JPS60166247A - 燐酸塩ガラスセラミツク材料 - Google Patents
燐酸塩ガラスセラミツク材料Info
- Publication number
- JPS60166247A JPS60166247A JP60009299A JP929985A JPS60166247A JP S60166247 A JPS60166247 A JP S60166247A JP 60009299 A JP60009299 A JP 60009299A JP 929985 A JP929985 A JP 929985A JP S60166247 A JPS60166247 A JP S60166247A
- Authority
- JP
- Japan
- Prior art keywords
- ceramic material
- mass
- phosphate glass
- glass
- phase
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229910010293 ceramic material Inorganic materials 0.000 title claims description 9
- 239000005365 phosphate glass Substances 0.000 title claims description 6
- 239000006112 glass ceramic composition Substances 0.000 claims description 33
- 229910052586 apatite Inorganic materials 0.000 claims description 21
- VSIIXMUUUJUKCM-UHFFFAOYSA-D pentacalcium;fluoride;triphosphate Chemical compound [F-].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O VSIIXMUUUJUKCM-UHFFFAOYSA-D 0.000 claims description 21
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 21
- 229910019142 PO4 Inorganic materials 0.000 claims description 19
- 239000010452 phosphate Substances 0.000 claims description 19
- 239000013078 crystal Substances 0.000 claims description 14
- 239000011521 glass Substances 0.000 claims description 13
- ILRRQNADMUWWFW-UHFFFAOYSA-K aluminium phosphate Chemical compound O1[Al]2OP1(=O)O2 ILRRQNADMUWWFW-UHFFFAOYSA-K 0.000 claims description 9
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 7
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 7
- 239000000203 mixture Substances 0.000 claims description 7
- 239000000463 material Substances 0.000 claims description 6
- -1 fluoro-hydroxy Chemical group 0.000 claims description 5
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 4
- 229910052742 iron Inorganic materials 0.000 claims description 4
- 229910052587 fluorapatite Inorganic materials 0.000 claims description 3
- 229910052588 hydroxylapatite Inorganic materials 0.000 claims description 3
- 238000000034 method Methods 0.000 claims description 3
- XYJRXVWERLGGKC-UHFFFAOYSA-D pentacalcium;hydroxide;triphosphate Chemical compound [OH-].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O XYJRXVWERLGGKC-UHFFFAOYSA-D 0.000 claims description 3
- JLVVSXFLKOJNIY-UHFFFAOYSA-N Magnesium ion Chemical compound [Mg+2] JLVVSXFLKOJNIY-UHFFFAOYSA-N 0.000 claims description 2
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 2
- 239000008187 granular material Substances 0.000 claims description 2
- 229910001425 magnesium ion Inorganic materials 0.000 claims description 2
- 229920002635 polyurethane Polymers 0.000 claims description 2
- 239000004814 polyurethane Substances 0.000 claims description 2
- 229910001414 potassium ion Inorganic materials 0.000 claims description 2
- 229910052905 tridymite Inorganic materials 0.000 claims description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims 2
- 239000002639 bone cement Substances 0.000 claims 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 claims 1
- 239000011777 magnesium Substances 0.000 claims 1
- 239000012778 molding material Substances 0.000 claims 1
- 150000003839 salts Chemical class 0.000 claims 1
- 229910001415 sodium ion Inorganic materials 0.000 claims 1
- 210000000988 bone and bone Anatomy 0.000 description 9
- 230000000975 bioactive effect Effects 0.000 description 6
- 238000002425 crystallisation Methods 0.000 description 5
- 230000008025 crystallization Effects 0.000 description 5
- 150000001875 compounds Chemical class 0.000 description 4
- 239000003462 bioceramic Substances 0.000 description 3
- 239000000316 bone substitute Substances 0.000 description 3
- 239000010453 quartz Substances 0.000 description 3
- 239000011734 sodium Substances 0.000 description 3
- 241001465754 Metazoa Species 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 239000003814 drug Substances 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 230000004927 fusion Effects 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 239000007943 implant Substances 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- 125000002467 phosphate group Chemical group [H]OP(=O)(O[H])O[*] 0.000 description 2
- 210000001519 tissue Anatomy 0.000 description 2
- 208000010392 Bone Fractures Diseases 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 238000002441 X-ray diffraction Methods 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 239000006121 base glass Substances 0.000 description 1
- 239000012620 biological material Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 210000001124 body fluid Anatomy 0.000 description 1
- 239000010839 body fluid Substances 0.000 description 1
- 230000008468 bone growth Effects 0.000 description 1
- 239000013590 bulk material Substances 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- IJKVHSBPTUYDLN-UHFFFAOYSA-N dihydroxy(oxo)silane Chemical compound O[Si](O)=O IJKVHSBPTUYDLN-UHFFFAOYSA-N 0.000 description 1
- XPPKVPWEQAFLFU-UHFFFAOYSA-J diphosphate(4-) Chemical group [O-]P([O-])(=O)OP([O-])([O-])=O XPPKVPWEQAFLFU-UHFFFAOYSA-J 0.000 description 1
- 230000012010 growth Effects 0.000 description 1
- 230000035876 healing Effects 0.000 description 1
- 238000005342 ion exchange Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 238000005191 phase separation Methods 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 150000003377 silicon compounds Chemical class 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 238000005245 sintering Methods 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011343 solid material Substances 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 230000000638 stimulation Effects 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C10/00—Devitrified glass ceramics, i.e. glass ceramics having a crystalline phase dispersed in a glassy phase and constituting at least 50% by weight of the total composition
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L24/00—Surgical adhesives or cements; Adhesives for colostomy devices
- A61L24/0047—Composite materials, i.e. containing one material dispersed in a matrix of the same or different material
- A61L24/0073—Composite materials, i.e. containing one material dispersed in a matrix of the same or different material with a macromolecular matrix
- A61L24/0084—Composite materials, i.e. containing one material dispersed in a matrix of the same or different material with a macromolecular matrix containing fillers of phosphorus-containing inorganic compounds, e.g. apatite
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L27/00—Materials for grafts or prostheses or for coating grafts or prostheses
- A61L27/02—Inorganic materials
- A61L27/12—Phosphorus-containing materials, e.g. apatite
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61F—FILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
- A61F2310/00—Prostheses classified in A61F2/28 or A61F2/30 - A61F2/44 being constructed from or coated with a particular material
- A61F2310/00005—The prosthesis being constructed from a particular material
- A61F2310/00179—Ceramics or ceramic-like structures
- A61F2310/00293—Ceramics or ceramic-like structures containing a phosphorus-containing compound, e.g. apatite
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Public Health (AREA)
- Inorganic Chemistry (AREA)
- Materials Engineering (AREA)
- Veterinary Medicine (AREA)
- Epidemiology (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Composite Materials (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oral & Maxillofacial Surgery (AREA)
- Medicinal Chemistry (AREA)
- Dermatology (AREA)
- Surgery (AREA)
- Ceramic Engineering (AREA)
- Crystallography & Structural Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Transplantation (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Organic Chemistry (AREA)
- Materials For Medical Uses (AREA)
- Glass Compositions (AREA)
- Prostheses (AREA)
- Dental Prosthetics (AREA)
- Compositions Of Oxide Ceramics (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DD84259561A DD247888A1 (de) | 1984-01-24 | 1984-01-24 | Phosphatglaskeramik |
| DD03C/259561-1 | 1984-01-24 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS60166247A true JPS60166247A (ja) | 1985-08-29 |
| JPH0155204B2 JPH0155204B2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1989-11-22 |
Family
ID=5554270
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP60009299A Granted JPS60166247A (ja) | 1984-01-24 | 1985-01-23 | 燐酸塩ガラスセラミツク材料 |
Country Status (4)
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS62128947A (ja) * | 1985-08-07 | 1987-06-11 | Kyushu Refract Co Ltd | ＣａＯ−Ａｌ↓２Ｏ↓３−Ｐ↓２Ｏ↓５系結晶化ガラス |
Families Citing this family (36)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB8612387D0 (en) * | 1986-05-21 | 1986-07-16 | Univ Sheffield | Glass ceramics |
| JPS6350344A (ja) * | 1986-08-15 | 1988-03-03 | Yoshihiro Abe | ガラスセラミツクス組成物 |
| JPS63282140A (ja) * | 1987-05-11 | 1988-11-18 | Kuraray Co Ltd | 結晶化ガラス |
| US4784976A (en) * | 1987-11-27 | 1988-11-15 | Corning Glass Works | Glass-ceramics containing NZP-type crystals |
| US4829026A (en) * | 1988-05-06 | 1989-05-09 | Kuraray Co., Ltd. | Glass ceramics |
| US4874724A (en) * | 1988-10-17 | 1989-10-17 | Corning Incorporated | Alkali zinc aluminophosphate glass-ceramics |
| DD282180A5 (de) * | 1989-03-03 | 1990-09-05 | Univ Schiller Jena | Verfahren zur herstellung bioaktiver und mechanisch hoch belastbarer implantate |
| US5488018A (en) * | 1989-04-21 | 1996-01-30 | Limaye; Santosh Y. | Ultra low thermal expansion, highly thermal shock resistant ceramic |
| US5074916A (en) * | 1990-05-18 | 1991-12-24 | Geltech, Inc. | Alkali-free bioactive sol-gel compositions |
| EP0473048B1 (en) * | 1990-08-21 | 1996-11-27 | Asahi Glass Company Ltd. | Calcium phosphate type glass-ceramic |
| DE4110316A1 (de) * | 1991-03-28 | 1992-10-01 | Uwe Storch | Verwendung einer mischung fuer die herstellung von medizinischen implantaten |
| DE4113021C2 (de) * | 1991-04-20 | 1995-01-26 | Carus Carl Gustav | Resorbierbare Phosphatgläser und resorbierbare Phosphatglaskeramiken, Verfahren zu ihrer Herstellung und Verwendung |
| DE69214005T2 (de) * | 1991-05-01 | 1997-05-15 | Chichibu Onoda Cement Corp | Erhärtende Zusammensetzungen zur Verwendung in der Medizin oder Zahnheilkunde |
| US5840638A (en) * | 1996-12-23 | 1998-11-24 | Brookhaven Science Associates | Phosphate glasses for radioactive, hazardous and mixed waste immobilization |
| US6526984B1 (en) | 1998-04-22 | 2003-03-04 | St. Jude Medical Ab | Biocompatible material for implants |
| SE9801405D0 (sv) | 1998-04-22 | 1998-04-22 | Pacesetter Ab | Implant |
| US6102896A (en) * | 1999-09-08 | 2000-08-15 | Cambridge Biostability Limited | Disposable injector device |
| RU2251405C2 (ru) * | 2000-03-27 | 2005-05-10 | Шотт Глас | Композиции для косметических препаратов, средств личной гигиены, компонентов очищающего действия, пищевых добавок, способы их получения и применения |
| US6623762B2 (en) | 2001-02-16 | 2003-09-23 | Cambridge Biostability Ltd. | Composition and method for controlled release injections |
| US7750063B2 (en) | 2001-10-24 | 2010-07-06 | Pentron Clinical Technologies, Llc | Dental filling material |
| US7204875B2 (en) | 2001-10-24 | 2007-04-17 | Pentron Clinical Technologies, Llc | Dental filling material |
| US7204874B2 (en) | 2001-10-24 | 2007-04-17 | Pentron Clinical Technologies, Llc | Root canal filling material |
| US7211136B2 (en) | 2001-10-24 | 2007-05-01 | Pentron Clinical Technologies, Llc | Dental filling material |
| US7303817B2 (en) | 2001-10-24 | 2007-12-04 | Weitao Jia | Dental filling material |
| KR101110759B1 (ko) | 2003-02-04 | 2012-03-13 | 오스테오테크, 인코포레이티드 | 골임플란트용 폴리우레탄 |
| EP1789088A4 (en) | 2004-03-24 | 2009-12-30 | Doctor S Res Group Inc | METHODS FOR EXECUTING MEDICAL PROCEDURES FOR PROMOTING BONE GROWTH, METHODS OF MAKING BONE GROWTH PROMOTING COMPOSITIONS, AND APPARATUS FOR SUCH METHODS |
| AU2005306857A1 (en) | 2004-11-16 | 2006-05-26 | 3M Innovative Properties Company | Dental compositions with calcium phosphorus releasing glass |
| US8710114B2 (en) * | 2004-11-16 | 2014-04-29 | 3M Innovative Properties Company | Dental fillers including a phosphorus containing surface treatment, and compositions and methods thereof |
| EP1811944B1 (en) | 2004-11-16 | 2010-09-08 | 3M Innovative Properties Company | Compositions including a caseinate treated dental filler |
| CN101098673B (zh) | 2004-11-16 | 2012-02-29 | 3M创新有限公司 | 包括磷酸盐的牙科填料和组合物 |
| US7431734B2 (en) * | 2005-02-04 | 2008-10-07 | Intellistem Orthopaedic Innovations, Inc. | Implanted prosthetic device |
| JP5110953B2 (ja) * | 2007-05-02 | 2012-12-26 | 国立大学法人九州大学 | インプラント |
| US20100086497A1 (en) * | 2008-10-08 | 2010-04-08 | Biofilm Limited | Tooth remineralisation |
| US8790707B2 (en) | 2008-12-11 | 2014-07-29 | 3M Innovative Properties Company | Surface-treated calcium phosphate particles suitable for oral care and dental compositions |
| WO2010131659A1 (ja) * | 2009-05-13 | 2010-11-18 | 旭硝子株式会社 | 固体撮像素子パッケージ用カバーガラス |
| CN114984313B (zh) * | 2022-04-26 | 2023-06-20 | 江苏省中医药研究院(江苏省中西医结合医院) | 一种提高丝素蛋白支架压电效应的方法 |
Family Cites Families (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3519445A (en) * | 1967-11-06 | 1970-07-07 | Corning Glass Works | Al2o3-p2o5-b2o3 glass-ceramic articles and methods |
| US3981736A (en) * | 1973-05-23 | 1976-09-21 | Ernst Leitz G.M.B.H. | Biocompatible glass ceramic material |
| US3919723A (en) * | 1974-05-20 | 1975-11-18 | Friedrichsfeld Gmbh | Bone shaft or bone joint prosthesis and process |
| CH595293A5 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) * | 1975-02-20 | 1978-02-15 | Battelle Memorial Institute | |
| JPS5264199A (en) * | 1975-11-21 | 1977-05-27 | Tokyo Ika Shika Daigakuchiyou | Artificial bone and dental root with sintered apatite and method of producing same |
| US4097935A (en) * | 1976-07-21 | 1978-07-04 | Sterling Drug Inc. | Hydroxylapatite ceramic |
| US4159358A (en) * | 1977-05-19 | 1979-06-26 | Board Of Regents, State Of Florida | Method of bonding a bioglass to metal |
| IL56141A (en) * | 1977-12-23 | 1981-10-30 | Sterling Drug Inc | Whitlockite ceramic and its manufacture |
| JPS58214B2 (ja) * | 1978-07-12 | 1983-01-05 | 株式会社日立製作所 | 多重化装置 |
| JPS5515044A (en) * | 1978-07-18 | 1980-02-01 | Aisin Seiki Co Ltd | Measuring unit for gap between bobbin case sword point and needle of sewing machine |
| JPS608985B2 (ja) * | 1979-08-10 | 1985-03-07 | 富士写真フイルム株式会社 | 結晶化ガラスおよびその製造方法 |
| JPS5777038A (en) * | 1980-10-28 | 1982-05-14 | Asahi Glass Co Ltd | Manufacture of crystallized glass from phosphate glass |
| DD218253A3 (de) * | 1982-02-26 | 1985-01-30 | Univ Schiller Jena | Maschinell bearbeitbare magnetische glaskeramik |
| US4576920A (en) * | 1985-05-23 | 1986-03-18 | Corning Glass Works | B2 O3 --P2 O5 --SiO2 glass-ceramics |
-
1984
- 1984-01-24 DD DD84259561A patent/DD247888A1/de not_active IP Right Cessation
- 1984-11-01 US US06/667,038 patent/US4698318A/en not_active Expired - Fee Related
-
1985
- 1985-01-07 DE DE19853500287 patent/DE3500287A1/de active Granted
- 1985-01-23 JP JP60009299A patent/JPS60166247A/ja active Granted
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS62128947A (ja) * | 1985-08-07 | 1987-06-11 | Kyushu Refract Co Ltd | ＣａＯ−Ａｌ↓２Ｏ↓３−Ｐ↓２Ｏ↓５系結晶化ガラス |
Also Published As
| Publication number | Publication date |
|---|---|
| DE3500287A1 (de) | 1985-08-01 |
| DD247888A1 (de) | 1987-07-22 |
| DE3500287C2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1988-03-10 |
| JPH0155204B2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1989-11-22 |
| US4698318A (en) | 1987-10-06 |
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