JPS6048488B2 - ブタンのプロパンへの接触的変換方法 - Google Patents
ブタンのプロパンへの接触的変換方法Info
- Publication number
- JPS6048488B2 JPS6048488B2 JP51071649A JP7164976A JPS6048488B2 JP S6048488 B2 JPS6048488 B2 JP S6048488B2 JP 51071649 A JP51071649 A JP 51071649A JP 7164976 A JP7164976 A JP 7164976A JP S6048488 B2 JPS6048488 B2 JP S6048488B2
- Authority
- JP
- Japan
- Prior art keywords
- butane
- hydrogen
- mordenite
- catalyst
- conversion
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000006243 chemical reaction Methods 0.000 title claims description 45
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 title claims description 41
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 title claims description 38
- 238000000034 method Methods 0.000 title claims description 27
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 title claims description 26
- 239000001273 butane Substances 0.000 title claims description 20
- 239000001294 propane Substances 0.000 title claims description 19
- 230000003197 catalytic effect Effects 0.000 title claims description 6
- 239000003054 catalyst Substances 0.000 claims description 43
- 229910052680 mordenite Inorganic materials 0.000 claims description 35
- 239000001257 hydrogen Substances 0.000 claims description 27
- 229910052739 hydrogen Inorganic materials 0.000 claims description 27
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 25
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 8
- 239000000654 additive Substances 0.000 claims description 7
- 230000000996 additive effect Effects 0.000 claims description 6
- 239000007788 liquid Substances 0.000 claims description 5
- 230000002378 acidificating effect Effects 0.000 claims description 3
- 229910052710 silicon Inorganic materials 0.000 claims description 3
- 239000002904 solvent Substances 0.000 claims description 2
- 229910002651 NO3 Inorganic materials 0.000 claims 1
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 claims 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims 1
- 229910052782 aluminium Inorganic materials 0.000 claims 1
- 239000010703 silicon Substances 0.000 claims 1
- NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 description 28
- 239000001282 iso-butane Substances 0.000 description 15
- 229930195733 hydrocarbon Natural products 0.000 description 12
- 150000002430 hydrocarbons Chemical class 0.000 description 12
- 230000000694 effects Effects 0.000 description 9
- 239000011148 porous material Substances 0.000 description 9
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 8
- 229910052675 erionite Inorganic materials 0.000 description 7
- 238000005336 cracking Methods 0.000 description 6
- 239000000203 mixture Substances 0.000 description 6
- 239000010457 zeolite Substances 0.000 description 6
- 229910021536 Zeolite Inorganic materials 0.000 description 5
- 238000004517 catalytic hydrocracking Methods 0.000 description 5
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 5
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 4
- 238000002441 X-ray diffraction Methods 0.000 description 4
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 4
- -1 butane Chemical class 0.000 description 4
- 239000001307 helium Substances 0.000 description 4
- 229910052734 helium Inorganic materials 0.000 description 4
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 4
- QWTDNUCVQCZILF-UHFFFAOYSA-N isopentane Chemical compound CCC(C)C QWTDNUCVQCZILF-UHFFFAOYSA-N 0.000 description 4
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 3
- 239000004215 Carbon black (E152) Substances 0.000 description 3
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 239000011575 calcium Substances 0.000 description 3
- 229910052791 calcium Inorganic materials 0.000 description 3
- 238000004523 catalytic cracking Methods 0.000 description 3
- 150000001768 cations Chemical class 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 150000002739 metals Chemical class 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- AFABGHUZZDYHJO-UHFFFAOYSA-N dimethyl butane Natural products CCCC(C)C AFABGHUZZDYHJO-UHFFFAOYSA-N 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 238000002347 injection Methods 0.000 description 2
- 239000007924 injection Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 150000004645 aluminates Chemical class 0.000 description 1
- 235000019270 ammonium chloride Nutrition 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- IAQRGUVFOMOMEM-UHFFFAOYSA-N butene Natural products CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 description 1
- 238000001354 calcination Methods 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 150000001722 carbon compounds Chemical class 0.000 description 1
- 238000003763 carbonization Methods 0.000 description 1
- 238000012512 characterization method Methods 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 229910002026 crystalline silica Inorganic materials 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000006356 dehydrogenation reaction Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- BCAARMUWIRURQS-UHFFFAOYSA-N dicalcium;oxocalcium;silicate Chemical compound [Ca+2].[Ca+2].[Ca]=O.[O-][Si]([O-])([O-])[O-] BCAARMUWIRURQS-UHFFFAOYSA-N 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 239000008246 gaseous mixture Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 238000004442 gravimetric analysis Methods 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 238000005984 hydrogenation reaction Methods 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 159000000001 potassium salts Chemical class 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C4/00—Preparation of hydrocarbons from hydrocarbons containing a larger number of carbon atoms
- C07C4/08—Preparation of hydrocarbons from hydrocarbons containing a larger number of carbon atoms by splitting-off an aliphatic or cycloaliphatic part from the molecule
- C07C4/10—Preparation of hydrocarbons from hydrocarbons containing a larger number of carbon atoms by splitting-off an aliphatic or cycloaliphatic part from the molecule from acyclic hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2529/00—Catalysts comprising molecular sieves
- C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
- C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- C07C2529/18—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the mordenite type
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S585/00—Chemistry of hydrocarbon compounds
- Y10S585/8995—Catalyst and recycle considerations
- Y10S585/906—Catalyst preservation or manufacture, e.g. activation before use
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR7518911A FR2314906A1 (fr) | 1975-06-17 | 1975-06-17 | Procede de transformation catalytique du butane |
| FR7518911 | 1975-06-17 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS52205A JPS52205A (en) | 1977-01-05 |
| JPS6048488B2 true JPS6048488B2 (ja) | 1985-10-28 |
Family
ID=9156633
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP51071649A Expired JPS6048488B2 (ja) | 1975-06-17 | 1976-06-17 | ブタンのプロパンへの接触的変換方法 |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US4061690A (show.php) |
| JP (1) | JPS6048488B2 (show.php) |
| BE (1) | BE842756A (show.php) |
| CA (1) | CA1070336A (show.php) |
| DE (1) | DE2626840C3 (show.php) |
| FR (1) | FR2314906A1 (show.php) |
| GB (1) | GB1507006A (show.php) |
| NO (1) | NO147147C (show.php) |
| SE (1) | SE420495B (show.php) |
Families Citing this family (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5759437A (en) * | 1980-09-27 | 1982-04-09 | Nippon Yusoki Co Ltd | Charger |
| US5900258A (en) * | 1996-02-01 | 1999-05-04 | Zeolitics Inc. | Anti-bacterial compositions |
| CN102807465B (zh) * | 2011-05-31 | 2015-04-29 | 中国石油化工股份有限公司 | 一种利用丁烷生产丙烷和汽油的方法 |
| SG11201704641VA (en) * | 2014-12-22 | 2017-07-28 | Sabic Global Technologies Bv | Process for producing c2 and c3 hydrocarbons |
| EA201791316A1 (ru) | 2014-12-22 | 2018-02-28 | Сабик Глобал Текнолоджис Б.В. | Способ получения lpg и btx |
| CN107109256B (zh) | 2014-12-22 | 2022-09-30 | 沙特基础工业全球技术有限公司 | 用于制备lpg和btx的方法 |
| CN114350408A (zh) | 2014-12-22 | 2022-04-15 | 沙特基础工业全球技术有限公司 | 用于生产c2和c3烃的方法 |
| EA201891045A1 (ru) | 2015-12-15 | 2018-11-30 | Сабик Глобал Текнолоджис Б.В. | Способ получения углеводородов c2 и c3 |
| US20200392415A1 (en) | 2018-02-22 | 2020-12-17 | Total Research & Technology Feluy | Selective Conversion of Paraffinic Naphtha to Propane in the Presence of Hydrogen |
| US11773037B2 (en) | 2019-03-05 | 2023-10-03 | Sabic Global Technologies B.V. | Distribution hub for C4 conversion to ethane/propane feedstock network |
| US11254628B1 (en) | 2020-07-28 | 2022-02-22 | Sabic Global Technologies B.V. | Methods of butane hydrogenolysis under hydrogen-lean conditions |
| CN113307717B (zh) * | 2021-06-11 | 2022-07-29 | 洛阳市科创石化科技开发有限公司 | 一种临氢轻烃转化生产丙烷的方法 |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3442795A (en) * | 1963-02-27 | 1969-05-06 | Mobil Oil Corp | Method for preparing highly siliceous zeolite-type materials and materials resulting therefrom |
| US3480539A (en) * | 1966-10-14 | 1969-11-25 | Exxon Research Engineering Co | Mordenite catalyst compositions |
| US3551353A (en) * | 1968-10-04 | 1970-12-29 | Mobil Oil Corp | Dealuminzation of mordenite |
-
1975
- 1975-06-17 FR FR7518911A patent/FR2314906A1/fr active Granted
-
1976
- 1976-06-09 US US05/694,434 patent/US4061690A/en not_active Expired - Lifetime
- 1976-06-09 BE BE167764A patent/BE842756A/xx not_active IP Right Cessation
- 1976-06-10 NO NO761994A patent/NO147147C/no unknown
- 1976-06-14 CA CA254,752A patent/CA1070336A/en not_active Expired
- 1976-06-15 DE DE2626840A patent/DE2626840C3/de not_active Expired
- 1976-06-16 SE SE7606851A patent/SE420495B/xx unknown
- 1976-06-16 GB GB24966/76A patent/GB1507006A/en not_active Expired
- 1976-06-17 JP JP51071649A patent/JPS6048488B2/ja not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| DE2626840C3 (de) | 1978-11-09 |
| NO147147B (no) | 1982-11-01 |
| SE7606851L (sv) | 1976-12-18 |
| NO147147C (no) | 1983-02-09 |
| JPS52205A (en) | 1977-01-05 |
| GB1507006A (en) | 1978-04-12 |
| DE2626840B2 (de) | 1978-03-16 |
| FR2314906B1 (show.php) | 1978-10-20 |
| BE842756A (fr) | 1976-10-01 |
| US4061690A (en) | 1977-12-06 |
| CA1070336A (en) | 1980-01-22 |
| DE2626840A1 (de) | 1976-12-23 |
| NO761994L (show.php) | 1976-12-20 |
| FR2314906A1 (fr) | 1977-01-14 |
| SE420495B (sv) | 1981-10-12 |
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