JPS60206845A - 発泡性熱可塑性共重合体粒子 - Google Patents
発泡性熱可塑性共重合体粒子Info
- Publication number
- JPS60206845A JPS60206845A JP6462884A JP6462884A JPS60206845A JP S60206845 A JPS60206845 A JP S60206845A JP 6462884 A JP6462884 A JP 6462884A JP 6462884 A JP6462884 A JP 6462884A JP S60206845 A JPS60206845 A JP S60206845A
- Authority
- JP
- Japan
- Prior art keywords
- weight
- flame retardant
- copolymer particles
- expandable thermoplastic
- thermoplastic copolymer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000002245 particle Substances 0.000 title claims abstract description 28
- 229920001169 thermoplastic Polymers 0.000 title claims description 16
- 239000004416 thermosoftening plastic Substances 0.000 title claims description 16
- 239000003063 flame retardant Substances 0.000 claims abstract description 43
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 claims abstract description 34
- 229920001577 copolymer Polymers 0.000 claims abstract description 11
- 239000000178 monomer Substances 0.000 claims abstract description 10
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims abstract description 8
- HGTUJZTUQFXBIH-UHFFFAOYSA-N (2,3-dimethyl-3-phenylbutan-2-yl)benzene Chemical compound C=1C=CC=CC=1C(C)(C)C(C)(C)C1=CC=CC=C1 HGTUJZTUQFXBIH-UHFFFAOYSA-N 0.000 claims abstract description 4
- SBYMUDUGTIKLCR-UHFFFAOYSA-N 2-chloroethenylbenzene Chemical compound ClC=CC1=CC=CC=C1 SBYMUDUGTIKLCR-UHFFFAOYSA-N 0.000 claims abstract description 4
- DXIJHCSGLOHNES-UHFFFAOYSA-N 3,3-dimethylbut-1-enylbenzene Chemical compound CC(C)(C)C=CC1=CC=CC=C1 DXIJHCSGLOHNES-UHFFFAOYSA-N 0.000 claims abstract description 4
- 238000000354 decomposition reaction Methods 0.000 claims abstract description 4
- 150000001875 compounds Chemical class 0.000 claims abstract description 3
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 13
- 239000000203 mixture Substances 0.000 claims description 10
- 239000004604 Blowing Agent Substances 0.000 claims description 9
- -1 acrylic ester Chemical class 0.000 claims description 5
- 229920000642 polymer Polymers 0.000 claims description 4
- 150000002430 hydrocarbons Chemical group 0.000 claims description 3
- 125000000217 alkyl group Chemical group 0.000 claims description 2
- 239000000446 fuel Substances 0.000 claims description 2
- 229910052736 halogen Inorganic materials 0.000 claims description 2
- 238000002844 melting Methods 0.000 claims description 2
- 230000008018 melting Effects 0.000 claims description 2
- RYICYNDRTWLWAN-UHFFFAOYSA-N (2,3-dimethyl-4-phenylhexan-3-yl)benzene Chemical compound C=1C=CC=CC=1C(C)(C(C)C)C(CC)C1=CC=CC=C1 RYICYNDRTWLWAN-UHFFFAOYSA-N 0.000 claims 1
- SHRRVNVEOIKVSG-UHFFFAOYSA-N 1,1,2,2,3,3-hexabromocyclododecane Chemical group BrC1(Br)CCCCCCCCCC(Br)(Br)C1(Br)Br SHRRVNVEOIKVSG-UHFFFAOYSA-N 0.000 claims 1
- 239000012752 auxiliary agent Substances 0.000 claims 1
- 239000003795 chemical substances by application Substances 0.000 claims 1
- 125000005843 halogen group Chemical group 0.000 claims 1
- 125000005397 methacrylic acid ester group Chemical group 0.000 claims 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims 1
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 abstract description 7
- JLBJTVDPSNHSKJ-UHFFFAOYSA-N 4-Methylstyrene Chemical compound CC1=CC=C(C=C)C=C1 JLBJTVDPSNHSKJ-UHFFFAOYSA-N 0.000 abstract description 4
- 239000004088 foaming agent Substances 0.000 abstract description 4
- DEIGXXQKDWULML-UHFFFAOYSA-N 1,2,5,6,9,10-hexabromocyclododecane Chemical compound BrC1CCC(Br)C(Br)CCC(Br)C(Br)CCC1Br DEIGXXQKDWULML-UHFFFAOYSA-N 0.000 abstract description 3
- WQJUBZMZVKITBU-UHFFFAOYSA-N (3,4-dimethyl-4-phenylhexan-3-yl)benzene Chemical compound C=1C=CC=CC=1C(C)(CC)C(C)(CC)C1=CC=CC=C1 WQJUBZMZVKITBU-UHFFFAOYSA-N 0.000 abstract 1
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 abstract 1
- 230000001747 exhibiting effect Effects 0.000 abstract 1
- 230000000979 retarding effect Effects 0.000 abstract 1
- 238000006116 polymerization reaction Methods 0.000 description 10
- 229920005989 resin Polymers 0.000 description 9
- 239000011347 resin Substances 0.000 description 9
- 238000000034 method Methods 0.000 description 7
- 238000006243 chemical reaction Methods 0.000 description 5
- 239000002270 dispersing agent Substances 0.000 description 5
- 239000006260 foam Substances 0.000 description 5
- 238000012662 bulk polymerization Methods 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- 238000010438 heat treatment Methods 0.000 description 4
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 4
- 238000010557 suspension polymerization reaction Methods 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 238000010556 emulsion polymerization method Methods 0.000 description 3
- 238000002474 experimental method Methods 0.000 description 3
- 239000011810 insulating material Substances 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
- 239000008188 pellet Substances 0.000 description 3
- RGSFGYAAUTVSQA-UHFFFAOYSA-N Cyclopentane Chemical compound C1CCCC1 RGSFGYAAUTVSQA-UHFFFAOYSA-N 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 2
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- 239000001273 butane Substances 0.000 description 2
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 2
- DIOQZVSQGTUSAI-UHFFFAOYSA-N decane Chemical compound CCCCCCCCCC DIOQZVSQGTUSAI-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 239000003999 initiator Substances 0.000 description 2
- 125000005395 methacrylic acid group Chemical group 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 2
- 238000005453 pelletization Methods 0.000 description 2
- 238000002791 soaking Methods 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 2
- 238000010558 suspension polymerization method Methods 0.000 description 2
- QORWJWZARLRLPR-UHFFFAOYSA-H tricalcium bis(phosphate) Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O QORWJWZARLRLPR-UHFFFAOYSA-H 0.000 description 2
- 235000019731 tricalcium phosphate Nutrition 0.000 description 2
- LNAZSHAWQACDHT-XIYTZBAFSA-N (2r,3r,4s,5r,6s)-4,5-dimethoxy-2-(methoxymethyl)-3-[(2s,3r,4s,5r,6r)-3,4,5-trimethoxy-6-(methoxymethyl)oxan-2-yl]oxy-6-[(2r,3r,4s,5r,6r)-4,5,6-trimethoxy-2-(methoxymethyl)oxan-3-yl]oxyoxane Chemical compound CO[C@@H]1[C@@H](OC)[C@H](OC)[C@@H](COC)O[C@H]1O[C@H]1[C@H](OC)[C@@H](OC)[C@H](O[C@H]2[C@@H]([C@@H](OC)[C@H](OC)O[C@@H]2COC)OC)O[C@@H]1COC LNAZSHAWQACDHT-XIYTZBAFSA-N 0.000 description 1
- AUTSLLHNWAZVLE-UHFFFAOYSA-N 1,1,2,2,3-pentabromo-3-chlorocyclohexane Chemical compound ClC1(Br)CCCC(Br)(Br)C1(Br)Br AUTSLLHNWAZVLE-UHFFFAOYSA-N 0.000 description 1
- DDMOUSALMHHKOS-UHFFFAOYSA-N 1,2-dichloro-1,1,2,2-tetrafluoroethane Chemical compound FC(F)(Cl)C(F)(F)Cl DDMOUSALMHHKOS-UHFFFAOYSA-N 0.000 description 1
- HQOVXPHOJANJBR-UHFFFAOYSA-N 2,2-bis(tert-butylperoxy)butane Chemical compound CC(C)(C)OOC(C)(CC)OOC(C)(C)C HQOVXPHOJANJBR-UHFFFAOYSA-N 0.000 description 1
- WBIQQQGBSDOWNP-UHFFFAOYSA-N 2-dodecylbenzenesulfonic acid Chemical compound CCCCCCCCCCCCC1=CC=CC=C1S(O)(=O)=O WBIQQQGBSDOWNP-UHFFFAOYSA-N 0.000 description 1
- VEORPZCZECFIRK-UHFFFAOYSA-N 3,3',5,5'-tetrabromobisphenol A Chemical compound C=1C(Br)=C(O)C(Br)=CC=1C(C)(C)C1=CC(Br)=C(O)C(Br)=C1 VEORPZCZECFIRK-UHFFFAOYSA-N 0.000 description 1
- ATVJXMYDOSMEPO-UHFFFAOYSA-N 3-prop-2-enoxyprop-1-ene Chemical compound C=CCOCC=C ATVJXMYDOSMEPO-UHFFFAOYSA-N 0.000 description 1
- 235000011293 Brassica napus Nutrition 0.000 description 1
- 240000008100 Brassica rapa Species 0.000 description 1
- 235000000540 Brassica rapa subsp rapa Nutrition 0.000 description 1
- PMPVIKIVABFJJI-UHFFFAOYSA-N Cyclobutane Chemical compound C1CCC1 PMPVIKIVABFJJI-UHFFFAOYSA-N 0.000 description 1
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- 239000004115 Sodium Silicate Substances 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 1
- 150000004996 alkyl benzenes Chemical class 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 230000001588 bifunctional effect Effects 0.000 description 1
- HAISMSJTPGJFIP-UHFFFAOYSA-N butyl 4-tert-butyl-4,5,5-trimethylhexaneperoxoate Chemical class CCCCOOC(=O)CCC(C)(C(C)(C)C)C(C)(C)C HAISMSJTPGJFIP-UHFFFAOYSA-N 0.000 description 1
- JUNWLZAGQLJVLR-UHFFFAOYSA-J calcium diphosphate Chemical compound [Ca+2].[Ca+2].[O-]P([O-])(=O)OP([O-])([O-])=O JUNWLZAGQLJVLR-UHFFFAOYSA-J 0.000 description 1
- 239000001506 calcium phosphate Substances 0.000 description 1
- 229940043256 calcium pyrophosphate Drugs 0.000 description 1
- NEHMKBQYUWJMIP-NJFSPNSNSA-N chloro(114C)methane Chemical compound [14CH3]Cl NEHMKBQYUWJMIP-NJFSPNSNSA-N 0.000 description 1
- HRYZWHHZPQKTII-UHFFFAOYSA-N chloroethane Chemical compound CCCl HRYZWHHZPQKTII-UHFFFAOYSA-N 0.000 description 1
- 239000000701 coagulant Substances 0.000 description 1
- 230000001112 coagulating effect Effects 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- DDTBPAQBQHZRDW-UHFFFAOYSA-N cyclododecane Chemical compound C1CCCCCCCCCCC1 DDTBPAQBQHZRDW-UHFFFAOYSA-N 0.000 description 1
- 235000019821 dicalcium diphosphate Nutrition 0.000 description 1
- UMNKXPULIDJLSU-UHFFFAOYSA-N dichlorofluoromethane Chemical compound FC(Cl)Cl UMNKXPULIDJLSU-UHFFFAOYSA-N 0.000 description 1
- 229940099364 dichlorofluoromethane Drugs 0.000 description 1
- 229940087091 dichlorotetrafluoroethane Drugs 0.000 description 1
- 229940060296 dodecylbenzenesulfonic acid Drugs 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 238000007720 emulsion polymerization reaction Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- SUPCQIBBMFXVTL-UHFFFAOYSA-N ethyl 2-methylprop-2-enoate Chemical compound CCOC(=O)C(C)=C SUPCQIBBMFXVTL-UHFFFAOYSA-N 0.000 description 1
- 229960003750 ethyl chloride Drugs 0.000 description 1
- 229920006248 expandable polystyrene Polymers 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 150000008282 halocarbons Chemical class 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- DMEGYFMYUHOHGS-UHFFFAOYSA-N heptamethylene Natural products C1CCCCCC1 DMEGYFMYUHOHGS-UHFFFAOYSA-N 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- 229910001629 magnesium chloride Inorganic materials 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 229960002900 methylcellulose Drugs 0.000 description 1
- 235000010981 methylcellulose Nutrition 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 150000001451 organic peroxides Chemical class 0.000 description 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 239000003505 polymerization initiator Substances 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- HNJBEVLQSNELDL-UHFFFAOYSA-N pyrrolidin-2-one Chemical compound O=C1CCCN1 HNJBEVLQSNELDL-UHFFFAOYSA-N 0.000 description 1
- 150000003254 radicals Chemical class 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
- 229910052911 sodium silicate Inorganic materials 0.000 description 1
- 229940032158 sodium silicate Drugs 0.000 description 1
- 235000019794 sodium silicate Nutrition 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 150000003440 styrenes Chemical class 0.000 description 1
- 125000003011 styrenyl group Chemical group [H]\C(*)=C(/[H])C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
- VEQHTYHLJYNSTG-UHFFFAOYSA-N tert-butyl 9-tert-butylperoxy-9-oxononanoate Chemical compound CC(C)(C)OOC(=O)CCCCCCCC(=O)OC(C)(C)C VEQHTYHLJYNSTG-UHFFFAOYSA-N 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 229920005992 thermoplastic resin Polymers 0.000 description 1
- 229910000391 tricalcium phosphate Inorganic materials 0.000 description 1
- 229940078499 tricalcium phosphate Drugs 0.000 description 1
- CYRMSUTZVYGINF-UHFFFAOYSA-N trichlorofluoromethane Chemical compound FC(Cl)(Cl)Cl CYRMSUTZVYGINF-UHFFFAOYSA-N 0.000 description 1
- 229940029284 trichlorofluoromethane Drugs 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
- 229960001296 zinc oxide Drugs 0.000 description 1
- 235000014692 zinc oxide Nutrition 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Landscapes
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP6462884A JPS60206845A (ja) | 1984-03-30 | 1984-03-30 | 発泡性熱可塑性共重合体粒子 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP6462884A JPS60206845A (ja) | 1984-03-30 | 1984-03-30 | 発泡性熱可塑性共重合体粒子 |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS60206845A true JPS60206845A (ja) | 1985-10-18 |
JPH0461896B2 JPH0461896B2 (enrdf_load_stackoverflow) | 1992-10-02 |
Family
ID=13263708
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP6462884A Granted JPS60206845A (ja) | 1984-03-30 | 1984-03-30 | 発泡性熱可塑性共重合体粒子 |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS60206845A (enrdf_load_stackoverflow) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH04154847A (ja) * | 1990-10-19 | 1992-05-27 | Sekisui Plastics Co Ltd | 難燃性発泡性樹脂粒子の製造法 |
EP0680831A1 (en) * | 1994-05-04 | 1995-11-08 | Dsm N.V. | Shaped article with a marking on a thermoplastic substrate and a process for the manufacture of the shaped article |
JP2016164213A (ja) * | 2015-03-06 | 2016-09-08 | 株式会社カネカ | 発泡性樹脂粒子とその製造方法 |
JP2019521196A (ja) * | 2016-07-08 | 2019-07-25 | ベルサリス、ソシエタ、ペル、アチオニVersalis S.P.A. | 自己消化性及び改善された加工性を有する芳香族ビニルポリマーを含有する発泡性組成物 |
Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS52142764A (en) * | 1976-05-24 | 1977-11-28 | Arco Polymers Inc | Antioxidant for |
JPS532910A (en) * | 1976-06-30 | 1978-01-12 | Matsushita Electric Works Ltd | Fitting method of ceiling board |
JPS543510A (en) * | 1977-06-09 | 1979-01-11 | Teac Corp | Cassette tape magnetic recorder*reproducer |
JPS5765735A (en) * | 1980-09-13 | 1982-04-21 | Kanegafuchi Chem Ind Co Ltd | Heat-resistant expandable synthetic resin particle and molded article thereof |
JPS57111337A (en) * | 1980-12-29 | 1982-07-10 | Achilles Corp | Foamable polystyrene resin composition with flame retardancy |
JPS57111332A (en) * | 1980-12-27 | 1982-07-10 | Badische Yuka Co Ltd | Self-extinguishing polystyrene resin particle |
JPS57185328A (en) * | 1982-04-07 | 1982-11-15 | Dow Chemical Co | Foam-linked body with foamable synthetic resin particles |
-
1984
- 1984-03-30 JP JP6462884A patent/JPS60206845A/ja active Granted
Patent Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS52142764A (en) * | 1976-05-24 | 1977-11-28 | Arco Polymers Inc | Antioxidant for |
JPS532910A (en) * | 1976-06-30 | 1978-01-12 | Matsushita Electric Works Ltd | Fitting method of ceiling board |
JPS543510A (en) * | 1977-06-09 | 1979-01-11 | Teac Corp | Cassette tape magnetic recorder*reproducer |
JPS5765735A (en) * | 1980-09-13 | 1982-04-21 | Kanegafuchi Chem Ind Co Ltd | Heat-resistant expandable synthetic resin particle and molded article thereof |
JPS57111332A (en) * | 1980-12-27 | 1982-07-10 | Badische Yuka Co Ltd | Self-extinguishing polystyrene resin particle |
JPS57111337A (en) * | 1980-12-29 | 1982-07-10 | Achilles Corp | Foamable polystyrene resin composition with flame retardancy |
JPS57185328A (en) * | 1982-04-07 | 1982-11-15 | Dow Chemical Co | Foam-linked body with foamable synthetic resin particles |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH04154847A (ja) * | 1990-10-19 | 1992-05-27 | Sekisui Plastics Co Ltd | 難燃性発泡性樹脂粒子の製造法 |
EP0680831A1 (en) * | 1994-05-04 | 1995-11-08 | Dsm N.V. | Shaped article with a marking on a thermoplastic substrate and a process for the manufacture of the shaped article |
BE1008341A3 (nl) * | 1994-05-04 | 1996-04-02 | Dsm Nv | Vormdeel met een markering op een ondergrond van een thermoplastische kunststof en een werkwijze voor de bereiding van het vormdeel. |
JP2016164213A (ja) * | 2015-03-06 | 2016-09-08 | 株式会社カネカ | 発泡性樹脂粒子とその製造方法 |
JP2019521196A (ja) * | 2016-07-08 | 2019-07-25 | ベルサリス、ソシエタ、ペル、アチオニVersalis S.P.A. | 自己消化性及び改善された加工性を有する芳香族ビニルポリマーを含有する発泡性組成物 |
US11359066B2 (en) | 2016-07-08 | 2022-06-14 | Versalis S.P.A. | Expandable compositions containing aromatic vinyl polymers having self-extinguishing properties and improved processability |
Also Published As
Publication number | Publication date |
---|---|
JPH0461896B2 (enrdf_load_stackoverflow) | 1992-10-02 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US4303757A (en) | Process for producing expandable thermoplastic resin beads using polypropylene as nucleus | |
JP2009536687A (ja) | 断熱特性に優れた発泡性ポリスチレン粒子の2段階製造方法 | |
US4337319A (en) | Self-extinguishing, fine particulate expandable styrene polymers | |
JP3093552B2 (ja) | 寸法安定性のよい難燃性発泡体製造用樹脂粒子及びその製造方法 | |
JP2007246566A (ja) | 発泡性熱可塑性樹脂粒子及び該発泡性熱可塑性樹脂粒子から得られる発泡成形体 | |
JPH04183706A (ja) | スチレン改質ポリエチレン系樹脂粒子の製造法 | |
JP4007738B2 (ja) | 発泡性熱可塑性共重合体粒子 | |
JPH03162425A (ja) | 発泡性スチロールポリマー及びそれから形成された芳香族耐性発泡体 | |
JPS60206845A (ja) | 発泡性熱可塑性共重合体粒子 | |
US4539335A (en) | Expandable thermoplastic resin particles and process for preparing the same | |
KR101099027B1 (ko) | 난연성이 우수한 발포성 폴리스티렌 입자의 제조 방법 | |
JP2003335891A (ja) | 発泡性ポリスチレン系樹脂粒子、ポリスチレン系発泡成形体、およびその製造方法 | |
JP2002194130A (ja) | 発泡性ポリスチレン系樹脂粒子及びその製造方法 | |
US3631132A (en) | Flame resistant expandable styrene polymers containing tribromophenyl-dibromopropyl ether and method of preparing | |
JPH0513174B2 (enrdf_load_stackoverflow) | ||
JPS60206849A (ja) | 発泡性熱可塑性共重合体粒子の製造方法 | |
JPH11255946A (ja) | 難燃性を有する発泡性スチレン系樹脂粒子およびその製造方法 | |
JPS5858372B2 (ja) | 発泡可能な自消性熱可塑性樹脂粒子の製造方法 | |
JPS60206848A (ja) | 発泡性熱可塑性共重合体粒子製造の方法 | |
JP2005281595A (ja) | スチレン改質ポリオレフィン系樹脂粒子、発泡性樹脂粒子、予備発泡樹脂粒子、発泡成形体及びスチレン改質ポリオレフィン系樹脂粒子の製造方法 | |
JPS5841302B2 (ja) | 難燃性を有する発泡性ポリスチレン樹脂組成物 | |
JP3093551B2 (ja) | 寸法安定性のよい難燃性発泡体製造用樹脂粒子及びその製造方法 | |
JP2002146083A (ja) | 耐熱難燃性アクリロニトリル・スチレン樹脂粒子及びこれを用いた発泡成形品 | |
JPS619432A (ja) | 球状のプロピレン系樹脂粒子の製造方法 | |
KR100742946B1 (ko) | 강도가 우수한 발포성 스티렌계 수지 입자, 그 제조방법및 상기 수지입자로 제조된 발포 성형품 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
LAPS | Cancellation because of no payment of annual fees |