JPS6012433B2 - 亜鉛電着浴組成物 - Google Patents
亜鉛電着浴組成物Info
- Publication number
- JPS6012433B2 JPS6012433B2 JP51021750A JP2175076A JPS6012433B2 JP S6012433 B2 JPS6012433 B2 JP S6012433B2 JP 51021750 A JP51021750 A JP 51021750A JP 2175076 A JP2175076 A JP 2175076A JP S6012433 B2 JPS6012433 B2 JP S6012433B2
- Authority
- JP
- Japan
- Prior art keywords
- zinc
- glycidol
- bath composition
- electrodeposition
- electrodeposition bath
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000004070 electrodeposition Methods 0.000 title claims description 27
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 title claims description 18
- 239000011701 zinc Substances 0.000 title claims description 18
- 229910052725 zinc Inorganic materials 0.000 title claims description 18
- 239000000203 mixture Substances 0.000 title claims description 10
- 229920000642 polymer Polymers 0.000 claims description 17
- CTKINSOISVBQLD-UHFFFAOYSA-N Glycidol Chemical compound OCC1CO1 CTKINSOISVBQLD-UHFFFAOYSA-N 0.000 claims description 16
- 229920002557 polyglycidol polymer Polymers 0.000 claims description 14
- 229920001577 copolymer Polymers 0.000 claims description 10
- 230000002378 acidificating effect Effects 0.000 claims description 7
- 125000002947 alkylene group Chemical group 0.000 claims description 7
- JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 claims description 6
- 239000000654 additive Substances 0.000 claims description 4
- 150000001875 compounds Chemical class 0.000 claims description 4
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 claims description 4
- 229960001763 zinc sulfate Drugs 0.000 claims description 4
- 229910000368 zinc sulfate Inorganic materials 0.000 claims description 4
- BRLQWZUYTZBJKN-UHFFFAOYSA-N Epichlorohydrin Chemical compound ClCC1CO1 BRLQWZUYTZBJKN-UHFFFAOYSA-N 0.000 claims description 3
- 239000011592 zinc chloride Substances 0.000 claims description 3
- 235000005074 zinc chloride Nutrition 0.000 claims description 3
- -1 zinc fluoroborate Chemical compound 0.000 claims description 3
- 150000003839 salts Chemical group 0.000 claims description 2
- 230000000996 additive effect Effects 0.000 claims 3
- 150000003751 zinc Chemical class 0.000 claims 3
- JJKVMNNUINFIRK-UHFFFAOYSA-N 4-amino-n-(4-methoxyphenyl)benzamide Chemical compound C1=CC(OC)=CC=C1NC(=O)C1=CC=C(N)C=C1 JJKVMNNUINFIRK-UHFFFAOYSA-N 0.000 claims 2
- WHMDKBIGKVEYHS-IYEMJOQQSA-L Zinc gluconate Chemical compound [Zn+2].OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C([O-])=O.OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C([O-])=O WHMDKBIGKVEYHS-IYEMJOQQSA-L 0.000 claims 2
- ZOIORXHNWRGPMV-UHFFFAOYSA-N acetic acid;zinc Chemical compound [Zn].CC(O)=O.CC(O)=O ZOIORXHNWRGPMV-UHFFFAOYSA-N 0.000 claims 2
- 239000004246 zinc acetate Substances 0.000 claims 2
- 239000011670 zinc gluconate Substances 0.000 claims 2
- 229960000306 zinc gluconate Drugs 0.000 claims 2
- 235000011478 zinc gluconate Nutrition 0.000 claims 2
- 239000007864 aqueous solution Substances 0.000 claims 1
- 238000003287 bathing Methods 0.000 claims 1
- 239000003792 electrolyte Substances 0.000 claims 1
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 24
- 238000007747 plating Methods 0.000 description 15
- 230000000052 comparative effect Effects 0.000 description 14
- 238000000034 method Methods 0.000 description 12
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 8
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 6
- WTEOIRVLGSZEPR-UHFFFAOYSA-N boron trifluoride Chemical compound FB(F)F WTEOIRVLGSZEPR-UHFFFAOYSA-N 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- KZMGYPLQYOPHEL-UHFFFAOYSA-N Boron trifluoride etherate Chemical compound FB(F)F.CCOCC KZMGYPLQYOPHEL-UHFFFAOYSA-N 0.000 description 4
- 235000019270 ammonium chloride Nutrition 0.000 description 4
- 238000006116 polymerization reaction Methods 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- 229910015900 BF3 Inorganic materials 0.000 description 3
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 3
- 239000004327 boric acid Substances 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 239000002202 Polyethylene glycol Substances 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 2
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 2
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 2
- 235000011130 ammonium sulphate Nutrition 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 230000010287 polarization Effects 0.000 description 2
- 229920001223 polyethylene glycol Polymers 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- UMGDCJDMYOKAJW-UHFFFAOYSA-N thiourea Chemical group NC(N)=S UMGDCJDMYOKAJW-UHFFFAOYSA-N 0.000 description 2
- WSLDOOZREJYCGB-UHFFFAOYSA-N 1,2-Dichloroethane Chemical compound ClCCCl WSLDOOZREJYCGB-UHFFFAOYSA-N 0.000 description 1
- RVBIGVSFBVOJSQ-UHFFFAOYSA-N 2-methyloxirane;oxirane;2-phenyloxirane Chemical compound C1CO1.CC1CO1.C1OC1C1=CC=CC=C1 RVBIGVSFBVOJSQ-UHFFFAOYSA-N 0.000 description 1
- SSZWWUDQMAHNAQ-UHFFFAOYSA-N 3-chloropropane-1,2-diol Chemical compound OCC(O)CCl SSZWWUDQMAHNAQ-UHFFFAOYSA-N 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- XFXPMWWXUTWYJX-UHFFFAOYSA-N Cyanide Chemical compound N#[C-] XFXPMWWXUTWYJX-UHFFFAOYSA-N 0.000 description 1
- RGHNJXZEOKUKBD-SQOUGZDYSA-M D-gluconate Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C([O-])=O RGHNJXZEOKUKBD-SQOUGZDYSA-M 0.000 description 1
- 241000238557 Decapoda Species 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- 108010010803 Gelatin Chemical group 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 1
- VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 description 1
- AWMVMTVKBNGEAK-UHFFFAOYSA-N Styrene oxide Chemical compound C1OC1C1=CC=CC=C1 AWMVMTVKBNGEAK-UHFFFAOYSA-N 0.000 description 1
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical group NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- DIZPMCHEQGEION-UHFFFAOYSA-H aluminium sulfate (anhydrous) Chemical compound [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 description 1
- 150000003934 aromatic aldehydes Chemical class 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 150000001805 chlorine compounds Chemical class 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 238000003795 desorption Methods 0.000 description 1
- 239000002659 electrodeposit Substances 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 229920000159 gelatin Chemical group 0.000 description 1
- 239000008273 gelatin Chemical group 0.000 description 1
- 235000019322 gelatine Nutrition 0.000 description 1
- 235000011852 gelatine desserts Nutrition 0.000 description 1
- 229940050410 gluconate Drugs 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 239000002198 insoluble material Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 150000002814 niacins Chemical group 0.000 description 1
- 235000001968 nicotinic acid Nutrition 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 239000001632 sodium acetate Substances 0.000 description 1
- 235000017281 sodium acetate Nutrition 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- IIACRCGMVDHOTQ-UHFFFAOYSA-M sulfamate Chemical compound NS([O-])(=O)=O IIACRCGMVDHOTQ-UHFFFAOYSA-M 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- YWYZEGXAUVWDED-UHFFFAOYSA-N triammonium citrate Chemical compound [NH4+].[NH4+].[NH4+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O YWYZEGXAUVWDED-UHFFFAOYSA-N 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- GTLDTDOJJJZVBW-UHFFFAOYSA-N zinc cyanide Chemical compound [Zn+2].N#[C-].N#[C-] GTLDTDOJJJZVBW-UHFFFAOYSA-N 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
- 229940118149 zinc sulfate monohydrate Drugs 0.000 description 1
- RNZCSKGULNFAMC-UHFFFAOYSA-L zinc;hydrogen sulfate;hydroxide Chemical compound O.[Zn+2].[O-]S([O-])(=O)=O RNZCSKGULNFAMC-UHFFFAOYSA-L 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D3/00—Electroplating: Baths therefor
- C25D3/02—Electroplating: Baths therefor from solutions
- C25D3/22—Electroplating: Baths therefor from solutions of zinc
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Electroplating And Plating Baths Therefor (AREA)
- Paints Or Removers (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US05/567,346 US3945894A (en) | 1975-04-11 | 1975-04-11 | Bath composition and method of electrodepositing utilizing the same |
| US567346 | 2006-12-06 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS51121042A JPS51121042A (en) | 1976-10-22 |
| JPS6012433B2 true JPS6012433B2 (ja) | 1985-04-01 |
Family
ID=24266778
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP51021750A Expired JPS6012433B2 (ja) | 1975-04-11 | 1976-02-28 | 亜鉛電着浴組成物 |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US3945894A (enExample) |
| JP (1) | JPS6012433B2 (enExample) |
| CA (1) | CA1075192A (enExample) |
| DE (1) | DE2609917C2 (enExample) |
| FR (1) | FR2307061A1 (enExample) |
| GB (1) | GB1540163A (enExample) |
| IT (1) | IT1057499B (enExample) |
| SE (1) | SE417988B (enExample) |
Families Citing this family (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5356139A (en) * | 1976-11-01 | 1978-05-22 | Shinko Electric Co Ltd | High frequency arc welding machine |
| US5290921A (en) * | 1990-01-08 | 1994-03-01 | Milliken Research Corporation | Intermediates and colorants having primary hydroxyl enriched poly (oxyalkylene) moieties and their preparation |
| US5082938A (en) * | 1990-03-01 | 1992-01-21 | Milliken Research Corporation | Organic materials containing poly(oxyalkylene) moieties having enhanced functionality and their preparation |
| US5591833A (en) * | 1990-06-28 | 1997-01-07 | Milliken Research Corporation | Colorants and intermediates therefor having branched poly(oxyalkylene)moieties, and their manufacture |
| US6822068B2 (en) * | 1998-12-22 | 2004-11-23 | Bayer Aktiengesellschaft | Method for producing highly-branched glycidol-based polyols |
| DE10058896C1 (de) * | 2000-10-19 | 2002-06-13 | Atotech Deutschland Gmbh | Elektrolytisches Kupferbad, dessen Verwendung und Verfahren zur Abscheidung einer matten Kupferschicht |
| EP1341951B1 (en) | 2000-10-19 | 2004-05-19 | ATOTECH Deutschland GmbH | Copper bath and method of depositing a matt copper coating |
| JP4249438B2 (ja) * | 2002-07-05 | 2009-04-02 | 日本ニュークローム株式会社 | 銅―錫合金めっき用ピロリン酸浴 |
| US6851200B2 (en) * | 2003-03-14 | 2005-02-08 | Hopkins Manufacturing Corporation | Reflecting lighted level |
| DE602005022650D1 (de) * | 2004-04-26 | 2010-09-16 | Rohm & Haas Elect Mat | Verbessertes Plattierungsverfahren |
| US20080169199A1 (en) * | 2007-01-17 | 2008-07-17 | Chang Gung University | Trivalent chromium electroplating solution and an electroplating process with the solution |
| ES2478267T3 (es) | 2012-01-25 | 2014-07-21 | Atotech Deutschland Gmbh | Método para producir depósitos de cobre mate |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB602591A (en) * | 1945-02-12 | 1948-05-31 | Du Pont | Improvements in or relating to the electro-deposition of metals |
| US2791554A (en) * | 1954-09-22 | 1957-05-07 | Ann F Hull | Method of electrodepositing zinc |
| US2989449A (en) * | 1960-04-06 | 1961-06-20 | Du Pont | Electrodeposition of zinc |
| DE1184172B (de) * | 1961-08-31 | 1964-12-23 | Dehydag Gmbh | Verfahren zum galvanischen Abscheiden festhaftender und hochglaenzender Kupferueberzuege |
| US3186926A (en) * | 1962-08-13 | 1965-06-01 | Hofmann Hans | Electroplating solution containing a diester of selenious acid |
| US3294689A (en) * | 1963-10-24 | 1966-12-27 | John S Pierce | Synergistic sequestering agent |
| US3838026A (en) * | 1971-05-10 | 1974-09-24 | Elektro Plating Patent Holding | Acidic zinc electroplating bath |
| US3745099A (en) * | 1971-06-11 | 1973-07-10 | Enthone | Alkaline bright zinc electroplating |
| US3751348A (en) * | 1971-06-14 | 1973-08-07 | Enthone | Alkaline bright zinc electroplating |
| US3855085A (en) * | 1973-06-14 | 1974-12-17 | Du Pont | Acid zinc electroplating electrolyte, process and additive |
-
1975
- 1975-04-11 US US05/567,346 patent/US3945894A/en not_active Expired - Lifetime
-
1976
- 1976-01-16 CA CA243,909A patent/CA1075192A/en not_active Expired
- 1976-02-04 SE SE7601203A patent/SE417988B/xx not_active IP Right Cessation
- 1976-02-28 JP JP51021750A patent/JPS6012433B2/ja not_active Expired
- 1976-03-09 FR FR7606722A patent/FR2307061A1/fr active Granted
- 1976-03-10 DE DE2609917A patent/DE2609917C2/de not_active Expired
- 1976-04-09 GB GB14564/76A patent/GB1540163A/en not_active Expired
- 1976-04-09 IT IT48940/76A patent/IT1057499B/it active
Also Published As
| Publication number | Publication date |
|---|---|
| SE417988B (sv) | 1981-04-27 |
| FR2307061B1 (enExample) | 1980-12-26 |
| FR2307061A1 (fr) | 1976-11-05 |
| DE2609917C2 (de) | 1982-06-16 |
| DE2609917A1 (de) | 1976-10-21 |
| SE7601203L (sv) | 1976-10-12 |
| IT1057499B (it) | 1982-03-10 |
| CA1075192A (en) | 1980-04-08 |
| JPS51121042A (en) | 1976-10-22 |
| GB1540163A (en) | 1979-02-07 |
| US3945894A (en) | 1976-03-23 |
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