760 oxygen Inorganic materials 0.000 claims description 4
- 229910052718 tin Inorganic materials 0.000 claims description 4
- 238000009826 distribution Methods 0.000 claims description 3
- 239000011261 inert gas Substances 0.000 claims description 3
- 239000011135 tin Substances 0.000 claims 2
- 230000003213 activating effect Effects 0.000 claims 1
- 230000015572 biosynthetic process Effects 0.000 claims 1
- 241000894007 species Species 0.000 description 30
- 238000002347 injection Methods 0.000 description 8
- 239000007924 injection Substances 0.000 description 8
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 6
- 230000004913 activation Effects 0.000 description 6
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 5
- 229910052785 arsenic Inorganic materials 0.000 description 5
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 description 5
- 229910052796 boron Inorganic materials 0.000 description 5
- 238000009792 diffusion process Methods 0.000 description 5
- 239000012535 impurity Substances 0.000 description 5
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 4
- 239000002019 doping agent Substances 0.000 description 4
- 238000002513 implantation Methods 0.000 description 4
- 230000007547 defect Effects 0.000 description 3
- 150000002500 ions Chemical class 0.000 description 3
- 235000012239 silicon dioxide Nutrition 0.000 description 3
- 239000000377 silicon dioxide Substances 0.000 description 3
- 229910052786 argon Inorganic materials 0.000 description 2
- 230000004888 barrier function Effects 0.000 description 2
- 238000005247 gettering Methods 0.000 description 2
- 239000007943 implant Substances 0.000 description 2
- 238000005468 ion implantation Methods 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 230000001590 oxidative effect Effects 0.000 description 2
- 229910021332 silicide Inorganic materials 0.000 description 2
- FVBUAEGBCNSCDD-UHFFFAOYSA-N silicide(4-) Chemical compound [Si-4] FVBUAEGBCNSCDD-UHFFFAOYSA-N 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 229910052787 antimony Inorganic materials 0.000 description 1
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000005684 electric field Effects 0.000 description 1
- 230000005669 field effect Effects 0.000 description 1
- 229910052733 gallium Inorganic materials 0.000 description 1
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 description 1
- 230000005012 migration Effects 0.000 description 1
- 238000013508 migration Methods 0.000 description 1
- 229910021420 polycrystalline silicon Inorganic materials 0.000 description 1
- 229920005591 polysilicon Polymers 0.000 description 1
- 210000002784 stomach Anatomy 0.000 description 1
- 229910052715 tantalum Inorganic materials 0.000 description 1
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 description 1
Classifications
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
- H01L21/18—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
- H01L21/26—Bombardment with radiation
- H01L21/263—Bombardment with radiation with high-energy radiation
- H01L21/265—Bombardment with radiation with high-energy radiation producing ion implantation
- H01L21/26506—Bombardment with radiation with high-energy radiation producing ion implantation in group IV semiconductors
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
- H01L21/18—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
- H01L21/22—Diffusion of impurity materials, e.g. doping materials, electrode materials, into or out of a semiconductor body, or between semiconductor regions; Interactions between two or more impurities; Redistribution of impurities
- H01L21/225—Diffusion of impurity materials, e.g. doping materials, electrode materials, into or out of a semiconductor body, or between semiconductor regions; Interactions between two or more impurities; Redistribution of impurities using diffusion into or out of a solid from or into a solid phase, e.g. a doped oxide layer
- H01L21/2251—Diffusion into or out of group IV semiconductors
- H01L21/2252—Diffusion into or out of group IV semiconductors using predeposition of impurities into the semiconductor surface, e.g. from a gaseous phase
- H01L21/2253—Diffusion into or out of group IV semiconductors using predeposition of impurities into the semiconductor surface, e.g. from a gaseous phase by ion implantation
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L21/00—Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
- H01L21/02—Manufacture or treatment of semiconductor devices or of parts thereof
- H01L21/04—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
- H01L21/18—Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
- H01L21/26—Bombardment with radiation
- H01L21/263—Bombardment with radiation with high-energy radiation
- H01L21/265—Bombardment with radiation with high-energy radiation producing ion implantation
- H01L21/26506—Bombardment with radiation with high-energy radiation producing ion implantation in group IV semiconductors
- H01L21/26513—Bombardment with radiation with high-energy radiation producing ion implantation in group IV semiconductors of electrically active species
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L29/00—Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
- H01L29/02—Semiconductor bodies ; Multistep manufacturing processes therefor
- H01L29/12—Semiconductor bodies ; Multistep manufacturing processes therefor characterised by the materials of which they are formed
- H01L29/16—Semiconductor bodies ; Multistep manufacturing processes therefor characterised by the materials of which they are formed including, apart from doping materials or other impurities, only elements of Group IV of the Periodic Table
- H01L29/167—Semiconductor bodies ; Multistep manufacturing processes therefor characterised by the materials of which they are formed including, apart from doping materials or other impurities, only elements of Group IV of the Periodic Table further characterised by the doping material
Landscapes
- Physics & Mathematics (AREA)
- Engineering & Computer Science (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Power Engineering (AREA)
- High Energy & Nuclear Physics (AREA)
- General Physics & Mathematics (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- Computer Hardware Design (AREA)
- Manufacturing & Machinery (AREA)
- Health & Medical Sciences (AREA)
- Toxicology (AREA)
- Ceramic Engineering (AREA)
- Insulated Gate Type Field-Effect Transistor (AREA)
- Bipolar Transistors (AREA)
Abstract
(57)【要約】本公報は電子出願前の出願データであるため要約のデータは記録されません。 (57) [Summary] This bulletin contains application data before electronic filing, so abstract data is not recorded.
Description
浅い接合の半導体デバイス 本発明の背景 本発明は浅い接合の半導体デバイスに係る。 金属−酸化物一半導本電界効果トランジスタ(MOSFET)のような各種の半 導体デバイスにおいて、デバイスのp−n接合は、できるだけ基板表面に近いこ とが望ましい。 本発明は従来得られたより、半導体基体表面に著しく近接したp −n接合を得 るための手段を実現する。 本発明の要約 中性種が最初、半導体基体の表面領域の中に注入される。−例において、中性種 が注入され、最大濃度がその後形成されるp−n接合より、深い位置で生じるよ うな層が形成される。(別の例((おいて、中性種層のピーク濃度の深さより深 い位置に接合が続いて形成される。)次に、ドーパント種が、先に注入された中 性種の最大儂′ 度の深さより、浅い深さの表面領域に注入される。次に、ドー パント種を活性化するだめのアニーリングが行われる。 このアニーリング工程中、中性種層はデバイスの基体中の点欠陥をゲッタする働 きをする。加えて、この層はドーパント種の拡散に対する物理的な障壁として働 く。 その結果、基体中のドーパント種の拡散の程度は、中性種層を形成しない場合に 比べ、著しく下げられる。いずきわめて浅い深さに形成されることになる。 図面の簡単な説明 第1ないし4図(は本発明の原理を実施する製作工程の、順次行われる段階にお けるMO!5FETデバイスの一部を概略的に示す図である。 詳細な記述 本発明に従うと、浅・ハル−n接合が各種の半導体デバイス中に、形成できる。 これらのデバイスには、たとえばp−nダイオード、バイポーラトランジスタ及 びMO3FETデバイスが含まれる。例として、本発明について、MO8FET デバイス中に浅いp−n接合を形成することに関して述べる。 製作工程の中間の段階におけるそのようなMOSデバイスの一部が、第1図て示 されており、そのような部分は周知のゲート及びソース及びドレイン(GASA D)構造から成る。構造は上に耐電界用酸rヒ物(二酸化シリコン)部分12. 14を有するシリコン基体1oがら唆る。 構造は更にゲート酸化物(二酸化シリコン)層16、ドープされたポリシリコン 層18及び金属シリサイド(たとえば、タンタル・シシリサイド)層2oを含む 。 また、構造は追加された二酸化シリコン層22.24を含む。開口25.26が 酸化物層12.22及び14.24によシ規定される。ソース及びドレイン領域 がその後これら開口に近接して位置合せされ、基体10中に形成される。 本発明 Shallow junction semiconductor devices Background of the invention The present invention relates to shallow junction semiconductor devices. Various semiconductors such as metal-oxide-semiconductor field-effect transistors (MOSFETs) In conductor devices, the p-n junction of the device should be as close to the substrate surface as possible. is desirable. The present invention provides a p-n junction that is much closer to the surface of the semiconductor substrate than was previously possible. Realize the means to do so. Summary of the invention Neutral species are first implanted into the surface region of the semiconductor body. - In the example, the neutral species is implanted, and the maximum concentration occurs deeper than the subsequently formed p-n junction. A layer is formed. (Another example (()) is deeper than the depth of the peak concentration of the neutral species layer. A bond is subsequently formed at the new location. ) The dopant species is then added to the previously injected medium. It is injected into the surface region at a shallower depth than the maximum depth of the species. Next, do Further annealing is performed to activate the punt species. During this annealing step, the neutral species layer acts as a getter for point defects in the device substrate. to read. In addition, this layer acts as a physical barrier to the diffusion of dopant species. Ku. As a result, the extent of diffusion of dopant species in the substrate is reduced when no neutral species layer is formed. In comparison, it is significantly lower. Eventually, it will be formed at an extremely shallow depth. Brief description of the drawing Figures 1 through 4 (showing the sequential steps of a fabrication process embodying the principles of the invention) MO! 1 schematically shows a portion of a 5FET device; FIG. detailed description According to the present invention, shallow, hull-n junctions can be formed in a variety of semiconductor devices. These devices include, for example, p-n diodes, bipolar transistors, and and MO3FET devices. As an example, for the present invention, MO8FET A discussion will be made regarding forming shallow p-n junctions in devices. A portion of such a MOS device at an intermediate stage of the fabrication process is shown in Figure 1. such parts are well-known gate, source and drain (GASA) D) consists of a structure. The structure consists of an acid and arsenide (silicon dioxide) portion for electric field resistance on top12. A silicon substrate 1o having a diameter of 14 is shown. The structure further includes a gate oxide (silicon dioxide) layer 16, doped polysilicon layer 18 and metal silicide (e.g., tantalum silicide) layer 2o. . The structure also includes an added silicon dioxide layer 22.24. opening 25.26 Defined by oxide layers 12.22 and 14.24. source and drain region are then aligned proximate these openings and formed in the substrate 10. present invention
【従うと、いわゆる中性種が、開O25,26により規定された基体10 の領域中に、注入される。周知のイオン注入技術が使用できる。 ″中性種パという用語は、半導体基体中に能動キャリヤを生じず、基体中の能動 様の拡散をおさえる働きをする物質を意味する。そのような中性種には、炭素、 酸素、アルゴン又は他の不活性気体、シリコン、ゲルマニウム及びスズのような ■族元素及び窒素(活性化率が小さい)が含まれる。 第2図の構造に向けられたイオンが、矢印28で表され、イオンは開口25.2 6を通してのみ、基体10に到達する。第2図において、基体10中に注入され た中性種のほぼガウス形分布のピーク又は量大濃度がXから成る線30.32に より、概;賂的に示されている。 たとえば、第2図に示された中性注入様のドーズ量は、ピーク濃度深さにおいて 、中・課程のほぼ1ないし2単原子層を生じるように、選択される。加えて、図 示されたMOSFETの例では、入射イオンのエネルギーハ、注入中課程のピー ク濃度が、基体10の表面下約2000八に生じるように、選択される。デバイ スによっては、中性注入様のピーク濃度は、その後基体10中に形成されるp− n接合の深さより、深い所に生じるように選択される。そのようなデバイスにお いて、その後形成されるp−n接合の深さは、たとえば中性種のピーク濃度の深 さのほぼ10分の1ないし4分の3の深さになる。(他のデバイスにおいて、以 下で述べるように、p n接合の深さは、中性・注入様のピークa度の深さより 大きい。)各種のドーズ量及びエネル牛−を用いることができる。 上で示した中性種に対する一組のドーズ量及びエネルギーの値は、以下のとうり である。炭素、1平方センチメートル当り(i/Cm2) 5X1o”’ 80 キロ電子ボルト(KeV);酸素、5×10151/cIn2.80 KeV ;シリコン、5×10151/Cm2.150KeV;ゲルマニウム、5X]0 ”’i/Cm2300 KeV ;スズ、5×1015】/cIn2.400 KeV ;アルゴン、5X1015i/cm” 、] 80 KeV ;及び窒 素5X]、0’51/c−In2.80Keyoこれらの値に対して、中性種の それぞれのピーク濃度深さは、第2図(に示される基体10の表面下、約200 0人である。 すべての場合ではないが、場合によってd、第21スに示されたデバイスの構造 は、次にアニーリング工程を受ける。(ヒ素のようなその後に導入される活性種 の場合、製作工程のこの時点で、注入された中性種をアニールしない方が、実際 には有利であろう。)このアニーリング工8において、中性種注入により生じた 基体10の結晶構造の損傷が、減少する。更に、注入様は安定化され、実効的に 基体10中に閉じ込められる。また、基体10中の欠陥及び不純物をある程度ゲ ッタリンクすることが、このア二−リンク工程中起る。 アニーリングは、たとえば不活性雰囲気中、約30分間、700ないし900℃ の範囲の温度で、行われる。 アニーリング中、注入された中性種の本質的な垂直又は横方向の移動は、起らな い。以下で述べる後のいわゆる活性化アニーリング工程中も、本質的な移動は起 らない。 次に、活性種が、たとえばイオン注入により、各種の周知の手段のいずれかによ り、第3図中の矢印34で示されるように、構造に導入される。注入された活性 種は、たとえばヒ素、リン又はアンチモンのような5価p形不純物、或いはホウ 素又はガリウムのような3価n形不純′吻から成る。 基体10中の活性注入柱のほぼガウス型分布のピーク又は最大濃度の深さは、点 から成る@3・6.38により1、第3図中に概略的に示されている。 注入された活性種のピーク濃度は、たとえば約200ないし100OAの深さと いった基体1oの最上部表面に、比較的近接して生じる。 よシ具体的には、約2000へのピーク濃度深さ30゜32(第3図)を有する 炭素中性注入様の場き、約200人のピーク濃度深さ36.38を有するヒ素注 入は、30 KeVにおける4X10I5i/cm2の注入により達成される。 約2000へのピーク濃度深さ30,32(第3図)を有する炭素又は窒素注入 の場合、約100 OAのピーク濃度深さ36.38を有するホウ素注入は、3 ’0KeVにおける4 X 10 ” i/cIt2の注入によシ達成される。 続いて第2の注入工程又は活性ドーパント種の、標準的な活性化アニーリングが 行われる。この工程中、基体10中で点欠陥及び金属不純物のゲッタリングが起 ると、信じられている。このゲッタリング動作のため、活性種の熱拡散は、中性 種注入を行わない場合よシ、本質的に抑えられることがわかる。加えて、先に形 成された中性注入種は、活性種の拡散に対する物理的な障壁として働くことがわ かる。しかし、含まれる物理的な現象にかかわらず、ここで述べたプロセスの結 果は、活性種の注入により形成されたp−n接合は、もし中性種注入を行5つな い場合に生じる深さより、はるかに浅い所に生じるということである。それによ り、きわめて浅いp−n接合が形成される。 ヒ素の活性種注入の場合、活性化アニーリングは、たとえば約1000℃で約3 時間、標準的なおだやかな乾式酸化雰囲気中で行われる。得られるp−n接合は 、約1400Aの深さにある。あらかじめ中性種の注入を行わず、他のすべての プロセス条件をほぼ同じに保つならば、p−n接合は約3700への深さになる 。 ホウ素の活性種注入の場合、活性化アニーリングは、たとえば約900℃で約5 時間、標準的なおだやかな乾式酸化雰囲気中で行われる。p−n接合は、約33 00Aに生じる。中性種の注入を行わず、すべての他のプロセス条件全回じにす るならば、p−n接合は約6700Aの深さに生じる。 活性種がヒ素から成る上の例において、p n接合は注入された中性種層のピー ク濃度の深さよシ、浅い所になる。逆に、活性種がホウ素から成る上の例におい て、p −n接合は注入された中性種層のピーク濃度の深さより深い所になる。 一般に、注入された中性種層のピーク濃度の深さの、約10分の1ないし2倍の 範囲の深さに、p−n接合を形成することが可能である。 注入された中性種層のピークa度の深さより浅い深さに、多くの方法でp−n接 合を形成することが可能である。たとえば、活性不純物様に対しては、最初、上 でホウ素に対して示した深さより浅いデバイス構造中に導入するか、上で述べた より低温で構造を活性化アニーリングすることのいずれか又は両方を行うことが できる。あるいは、中性種層のピーク濃度は、最初十分深く形成し、アニーリン グ後接合が中性種層のピーク濃度の深さより、浅い所に形成されるようにするこ ともできる。 国際調査報告[Accordingly, the so-called neutral species is the substrate 10 defined by the open O25,26 is injected into the area. Well known ion implantation techniques can be used. ``The term neutral specie does not produce active carriers in the semiconductor substrate and A substance that works to suppress the diffusion of substances. Such neutral species include carbon, oxygen, argon or other inert gases, such as silicon, germanium and tin Contains group Ⅰ elements and nitrogen (low activation rate). Ions directed into the structure of FIG. 2 are represented by arrows 28, and the ions are The base body 10 is reached only through 6. In FIG. 2, injected into the substrate 10, The peak or mass concentration of the nearly Gaussian distribution of neutral species is on the line 30.32 consisting of X. It's more like a bribe. For example, the neutral implant-like dose shown in Figure 2 is , is selected to yield approximately 1 to 2 monolayers of medium to high density. In addition, fig. In the MOSFET example shown, the energy of the incident ion is The concentration is selected to occur approximately 2,000 times below the surface of the substrate 10. Debye Depending on the source, the neutral implant-like peak concentration may be affected by the p- It is selected so that it occurs deeper than the depth of the n-junction. For such devices The depth of the subsequently formed p-n junction is, for example, the depth of the peak concentration of neutral species. The depth is about one-tenth to three-quarters of the original size. (On other devices, As discussed below, the depth of the pn junction is greater than the depth of the neutral/injection-like peak a degree. big. ) Various doses and energies can be used. The set of dose and energy values for the neutral species shown above is as follows: It is. Carbon, per square centimeter (i/Cm2) 5X1o”’80 Kiloelectron volt (KeV); oxygen, 5×10151/cIn2.80 KeV ;Silicon, 5×10151/Cm2.150KeV;Germanium, 5X]0 ”’i/Cm2300 KeV; Tin, 5×1015]/cIn2.400 KeV; argon, 5X1015i/cm",] 80 KeV; and nitrogen element 5X], 0'51/c-In2.80KeyoFor these values, the neutral species The depth of each peak concentration is approximately 200 mm below the surface of the substrate 10 shown in FIG. There are 0 people. In some cases, but not all cases, d, the structure of the device shown in paragraph 21. is then subjected to an annealing step. (active species introduced subsequently such as arsenic) , it is actually better not to anneal the injected neutral species at this point in the fabrication process. would be advantageous. ) In this annealing process 8, the Damage to the crystal structure of the substrate 10 is reduced. Furthermore, the injection pattern is stabilized and effectively It is confined within the base body 10. Also, defects and impurities in the substrate 10 can be removed to some extent. terlinking occurs during this anneal linking process. Annealing can be carried out, for example, at 700 to 900° C. for about 30 minutes in an inert atmosphere. It is carried out at a temperature in the range of . During annealing, no substantial vertical or lateral movement of the implanted neutral species occurs. stomach. During the later so-called activation annealing step described below, no essential migration occurs. No. Activated species are then introduced by any of a variety of well-known means, such as by ion implantation. is introduced into the structure as indicated by arrow 34 in FIG. injected activity The seeds may contain pentavalent p-type impurities such as arsenic, phosphorous or antimony, or boron. It consists of trivalent n-type impurities such as elemental or gallium. The depth of the peak or maximum concentration of the approximately Gaussian distribution of active injection columns in the substrate 10 is at the point 1, schematically illustrated in FIG. The peak concentration of the injected active species may be, for example, at a depth of about 200 to 100 OA. occurs relatively close to the top surface of the substrate 1o. Specifically, it has a peak concentration depth of 30°32 (Figure 3) to about 2000 Carbon neutral injection-like field, arsenic injection with a peak concentration depth of about 200 36.38 The injection is achieved by implanting 4×10I5i/cm2 at 30 KeV. Carbon or nitrogen implantation with peak concentration depth 30,32 (Figure 3) to approximately 2000 For the case, a boron implant with a peak concentration depth of about 100 OA is 36.38 This is achieved by implanting 4×10” i/cIt2 at 0 KeV. A second implantation step or standard activation anneal of the active dopant species follows. It will be done. During this process, point defects and gettering of metal impurities occur in the substrate 10. It is believed that. Because of this gettering behavior, the thermal diffusion of active species becomes neutral. It can be seen that if seed injection is not performed, it can be essentially suppressed. In addition, the shape first The resulting neutral implant species is known to act as a physical barrier to the diffusion of active species. Karu. However, regardless of the physical phenomena involved, the outcome of the process described here is As a result, the p-n junction formed by the injection of active species is This means that it occurs at a much shallower depth than would otherwise occur. That's it As a result, an extremely shallow pn junction is formed. In the case of arsenic active species implantation, the activation annealing is, for example, about 3 time in a standard mild dry oxidizing atmosphere. The resulting p-n junction is , at a depth of about 1400A. Without prior injection of neutral species, all other If process conditions are kept approximately the same, the p-n junction will be approximately 3700 mm deep. . In the case of boron active species implantation, the activation annealing is, for example, about 5 time in a standard mild dry oxidizing atmosphere. The p-n junction is approximately 33 Occurs at 00A. No injection of neutral species and all other process conditions maintained throughout. If so, the p-n junction occurs at a depth of about 6700A. In the above example where the active species is arsenic, the pn junction is located at the peak of the implanted neutral species layer. Depending on the depth of the concentration, it will be shallow. Conversely, in the above example where the active species is boron, Therefore, the p-n junction is deeper than the depth of the peak concentration of the injected neutral species layer. Generally, the depth of the peak concentration of the injected neutral species layer is approximately one-tenth to twice the depth. It is possible to form p-n junctions to a range of depths. Many methods can be used to create a p-n junction at a depth shallower than the peak depth of the injected neutral species layer. It is possible to form a combination. For example, for active impurities, first or introduced into the device structure shallower than the depth shown for boron in or as described above. Either or both of activation annealing of the structure at a lower temperature can be performed. can. Alternatively, the peak concentration of the neutral species layer may be initially formed deep enough and annealed After mixing, the junction should be formed at a shallower depth than the depth of the peak concentration of the neutral species layer. Can also be done. international search report
Claims (1)
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US51675583A | 1983-07-25 | 1983-07-25 | |
US516755 | 1995-08-18 |
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JPS60501927A true JPS60501927A (en) | 1985-11-07 |
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JP59502397A Pending JPS60501927A (en) | 1983-07-25 | 1984-06-04 | Shallow junction semiconductor devices |
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EP (1) | EP0151585A4 (en) |
JP (1) | JPS60501927A (en) |
CA (1) | CA1222835A (en) |
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JPH05190849A (en) * | 1992-01-14 | 1993-07-30 | Oki Electric Ind Co Ltd | Manufacture of semiconductor device |
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US4683637A (en) * | 1986-02-07 | 1987-08-04 | Motorola, Inc. | Forming depthwise isolation by selective oxygen/nitrogen deep implant and reaction annealing |
US4786608A (en) * | 1986-12-30 | 1988-11-22 | Harris Corp. | Technique for forming electric field shielding layer in oxygen-implanted silicon substrate |
EP0350845A3 (en) * | 1988-07-12 | 1991-05-29 | Seiko Epson Corporation | Semiconductor device with doped regions and method for manufacturing it |
US5654209A (en) * | 1988-07-12 | 1997-08-05 | Seiko Epson Corporation | Method of making N-type semiconductor region by implantation |
JP2773957B2 (en) * | 1989-09-08 | 1998-07-09 | 富士通株式会社 | Method for manufacturing semiconductor device |
EP0806794A3 (en) * | 1996-04-29 | 1998-09-02 | Texas Instruments Incorporated | Method of forming shallow doped regions in a semiconductor substrate, using preamorphization and ion implantation |
JP4139907B2 (en) * | 1996-05-08 | 2008-08-27 | アドバンスト・マイクロ・ディバイシズ・インコーポレイテッド | Ion implantation method, integrated circuit manufacturing process, and integrated circuit MOS manufacturing process |
US6051460A (en) * | 1997-11-12 | 2000-04-18 | Advanced Micro Devices, Inc. | Preventing boron penetration through thin gate oxide of P-channel devices by doping polygate with silicon |
US6146934A (en) * | 1997-12-19 | 2000-11-14 | Advanced Micro Devices, Inc. | Semiconductor device with asymmetric PMOS source/drain implant and method of manufacture thereof |
US6013546A (en) * | 1997-12-19 | 2000-01-11 | Advanced Micro Devices, Inc. | Semiconductor device having a PMOS device with a source/drain region formed using a heavy atom p-type implant and method of manufacture thereof |
US6087209A (en) * | 1998-07-31 | 2000-07-11 | Advanced Micro Devices, Inc. | Formation of low resistance, ultra shallow LDD junctions employing a sub-surface, non-amorphous implant |
FR2828331A1 (en) * | 2001-07-31 | 2003-02-07 | St Microelectronics Sa | METHOD FOR MANUFACTURING BIPOLAR TRANSISTOR IN A CMOS INTEGRATED CIRCUIT |
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JPS492786B1 (en) * | 1969-03-28 | 1974-01-22 | ||
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JPS553828B2 (en) * | 1972-11-30 | 1980-01-26 | ||
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JPS53120263A (en) * | 1977-03-29 | 1978-10-20 | Nec Corp | Manufacture of semiconductor device |
JPS5583263A (en) * | 1978-12-19 | 1980-06-23 | Fujitsu Ltd | Mos semiconductor device |
JPS55121680A (en) * | 1979-03-13 | 1980-09-18 | Nec Corp | Manufacture of semiconductor device |
JPS5627924A (en) * | 1979-08-14 | 1981-03-18 | Toshiba Corp | Semiconductor device and its manufacture |
JPS5632742A (en) * | 1979-08-24 | 1981-04-02 | Toshiba Corp | Manufacture of semiconductor device |
JPS5693367A (en) * | 1979-12-20 | 1981-07-28 | Fujitsu Ltd | Manufacture of semiconductor device |
JPS577161A (en) * | 1980-06-16 | 1982-01-14 | Toshiba Corp | Mos semiconductor device |
JPS57106123A (en) * | 1980-12-24 | 1982-07-01 | Toshiba Corp | Manufacture of semiconductor device |
JPS5856417A (en) * | 1981-09-30 | 1983-04-04 | Toshiba Corp | Low-temperature activating method for boron ion implanted layer in silicon |
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1984
- 1984-06-04 JP JP59502397A patent/JPS60501927A/en active Pending
- 1984-06-04 WO PCT/US1984/000851 patent/WO1985000694A1/en not_active Application Discontinuation
- 1984-06-04 EP EP19840902405 patent/EP0151585A4/en not_active Withdrawn
- 1984-06-27 CA CA000457570A patent/CA1222835A/en not_active Expired
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JPH05190849A (en) * | 1992-01-14 | 1993-07-30 | Oki Electric Ind Co Ltd | Manufacture of semiconductor device |
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EP0151585A4 (en) | 1986-02-20 |
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